TWI479643B - 矽基底上所形成之互補金氧半導體(cmos)及iii-v族裝置之電接點 - Google Patents
矽基底上所形成之互補金氧半導體(cmos)及iii-v族裝置之電接點 Download PDFInfo
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- 239000000758 substrate Substances 0.000 title claims description 24
- 229910052710 silicon Inorganic materials 0.000 title description 3
- 239000010703 silicon Substances 0.000 title description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title 1
- 229910052732 germanium Inorganic materials 0.000 claims description 29
- 229910052721 tungsten Inorganic materials 0.000 claims description 26
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 18
- 229910052763 palladium Inorganic materials 0.000 claims description 18
- 229910052782 aluminium Inorganic materials 0.000 claims description 17
- 239000010949 copper Substances 0.000 claims description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 16
- 229910052802 copper Inorganic materials 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 239000004065 semiconductor Substances 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 230000005669 field effect Effects 0.000 claims description 8
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 12
- 239000010410 layer Substances 0.000 description 123
- VGRFVJMYCCLWPQ-UHFFFAOYSA-N germanium Chemical compound [Ge].[Ge] VGRFVJMYCCLWPQ-UHFFFAOYSA-N 0.000 description 18
- 238000000034 method Methods 0.000 description 13
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 11
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 11
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 10
- 238000000231 atomic layer deposition Methods 0.000 description 9
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 9
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 6
- 239000010937 tungsten Substances 0.000 description 6
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000009413 insulation Methods 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 4
- 230000000149 penetrating effect Effects 0.000 description 4
- 239000004020 conductor Substances 0.000 description 3
