TWI356071B - Flame retardant compositions - Google Patents
Flame retardant compositions Download PDFInfo
- Publication number
- TWI356071B TWI356071B TW093129611A TW93129611A TWI356071B TW I356071 B TWI356071 B TW I356071B TW 093129611 A TW093129611 A TW 093129611A TW 93129611 A TW93129611 A TW 93129611A TW I356071 B TWI356071 B TW I356071B
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- TW
- Taiwan
- Prior art keywords
- group
- compound
- ring
- formula
- flame retardant
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 88
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 75
- 239000003063 flame retardant Substances 0.000 title claims abstract description 73
- 150000001875 compounds Chemical class 0.000 claims abstract description 198
- -1 cycloalkyl alkane Chemical class 0.000 claims description 183
- 239000011159 matrix material Substances 0.000 claims description 73
- 125000003118 aryl group Chemical group 0.000 claims description 60
- 125000000623 heterocyclic group Chemical group 0.000 claims description 58
- 125000000217 alkyl group Chemical group 0.000 claims description 54
- 229920006395 saturated elastomer Polymers 0.000 claims description 43
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 39
- 125000003342 alkenyl group Chemical group 0.000 claims description 36
- 125000001424 substituent group Chemical group 0.000 claims description 35
- 125000004432 carbon atom Chemical group C* 0.000 claims description 33
- 125000004429 atom Chemical group 0.000 claims description 32
- 150000001412 amines Chemical class 0.000 claims description 28
- 125000002947 alkylene group Chemical group 0.000 claims description 27
- 125000004122 cyclic group Chemical group 0.000 claims description 25
- 125000002993 cycloalkylene group Chemical group 0.000 claims description 23
- 125000002950 monocyclic group Chemical group 0.000 claims description 20
- 125000006413 ring segment Chemical group 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 12
- 229920000877 Melamine resin Polymers 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 11
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims description 11
- 125000002619 bicyclic group Chemical group 0.000 claims description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- 125000000304 alkynyl group Chemical group 0.000 claims description 10
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 10
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 9
- 229910044991 metal oxide Inorganic materials 0.000 claims description 9
- 125000003367 polycyclic group Chemical group 0.000 claims description 9
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- 150000004706 metal oxides Chemical class 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 7
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 7
- 150000002923 oximes Chemical class 0.000 claims description 6
- 239000011574 phosphorus Substances 0.000 claims description 6
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims description 5
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- 239000004611 light stabiliser Substances 0.000 claims description 5
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000008901 benefit Effects 0.000 claims description 4
- 125000002618 bicyclic heterocycle group Chemical group 0.000 claims description 4
- 150000004692 metal hydroxides Chemical class 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 230000002195 synergetic effect Effects 0.000 claims description 4
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- 230000000996 additive effect Effects 0.000 claims description 3
- 150000001639 boron compounds Chemical class 0.000 claims description 3
- 150000001924 cycloalkanes Chemical class 0.000 claims description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 230000002745 absorbent Effects 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 150000002903 organophosphorus compounds Chemical class 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 2
- 101100439662 Arabidopsis thaliana CHR5 gene Proteins 0.000 claims 1
- 244000122871 Caryocar villosum Species 0.000 claims 1
- 125000004653 anthracenylene group Chemical group 0.000 claims 1
- 150000001622 bismuth compounds Chemical class 0.000 claims 1
