TWI527890B - 建基於氫氟烯烴類之組成物 - Google Patents

建基於氫氟烯烴類之組成物 Download PDF

Info

Publication number
TWI527890B
TWI527890B TW098116905A TW98116905A TWI527890B TW I527890 B TWI527890 B TW I527890B TW 098116905 A TW098116905 A TW 098116905A TW 98116905 A TW98116905 A TW 98116905A TW I527890 B TWI527890 B TW I527890B
Authority
TW
Taiwan
Prior art keywords
weight
hfc
composition
tetrafluoropropene
patent application
Prior art date
Application number
TW098116905A
Other languages
English (en)
Other versions
TW201012911A (en
Inventor
威森 羅奇德
Original Assignee
艾克瑪公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40225399&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=TWI527890(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 艾克瑪公司 filed Critical 艾克瑪公司
Publication of TW201012911A publication Critical patent/TW201012911A/zh
Application granted granted Critical
Publication of TWI527890B publication Critical patent/TWI527890B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/12—Hydrocarbons
    • C09K2205/126—Unsaturated fluorinated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/22—All components of a mixture being fluoro compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Lubricants (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

建基於氫氟烯烴類之組成物
本發明係關於包括氫氟烯烴之組成物及其作為傳熱液、發泡劑、溶劑和氣溶膠之用途。
於蒙特婁處理消耗大氣臭氧層的物質(ODP：臭氧消耗潛質)所引發的問題，於蒙特婁簽訂的協定書要求減少氯氟化碳(CFC)之製造和使用。此協定書已構成修正案標的，該修正案要求不再使用CFC及以更多規則控管其他產品，包括氫氯氟化碳(HCFC)。
冷凍工業和空調產製已針對這些冷凍劑的替代品進行許多硏究且因此氫氟化碳(HFC)上市。
亦曾使用(氫)氯氟化碳代替HFC作為發泡劑或溶劑。
在電動載具工業中，許多國家銷售的載具之空調系統自氯氟化碳(CFC-12)冷凍劑改為對臭氧層較無害的氫氟化碳(1,1,1,2-四氟乙烷：HFC-134a)冷凍劑。但是，由京都協定書設定的目標觀點，HFC-134a(GWP=1300)被認為具有高加熱力。冷凍劑對溫室效應的影響藉規範(GWP(地球暖化潛能)，其為加熱力的指標，以二氧化碳作為參考值1)定出。
二氧化碳由於無毒且非可燃並具有極低的GWP，所以曾被建議作為供空調系統之用的冷凍劑以代替HFC-134a。然而，使用二氧化碳有數個缺點，特別關於其在現有裝置中作為冷卻劑的使用壓力極高和技術。
論文WO 2004/037913揭示包含至少一具有三或四個碳原子的氟烯(特別是五氟丙烯和四氟丙烯，以GWP至多150者為佳)之組成物作為傳熱液之使用。
論文WO 2005/105947指出輔助發泡劑(如，二氟甲烷、五氟乙烷、四氟乙烷、二氟乙烷、七氟丙烷、六氟丙烷、五氟丙烷、五氟丁烷、水和二氧化碳)添加至四氟丙烯(以1,3,3,3-四氟丙烯為佳)。
