TWI482853B - 包含微纖維纖維素之界面活性劑稠化系統及其製造方法 - Google Patents

包含微纖維纖維素之界面活性劑稠化系統及其製造方法 Download PDF

Info

Publication number
TWI482853B
TWI482853B TW096142247A TW96142247A TWI482853B TW I482853 B TWI482853 B TW I482853B TW 096142247 A TW096142247 A TW 096142247A TW 96142247 A TW96142247 A TW 96142247A TW I482853 B TWI482853 B TW I482853B
Authority
TW
Taiwan
Prior art keywords
surfactant
cellulose
concentration
present
microfiber
Prior art date
Application number
TW096142247A
Other languages
English (en)
Other versions
TW200844222A (en
Inventor
John M Swazey
Neil A Morrison
Original Assignee
Cp Kelco Us Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cp Kelco Us Inc filed Critical Cp Kelco Us Inc
Publication of TW200844222A publication Critical patent/TW200844222A/zh
Application granted granted Critical
Publication of TWI482853B publication Critical patent/TWI482853B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/027—Fibers; Fibrils
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/044—Suspensions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P19/00—Drugs for skeletal disorders
    • A61P19/08—Drugs for skeletal disorders for bone diseases, e.g. rachitism, Paget's disease
    • A61P19/10—Drugs for skeletal disorders for bone diseases, e.g. rachitism, Paget's disease for osteoporosis
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P5/00—Drugs for disorders of the endocrine system
    • A61P5/02—Drugs for disorders of the endocrine system of the hypothalamic hormones, e.g. TRH, GnRH, CRH, GRH, somatostatin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48—Thickener, Thickening system
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Molecular Biology (AREA)
  • Dermatology (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Medicinal Chemistry (AREA)
  • Rheumatology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Orthopedic Medicine & Surgery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Endocrinology (AREA)
  • Diabetes (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Processing Of Solid Wastes (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Artificial Filaments (AREA)