- 125000003739 carbamimidoyl group Chemical group C(N)(=N)* 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
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- 150000002443 hydroxylamines Chemical class 0.000 claims 1
- 230000004936 stimulating effect Effects 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims 1
- 150000003573 thiols Chemical class 0.000 claims 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 21
- 239000000758 substrate Substances 0.000 abstract description 4
- 230000000979 retarding effect Effects 0.000 abstract description 3
- 150000002978 peroxides Chemical class 0.000 abstract description 2
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- 229910052757 nitrogen Inorganic materials 0.000 description 28
- 239000005977 Ethylene Substances 0.000 description 25
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 21
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- 239000007983 Tris buffer Substances 0.000 description 12
- 125000005842 heteroatom Chemical group 0.000 description 11
- 229960003742 phenol Drugs 0.000 description 11
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- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 10
- 239000005062 Polybutadiene Substances 0.000 description 10
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical class [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 10
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 description 10
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 10
- 229920000768 polyamine Polymers 0.000 description 10
- 229920002857 polybutadiene Polymers 0.000 description 10
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 239000004698 Polyethylene Substances 0.000 description 9
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 9
- 229910052707 ruthenium Inorganic materials 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000012964 benzotriazole Substances 0.000 description 8
- 239000004305 biphenyl Substances 0.000 description 8
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 description 7
- 125000000732 arylene group Chemical group 0.000 description 7
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 7
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- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 7
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- 125000005717 substituted cycloalkylene group Chemical group 0.000 description 7
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 7
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 6
- IYNWNKYVHCVUCJ-UHFFFAOYSA-N bismuth Chemical compound [Bi].[Bi] IYNWNKYVHCVUCJ-UHFFFAOYSA-N 0.000 description 6
- 229910052797 bismuth Inorganic materials 0.000 description 6
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 6
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- 125000006588 heterocycloalkylene group Chemical group 0.000 description 6
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
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- AYNNSCRYTDRFCP-UHFFFAOYSA-N triazene Chemical compound NN=N AYNNSCRYTDRFCP-UHFFFAOYSA-N 0.000 description 6
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 5
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/23—Azo-compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
- Plural Heterocyclic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
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| EP03396092 | 2003-10-01 |
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| TWI356071B true TWI356071B (en) | 2012-01-11 |
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| TW093129611A TWI356071B (en) | 2003-10-01 | 2004-09-30 | Flame retardant compositions |
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| EP (1) | EP1668073B1 (enExample) |
| JP (1) | JP4787160B2 (enExample) |
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| CN (1) | CN1860165B (enExample) |
| AT (1) | ATE430179T1 (enExample) |
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| BR (1) | BRPI0414992A (enExample) |
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| DE (1) | DE602004020903D1 (enExample) |
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| RU (1) | RU2372362C2 (enExample) |
| SG (1) | SG131932A1 (enExample) |
| TW (1) | TWI356071B (enExample) |