- 230000005693 optoelectronics Effects 0.000 description 3
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 125000005626 carbonium group Chemical group 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 229940119177 germanium dioxide Drugs 0.000 description 2
- MWRJCEDXZKNABM-UHFFFAOYSA-N germanium tungsten Chemical compound [Ge].[W] MWRJCEDXZKNABM-UHFFFAOYSA-N 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910001258 titanium gold Inorganic materials 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000001451 molecular beam epitaxy Methods 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910001936 tantalum oxide Inorganic materials 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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Description
此申請案有關於與此專利申請案同天申請的共同申請之專利申請案美國專利申請案第(專利代理人卷號RTN2-214PUS),其全部標的以引用方式包含於此。
本發明主要有關於電接點,尤其關於形成在矽基底上之CMOS裝置及III-V族裝置的電接點。
如在此技藝中已知,CMOS VLSI整合能力超過一億電晶體的程度。亦如在此技藝中已知,一些應用要求類比、RF或光電裝置亦形成在與CMOS裝置相同的基底上。這些類比、RF或光電裝置典型為III-V族裝置。說明整合CMOS裝置及III-V族裝置之一種技術使用Ge晶種層,如於2008年6月26日公開之美國專利申請公開案第2008/0149915 A1號中所述,亦參見美國專利案第7,374,106、7,286,726、7,057,256、6,930,82、5,767,539、6,154,475、7,321,713、及7,057,256號。亦參見,由Dohrman等人發表在Materials Science and Engineering B 135(2006)第235-237頁中之“Fabrication of silicon on lattice-engineered substrate(SOLES) as a platform for monolithic integration of CMOS and optoelectronic devices”。亦參見由Herrick等人發表於Material Research Society Symposium Proceedings,第1068冊,Materials Research Society(1068-C02-10)中之“Direct Growth of III-V Devices on Silicon”。
亦如在此技藝中已知,高溫程序技術用來形成小幾何的TaN或TiN上Cu之電接點到CMOS裝置;另一方面,III-V族電接點典型為TiPtAu或TiAu且使用剝離技術加以製造。
本發明人已認知TiPtAu或TiAu剝離技術的使用會限制電路密度且亦與已根深蒂固之基於Si CMOS VLSI銅互連程序不相容。本發明解決在第一層級金屬互連步驟異質整合的III-V族裝置與基於Si CMOS VLSI銅互連程序之間的互連問題。本發明描述一種異質整合的III-V族裝置與Si CMOS的金屬化方法,其與CMOS VLSI金屬互連程序完全相容。
根據本發明,設置一半導體結構,其具有:基底;在該基底上之晶種層;配置在該晶種層上之矽層;在該矽層中之電晶體裝置;配置在該晶種層中之III-V族裝置;以及複數電接點,該等電接點之每一個具有一TiN或TaN層及在該TaN或TiN層上之金屬層,該等電接點之一電連接至該Si CMOS電晶體且該等電接點之另一電連接至該III-V族裝置。
在一實施例中,該金屬為銅或鋁。
