TW467932B - Benzotriazole UV absorbers having enhanced durability - Google Patents

Abstract

Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings. A coating composition, stabilized with a benzotriazole, which benzotriazole exhibits enhanced durability and a low loss rate when incorporated in said coating, which composition comprises (a) a resin selected from the group consisting of a thermoset acrylic melamine resin, an acrylic urethane resin, an epoxy carboxy resin, a silane modified acrylic melamine, an acrylic resin with carbamate pendant groups crosslinked with melamine or an acrylic polyol resin crosslinked with melamine containing carbamate groups, and (b) 0.01 to 5% by weight, based on resin solids, of a benzotriazole of formula A' wherein G2 is fluoro, cyano, R3SO2-, CF3-, -COO-G3 or -CO-N(G3)2, G3 is alkyl of 1 to 12 carbon atoms, R1 is hydrogen, alkyl of 1 to 12 carbon atoms, phenyl, phenylalkyl of 7 to 15 carbon atoms, R2 is alkyl of 1 to 12 carbon atoms, phenyl, phenylalkyl of 7 to 15 carbon atoms or -CH2CH2COOG4 where G4 is hydrogen, alkyl of 1 to 12 carbon atoms, and R3 is alkyl of 1 to 18 carbon atom or phenyl; which benzotriazole exhibits enhanced durability and low loss rate values when the coating is exposed to actinic radiation as witnessed by a loss of less than 0.22 absorbance units after exposure for 1200 hours, or less than 0.27 absorbance units after 1500 hours exposure, or less than 0.40 absorbance units after 2500 hours exposure in a Xenon-Arc Weather-Ometer with the proviso that the benzotriazole is not (a) 5-n-dodecylsulfonyl-2-(2-hydroxy-3,5-di-tert.-butylphenyl)-2H-benzotriazole; (b) 5-n-dodecylsulfinyl-2-(2-hydroxy-3,5-di-tert.-butylphenyl)-2H-benzotriazole; (c) 5-benzenesulfonyl-2-(2-hydroxy-3,5-di-tert.-butylphenyl)-2H-benzotriazole;(d) 5,5'-sulfonylbis(2-(2-hydroxy-3,5-di-tert.-butylphenyl)-2H-benzotriazole; (e) 5-benzenesulfonyl-2-(2-hydroxy-3-tert.-butyl-5-(2-octyloxycarbonylethyl)-phenyl)-2H-benzotriazole; (g) 3-(5-benzenesulfonyl-2H-benzotriazol-2-yl)-5-tert.-butyl-4-hydroxyhydrocinnamic acid; (h) 3-(5-benzenesulfonyl-2H-benzotriazol-2-yl)-5-tert.-butyl-4-hydroxyhydrocinnamamide.

Description

67932 β; one ,. one ... 丨.-.- — .. — .— — V. Description of the invention () Benzotriazole UV absorber substituted with an electron attracting group in the benzo ring when it is added to Lycon There is increased durability and low loss rate during coating. For a long period of time, benzotriazole is an important UV absorber. Many industrial applications have obtained extensive, commercial value and acceptability. There are many references in previous techniques describing its manufacture and application. However • As the requirements for its specifications become more stringent, all need to continue to find more stable and durable benzotriazoles. Due to environmental considerations, solvents will be gradually abolished, such as dimethylbenzyl solvents, so KK non-HAP S solvents are replaced * like esters, ethers, ketones, and increased demand for the durability of automotive coatings The search for novel benzotriazoles is urgent. In fact, the automotive industry is most concerned about UVA loss in automotive coatings and coatings, as disclosed in J. L. Gerlock et al., Proc. 36th Annual Tech. Sym. (Clkeveland Coating Society), May 1 8, 1 9 9 3 ° V ys KO in o 1 Soedin, Ser _ A, 1 8 (3), 5 5 3 (1 9 7 6) describe the hydrogen bond strength and _ in the benzotriazole .. Sui_Ding .. Sexual line. Sexual dependency. Attachment. Department. —-&Quot;-I ---------- Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs L --.------. .I-/ · (Please read the Note: Please fill in this page again.) J. E. Pickett eta 1., Angew. Hakromo 1. Cheai. 2 3 2, 22 9 (1995) describe benzotriazole UV absorber in poly (methacrylic acid) Photodegradation. In general • Unless intramolecular hydrogen bonding, which is decisive for ear characterization, has been disturbed, structural variations will only cause slight differences in degradation rates. Pickett et al. Did not test any benzopyrene containing pull-electrons and electron-donating groups such as the present invention. Xiu.Jiangji.Yi-Hou et al. Came to a conclusion, that is, the stronger the hydrogen bond can produce more -3-this paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 4 Ministry of Economic Affairs 6 7 9 3 2 A7 B7 printed by Bureau Shelley Consumer Cooperative V. Description of the invention () Stable benzotriazole, but did not reveal how this was achieved. The present invention reveals the existence of benzotrimile which has improved durability, but it is surprising that this improves Jtl durability-it has nothing to do with the stronger Argon. In fact, these compounds with enhanced durability often have (not as strong as Ji) ..... articles. gmiQϋ 4, 2 2 6,7 6 3; 4,2 7 8,5 8 9; 4,3 1 5,8 4 8; 4,275,004; 4,347,180; 5,554,760; 5,563,242; 5, 5 74,1 6 6 and 5, 60 7, 98 7 describes the selective benzotriazole, which is substituted by α-cumyl at the third position on the hydroxyphenyl ring, and it shows very good adhesion when applied to automotive coatings. Permanent. Some benzotriazoles represent the state of the art. The present invention relates to a benzotriazole prepared from a benzotriazole of the prior art which has better durability and lower loss rate. U.S. Pat. Sulfonium or phenylsulfonium. These benzotriazoles are transferred in red for optical reasons. A pull electron group group substituted at the 5 position, as found in the present invention, also provides the additional advantages of low loss rate and durability. The present invention relates to a benzotriazole U V absorbent having improved tritium properties, durability, and low loss rate when added to automotive coatings. More specifically, the present invention relates to a benzotriazole-stabilized coating composition. When these benzotriazoles are added to the coating, there is improved durability and a low loss rate. The composition includes: (a) — A resin selected from the following groups: Thermosetting melamine acrylate-4- This paper is compliant with Chinese National Standard (CNS) A4 specifications (210X 297 mm) (Please read the precautions on the back before filling this page)

467932 A7 B7 V. Description of the invention () Resin * propyl carbamate: acid. Ethyl ester resin, epoxy carboxyl resin, silamidine _ insect. _. Quality acrylic melamine, with urethane side chain and Amine crosslinked acrylic resin, or acrylic polyol resin crosslinked with urethane group melamine, and (b) 0 * 01 to 5% by weight (calculated based on resin solid content) Formula A, B , C or benzotriazole: {Please read the notes on the back before filling out this page) Printed by the Employees' Cooperative of the Central Government Bureau of the Ministry of Economic Affairs

1 5-This paper size applies to China National Standard (CNS) A4 (210X 297 mm) 467932 A7 B7 5. Description of the invention ()

(D ^ I ^^^^ 1-----1 II t ^ \, i (please read the notes on the back before writing this page) Yes, basic CT element nitrate, or halogen * 3 2 or The prime GG hydrogen is a tooth °, yes, it is 0Ή ~ 1 1 2 C, its GGG ί base should be reversed " 'wing pull one: ο ο S (3 PRI radical * gas 3

2ο S 3 R S Η βc Order

3 G Iο C

3 G 一 Η Ν Iο C

3 G / | \ Ν Iο C 2 3 G / IV Ν

G 1ο C Central Standards Bureau of the Ministry of Economy—Printed by Industrial and Consumer Cooperatives

Or Ν〇

G0 groups, alkyl groups of 1 benzene chain, branched 5 group containing, alkyl or alkene chain of straight benzene chain, mycogen containing carbon or chain 5 4 straight 1 2 of, To Zhi 7 * -II, the hydrocarbon alkane is 8 ring 3 1 G to Zi 2 original, the carbon paper size is applicable to the Chinese National Standard (CNS) A # specifications (21 0X 297 mm) A7 B7 467932 5 Description of the invention () or the phenyl or the phenylalkyl group on the phenyl ring is substituted by an alkyl group of 4H and 1 to 4 carbon atoms * is hydrogen: 'a straight chain containing 1 to 24 carbon atoms or containing Branched alkyl, straight or branched alkenyl with 2 to 18 carbon atoms, cycloalkyl with 5 to 12 carbon atoms, benzoyl group with 7 to 15 carbon atoms, phenyl , Or radical or the ^: radical on the polycyclic ring is replaced by 1 to 4 alkyl groups containing 1 to 4 carbon atoms, R2 is hydrogen '1 to 24 ½ carbon atoms straight or branched Alkyl chain, straight or branched alkenyl group of 2 to 18 carbon atoms, cycloalkyl group of 5 to 12 carbon atoms, phenylalkyl group of 7 to 15 carbon atoms , Or the phenyl or the benzyl alkyl is 1 on the phenyl ring 3) substituted by an alkyl group containing 1 to 4 carbon atoms, or R2 is a hydroxyl group or 10r4, where R4 is a straight or branched alkyl group of 1 to 2.4 carbon atoms; or the alkyl group Group is substituted via one or more -〇H * -〇 CO-Rii, -〇R 4 *-NCO or -NH2 group or a mixture thereof; or the alkyl or the alkenyl group is substituted by one or more 10 —, — NH— or —NR4 — group bases or their mixtures can be interrupted and can be unsubstituted, or by —.1 virtual — poly —.xia-QH, 10R4 or —NH2 group bases or Its mixture is substituted; or R2 is an SR3, '-NHR3 or -N (R 3) 2; or only 2 is ~ (C Η 2) m — C 0 — X — (2) p — Y — Ri 5 Where X is a Q —or -N (Ri 6) — * -7- This paper size is applicable to Chinese National Standard (CNS) A4 (2! 0X 297). (Please read the notes on the back before filling in this page)

* 1T Printed by A7 467932 B7 of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (Y) — 0 — or One N (Ri7) —, (Please read the notes on the back before filling this page) Z is C2 -C: 2 alkylene, C4 — Ci 2 alkylene interrupted by one to three nitrogen atoms, oxygen atoms or mixtures thereof, or C3-Ci 2 alkylene, butylene, butyne and cyclohexyl Or phenylene each is substituted via a hydroxyl group, m is 0, 1 or 2, p is 1 or when X and Y are -N (R16) _ and -N (Ri7), p is 0,

Ri5 is a group of CO — C (R 1 8) = C (H) Ri9 group, or when Y is a N (R! 7) group, together with Ri 7 —C0—CH = CH_C0 — group Group, where Ri 8 is hydrogen or methyl, and Ri 9 is hydrogen, methyl, or CO — X — R 2 O group, where Rz 0 is hydrogen, Ci — Ci 2 垸 group, or a group group of the formula

0H

Printed by the Central Bureau of Standards of the Ministry of Economic Affairs, Tiberium Consumer Cooperative, where the symbols Ri-R 3, X, Z, m, and p are as defined above, and R16 and Rl7 are unrelated to each other. Nitrogen * Cl — Cl 2 — Alkyl * C3 —Ci 2 —alkyl, which is fluorinated by 1 to 3 oxygen atoms, or cyclohexyl or C7 — Cl S arylene, and Ri s and Ri 7 are at -8- This paper size applies China National Standard (CNS) A4 specification (2 丨 OX297 mm) 4 S 7 9 3 2 A7 B7 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and Consumer Product Cooperatives V. Invention Description () Z can also be used in the case of ethylene Ethylene group formation · η is 1 or 2, when η is 1 * Rs is C1, 0RS or NR7R3, or R5 is a POiORizJz'—OSi or -0 C 0-RII * or straight or branched Ci —C24 alkyl (which is interrupted by a 10—, an S— or a NRt 1 and can be unsubstituted or substituted via a 0H or a 0C0—ί) * CS -Ci 2 ring Alkyl (which is unsubstituted or substituted with -0Η), straight or branched C2-Ci 8 alkenyl (which is unsubstituted or substituted with -0H), C7_Ci 5 arane Base, -CHz-CHOH-Ri 3 • or ring Propyl, R6 is hydrogen, straight or branched Ci_C2 4 alkyl (which is unsubstituted or substituted by one or more oH, OR4 or NH2 group), or -0RS is One (OCH2CH2) wOH. Or one (0 C Η 2 C Η 2) w 0 R 2 1, where w is 1 to 12, R 2 i is an alkyl group of 1 to 12 2 carbon atoms, R 7 and R 8 are not related to each other Are hydrogen · alkyl groups of 1 to 18 carbon atoms, straight or branched C3 —Ci s alkyl groups * which are interrupted by —0 — * one S — or one NR, i — , CS 2 cycloalkyl • Cs 4 aryl or Ci —C3 hydroxyalkyl, or R7 and Rs — together with the N atom is a pyrrolidine, perine, piperazine or morpholine ring * When η is 2, Rs is One divalent reactive group 0-Rs — 0 — or —N (R 1 1) —Ri〇 — N (R 1 1) —, -9- (Please read the notes on the back before filling this page) This paper The standard is applicable to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 4 6 7 93 2 A7 B7 V. Description of the invention () R3 is C2-C8 alkylene, C4-C3 alkylene, C4 acetylene, cyclohexyl, C4-Ci, straight or branched. Alkylene (which is interrupted by (Please read the notes on the back before filling this page) or by a CH2 — CHOH — CH2 — 〇 — Ri 4 — 0 — CH2CHOH — CH2-)

Ri 〇 is linear or branched-Ci 2 alkylene (which can be interrupted by 0-), cyclohexyl,

Or Ri 〇 and Ri 1 and two gas atoms form a fluorene ring,

Ri + is a straight chain or branched C2 — Cs chain support, printed on a straight chain or including a consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs-chain support butane

0 _C3 ·-· ....... ο 的 中 中 所 I ο I by its / IV support paper size of this paper applies Chinese National Standard (CNS) Α4 specification (21〇 × 297 mm) 4 6 7 93 2 a? B7 Printed by the Male Workers' Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs 51 5. Description of the invention (or

