ES2627435T3 - Método de utilización de polímeros funcionalizados con aldehído para aumentar el rendimiento de la máquina de papel y mejorar el apresto - Google Patents
Método de utilización de polímeros funcionalizados con aldehído para aumentar el rendimiento de la máquina de papel y mejorar el apresto Download PDFInfo
- Publication number
- ES2627435T3 ES2627435T3 ES11838677.0T ES11838677T ES2627435T3 ES 2627435 T3 ES2627435 T3 ES 2627435T3 ES 11838677 T ES11838677 T ES 11838677T ES 2627435 T3 ES2627435 T3 ES 2627435T3
- Authority
- ES
- Spain
- Prior art keywords
- composition
- aldehyde
- polymers
- sizing
- functionalized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 137
- 238000004513 sizing Methods 0.000 title claims description 75
- 238000000034 method Methods 0.000 title claims description 50
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 claims abstract description 67
- 239000000178 monomer Substances 0.000 claims abstract description 51
- 125000000129 anionic group Chemical group 0.000 claims abstract description 15
- 125000002091 cationic group Chemical group 0.000 claims abstract description 15
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 6
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 6
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000000087 stabilizing effect Effects 0.000 claims abstract description 3
- YAXXOCZAXKLLCV-UHFFFAOYSA-N 3-dodecyloxolane-2,5-dione Chemical class CCCCCCCCCCCCC1CC(=O)OC1=O YAXXOCZAXKLLCV-UHFFFAOYSA-N 0.000 claims abstract 2
- 150000001299 aldehydes Chemical class 0.000 claims description 51
- 239000000123 paper Substances 0.000 claims description 29
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000000654 additive Substances 0.000 claims description 19
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000011111 cardboard Substances 0.000 claims description 17
- 239000002243 precursor Substances 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 15
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 10
- 229940015043 glyoxal Drugs 0.000 claims description 9
- 239000011087 paperboard Substances 0.000 claims description 8
- 239000008346 aqueous phase Substances 0.000 claims description 7
- 150000001408 amides Chemical class 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 3
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 238000011068 loading method Methods 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 229930040373 Paraformaldehyde Natural products 0.000 claims 1
- 229920002866 paraformaldehyde Polymers 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 abstract description 4
- 239000000839 emulsion Substances 0.000 description 61
- -1 diallyl alkylammonium halide Chemical class 0.000 description 27
- 150000003839 salts Chemical class 0.000 description 19
- 239000003381 stabilizer Substances 0.000 description 17
- 239000002245 particle Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- 238000006116 polymerization reaction Methods 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 230000008901 benefit Effects 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 10
- 125000003118 aryl group Chemical group 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 9
- 238000009826 distribution Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 230000000996 additive effect Effects 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- 125000003368 amide group Chemical group 0.000 description 7
- 125000003277 amino group Chemical group 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 6