Description

包含微纖維纖維素之界面活性劑稠化系統及其製造方法
通常藉由利用高濃度界面活性劑、藉由組合黏度協同之界面活性劑或藉由將界面活性劑與少量諸如鈉鹽之鹽組合，使諸如沐浴露、洗髮精、餐具洗滌劑、衣用洗滌劑及機用洗滌劑之基於界面活性劑之產品稠化。此等調配物產生呈濃及滑之高黏度產品，但該等產品之限制性在於其無法提供足夠低之剪切黏度以使顆粒懸浮。該等顆粒可包括美化劑(裝飾性珠粒、珠光、氣泡、芳香珠粒等)或活性成份(不溶性酶、經囊封之活性成份(諸如保濕劑)、沸石、剝落劑(例如，α羥基及/或乙醇酸或聚乙烯珠粒)、維生素(例如，維生素E))等或兩者。
諸如三仙膠、羧甲基纖維素(CMC)、羥乙基纖維素(HEC)、羥丙基甲基纖維素(HPMC)及多種聚丙烯酸酯之習知稠化劑及懸浮助劑在界面活性劑稠化系統中無法充分起作用且常由於渾濁、凝膠及/或相分離或缺乏足夠懸浮性而導致透明性之喪失。舉例而言，雖然三仙膠在某些具有低界面活性劑稠化之沐浴露調配物中給予優良懸浮性質，但該膠在具有高界面活性劑稠化之系統中常失去其懸浮能力，通常導致混濁、不規則外觀及粒狀或塊狀結構。作為習知稠化劑之另一實例，纖維素產品(CMC、HEC、HPMC等)提供不可靠之懸浮且對於界面活性劑相容性具有顯著限制。丙烯酸酯系統為常見的，然而，此等系統一直無法實現足夠清澈度，需要高濃度聚合物且被認為非天然的。 雖然鹽通常能夠在界面活性劑稠化系統中增加高剪切黏度，但其無法給予長期懸浮能力。
目前在消費品工業中需要提供具有懸浮於其中之顆粒的透明界面活性劑稠化系統以及針對許多替代稠化劑在其中無法起作用之高界面活性劑系統的懸浮助劑。
已發現來源於細菌或以其他方式獲得之微纖維纖維素(MFC)可用於提供顆粒在界面活性劑稠化系統以及具有高界面活性劑濃度之調配物中懸浮。亦發現MFC可在助劑存在或不存在之情況下用於達成此目的。當利用來源於細菌之微纖維纖維素時，可除去在典型用量下產生透明溶液之細胞碎屑。
微纖維纖維素似乎未受表面活性劑膠束發展之影響，且在此等系統中維持良好懸浮。在很大程度上微纖維纖維素在此等系統中之作用能力為獨特的，因為其分散而非溶解，藉此實現調配物中所需懸浮性質，而使用其他溶解聚合物常可見調配物顯示渾濁及/或沈澱。
描述包含微纖維纖維素之界面活性劑系統。"界面活性劑系統"意欲包括(但不限於)界面活性劑稠化系統及高界面活性劑系統。微纖維纖維素(MFC)包括藉由微生物醱酵製備之MFC或藉由機械破壞/改變基於穀物、木材或棉花之纖維素纖維製備的MFC。當利用來源於細菌之微纖維纖維素時，可除去在典型用量下產生透明溶液之細胞碎屑。本發明利用界面活性劑來實現高剪切速率下極稠(高黏度)之 系統，其中藉由使用微纖維纖維素使顆粒懸浮於其中。
此等系統之界面活性劑濃度在約5%至約50%(w/w活性界面活性劑)之範圍內，其中比濃度視產品而定。沐浴露通常含有約5%至約15% (w/w)之界面活性劑，餐具洗滌劑通常含有約20%至約40% (w/w)之界面活性劑(其中40%為"超"濃產品)及衣用洗滌劑通常含有約15%至約50% (w/w)之界面活性劑。
MFC以約0.05%至約1.0%之濃度存在，但濃度視所需產品而定。舉例而言，雖然約0.06% (w/w)MFC對用於將小的海藻酸鹽珠粒懸浮於沐浴露中為較佳，但約0.075%對用於將氣泡懸浮於沐浴露中為較佳，且約0.150% (w/w)對用於將氣泡或珠粒懸浮於含有約40% (w/w)界面活性劑之系統中為較佳。此外，若需要高度透明之系統，則將相應地調整MFC濃度。特定而言，約5%至約15%(w/w活性界面活性劑)之極透明沐浴露可使用約0.055至約0.25%(w/w活性界面活性劑)之MFC含量來達成。
待懸浮之顆粒可包括美化劑(裝飾性珠粒、珠光、氣泡、芳香珠粒等)或活性成份(不溶性酶、經囊封之活性成份(諸如保濕劑)、沸石、剝落劑(例如，α羥基及/或乙醇酸或聚乙烯珠粒)、維生素(例如，維生素E))等或兩者。其他合適之顆粒為熟習此項技術者顯而易見。
本發明亦係針對在本文所述之界面活性劑系統中配合微纖維纖維素使用諸如CMC、三仙膠(xanthan gum)及/或瓜爾膠(guar gum)之助劑及/或共處理劑。微纖維纖維素摻合 物為含有助劑之微纖維纖維素產物。描述兩種摻合物：比率為6:3:1之MFC、三仙膠及CMC及比率為3:1:1之MFC、瓜爾膠及CMC。此等摻合物允許MFC經製備為無水產物形式，其可用高剪切或高延伸混合於水或其他水基溶液中來"活化"。當將MFC摻合物添加至水中且助劑/共處理劑水合時發生"活化"。助劑/共處理劑水合之後，接著一般需要高剪切以有效分散微纖維纖維素纖維以產生展示真實屈服點之三維功能網路。意外地，儘管在高界面活性劑系統中普遍缺乏相容性，但此等微纖維纖維素摻合物中存在之助劑及/或共處理劑CMC、三仙膠及/或瓜爾膠似乎仍然溶解(於水中活化後)於許多高界面活性劑調配物中，此很可能係由於此等具有MFC之調配物中此等聚合物之用量低。
本發明進一步針對在助劑及/或共處理劑存在或不存在下製造所述界面活性劑系統之方法。
使用0.125% MFC/三仙膠/CMC(6:3:1)摻合物之證明界面活性劑稠化及懸浮性質的沐浴露調配物描述於實例1及2中。該等沐浴露展示極好之清澈度及懸浮氣泡及珠粒之能力。
亦描述界面活性劑含量比沐浴露中發現之界面活性劑含量高的手用餐具洗滌液及液體衣用洗滌劑。具有懸浮於其中之海潔酸鹽的手用餐具洗滌液描述於實例3中。
具有懸浮於其中之芳香珠粒的液體衣用洗滌劑描述於實例4中。
濕餅形式之微纖維纖維素用於實例5中以製備包含具有懸浮於其中之氣泡之濃液體洗衣皂的高界面活性劑系統。
實例1
製備具有氣泡之液體沐浴露。圖1展示此系統之清澈度及懸浮品質。基於目測，所得沐浴露展示極稠之界面活性劑流變學，具有懸浮氣泡之能力及約3.4 Pa之屈服值(如使用Brookfield® 屈服流變儀所量測)。
步驟A：將去離子水、10% NaCl溶液及Kathon® CG添加至小的Oster® 混合瓶中。將微纖維纖維素(MFC/三仙膠/CMC 6:3:1之摻合物)添加至水之頂部且接著組裝Oster® 混合器刀片且以最高速度混合組合5分鐘("液化"速度)。
步驟B：將內含物轉移至具有塗料混合葉片之400 mL高型燒杯中。將月桂醇醚硫酸鈉(JEELATE® ES-3)添加至步驟A中所述之溶液中且以約1000 rpm混合5分鐘。接著將可可醯胺基丙基甜菜鹼鈉(JEETERIC® CAB-LC)添加至混合物中且以1000 rpm混合另外5分鐘。接著添加芳香劑。
步驟C：將可可醯胺DEA添加至步驟B中所述之溶液中。當添加更多DEA時，稠化發生。接著檸檬酸以50%溶液形式添加以降低pH至所需程度(在此狀況下pH 5.5)。將內含物自混合器移除。混合期間輸入之空氣藉由MFC/三仙膠/CMC 6:3:1摻合物之存在而穩定。
實例2
如實例1所述製備沐浴露，但併入珠粒懸浮液而非氣泡。添加海藻酸鹽珠粒作為步驟C之結束。此實施例之直觀表示可見於圖2。
實例3
使用手用餐具洗滌劑及衣用洗滌劑來製備高界面活性劑系統。將海藻酸鹽珠粒或空氣懸浮於該等溶液中。將Palmolive Ultra® 餐具皂稀釋一半以製成"正常"濃度之餐具皂。首先製備含有於去離子水中之0.25%微纖維纖維素摻 合物(MFC/三仙膠/CMC 6:3:1之摻合物)的濃縮物。藉由在Oster® 摻合機上以"液化"(最高速度)混合溶液5分鐘來製成濃縮物。接著使用塗料混合或旋槳式葉片將微纖維纖維素混合物用Palmolive Ultra® 洗滌劑或Dawn Ultra® 洗滌劑(Palmolive® 含有0.1%三氯生(triclosan))1:1稀釋。將餐具皂添加至微纖維纖維素溶液中同時混合。對於Palmolive Ultra® 洗滌劑及Dawn Ultra® 洗滌劑樣品，均實現優良清澈度及空氣及/或海藻酸鹽珠粒之懸浮。儘管塗料或旋槳式混合葉片之剪切相對低，但微纖維纖維素完全稀釋。此等溶液之屈服點為約2.5 Pa。直觀表示可見於圖3中。
實例4
製備使用濃液體洗衣皂之高界面活性劑系統。使用"All Small and Mighty® 三倍濃縮"洗滌劑。將0.25%微纖維纖維素摻合物(MFC/三仙膠/CMC 6:3:1之摻合物)濃縮物在蒸餾水中用設定在最高速度(液化)下之Oster® 摻合機活化。混合時間為5分鐘。用All Small and Mighty® 三倍濃縮洗滌劑1:1稀釋微纖維纖維素溶液。對於產生0.62 Pa屈服點之稀釋液，實現極好之清澈度及懸浮。將洗滌劑放於45℃烘箱中以評定熱穩定性，其展示優良穩定性且清澈度或懸浮經4週老化不喪失。直觀表示可見於圖4中。
實例5
使用濕餅形式之微纖維纖維素製備使用濃液體洗衣皂之高界面活性劑系統。使用"All Small and Mighty® 三倍濃縮"洗滌劑。將1.56%濕餅狀微纖維纖維素濃縮物在蒸餾水中 用設定在最高速度(液化)下之Oster® 摻合機活化。混合時間為5分鐘。此濕餅形式之MFC之活性(%固體)為約16%，因此濃縮物中活性MFC含量為約0.25%。用All Small and Mighty® 三倍濃縮洗滌劑1:1稀釋微纖維纖維素溶液。對於產生13 Pa屈服點之稀釋液，實現極好之清澈度及懸浮。直觀表示可見於圖5中。
圖1顯示具有懸浮於其中之氣泡的界面活性劑稠化沐浴露中0.125%微纖維纖維素摻合物(MFC/三仙膠/CMC 6:3:1之摻合物)。
圖2顯示具有懸浮於其中之海藻酸鹽珠粒的界面活性劑稠化沐浴露中0.125%微纖維纖維素摻合物(MFC/三仙膠/CMC 6:3:1之摻合物)。
圖3顯示超濃餐具皂中0.125%微纖維纖維素摻合物(經水1:1稀釋：MFC/三仙膠/CMC 6:3:1之摻合物)。
圖4顯示超濃液體衣用洗滌劑中0.125%微纖維纖維素摻合物(經水1:1稀釋：MFC/三仙膠/CMC 6:3:1之摻合物)。
圖5顯示超濃液體衣用洗滌劑中0.125%微纖維纖維素(以濕餅形式添加)(經水1:1稀釋：MFC溶液)。不使用助劑。圖片顯示氣泡懸浮。
(無元件符號說明)