Among them, R7 and R8 are different from each other, respectively, hydrogen, an alkyl group of 1 to 18 carbon atoms, or R7 and Ra — an alkylene group of 4 to S carbon atoms, 3 — oxapentane, 3 —Imine pentamethyl or 3-methylimino pentamethyl, R 1 1 is C i 2 ring C 1 4 aryl R 1 z is a bond C 3 CI 6 ^ R 1 3 is -P 0 ( Or from 0-C Η 2 hydrogen, straight or branched Ci-Ci 8 alkyl, C5-alkyl, straight or branched C3-C8 alkenyl, C6- — or C7 — Ci 5 Aralkyl, straight chain or branched fluorinated C i -Cl s alkyl, straight chain or branched -Ci a alkenyl, Cs-Ci cycloalkyl, Cs-or C7-cis aralkyl, Η · Straight or branched (: ^-Ct 8 alkyl (which is substituted by OR: 2) 2), phenyl (which is substituted by unsubstituted Η), 〇7_ 匸 15 aromatic Alkyl, or 0 R 1 2 * R3 is an alkyl group of 1 to 20 carbon atoms, a hydroxyl group of 2 to 20 carbon atoms, an alkenyl group of 3 to 18 carbon atoms * 5 to 12 carbon atoms Cycloalkyl, phenylalkyl with 7 to 15 carbon atoms, aryl with 6 to 10 carbon atoms or the aryl group is selected from a second alkyl group with 1 to 4 carbon atoms Paper Standards are applicable to China National Standards (CNS) M specifications (210 X 2 mm) (Please read the notes on the back before filling out this page) 4 β 7 93 2 Α7 Β7 V. Description of the invention (for generation, or 1 1,1,2,2-tetraargon perfluorinated alkyl, wherein the perfluorinated alkyl is 6 to 16 carbon atoms * L is an alkylene of 1 to 12 carbon atoms, 2 to 12 carbon atoms Fork, knot fork, P-xylene or naphthene fork, and T is a S0—, a S02_, a SO — E — S〇1, —S 〇2 — E — S 0 2 —, One C0, one, _Cq_E-CO->-COO-E-OCO " ^ —CQ-NG3 — E-NG3 — CO — or —NG3 —-CO — E — CO — NG3 f where E is 2 to 1 2 carbon atoms of alkylene, 5 to 12 carbon atoms of cycloalkylene, or 8 to 12 carbon atoms of cyclohexane to be interrupted or terminated (please read the precautions on the back before filling this page) The alkylenes printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs when the coatings are resistant to Oaet er are lost or exposed to light longevity and bottom loss at a 250% better cladding-1 2 0 0 exposure Over 1 500 hours of exposure, composition b In the case of chemical radiation, the presence of this benzotriazole is, for example, less than O '. 2 2 absorption after 1 Xenon-Arc Weather- hour. ......- less than 0 · 27 absorption Qin bit after 'or less than 0 · 40 absorption units after hour. ) Is a compound of formula A ':

OH

Ri (A,) r2 -12- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm ') Order 467932 A 7 B7_______ 5. Description of the invention () Among them: (Please read the notes on the back before filling in (This page) G2 is fluorine, gas * cyanide, R3 S 0 2 — 1 c F 3 —, -C 0-G 3, one C0 0- G3 or-C〇-N (G 3) Z G3 is one to 1 An alkyl group of 12 carbon atoms,

Ri is hydrogen, an alkyl group of 1 to 12 carbon atoms, phenyl * 7 to 15 carbon atoms of phenylalkyl * or the phenyl group or the phenylalkyl group contains 1 or 2 on the phenyl ring An alkyl group of 1 to 4 carbon atoms is substituted by an alkyl group of 1 to 12 carbon atoms, a phenyl group, a phenyl alkyl group of 7 to 15 carbon atoms > or (:! 12 < 31 ^ 2 〇00〇4, where G4 is hydrogen, an alkyl group of 1 to 24 carbon atoms, or the alkyl group is substituted by 0H, interrupted by one to six one 0-atoms, or substituted by 0Η and one to six -0-interrupted by an atom, and R3 is an alkyl group of 1 to 18 carbon atoms * an aryl group of 6 to 10 carbon atoms, or the aryl group is composed of one or two alkyl groups containing 1 to 4 carbon atoms Superseded by. Optimally * in the compound of formula A '* printed by the Central Bureau of Standards of the Ministry of Economic Affairs and Consumer Cooperatives G 2' CM? * S〇2-> CF3-> -C0 0- G3 or- CO-N (G 3) 2, G3 is an alkyl group of 1 to 8 carbon atoms,

Ri is hydrogen, phenyl or α-cumyl,

Rz is an alkyl or phenyl group of 4 to 12 carbon atoms, and R3 is a phenyl or alkyl group of 8 to 12 carbon atoms. -13- This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 7 93 2 A7 B7 Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives i 'Invention Description () Particularly good formula A' compounds Where G2 is phenyl-S02-2 octyl-S02-'fluoro or CF3-, Ri is 0-cumyl or phenyl, and R2 is s-butyl or tert-octyl. Preferably, the resin is a thermosetting acrylic melamine resin or a propanoic acid ethyl formate resin. Examples of these various reactive groups are as follows: When R 1 to R 2 i are alkyl groups, examples of these group groups are methyl, ethyl, isopropyl * n-butyl, isobutyl, Sec-butyl, tert-butyl * tert-pentyl, 2-ethylhexyl, tert-octyl, lauryl, tert- (dodecyl), tridecyl, n-hexadecyl, N-octadecyl and fluorenyl; when any reactive group is alkenyl, examples of these groups are allyl or oleyl; when any reactive group is cycloalkyl, these groups are Examples are cyclopentyl, cyclohexyl, cycloheptyl • cyclooctyl, and cyclododecyl; when any reactive group is phenylalkyl, examples of these groups are fluorene, phenethyl * 0C — Methylbenzyl and 0:, 0 [-dimethylbenzyl; and when a reactive group is aryl, examples of these groups are phenyl, naphthyl, or when it is substituted with alkyl, Examples are tolyl and xylyl. When Rs is replaced by one or more groups of 0 groups, and / or a group of groups replaced by one or more groups, the group of ~ 6R6 becomes, for example,-(0 C Η 2 C Η 2) w〇H or-(0 C Η 2 C Η 2) w 〇R 2 1, where w is 1 to 12, and Rz: is an alkyl group of 1 to 12 carbon atoms. -14- The size of this paper is applicable to China National Supervision (CNS) A4 specification (21 0X 297 mm) I .--, ---, —— rr " —I (Please read the notes on the back before filling in this Page) Order 6 4; 7932 A7 _______B7_____ 5. Explanation of the invention () When E is alkylene, examples are ethylene, tetramethylene, hexamethylene, 2_methyl-1, 4 one tetramethylene, hexamethylene, eight Methane, Decamethyl, and Dodecyl; when E is cycloalkane, examples are cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, and cyclododecane; and when E is cyclopentadiene When hexylene is interrupted or terminated by alkylene, an example is derived from disadiene, herein (referred to as dihydrofluorenediyl) saturated diyl reactive group. Other preferred embodiments of the present invention are compounds of formula III, wherein Ri is tert-butyl, η is; l, R3 is phenyl * and R5 is -0 R β, where Rs is ~ linear or substituted octyl . Yet another preferred embodiment of the present invention is a compound of formula C, wherein η is 2, Ri is tert-butyl '3? Is phenyl * and is 0-Rs-' wherein R 9 is from 0-or -CHz -CHOH-CH2 -O-Ri 4 -o-CHz -CHOH-CH2-Interrupted C2-C2 4 alkylene. When E is alkylene, examples are ethylene, tetramethylene * hexamethylene, 2-methyl-1,4-tetramethylene, hexamethylene, octamethyl, tenmethyl, and twelve central standards of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperative (please read the notes on the back before filling out this page) Methane; when E is naphthenic, examples are cyclopentyl, cyclohexyl, cycloheptyl, and cyclotenyl Dialkylene; and when E is an alkylene interrupted or terminated by cyclohexylene, examples are derived from fluorenediene, herein (known as dihydrothadiene diyl) saturated diyl reactive group . When the compound of the present invention contains a free carboxylic acid group (where Rz is -CHz CHz COO Re and R6 is hydrogen), the alkali metal sulfonium or amine salt of the acid is also a part of the present invention. Raise -15- This paper standard is applicable to China's national standard < CNS) A4 size (210X297 mm) 4 6 7 93 2 A7 B7 V. Description of the invention () Water dissolution printed by the Central Standards Bureau, Ministry of Economic Affairs and Consumer Cooperatives R 6, R 7 and R 8 can be used in aqueous solution systems. 0 R 6, R 7 and R 8 can be interrupted by — 0 — f — S — i or — NR 1 1 — and C 3 —CI 8 can be replaced by 0 Η. Oxyethyl ί ethoxyethyl 1 butoxyethyl t butoxypropyl > formamidinethioethyl C Η 3 0 C Η 2 C Η 2 0 C Η Zn C Η 2 — »C Η 3 C Η Z 〇C Η ζ C Η 2 0 C Η 2 C Η Zn — 1 C 4 Η 9 0 C Η 2 C Η 2 0 C Η ζ C Η ζ — * Ethylthiopropyl, octylthiopropyl F dodecyloxypropyl t 2 monohydroxyZyl »2 — hydroxypropyl» 4 — hydroxy Butyl * 6 —hydroxyhexyl * — C Η ZC Η ζ — Ν Η — c 4 Η 9 ψ — C Η 2 C Η 2 C Η 2 N Η — C 8 Η 1 7 and '— C Η ZC Η 2 C Η ZZ — Ν (C Η 3) — C Η 2 C Η (C Ζ Η) C 4 Η si R 6 t R 7 R 8, R i 1 and R 1 Zn can be C 5 — C 1 ζ- pm Cycloalkyl reactive group: cyclopentyl 9 cyclohexyl, cycloheptyl cyclooctyl or cyclodecyl 0 In the case of R 6, the reactive group can also be substituted through — 0 Η 0 R 7 t R 8 And RX 1 can be the following alkenyl fluorenyl groups «• allyl 9 methallyl ψ 2-n-hexenyl or 4-n-octenyl 0 when R 6 is alkenyl 1 Has the phase and when R 7 »R 8 and R 1 1 are the definition of alkenyl reactive group 9 but it can also be — C Η = C Η ζ 9 positive ten — — 1 0 — alkenyl or positive — eighteen one 9 -alkenyl 4 reactive group R 6 may also be taken via — 0 Η 0 -16- (Please read the precautions on the back before filling out this page) This paper size applies Chinese National Standard (CNS) A4 specification (21 × 297 mm) A7 467932 B7 V. Description of invention () R7 and R8 It can be the following C7 ~ Ci 5 aralkyl reactive group: τ group, ot —phenethyl * 2 —cyl ethyl or 4-monobutylfluorenyl. (Please read the notes on the back before filling this page.) When Ri i, Ri 3 or only: 2 is aralkyl, it may be irrelevant to have the same definition as R 7 or R 3, respectively. R 7 * Rs and Ri 1 are independent of each other and are Ce—

Ci 4 aryl reactive group: phenyl ' α-Czeki or / 3-naphthyl. When R7 and R8 are 0: _Cs hydroxyalkyl, they can be the following reactive groups: hydroxymethyl, 2-hydroxyethyl or 2-hydroxypropyl.

When Rg 4 is C2-c8 alkylene, it can be the following reactive group: ethylene, propylene, butyl, hexamethylene or octyl. When R i 0 is an alkylene group, it can be the same reactive group. In addition, it can also be a polymer group 1 such as decyl or dodecyl. When R3 is a c4-C8 olefinic reactive group * The following is a suitable example: butylene. In R9 and! ^ In the case of 4, a suitable straight chain or a branched C4-Ci 0 support group with:-CHa CH2 OCH2 CH2-* Employee Consumer Cooperatives, China Standards Bureau, Ministry of Economic Affairs, India-CH (C Η 3)-C Η z-Ο-C Η 2-CH (C Η 3)-CH2 CH2 〇CHz CH2 0CH2 CH2-, and -CH2 CH z OCHz CHZ OCHz CHz OCHz CH 2-° When Ri 4 is In the case of a cycloalkylene reactive group, the following group groups are included: 1'3-cyclohexylene and 1,4-cyclohexylene. -17- This paper is again applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 467932 B7 V. Description of the invention () When ^^ 4 is arylene, it can especially be the following group base: 1 | 3 a stupid or 1,4 a phenylene. LI r--L-Hr-1-1---i I--.1 I (Please read the notes on the back before filling this page) Z is Cz — C i 2 alkylene, it is straight chain Or branched, such as ethylene, propane, tetramethyl, hexamethyl, octadecane, ten methyl, twelve methyl, 1, 1, ethyl fork, 2, 2-propane, 2, 2, —Pentanyl or 2-ethylhexamethylene. C2_CS-alkylene is preferred. When Z is C4 _Ci 2 —alkylene interrupted by oxygen * Examples are: CH2 _CH2 ~ * 0_CH2 CHz —, -CHz CHz OCH2 CHz CHz, CH2 CHz-o- ch2 CH2-o- ch2 CH2 or- CH 2 CHz-Ο- CHz CHz-Ο- CHz CHz _0 — CH2 CH2 —, and when alkylene is interrupted by nitrogen, that is -N (R 1 6)-(where Ri 6 is as defined above) ) * Examples are: -CHz CHz-NH-CHz CHz CH2 CHz--CHz CH 2 CHz-NH-(CH 2) a —or -CHz CHz CHz — N (CH 3 CHz CH-Central Bureau of Standards, Ministry of Health Printed by (C 2 H 5) (CH2) 4_ .. Z is a C3-Ci 2 alkylene substituted with a hydroxyl group, examples are 2-methylmethylene, 2-hydroxyhexamethylene, especially 2 — Hydroxytrimethylene. When Z is cyclohexyl, examples are 1, 4-cyclohexyl *, especially 1 2-cyclohexyl. When Z is phenylene, examples are m-phenylene or p-phenylene. -18 -The scale of this paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 4 6 7 93 2 A7 B7 V. Description of the invention () m energy can be 0, 1 or 2, but the preferred is 2. P is better Is 1 but if X and Y are bound by nitrogen, it can also be 0. 〇 feet: is 匚!-C8 alkyl, examples are: methyl, ethyl, n-propyl * isopropyl, n-butyl, sec-butyl, tert-butyl, n-pentyl, Tert-pentyl, n-hexyl, n-heptyl, n-octyl, 2-ethylhexyl or tert-octyl. Tert-butyl is preferred. R i 6 * Ri 7 and Rz 0 are Ci -Ci 2-Yuan has the same definition as R 1 above * and can additionally be a straight or branched nonyl, decyl, undecyl, or dodecyl. When Ri 6 and Ri 7 are In the case of an alkyl group interrupted by an oxygen atom, applicable examples are those applicable to the aforementioned definition of Z.