| WO (1) | WO2005030852A2 (enExample) |
| ZA (1) | ZA200601503B (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US8461272B2 (en) * | 2005-04-06 | 2013-06-11 | Basf Se | Azo compounds for polypropylene degradation |
| US20080179360A1 (en) * | 2006-10-23 | 2008-07-31 | Lowe Michael V | Top lock security holster ii |
| US8202449B2 (en) * | 2006-10-31 | 2012-06-19 | Icl Performance Products, Lp | Corrosion-inhibited ammonium polyphosphate fire retardant compositions |
| WO2008101845A1 (en) | 2007-02-21 | 2008-08-28 | Basf Se | Symmetric azo compounds in flame retardant compositions |
| KR20110138263A (ko) * | 2009-03-30 | 2011-12-26 | 바스프 에스이 | 중합성 조성물 |
| KR101786505B1 (ko) * | 2009-09-24 | 2017-10-18 | 준포르 쿤스트슈토프 게젤샤프트 엠.베.하. | 방염성의 발포성 중합체 |
| US20140094539A1 (en) * | 2010-12-20 | 2014-04-03 | Cantech Industrial Research Corporation | Fire resistant coatings |
| SK5976Y1 (sk) * | 2011-02-24 | 2011-12-05 | Moles Technology A S | Fireproof paint coat matter |
| EP2681266B1 (en) * | 2011-03-02 | 2016-11-02 | Huntsman International LLC | Flame retardant composition for thermoplastic polyurethane polymers |
| CN102532662A (zh) * | 2011-12-31 | 2012-07-04 | 潘雪峰 | 一种聚乙烯复合材料的制备方法 |
| BR112015014043B1 (pt) | 2012-12-27 | 2021-09-08 | Dow Global Technologies Llc | Processo para produzir uma membrana de poliolefina termoplástica para telhado |
| US9926491B2 (en) | 2013-02-06 | 2018-03-27 | X'aan Innovations Inc. | Ammonium polyphosphate based fire-retardant compositions |
| EP2871208A1 (en) | 2013-11-08 | 2015-05-13 | Carl-Eric Wilen | Sulfenamides, sulfinamides and sulfonamides as flame retardants |
| DE102014218811A1 (de) | 2014-09-18 | 2016-03-24 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von phosphorhaltigen organischen Oxyimiden als Flammschutzmittel, Radikalgeneratoren und/oder als Stabilisatoren für Kunststoffe, flammgeschützte Kunststoffzusammensetzung, Verfahren zu deren Herstellung sowie Formteile, Lacke und Beschichtungen |
| DE102014218810B3 (de) | 2014-09-18 | 2016-01-28 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von organischen Oxyimidsalzen als Flammschutzmittel, flammengeschützte Kunststoffzusammensetzung, Verfahren zur ihrer Herstellung sowie Formteil, Lack oder Beschichtung |
| WO2016208656A1 (ja) * | 2015-06-24 | 2016-12-29 | 株式会社フジクラ | 難燃性樹脂組成物、及び、これを用いたケーブル並びに光ファイバケーブル |
| CN105114612B (zh) * | 2015-09-18 | 2017-11-24 | 宁波明佳汽车内饰有限公司 | 换挡杆护套总成 |
| CN108003899A (zh) * | 2017-12-01 | 2018-05-08 | 宁波甬凌新材料科技有限公司 | 一种强度高的阻燃材料及其制备方法和应用 |
| CN109524162B (zh) * | 2018-11-23 | 2019-06-18 | 廊坊江海洋线缆有限公司 | 一种超高阻燃耐候性电缆 |
| FR3104593B1 (fr) * | 2019-12-12 | 2021-12-03 | Michelin & Cie | Système de réticulation et composition de caoutchouc diénique le comprenant |
| WO2021151493A1 (en) | 2020-01-30 | 2021-08-05 | Nordtreat Finland Oy | Flame retardant chemical compositions |
| CN112831117A (zh) * | 2021-02-26 | 2021-05-25 | 江西洪茂线缆有限公司 | 一种阻燃型交联聚乙烯电缆料及其制备方法 |
| CN117720769B (zh) * | 2024-02-07 | 2024-04-30 | 四川兴晶铧科技有限公司 | 一种复合阻燃增效剂以及一种阻燃尼龙材料 |
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| US3058926A (en) * | 1958-07-24 | 1962-10-16 | Dow Chemical Co | Method for making self-extinguishing alkenyl aromatic resin compositions comprising incorporating therein an organic bromine-containing compound and an organic peroxide |
| NL135462C (enExample) * | 1963-03-28 | |||
| US3269962A (en) * | 1963-04-01 | 1966-08-30 | Dow Chemical Co | Self-extinguishing polymer composition containing a halide and a hydrazone |
| US3296340A (en) * | 1963-04-01 | 1967-01-03 | Dow Chemical Co | Self-extinguishing alkenyl aromatic resins containing sulfenamides |
| US3271333A (en) * | 1963-03-28 | 1966-09-06 | Dow Chemical Co | Self-extinguishing alkenyl aromatic polymers |
| US3284544A (en) * | 1963-04-01 | 1966-11-08 | Dow Chemical Co | Self-extinguishing alkenyl aromatic resins containing organic polysulfide |
| NL127714C (enExample) * | 1965-04-01 | |||
| US3862107A (en) * | 1971-10-28 | 1975-01-21 | Pennwalt Corp | Method of curing polymers with azo compounds |
| US3897373A (en) * | 1973-04-21 | 1975-07-29 | Basf Ag | Self-extinguishing thermoplastic molding compositions |
| JPS5025651A (enExample) * | 1973-07-06 | 1975-03-18 | ||
| JPS5135504B2 (enExample) * | 1974-01-25 | 1976-10-02 | ||