論文WO 2006/094303揭示2,3,3,3-四氟丙烯(1234yf)與二氟甲烷(HFC-32)和2,3,3,3-四氟丙烯與1,1,1,2-四氟乙烷(HFC-134a)的二元組成物。
該論文中亦揭示包含1,1,1,2,3-五氟丙烯(1225ye)與二氟甲烷、2,3,3,3-四氟丙烯和HFC-134a併用之四元混合物。但1,1,1,2,3-五氟丙烯具毒性。
亦於論文WO 2006/094303中揭示包含2,3,3,3-四氟丙烯與碘三氟甲烷(CF3I)、HFC-32和HFC-134a併用的四元混合物。但是，CF3I的ODP非0且有安定性和腐蝕方面的問題。
申請人的公司現已發展包括氫氟丙烯的組成物，該組成物不具前述缺點且兼具零ODP和比現有的傳熱液(如，R404A(五氟乙烷(44重量%)、三氟乙烷(52重量%)和HFC-134a(4重量%)的三元混合物)及R407C(HFC-134a(52重量%)、HFC-125(25重量%)和HFC-32(23重量%)的三元混合物))為低的GWP。
根據本發明之組成物之特徵在於其包含5至65重量%(以5至15重量%為佳)的2,3,3,3-四氟丙烯，5至70重量%(以40至60重量%為佳)的HFC-134a和25至42重量%的HFC-32。
根據本發明之較佳形式，該組成物包含25至42重量%的HFC-32、30至55重量%的2,3,3,3-四氟丙烯和20至35重量%的HFC-134a。
包含40重量%的HFC-32、10重量%的2,3,3,3-四氟丙烯和50重量%的HFC-134a之組成物係特別有利。
包含40重量%的HFC-32、40重量%的2,3,3,3-四氟丙烯和20重量%的HFC-134a之組成物亦有利。
有利地，根據本發明之組成物實質上包含2,3,3,3-四氟丙烯、HFC-134a和HFC-32作為氫氟碳(飽和或不飽和)。
根據本發明之組成物可作為傳熱液，在壓縮系統中較佳。它們特別適合用於冷凍，以作為R404A和HCFC-22(氯二氟甲烷)的替代品為佳。
根據本發明之組成物亦適用於供空調和加熱用的壓縮系統，特別是熱幫浦，以作為R407C和HFC-134a的替代品為佳。
根據本發明之組成物可包含供2,3,3,3-四氟丙烯用的安定劑。相對於總組成物，該安定劑至多5重量%。
特別可提及作為安定劑者為硝基甲烷、抗壞血酸、對酞酸、唑(如，甲苯並三唑或苯並三唑)、酚系化合物(如，生育酚、氫醌、三級丁基氫醌或2,6-二(三級丁基)-4-甲酚)、環氧化物(烷基，隨意地經氟化或全氟化，或烯基或芳族)(如，正丁基縮水甘油醚、己二醇二縮水甘油醚、烯丙基縮水甘油醚或丁基苯基縮水甘油醚)、亞磷酸鹽、磷酸鹽、膦酸鹽或硫醇和內酯。
根據本發明之組成物可包含潤滑劑，如，礦油、烷基苯、聚烷二醇和聚乙烯醚。
根據本發明之組成物可同時作為發泡劑、氣溶膠和溶劑。
實驗部分
根據本發明之組成物在冷凍方面的效能示於表1。每一組成物的組成(1234yf/32/134a)值以重量%表示。
當涉及到以現有設備代替時，測定參數(如，效能係數(COP)、體積容量(容量)和高壓(Cond P)。就R404A而言，在下列操作條件下，公稱操作壓力為1829kPa，容量為1471千焦耳/立方米，而COP為1.8：
蒸發溫度：-20℃
凝結溫度：40℃
壓縮機入口溫度：-5℃
次冷卻液體的溫度：35℃
壓縮機的等熵效率：70%
Evap P：蒸發器壓力
Cond P：凝結器壓力
Ratio：壓縮比
T comp outlet：壓縮機出口處溫度
COP：效能係數並在涉及冷凍時，定義為系統供應之有用的冷卻功率對系統引入或消耗的功率之比。
在與R404A相同的操作條件下，根據本發明之組成物之體積容量和COP等同或甚至高於自R404A得到的值。
根據本發明之組成物在空調和熱幫浦操作條件下之效能示於表2。每一組成物的組成值(1234yf/32/134a)以重量%表示。
就R407C而言，在下列操作條件下，公稱操作壓力為3442kPa，容量為1461千焦耳/立方米，而COP為2.1：
蒸發溫度：-5℃
凝結溫度：70℃
壓縮機入口溫度：5℃
次冷卻液體溫度：65℃
壓縮機的等熵效能：70%
Evap P：蒸發器壓力
Cond P：凝結器壓力
Ratio：壓縮比
T comp outlet：壓縮機出口處溫度
COP：效能係數並在涉及冷凍時，定義為系統供應之有用的冷卻功率與系統引入或消耗的功率之比。
在相同條件下，根據本發明之組成物提供的容量大於R407C的容量且可能使得使用尺寸較小的設備，減少冷凍劑用量及降低設備成本。

