TWI569819B - 用於鎂植入物材料上的生物相容性電漿電解塗覆物之貧電解質 - Google Patents
用於鎂植入物材料上的生物相容性電漿電解塗覆物之貧電解質 Download PDFInfo
- Publication number
- TWI569819B TWI569819B TW101141367A TW101141367A TWI569819B TW I569819 B TWI569819 B TW I569819B TW 101141367 A TW101141367 A TW 101141367A TW 101141367 A TW101141367 A TW 101141367A TW I569819 B TWI569819 B TW I569819B
- Authority
- TW
- Taiwan
- Prior art keywords
- implant
- mol
- magnesium
- coated
- ceramic layer
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/08—Materials for coatings
- A61L31/082—Inorganic materials
- A61L31/088—Other specific inorganic materials not covered by A61L31/084 or A61L31/086
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B17/00—Surgical instruments, devices or methods
- A61B17/56—Surgical instruments or methods for treatment of bones or joints; Devices specially adapted therefor
- A61B17/58—Surgical instruments or methods for treatment of bones or joints; Devices specially adapted therefor for osteosynthesis, e.g. bone plates, screws or setting implements
- A61B17/68—Internal fixation devices, including fasteners and spinal fixators, even if a part thereof projects from the skin
- A61B17/80—Cortical plates, i.e. bone plates; Instruments for holding or positioning cortical plates, or for compressing bones attached to cortical plates
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B17/00—Surgical instruments, devices or methods
- A61B17/56—Surgical instruments or methods for treatment of bones or joints; Devices specially adapted therefor
- A61B17/58—Surgical instruments or methods for treatment of bones or joints; Devices specially adapted therefor for osteosynthesis, e.g. bone plates, screws or setting implements
- A61B17/68—Internal fixation devices, including fasteners and spinal fixators, even if a part thereof projects from the skin
- A61B17/80—Cortical plates, i.e. bone plates; Instruments for holding or positioning cortical plates, or for compressing bones attached to cortical plates
- A61B17/8085—Cortical plates, i.e. bone plates; Instruments for holding or positioning cortical plates, or for compressing bones attached to cortical plates with pliable or malleable elements or having a mesh-like structure, e.g. small strips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F2/00—Filters implantable into blood vessels; Prostheses, i.e. artificial substitutes or replacements for parts of the body; Appliances for connecting them with the body; Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
- A61F2/02—Prostheses implantable into the body
- A61F2/28—Bones
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/02—Inorganic materials
- A61L31/022—Metals or alloys
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/08—Materials for coatings
- A61L31/082—Inorganic materials
- A61L31/086—Phosphorus-containing materials, e.g. apatite
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/14—Materials characterised by their function or physical properties, e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
- A61L31/148—Materials at least partially resorbable by the body
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/022—Anodisation on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/026—Anodisation with spark discharge
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/30—Anodisation of magnesium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/36—Phosphatising
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/54—Electroplating: Baths therefor from solutions of metals not provided for in groups C25D3/04 - C25D3/50
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F2210/00—Particular material properties of prostheses classified in groups A61F2/00 - A61F2/26 or A61F2/82 or A61F9/00 or A61F11/00 or subgroups thereof
- A61F2210/0076—Particular material properties of prostheses classified in groups A61F2/00 - A61F2/26 or A61F2/82 or A61F9/00 or A61F11/00 or subgroups thereof multilayered, e.g. laminated structures
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2400/00—Materials characterised by their function or physical properties
- A61L2400/18—Modification of implant surfaces in order to improve biocompatibility, cell growth, fixation of biomolecules, e.g. plasma treatment
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2420/00—Materials or methods for coatings medical devices