Claims (15)

  1. 一種水性組合物，其包含一高界面活性劑或界面活性劑稠化系統，該系統係包含濃度0.05%至0.15%(w/w)之微纖維纖維素，5%至50%(w/w活性界面活性劑)之界面活性劑，及懸浮顆粒，該水性組合物是透明的。
  2. 如請求項1之組合物，其中該微纖維纖維素係以0.06%(w/w)之濃度存在。
  3. 如請求項1之組合物，其中該微纖維纖維素係以0.075%(w/w)之濃度存在。
  4. 如請求項1之組合物，其中該微纖維纖維素係以0.09%(w/w)之濃度存在。
  5. 如請求項2之組合物，其中該界面活性劑係以自5%至15%(w/w活性界面活性劑)之濃度存在。
  6. 如請求項5之組合物，其中該顆粒包含氣泡、珠粒或其組合。
  7. 一種製備如請求項1至6中任一項之水性組合物之方法，其包含：將粉末狀之微纖維纖維素與水組合，且於高剪切下進行混合，添加界面活性劑且接著混合，添加顆粒且接著混合，其中，該微纖維纖維素係以0.05%至0.15%(w/w)之濃度存在於該水性組合物中，該界面活性劑係以5%至50%(w/w活性界面活性劑)之濃度存在於該水性組合物中，且 其中該所得組合物係清澈且該等顆粒係懸浮於其中。
  8. 如請求項7之方法，其中該微纖維纖維素係以0.06%(w/w)之濃度存在。
  9. 如請求項7之方法，其中該微纖維纖維素係以0.075%(w/w)之濃度存在於該水性組合物中。
  10. 如請求項7之方法，其中該微纖維纖維素係以0.09%(w/w)之濃度存在於該水性組合物中。
  11. 如請求項7之方法，其中該界面活性劑係以自5%至15%(w/w活性界面活性劑)之濃度存在。
  12. 一種界面活性劑系統，其基本上由水、微纖維纖維素摻合物、界面活性劑及懸浮顆粒所組成，其中該微纖維纖維素摻合物包含比例為6：3：1之微纖維纖維素、三仙膠及羧甲基纖維素摻合物。
  13. 一種包含如請求項12之界面活性劑系統之水性組合物，其中該微纖維纖維素摻合物係以0.125%(w/w)之濃度存在於該水性組合物中。
  14. 一種界面活性劑系統，其基本上由水、微纖維纖維素摻合物、界面活性劑及懸浮顆粒所組成，其中該微纖維纖維素摻合物包含比例為3：1：1之微纖維纖維素、三仙膠及羧甲基纖維素摻合物。
  15. 一種包含如請求項14之界面活性劑系統之水性組合物。
TW096142247A 2006-11-08 2007-11-08 包含微纖維纖維素之界面活性劑稠化系統及其製造方法 TWI482853B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/557,622 US9045716B2 (en) 2006-11-08 2006-11-08 Surfactant thickened systems comprising microfibrous cellulose and methods of making same

Publications (2)

Publication Number Publication Date
TW200844222A TW200844222A (en) 2008-11-16
TWI482853B true TWI482853B (zh) 2015-05-01

Family

ID=39360400

Family Applications (1)

Application Number Title Priority Date Filing Date
TW096142247A TWI482853B (zh) 2006-11-08 2007-11-08 包含微纖維纖維素之界面活性劑稠化系統及其製造方法

Country Status (27)