Claims (13)

  1. 一種組成物，其係由5至65重量%的2,3,3,3-四氟丙烯，5至70重量%的1,1,1,2-四氟乙烷HFC-134a和25至42重量%的二氟甲烷HFC-32所組成。
  2. 如申請專利範圍第1項之組成物，其由25至42重量%的HFC-32、30至55重量%的2,3,3,3-四氟丙烯和20至35重量%的HFC-134a所組成。
  3. 如申請專利範圍第1項之組成物，其由40重量%的HFC-32、10重量%的2,3,3,3-四氟丙烯和50重量%的HFC-134a所組成。
  4. 如申請專利範圍第1或2項之組成物，其由40重量%的HFC-32、40重量%的2,3,3,3-四氟丙烯和20重量%的HFC-134a所組成。
  5. 如申請專利範圍第1項之組成物，其由5至15重量%的2,3,3,3-四氟丙烯，40至60重量%的HFC-134a和25至42重量%的HFC-32所組成。
  6. 一種傳熱液，其包含如申請專利範圍第1項之組成物。
  7. 一種傳熱液，其包含如申請專利範圍第3項之組成物。
  8. 一種傳熱液，其包含如申請專利範圍第4項之組成物。
  9. 如申請專利範圍第6至8項中任一項之傳熱液，其代替五氟乙烷44重量%、三氟乙烷52重量%和HFC-134a 4重量%的三元混合物R404A和氯二氟甲烷HCFC-22用於冷凍。
  10. 如申請專利範圍第6項之傳熱液，其用於供空調和加熱用的壓縮系統。
  11. 一種發泡劑，其包含如申請專利範圍第1項之組成物。
  12. 一種溶劑，其包含如申請專利範圍第1項之組成物。
  13. 一種氣溶膠，其包含如申請專利範圍第1項之組成物。
TW098116905A 2008-06-11 2009-05-21 建基於氫氟烯烴類之組成物 TWI527890B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0853859A FR2932492B1 (fr) 2008-06-11 2008-06-11 Compositions a base d'hydrofluoroolefines

Publications (2)

Publication Number Publication Date
TW201012911A TW201012911A (en) 2010-04-01
TWI527890B true TWI527890B (zh) 2016-04-01

Family

ID=40225399

Family Applications (3)

Application Number Title Priority Date Filing Date
TW107103873A TWI688648B (zh) 2008-06-11 2009-05-21 建基於氫氟烯烴類之組成物
TW104127679A TWI649413B (zh) 2008-06-11 2009-05-21 建基於氫氟烯烴類之組成物
TW098116905A TWI527890B (zh) 2008-06-11 2009-05-21 建基於氫氟烯烴類之組成物

Family Applications Before (2)

Application Number Title Priority Date Filing Date
TW107103873A TWI688648B (zh) 2008-06-11 2009-05-21 建基於氫氟烯烴類之組成物
TW104127679A TWI649413B (zh) 2008-06-11 2009-05-21 建基於氫氟烯烴類之組成物

Country Status (10)

Country Link
US (2) US8070977B2 (zh)
EP (2) EP2615150A3 (zh)
JP (1) JP5525517B2 (zh)
KR (1) KR101614693B1 (zh)
CN (1) CN102066520B (zh)
ES (1) ES2566391T3 (zh)
FR (1) FR2932492B1 (zh)
PL (1) PL2283101T3 (zh)
TW (3) TWI688648B (zh)
WO (1) WO2010000993A2 (zh)

