TWI527758B - 具有可調孔隙度和表面形態的矽材料及其合成之方法 - Google Patents

具有可調孔隙度和表面形態的矽材料及其合成之方法 Download PDF

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Publication number
TWI527758B
TWI527758B TW098123187A TW98123187A TWI527758B TW I527758 B TWI527758 B TW I527758B TW 098123187 A TW098123187 A TW 098123187A TW 98123187 A TW98123187 A TW 98123187A TW I527758 B TWI527758 B TW I527758B
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Taiwan
Prior art keywords
metal
pores
solution
particles
metals
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TW098123187A
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English (en)
Chinese (zh)
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TW201010942A (en
Inventor
布萊恩Ｔ 何嵐
莎莎 沃茲
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奈寇公司
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Publication of TW201010942A publication Critical patent/TW201010942A/zh
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/126—Preparation of silica of undetermined type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/141—Preparation of hydrosols or aqueous dispersions
    • C01B33/142—Preparation of hydrosols or aqueous dispersions by acidic treatment of silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
    • C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Silicon Compounds (AREA)
  • Catalysts (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
TW098123187A 2008-09-12 2009-07-09 具有可調孔隙度和表面形態的矽材料及其合成之方法 TWI527758B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US12/209,790 US8790608B2 (en) 2008-09-12 2008-09-12 Siliceous materials having tunable porosity and surface morphology and methods of synthesizing same

Publications (2)

Publication Number Publication Date
TW201010942A TW201010942A (en) 2010-03-16
TWI527758B true TWI527758B (zh) 2016-04-01

Family

ID=41572620

Family Applications (1)

Application Number Title Priority Date Filing Date
TW098123187A TWI527758B (zh) 2008-09-12 2009-07-09 具有可調孔隙度和表面形態的矽材料及其合成之方法

Country Status (8)

Country Link
US (1) US8790608B2 (enExample)
EP (1) EP2346782A2 (enExample)
JP (1) JP5615281B2 (enExample)
KR (1) KR101682254B1 (enExample)
CN (1) CN102186772B (enExample)
MY (1) MY155398A (enExample)
TW (1) TWI527758B (enExample)
WO (1) WO2010030878A2 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10227238B2 (en) * 2006-04-04 2019-03-12 Ecolab Usa Inc. Production and use of polysilicate particulate materials
US8764974B2 (en) 2010-04-16 2014-07-01 Nalco Company Processing aids to improve the bitumen recovery and froth quality in oil sands extraction processes
US10087081B2 (en) 2013-03-08 2018-10-02 Ecolab Usa Inc. Process for producing high solids colloidal silica
US10926241B2 (en) 2014-06-12 2021-02-23 Arizona Board Of Regents On Behalf Of Arizona State University Carbon dioxide adsorbents
CA2992720C (en) 2015-07-18 2025-04-22 Ecolab Usa Inc. Chemical additives for improving oil removal in distillation residue treatment operations
CN105251446B (zh) * 2015-11-11 2018-02-02 中国电建集团中南勘测设计研究院有限公司 一种地下水复合重金属污染修复材料
CN105329906B (zh) * 2015-11-30 2017-06-23 中海油天津化工研究设计院有限公司 一种丙烯腈催化剂用硅溶胶的制备方法
US10829382B2 (en) 2017-01-20 2020-11-10 Skysong Innovations Aluminosilicate nanorods
CN106823850B (zh) * 2017-03-08 2019-05-24 常州大学 一种桥架有机硅膜孔径的调控方法
JP7034435B2 (ja) * 2017-11-29 2022-03-14 東洋製罐グループホールディングス株式会社 複合体及びその製造方法。
KR102252313B1 (ko) * 2019-01-23 2021-05-14 청주대학교 산학협력단 중공의 다공성 실리카 나노구 및 그 제조방법
US12006439B2 (en) * 2019-03-27 2024-06-11 Canon Kabushiki Kaisha Optical member, optical device and coating liquid
CN120137436B (zh) * 2025-04-22 2025-11-11 中国科学院宁波材料技术与工程研究所 一种硅钛复合防雾涂层及其制备方法与应用