Country Link
US (3) US9045716B2 (zh)
EP (2) EP2486912B1 (zh)
JP (2) JP5520049B2 (zh)
KR (1) KR20090087030A (zh)
CN (3) CN102973430B (zh)
AR (1) AR063466A1 (zh)
AU (1) AU2007317389B2 (zh)
BR (1) BRPI0718779A2 (zh)
CA (1) CA2668898C (zh)
CL (1) CL2007003213A1 (zh)
DE (1) DE12167764T8 (zh)
DK (2) DK2091510T3 (zh)
ES (2) ES2393973T3 (zh)
HU (1) HUE028101T2 (zh)
IL (1) IL198608A (zh)
MX (1) MX2009004915A (zh)
MY (1) MY186434A (zh)
PE (1) PE20081055A1 (zh)
PL (2) PL2091510T3 (zh)
PT (1) PT2486912E (zh)
RU (1) RU2471476C2 (zh)
SG (1) SG186009A1 (zh)
SI (1) SI2091510T1 (zh)
TW (1) TWI482853B (zh)
UY (1) UY30701A1 (zh)
WO (1) WO2008057985A1 (zh)
ZA (1) ZA200903263B (zh)

Families Citing this family (90)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9045716B2 (en) 2006-11-08 2015-06-02 Cp Kelco U.S., Inc. Surfactant thickened systems comprising microfibrous cellulose and methods of making same
US8772359B2 (en) * 2006-11-08 2014-07-08 Cp Kelco U.S., Inc. Surfactant thickened systems comprising microfibrous cellulose and methods of making same
JP2009040968A (ja) * 2007-08-10 2009-02-26 Sanei Gen Ffi Inc 発酵セルロース含有洗浄剤
US7994111B2 (en) * 2008-02-15 2011-08-09 The Procter & Gamble Company Liquid detergent composition comprising an external structuring system comprising a bacterial cellulose network
CA2715652C (en) * 2008-02-15 2014-08-12 The Procter & Gamble Company Liquid detergent composition comprising an external structuring system comprising a bacterial cellulose network
GB0808293D0 (en) * 2008-05-08 2008-06-11 Unilever Plc Laundry detergent composition
US7776807B2 (en) 2008-07-11 2010-08-17 Conopco, Inc. Liquid cleansing compositions comprising microfibrous cellulose suspending polymers
WO2010039574A1 (en) * 2008-09-30 2010-04-08 The Procter & Gamble Company Liquid hard surface cleaning composition
WO2010039572A1 (en) 2008-09-30 2010-04-08 The Procter & Gamble Company Liquid hard surface cleaning composition
EP2328998A1 (en) * 2008-09-30 2011-06-08 The Procter & Gamble Company Liquid hard surface cleaning composition
US8450260B2 (en) 2008-12-29 2013-05-28 Conopco, Inc. Structured aqueous detergent compositions
EP2213714B1 (en) 2009-02-02 2014-06-11 The Procter and Gamble Company Liquid hand dishwashing detergent composition
EP2216390B1 (en) * 2009-02-02 2013-11-27 The Procter and Gamble Company Hand dishwashing method
RU2011131109A (ru) * 2009-02-02 2013-03-10 Дзе Проктер Энд Гэмбл Компани Жидкий моющий состав для мытья посуды ручным способом
ES2461892T3 (es) * 2009-02-02 2014-05-21 The Procter & Gamble Company Composición detergente líquida para lavado de vajillas a mano
EP2216391A1 (en) * 2009-02-02 2010-08-11 The Procter & Gamble Company Liquid hand dishwashing detergent composition
EP3023483A1 (en) 2009-02-02 2016-05-25 The Procter and Gamble Company Liquid hand diswashing detergent composition
EP2216392B1 (en) * 2009-02-02 2013-11-13 The Procter and Gamble Company Liquid hand dishwashing detergent composition
PL2408857T3 (pl) * 2009-03-20 2018-08-31 Borregaard As Mikrofibryle celulozowe jako środek uwalniający powietrze
US8097574B2 (en) * 2009-08-14 2012-01-17 The Gillette Company Personal cleansing compositions comprising a bacterial cellulose network and cationic polymer
CA2772172A1 (en) * 2009-09-08 2011-03-17 John Mcarthur Swazey, Jr. Methods to improve the compatibility and efficiency of powdered versions of microfibrous cellulose
WO2011056947A1 (en) 2009-11-04 2011-05-12 Colgate-Palmolive Company Composition with stable suspending system
AU2010315151B2 (en) 2009-11-04 2013-06-06 Colgate-Palmolive Company Microfibrous cellulose and alkaline earth metal ion structured surfactant composition
US8546318B2 (en) 2009-11-04 2013-10-01 Colgate-Palmolive Company Microfibrous cellulose having a particle size distribution for structured surfactant compositions
WO2011054389A1 (en) * 2009-11-05 2011-05-12 Unilever Plc Laundry compositions
US8440602B2 (en) * 2009-12-22 2013-05-14 The Procter & Gamble Company Liquid cleaning and/or cleansing composition comprising a divinyl benzene cross-linked styrene polymer
EP2338963B1 (en) * 2009-12-22 2018-08-08 The Procter & Gamble Company Liquid cleaning and/or cleansing composition
JP5902669B2 (ja) 2010-04-21 2016-04-13 ザ プロクター アンド ギャンブル カンパニー 液体クリーニング及び／又はクレンジング組成物
US8697041B2 (en) 2010-08-10 2014-04-15 Conopco, Inc. Anti-dandruff compositions with citrus fibers
EP2431451A1 (en) 2010-09-21 2012-03-21 The Procter & Gamble Company Liquid detergent composition with abrasive particles
EP2431455A1 (en) 2010-09-21 2012-03-21 The Procter & Gamble Company Liquid cleaning and/or cleansing composition
EP2431454B1 (en) 2010-09-21 2016-11-02 The Procter & Gamble Company Liquid cleaning and/or cleansing composition
WO2012040136A1 (en) 2010-09-21 2012-03-29 The Procter & Gamble Company Liquid cleaning composition
EP2431452B1 (en) 2010-09-21 2015-07-08 The Procter & Gamble Company Liquid cleaning composition
US8642529B2 (en) * 2010-11-15 2014-02-04 Conopco, Inc. Liquid low surfactant compositions structured with a fibrous polymer
EP2640814B1 (en) * 2010-11-15 2016-07-06 Unilever PLC Liquid surfactant compositions structured with fibrous polymer and water soluble polymers
US8852643B2 (en) 2011-06-20 2014-10-07 The Procter & Gamble Company Liquid cleaning and/or cleansing composition
US8440603B2 (en) 2011-06-20 2013-05-14 The Procter & Gamble Company Liquid cleaning and/or cleansing composition comprising a polylactic acid biodegradable abrasive
EP2537917A1 (en) 2011-06-20 2012-12-26 The Procter & Gamble Company Liquid detergent composition with abrasive particles
MX338952B (es) 2011-06-20 2016-05-05 Procter & Gamble Composicion liquida de limpieza y/o lavado.