藉由此種佈置,解決在第一層級金屬互連步驟異質整合的III-V族裝置與基於Si CMOS VLSI銅或鋁互連程序之間的互連問題。此佈置與CMOS VLSI金屬互連程序完全相容。此佈置使用現有的先進薄膜技術,如原子層沈積(ALD)方法來提供完全CMOS VLSI程序相容的金屬互連方法,其藉由使用ALD沈積的TiN及/或TaN來接觸III-V族FET之源極、汲極、及閘極或III-V族HBT之射極、基極、及集極,以防止在這些接點及基於銅或鋁的Si CMOS VLSI互連之間的相互擴散。此外,此佈置提供對在Si基底上之異質整合的III-V族裝置中的基於III-V族裝置的端子之基於銅或鋁的低電阻及電感存取。如前述,此佈置與Si CMOS VLSI金屬互連程序完全相容。
在附圖及下列說明中提出本發明之一或更多實施例的細節。本發明之其他特徵、目的及優點將從說明及圖示及從申請專利範圍變得更清楚。
茲參照第1圖,顯示半導體結構10,其具有形成在矽半導體12之一部分上的CMOS場效電晶體(FET) 14及形成在矽基底上之橫向間隔的部份上的III-V族FET 15。矽半導體12在此為具有取決於應用之高或低電阻率的大塊矽。
配置在矽基底12上為二氧化矽絕緣層16及於二氧化矽絕緣層16上之如Ge的晶種層18。一二氧化矽絕緣層20配置在其上有CMOS電晶體14之矽基底12的部份上。如所示,在二氧化矽絕緣層20上有一矽層22。如所示,CMOS電晶體14形成在矽層22上。NMOS電晶體與PMOS電晶體藉由介電質(在此二氧化矽)區域24電絕緣。
晶種層18上形成有GaAs的高電阻率/半絕緣緩衝層19。如GaAs之III-V族材料層21係形成在緩衝層19上。
如所示,有至CMOS電晶體14之源極與汲極區域的鎢(W)接點26。CMOS電晶體14之閘極電極由參考符號27表示。如所示,鎢接點26藉由二氧化矽層28互相電絕緣。有至III-V族FET 15之源極與汲極區域之Ge/W、Ni/Ge/W、Pd/Ge/Al、Pd/Ge/W接點30。
TiN及/或TaN之原子層沈積(ALD)層32係沈積在鎢接點26上及Ge/W或Ni/Ge/W接點30上。TiN及/或TaN層32與III-V族FET 15之閘極區域肖特基接觸。有導電體34(在此電鍍銅)形成在層32上。注意到由介電質層36、37、38、及40電絕緣層32及34。在此層36、37、38、及40為:二氧化矽(層36)、PECVD SiN(層37)、低K的SiOC(碳氧化矽,亦即摻雜C之二氧化矽層並用於Si CMOS VLSI的製造中)間層(層38)、及PECVD的SiN層(層4())。在此層32為TiN或TaN。
詳言之,在層28上及鎢(W)接點26上之層36為二氧化矽。層37在層36上,層37為薄PECVD的SiN層。層38在層37上,層38為低介電質常數(低k ILD,在此碳氧化矽,亦即摻雜C之二氧化矽層並用於Si CMOS VLSI的製造中)。層40在層38上,層40為銅CMP之PECVD硬遮罩。
茲參照第2A至2G圖,其顯示形成結構10之程序。因此,參照第2A圖,在形成結構(其具有在矽基底12上之二氧化矽絕緣層16、在二氧化矽絕緣層16上之晶種層18、在晶種層18上之二氧化矽絕緣層20、在二氧化矽絕緣層20上之矽層22、形成在矽層22上之CMOS電晶體14、形成至CMOS電晶體14的源極與汲極區域及介電質層36的鎢(W)接點26)之後,蝕刻一III-V族裝置島區域50直至晶種層18的上表面。
茲參照第2B圖,將高電阻率/半絕緣緩衝層19(在此例如GaAs的III-V族材料)形成在晶種層18的上表面上。使用例如熟悉III-V族材料生長技藝者已知之分子束磊晶(MBE)或金屬有機CVD(MOCVD)生長技術將例如InP或GaAs的主動III-V族層21形成在緩衝層19上。
茲參照第2C圖,將源極與汲極接點30(在此Ge/W或Ni/Ge/W)形成在主動層21之源極與汲極區域上,之後取決於III-V族裝置結構在410至450℃的溫度熔合。如所述,在此將閘極凹部23形成在主動層21的上表面上。
茲參照第2D圖,如所示,將薄PECVD SiN層37形成於第2C圖中所示之結構的上表面上方。
茲參照第2E圖,將低介電質(低K)間層38形成在薄PECVD SiN層37上,接著沈積銅CMP用之PECVD SiN硬遮罩層40於低介電質(低K)間層38上。
茲參照第2F圖,形成貫穿介電質之接觸洞52以到達NMOS及PMOS FET 14之鎢拴26,且形成貫穿介電質之接觸洞53以到達III-V族FET裝置15之源極與汲極接點30及III-V族FET裝置15用之閘極區域23。在此,在閘極23之主動層21的部份上有一額外非關鍵濕蝕刻以形成雙凹部閘極區域。
茲參照第2G圖,將原子層沈積層32 Ni/TiN或Ni/TaN(注意到若III-V族裝置為基於GaAs或InP,原子層沈積薄膜可為TiN或TaN,而若III-V族裝置為基於GaN,原子層沈積薄膜可為Ni/TiN或Ni/TaN)沈積在第2F圖中所示之結構的表面上方。