Families Citing this family (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8974688B2 (en) * 2009-07-29 2015-03-10 Honeywell International Inc. Compositions and methods for refrigeration
WO2009018117A1 (en) * 2007-07-27 2009-02-05 E. I. Du Pont De Nemours And Company Compositions comprising fluoroolefins and uses thereof
GB201002625D0 (en) 2010-02-16 2010-03-31 Ineos Fluor Holdings Ltd Heat transfer compositions
US8333901B2 (en) 2007-10-12 2012-12-18 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
US8512591B2 (en) 2007-10-12 2013-08-20 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
US8628681B2 (en) 2007-10-12 2014-01-14 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
US9546311B2 (en) 2008-08-19 2017-01-17 Honeywell International Inc. Azeotrope-like compositions of 1,1,1,2-tetrafluoropropene and 1,1,1,2-tetrafluoroethane
FR2936806B1 (fr) 2008-10-08 2012-08-31 Arkema France Fluide refrigerant
FR2937328B1 (fr) 2008-10-16 2010-11-12 Arkema France Procede de transfert de chaleur
US20170080773A1 (en) 2008-11-03 2017-03-23 Arkema France Vehicle Heating and/or Air Conditioning Method
DE202009019200U1 (de) * 2008-11-19 2018-10-15 The Chemours Company Fc, Llc Tetrafluorpropen-Zusammensetzungen und Ihre Verwendungen
US20100122545A1 (en) 2008-11-19 2010-05-20 E. I. Du Pont De Nemours And Company Tetrafluoropropene compositions and uses thereof
FR2942237B1 (fr) * 2009-02-13 2013-01-04 Arkema France Procede de chauffage et/ou climatisation d'un vehicule
GB0915004D0 (en) * 2009-08-28 2009-09-30 Ineos Fluor Holdings Ltd Heat transfer composition
US9074115B2 (en) 2009-08-28 2015-07-07 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
FR2950065B1 (fr) 2009-09-11 2012-02-03 Arkema France Fluide refrigerant binaire
US10035938B2 (en) 2009-09-11 2018-07-31 Arkema France Heat transfer fluid replacing R-134a
FR2950068B1 (fr) 2009-09-11 2012-05-18 Arkema France Procede de transfert de chaleur
FR2950070B1 (fr) 2009-09-11 2011-10-28 Arkema France Compositions ternaires pour refrigeration haute capacite
FR2950066B1 (fr) 2009-09-11 2011-10-28 Arkema France Refrigeration basse et moyenne temperature
FR2950071B1 (fr) 2009-09-11 2012-02-03 Arkema France Compositions ternaires pour refrigeration basse capacite
FR2950069B1 (fr) * 2009-09-11 2011-11-25 Arkema France Utilisation de compositions ternaires
FR2950067B1 (fr) 2009-09-11 2011-10-28 Arkema France Fluide de transfert de chaleur en remplacement du r-410a
FR2954342B1 (fr) 2009-12-18 2012-03-16 Arkema France Fluides de transfert de chaleur a inflammabilite reduite
GB201002622D0 (en) 2010-02-16 2010-03-31 Ineos Fluor Holdings Ltd Heat transfer compositions
FR2957083B1 (fr) 2010-03-02 2015-12-11 Arkema France Fluide de transfert de chaleur pour compresseur centrifuge
CA2796051C (en) * 2010-04-16 2019-03-05 E. I. Du Pont De Nemours And Company Composition comprising 2,3,3,3-tetrafluoropropene and 1,1,1,2-tetrafluoroethane, chillers containing same and methods of producing cooling therein
FR2959999B1 (fr) 2010-05-11 2012-07-20 Arkema France Fluides de transfert de chaleur et leur utilisation dans des echangeurs de chaleur a contre-courant
FR2959998B1 (fr) 2010-05-11 2012-06-01 Arkema France Fluides de transfert de chaleur ternaires comprenant du difluoromethane, du pentafluoroethane et du tetrafluoropropene
FR2959997B1 (fr) * 2010-05-11 2012-06-08 Arkema France Fluides de transfert de chaleur et leur utilisation dans des echangeurs de chaleur a contre-courant
AU2011254381C1 (en) 2010-05-20 2014-09-18 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
EP2571952B1 (en) 2010-05-20 2015-07-29 Mexichem Fluor S.A. de C.V. Heat transfer compositions