- 239000004908 Emulsion polymer Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 125000003710 aryl alkyl group Chemical group 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 230000001965 increasing effect Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- 238000013459 approach Methods 0.000 description 4
- 229920006317 cationic polymer Polymers 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 238000007306 functionalization reaction Methods 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 229920002401 polyacrylamide Polymers 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 229920003169 water-soluble polymer Polymers 0.000 description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 229920001131 Pulp (paper) Polymers 0.000 description 3
- 150000003926 acrylamides Chemical class 0.000 description 3
- 125000003172 aldehyde group Chemical group 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 239000011436 cob Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 239000004815 dispersion polymer Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 3
- 239000006174 pH buffer Substances 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000012674 dispersion polymerization Methods 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229940014800 succinic anhydride Drugs 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000007762 w/o emulsion Substances 0.000 description 2
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- WDRZVZVXHZNSFG-UHFFFAOYSA-N 1-ethenylpyridin-1-ium Chemical compound C=C[N+]1=CC=CC=C1 WDRZVZVXHZNSFG-UHFFFAOYSA-N 0.000 description 1
- CCTFAOUOYLVUFG-UHFFFAOYSA-N 2-(1-amino-1-imino-2-methylpropan-2-yl)azo-2-methylpropanimidamide Chemical compound NC(=N)C(C)(C)N=NC(C)(C)C(N)=N CCTFAOUOYLVUFG-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- ZSZRUEAFVQITHH-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 2-(trimethylazaniumyl)ethyl phosphate Chemical compound CC(=C)C(=O)OCCOP([O-])(=O)OCC[N+](C)(C)C ZSZRUEAFVQITHH-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- QHVBLSNVXDSMEB-UHFFFAOYSA-N 2-(diethylamino)ethyl prop-2-enoate Chemical compound CCN(CC)CCOC(=O)C=C QHVBLSNVXDSMEB-UHFFFAOYSA-N 0.000 description 1
- SPPGBVHTKYQNLW-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate;sulfuric acid Chemical compound OS(O)(=O)=O.CN(C)CCOC(=O)C(C)=C SPPGBVHTKYQNLW-UHFFFAOYSA-N 0.000 description 1
- SSZXAJUPVKMUJH-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate;hydrochloride Chemical group Cl.CN(C)CCOC(=O)C=C SSZXAJUPVKMUJH-UHFFFAOYSA-N 0.000 description 1
- YGHMHBJQRYMXSQ-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate;sulfuric acid Chemical group OS(O)(=O)=O.CN(C)CCOC(=O)C=C YGHMHBJQRYMXSQ-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- BNZKJJKMNCBHIQ-UHFFFAOYSA-N 2-[(prop-2-enoylamino)methyl]butanoic acid Chemical compound CCC(C(O)=O)CNC(=O)C=C BNZKJJKMNCBHIQ-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- ZQRNRKASNNVFAJ-UHFFFAOYSA-N 3-[dimethyl(2-prop-2-enoyloxyethyl)azaniumyl]propane-1-sulfonate Chemical compound [O-]S(=O)(=O)CCC[N+](C)(C)CCOC(=O)C=C ZQRNRKASNNVFAJ-UHFFFAOYSA-N 0.000 description 1
- KVKJQOXYGGPBIW-UHFFFAOYSA-N 3-[dimethyl-[3-(prop-2-enoylamino)propyl]azaniumyl]propane-1-sulfonate Chemical compound [O-]S(=O)(=O)CCC[N+](C)(C)CCCNC(=O)C=C KVKJQOXYGGPBIW-UHFFFAOYSA-N 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- NYUTUWAFOUJLKI-UHFFFAOYSA-N 3-prop-2-enoyloxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCOC(=O)C=C NYUTUWAFOUJLKI-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- PPSBTBVJQPRDHL-UHFFFAOYSA-N C=C[N+]1=CN(CCCS(O)(=O)=O)C=C1.[Cl-] Chemical compound C=C[N+]1=CN(CCCS(O)(=O)=O)C=C1.[Cl-] PPSBTBVJQPRDHL-UHFFFAOYSA-N 0.000 description 1
- DPHNVXKAGOPSQK-UHFFFAOYSA-N CC(C(OC)=O)=CCCN(C)C.Cl Chemical compound CC(C(OC)=O)=CCCN(C)C.Cl DPHNVXKAGOPSQK-UHFFFAOYSA-N 0.000 description 1