將銅層34電鍍在層32之表面上並接著予以化學機械研磨(CMP)而得到第1圖中所示之結構。
茲參照第3A至3H圖,其顯示形成具有CMOS電晶體及III-V族異質接面雙極電晶體(HBT)的結構之程序。在此同樣地程序以具有在矽基底12上之二氧化矽絕緣層16、在二氧化矽絕緣層16上之晶種層18、在晶種層18上之二氧化矽絕緣層20、在二氧化矽絕緣層20上之矽層22、形成在矽層22上之CMOS電晶體14、形成至CMOS電晶體14的源極與汲極區域及介電質層36的鎢(W)接點26的結構開始,蝕刻一III-V族裝置島區域50直至晶種層18的上表面。
茲參照第3B圖,將高電阻率/半絕緣緩衝層19形成在晶種層18的上表面上。將例如InP或GaAs的主動III-V族層21’形成在緩衝層19上。在此,如所示,有在頂部有非常高摻雜之較低子集極層21a,且其上有III-V族集極層21b,且其上有III-V族基極層21c,且其上有III-V族射極層21d。
茲參照第3C圖,沿著基極-集極凸部67、基極歐姆接點68、射極歐姆接點69、及射極-基極凸部70形成集極歐姆接點66。再次以PECVD SiN層37覆蓋結構作為III-V族HBT 15’的第一被動層,如第3D圖中所示。可經由Pt/W薄層形成集極、基極、及射極歐姆接點。
茲參照第3E圖,接著如連同第2E、2F、及2G圖所述般處理結構,以分別產生如第3E、3F、及3G圖中所示之結構,以產生如第3H圖中所示之結構。因此,茲參照第3E圖,將低介電質(低K)間層38形成在薄PECVD SiN層37上,接著沈積銅CMP用之PECVD SiN硬遮罩層40於低介電質(低K)間層38上。
茲參照第3F圖,形成貫穿介電質之接觸洞52以到達NMOS及PMOS FET 14之鎢拴26,且形成貫穿介電質之接觸洞53a、53b、及53c以到達III-V族HBT裝置15’之集極、基極、及射極接點66、68、及69。
茲參照第3G圖,將原子層沈積層32 Ni/TiN或Ni/TaN沈積在第3F圖中所示之結構的表面上方。將銅層34電鍍在層32之表面上並接著予以化學機械研磨(CMP)而得到第3H圖中所示之結構。
已經說明本發明的多個實施例。然而,可了解到可做出不背離本發明之精神與範疇之各種修改。例如,取代銅可藉由噴濺沈積及減去圖案化而使用鋁作為層34。依此,其他實施例係在下列申請專利範圍之範疇內。
10...半導體結構
12...矽半導體
14...CMOS場效電晶體(FET)
15...III-V族FET
15’...III-V族異質接面雙極電晶體
16...二氧化矽絕緣層
18...晶種層
19...緩衝層
20...二氧化矽絕緣層
21、21’...III-V族材料層
21a...較低子集極層
21b...III-V族集極層
21c...III-V族基極層
21d...III-V族射極層
22...矽層
23...閘極凹部
24...介電質區域
26...接點
27...閘極電極
28...二氧化矽層
30...接點
32...原子層沈積(ALD)層
34...導電體
36、37、38、40...介電質層
50...III-V族裝置島區域
52、53、53a、53b、53d...接觸洞
66...集極歐姆接點
67...基極-集極凸部
68...基極歐姆接點
69...射極歐姆接點
70...射極-基極凸部
第1圖為根據本發明之半導體結構的剖面圖,此結構具有形成在基底上之矽層中之CMOS FET且具有形成在基底上之III-V族FET;
第2A至2G圖為第1圖之半導體結構在其之製造中的各個階段之剖面圖;以及
第3A至3H圖為根據本發明之另一實施例的另一半導體結構在其之製造中的各個階段之剖面圖,此結構具有形成在基底上之矽層中之CMOS FET且具有形成在基底上之III-V族HBT。
各個圖中之類似參考符號表示類似元件。
10...半導體結構
12...矽半導體
14...CMOS場效電晶體(FET)
15...III-V族FET
16...二氧化矽絕緣層
18...晶種層
19...緩衝層
20...二氧化矽絕緣層
21...III-V族材料層
22...矽層
24...介電質區域
26...接點
28...二氧化矽層
30...接點
32...原子層沈積(ALD)層
34...導電體
36、38、40...介電質層
Claims (20)
- 一種半導體結構,包含:基底;在該基底上之晶種層;配置在該晶種層上之矽層;在該矽層中之電晶體裝置;配置在該晶種層上之III-V族層;配置在該III-V族層中之III-V族裝置;以及複數電接點,該等電接點之每一個具有一TiN或TaN層及在該TaN或TiN層上之金屬層,該等電接點之一電連接至該矽層中之該電晶體裝置且該等電接點之另一電連接至該III-V族裝置,該等電接點之該另一具有與該III-V族層接觸之一Ge/W、Ni/Ge/W、Pd/Ge/Al或Pd/Ge/W層,且其中該TaN或TiN層被配置在該Ge/W、Ni/Ge/W、Pd/Ge/Al或Pd/Ge/W層上。