MX341152B (es) 2011-07-20 2016-08-09 Colgate Palmolive Co Composicion de limpieza con textura de crema batida.
EP2551337A1 (en) * 2011-07-27 2013-01-30 The Procter & Gamble Company Process for the production of a rheology modifier containing composition
WO2013016031A1 (en) 2011-07-27 2013-01-31 The Procter & Gamble Company Multiphase liquid detergent composition
EP2573156A1 (en) 2011-09-20 2013-03-27 The Procter & Gamble Company Liquid cleaning composition
EP2573157A1 (en) 2011-09-20 2013-03-27 The Procter and Gamble Company Liquid detergent composition with abrasive particles
JP6095944B2 (ja) * 2011-12-28 2017-03-15 三栄源エフ・エフ・アイ株式会社 泡組成物
EP2631286A1 (en) 2012-02-23 2013-08-28 The Procter & Gamble Company Liquid cleaning composition
DE102012206014A1 (de) 2012-04-12 2013-10-17 Henkel Ag & Co. Kgaa Mikrofibrilläre Cellulose als schmutzablösevermögender Wirkstoff
EP2836581B1 (en) * 2012-04-13 2021-04-07 CP Kelco U.S., Inc. A highly efficient and convenient form of microfibrous cellulose
ES2577147T3 (es) 2012-10-15 2016-07-13 The Procter & Gamble Company Composición detergente líquida con partículas abrasivas
US9370478B2 (en) 2012-11-09 2016-06-21 Johnson & Johnson Consumer Inc. Skin care compositions containing cotton and citrus-derived materials
US20140134217A1 (en) 2012-11-09 2014-05-15 Johnson & Johnson Consumer Companies, Inc. Leave-on compositions containing cellulose materials
US20140134218A1 (en) 2012-11-09 2014-05-15 Johnson & Johnson Consumer Companies, Inc. Rinse-off skin care compositions containing cellulosic materials
EP2978832A1 (en) 2013-03-26 2016-02-03 The Procter & Gamble Company Cleaning compositions for cleaning a hard surface
EP2824169A1 (en) * 2013-07-12 2015-01-14 The Procter & Gamble Company Structured fabric care compositions
EP3447113B1 (en) * 2013-07-12 2021-06-02 The Procter & Gamble Company Structured liquid compositions
CN105018250B (zh) * 2014-04-28 2020-04-03 海南光宇生物科技有限公司 生物纤维素在制备皮革清洁剂中的新应用
WO2016107793A1 (en) 2014-12-31 2016-07-07 Unilever N.V. Cleaning composition
BR112018006383B8 (pt) * 2015-09-30 2022-08-09 Johnson & Johnson Consumer Inc Composição de limpeza trifásica e seus métodos de preparação e uso
US11261402B2 (en) 2016-01-25 2022-03-01 The Procter & Gamble Company Treatment compositions
CA3011431C (en) 2016-01-25 2021-06-01 The Procter & Gamble Company Fabric treatment compositions, their manufacture and use
WO2018064284A1 (en) 2016-09-30 2018-04-05 Novaflux, Inc. Compositions for cleaning and decontamination
SE540853C2 (en) * 2016-10-28 2018-12-04 Stora Enso Oyj A method to form a web comprising cellulose fibers
EP3339411B1 (en) 2016-12-22 2019-12-11 The Procter & Gamble Company Fabric softener composition having improved viscosity stability
EP3339408B1 (en) 2016-12-22 2020-01-29 The Procter & Gamble Company Fabric softener composition having improved dispensing properties
US10676694B2 (en) 2016-12-22 2020-06-09 The Procter & Gamble Company Fabric softener composition having improved detergent scavenger compatibility
EP3339409B1 (en) 2016-12-22 2020-04-15 The Procter & Gamble Company Fabric softener composition having improved freeze thaw stability
EP3375856B1 (en) 2017-03-16 2021-09-01 The Procter & Gamble Company Fabric softener composition comprising encapsulated benefit agent
BR112019020034B1 (pt) 2017-04-07 2023-09-26 Unilever Ip Holdings B.V Composição de limpeza, método para preparar uma composição de limpeza e uso de material da parede celular
SE543324C2 (en) 2017-12-19 2020-11-24 Stora Enso Oyj A method to produce a fibrous product comprising microfibrillated cellulose
JP7018345B2 (ja) * 2018-03-30 2022-02-10 大王製紙株式会社 ゲル状洗浄剤組成物及び洗浄剤製品
EP3775133A4 (en) 2018-04-03 2021-12-15 Novaflux, Inc. CLEANING COMPOSITION WITH SUPERABSORBENT POLYMER
GB2574006B (en) * 2018-05-21 2023-05-10 Reckitt Benckiser Vanish Bv Peroxide laundry formulation
JP6653364B1 (ja) * 2018-09-28 2020-02-26 大王製紙株式会社 ゲル状洗浄剤組成物及び洗浄剤製品
JP2022525320A (ja) * 2019-03-14 2022-05-12 ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド 増強ケイ素沈着組成物およびそのための方法
EP3730594B1 (en) 2019-04-24 2023-08-30 The Procter & Gamble Company Dishwashing composition having improved sudsing
EP3757196A1 (en) * 2019-06-28 2020-12-30 The Procter & Gamble Company Liquid hand dishwashing detergent composition
KR102293301B1 (ko) * 2019-07-23 2021-08-25 세메스 주식회사 기판 세정 조성물, 기판 세정 조성물의 제조 방법 및 이를 이용한 기판 세정 방법
US11634671B2 (en) 2019-08-28 2023-04-25 Henkel Ag & Co. Kgaa Structured liquid detergent compositions that include a bacterial-derived cellulose network
EP4041180A1 (en) 2019-10-03 2022-08-17 Novaflux Inc. Oral cavity cleaning composition, method, and apparatus
US11186804B2 (en) 2019-11-27 2021-11-30 Henkel IP & Holding GmbH Structured liquid detergent composition for a unit dose detergent pack having improved structuring properties and suspension stability
CN111568802A (zh) * 2020-06-18 2020-08-25 广州家化化学有限公司 一种纳米纤维素去屑洗发水及其制备方法
IT202000017485A1 (it) 2020-07-17 2022-01-17 Davines S P A Formulazioni cosmetiche per il trattamento di capelli con migliorate proprietà
WO2022240478A1 (en) 2021-05-14 2022-11-17 Tyco Fire Products Lp Fire-fighting foam concentrate
US11666791B2 (en) 2021-05-14 2023-06-06 Tyco Fire Products Lp Fire-fighting foam composition
US11497952B1 (en) 2021-05-14 2022-11-15 Tyco Fire Products Lp Fire-fighting foam concentrate
US11673010B2 (en) 2021-05-14 2023-06-13 Tyco Fire Products Lp Fire-fighting foam concentrate
EP4337339A1 (en) 2021-05-14 2024-03-20 Tyco Fire Products LP Fire-fighting foam composition with microfibrous cellulose
US11673011B2 (en) 2021-05-14 2023-06-13 Tyco Fire Products Lp Firefighting foam composition
EP4186969A1 (en) * 2021-11-26 2023-05-31 Henkel AG & Co. KGaA Super-concentrated dilutable powder for dishwashing application