Examples of Ris 7 as arylfluorenyl are benzyl, α-methylbenzyl, 1-phenylethyl. A, a-dimethylbenzyl or 1-phenylpropyl. Let Z be ethylene Ri 6 and Ri 7 can similarly form an ethylene together, which is equivalent to the bridge base of Oh. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs when Y is a form N (Rl7) — group base, Rl5 and 7 — start as a form CO-CH = CH — C0 — and on a form X (Z) p Formation of a substituent: 〇

Ο (Please read the notes on the back before filling this page)

-—— N -1 9- This paper size applies to Chinese National Standard (CNS) A4 specification (2! OX297 mm) β 4 7 93 2 V. Description of invention (A7 B7

I I, I I I or I V However, Ri s is better defined as C0-C (R 1 8) = C H R 1 4 and R19 is preferably methyl, especially hydrogen. R2 is -CHz-C Η 2 — CO-O — C (G) = C H 2 and G is hydrogen or methyl. The invention also relates to a novel benzotriazole of formula I (please read the notes on the back before filling this page)

0H

^ 2 (0-丁 -a Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

OH

N-

OH

20- (II) (ΙΠ) -E5 The paper size is applicable to Chinese National Standard (CNS) A4 specification (210 × 2Mmm) 6 4) 7 93 2 A7 B7 V. Description of the invention (--Γ

N-

(IV) g2 (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs where G i is hydrogen or halogen, G2 is cyano, E3 S〇-'E3 S〇2_ , -C00G3 > CF 3 " ", — P (0) (C β Η 5) ζ '— C Ο — G 3, —C〇—NH — G3 or * ~ C〇_NCG 3) 2,

Gs is a straight or branched alkyl group of 1 to 24 carbon atoms, a straight or branched alkenyl group of 2 to 18 carbon atoms, a cycloalkyl group of 5 to 12 carbon atoms, 7 Phenylalkyl, phenyl, or phenyl or phenylalkyl of 1 to 15 carbon atoms are substituted on the phenyl ring by 1 to 4 alkyl groups containing 1 to 4 carbon atoms, E i is hydrogen, a phenylalkyl group of 7 to 15 carbon atoms, a phenyl group, or the phenyl ring or the phenyl ring of the phenylalkyl group is 1 to 4 alkyl groups containing 1 to 4 carbon atoms Replaced by

Ez is a linear or branched alkyl group of 1 to 24 carbon atoms, 2 -2 1- This paper size applies Chinese National Standard (CNS) A4 specification (2 丨 0X297 mm) 7932 λτ ____ Β7_ V. Invention Explanation () (Please read the notes on the back before filling out this page) Straight chain or branched fluorenyl group with 18 carbon atoms, 5 to 12 fluorene alkyl group with 7 to 15 carbon atoms, 7 to 15 Carbon atom of phenylalkyl, phenyl, or the phenyl or phenylalkyl is substituted on the phenyl ring by 1 to 3 alkyl groups containing 1 to 4 carbon atoms, or E2 is hydroxyl Or -OE4, where E4 is a straight or branched alkyl group of 1 to 24 carbon atoms; or the alkyl group is passed through one or more -0H, -0C0-Ei! *-〇E4, -NCO Or-the group or a mixture thereof is substituted; or the alkyl or the alkenyl group is interrupted by one or more 10-, -NH- or -NE4 groups or a mixture thereof and can be unsubstituted , Or substituted by one or more 涸 —OH, one 0E4, or —NHa group or a mixture thereof; or E2 is one SE3, —NHE3 or one N (Es) 2: or E 2 is— (C Η 2 ) m-C 0 ~ X- (Z) p-Y-E ts where X is a 0-or a N (Eis) Y is a 0 — or a N (Ei7) printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economy Z is C2 — Ci 2 alkane C4-Ci 2 alkylene interrupted by one to three nitrogen atoms' oxygen atoms or mixtures thereof, or C3-Ci 2 alkylene, butylene, butyne, cyclohexylene or phenylene, each One is substituted through a hydroxyl group | m is 0, 1, or 2, p is 1, or when X and Y are N (Eii5) _ and -N (El7), p is ◦, -22- This paper applies to the standard China National Standards (CNS) Λ4 Lige (2 [〇Χ 297mm) 487932 A 7 B7 V. Description of the invention () ι 5 is a form of CO- C (E ia) = C (H) Ev9 group (read Read the notes on the back before filling this page), or when Y is a N (Ei 7) —, together with E 7 form a CO — CH = CH — CO — group group, where Ei 8 is hydrogen or Methyl, and Ei 9 are hydrogen, methyl or a CO-X-E2o group, where Ez0 is hydrogen, Ci-Ci2 alkyl, or a group of the formula

0H

Where the symbols Ei, G2, X, Z, m and p are as defined above, and E: s and E 7 are unrelated to each other hydrogen — — Ci 2 — alkyl, represented by 1 to 3 oxygen atoms Interrupted C3 —Ci 2 —alkyl, or cyclohexyl or C7 —Ci 5 aralkyl * and El s and £ 1 7 can also form ethylene when Z is ethylene, η is 1 or 2 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs when η is 1, Es is Cl, 0E6 or Ν7 Es * or E5 is a P0 (0Ei2) 2, 10Si or -0 C 0-E 1 1, or Is a straight or branched Ci—C2 4 垸 group (which is interrupted by —0—, —S — or —NEi, and can be unsubstituted or replaced by —0H or OCO-Ei: ), CS — Ci z cycloalkyl (which is unsubstituted or taken from a 0H -2 3-This paper size applies to Chinese National Standard (CNS) A4 specifications (2I0X297 mm) 417932 A7 B7 (Please read first Note on the back, please fill out this page again} Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (of the generation), straight or branched c generation or replaced by 10）) Η 2-C Η Ο Η- Ε 1 Ε6 is hydrogen, linear or branched, or substituted by one or more 0's, or an OEs is one (0-(0 C Η 2 C Η 2) w 0 E2 1 is 1 to Twelve carbon atoms E7 and E8 are independent of each other, straight or branched C3 — one S — or one NEi 1 — where C6 — Ci 4 aryl or Ci E8 — and the N atom are Pyrrolidine When η is 2, 1 Es is mono or -N (E 1 1)-E 1 〇E 3 is C z-C 8 alkylene, cyclohexyl, straight chain or branched chain-◦-or One CHz — CH 0-CHe CH0H-CH E i. It is a straight chain or branched chain interrupted by a cyclohexyl, Z-CIS alkenyl (which is not taken C 7-C 1 5 aralkyl »3, or glycidyl 9 C 1-C 2 4 alkyl (which is C Η 2 C Η Z without substitution by Η 9 0 Ε 4 or N Η ZE group) W 〇Η > or Ε Ζ 1 y where W is 1 to 1 2 > alkyl * is hydrogen »alkane of 1 to 18 carbon atoms C 1 8 is radical f which is interrupted by — 0 — r) JC 5-C 1 2 Yiui ring Alkyl — C 3 hydroxyfluorenyl I or E 7 and 1 pyridine »Piperazine Morpholine ring 9 divalent reactive group — 0 — Ε 3 '~ h 0 — — Ν (E 1 I) — t 9 C 4 — C 8 alkenyl t C 4 alkynyl C 4 — C 1 〇 It is interrupted by 0 Η — C Η 2 — 〇—Ε 1 4 — 2 —)) C ZO-C 1 Z alkylene (which can be 2 4-this paper size applies Chinese National Standard (CNS) A4 specifications ( 210 X 297 mm) 467932 A7 B7 V. Description of the invention (

{V

or

C Η E or

E Contains or .chain straight cycloidazinane # 8 a C into I form Z subc original nitrogen chain branches and two or and 1 chain 1 straight Ε is and 4 chain branched branch

ο] —.— 1 o I C's interruption-ο- is its -rfv butane ring

Jr ----------- (Please read the notes on the back before filling out this page) OR OR Printed by Zhengong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs

C1- ° ~ —C Substituted formazan, pentacarbonyl alkylamine 8 subunit 1 to protoformanyl 1 carbon 1, 3 hydrogen 6 or 4 to 5 min. Amine phase 8 sub-E I mutual 3 87 · E Eif and or 7, 7 alkoxy in penta-E-based one of this paper size applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) A7 467932 _ __B7___ V. Description of the invention () Support,

Ei i is hydrogen, straight or branched Cl-Ci 8 alkyl, cs — (Please read the notes on the back before filling this page)

Cl 2 cycloalkyl, straight or branched C3-Cs alkenyl, Cs —

Cl 4 aryl or C7 — Cl 5 aryl, E, 2 is a straight or branched Ci — Ci 3 alkyl group, straight or branched C 3-Ci 8 alkyl group ~ ~ Ci Base 'Cs —

Ci 6 aryl or C7 — Ci s aryl

El 3 is fluorene, straight or branched ^^ — Ci 3 fluorene (which is substituted by ~ P 0 (OR: 2) 2), phenyl fluorene (which is unsubstituted or substituted by 0H (Substituted) 'C7 — Ci S aralkyl, or ~ C Η 2 〇Ε 1 2, Ε3 is an alkyl group of 1 to 20 carbon atoms, hydroxyalkyl group of 2 to 20 carbon atoms * 3 to 1 8 carbon Atomic alkenyl, cycloalkyl of 5 to 12 carbon atoms * phenylalkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon atoms or the aryl group consists of one to two Substituted by an alkyl group of 1 to 4 carbon atoms, or 1,1,2,2,2-tetrahydroperfluorinated alkyl group, wherein the perfluorinated alkyl group is 6 to 16 carbon atoms. The Bureau ’s consumer cooperative printed L is an alkylene of 1 to 12 carbon atoms, an alkylidene * benzyl fork of 2 to 12 carbon atoms, ρ—xylene or naphthene, and Γ is a S0 — , One S〇2 —, one SO — Ε — so —, — S 0 2 _E — SO2-1 — CO — * -C0-E-CO —,-COO — E-0C0-, or one CO — NG5- E— NGs-CO — * -26- This paper size applies to Shen Guo National Standards China (CNS) A4 specification (21〇297 mm) ) 6 A7 B7 5. Description of the invention () where E is an alkane of 2 to 12 carbon atoms * 5 to 12 carbon atoms of cycloalkane, or interrupted by 8 to 12 carbon atoms of cyclohexane Or terminal alkylene, Gs is G3 or hydrogen, and it is limited to when G2 is E3 SO— or E3 S02, EiF is phenylalkyl. Preferably, the novel benzotriazole is a compound of formula I ^:

0H

, Ε, (〇 (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs: G2 is nitrogen-based, -Ε2 S〇 £ _, CF3 —, one C00 — G3 — C0-NHG3 or one Co-N (G3) 2, G3 is an alkyl group of 1 to 12 carbon atoms, E t is hydrogen, phenyl alkyl group of 7 to 15 carbon atoms, or the Phenyl or the phenylalkyl group is substituted on the phenyl ring by one or two alkyl groups having 1 to 4 carbon atoms | Ez is an alkyl group of 1 to 12 carbon atoms * phenyl> 7 Phenylalkyl to 15 carbon atoms or one CHZ CHz C00G4, where G + -27- This paper size applies to Chinese National Standard (CNS) A4 specifications (2 丨 OX297 mm), A7 467932 — B7 V. Description of the Invention () (Please read the notes on the back before filling out this page} Is hydrogen, an alkyl group of 1 to 24 carbon atoms or the alkyl group is replaced by 0Ο, or interrupted by one to six one by one , Or both substituted with an amidyl group and interrupted through one to six and one 0—E3 is an alkyl group of 8 to 18 carbon atoms * an aryl group of 6 to 10 carbon atoms, or the aryl group is Via a stack or Substituted by two alkyl groups containing 1 to 4 carbon atoms | and it is limited that when it is E3 SO — or E3 S0 2 — Eι is not a phenylalkyl group. Optimally * in the compound of formula 1 ' Middle * G2 is a gas group, E3 S〇2 — * CF3 —, ~ C0 — G3 or _C0 — N (G3) 2, G3 is an alkyl group of 1 to 18 carbon atoms, E i is hydrogen, phenyl Or ct-cumyl, E2 is an alkyl group of 4 to 12 carbon atoms, and Es is phenyl or octyl | and its limitation is when G2 is E3 S〇2 — * Eι is not 0C —cumyl. Economy The Ministry of Central Standards Bureau ’s Consumer Cooperative has a particularly good formula: G2 is CF3-, Ei is Ct-cumyl, and E2 is tert-butyl or tert-octyl. The present invention also relates to a stable resistance Thermal, oxidative or light-induced degradation compositions include: (a)-organic substances that are sensitive to thermal, oxidative or light-induced degradation, and (b)-effective stable amounts of compounds of formula I, II * III or IV -2 8-This paper size applies to Chinese national standards (CNS > A4 size (210X 297mm) A7 467932 ______ ^ _ 5. Description of invention () 0 {Please read the notes on the back first (Please fill out this page)) Preferably * the organic substance is a natural, semi-synthetic or synthetic polymer, especially a thermoplastic polymer. Optimally, the polymer is a polyolefin or polycarbonate, especially polyethylene Or polypropylene I is most particularly polypropylene. In another preferred embodiment of the present invention, the organic substance is a resin selected from the group consisting of a thermosetting acrylic melamine resin, an acrylic urethane resin * epoxy carboxyl resin, and a silane-modified acrylic melamine resin. Urethane side chain and acrylic resin crosslinked with melamine, or melamine crosslinked acrylic polyol β containing urethane group. Preferably, the resin is a thermosetting acrylic melamine resin or acrylic acid. Urethane resin. In another preferred embodiment of the present invention, the organic substance is a recording substance. The recording material according to the present invention is suitable for a pressure-sensitive coating system *, a light coating system using micro glue, a cooked-type coating system, a photo substance, and inkjet ink. The characteristics of the recording substance printed by the employee's cooperative of the Central Standards Bureau of the Ministry of Economic Affairs are the unpredictable improvement in quality * Especially for light fixation α The recording substance of the present invention has a structure that can be used for special purposes. Includes one or more coated carriers * such as paper or plastic film. Depending on the type of substance used, these coatings contain appropriate essential ingredients, such as silver halide emulsion * dye coupling agent when photographing substances, -2 9- This paper size applies Chinese National Standards (CNS) (2Ι0χ297 (Mm) 467932 A7 B7 5. Description of the invention () Dyes and their analogs. Substances particularly suitable for jetting ink-jet inks have a coating on a traditional carrier that is particularly strong at absorbing ink. Uncoated paper can also be used for inkjet printing, in which case it plays the role of carrier substance and ink absorption calendar. Substances suitable for printing with a jet ink are described in U.S. Patent No. 5,073,448 (herein incorporated by reference). The recording material can also be transparent, such as a rubidium projection film. Compounds of the formula I, II * III or IV can also be added as early as the production of paperboard or paper material *, for example to pulp. A second method of application is to spray the water-soluble compounds of the formula I * I I, I I I or IV on a paper board, or add these compounds to the coating composition. The coating composition suitable for the projection type transparent recording material must not include any particles that can scatter light, such as pigments and fillers. The dye-bonded coating composition can contain many other additives, such as antioxidants, light stabilizers (also UV absorbers that are not part of the UV absorber of the present invention), viscosity modifiers I, a fluorescent brightener, and Microbial and / or antistatic agents. Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Consumer Cooperatives (please read the notes on the back before filling this page) The coating composition is usually prepared in the following way: Water-soluble ingredients (such as adhesives) are dissolved in water > and Search and mix together, solid components (such as fillers and other additives mentioned above) are dispersed into the aqueous solution. It is advantageous to use a device * such as ultrasonic samples, vortex mixer, homogenizer, colloid machine (c ο 1 1 0 id IH i 1 1 s), particle mills (bead mills) * sand mills (sand mills), and high-speed mixing and -3 0-This paper size applies Chinese National Standard (CNS) A4 specifications (210X297) (B) B7 6 7 9-3-2- 5. Description of the invention () Its analogues are stirred. Compounds of formula I, I I, I I I and IV can be easily added to the coating composition. (Please read the notes on the back before filling this page) The recording material of the present invention preferably contains 1 to 5 0 0 mg / m 2, especially 50-1 200 mg / m 2 of the compound of formula I. 0 As described above • The recording material of the present invention includes a very wide range, for example, compounds of formula I, II, III or IV can be used in pressure-sensitive systems, which can be added to the paper in the form of K-protected microgel II coated dyes. The material resists light I or is added to the adhesive of the developing layer to prevent dyes from forming therein. Photosensitive photo-recovery systems using pressure imaging are described in U.S. Pat. ; 4,562,137 and 4,608,330, also described in EP-A-139,4 79; EP-A- 1 8 2, 6 6 4; EP-A- 1 6 4, 9 3 1; EP-A-237,024; EP -A-237,025 or EP-A-260,129. In all of these systems, the compounds of the present invention can be placed in the dye receiving layer, however, the compounds printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs can also be placed in the supply layer to protect the color forming agent. Damage to light. Photographic materials that can be identified are photographic dyes and dye layers containing these dyes or their precursors, such as photo papers and negatives. Suitable materials are as described in U.S. Patent No. 5,364,749 (the present invention is incorporated herein by reference). Here, the compound of formula I, I I, I I I or IV acts as a UV filter to prevent electrostatic flash. In color photographic materials, -3 1-This paper is again applicable to China National Standard (CNS) A4 (210X297 mm) '4 6 7 9 3 2 A7 ___ B7 V. Description of the invention () Coupling agent and The dye is also protected from photochemical decomposition. (Please read the note on the back before filling this page) The compound of the present invention can be used for various types of color photographic materials, for example, it can be used in color photo paper * color reversal paper, directly— Direct-positive colour material, coioui * negative film, colour positive film, j = f (colour film), etc. It is preferably used in a color photographic material containing an inverse base material or a positive material. Color photographic recording materials usually include a blue-sensitive and / or green-sensitive and / or red-sensitive silverized layer * on a support and, if necessary, a protective layer. A green-sensitive or red-sensitive layer, or an interlayer between a green-sensitive and a red-sensitive calendar, or a top layer above a silver halide emulsion layer. The compounds of formula I, II, III or IV can also be applied mainly based on the principles of photopolymerization, photoplasticization or microcapsule rupture, or in the use of heat-sensitive and light-sensitive diazonium salts * white dyes with oxidants or Lewis In the case of acid dye lactones. In addition to printing by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, it can be used for dye diffusion transfer, thermal wax transfer, and non-matrix printing of recording materials *. It can also be used for electrostatic, electrographic, electrophoretic, magnetic and Recording materials for laser-photoelectric printers and pen-tracers. In the above application, it is better to be used for dye diffusion transfer, for example, described in US Patent No. 5,098,477 (herein incorporated by reference) 0-3 2 _ This paper is also suitable for China Standard (CNS) Α4 Regulation ^ (210X297 mm) 467932 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