- 如申請專利範圍第1項所述之結構,其中該金屬層為鋁。
- 如申請專利範圍第1項所述之結構,其中該金屬層為銅。
- 如申請專利範圍第1項所述之結構,其中該電晶體裝置為矽場效電晶體。
- 如申請專利範圍第1項所述之結構,其中該矽層中具有CMOS FET。
- 如申請專利範圍第4項所述之結構,其中該III-V 族裝置為FET。
- 如申請專利範圍第5項所述之結構,其中該III-V族裝置為FET。
- 如申請專利範圍第4項所述之結構,其中該III-V族裝置為雙極電晶體。
- 如申請專利範圍第5項所述之結構,其中該III-V族裝置為雙極電晶體。
- 一種半導體結構,包含:基底;配置在該基底上之矽層;在該矽層中之電晶體裝置;配置在該基底上之III-V族裝置;以及複數電接點,該等電接點之每一個具有一TiN或TaN層及在該TaN或TiN層上之金屬層,該等電接點之一電連接至該電晶體裝置且該等電接點之另一電連接至該III-V族裝置,該等電接點之該另一具有與該III-V族層接觸之一Ge/W、Ni/Ge/W、Pd/Ge/Al或Pd/Ge/W層,且其中該TaN或TiN層被配置在該Ge/W、Ni/Ge/W、Pd/Ge/Al或Pd/Ge/W層上。
- 如申請專利範圍第10項所述之結構,其中該金屬層為鋁。
- 如申請專利範圍第10項所述之結構,其中該金屬層為銅。
- 一種半導體結構,包含: 基底;在該基底上之晶種層;配置在該晶種層上之矽層;在該矽層中之電晶體裝置;配置在該晶種層上之III-V族裝置;以及複數電接點,該等電接點之每一個具有一TiN或TaN層及在該TaN或TiN層上之銅或鋁層,該等電接點之一電連接至該電晶體裝置且該等電接點之另一電連接至該III-V族裝置,該等電接點之該另一具有與該III-V族層接觸之一Ge/W、Ni/Ge/W、Pd/Ge/Al或Pd/Ge/W層,且其中該TaN或TiN層被配置在該Ge/W、Ni/Ge/W、Pd/Ge/Al或Pd/Ge/W層上。
- 如申請專利範圍第12項所述之結構,其中該電晶體裝置為矽場效電晶體。
- 如申請專利範圍第12項所述之結構,其中該矽層中具有CMOS FET。
- 如申請專利範圍第13項所述之結構,其中該III-V族裝置為FET。
- 如申請專利範圍第14項所述之結構,其中該III-V族裝置為FET。
- 如申請專利範圍第13項所述之結構,其中該III-V族裝置為雙極電晶體。
- 如申請專利範圍第14項所述之結構,其中該III-V族裝置為雙極電晶體。
- 一種半導體結構,包含:基底;配置在該基底上之矽層;在該矽層中之電晶體裝置;配置在該基底上之III-V族層;配置在該III-V族層中之III-V族場效電晶體;以及複數電接點,該等電接點之每一個具有一TiN或TaN層,該TaN或TiN層為:(A)電連接至該矽層中之該電晶體裝置;(B)與III-V族材料肖特基接觸以提供閘極接觸給該III-V族場效電晶體;及(C)配置在一Ge/W、Ni/Ge/W、Pd/Ge/Al或Pd/Ge/W層上,該Ge/W、Ni/Ge/W、Pd/Ge/Al或Pd/Ge/W層與該III-V族場效電晶體之源極和汲極區接觸。
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- 2010-01-18 TW TW099101218A patent/TWI479643B/zh active
- 2010-01-20 WO PCT/US2010/021443 patent/WO2010085458A1/en active Application Filing
- 2010-01-20 JP JP2011546436A patent/JP5603882B2/ja active Active
- 2010-01-20 EP EP10700798.1A patent/EP2380195B1/en active Active
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EP2380195B1 (en) | 2018-09-12 |
JP2012516037A (ja) | 2012-07-12 |
EP2380195A1 (en) | 2011-10-26 |
US7834456B2 (en) | 2010-11-16 |
WO2010085458A1 (en) | 2010-07-29 |
US20100181674A1 (en) | 2010-07-22 |
JP5603882B2 (ja) | 2014-10-08 |
TW201044554A (en) | 2010-12-16 |
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