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62172099A (ja) * 1986-01-24 1987-07-29 ダイセル化学工業株式会社 分散安定性の優れた液状クレンザ−組成物
CN1335856A (zh) * 1999-02-10 2002-02-13 赫尔克里士公司 微纤维状多糖衍生物
WO2006017828A1 (en) * 2004-08-06 2006-02-16 The Procter & Gamble Company Personal cleansing composition containing fibers

Family Cites Families (75)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1338249A (en) * 1969-12-10 1973-11-21 Colgate Palmolive Co Granular enzyme products
US3975536A (en) * 1971-05-12 1976-08-17 Fisons Limited Composition
US4452722A (en) * 1980-10-31 1984-06-05 International Telephone And Telegraph Corporation Suspensions containing microfibrillated cellulose
US4378381A (en) * 1980-10-31 1983-03-29 International Telephone And Telegraph Corporation Suspensions containing microfibrillated cellulose
US4500546A (en) * 1980-10-31 1985-02-19 International Telephone And Telegraph Corporation Suspensions containing microfibrillated cellulose
PH18436A (en) * 1980-11-07 1985-07-08 Unilever Nv A fabric softening composition and a process for preparing it
US4483743A (en) * 1981-10-22 1984-11-20 International Telephone And Telegraph Corporation Microfibrillated cellulose
US5988349A (en) * 1987-04-27 1999-11-23 Imonex Services, Inc. Apparatus and method for separating and rejecting coins
US5087471A (en) * 1990-12-13 1992-02-11 Kraft General Foods, Inc. Low calorie salad dressing having smooth, creamy, organoleptic characteristics
JPH0643600A (ja) 1991-06-27 1994-02-18 Fuji Color Service:Kk 写真プリントの焼付・仕上げ方法
WO1995002966A1 (en) * 1993-07-26 1995-02-02 Fmc Corporation Fat-like agents for low calorie food compositions
US5441753A (en) * 1994-01-28 1995-08-15 Fmc Corporation Coprocessed particulate bulking and formulating AIDS: their composition, production, and use
JP2873927B2 (ja) * 1995-04-18 1999-03-24 株式会社バイオポリマー・リサーチ バクテリアセルロースの乾燥方法および乾燥物
JPH0959301A (ja) * 1995-08-21 1997-03-04 Bio Polymer Res:Kk 微小繊維状セルロースの乾燥方法および乾燥物
FR2739394B1 (fr) * 1995-10-03 1997-12-05 Rhone Poulenc Chimie Formulations detartrantes et nettoyantes a base de microfibrilles de cellulose
JPH1088196A (ja) * 1996-09-13 1998-04-07 Kao Corp 洗浄剤組成物
JP4061661B2 (ja) * 1996-05-24 2008-03-19 味の素株式会社 バクテリアセルロース濃縮物の処理方法
JP2000512850A (ja) * 1996-06-20 2000-10-03 ザ・ニユートラスイート・ケルコ・カンパニー 細菌セルロースを含有する食品
EP0912633B1 (fr) * 1996-07-15 2001-03-21 Rhodia Chimie Additivation de nanofibrilles de cellulose avec de la cellulose carboxylee a bas degre de substitution
DE69716917T2 (de) * 1996-07-15 2003-07-17 Rhone Poulenc Chimie Zusammensetzung von nanofibrillen von cellulose mit carboxyliertem cellulose mit hohem substitutionsgrad
FR2759376B1 (fr) 1997-02-12 1999-04-16 Ard Sa Procede pour obtenir des microfibrilles de cellulose cationiques ou leurs derives solubles, ainsi que celluloses obtenues par ce procede
US5951910A (en) 1997-03-17 1999-09-14 Monsanto Company Reticulated bacterial cellulose as a rheological modifier for polyol fluid compositions
US6302209B1 (en) 1997-09-10 2001-10-16 Bj Services Company Surfactant compositions and uses therefor
FR2769836B1 (fr) * 1997-10-21 2000-03-10 Rhodia Chimie Sa Utilisation de nanofibrilles de cellulose essentiellement amorphes associees a au moins un compose organique polyhydroxyle dans des formulations cosmetiques
EP1053282A1 (en) * 1998-02-06 2000-11-22 Monsanto Company Acid-stable and cationic-compatible cellulose compositions and methods of preparation
JPH11255806A (ja) * 1998-03-13 1999-09-21 Bio Polymer Reserch:Kk 微細繊維状セルロース濃縮物の凍結乾燥方法
JP4236064B2 (ja) 1998-05-07 2009-03-11 旭化成ケミカルズ株式会社 低結晶性のセルロース微粒子を含む化粧料組成物
SE9900431D0 (sv) 1999-02-09 1999-02-09 Johan Stenflo Monoklonal antikropp
US6126954A (en) * 1999-04-05 2000-10-03 Unilever Home & Personal Care Usa, Division Of Conopco Liquid compositions comprising stable emulsion of small particle skin benefit agent
FR2794466B1 (fr) * 1999-06-02 2001-06-29 Oreal Composition sous forme d'emulsion huile-dans-eau contenant des fibrilles de cellulose et ses utilisations notamment cosmetiques
FR2794762B1 (fr) * 1999-06-14 2002-06-21 Centre Nat Rech Scient Dispersion de microfibrilles et/ou de microcristaux, notamment de cellulose, dans un solvant organique
US6231651B1 (en) * 1999-06-18 2001-05-15 Mississippi State University Enhanced wood preservative composition
US20010041346A1 (en) 1999-07-14 2001-11-15 Michael E. Mendelsohn Method for assaying compounds affecting smooth muscle contractile state
WO2001005838A1 (en) * 1999-07-15 2001-01-25 Pharmacia Corporation Process for drying reticulated bacterial cellulose without co-agents
AU2001285038A1 (en) 2000-08-25 2002-03-13 Cp Kelco U.S., Inc. Hydrophilic insoluble cellulose as rheological modifier in water-immiscible liquids
US6486785B1 (en) * 2001-08-06 2002-11-26 Universal Thermography, Inc. Method of taking infrared temperature readings through a wildlife shield for electrical equipment
GB2398571A (en) * 2003-02-22 2004-08-25 Reckitt Benckiser Inc Acidic hard surface cleaning and/or disinfecting composition