V. Description of the invention () I The compound of the present invention has excellent hydrophilic stability and storage 1 I storage stability t and good extraction resistance when present in the composition of the paniculum 1 resistance 0 ^^ Please I The method of making the compound is described in the previous technique. The preparation of the compound is described in the previous art. The intermediate of this ith compound has also been widely commercialized. The main compounds are those where X And Y of — one is — 〇1 of the matter 1 compounds r are particularly preferred are those compounds in which both X and Y are — 0 — # 1, A 0 on this page — ordinary polymers that can be identified Including 1 i 1 ♦ Mono- and di-olefin polymers such as propylene polyisobutylene Olefin 1 polybutene — * 1 — olefin poly 4 -methylpentene 1 — ene polyisoprene or 1 1 order. Polybutadiene and cycloolefin polymers such as cyclopentene or probornene (1 1 1 Π 〇rb 〇Γ η ene), polyethylene (which is crosslinked or uncrosslinked) 9 such as high density polyethylene (Η DPE) »high density and high polymer 1 * μ» children's polyethylene ( Η D PE — Η Μ W) > High-density and ultra-high molecular weight t Λ polyethylene (Η D Ρ E -U Η MW) 9 medium density polyethylene (Μ DP i E), low density polyethylene (L DP E ) t Linear Low Density Polyethylene (I 1 ILLDP Ε) > Branched Low Density Polyethylene (BLDPE) 0 1 I Polyolefin 1 i.e., a polymer of a monoolefin ϊ as in the previous paragraph i 1 Olefin polymers, especially polyethylene and polypropylene [utl Jm can be prepared by different methods [-1 method, especially the following method * 1 1) Polymerization of free anti-ntff reactant (usually under high pressure and high temperature) 0 1 1 ~ b) Polymerization of anti-rrffT J® catalyst using a catalyst This catalyst usually contains species or 1 1 -33- • I This paper size applies to Chinese National Standards (CNS) A4 size OlOx 297 mm> 4 67 93 2 B7 Printed by the Consumers and Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () -----_ 1 from S3 — Group IV b, V bt VI b or Group VIII 1 on the periodic table | Metals> These metals usually have one or more types > Typical is oxygen ib | Compound halides i Alcohol esters, Ethyl ethers, Amines & gt Alkenyl and alkenyl alkoxides and 1 / or arylates * which can be π — or σ — covalent 〇 This metal composite reading backing material can be free or fixed on the substrate > typically on Note 1 of activated magnesium chloride > Titanium (III)% aluminum or silicon oxide m 0 These catalysts are soluble or intended 1 Insoluble in the polymer matrix, and the lb catalyst can be used in the polymerization reaction to refill 1 1 or The activator can be used. Typical examples are gold-based compounds, gold-based argonization, J-I, gold-based compounds, alkyl-based compounds, metal-based alkyl oxides, or metal alkyl-based oxane. I a II a and / or IIIA group of I 1 1 element activators can be further modified with esters, ethers, amines or silane groups. 1 1 These catalysts are commonly referred to as Phil li PS S ta nd ar d Oil 1 In di an a, Zi elgl er (-N a 11 a) > T S2 (DuP 0 Ω t), 1 1 ot eta 11 0 C e η e or single-sided catalyst (SSC) C ί 1 2 A mixture of polymers mentioned in 1) > Example > A mixture of polypropylene and polyiso-1 Λ-butene * Polypropylene and Blends of ethylene (e.g. PP / τ I Η DPE j PP / LDPPE) and different types of polyethylene mixed 1 1 (e.g. LDPE / Η DPE) 〇1 I 3 • copolymer of fluorene and diene, or and Copolymers of other ethylene monomers, such as ethylene / propylene copolymers * linear low density polyethylene (LL 1 1, DPE) and mixtures thereof and low density polyethylene (LDPE) t propylene 1 1 / butane 1 monoene copolymerization Propylene / isobutylene copolymer 1 ethylene / butene 1 1 1 monoene copolymer I ethylene / hexene copolymer »ethylene / methylpentene copolymer 1 1 3 4-1 1 This paper size applies to Chinese National Standards (CNS) A4 specification (210X297 mm) A7 4 6 7 932 B7 — — — — __ 5. Description of the invention (), ethylene / heptene copolymer, ethylene / octene copolymer, propylene / butadiene copolymer, isobutene / Isoprene copolymer * ethylene / alkyl acrylate copolymer, and its formation with carbon monoxide Copolymers, or ethylene / acrylic acid copolymers, and their toilet products (ionized products) and terpolymers of ethylene and propylene and monodiene, like hexadiene'dicyclopentadiene or ethylenediene-raw borneol Ene; and the mixture between the copolymers and the mixture of the polymers mentioned in 1), for example, polypropylene / ethylene-propylene copolymer, LDPE / ethylene-ethylene acetate copolymer (EVA), LDPE / ethylene acrylic copolymer (EAA) > LLDPE / EVA · LLD PE / EAA and alternate or random polyolefin / carbon monooxide copolymers and mixtures thereof with other polymers, such as > polyamide. 4. Hydrocarbon resins (such as Cs-C3), including their hydrogenated modifiers (e.g., adhesives), and mixtures of polyolefins and splash powder. 5. Polystyrene, poly (P-methylbenzylethylene), poly (σ-methylstyrene). -6 ♦ Copolymers of styrene or "-formamene styrene and diene or acrylic acid derivatives, for example, styrene / butadiene, styrene / acrylonitrile, styrene / alkyl methacrylate, styrene / Butadiene / alkyl acrylate. Styrene / butadiene / alkyl methacrylate, styrene / maleic anhydride, styrene / acrylonitrile / methyldienoate; Impact strength blends, and another polymer, such as polyacrylic acid, a diene polymer or an ethylene / propylene / diene terpolymer; and -35- for styrene. This paper standard applies to China's national standards. CNS) Α4 specification (210 X 297 mm) (Please read the notes on the back before filling this page)-* 1Τ Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 4 S 7 93 2 ___B7_ V. Description of the invention () Block copolymers like styrene / butadiene / styrene, styrene / isoprene / styrene, styrene / ethylene / butene / styrene or styrene / ethylene / propylene / styrene. 7. Graft copolymers of styrene or ct-methylstyrene, for example, styrene on polybutadiene, on polybutadiene-styrene, or on polybutadiene-acrylonitrile copolymers Styrene on polybutadiene and acrylonitrile (or methacrylonitrile); styrene, acrylonitrile and methacrylic acid on polybutadiene; benzene on polybutadiene Ethylene and maleic anhydride; styrene, acrylonitrile and maleic anhydride or maleimide on polybutadiene; styrene and maleimide on polybutadiene Imines; acetophenone and methacrylic acid esters or mevalonate on polybutadiene diene; styrene and acrylonitrile on ethylene / propylene / diene terpolymers; or polyalkyl acrylate or Styrene and acrylonitrile on polyalkylmethacrylates; styrene and acrylonitrile on acrylate / butadiene copolymers, and mixtures with copolymers listed in item 6), for example, known ABS, MBS A or AES polymerized copolymer blend. 8. Halogen-containing polymers, such as polyaerated pentadiene, chlorinated rubber, aerated or vulcanized chlorinated polyethylene, copolymers of ethylene and vinyl chloride, homochlorinated and copolymers' especially Polymers containing pigmented ethylene compounds, such as polyethylene nitrides, polyethylene chlorides, polyethylene fluorides, polyethylene fluorides, and copolymers thereof, such as ethylene chloride / ethylene dichloride , Ethylene chloride / ethylene acetate or ethylene dichloride / ethylene acetate copolymer. -36- 'The scale of this paper applies the Chinese National Standard (CNS) A4 specification (210X297mm) L „---; ----- (Please read the precautions on the back before filling this page) i-Order Ministry of Economy Printed by the Consumer Standards Cooperative of the Central Bureau of Standards 4 6 7932 A7 B7 V. Description of the invention () 9. Polymers prepared from σ 'Θ-unsaturated acids and their derivatives, such as polyacrylates and polymethacrylates ; Polymethacrylic acid vinegar, polyamidamine and polyacrylonitrile, M butyl acrylate into impact modifiers. 10 'the above 9) copolymer between monomers and other unsaturated carcass, Examples include acrylonitrile / butadiene copolymers, acrylonitrile / fluorene-based acrylic copolymers, acrylonitrile / alkoxyalkyl acrylate or acrylonitrile / ethylene halide copolymers or acrylonitrile / alkyl methacrylate / butadiene Diene terpolymers 1 1 · Polymers derived from unsaturated alcohols and amines or their halogenated derivatives or their acetals-for example, polyvinyl alcohol, polyvinyl acetate, polyethylene stearate, Polyvinyl benzoate, polyethylene maleate, polyethylene butyral, polyallyl peptidate Polyallyl melamine; and copolymers thereof with the olefins mentioned in point 1 above. 1 2 · Homopolymers and copolymers of cyclic ethers, such as polyolefin diols, polyethylene oxides, and polypropylene oxides Or its copolymer with dioxolan. 1 3 * Polyacetals, like polyoxymethylene and those polyoxymethylenes, which contain ethylene oxide as a comonomer, and thermoplastic polyurethane , Acrylate or MB S modified polyacetal. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) 1 4 ♦ Polyphenylene oxide and sulfide, and poly Mixture of styrene oxide and styrene polymer or polyamide. 1 5 Polyurethane derived from hydroxyl terminated polyether, polyester or polybutadiene on one side, and aliphatic or aromatic polymer Isofluorates are in another 逄 * and its precursors. 1 6 · Polyamines and diamines and dicarboxylic acids and / or amine carboxylic acids or equivalent CNS) A4 specification (210X297 mm) ΑΊ 467932 Β7 V. Description of the invention () (Please read the precautions on the back before (Write this page) Copolymer derived from lactam, '洌 如' Polyamine 4 < Polyamine 6 | Polyamine 6/6, 6 / 1〇 '6/9' 6/1 2, 4 / 6, 12/12, polyamines 1 1, polyamines; ί 2, aromatic polyamines starting from m-xylylene diamine and adipic acid; hexamethylene diamine and isotitanic acid or / and Polyacetamide derived from p-acid, with or without an elastomer as a modifier, for example, poly-2,4,4-trimethylhexamethylene-p-amine or poly-phenylene isopeptide Amines; and the above-mentioned polyamines and polyolefins, olefin copolymers, ionides' or chemically bonded or grafted elastomers; or polyethers, such as polyethylene glycol, polypropylene glycol, or polytetramethylene dimer Alcohol block copolymers; and polyamines or copolyamides modified with EPDM or ABS; and polyamines concentrated in the hydrazine preparation process (Polymeramine system). 17 Polyurethane Pyridine 'polypyridine_pyridine and polybenzoxazole. 18. Polymerases derived from dicarboxylic acids and diols and / or hydroxycarboxylic acids or equivalent lactones, such as 'polyethylene para-acetate', polybutene para-peptide, central standard of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperative, Poly 1,4-Dimethylolcyclohexane Peptide and Polyhydroxybenzoate, and Block Copolyether and Polycarbonate Derived from Hydroxy Terminated Poly® Modified or MB s modified poly_ ° 19 · Polycarbonate and Polycarbonate. 20 · Juyan * Jumei Feng and Jumei. 2 1. Cross-linked polymer 'like phenol / formaldehyde resin' urea / formaldehyde resin 'and melamine / formaldehyde resin α-3 8- This paper size is applicable to China National Feng- (CNS) A4 size (210x 297 mm) 4 6 7 93 2 Printed by the staff of the Central Bureau of Standards of the Ministry of Economic Affairs F7 A7 ____ B7 V. Description of the invention () 2 2. Non-drying alkyd resin. 2 3 Unsaturated poly-resin derived from saturated and unsaturated dicarboxylic acids and polyhydric alcohols and ethylene compounds as cross-linking agents, and their low-flammability halogen-containing modifiers. 2 4 'Crosslinked acrylic resin derived from substituted acrylates, such as epoxy acrylic resins, urethane acrylic resins, or polyester resins. 2 2 · Alkyd resins, polyester resins, and melamines Resin crosslinked acrylic resin * urea resin | polyisocyanate or epoxy resin. 26 'Cross-linked epoxy resins derived from aliphatic, cycloaliphatic, heterocyclic or arylene oxypropane compounds, such as products derived from bisphenol A and bisphenol Ft® oxypropane ether * It can be cross-linked with traditional hardeners, like anhydrides or amines (either in the presence or absence of accelerators). 27. Natural polymers, for example, cellulose, rubber, gelatin and its homologous derivatives modified by chemical methods such as cellulose acetate, cellulose propionate and cellulose butyrate, or cellulose ether * Like methyl cellulose; and turpentine and its derivatives.