- FYPNNJFHXFVZRS-UHFFFAOYSA-N CC(C([S+](CCCS([O-])(=O)=O)CCSC)=O)=C Chemical compound CC(C([S+](CCCS([O-])(=O)=O)CCSC)=O)=C FYPNNJFHXFVZRS-UHFFFAOYSA-N 0.000 description 1
- MUBCQMNWZAUBDA-UHFFFAOYSA-N C[S+](CCOC(C=C)=O)CC([O-])=O Chemical compound C[S+](CCOC(C=C)=O)CC([O-])=O MUBCQMNWZAUBDA-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004819 Drying adhesive Substances 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000012726 Water-in-Oil Emulsion Polymerization Methods 0.000 description 1
- MZVQCMJNVPIDEA-UHFFFAOYSA-N [CH2]CN(CC)CC Chemical group [CH2]CN(CC)CC MZVQCMJNVPIDEA-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical group 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical group ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 230000009435 amidation Effects 0.000 description 1
- 238000007112 amidation reaction Methods 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- WPKYZIPODULRBM-UHFFFAOYSA-N azane;prop-2-enoic acid Chemical compound N.OC(=O)C=C WPKYZIPODULRBM-UHFFFAOYSA-N 0.000 description 1
- DZGUJOWBVDZNNF-UHFFFAOYSA-N azanium;2-methylprop-2-enoate Chemical compound [NH4+].CC(=C)C([O-])=O DZGUJOWBVDZNNF-UHFFFAOYSA-N 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- LWMFAFLIWMPZSX-UHFFFAOYSA-N bis[2-(4,5-dihydro-1h-imidazol-2-yl)propan-2-yl]diazene Chemical compound N=1CCNC=1C(C)(C)N=NC(C)(C)C1=NCCN1 LWMFAFLIWMPZSX-UHFFFAOYSA-N 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229920003118 cationic copolymer Polymers 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- WQHCGPGATAYRLN-UHFFFAOYSA-N chloromethane;2-(dimethylamino)ethyl prop-2-enoate Chemical compound ClC.CN(C)CCOC(=O)C=C WQHCGPGATAYRLN-UHFFFAOYSA-N 0.000 description 1
- BOYBOCSCIOGQOZ-UHFFFAOYSA-N chloromethane;2-methylprop-2-enoic acid Chemical compound ClC.CC(=C)C(O)=O BOYBOCSCIOGQOZ-UHFFFAOYSA-N 0.000 description 1
- ZTUMLBMROBHIIH-UHFFFAOYSA-N chloromethylbenzene;2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound ClCC1=CC=CC=C1.CN(C)CCOC(=O)C(C)=C ZTUMLBMROBHIIH-UHFFFAOYSA-N 0.000 description 1
- CEJFYGPXPSZIID-UHFFFAOYSA-N chloromethylbenzene;2-(dimethylamino)ethyl prop-2-enoate Chemical compound ClCC1=CC=CC=C1.CN(C)CCOC(=O)C=C CEJFYGPXPSZIID-UHFFFAOYSA-N 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000000412 dendrimer Substances 0.000 description 1
- 229920000736 dendritic polymer Polymers 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 description 1
- IOMDIVZAGXCCAC-UHFFFAOYSA-M diethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](CC)(CC)CC=C IOMDIVZAGXCCAC-UHFFFAOYSA-M 0.000 description 1
- JCRDPEHHTDKTGB-UHFFFAOYSA-N dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound Cl.CN(C)CCOC(=O)C(C)=C JCRDPEHHTDKTGB-UHFFFAOYSA-N 0.000 description 1
- ZMYRMZSAJVTETR-UHFFFAOYSA-N dimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound Cl.CN(C)CCCNC(=O)C=C ZMYRMZSAJVTETR-UHFFFAOYSA-N 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- IWVKTOUOPHGZRX-UHFFFAOYSA-M methyl 2-methylprop-2-enoate;2-methylprop-2-enoate Chemical compound CC(=C)C([O-])=O.COC(=O)C(C)=C IWVKTOUOPHGZRX-UHFFFAOYSA-M 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- OVHHHVAVHBHXAK-UHFFFAOYSA-N n,n-diethylprop-2-enamide Chemical compound CCN(CC)C(=O)C=C OVHHHVAVHBHXAK-UHFFFAOYSA-N 0.000 description 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 description 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- PMPYZXFIZYUAEN-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]prop-2-enamide;methyl hydrogen sulfate Chemical compound COS(O)(=O)=O.CN(C)CCCNC(=O)C=C PMPYZXFIZYUAEN-UHFFFAOYSA-N 0.000 description 1