GB2379223A (en) * 2001-08-31 2003-03-05 Reckitt Benckiser Inc Cleaning composition comprising citric acid
JP2003095904A (ja) 2001-09-26 2003-04-03 Asahi Kasei Corp セルロース含有口腔用組成物の製造方法
US20030109391A1 (en) * 2001-10-03 2003-06-12 The Procter & Gamble Company Shampoo containing particles and a deposition aid
JP4393193B2 (ja) * 2001-11-08 2010-01-06 旭化成株式会社 新規なセルロース系物質
US20030162689A1 (en) * 2002-01-25 2003-08-28 Tatiana Schymitzek Conditioning preparation for fabric care
DE50307290D1 (de) 2002-01-25 2007-06-28 Henkel Kgaa Konditioniermittel zur textilschonung
US20050119151A1 (en) * 2002-04-10 2005-06-02 Konstanze Mayer Textile cleaning agent which is gentle on textiles
DE10215602A1 (de) 2002-04-10 2003-10-30 Henkel Kgaa Textilschonendes Textilreinigungsmittel
US6846785B2 (en) 2002-07-31 2005-01-25 The Dial Corporation Liquid soap with vitamin beads and method for making same
JP2004277544A (ja) 2003-03-14 2004-10-07 Tonen Chem Corp 変性ポリオレフィン溶液の製造方法
RU2369384C2 (ru) 2003-11-20 2009-10-10 ЙЭм БАЙОСАЙЕНСИЗ ИНК. Стабильные липосомальные композиции
DE102004040849A1 (de) * 2004-08-23 2006-03-02 Henkel Kgaa Klares Wasch- und Reinigungsmittel mit Fließgrenze
US7410649B2 (en) * 2004-10-15 2008-08-12 The Procter & Gamble Company Personal care compositions comprising visible beads, cationic polymer, and surfactant
US20060110416A1 (en) * 2004-11-23 2006-05-25 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Hydroalcoholic cosmetic compositions
US20060127345A1 (en) * 2004-12-10 2006-06-15 Hilvert Jennifer E Conditioning shampoo containing stabilized silicone particles
US8053216B2 (en) * 2005-05-23 2011-11-08 Cp Kelco U.S., Inc. Bacterial cellulose-containing formulations
US20070027108A1 (en) * 2005-05-23 2007-02-01 Zhi-Fa Yang Method of producing effective bacterial cellulose-containing formulations
US8772359B2 (en) * 2006-11-08 2014-07-08 Cp Kelco U.S., Inc. Surfactant thickened systems comprising microfibrous cellulose and methods of making same
US9045716B2 (en) * 2006-11-08 2015-06-02 Cp Kelco U.S., Inc. Surfactant thickened systems comprising microfibrous cellulose and methods of making same
US7888308B2 (en) * 2006-12-19 2011-02-15 Cp Kelco U.S., Inc. Cationic surfactant systems comprising microfibrous cellulose
US20080227892A1 (en) * 2007-03-13 2008-09-18 Van Der Wielen Maarten Paint formulations comprising cellulose ether/network building polymer fluid gel thickeners
US7994111B2 (en) * 2008-02-15 2011-08-09 The Procter & Gamble Company Liquid detergent composition comprising an external structuring system comprising a bacterial cellulose network
US7776807B2 (en) * 2008-07-11 2010-08-17 Conopco, Inc. Liquid cleansing compositions comprising microfibrous cellulose suspending polymers
US20100016575A1 (en) * 2008-07-15 2010-01-21 Zhi-Fa Yang Bacterial cellulose-containing formulations lacking a carboxymethyl cellulose component
EP2213714B1 (en) * 2009-02-02 2014-06-11 The Procter and Gamble Company Liquid hand dishwashing detergent composition
US8097574B2 (en) * 2009-08-14 2012-01-17 The Gillette Company Personal cleansing compositions comprising a bacterial cellulose network and cationic polymer
CA2772172A1 (en) * 2009-09-08 2011-03-17 John Mcarthur Swazey, Jr. Methods to improve the compatibility and efficiency of powdered versions of microfibrous cellulose
WO2011056947A1 (en) * 2009-11-04 2011-05-12 Colgate-Palmolive Company Composition with stable suspending system
AU2010315151B2 (en) * 2009-11-04 2013-06-06 Colgate-Palmolive Company Microfibrous cellulose and alkaline earth metal ion structured surfactant composition
US8546318B2 (en) * 2009-11-04 2013-10-01 Colgate-Palmolive Company Microfibrous cellulose having a particle size distribution for structured surfactant compositions
US8642529B2 (en) * 2010-11-15 2014-02-04 Conopco, Inc. Liquid low surfactant compositions structured with a fibrous polymer
US7981855B1 (en) * 2010-11-15 2011-07-19 Conopco, Inc. Liquid surfactant compositions structured with fibrous polymer and citrus fibers having no flow instability or shear banding
EP2551337A1 (en) * 2011-07-27 2013-01-30 The Procter & Gamble Company Process for the production of a rheology modifier containing composition
US8470755B1 (en) * 2012-03-23 2013-06-25 The Procter & Gamble Company Liquid cleaning and disinfecting compositions comprising a zinc inorganic salt
US20130274149A1 (en) * 2012-04-13 2013-10-17 Schlumberger Technology Corporation Fluids and methods including nanocellulose
EP2836581B1 (en) * 2012-04-13 2021-04-07 CP Kelco U.S., Inc. A highly efficient and convenient form of microfibrous cellulose
CN104684936B (zh) * 2012-07-27 2017-10-17 克宁克莱克合作侨兴公司 用作液体清洁剂和个人护理产品的结构化剂
EP3447113B1 (en) * 2013-07-12 2021-06-02 The Procter & Gamble Company Structured liquid compositions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62172099A (ja) * 1986-01-24 1987-07-29 ダイセル化学工業株式会社 分散安定性の優れた液状クレンザ−組成物
CN1335856A (zh) * 1999-02-10 2002-02-13 赫尔克里士公司 微纤维状多糖衍生物
WO2006017828A1 (en) * 2004-08-06 2006-02-16 The Procter & Gamble Company Personal cleansing composition containing fibers