28 ‘A mixture of polymers (polymixtures), such as PP / E PDM, polyamide / EPDM or ABS * PVC / EVA, PVC / ABS, PVC / MBS * PC / ABS, PB

TP / ABS > PC / ASA < PC / PBT · PVC / CPE, PVC / Acrylic * POM / Thermoplastic PUR, p C / Thermoplastic PUR, POM / Acrylic, POM / MBS ™ 3 9-Applicable to this paper size China National Standard (CNS) A4 specification (2 i 〇X 297 mm) (Please read the precautions on the back before filling this page)

467932 A7 B7 Printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () 1 1 I 1 PP 0 / Η IPS > PP 0 / PA 6 ♦ 6 and copolymer 9 P 1 A / Η D Ρ Ε , PA / PP f PA / PP 0 y 1 1 2 9. Naturally occurring and synthetic organic olives, which are pure compounds or mixtures of these compounds. For example, mineral oils> animal and vegetable fats t oil and m read back 丨 | 9 or synthetic ester-based oil t fats and waxes (such as phthalate < hexadecane __- Note 1 1 acid acid 9 phosphate * diphenyl acid 3d-ester) and synthesis Ester and mineral oil in any important item 重 I most proportioned mixtures > are typically those used as rotating composition and rewrite 1 of this substance aqueous emulsion 〇 page 1 1 0 0 * Emulsion of natural or synthetic rubber in aqueous solution Ethyl Carboxylate / 1 1 Butadiene Copolymer days ρ ”Latex or emulsion 0 1 I 3 1 Polysilicon like soft% Hydrophilic polysiloxane is described in Example 1 US Patent No. 4 2 5 9 4 6 7 and hard polyorganosiloxane焼 1 is described in, for example, U.S. Patent No. 4 3 5 5 1 4 7 0 1 1 3 2 Blends of polyketimine and unsaturated acrylic polyethylene / ^ 1 acid m resin 1 1 t or unsaturated acrylic acid Resin complex 0 Unsaturated acrylic resin 1 Λ Includes vinyl or acrylic copolymers made of urethane acrylic polyether acrylic m and side chain unsaturated group r 1 and melamine melamine 0 Polyketimine is 1 1 Manufactured from polyamines and ketones in the presence of an acid catalyst 0 1 1 3 3 Ray hardenable composition »which includes ethylenically unsaturated monomers * or JI oligomers and — polyunsaturated fatty oligosaccharides Polymer 0 [j 3 4-ring Oxymelamine resin i is like a high solid epoxy resin-functionalized co-ether containing 1 1 amount of melamine resin cross-linked — de-qualified oxyresin> such as LES — 1 i 4 1 0 3 (Mo ns an to ) 6 1 ί-4 0-i 1 This paper scale is applicable to the Chinese National Standard (CMS) A4 specification (210X297 mm) 4 6 7 93 2 A7 B7 V. Description of the invention (Printed by the Consumer Cooperatives of the China Standards Bureau of the Ministry of Economic Affairs * In general, the amount of the invention compound used will vary depending on the specific substrate and application. * However, it is usually from about 0.001 to about 5%. The percentage of stable compounds is an advantageous range from about 0. -〇5 about 3% t, especially 〇 · 〇5 to about 1% 0 The spike fixing agent of the present invention can be easily added to the organic polymer at any convenient stage before its preparation into a molded product i Example: this formula m can be used to dry powder suspension fatigue pattern and polymerization Emulsions mixed with t or solvent can be mixed with polymer solution Λ suspension or% solution. As a result, the stable polymer composition can optionally contain about 0 • 〇1 about 5% by weight t preferably from About 0 * 0 2 5 to about 2% > It is from about 0 • 0 1 to about 1% by weight of various conventional additions > listed under λ or a mixture thereof 0 1 • Antioxidant 1 • 1 • For example: 2 * 6 — di-tert-butyl — 4 — methylphenol> 2 —butyl — 4 i 6 — dimethylphenol> 2 > 6 — 2 — tert-butyl 4 4-n-butylphenol, 2 r 6-di-tert-butyl-4 -ethylphenol, 2 »6-di-tert-butyl-4-isobutylphenol 2» 6-dicyclopentyl -4-methylphenol, 2-(α-methylcyclohexyl) 4 > 6-dimethyl alcohol 2 > 6 — Twenty-eight (18 bases) — 4 — Methylphenol> 2 t 4 6 One tricyclohexylphenol, -41- (Please read the notes on the back before filling this page) This paper size Applicable to China National Standard (CNS) A4 specification (210X 297 mm) 4 6 7 93 2 A7 B7 V. Description of the invention (2), 6-di-tert-butyl-4-methoxymethylphenol. 1 · 2 · alkylated hydroquinone, for example: 2,6-di-tert-butyl-4 -methoxyfluorene, 2 · 5-di-tert-butylhydroquinone, 2,5 -Di-tert-pentylhydroquinone, 2,6-di-benzyloctadecyloxyphenol. 1 · 3 · hydroxylated thiodiphenyl ether, for example: 2 · 2, monothio-bis-one (6-tert-butyl-4 -methylphenol), 2,2'-thio-bis-one ( 4-octylphenol), 4,4'-sulfur bis (6-tert-butyl-3-methylphenol), 4,4'-sulfur bis (6-tert-butyl-1 2- Methylphenol). (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economy, China, 1 · 4 · Alkylene-bisphenols, for example: 2 > 2,-甲 甲--双 一 ' (6--tert-butyl ~ 4 -methylphenol) t 2 t 2, monomethylidene--bis- (6--tert-butyl -4 monoethylphenol) 9 2 9 2 / -methylidene -_ Bis _ '(4--methyl-6-(α -methylcyclohexyl) phenol] 9 2 «2, monomethylidene-bis- (4--methyl-6-dihexyl mm) 2 J 2 x -methylene- _bis-C 6-_nonyl — 4 -methylphenol), 2 i 2, -methylene- -bis-C 6--(a —methylbenzyl) — 4 —nonan Base phenol], -42- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 4 6 7 9 3 2 a? B7 V. Description of the invention () 2 * 2 '— One wave one pair one (6 — (ot, α —dimethylτyl) — 4 -nonylphenol] · (Please read the precautions on the back before filling in this education) 2,2 ^ —Methylated one pair one (4,6_ Di-tert-butyl phenol), Σ 2 ^ —ethylidene one pair — (4,6-di-tert-butylbutyl hydrazone), 2,2'-Ethylidene-di-bi- (6_tert-butyl-4-isobutylphenol) > 4,4'_Alou one pair Mono (2,6-di-tert-butyl-butyl), 4,4 'monomethyl-di- (1,6-tert-butyl-2-methylphenol) · 1, 1, 1-bis- (5_tert _Butyl-4, 4-methyl- 2-methylphenyl) -butane, 2,6-bis- (3-tert-butyl-methyl-2, 2-pentanyl), 4-methyl, 1, 1, 3, 3-tris (5-tert-butyl-4) mesityl-2-methylphenyl) butane, 1,1, bis (5-tert-butyl-4, mesityl-2) —Methylphenyl) —3-n-dodecylmercaptobutane * Ethylene glycol bis [3,3-bis ((3Λ-tert-butyl-4'-hydroxyl), employee of Central Sample Bureau of Ministry of Economic Affairs Consumer Cooperative Printed Phenyl Ester Pentenyl Benzyl 3 2 Tertyl 4-yl Phenylmethyl I 5 I Hydroxyl 6 3 Tertyl Butyl I. Ester, Acid 5 呔 I Parathyl 3 hydroxy-benzene, radical 2A II Base 4 This paper size applies to Chinese National Standard (CNS) Α4 size (2 丨 〇 X 297 male 1) A7 46793 2 B7 V. Description of the invention () 1 _ 5 _ benzyl phosphonate, for example: 1, 3, 5-tri- (3, 5-di-tert-butyl-4-hydroxybenzene (please read first) Note on the back page, please fill in this page again) Methyl) -2,4,6-trimethylbenzene * Di- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfide 3,5 —Di-tert-butyl-4-hydroxybenzidine mono-n-iso-octyl acetate, bis (4-tert-butyl-3-hydroxy-2,6-dimethylbenzidine) disulfide Alcohol-to-peptide esters * 1, 3, 5-tris- (3,5-di-tert-butyl-4-hydroxybenzyl) isoazaurate, 1, 3, 5-tris- (4- Tert-butyl-3 -hydroxy-2,6-dimethylbenzidine) isocyanurate * 3,5-di-tert-butyl- 4 monohydroxybenzyl monophosphate di (: 18 ) Alkyl alcohol > 3,5-di-tert-butyl-1, 4-hydroxybenzyl monophosphate, ethyl ethyl phosphate, salt consumption. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, 1.6-Aminoaminophenols, for example: 4-hydroxymonolaurate, tetifenil, 4-hydroxymonostearate, tetifen, 2,4-bis-octyl Base 6 — (3,5-tert-butyl-4 4-hydroxybenzylamino) -s-triazine, -44- This paper size is applicable to China National Standard (CNS) A4 (210X297 male; i) 46793 2 Λ7 Β7 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention () Octyl-N-(3,5-di-tert-butyl-4 4-hydroxyphenyl) carbamate. 1 7 β-(3,5-di-tert-butyl-4-hydroxyphenyl)-an ester of propionic acid and a mono or polyhydric alcohol, such as: formazan diethylene glycol octadecane triethyl Diol 1,6 —Adipic acid, Pentaerythritol, New Glutaric acid, Tris-hydroxyethyl isocyanate, thiodioxal, di-hydroxyethylglyoxedioic acid, diammonium amine 1 8 β ~ (5-tert-butyl Esters of 4-, 4-hydroxy- 3 -methylphenyl) -propionic acid and mono- or polyhydrogenases • Example: methanol dioxane octadecanease triethylene glycol 1,6-hexanediol neopentyl Di-fermented thiodiethylene glycol pentaerythritol tri-hydroxyethyl isocyanate di-hydroxyethyldiamine diammonium amine 1 · 9 · / 3-(3,5-di-t-tert-butyl-4 4-hydroxyphenyl ) Ammonium monopropionate | For example, Ν * Ν / one two-(3,5 ~ di-tert-butyl-4-hydroxyphenylpropionyl) hexamethylene diamine * -45- Standards apply to Chinese national standards (CNS> Α4 specifications (2 丨 0 × 297 mm) (please read the precautions on the back before filling out this page) 4 Printed by the Central Bureau of Standards of the Ministry of Economy—Industrial Consumer Cooperatives 6 7 9 3 2 Λ7 B7 Fifth, the invention () N, N'-dione (3,5-di-tert-butyl-4 4-hydroxyphenylpropanyl) -trimethylene diamine | Ν-Ν, -dione (3,5-di Mono-tert-butyl-4 monohydroxyphenylpropanyl) -hydrazine. 1 * 1 0 · diarylamine, for example, diphenylamine, N-phenyl- 1-naphthylamine, N-(4 —Tert-octylphenyl) — 1-naphthylamine, 4,4′-di-tert-octyl-diphenylamine, N-benzylbenzylamine and 2,4,4-trimethylpentyl Reaction product of alkene, reaction product of diphenylamine and 2,4,4-trimethylpentene, reaction product of N-phenyl_1-naphthylamine and 2,4,4-trimethylpentene 2 * UV absorber and photo-fixing agent 2 · 1 · 2 ~ (2 '—Hydroxybenzyl) —benzotriazole, for example: 5, monomethyl_, 3,, 5, —di-tert-butyl -'5, _tert-butyl-> 5 '-(1 * 1,3,3-tetramethylbutyl)-, 5 -nitrogen-3,, 5, _di-tert-butyl- , 5 —Chloro-t-butyl-5, —methyl —, 3, —sec-butyl-5, —t-butyl —4, monooctyloxy, 3,, 5, —di — Tert-pentyl—, 3 ' , 5'-bis (a, ct-dimethylbenzyl), 3'-tert-butyl-5 '-(2-(Ω -hydroxyl-octa (ethyleneoxy) fluorenyl-ethyl ) I, 3'-dodecyl-5'-methyl- and 3'-tert-46- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X297 male feet) 1N ------ ^ --- ^ ------ 1T (Please read the notes on the back before filling out this page) 467932 A7 B7 V. Description of the invention () Monobutyl-5 '— (2-octyloxycarbonyl) ethyl And dodecylated 5'_methyl derivatives. 2.2. 2-Hydroxymonobenzophenone, for example 4-hydroxyl-> 4-methoxyl, octyloxy, 4-decyloxy-1, 4-dodecyloxy-1, 4-benzyloxy Group, 4,2 ', 4'-trihydroxyl and 2'-hydroxyl-4,4 ^ -di-methoxy derivatives. 2.3 • Selectively substituted benzoic acid esters, such as phenylsalicylic acid, 4-tert-butylphenylsalicylic acid, octylphenylsalicylic acid, benzophenone resorcinol , Bis- (4-sylo-butylbenzoic acid) ~ resorcinol, benzoic acid resorcinol '3' 5-di-tert-butyl- 4-hydroxybenzoic acid, 2 * 4 -di Mono-tert-butylbenzyl and 3,5-di-tert-butyl-4-hydroxybenzoic acid hexadecane. 2 · 4 · Acrylic esters * For example α-fluoro-mono /? * / 9 mono-diphenylethyl acrylate or isooctyl, ct-Carbomethoxy-cinnamic acid methyl ester, α-cyano- Monomethyl-P-methoxy-cinnamate methyl or butyl ester, ct_Carbonylmethoxy-P-methoxy-cinnamate methyl ester, N _ (/ 3 / 3-Carbonylmethoxy 1 / 3-fluorovinyl) -2-methyl-indoline. 2 · 5. Nickel compounds, such as 2 * 2'-thio-bis-[[4-(1,1,3,3-tetramethylbutyl) -mono]] nickel compounds * like 1 -4 7- This paper · size applies to China National Standard (CNS) Α4 specification (210X297 mm) (Please read the precautions on the back before filling this page) Order the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Print the Employee Cooperatives of the Central Standards Bureau of the Ministry of Economy Print S793 2 V. Description of the invention (): 1 or 1: 2 complex, optionally containing other chain groups, such as n-butylamine, triethanolamine or N-cyclohexyl-diethanolamine, dibutyldisulfide Carbamate _, 4_hydroxy_3,5-di-tert-butylbenzylphosphonic acid monoalkyl nickel salt, nickel salt like methyl, ethyl or butyl ester, nickel complex of oxime Compounds, such as 2-hydroxy-4-methyl-benzylundecylsulfonium oxime white 5 nickel complexes, 1-phenyl-4 4-lauric acid-5-hydroxy-pyrazole nickel complexes * which selectively Contains other chain groups. 2 · 6 · sterically hindered amines, such as bis (2,2,6,6-tetramethyltonidinyl) sebacate, bis (1,2,2,6,6-pentamethylton) Pyridyl) sebacate, n-butyl-3,5-di-tert-butyl-4 monohydroxybenzylmalonate bis- (1,2,2,6,6-pentamethyl # pyridine Ester), 1 ~ hydroxyethyl-2,2,6,6-tetramethyl-4, a condensation product of hydroxystilbidine and succinic acid, N, N '-(2, 2, 6, 6, 6-4 Methyltonidyl) Condensation product of hexamethylenediamine and 4-tert-octylamino-2.6-digas-s-triazine, Trione (2,2,6,6-tetramethyl Gyridinyl) monoazine monotriacetate, tetra- (2,2,6,6-tetramethyl-4-tetramidyl) 1,2,3,4-butanetetracarboxylate, 1 , Ly — (1,2-ethanediyl) -bis— (3,3 * 5,5-tetramethylpiperazinone), bis (1-octyloxy-2,2,6,6—tetra Methylpiperidine-4-yl) sebacate. 2 '7. Glycol dietheramine, for example, 4, 4' 1,2 octyloxy-4 8 _ This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) !: 'I ^ — ^ 1 ^^^^ 1 H · ----......-丨, J (Please read the notes on the back before filling in this page) --a 7 93 2 Λ7 B7 θ. Central Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Standard Bureau 4 V. Description of the invention () 1 I Benzamidine t 2 ϊ 2 / — Di-octyloxy — 5 V 5 / — Di-tert- 1 I — Butyl — chloramidine Aniline * 2 t 2 12-dodecyloxy- 5 1 1 I 5 / —— di-tert- __butyl- 1-methane aniline, 2-ethoxy- 2 f 1 please! Read [ethyl — Grasshopper aniline * N »N / One bis (3-dimethylaminopropylpropyl reading [face I] — Grasshopper amine 9 2 — Ethoxy — 5 — tert-butyl — 2 / Note of Yiyi 1 1 means 1 chlorfendibenzidine and its 2 —ethoxy — 2 / — ethyl — 5 S 4 / thing 1 I again 1 —-a mixture of mono-tert-butylgrabentifen 9 and the ortho- and para-positions \ write Bennonoxy and ortho- and para- Position — ethoxy — di-substituted oxaprofenil, a mixture of f 1 〇J 1 1 2 8 hydroxyphenyl S 嗦 for example 2 t 6 bis (2 > 1 1 order 4 — dimethyl group) — 4 — (2 —hydroxyl — 4 —octyloxyphenyl) 1 r — S —diazine * 1 1 2 9 6 —bis — (2 4 —dimethylphenyl) — 4 — (2 t 4 a 1 Dihydroxyphenyl) — S —triazine> 1) 2 f 4 — bis- (2 9 4 ~ dihydroxyphenyl) — 6 — (4 —chlorinated] benzyl) — S —diazine * 1 2 , 4 aate bis— [2 —hydroxyl — 4 — (2 \ 1 1 —hydroxyethoxy) benzyl] — 6 — (4 —chlorinyl) — S — 1 1 hydrazine t 2 9 4 — bis C 2 — hydroxy — 4 — (2 — hydroxy — 4 mono (2 1 Γ — hydroxyethoxy) phenyl] — 6 (2 t 4 — dimethylphenyl) — ί S one two Hydrazine 1 2 t 4 —bis [2 monohydroxy-4 — (2-hydroxyhydroxyethoxy I [| radical) phenyl] 6 6 (4-monobromophenyl) — S — triazine 2 t 4 1 [mono Double C 2 — hydroxy — 4 — (2 — ethoxyloxyethoxy) phenyl — 1 [-49-1 1 This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210 X 297 public 逄) Λ7 467932 B7 V. Explanation of the invention () 6 — (4-monophenylated phenyl) — s —triazine; 2 ^ 4 —bis (2,4-dihydroxyphenyl) -6- (2,4-dimethylbenzene Base) — s — III (Please read the notes on the back before filling out this page) 嘹. 3 'Metal deactivating agent, such as N, N'-diphenylethylenediaminediamine, Ν-salicyl-monosalicylhydrazine, Ν, ϊ ^-bis (salicyl) hydrazine, Ν, N'- Bis (3,5 —di-tert-butyl-1,4-hydroxybenzyl-propanil) hydrazine | 3-salicylamino-1,2 > 4-triazole, bis (benzylidene) ethylenedifluorene Twenty-one hydrazine. 4 Phosphites and phosphonates such as triphenylphosphite, diphenylalkylphosphite, phenyldialkylphosphite, tris (nonylphenyl) phosphite, trilauryl Phosphite, tris-octadecylphosphite, distearylpentaerythritol diphosphite, tris (2,4-di-tert-butylphenyl) phosphite, diisodecylpentaerythritol Diphosphite, di- (printed by 2,4-di-tert-butylphenyl) pentaerythritol diphosphite, tristearyl-sorbitol triphosphite * (printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs * Tetrakis (2,4-di-tert-butylphenyl) 4,4'-diphenylene diphosphonate. 5. Compounds that break down peroxides, such as esters of / 3-thiodipropionic acid, such as lauryl * stearyl, tetradecyl or tridecyl esters, mercapto-benzimidazole, or 2-mercaptobenzene Zinc salt of imidazole, zinc dibutyl-dithiocarbamate, octacosyl disulfide, pentaerythritol tetral (/ 3-dodecyl-50- This paper is in accordance with China National Standard (CNS ) A4 specification (210X 297 mm) Λ7 467932 B7 V. Description of the invention () Mercapto group)-propionate. 6 · Hydroxylamines * For example, N, N -dibenzylhydroxylamine, N * N -diethylhydroxylamine, N, N -dioctylhydroxylamine, N, N -dilaurylhydroxylamine, N, N —Di (tetradecyl) hydroxylamine, N, N —di (hexadecyl) hydroxylamine, N, N —di (octadecyl) hydroxyamine, N—hexadecyl—N—octadecyl Alkylhydroxylamine * N —heptadecyl —N_ octadecylhydroxylamine> N, N —dialkylhydroxylamine from hydrogenated tallowamine 07 • Nitranium, for example, N-benzyl —α- Phenyl mononitrone, N-ethyl-α-methyl mononitrate, N-octyl-10; _heptyl mononitrate, N-lauryl-α-undecyl-nitron Fourteen-base-one-ct-thirteen-base-one-nitrone, N-hexadecyl-ct-pentadecyl-one-nitrone, N-octadecyl-c (heptadecyl-nitrone | N —Hexadecanyl-ct 17-Heptadecyl-Nitrone ”N —Octadecyl—α —Pentadecyl-Nitrate * N-Heptadecyl—α —Heptadecyl-Nitrate , N—octadecyl_α-hexadecyl mononitrone, derived from N, N—dialkylhydroxyl of hydrogenated tallowamine Nitrones in the base limbs. 8 · Polyamide stabilizers such as copper salts combined with iodide and / or phosphorus compounds, and salts of divalent manganese. -5 1- This paper size applies Chinese national standards ( CNS) A4 specification (2 l'OX 297 mm) (Please read the notes on the back before filling out this page) r: f · Order the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Print the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Printed 467932 A7 __ B7 V. Description of the invention (9) Alkaline co-spike agent * For example, melamine, polyvinylpyrrolidone, digas diamine, tri-allyl cyanurate, urea derivative, Hydrazine derivatives, amines * polycarp, polyurethanes * alkali metal or alkaline earth metal salts of higher fatty acids • For example, calcium stearate, zinc stearate, magnesium stearate, sodium mate Potassium hexadecanoate, antimony pyrocaterate or zinc pyrocatechin. Nucleic acid agents such as 4-tert-butylbenzylmethyl, adipic acid, diphenylacetic acid. 11. Fillers and reinforcements , For example, calcium carbonate, silicic acid, glass fiber 'asbestos, talc, high-sensitivity clay, mica, barium sulfate, metal oxides and hydroxides Chemical compounds, carbon, graphite. 1 2 Other additives, such as plasticizers, lubricants, emulsifiers *, colorants, optical brighteners, fire retardants, antistatic agents and blowing agents, and sulfur Take medicine, such as dilauryl thiodipropionate or February. Lauryl thiodipropionate. (Please read the notes on the back before filling out this page) Order 467932 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Preparation of Λ7 B7 V. Description of the invention () Monoketone, 3,3 '— bis- [5,7 —di-tert- ~ -butyl-3 — (4-mono [2-pyridylethoxy] phenyl) benzene Youfuran_2_one], 5,7-di-tert-butyl_3_ (4_ethoxyphenyl) _benzofuran 2 -fluorene, 3 ~ (4 -ethoxyl-3 , 5-Dimethylphenyl), 7 —— -tert-butylbenzofuran_2_one, 3_ (3 '5-dimethyl-1-4-pentamyloxyphenyl)-5, 7 —Di-tert-butyl-benzofuran-2-one. Except for the benzofuranone listed in item 13, these conjugated stabilizers are added in an amount of, for example, 0.001 to (calculated with respect to the weight of the weighed substance). In addition to the other additives of ingredients (a) and (b), other preferred compositions include, in particular, phenol antioxidants, photo stabilizers or processing stabilizers. Particularly good additives are phenolic antioxidants (listed in item 1), steryl amines (listed in item 2. 6), phosphorous acid and phosphonates (listed in item 4), and peroxide Physical destruction compounds (listed in item 5).