- AXINSVAJCOSLQU-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]prop-2-enamide;sulfuric acid Chemical compound OS(O)(=O)=O.CN(C)CCCNC(=O)C=C AXINSVAJCOSLQU-UHFFFAOYSA-N 0.000 description 1
- YRVUCYWJQFRCOB-UHFFFAOYSA-N n-butylprop-2-enamide Chemical compound CCCCNC(=O)C=C YRVUCYWJQFRCOB-UHFFFAOYSA-N 0.000 description 1
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004344 phenylpropyl group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000962 poly(amidoamine) Polymers 0.000 description 1
- RZKYDQNMAUSEDZ-UHFFFAOYSA-N prop-2-enylphosphonic acid Chemical compound OP(O)(=O)CC=C RZKYDQNMAUSEDZ-UHFFFAOYSA-N 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920013730 reactive polymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007652 sheet-forming process Methods 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- SONHXMAHPHADTF-UHFFFAOYSA-M sodium;2-methylprop-2-enoate Chemical compound [Na+].CC(=C)C([O-])=O SONHXMAHPHADTF-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000007056 transamidation reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C3/00—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material
- B05C3/02—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/47—Condensation polymers of aldehydes or ketones
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08L57/06—Homopolymers or copolymers containing elements other than carbon and hydrogen
- C08L57/10—Homopolymers or copolymers containing elements other than carbon and hydrogen containing oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08L57/06—Homopolymers or copolymers containing elements other than carbon and hydrogen
- C08L57/12—Homopolymers or copolymers containing elements other than carbon and hydrogen containing nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US938017 | 2010-11-02 | ||
| US12/938,017 US8709207B2 (en) | 2010-11-02 | 2010-11-02 | Method of using aldehyde-functionalized polymers to increase papermachine performance and enhance sizing |
| PCT/US2011/058783 WO2012061384A2 (en) | 2010-11-02 | 2011-11-01 | Method of using aldehyde-functionalized polymers to increase papermachine performance and enhance sizing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2627435T3 true ES2627435T3 (es) | 2017-07-28 |
Family
ID=45995353
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES11838677.0T Active ES2627435T3 (es) | 2010-11-02 | 2011-11-01 | Método de utilización de polímeros funcionalizados con aldehído para aumentar el rendimiento de la máquina de papel y mejorar el apresto |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US8709207B2 (enExample) |
| EP (1) | EP2635634B1 (enExample) |
| JP (1) | JP5925794B2 (enExample) |
| KR (1) | KR101789526B1 (enExample) |
| CN (1) | CN102892832B (enExample) |
| AU (1) | AU2011323531B2 (enExample) |
| BR (1) | BR112013010635B1 (enExample) |
| CA (1) | CA2816565C (enExample) |
| ES (1) | ES2627435T3 (enExample) |
| MX (1) | MX351556B (enExample) |
| MY (1) | MY163925A (enExample) |
| RU (1) | RU2595681C2 (enExample) |
| TW (1) | TWI582290B (enExample) |
| WO (1) | WO2012061384A2 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8088250B2 (en) | 2008-11-26 | 2012-01-03 | Nalco Company | Method of increasing filler content in papermaking |
| US9752283B2 (en) | 2007-09-12 | 2017-09-05 | Ecolab Usa Inc. | Anionic preflocculation of fillers used in papermaking |
| US8852400B2 (en) * | 2010-11-02 | 2014-10-07 | Ecolab Usa Inc. | Emulsification of alkenyl succinic anhydride with an amine-containing homopolymer or copolymer |
| US8636875B2 (en) * | 2011-01-20 | 2014-01-28 | Hercules Incorporated | Enhanced dry strength and drainage performance by combining glyoxalated acrylamide-containing polymers with cationic aqueous dispersion polymers |