Also Published As

Publication number Publication date
AU2007317389A1 (en) 2008-05-15
EP2091510B1 (en) 2015-03-04
HUE028101T2 (en) 2016-11-28
IL198608A (en) 2017-02-28
PT2486912E (pt) 2015-12-24
UY30701A1 (es) 2009-04-30
DK2091510T3 (da) 2015-05-18
ES2393973T3 (es) 2015-12-28
DE12167764T1 (de) 2013-01-17
US20150240193A1 (en) 2015-08-27
EP2486912B1 (en) 2015-09-09
JP2010509462A (ja) 2010-03-25
IL198608A0 (en) 2010-02-17
ZA200903263B (en) 2010-04-28
US10030214B2 (en) 2018-07-24
AU2007317389B2 (en) 2012-09-20
DE12167764T8 (de) 2013-04-25
US9045716B2 (en) 2015-06-02
KR20090087030A (ko) 2009-08-14
DK2486912T3 (da) 2015-12-07
CA2668898C (en) 2014-12-23
US20080108714A1 (en) 2008-05-08
CA2668898A1 (en) 2008-05-15
CN102973430A (zh) 2013-03-20
WO2008057985A1 (en) 2008-05-15
US10214708B2 (en) 2019-02-26
JP2014098163A (ja) 2014-05-29
MY186434A (en) 2021-07-22
EP2091510A4 (en) 2011-04-06
CN101557797A (zh) 2009-10-14
PE20081055A1 (es) 2008-08-25
JP5520049B2 (ja) 2014-06-11
PL2486912T3 (pl) 2016-01-29
ES2393973T1 (es) 2013-01-03
CN102973430B (zh) 2018-04-20
TW200844222A (en) 2008-11-16
AR063466A1 (es) 2009-01-28
RU2009120142A (ru) 2010-12-20
CN108251234A (zh) 2018-07-06
BRPI0718779A2 (pt) 2017-05-16
JP5788035B2 (ja) 2015-09-30
EP2091510A1 (en) 2009-08-26
MX2009004915A (es) 2009-08-31
US20150240191A1 (en) 2015-08-27
PL2091510T3 (pl) 2015-08-31
ES2534542T3 (es) 2015-04-24
CN108251234B (zh) 2021-10-26
CL2007003213A1 (es) 2008-10-10
EP2486912A1 (en) 2012-08-15
CN101557797B (zh) 2018-04-20
SG186009A1 (en) 2012-12-28
SI2091510T1 (sl) 2015-06-30
RU2471476C2 (ru) 2013-01-10

Similar Documents

Publication Publication Date Title
TWI482853B (zh) 包含微纖維纖維素之界面活性劑稠化系統及其製造方法
US8772359B2 (en) Surfactant thickened systems comprising microfibrous cellulose and methods of making same
RU2471860C2 (ru) Катионная система поверхностно-активных веществ, содержащая микроволокнистую целлюлозу
AU2007337158B2 (en) Cationic surfactant systems comprising microfibrous cellulose