Other particularly good additives (stabilizers) are benzofuran 2-fluorene, as described in, for example, US-A-4,325,863; US-A-5,175,312. Particularly advantageous phenolic antioxidants are selected from the group consisting of: n-octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, neopentane tetrayl tetrakis (3,5 -Di-tert-butyl-4 monohydroxyhydrocinnamate), di-n-octadecyl-3,5 di-tert-butyl-4-hydroxybenzyl phosphonate, 1, 3, 5 — three (3, 5 — two_shuyi-5 3-This paper size applies to the Chinese National Standard (CNS) Λ4 specification (2) 0 × 297 mm) ) Order

rS 467932 Λ7 B7 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention () Butyl — 4 — hydroxy + wide base) Isoturonic acid 1 Thiodiethylene bis (3 9 5 1 2 — Uncle — Butyl — 4 — hydrogenated cinnamate) j 1 3 t 5 — trimethyl — 2 t 4 > 6 — tris (3 t 5 di-tert-butyl — 4 monohydroxy) benzene 3 i 6 Dioxaoctamethylbis (3-methyl-5—tert-butyl- 4—hydroxymethylated cinnamate) f 2 6 mono-tert-butyl—P—cresol 1 2 » 2 / — ethylidene — bis (4 1 6 — — " — tert-butylphenol) 1 t 3 5 a — (2 6 —dimethyl — 4 — tert-butyl — 3 —hydroxybenzyl) iso Aqueous uric acid ester 1 1 9 3 —bis (2 monomethyl-4 —hydroxy-5 —tert-butyl-phenyl) butane 1 3 5 dichloro 2 — (3 5 —di-tert-butyl) — 4 —Naphthyloxyhydro) ethyl] isocyanate Ester * 3 5—Di (3 5—Di-tert-butyl-4—hydroxybenzyl) Homo-cresol Methylbis (3 S 5 —Di-tert-butyl-4—hydroxyhydrocinnamic acid Esters) 1 — (3 t 5 —di-tert-butyl-1—hydroxyaniline) — 3 5 —di (octylthio) — S monodiazine> N 9 N / —methylene — bis (3 »5-Di-tert-butyl- 4-hydroxyhydrocinnamonamine)» Bis (ethyl 3 5 -di-tert-butyl-4 monohydroxybenzylphosphonic acid calcium) > EthylenebisC 3 t 3-bis (3-tert-butyl-4-hydroxyphenyl) butyrate 1 octyl 3 5-di-tert-butyl-4 4-hydroxybenzylfluorenylacetate »bis (3 > 5 — Di-tert-butyl-1, 4-hydroxyhydrocinnamonium hydrazone)-hydrazine t and Ni N /-bis C 2 one (3 5-12-tert-butyl-4-hydroxyhydrocinnamonyloxy)-ethyl Radical] monooxamine 〇 best m antioxidant The chemical agent is Xinjiyuan Sijiyuan (3 t 5 — Uncle Eryi-54) This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X297 mm) 4 6 7932 A7 B7 Employee Consumer Cooperative of Shiyang Standards Bureau of the Ministry of Economic Affairs Printed 5. Description of the invention () — butyl — 4 — hydroxyhydrocinnamate) n — octadecyl 3 t 5 12 — tert-butyl — 4 — hydroxyhydrocinnamate 1 t 3 1 5 1 Methyl-2,4] 6-diC 3 9 5-di-tert-butyl-4 -hydroxybenzyl) benzene f 1 3 9 5 -di (3 f 5 -di-tert-butyl- 4- Hydroxyl) isocyanurate J 2 j 6 —di-tert-butyl-P—cresol or 2 2 ethylidene—bis (4 * 6 di-tert-butylphenol) 0 is particularly advantageous Hindered amines are the following group groups; bis (2 2 6 »6 — tetramethylpiperidine — 4 —yl) sebacate y bis (1 2 2 I 6 t 6 — pentamethylpiperidine — 4 — base) Ester Di (1 2, 2 9 6 6 —Pentamethylpiperidine-4 —yl) (3 5 —Di-tert-butyl-4 —hydroxybenzyl) butylmalonate 1 4 —formamidine One 2 2 6 6 —tetramethyl #pyridine 4 — stearyloxy — 2 y 2 6 6 —tetramethylpyridine »3 — n-octyl — 7 9 7 i 9 * 9 — tetramethyl — 1 * 3 > 8-diacridyl-spiro C 4 5] undecane-2 t 4-dione tris (2 2 9 6 9 6 tetramethylmorphinidine 4 -yl) nitrogen triacetate »1 9 2 —Bis (2 t 2 y 6 »6 Tetramethyl — 3 —oxoxazine — 4 mono) ethane% 2 t 2, 4 t 4 Tetramethyl — 7 — oxygen — 3 2 0 — Di Acridine — 2 1 — oxodispiro C 5 1 * 1 1 * 2 3 fluorene-tane t 2 t 4 — dichloro-6 — tertiary — octylamino — S — triazine and 4 > 4 / monomethylene Bis C-amino — 2 »2 1 6 > 6-tetramethylpyridine) condensation product > 1-(2-hydroxyethyl)-2 i 2 > 6 6-tetramethyl-4-hydroxy Pyridine He Ding Er-5 5--This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) 4 6793 2 Λ7 B7 r 4, 4 / — ^-methylpiperidine) and 1 2 — 7 6 1 6 —tetramethylethene tetracarboxylate j tetra (1 —yl) 1 i 2 »3 > 6 —morpholinyl — S — tri, 2» 6 i 6 tetramethyl N t N // t — tetra C 6 — tetramethyl — neridine —yl — 3 f 9 — (2 9 eleven houses) diethyl] 1 C 1 > 2 f 2 • 6 9 β t β / — tetramethyl oxygen Heterospiro C 5 5 Decadecyltetracarboxylic acid octadecyl 4-carboxylic acid m) T-tetramethylpiperazine-3-benzidine-4 -yl-n-2 6 »6-pentamethylimine Amine 1 N — 1 — Acetyl — Base — n — Dodecyl radical — 7 * 7 9 »9 1 5] Decane — 2 y 4 56 (Please read the notes on the back before filling this page) Ministry of Economic Affairs Printed by the Consumers' Cooperative of the Central Bureau of Standards 5. Description of the invention () Polycondensation products of acids < 6, 6-Tetramethyl, 4 ( 2,2 2,3,4-Butylpentamethylpiperidine- 4 2,4 -dichloro- bis (amino- 2-, N * N v, -2,2,6, ,, β f- Tetramethylheterospiro [5 · 5] tetracarboxylic acid ester, mixed-group / point, hydrazone,, 8 * 1 0 —tetra-2,3,4-butane-tetramethylpiperidine-2-2-6-6 6, 6-tetramethyl * N-1, 2, undecyl butane, tetramethyl tetrabenzyl-4, 4-3-twelve, 8-di-π-spiro [4 bis (amino-1 2 Polycondensation syndrome of 2,2 dibromoethane—4-one) —1,2,2,2,6,6—4-butanetetracarboxylic acid ester, pyrene and 4,4′-hexamethylpiperidine) Polycondensation yields (4,6-bis (butyl4-yl / S, > 3, /? 4,8,1 0-tetraoxy, 2,3,4-butane 6-pentamethyl) Doubt 4 -3-9-(2-4 monoalkane) diethyl] 1, bis (2,2,6,6 4,4 ^ monoethylene bis (ketone), N-2 * 2, 11 Alkyl butanediamine 4-1-1-1-2 * 2 > 6 · 8-butane diimine, 1-ethyl-tetramethyl-1, 3 *-diamidine, di ( 1 Chinese paper standard (CNS) is applicable 4 Specifications (210X; 297 mm) A7 467932 B7 V. Description of the invention () {Please read the precautions on the back before filling out this page) Oxy-2, 2, 6, 6_tetramethylmorphine-1 4 _Yl) sebacate * di (1,1-cyclohexyloxy-2,2,6,6-tetramethylamidine-4-yl) succinate, 1-octyloxy-2,2, 6, 6-tetramethyl-4 monohydroxyl-pyridine * poly ([6-tert-octylamino-s-triazine-2,4-diyl] [2 — (1-cyclohexyloxy-2 , 2,6,6-tetramethylpiperidine- 4-yl) imino-hexamethylidene- [4- — (1-cyclohexyloxy-2,2,6, S-tetramethylmethylpyridine-4 —Yl) imino], and 2,4,6-tris [N — (1-cyclohexyloxy-2,2,6,6-tetramethylmethylpyridin-4-yl) -n-butyl Amine group] -s -triamidine 0 The best amine compound is bis (2,2,6,6-tetramethylpiperidine-4-yl) sebacate, bis (1,2,2, 6,6 —Five Methylpyridin-4-yl sebacate printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, di (1 * 2, 2, 6, 6 _ Wujia Ketoline-4 -yl) (3,5-di-tert-butyl-4 -hydroxybenzyl) butylmalonate, 1-(2-hydroxyethyl)-2, 2, 6, 6 -A polycondensation product of tetramethyl-1, 4-hydroxypyridine and succinic acid, 2,4, 2-gas, 6-tert-octyl-amino-s-difluorene, and 4,4'-hexamethylenebis ( Polycondensation product of amino-2,2,6,6-tetramethylpiperidine), N, N ′, N ′, N # / — tetra [(4 * 6 —bis (butyl- (2,2 , 6,6-tetramethylpiperidine-4-yl) amino group ~ s-trifluoro-1-yl group--1,10-diamino-4, 7-diazecane, di (1- Octyloxy-2,2,6,6-tetramethylpiperidine-4-yl sebacate, dione (1-cyclohexyloxy-2 -57-) This paper is in accordance with China National Standard (CNS) ) Λ4 specification (210X297 mm) 6 4 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 _B7__ V. Description of the invention () • 2, 6, 6-tetramethylpiperidine-1, 4-yl) succinate , 1 -octyloxy-2,2,6,6-tetramethyl-4 4-hydroxypiperidine, poly- {[6-tert-octylamino s—triamidine-2,4-diyl] [2- (1-cyclohexyloxy-2,2,6,6-tetramethylpiperidine-4-yl) imine hexamethylene-1 [4 一 ( 1-cyclohexyloxy-2,2,6,6-tetramethylpyridine-4imyl) imine], or 2,4,6-H [N-(1-cyclohexyloxy-2 * 2,6,6-tetramethylmethylpyridine-4-yl) -n-butylamino] -s-triazine. The composition of the present invention can further include another UV absorber selected from the group consisting of s-triazine > oxaloptidine * hydroxybenzobenzopyrene | benzoate and ct-amino acrylate. In particular, the sister product of the present invention may additionally contain an effective amount of at least -other 2-hydroxyphenyl-2H-benzotriazole, triaryl-s-triazine, or hindered amine · and mixtures thereof . Preferably, 2-hydroxyphenyl-2H-benzotriazole is a composition selected from the group consisting of: 2- (2-hydroxy-3,5-di-tert-pentylphenyl) -2H-benzotriazole Oxazole; 2-[2-hydroxy-1,3,5-bis (α, α-dimethylbenzyl) phenyl] _2Η-benzotriazole; 2-[2-hydroxy-1-(a, ct one two Methylbenzyl)-5-octylphenyl]-2H_benzotriazole; 2 — {2 ~ diameter group 3-tert-butyl- 5-[2-(omega —Control-58-- ----.--- 衣 _ — (Please read the notes on the back before filling out this page), v5 This paper size is applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) 16 793 2 A7 B7 Printed by the Central Laboratories of the Ministry of Economic Affairs and the Consumers' Cooperatives. 5. Description of the invention () II group — (octadecyloxy) carbonyl) ethyl] phenyl} — 2 Η monobenzodi 1 1 I wow > and 1 I 2 — {2 monohydroxy — 3 — tert-butyl mono 5 — C 2 — (octyloxy) first 1 1 m carbonyl) ethyl] phenyl} — 2 Η — Benzolite Read back I 1 | Preferably 1 Other di-aryl-S-diazines are notes of the following composition 1 I meaning 1 matter 1 item 1 2 4 — double (2 4 — Dimethylphenyl) — 6 — (2 —Hydroxyone filled with 4 —oxyphenyl) — S —Diazine Page 1 2 4 — Diphenyl: — 6 1 (2 —Hydroxy — 4 — Hexyloxyphenyl) — 1 IS — Diazine 1 I 2 4 bis (2 »4 dimethylphenyl) _ 6 -C 2 hydroxy_ i Order 4 — (3 — twelve — / thirteen —Oxy — 2 — hydroxypropanyl) poly 1] — S — — azine and 1 1 2 — (2 — hydroxyethyl limbyl) — 4 * 6 — bis c N — butyl-N 1 1 — (1 — cyclohexyloxy — 2 »2 6 t 6 — tetramethylpiperidine — 4 — 1 ) Amino-S-diazine 0 i According to the present invention * A fermented acid tree that can be stabilized against the effects of light and moisture 1 1 Fat varnishes are traditional oven varnishes 1 Especially ΠΤΐ Used to coat automotive varnishes (steam 1 1 car final coating) 9 For example, zymotic resin / melamine resin 4 and alkyd resin 1 1 / acrylic / melamine resin-based varnish (refer to Η. Wagner and Η IF. S a Γ X) " L ac kk u η stha V Ze ”(19 7 7), P ag es 9 9- 123) 〇1 I Other crosslinking agents include diuretic resin t-block isocyanate or epoxy resin. 1 1 Η Invention varnish is suitable for the final coating of metals and the overall color tone 1!-59-1 1 This paper size applies to China National Standard (CNS) A4 (210X297 mm) 67932 Α7 Β7 Central Bureau of Standards, Ministry of Economic Affairs Printed by the Consumer Cooperatives V. Description of the Invention () Coating, especially for retouching coating, and various line coating applications. Μ The varnish of the present invention is preferably the traditional method of M. Two methods can be used to coat S: single-layer coating method or double-layer coating method. In the latter method, a pigment-containing base coat is applied first and then a clear coat is overlaid thereon. It must also be noted that the compounds of the present invention can be used in non-acid-catalyzed thermoplastic resins, such as ring gas, epoxy-polyester, ethylene, zymoic acid, acrylic, and polyester resins, and their selective M silicon, isocyanate Or outgassing uric acid and seaweed. This epoxy and epoxy-polyfluorene resin are traditional cross-linking and cross-linking resins, like acids, anhydrides, amines, and the like. In contrast, * epoxides can be used as crosslinkers for various acrylic or polyresin systems that have been modified in the backbone structure by reactive groups. When used for two-layer coatings * the compounds of the present invention can be added to clear coatings * or to clear coatings and pigment-containing base coatings. When a water-soluble, water-miscible or water-dispersible coating is desired, the acid groups present in the resin form a monoammonium salt. The powder coating composition can be prepared by reacting monoglycidyl methacrylate with a selected alcohol component. Benzotriazole of the present invention is prepared by a conventional method. Useful steps include the diazotization of a substituted 0-nitroaniline followed by a substituted phenol coupling resulting in the diazonium salt and the intermediate azobenzene intermediate as the relatively desired benzotriazole. The starting materials for the preparation of some benzotriazoles have been commercially produced, or can be prepared by the general method of synthesizing with sickle. -60- III-III— i