| CN103132383B (zh) * | 2011-11-25 | 2017-04-12 | 纳尔科公司 | 在造纸中用于改善纸强度助剂性能的浆料预处理 |
| US8747616B2 (en) | 2012-09-12 | 2014-06-10 | Ecolab Usa Inc | Method for the emulsification of ASA with polyamidoamine epihalohydrin (PAE) |
| CN105026648B (zh) * | 2013-03-01 | 2017-12-08 | 巴斯夫欧洲公司 | 施胶剂水乳液 |
| ES2987934T3 (es) | 2013-03-13 | 2024-11-18 | Nalco Co | Método de uso de polímeros funcionalizados con aldehído para aumentar el rendimiento de la máquina para fabricar papel y mejorar el encolado |
| US9562326B2 (en) * | 2013-03-14 | 2017-02-07 | Kemira Oyj | Compositions and methods of making paper products |
| CN104746388B (zh) * | 2013-12-25 | 2018-05-08 | 艺康美国股份有限公司 | 一种提高高分子乳化剂乳化的asa 乳液的施胶效果的方法 |
| US9567708B2 (en) | 2014-01-16 | 2017-02-14 | Ecolab Usa Inc. | Wet end chemicals for dry end strength in paper |
| US9920482B2 (en) | 2014-10-06 | 2018-03-20 | Ecolab Usa Inc. | Method of increasing paper strength |
| US9702086B2 (en) | 2014-10-06 | 2017-07-11 | Ecolab Usa Inc. | Method of increasing paper strength using an amine containing polymer composition |
| US9689115B2 (en) * | 2014-12-26 | 2017-06-27 | Westrock Mwv, Llc | Sizing of paperboard |
| CN106317421B (zh) * | 2015-06-19 | 2019-09-10 | 上海东升新材料有限公司 | 一种高性能阳离子松香胶及其制备方法 |
| CN107849821B (zh) | 2015-08-06 | 2021-12-14 | 艺康美国股份有限公司 | 用于纸张强度和脱水的醛官能化聚合物 |
| CN106917324B (zh) | 2015-12-25 | 2019-11-08 | 艺康美国股份有限公司 | 一种造纸施胶方法及其制备的纸张 |
| KR102063409B1 (ko) * | 2015-12-25 | 2020-01-07 | 세이코 피엠씨 가부시키가이샤 | 폴리아크릴아미드계 제지용 첨가제 및 그의 제조 방법, 및 종이의 제조 방법 |
| US10006171B2 (en) * | 2016-04-25 | 2018-06-26 | Ecolab Usa Inc. | Methods and compositions for enhancing sizing in papermaking process |
| US10648133B2 (en) | 2016-05-13 | 2020-05-12 | Ecolab Usa Inc. | Tissue dust reduction |
| WO2021102266A1 (en) | 2019-11-22 | 2021-05-27 | Ecolab Usa Inc. | Di alkenyl succinic amide acids and processes for making and using same |
| CN118480984A (zh) * | 2023-07-25 | 2024-08-13 | 上海君周化工科技有限公司 | 一种烯基琥珀酸酐乳化施胶剂及其制备方法与应用 |
Family Cites Families (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2982749A (en) | 1957-07-15 | 1961-05-02 | Dow Chemical Co | Inverse suspension polymerization of water soluble unsaturated monomers |
| US3284393A (en) | 1959-11-04 | 1966-11-08 | Dow Chemical Co | Water-in-oil emulsion polymerization process for polymerizing watersoluble monomers |
| US3556932A (en) * | 1965-07-12 | 1971-01-19 | American Cyanamid Co | Water-soluble,ionic,glyoxylated,vinylamide,wet-strength resin and paper made therewith |
| US3734873A (en) | 1970-12-15 | 1973-05-22 | Nalco Chemical Co | Rapid dissolving water-soluble polymers |
| US4240935A (en) * | 1978-12-22 | 1980-12-23 | Hercules Incorporated | Ketene dimer paper sizing compositions |
| JPS60246893A (ja) * | 1984-01-27 | 1985-12-06 | ナルコ ケミカル カンパニ− | サイズ剤の調製方法 |
| AU577735B2 (en) | 1984-01-27 | 1988-09-29 | Nalco Chemical Company | Emulsion for paper sizing |
| US4657946A (en) | 1984-06-25 | 1987-04-14 | Nalco Chemical Company | Paper sizing method and emulsion |
| US4605702A (en) | 1984-06-27 | 1986-08-12 | American Cyanamid Company | Temporary wet strength resin |
| CA1267483A (en) | 1984-11-19 | 1990-04-03 | Hisao Takeda | Process for the production of a water-soluble polymer dispersion |
| US4603176A (en) | 1985-06-25 | 1986-07-29 | The Procter & Gamble Company | Temporary wet strength resins |
| US4919821A (en) | 1986-03-21 | 1990-04-24 | Nalco Chemical Company | Modified maleic anhydride polymers and the like for use as scale inhibitors |
| JPH0651755B2 (ja) | 1988-10-14 | 1994-07-06 | ハイモ株式会社 | 水溶性カチオンポリマー分散液の製造方法 |
| US5147908A (en) | 1990-09-24 | 1992-09-15 | Sequa Chemicals Inc. | Cationic polyvinyl alcohol binder additive |