| CH618563B (de) * | 1976-08-27 | 1900-01-01 | Ciba Geigy Ag | Verfahren zum flammfestmachen von mit kupfer-komplexazofarbstoffen gefaerbtem, cellulosehaltigem textilmaterial. |
| SU654649A1 (ru) * | 1976-09-01 | 1979-03-30 | Предприятие П/Я А-3324 | Негорюча волокнообразующа полимерна композици |
| US4115344A (en) * | 1977-07-05 | 1978-09-19 | Phillips Petroleum Company | Mold corrosion inhibition in poly(arylene) sulfide processing |
| SU908062A1 (ru) * | 1978-09-18 | 1983-06-07 | Центральный научно-исследовательский институт шерстяной промышленности | Кислотные бромбензолазокрасители дл крашени и одновременно огнезашитной отделки материалов из натуральных полиамидных волокон |
| DE2906336C3 (de) * | 1979-02-19 | 1982-01-07 | Chemische Werke Hüls AG, 4370 Marl | Feinteilige selbstverlöschende expandierbare Styrolpolymerisate |
| IT1185558B (it) * | 1985-04-30 | 1987-11-12 | Himont Inc | Composizioni polimeriche dotate di migliorate caratteristiche di resistenza alla fiamma |
| JPH0686556B2 (ja) * | 1986-08-27 | 1994-11-02 | 三菱電線工業株式会社 | 難燃性電気絶縁電線 |
| US5269963A (en) * | 1987-06-29 | 1993-12-14 | Idemitsu Kosan Co., Ltd. | Liquid-crystalline polymer composition |
| JP3409466B2 (ja) * | 1994-09-21 | 2003-05-26 | 住友電気工業株式会社 | ポリオレフィン組成物及びこれを被覆した絶縁電線 |
| JPH0995566A (ja) * | 1995-09-29 | 1997-04-08 | Yazaki Corp | ノンハロ難燃耐熱樹脂組成物 |
| JP3499175B2 (ja) * | 1999-11-05 | 2004-02-23 | 平岡織染株式会社 | 着色性に優れた実質的に無色のノンハロゲン難燃性ポリオレフィン系樹脂組成物積層シート |
| JP2001348481A (ja) * | 2000-06-09 | 2001-12-18 | Wacker Asahikasei Silicone Co Ltd | 耐熱性シリコーンゴム組成物及びその成形体 |
| JP2002322322A (ja) | 2001-02-27 | 2002-11-08 | Bromine Compounds Ltd | 難燃性ポリオレフィン組成物 |
| ITMI20012515A1 (it) | 2001-11-30 | 2003-05-30 | Enichem Spa | Polimeri vinilaomatici a migliorati comportamento al fuoco |
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2004
- 2004-09-22 CA CA2537157A patent/CA2537157C/en not_active Expired - Lifetime
- 2004-09-22 KR KR1020067006323A patent/KR101166752B1/ko not_active Expired - Fee Related
- 2004-09-22 EP EP04787189A patent/EP1668073B1/en not_active Expired - Lifetime
- 2004-09-22 WO PCT/EP2004/052271 patent/WO2005030852A2/en not_active Ceased
- 2004-09-22 DE DE602004020903T patent/DE602004020903D1/de not_active Expired - Lifetime
- 2004-09-22 JP JP2006530250A patent/JP4787160B2/ja not_active Expired - Lifetime
- 2004-09-22 AT AT04787189T patent/ATE430179T1/de not_active IP Right Cessation
- 2004-09-22 RU RU2006114397/04A patent/RU2372362C2/ru not_active IP Right Cessation
- 2004-09-22 AU AU2004276001A patent/AU2004276001B2/en not_active Ceased
- 2004-09-22 SG SG200702453-2A patent/SG131932A1/en unknown
- 2004-09-22 ES ES04787189T patent/ES2323176T3/es not_active Expired - Lifetime
- 2004-09-22 CN CN2004800286107A patent/CN1860165B/zh not_active Expired - Fee Related
- 2004-09-22 BR BRPI0414992-0A patent/BRPI0414992A/pt not_active IP Right Cessation
- 2004-09-22 US US10/573,850 patent/US20070029531A1/en not_active Abandoned
- 2004-09-30 TW TW093129611A patent/TWI356071B/zh not_active IP Right Cessation
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2006
- 2006-02-21 ZA ZA200601503A patent/ZA200601503B/en unknown
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- 2009-01-09 US US12/319,676 patent/US7691929B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007507571A (ja) | 2007-03-29 |
| CN1860165A (zh) | 2006-11-08 |
| AU2004276001A1 (en) | 2005-04-07 |
| AU2004276001B2 (en) | 2011-04-28 |
| ZA200601503B (en) | 2007-04-25 |
| ATE430179T1 (de) | 2009-05-15 |
| EP1668073B1 (en) | 2009-04-29 |
| CA2537157C (en) | 2014-03-25 |
| KR20060096479A (ko) | 2006-09-11 |
| CN1860165B (zh) | 2010-04-14 |
| CA2537157A1 (en) | 2005-04-07 |
| RU2006114397A (ru) | 2007-11-20 |
| SG131932A1 (en) | 2007-05-28 |
| TW200530313A (en) | 2005-09-16 |
| WO2005030852A3 (en) | 2005-11-03 |
| EP1668073A2 (en) | 2006-06-14 |
| US7691929B2 (en) | 2010-04-06 |
| KR101166752B1 (ko) | 2012-07-27 |
| JP4787160B2 (ja) | 2011-10-05 |
| BRPI0414992A (pt) | 2006-11-21 |
| ES2323176T3 (es) | 2009-07-08 |
| RU2372362C2 (ru) | 2009-11-10 |
| US20070029531A1 (en) | 2007-02-08 |
| WO2005030852A2 (en) | 2005-04-07 |
| DE602004020903D1 (de) | 2009-06-10 |
| US20090186970A1 (en) | 2009-07-23 |
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