I 1 I— I 11— «--I. ^, -H in (Please read the precautions on the back before filling out this page) This paper size applies Chinese National Standard (CNS) Α4 Specifications (210 × 297 mm) 4 6 7 9 3 2 Printed by the China Bureau of Standardization Shellfish Consumer Cooperative A7 B7 5. Description of the invention ()! I The benzodiazole of the present invention with improved durability is applicable to automobiles — i I coated m may be used especially for other applications that need to improve durability 1 such as I 1 sunshade film and its class M 0 Please read the examples under I M only for the purpose of 0 back III | of [Note I Example 1 Note j 5 Difluoromethyl — 2 — (2 — hydroxy — 3 — α — fluorenyl — 5 — tert-filled with S — octylphenyl) — 2 fluorene — benzotriazole Prepare the topcoat (a) 4 monoamino-3 —nitro-poly-trifluoride diazonium II in a 500 ml device 3-necked flask with a mechanical stirrer II add 4.1 2 grams of 4 —amino — 3 —nitromonobenzyl trifluoride «I order 5_ .2 mdan» dCl concentrated hydrochloric acid and 100 ml of distilled water. Cool the stirred solution i to 5 υ and 50 ml of I I water with 173 g of sodium nitrite dissolved was added, and the solution was stirred at 0 to 5 V for 2 hours, then filtered and stored in II—100 〇I b). Monoazo adduct I in A 100 ml flask equipped with a mechanical stirrer was charged with I! 200 ml of 40 ml of sodium hydroxide dissolved in 200 ml of methanol and 3 2 • 4 i I of 2 a-cumyl — 4 tert-octylphenol in 50 ml of dimethylbenzyl 0 r cooled to 5 V and Into the above a) Part 4-Amino-nitro-I. Diazo solution of trifluoride 9 Temperature 0 to 5 V 9 Add time II for 2 hours 〇 Then add 100 ml of xylene and > Λ Hydrogen atmosphere II acid solution > Water sodium bicarbonate solution and finally washed with organic layer 〇II 61--II This paper size applies to China National Standard (CNS) A4 (210X297 mm) 467932 A7 B7 5 2. Description of the invention () The solvent was removed under reduced pressure, and the residue was purified by chromatography (silica gel, heptane: ethyl acetate 95: 5), and 42.1 g of an adduct was obtained, which was a dark red paste. Thing. c) Kashihara of monoazo adduct — 1 ◦A flask of 00 liters containing 20 g of sodium hydroxide, 40 ml of water, 42.1 g of b) And 400 ml of acetic acid. The mixture was heated to 80¾, and a total of 27 g of formamidinesulfinic acid was added in a manner such that the fractions were mixed. After 15 hours * cool the solution to room temperature and add 100 ml of water. The pH value M was adjusted to 7 and then the ethanol was removed under vacuum. The aqueous phase was extracted with formazan, the solution was removed in the sky, and the residue was purified by K chromatography (silica gel, heptane: Meben 9: 1) * and recrystallized from ethanol. 5.6 g of the title compound was obtained as a pale yellow solid with a melting point of 1 19 to 12 1. . ° Example 2 5-Fluoro-2-(2-hydroxy-3-α-cumyl-5-tert "printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs of the Ministry of Occupation {Please read the notes on the back before filling in this education) Preparation of phenyl) -2 fluorene-benzotriazole This compound was prepared according to the procedure of Example 1 using 3 1.2 grams of 4 monofluoronitroaniline. In step c), an additional 9 grams of methysulfinic acid was added to completely reduce. The crude product was purified on silica gel (heptane:: 1) to give 4.5 g of the title compound as an off-white solid. Further recrystallized from acetonitrile: toluene to obtain 1.1 g of the title -6 2-This paper size is generally Chinese National Standard (CNS) Λ4 specification (210X297 mm) 6 4 Printed by the Central Standards Bureau of the Ministry of Economy—Industrial and Consumer Cooperatives Preparation 7932 a7 _B7___ 5. Description of the invention () Compound, melting point 93-96¾. Example 3 5 —African — 2 — (2 —Xianji — 3 — α —fluorenyl — 5 —tert-octyl phenylphenyl :;) — Preparation of 2 2 —benzobenzotriazole \ According to Example 1 a) and b ) Part of the step, from 3 39,3 grams of 4-chloro-2-nitroaniline to prepare the intermediate of the K title compound, the crude product was recrystallized from methanol | 7 0 9 grams of dark red monomer Nitrogen adducts. C) The monoazo adduct Kashihara-a mixture containing 11.8 g of sodium hydroxide and 138 g of 2-butanol is heated to 95, and it is dissolved in 90 g over 90 minutes with stirring. A solution of 60 * 1 g of the above monoazo adduct in 2-butanol and 1.3 g of 2,3-diaza-1,4-naphthoquinone. The reaction mixture was heated to remove 2-butane by-products, and additional 2-butanol was added to replace the distillate. The reaction mixture was cooled to 8 ¾, washed with 2 ' 5N acid and brine, then concentrated. The residue was recrystallized from methanol: xylene to obtain 45.6 g of the title compound. * It was a pale yellow solid, melting point: 104-105. Example 4 5 —Phenylthio-2 — (2 -hydroxy_3- α-cumyl-5—preparation of pyrene-octyl germanium phenyl i—2Η-benzotriazole-63- The standard of this paper is applicable to China National Standard (CNS) Λ4 specification (2 [0X 297 mm) (please first Read the notes on the back and fill out this page), 1T-467932 V. Description of the invention () In a containing 75 grams of 5-chloro-2- (2-hydroxy-3-α-cumyl-tert-octylphenyl) 1 2H — Stirred three miles and 105 grams of 1 ^ -methylpyrrolidine brewed in a stirred mixture, first heated to 9 QC ', and then added 44.3 grams of 45 Zheng aqueous potassium oxide solution in 15 minutes, and then Add 20.4 grams of thioxol over 15 minutes. Then heat the reaction mixture for 4 hours at a temperature of 170 ° -175 ° C, where the water is removed by distillation. After cooling to 1000 ° C, Xylene and water were added, and as a result, the mixture was acidified with a 15% aqueous solution of hydrogen chloride; the organic phase layer was separated and washed with K water, and then concentrated. The crude product remained The product was recrystallized from methanol to obtain 82 g of the title compound, which was a pale yellow solid. Melting point: 124-1251. Example 5 5 —Benzenesulfonyl-2- (2-hydroxy-3-α-cumyl) Preparation of 5-tert-octyl.phenyl / ¾-2 fluorene-benzotriazole-A 1000 ml flask containing 75.2 g of 5-phenylsulfan-2- (2-hydroxy-3-α- Fluorenyl-5—tert-octyl—printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page)) —2fluorene-benzotriazole (prepared in Example 4) , 102 grams of xylene, 9 grams of sodium tungstate dihydrogenate and 18.4 grams of formic acid. Heat the mixture to 50 ° C, and slowly add 36.3 grams of 50% Hydrogen oxide, so that the temperature does not exceed 85Ό. Then add additional xylene and water, separate the organic phase layer 'and wash once with sodium sulfite, then wash twice with M water, and finally concentrate. The crude product is made from A-64-paper Zhang scale is applicable to Chinese National Standard (CNS) Λ4 specification (210 X 297 male thin > 4 6 7 93 A7 B7 V. Description of the invention () Recrystallization in alcohol, but 75 · 2 g of the title compound * which is a pale yellow solid, melting point: 170-171 ° C. Example 6 5-Nonylthio-2-(2-hydroxyfluorene 3-oc -cumyl-5-tert-octylbenzene /)-2 fluorene-benzotriazole was prepared according to the procedure of Example 4 * from 30 grams of 5-chloro_2- (2-hydroxy-3-α-fluorenyl-5 -t-octylphenyl) —2Η—benzotriazole and 1 7 * 6 g of nonyl mercaptan to prepare the title compound. (谙 Please read the precautions on the back before filling this page) 醯 .'y ((基基 〆 '" 7 // 玫瑰 例 I 辛 实 5_ 2 Η 2 II 5-基 枯 I α-备 3 制 1 Oxazolyl-triphenylenesulfonyl} nonylbenzene. I group 5 octyl tertiary 2 hydroxy 1 2 5 I hydrazone I α oxazotriacene 1 Η 2 No preparation of Urr 6 I Example 3 For the oxidization of hydrogen's methacrylic acid% 7 ο. 5 8 of the use of gram to make 6 times. Case 7 of case 1 of the pentanoic acid in the hydrogenated hydrogen disulfate pure gram 7 economic. Which central Standard Bureau employee consumer cooperatives printed m for product ion lipolipid color yellow for its chemical composition. Preparation 1 K 3 »6 0 e Example 5 nitrogen nitrogen 2 I 5 I phenylbenzene 3 I hydroxy The prepared azole triacene paper paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2IOX: 297 mm) 467 93 'Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and printed by the Consumer Cooperative Λ7 _________________ 5. Examples of the invention () Use examples 1 steps a and b, the title was prepared from 4-nitro-2-nitroaniline and 2-phenyl-4-tert-octylphenol An intermediate of the nitrogen compound of the compound. The crude product was recrystallized from methanol to obtain a dark red monoazo adduct. This title compound was obtained from 65 g of the above mononitrogen adduct according to the procedure of Example 3. 1.9 g of sodium hydroxide and 2.4 g of 2,3-difluoro-1,4-naphthoquinone were prepared. The crude product was purified by chromatography on silica gel (hexane: ethyl acetate, 5 : 1), which can be obtained mainly by the title compound, its molecular ion m / e = 43 3. Example 9 5 -Bentylsulfur 2_ (2 -hydroxyl 3 -benzyl 5 -tert-specific Phenylphenyl) _2H —benzotriazole. The title compound can be prepared according to the procedure of Spring Example 4. 20 g of solid compound 8, 20 ′ 4 g of 45 sodium hydroxide aqueous solution, and 10 g of 3 g. It was prepared from thiophenol and 100 g of copper N-methylpyrrolidine. The title compound was purified by chromatography on silica gel (eluent: toluene) as an oil. Preparation of 2- (2-Ethyl-3-phenyl-5-tert-octylphenyl) and 2-H-benzotriazole This title compound can be prepared from 20 g by using the procedure described in Example 5. real -66- Zhang's scale is applicable to Chinese National Standard (CNS) Λ4 specification (2! 〇 > < 297 mm) ~ '(Please read the precautions on the back before filling in' Write this page j Order Λ7 467932 ____ B7 V. Description of the invention () (Please read the precautions on the back before filling out this page) 9 compounds, 6.4 g of formic acid, 15.0 g of 50% hydrogen peroxide and 0.6 g of tungstic acid di Obtained from sodium hydrogen acid. 2.5 g of the crude product was recrystallized from dimethylbenzyl alcohol / methanol to obtain 2.0 g of the purified title compound * as a pale yellow powder, melting point: 204-206D. Example 1 1 5 ~ " Chloro-2- (2-hydroxy-3 * 5-dialkylphenyl) _ 2 fluorene-benzotriazole (fluorenyl groups are unrelated to C *, C8, C i 2 # C: s) Preparation of mixture-65.4 g of 5-chloro-2- (2-hydroxy ~ 3,5-dialkylbenzyl) ~ 2H_benzotriazole, 45 ml of twelve Ethylene and -..., the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed 13 ml of a methanesulfonic acid mixture, heated it to a temperature of 170 ° C under a nitrogen atmosphere, and added it in 4.5 hours. 135 ml of the twelve hydrazone reaction mixture was cooled to 100 Å, and then quenched with 400 g of crushed ice * and extracted twice with ethyl acetate. Combine the organic phase layers, rinse with K water, aqueous sodium bicarbonate solution, water and M water *, dry over anhydrous magnesium sulfate, and finally concentrate. The polymerization residue M ball-to-ball distillation was removed under vacuum at a temperature of 0.2 mm and a temperature of up to 210 ° C. Distillation (0 · 0 1 mm • 1 S 0 ° C) then removed the unreacted starting material | 45 g of the title warm compound were obtained as a yellow oil. Example 1 2 5 -Phenylthio-2-(2-Hydroxy-3 * 5, dialkylphenyl) -67- This paper size applies to China National Standard (CNS) A4 (210 X 297 cm) Α7 Β7 467932 V. Description of the invention () Preparation of 2H-benzotriazole (C4, Ca, Cl2 and C i S) mixture (please read the notes on the back before filling this page) It was prepared according to the procedure of Example 4 using 40 g of the mixture of Example 11 and 1 1.2 g of potassium hydroxide and 12.3 ml of thiophene. Example 1 3 5 -Polybutene-2-(2 -Cyclo-3,5 -dialkylpyryl-1 2H -benzotriazole (alkyl groups are C4, C8, C12 and