| SE9103140L (sv) * | 1991-10-28 | 1993-04-29 | Eka Nobel Ab | Hydrofoberat papper |
| US5571380A (en) | 1992-01-08 | 1996-11-05 | Nalco Chemical Company | Papermaking process with improved retention and maintained formation |
| ES2126018T3 (es) | 1993-06-04 | 1999-03-16 | Nalco Chemical Co | Procedimiento de polimerizacion de dispersiones. |
| US5597858A (en) | 1993-06-10 | 1997-01-28 | Nalco Chemical Company | Hydrophobically associating dispersants used in forming polymer dispersions |
| AU8024794A (en) | 1993-12-09 | 1995-06-15 | Nalco Chemical Company | An improved process for the preparation of water soluble polymer dispersion |
| US6133368A (en) | 1993-12-09 | 2000-10-17 | Nalco Chemical Company | Seed process for salt dispersion polymer |
| US6610209B1 (en) | 1994-12-27 | 2003-08-26 | Ondeo Nalco Company | Use of polymers containing vinylamine/vinylformamide for the treatment of food processing wastewater |
| US5654198A (en) * | 1995-06-05 | 1997-08-05 | National Starch And Chemical Investment Holding Corporation | Detectable water-treatment polymers and methods for monitoring the concentration thereof |
| US5674362A (en) * | 1996-02-16 | 1997-10-07 | Callaway Corp. | Method for imparting strength to paper |
| US5837776A (en) | 1996-03-20 | 1998-11-17 | Nalco Chemical Company | Process for producing water soluble anionic dispersion polymers |
| US5605970A (en) | 1996-03-20 | 1997-02-25 | Nalco Chemical Company | Synthesis of high molecular weight anionic dispersion polymers |
| US6238521B1 (en) | 1996-05-01 | 2001-05-29 | Nalco Chemical Company | Use of diallyldimethylammonium chloride acrylamide dispersion copolymer in a papermaking process |
| US6013708A (en) | 1996-10-03 | 2000-01-11 | Cytec Technology Corp. | Cationic water-soluble polymer precipitation in salt solutions |
| DE19654390A1 (de) | 1996-12-27 | 1998-07-02 | Basf Ag | Verfahren zur Herstellung von Papier |
| US6426383B1 (en) | 1997-05-28 | 2002-07-30 | Nalco Chemical Company | Preparation of water soluble polymer dispersions from vinylamide monomers |
| US5985992A (en) | 1997-12-10 | 1999-11-16 | Cytec Technology Corp. | Anionic polymer products and processes |
| AU3217399A (en) | 1998-03-31 | 1999-10-18 | Callaway Corporation | Improving retention and drainage in alkaline fine paper |
| US6491790B1 (en) | 1998-09-10 | 2002-12-10 | Bayer Corporation | Methods for reducing amine odor in paper |
| CO5180563A1 (es) | 1999-01-25 | 2002-07-30 | Kimberly Clark Co | Polimeros de vinilo modificados que contienen medios de hidrocarbono anfifilico de y el metodo para su fabricacion |
| US6315866B1 (en) * | 2000-02-29 | 2001-11-13 | Nalco Chemical Company | Method of increasing the dry strength of paper products using cationic dispersion polymers |
| EP1314822A1 (en) * | 2001-11-19 | 2003-05-28 | Akzo Nobel N.V. | Process for sizing paper and sizing composition |
| US7641766B2 (en) | 2004-01-26 | 2010-01-05 | Nalco Company | Method of using aldehyde-functionalized polymers to enhance paper machine dewatering |
| US7119148B2 (en) | 2004-02-25 | 2006-10-10 | Georgia-Pacific Resins, Inc. | Glyoxylated polyacrylamide composition strengthening agent |
| US7488403B2 (en) | 2004-08-17 | 2009-02-10 | Cornel Hagiopol | Blends of glyoxalated polyacrylamides and paper strengthening agents |
| US7034087B2 (en) | 2004-08-17 | 2006-04-25 | Georgia-Pacific Resins, Inc. | Aldehyde scavengers for preparing temporary wet strength resins with longer shelf life |
| US7897013B2 (en) | 2004-08-17 | 2011-03-01 | Georgia-Pacific Chemicals Llc | Blends of glyoxalated polyacrylamides and paper strengthening agents |
| WO2006068964A2 (en) | 2004-12-21 | 2006-06-29 | Hercules Incorporated | Reactive cationic resins for use as dry and wet strength agents in sulfite ion-containing papermaking systems |