- A61L2420/02—Methods for coating medical devices
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2430/00—Materials or treatment for tissue regeneration
- A61L2430/02—Materials or treatment for tissue regeneration for reconstruction of bones; weight-bearing implants
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Surgery (AREA)
- Heart & Thoracic Surgery (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Orthopedic Medicine & Surgery (AREA)
- Vascular Medicine (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Biomedical Technology (AREA)
- Medical Informatics (AREA)
- Neurology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Molecular Biology (AREA)
- Transplantation (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Cardiology (AREA)
- Materials For Medical Uses (AREA)
- Prostheses (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161556563P | 2011-11-07 | 2011-11-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201334816A TW201334816A (zh) | 2013-09-01 |
| TWI569819B true TWI569819B (zh) | 2017-02-11 |
Family
ID=47179005
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW101141367A TWI569819B (zh) | 2011-11-07 | 2012-11-07 | 用於鎂植入物材料上的生物相容性電漿電解塗覆物之貧電解質 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US9066999B2 (enExample) |
| EP (1) | EP2776083B1 (enExample) |
| JP (1) | JP6177789B2 (enExample) |
| KR (1) | KR102122707B1 (enExample) |
| CN (1) | CN104023759B (enExample) |
| AU (1) | AU2012335990B2 (enExample) |
| BR (1) | BR112014010980B1 (enExample) |
| CA (1) | CA2854667C (enExample) |
| IN (1) | IN2014DN03158A (enExample) |
| TW (1) | TWI569819B (enExample) |
| WO (1) | WO2013070669A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3011979A4 (en) * | 2013-06-18 | 2017-02-15 | Olympus Corporation | Implant for living organisms |
| JP2015085098A (ja) * | 2013-11-01 | 2015-05-07 | オリンパス株式会社 | 生体用インプラント |
| JP2015228906A (ja) * | 2014-06-03 | 2015-12-21 | オリンパス株式会社 | 骨接合用インプラント |
| JP2015229792A (ja) * | 2014-06-05 | 2015-12-21 | オリンパス株式会社 | インプラントとその製造方法 |
| JP6253528B2 (ja) * | 2014-06-26 | 2017-12-27 | オリンパス株式会社 | インプラント |
| KR101695858B1 (ko) * | 2015-07-14 | 2017-01-13 | 전북대학교산학협력단 | 생체 분해성 임플란트 및 이의 제조방법 |
| WO2018134930A1 (ja) * | 2017-01-19 | 2018-07-26 | オリンパス株式会社 | 整形外科用インプラントおよびその製造方法 |
| EP3981444A1 (en) * | 2017-03-30 | 2022-04-13 | Biomet Manufacturing, LLC | Methods of modifying the porous surface of implants |
| KR102056844B1 (ko) | 2018-04-19 | 2019-12-17 | 조선대학교산학협력단 | 전해질 조성물과 그 조성물을 이용하는 플라즈마 전해 산화 공정이 포함된 임플란트 제조방법 |
| CN110585481B (zh) * | 2019-08-28 | 2021-12-17 | 华南师范大学 | 一种针对脊柱损伤修复的纳米氢氧化镁区域性涂布聚乳酸-己内酯支架的制备及应用 |
| CN113373491B (zh) * | 2020-12-15 | 2024-07-09 | 北京航空航天大学 | 一种类牙釉质结构复合材料的制备方法 |
| CN116940390A (zh) * | 2021-02-03 | 2023-10-24 | 博恩解决方案有限公司 | 用于骨科植入物的镁基多孔涂层 |
| DE102021103786B4 (de) | 2021-02-17 | 2023-07-20 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Implantat zum Implantieren in einen Organismus und Verfahren |
| CN116098691B (zh) * | 2022-12-30 | 2025-10-10 | 沪创医疗科技(上海)有限公司 | 可降解镁金属颅骨固定系统 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5811194A (en) * | 1991-11-27 | 1998-09-22 | Electro Chemical Engineering Gmbh | Method of producing oxide ceramic layers on barrier layer-forming metals and articles produced by the method |
| CN1267585C (zh) * | 1995-03-13 | 2006-08-02 | 镁技术有限公司 | 镁和镁基合金的阳极氧化法 |
| CN101484599A (zh) * | 2006-04-28 | 2009-07-15 | 生物镁系统有限公司 | 生物可降解的镁合金及其用途 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1105105A (en) * | 1912-02-10 | 1914-07-28 | William O'n Sherman | Surgical appliance. |
| DE8706912U1 (de) * | 1987-05-14 | 1987-08-27 | Howmedica GmbH, 2314 Schönkirchen | Kleinknochenplatte und Schrauben, insbesondere für die Versorgung von Frakturen des Schädel- und Gesichtsskeletts o. dgl. |
| US4905679A (en) * | 1988-02-22 | 1990-03-06 | M P Operation, Inc. | Bone fracture reduction device and method of internal fixation of bone fractures |
| DE3808609A1 (de) * | 1988-03-15 | 1989-09-28 | Electro Chem Eng Gmbh | Verfahren zur erzeugung von korrosions- und verschleissbestaendigen schutzschichten auf magnesium und magnesiumlegierungen |
| US5264113A (en) | 1991-07-15 | 1993-11-23 | Technology Applications Group, Inc. | Two-step electrochemical process for coating magnesium alloys |
| CN1081298C (zh) | 1999-03-17 | 2002-03-20 | 任久东 | 可伸缩杆 |