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2892797A (en) 1956-02-17 1959-06-30 Du Pont Process for modifying the properties of a silica sol and product thereof
US2913419A (en) 1956-04-18 1959-11-17 Du Pont Chemical process and composition
US2974108A (en) 1957-01-14 1961-03-07 Du Pont Aluminosilicate aquasols and their preparation
US3442795A (en) 1963-02-27 1969-05-06 Mobil Oil Corp Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom
US3745126A (en) 1971-04-22 1973-07-10 Du Pont Stable positively charged alumina coated silica sols
US3864142A (en) 1971-04-26 1975-02-04 Nalco Chemical Co Metal oxide sols
US4287086A (en) 1975-05-02 1981-09-01 Nl Industries, Inc. Viscous organic systems containing an organophilic clay gellant without an organic dispersant therefor
IT1127311B (it) 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
US4451388A (en) 1981-11-02 1984-05-29 Nalco Chemical Company Preparation of aluminum oxide coated silica sols using ultrafiltration
FR2567505B1 (fr) * 1984-07-11 1986-11-21 Rhone Poulenc Chim Base Silice a prise d'huile elevee et a structure primaire controlee et procede pour son obtention
JPS61158810A (ja) * 1984-12-28 1986-07-18 Shokubai Kasei Kogyo Kk 高純度シリカゾルの製造法
US5221497A (en) 1988-03-16 1993-06-22 Nissan Chemical Industries, Ltd. Elongated-shaped silica sol and method for preparing the same
FI952954A0 (fi) 1992-12-16 1995-06-15 Chevron Res & Tech Alumosilikaattizeoliittien valmistus
JP3517913B2 (ja) * 1993-10-15 2004-04-12 日産化学工業株式会社 細長い形状のシリカゾルの製造法
JP2908253B2 (ja) * 1994-09-26 1999-06-21 日本化学工業株式会社 水和珪酸とその製造方法
DE19648798C2 (de) * 1996-11-26 1998-11-19 Hoechst Ag Verfahren zur Herstellung von organisch modifizierten Aerogelen durch Oberflächenmodifikation des wäßrigen Gels (ohne vorherigen Lösungsmitteltausch) und anschließender Trocknung
US6358882B1 (en) 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst
US5968473A (en) 1998-12-18 1999-10-19 Uop Llc Stannosilicate molecular sieves
US6680013B1 (en) * 1999-04-15 2004-01-20 Regents Of The University Of Minnesota Synthesis of macroporous structures
US6191323B1 (en) 2000-04-25 2001-02-20 Uop Llc Process for the reduction of ketones and aldehydes to alcohols using a tin substituted zeolite beta
JP2002173314A (ja) * 2000-11-30 2002-06-21 Watanabe Shoko:Kk 高純度コロイダルシリカ及び高純度合成石英粉の製造方法
JP4976613B2 (ja) * 2000-12-08 2012-07-18 水澤化学工業株式会社 シリカゾルの製造方法
JP2003253154A (ja) * 2001-12-25 2003-09-10 Asahi Kasei Corp 無機多孔性微粒子
US6916514B2 (en) 2003-07-18 2005-07-12 Eastman Kodak Company Cationic shelled particle
JP4041892B2 (ja) * 2003-10-03 2008-02-06 独立行政法人物質・材料研究機構 多孔質ガラス微小粒子およびその製造方法
US20070034116A1 (en) 2005-08-10 2007-02-15 Mac Donald Dennis L Silica sols with controlled minimum particle size and preparation thereof

Also Published As

Publication number Publication date
JP2012501958A (ja) 2012-01-26
WO2010030878A2 (en) 2010-03-18
WO2010030878A3 (en) 2010-05-06
MY155398A (en) 2015-10-15
KR101682254B1 (ko) 2016-12-02
TW201010942A (en) 2010-03-16
JP5615281B2 (ja) 2014-10-29
EP2346782A2 (en) 2011-07-27
US8790608B2 (en) 2014-07-29
CN102186772A (zh) 2011-09-14
US20100068519A1 (en) 2010-03-18
KR20110073443A (ko) 2011-06-29
CN102186772B (zh) 2015-07-22

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