| US7455751B2 (en) | 2005-04-15 | 2008-11-25 | Nalco Company | Use of alkenyl succinic anhydride compounds derived from symmetrical olefins in internal sizing for paper production |
| US7550060B2 (en) | 2006-01-25 | 2009-06-23 | Nalco Company | Method and arrangement for feeding chemicals into a process stream |
| US7938934B2 (en) | 2006-01-25 | 2011-05-10 | Nalco Company | ASA emulsification with ultrasound |
| CN100507148C (zh) * | 2006-06-23 | 2009-07-01 | 华章电气（桐乡）有限公司 | 一种多层喷雾纸张表面施胶方法 |
| US7875676B2 (en) | 2006-09-07 | 2011-01-25 | Ciba Specialty Chemicals Corporation | Glyoxalation of vinylamide polymer |
| CN101688370A (zh) * | 2007-05-09 | 2010-03-31 | 巴科曼实验室国际公司 | 用于纸或纸板的烯基琥珀酸酐施胶乳液 |
| WO2008157321A2 (en) | 2007-06-15 | 2008-12-24 | Buckman Laboratories International, Inc. | High solids glyoxalated polyacrylamide |
| US8288502B2 (en) | 2009-12-18 | 2012-10-16 | Nalco Company | Aldehyde-functionalized polymers with enhanced stability |
-
2010
- 2010-11-02 US US12/938,017 patent/US8709207B2/en active Active
-
2011
- 2011-10-12 TW TW100136901A patent/TWI582290B/zh active
- 2011-11-01 CA CA2816565A patent/CA2816565C/en active Active
- 2011-11-01 CN CN201180023819.4A patent/CN102892832B/zh active Active
- 2011-11-01 MX MX2013004955A patent/MX351556B/es active IP Right Grant
- 2011-11-01 BR BR112013010635-2A patent/BR112013010635B1/pt active IP Right Grant
- 2011-11-01 KR KR1020137011361A patent/KR101789526B1/ko active Active
- 2011-11-01 EP EP11838677.0A patent/EP2635634B1/en not_active Revoked
- 2011-11-01 MY MYPI2013001543A patent/MY163925A/en unknown
- 2011-11-01 RU RU2013119833/05A patent/RU2595681C2/ru active
- 2011-11-01 AU AU2011323531A patent/AU2011323531B2/en active Active
- 2011-11-01 ES ES11838677.0T patent/ES2627435T3/es active Active
- 2011-11-01 JP JP2013537764A patent/JP5925794B2/ja active Active
- 2011-11-01 WO PCT/US2011/058783 patent/WO2012061384A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US8709207B2 (en) | 2014-04-29 |
| EP2635634B1 (en) | 2017-03-22 |
| TW201226659A (en) | 2012-07-01 |
| TWI582290B (zh) | 2017-05-11 |
| WO2012061384A2 (en) | 2012-05-10 |
| CA2816565A1 (en) | 2012-05-10 |
| RU2013119833A (ru) | 2014-12-10 |
| KR20140027054A (ko) | 2014-03-06 |
| CA2816565C (en) | 2020-08-04 |
| AU2011323531B2 (en) | 2017-02-02 |
| AU2011323531A1 (en) | 2013-05-23 |
| MY163925A (en) | 2017-11-15 |
| JP5925794B2 (ja) | 2016-05-25 |
| MX351556B (es) | 2017-10-19 |
| EP2635634A4 (en) | 2015-10-21 |
| WO2012061384A3 (en) | 2012-07-19 |
| MX2013004955A (es) | 2013-06-28 |
| US20120103547A1 (en) | 2012-05-03 |
| BR112013010635B1 (pt) | 2020-12-08 |
| JP2013543067A (ja) | 2013-11-28 |
| KR101789526B1 (ko) | 2017-10-25 |
| EP2635634A2 (en) | 2013-09-11 |
| AU2011323531A9 (en) | 2017-02-09 |
| CN102892832A (zh) | 2013-01-23 |
| RU2595681C2 (ru) | 2016-08-27 |
| BR112013010635A2 (pt) | 2016-08-09 |
| CN102892832B (zh) | 2016-01-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2627435T3 (es) | Método de utilización de polímeros funcionalizados con aldehído para aumentar el rendimiento de la máquina de papel y mejorar el apresto | |
| US8840759B2 (en) | Method of using aldehyde-functionalized polymers to increase papermachine performance and enhance sizing | |
| ES2425634T3 (es) | Polímeros funcionalizados con aldehído y su uso para aumentar la eliminación de agua de una máquina de papel | |
| TWI576359B (zh) | 具有增強穩定性的醛官能化聚合物 | |
| TWI624577B (zh) | 以含有胺之均聚物或共聚物對烯基琥珀酐行乳化作用 | |
| ES2987934T3 (es) | Método de uso de polímeros funcionalizados con aldehído para aumentar el rendimiento de la máquina para fabricar papel y mejorar el encolado |