TWI365104B - High activity small crystal zsm-12 - Google Patents

High activity small crystal zsm-12

Info

Publication number
TWI365104B
TWI365104B TW092128316A TW92128316A TWI365104B TW I365104 B TWI365104 B TW I365104B TW 092128316 A TW092128316 A TW 092128316A TW 92128316 A TW92128316 A TW 92128316A TW I365104 B TWI365104 B TW I365104B
Authority
TW
Taiwan
Prior art keywords
high activity
small crystal
crystal zsm
activity small
zsm
Prior art date
Application number
TW092128316A
Other languages
English (en)
Chinese (zh)
Other versions
TW200420350A (en
Inventor
Ivy Dawn Johnson
Wenyih Frank Lai
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Publication of TW200420350A publication Critical patent/TW200420350A/zh
Application granted granted Critical
Publication of TWI365104B publication Critical patent/TWI365104B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/42—Type ZSM-12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/33—MTW, e.g. ZSM-12, NU-13, CZH-5, TPZ-3

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)
TW092128316A 2002-11-15 2003-10-13 High activity small crystal zsm-12 TWI365104B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/294,780 US6893624B2 (en) 2002-11-15 2002-11-15 High activity small crystal ZSM-12

Publications (2)

Publication Number Publication Date
TW200420350A TW200420350A (en) 2004-10-16
TWI365104B true TWI365104B (en) 2012-06-01

Family

ID=32297040

Family Applications (1)

Application Number Title Priority Date Filing Date
TW092128316A TWI365104B (en) 2002-11-15 2003-10-13 High activity small crystal zsm-12

Country Status (9)

Country Link
US (1) US6893624B2 (enExample)
EP (1) EP1560793A1 (enExample)
JP (1) JP2006506311A (enExample)
KR (1) KR101064796B1 (enExample)
CN (1) CN100404419C (enExample)
AU (1) AU2003284254A1 (enExample)
MY (1) MY134623A (enExample)
TW (1) TWI365104B (enExample)
WO (1) WO2004046034A1 (enExample)

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US7553791B2 (en) 2002-11-14 2009-06-30 Exxonmobil Chemical Patents Inc. Heavy aromatics conversion catalyst composition and processes therefor and therewith
DE10314753A1 (de) * 2003-04-01 2004-10-14 Süd-Chemie AG Synthetischer Zeolith, insbesondere für die katalytische Hydroisomerisierung von höheren Paraffinen
EA200800522A1 (ru) * 2005-08-04 2009-12-30 Шеврон Ю.Эс.Эй. Инк. Способ депарафинизации при использовании цеолитов мтт и mtw
US8816145B2 (en) 2007-06-21 2014-08-26 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
US20090093662A1 (en) * 2007-10-08 2009-04-09 Whitchurch Patrick C Aromatic isomerization catalyst
US8030240B2 (en) * 2007-12-28 2011-10-04 Exxonmobil Research And Engineering Company Multiple molecular sieve catalyst for sour service dewaxing
US7626064B1 (en) * 2008-06-26 2009-12-01 Uop Llc Transalkylation process
RU2011103935A (ru) 2008-07-04 2012-08-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Катализатор и способ изомеризации
US20110034749A1 (en) * 2009-08-07 2011-02-10 Exxonmobil Research And Engineering Company Synthesis and use of ZSM-12
US8202506B2 (en) 2009-11-17 2012-06-19 Exxonmobil Research And Engineering Company High activity small crystal ZSM-12
US8679451B2 (en) * 2009-11-20 2014-03-25 Chevron U.S.A. Inc. Method for making aluminosilicate ZSM-12
US8101811B2 (en) * 2009-11-20 2012-01-24 Chevron U.S.A. Inc. Process for isomerizing a hydrocarbonaceous feedstock using aluminosilicate ZSM-12
CN101792153B (zh) * 2010-03-02 2012-03-07 黑龙江大学 硅镓酸盐分子筛Ga-ZSM-12的合成方法
JP5635679B2 (ja) * 2010-04-21 2014-12-03 エクソンモービル ケミカル パテンツ インコーポレイテッド キシレンの異性化プロセスおよびそのための触媒
EP2455160A1 (en) 2010-11-18 2012-05-23 Shell Internationale Research Maatschappij B.V. Isomerisation catalyst preparation process
EP2455161A1 (en) 2010-11-18 2012-05-23 Shell Internationale Research Maatschappij B.V. Isomerisation catalyst preparation process
TWI483775B (zh) * 2011-09-16 2015-05-11 Exxonmobil Chem Patents Inc 經改善之ｍｃｍ－５６製法
WO2013090534A1 (en) 2011-12-16 2013-06-20 Shell Oil Company A titania-bound zsm-12 zeolite composition and method of making and using such composition
WO2014088723A1 (en) 2012-12-07 2014-06-12 Exxonmobil Research And Engineering Company Synthesis of zsm-5 crystals with improved morphology
US9522858B2 (en) 2013-05-31 2016-12-20 Exxonmobil Chemical Patents Inc. Transalkylation system
CN103922362A (zh) * 2014-04-19 2014-07-16 复旦大学 一种的mtw沸石及其制备方法
US10450243B2 (en) 2014-12-19 2019-10-22 Exxonmobil Chemical Patents Inc. Sulfiding process for aromatic transalkylations
CN106564909B (zh) * 2015-10-09 2018-11-30 中国石油化工股份有限公司 一种zsm-12分子筛的制备方法
EP3383796B1 (en) * 2015-12-04 2020-09-16 ExxonMobil Research and Engineering Company Emm-28, a novel synthetic crystalline material, its preparation and use
KR101692547B1 (ko) * 2016-04-26 2017-01-03 에스케이이노베이션 주식회사 중질기유의 헤이즈 저감 방법 및 헤이즈가 저감된 수소 첨가 이성화 촉매계
CA3045734A1 (en) 2016-12-16 2018-06-21 Shell Internationale Research Maatschappij B.V. Catalyst system for dewaxing
US11261141B2 (en) 2017-12-14 2022-03-01 Exxonmobil Chemical Patents Inc. Processes for isomerizing alpha olefins
CA3096149A1 (en) 2018-04-17 2019-10-24 Shell Internationale Research Maatschappij B.V. Catalyst system for dewaxing
CN112939009B (zh) * 2019-12-11 2022-11-15 中国科学院大连化学物理研究所 一种mtw型分子筛的固相合成方法
JP7687032B2 (ja) * 2021-04-15 2025-06-03 東ソー株式会社 Ｍｔｗ型ゼオライト

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US6652832B2 (en) * 2001-02-05 2003-11-25 Exxonmobil Oil Corporation Synthesis of ZSM-12
US7308067B2 (en) * 2003-08-04 2007-12-11 Intel Corporation Read bias scheme for phase change memories

Also Published As

Publication number Publication date
US20040097363A1 (en) 2004-05-20
MY134623A (en) 2007-12-31
CN1774398A (zh) 2006-05-17
CN100404419C (zh) 2008-07-23
EP1560793A1 (en) 2005-08-10
KR101064796B1 (ko) 2011-09-14
JP2006506311A (ja) 2006-02-23
TW200420350A (en) 2004-10-16
KR20050085004A (ko) 2005-08-29
US6893624B2 (en) 2005-05-17
AU2003284254A1 (en) 2004-06-15
WO2004046034A1 (en) 2004-06-03

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