GB2481443B (en) 2010-06-25 2012-10-17 Mexichem Amanco Holding Sa Heat transfer compositions
FR2962442B1 (fr) 2010-07-09 2016-02-26 Arkema France Composition stable de 2,3,3,3-tetrafluoropropene
FR2964975B1 (fr) 2010-09-20 2012-08-24 Arkema France Composition a base de 2,3,3,3-tetrafluoropropene
FR2964977B1 (fr) 2010-09-20 2013-11-01 Arkema France Composition a base de 3,3,3-tetrafluoropropene
FR2971512B1 (fr) 2011-02-10 2013-01-18 Arkema France Compositions binaires de 2,3,3,3-tetrafluoropropene et d'ammoniac
FR2974812B1 (fr) 2011-05-04 2014-08-08 Arkema France Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification
JP5941056B2 (ja) 2011-10-26 2016-06-29 Ｊｘエネルギー株式会社 冷凍機用作動流体組成物及び冷凍機油
FR2986236B1 (fr) 2012-01-26 2014-01-10 Arkema France Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification
KR101909545B1 (ko) 2012-03-27 2018-10-19 제이엑스티지 에네루기 가부시키가이샤 냉동기용 작동 유체 조성물
EP2832833B9 (en) * 2012-03-29 2019-07-10 JX Nippon Oil & Energy Corporation Working fluid composition for refrigerator
US9783721B2 (en) 2012-08-20 2017-10-10 Honeywell International Inc. Low GWP heat transfer compositions
US9528735B2 (en) 2012-09-04 2016-12-27 Daikin Industries, Ltd. Method for filling mixed refrigerant containing 2,3,3,3-tetrafluoropropene
FR2998302B1 (fr) 2012-11-20 2015-01-23 Arkema France Composition refrigerante
US8940180B2 (en) 2012-11-21 2015-01-27 Honeywell International Inc. Low GWP heat transfer compositions
FR3000096B1 (fr) 2012-12-26 2015-02-20 Arkema France Composition comprenant du 2,3,3,3-tetrafluoropropene
FR3000095B1 (fr) 2012-12-26 2015-02-20 Arkema France Composition comprenant du 2,3,3,3-tetrafluoropropene et du 1,2-difluoroethylene
FR3000093B1 (fr) 2012-12-26 2015-07-17 Arkema France Composition azeotropique ou quasi-azeotropique de chloromethane
US9982180B2 (en) 2013-02-13 2018-05-29 Honeywell International Inc. Heat transfer compositions and methods
US20160024361A1 (en) * 2013-03-15 2016-01-28 Honeywell Internatioanl, Inc. Heat transfer compositions and methods
FR3003565B1 (fr) 2013-03-20 2018-06-29 Arkema France Composition comprenant hf et 2,3,3,3-tetrafluoropropene
FR3008419B1 (fr) 2013-07-11 2015-07-17 Arkema France Compositions a base de 2,3,3,3-tetrafluoropropene presentant une miscibilite amelioree
FR3010415B1 (fr) 2013-09-11 2015-08-21 Arkema France Fluides de transfert de chaleur comprenant du difluoromethane, du pentafluoroethane, du tetrafluoropropene et eventuellement du propane
JP5861727B2 (ja) 2014-03-04 2016-02-16 ダイキン工業株式会社 トランス−１，３，３，３−テトラフルオロプロペンを含む混合冷媒の充填方法
US10330364B2 (en) 2014-06-26 2019-06-25 Hudson Technologies, Inc. System and method for retrofitting a refrigeration system from HCFC to HFC refrigerant
DK3241878T4 (da) * 2014-09-25 2024-02-05 Daikin Ind Ltd Sammensætning, der omfatter hfc og hfo
FR3033791B1 (fr) 2015-03-18 2017-04-14 Arkema France Stabilisation du 1-chloro-3,3,3-trifluoropropene
FR3057271B1 (fr) 2016-10-10 2020-01-17 Arkema France Utilisation de compositions a base de tetrafluoropropene
FR3057272B1 (fr) 2016-10-10 2020-05-08 Arkema France Compositions azeotropiques a base de tetrafluoropropene
FR3064264B1 (fr) 2017-03-21 2019-04-05 Arkema France Composition a base de tetrafluoropropene
FR3064275B1 (fr) 2017-03-21 2019-06-07 Arkema France Procede de chauffage et/ou climatisation d'un vehicule
FR3070982B1 (fr) 2017-09-12 2019-08-30 Arkema France Composition a base d'hydrochlorofluoroolefine et d'huile minerale
FR3077572B1 (fr) 2018-02-05 2021-10-08 Arkema France Composition azeotropique ou quasi-azeotropique ternaire comprenant hf, 2,3,3,3-tetrafluoropropene et 1,1,1,2,2,-pentafluoropropane.
FR3077822B1 (fr) 2018-02-15 2020-07-24 Arkema France Compositions de transfert de chaleur en remplacement du r-134a