| JP2003515426A (ja) | 1999-12-06 | 2003-05-07 | ジンテーズ アクチエンゲゼルシャフト クール | 再吸収可能な骨板 |
| CN100342063C (zh) * | 2002-04-27 | 2007-10-10 | 中国科学院上海微系统与信息技术研究所 | 镁合金表面复合陶瓷质膜和生成方法 |
| US20050149032A1 (en) | 2003-12-30 | 2005-07-07 | Douglas Vaughen | Resorbable surgical fixation device |
| US7717946B2 (en) * | 2004-06-07 | 2010-05-18 | Degima Gmbh | Polymeric plate bendable without thermal energy and methods of manufacture |
| ZA200700096B (en) * | 2004-06-07 | 2008-05-28 | Synthes Gmbh | Orthopaedic implant with sensors |
| US20060016690A1 (en) * | 2004-07-23 | 2006-01-26 | Ilya Ostrovsky | Method for producing a hard coating with high corrosion resistance on articles made anodizable metals or alloys |
| KR100929133B1 (ko) * | 2006-09-22 | 2009-12-01 | 유앤아이 주식회사 | 생체분해성 금속을 포함하는 임플란트 및 이의 제조방법 |
| DE102008040253A1 (de) * | 2008-07-08 | 2010-01-14 | Biotronik Vi Patent Ag | Implantatsystem mit einem Funktionsimplantat aus abbaubarem Metallmaterial |
| DE102008037204B4 (de) * | 2008-08-11 | 2016-01-07 | Alfred Buck | Platte zur Fixierung von Knochenfragmenten sowie Verfahren zu deren Herstellung |
| DE102008037200B4 (de) * | 2008-08-11 | 2015-07-09 | Aap Implantate Ag | Verwendung eines Druckgussverfahrens zur Herstellung eines Implantats aus Magnesium sowie Magnesiumlegierung |
| US9107712B2 (en) * | 2008-09-15 | 2015-08-18 | Biomet C.V. | Bone plate system for hand fractures and other small bones |
| DE102008043970A1 (de) * | 2008-11-21 | 2010-05-27 | Biotronik Vi Patent Ag | Verfahren zur Herstellung einer korrosionshemmenden Beschichtung auf einem Implantat aus einer biokorrodierbaren Magnesiumlegierung sowie nach dem Verfahren hergestelltes Implantat |
| DE102008054400A1 (de) * | 2008-12-09 | 2010-06-10 | Biotronik Vi Patent Ag | Implantat und Verfahren zur Herstellung desselben |
| US9131973B2 (en) * | 2010-07-09 | 2015-09-15 | Medartis Ag | Osteosynthesis system |
| CN101871119B (zh) * | 2010-07-28 | 2012-01-18 | 哈尔滨工业大学 | 一种镁合金表面微弧氧化/喷涂复合膜的制备方法 |
| BR112013000997B1 (pt) * | 2010-08-31 | 2021-05-04 | Synthes Gmbh | controle da degradação de implantes de metal bioreabsorvíveis |
| US20120277748A1 (en) * | 2011-04-28 | 2012-11-01 | Warsaw Orthopedic, Inc. | Bone plate |
-
2012
- 2012-11-07 KR KR1020147015428A patent/KR102122707B1/ko active Active
- 2012-11-07 WO PCT/US2012/063815 patent/WO2013070669A1/en not_active Ceased
- 2012-11-07 EP EP12787322.2A patent/EP2776083B1/en active Active
- 2012-11-07 CA CA2854667A patent/CA2854667C/en active Active
- 2012-11-07 CN CN201280054582.0A patent/CN104023759B/zh not_active Expired - Fee Related
- 2012-11-07 AU AU2012335990A patent/AU2012335990B2/en not_active Ceased
- 2012-11-07 BR BR112014010980-0A patent/BR112014010980B1/pt not_active IP Right Cessation
- 2012-11-07 US US13/670,803 patent/US9066999B2/en active Active
- 2012-11-07 IN IN3158DEN2014 patent/IN2014DN03158A/en unknown
- 2012-11-07 JP JP2014540206A patent/JP6177789B2/ja not_active Expired - Fee Related
- 2012-11-07 TW TW101141367A patent/TWI569819B/zh not_active IP Right Cessation
-
2015
- 2015-05-27 US US14/722,568 patent/US9682176B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5811194A (en) * | 1991-11-27 | 1998-09-22 | Electro Chemical Engineering Gmbh | Method of producing oxide ceramic layers on barrier layer-forming metals and articles produced by the method |
| CN1267585C (zh) * | 1995-03-13 | 2006-08-02 | 镁技术有限公司 | 镁和镁基合金的阳极氧化法 |
| CN101484599A (zh) * | 2006-04-28 | 2009-07-15 | 生物镁系统有限公司 | 生物可降解的镁合金及其用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104023759B (zh) | 2016-06-22 |
| US20150258252A1 (en) | 2015-09-17 |
| JP2015502193A (ja) | 2015-01-22 |
| JP6177789B2 (ja) | 2017-08-09 |
| WO2013070669A1 (en) | 2013-05-16 |
| KR20140091579A (ko) | 2014-07-21 |
| KR102122707B1 (ko) | 2020-06-29 |
| EP2776083B1 (en) | 2017-07-26 |
| EP2776083A1 (en) | 2014-09-17 |
| IN2014DN03158A (enExample) | 2015-05-22 |
| AU2012335990B2 (en) | 2016-03-24 |
| TW201334816A (zh) | 2013-09-01 |
| AU2012335990A1 (en) | 2014-05-29 |
| CA2854667A1 (en) | 2013-05-16 |
| CA2854667C (en) | 2021-03-30 |
| US9682176B2 (en) | 2017-06-20 |
| CN104023759A (zh) | 2014-09-03 |
| US9066999B2 (en) | 2015-06-30 |
| BR112014010980A2 (pt) | 2017-06-06 |
| BR112014010980B1 (pt) | 2019-09-24 |
| US20130116696A1 (en) | 2013-05-09 |
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