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2728672T3 (es) 2002-10-25 2019-10-28 Honeywell Int Inc Composiciones que contienen olefinas sustituidas con flúor
US20090253820A1 (en) * 2006-03-21 2009-10-08 Honeywell International Inc. Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming
US7279451B2 (en) * 2002-10-25 2007-10-09 Honeywell International Inc. Compositions containing fluorine substituted olefins
US20060243944A1 (en) * 2005-03-04 2006-11-02 Minor Barbara H Compositions comprising a fluoroolefin
DE202007008291U1 (de) * 2006-06-17 2007-10-18 Ineos Fluor Holdings Ltd., Runcorn Wärmeübertragungszusammensetzungen
GB0614067D0 (en) * 2006-07-17 2006-08-23 Ineos Fluor Holdings Ltd Heat transfer compositions
GB0614080D0 (en) * 2006-07-17 2006-08-23 Ineos Fluor Holdings Ltd Heat transfer compositions

Also Published As

Publication number Publication date
ES2566391T3 (es) 2016-04-12
TW201842149A (zh) 2018-12-01
US20120049104A1 (en) 2012-03-01
TWI649413B (zh) 2019-02-01
KR101614693B1 (ko) 2016-04-22
TW201012911A (en) 2010-04-01
KR20110042265A (ko) 2011-04-26
JP5525517B2 (ja) 2014-06-18
EP2283101B1 (fr) 2016-02-17
CN102066520A (zh) 2011-05-18
US20110095224A1 (en) 2011-04-28
US8252198B2 (en) 2012-08-28
EP2283101A2 (fr) 2011-02-16
CN102066520B (zh) 2014-04-09
PL2283101T3 (pl) 2016-06-30
EP2615150A2 (fr) 2013-07-17
WO2010000993A2 (fr) 2010-01-07
EP2615150A3 (fr) 2017-03-08
TWI688648B (zh) 2020-03-21
JP2011522947A (ja) 2011-08-04
WO2010000993A3 (fr) 2010-03-04
US8070977B2 (en) 2011-12-06
TW201612295A (en) 2016-04-01
FR2932492A1 (fr) 2009-12-18
FR2932492B1 (fr) 2010-07-30

Similar Documents

Publication Publication Date Title
TWI527890B (zh) 建基於氫氟烯烴類之組成物
US11130893B2 (en) Heat transfer fluid
TWI492917B (zh) 以氫氟烴類為底質之組成物
TWI460149B (zh) 以氫氟烴類為底質之組成物