Printed by the Employees' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs—Contains a mixture of Example 12, 350 ml of isopropanol, 14.7 ml of formic acid and 1.8 ml of sulphuric acid, heated to reflux temperature, and the method of M droplet 30 ml of 50% M peroxide was added over 2 hours. After refluxing for another 3 hours, the reaction mixture was cooled and 10% aqueous sodium phosphite solution and aqueous sodium bicarbonate solution were added. Isopropanol was evaporated off, the residue was extracted with methylene chloride, the organic layer was washed with water, and then dried over anhydrous magnesium sulfate. The resulting solution was reduced in size to leave 45 g of a crude product as a viscous orange oil. Approximately 30 grams of this crude product was purified by chromatography on silica gel (heptane: ethyl acetate, 4: 1) to give 28.9 grams of the title mixture as a yellow oil. Example 1 4 5 —Diphenylphosphonium — 2 — (2 —Hydroxy-3,5 —tert-butylbenzene_ 6 8-This paper size applies to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) Economic Printed by the Consumer Standards Cooperative of the Ministry of Standards of the People's Republic of China 4 6 7 9 3 2 Λ7 Β7 V. Description of the Invention (2)-2H-benzotriazole in a flame-dried 500 ml, equipped with a condenser, magnetic search and mixing Into a three-necked round-bottomed flask with a decoupling device, filled with 100 ml of dimethyl methylene chloride, 7.41 g (0.066 mol) of t-butyric oxide and 1 1 · 7 g (0.060 mol) of diphenylphosphine. A solution containing 10.56 g (0 030 mol) of 5-chloro-2- (2-hydroxy-1,3-di-tert-butylphenyl) -2H-benzotriazole in 50 ml of The dimethylimide® mud was added all at once to this red mixture. As a result, the brown solution was stirred at 1 3 5¾ for 3.5 hours * and then cooled to room temperature. The mixture was quenched with a portion of a saturated ammonium chloride solution, and then ethyl acetate was added. Separate the organic phase layer * and wash with K water twice, rinse with brine once, then dry with K anhydrous magnesium sulfate, and then add a 50% aqueous hydrogen peroxide solution to this solution. * Addition will cause exothermic results, and then The mixture was left for 30 minutes, washed once with M10 sodium metabisulfite, twice with saturated sodium bicarbonate solution, and once with brine, and finally dried over anhydrous magnesium sulfate. The mixture was filtered with a silica gel plug, and the solvent was filtered. Removal under reduced pressure gave 8 * 0 g of a crude yellow product. The crude product M was subjected to a pressure analysis method and treated with heptane: acetamidine acetate (1: i) to obtain 4.2 g (27¾ yield) of the title compound 'as a yellow solid with a melting point of 98-100 ° C. Example 1 5 5 -Diphenylphosphine brewing 2-(2 -hydroxyl 3 -α -fluorenyl 5--69- This paper size is applicable to China National Standard Apple (CNS) Λ4 specification (210X297 mm) (please Read the precautions on the back before filling in this page). 〒 Order 467932 Α7 Β7 V. Description of the invention () tert-octylphenyl) 2H_benzotriazole According to the steps of the actual fluorene 14, use 5-chloro-1 The title compound was prepared from 2- (2-hydroxy-3_α_cumyl-5-sylo-octylphenyl) -2H-benzodiwa as the starting benzotriazole intermediate. Example 1 6-2 6 According to the general procedure of Example 1, the following 2 ， -benzotriazole of formula 1 'can be prepared as follows: Example G 2 E j Ε ζ (Please read the precautions on the back before filling in this Page) Printed by the Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs 1 6 CF 3 Phenyl-tert-octyl 1 7 CF 3 a —Cumyl-tert-butyl 1 8 C Ν α-Cumyl-tert-octyl 1 9 C Ν a — cumyl nonyl 2 0 C Ν a mono cumyl tert-butyl 2 1 C 0 0 C Η 3 a — cumyl dodecyl 2 2 F phenyl tert- octyl 2 3 CF 3 a — Cumyl nonyl 2 4 CF 3 a — cumyl dodecayl 2 5 C 0 Ν (Bu) ZA — cumyl tert- octyl 2 6 C 0 0 C Η 3 phenyl tert- octyl- 70 This paper size applies the Chinese National Standard (CNS) A4 specification (2 丨 〇 X 297 mm) 67 93 2 A7 B7 V. Description of the invention () Example 2 7 5 —Octylsulfur—2-(2 -Control group one 3 — α —Cumyl — 5 —Syl-octylphenyl) —2′-Benzotriazole was prepared using the procedure of Example 6 from 5-chloro-1 2 _ (2-Hydroxy-1, 3-Oc-cumyl-5, Sy-octyltrityl;) A 2-pyrene-benzotriol and octyl mercaptan to prepare the title compound. Example 2 8 5 —Octylsulfonaminium 2 — (2-hydroxy-3-O (_cumyl-5 —t-octylphenyl) — 2 fluorene —benzotriazole Prepared according to Example 27 5-octylsulfan-2- (2-hydroxy-3 -cc-cumyl-5-tert-octyl: phenyl) -2fluorene-benzotriazole was oxidized to boron using the general procedure of Example 7 without purification The title compound was prepared in the case of a thio intermediate. Example 2 9-5 —Chloro-2- — (2 * 4 -dihydroxybenzyl) — 2Η —Pentatriazole Printed by the Consumer Cooperative of the Central Standards Bureau, Ministry of Economic Affairs ( (Please read the precautions on the back before filling this page). The preparation is based on the steps of Example 1, parts a and b. The monoazo intermediate of this title compound can be 17.3 g of 4-chloro-2-nitroaniline. 3 4 · 7 g of dark red monoazo addition product were obtained, which was a moist cake. Reduction reaction of monoazo adducts ^ A mixture • containing 20 g of sodium hydroxide, 500 ml的 水 -7 1-This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 4 6/9 3 2 Λ 7 Β7 Staff Consumption of the Central Standards Bureau of the Ministry of Economic Affairs The company printed five, description of the invention () and 26.3 grams of the above monoazo addition wet cake, add it to 30. Add zinc powder (33.0 grams) within two hours, after the addition is complete 180 g of a 40% aqueous solution of sodium hydroxide * were added as droplets within 1 hour and the mixture was stirred at room temperature for 96 hours. The zinc residue was removed by filtration, and the aqueous solution was then neutralized to form PΗ 5-6, and the result was mud. As a result, the cake K was washed and washed with water and bottom, and 2 2 · 5 g of crude product was obtained after drying. The crude product M acetone * was purified by S ο X h 1 et extraction method. 9.6 g of the title compound are obtained. Preparation of a mixture of 3 0 5-chloro-2- (2-hydroxy-4-octyloxyphenyl-2 fluorene-benzotriazole, including 6.5 g of 5-Chloro-2— (2,4-dihydroxyphenyl) —2Η—benzotriazole, 7.1 g of 1-bromofb octane, 5 * 2 g of anhydrous potassium carbonate and 100 ml of propylene _, Reflux it for 24 hours. To this result mixture was added about 1 ◦ 0 ml of water and ethyl acetate, and then 10 * 6 g of crude product was separated. Using petroleum ether tube to chromatography, can 0 * 9 g of the title compound, the structure of which is consistent with Hnmr and mass spectrum. Example 3 1 • / 5 -trifluoromethyl-2-(2,4-dihydroxy'phenyl,) -2H-benzotriazole Preparation of -72- (Please read the precautions on the back before filling out this page), 1Τ i β. This paper size is applicable to China National Standard (CNS) Α4 size (210 × 297 mm) Λ7 Ministry of Economic Affairs' t Central Standards Bureau Printed by employee consumer cooperatives 4 6 7 S 3 2 B7 V. Description of the invention () Steps according to actual conditions 2 9 > The title compound can be made from 13 g of 4_amino-3 -nitrobenzotrifluoride 6.4 g of the title compound were obtained, the structure of which corresponds to Η nmr. Spring Example 3 2 5 —Trifluoromethyl-2 — (2-hydroxy_4-octyloxyphenyl) — 2 fluorene —benzotriazole This title compound can be prepared according to the procedure in Example 30 by 5. · 6 grams of 5-trifluoromethyl-2— (2,4-dihydroxybenzyl) —2Η-benztriazole. The crude product was purified by column chromatography to give 1.1 g of the title compound as a white solid, mp 79-81, ° C. Its structure is consistent with Hnmr and mass spectrometry. Example 3 3 5 —Tri-gasification of methyl 2-[2-hydroxy_4_ (3-butoxy-1 -hydroxypropyloxy) phenyl ^]-2 fluorene-Benzotriazole Preparation of a mixture containing 2 · 3 g of 5-trifluoride. Methyl-2-(2,4-dihydroxyphenyl)-2Η-benzotriazole (prepared in Example 31 1), 13 ml of butylepoxypropyl ether And 100 mg of ethyl triphenylphosphine desert was dissolved in 50 ml of xylene. The mixture was heated under reflux under a nitrogen atmosphere for 14 hours. Water (25 ml) and 25 ml of ethyl acetate were added to isolate 3 g of the crude product. After recrystallization from heptane, 2.1 g of the title compound was obtained, and its structure was consistent with Η n m r. -7 3- This paper size applies to Chinese National Standard (CNS) A4 (210X 297mm) {Please read the precautions on the back before filling this page)

467932 A7 B7 Yu V. Description of the invention () Example 3 4 5 —Trifluoromethyl-1 — 2 — (hydroxyl 4 -aminophenyl J) _ 2 Η ~ Benzotriazole Preparation This title compound can be prepared It was prepared according to the procedures of Examples 1 and 29 from the starting compound 4-monoamino-3-nitrobenzotrifluoride and 3-aminophenol. The structural formula of the product is in accordance with the examples. 3 5 5 -Trifluoromethyl- 2_ [2-hydroxy-1 4-(4-ethylhexylamino) phenyl] -2H -benzotriazole Preparation 4 g 5 _Trifluoride (methyl-2- (2-hydroxy-4aminophenyl)-2H-benzotriazole and 1.4 g of triethylamine in 75 ml of toluene mixture A mixture containing 2-2: hexamethylene chloride dissolved in 125 ml of toluene was added. As a result, the mixture was treated with 10 ml of water, and the resulting crude product was purified by column chromatography to obtain 1 9 g of the title compound, melting point: 179 —. Its structural formula is consistent with the NMR spectrum. Example 3 6 5-Carboxymethoxy- 2-(2-hydroxy-3-ot-fluorenyl-octyl pen, hydrazone -2 Preparation of pyrene-benzotriazole a) Esterification of 4-amino-3-nitrobenzoic acid-74-. This paper size is applicable to China National Standard (CNS) A4 specification (210'〆297 mm) (Please read the notes on the back before filling out this page) •-° Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5 467932 Λ7 B7 Printed by the Central Government of the Ministry of Economic Affairs i Consumer Cooperative

V. Description of the invention () 1 1 i Add '! 700 ml of methanol 9 2 g of xylene > Concentrated sulfuric acid and 1 I 100 g of 4-amino- 3 nitrobenzoic acid. Heating solution under reflux Please first cool the mixture to 3 5 3 hours and neutralize to P Η value 7 0 read Back | 1¾ 1 Add water (1 liter) »Collect the solid product and vx 500 ml of water for washing and pouring. After drying overnight, you can get 10.0 g of methyl 4-amino ~ 3 mononitrate. Matter 1 I re 1 \ Benzyl benzoic acid 0 Fill in b) Methyl 4-Amino-3-Nitrobenzoic acid diazotization page > — II to — 1 liter i 3 — Neck one device Into a mechanically stirred flask, 1 1 1 7 7 g of 96% sulfuric acid was added. Slowly add 1 1 1 1 g of sodium nitrite over 90 minutes. Add the hydrazone mixture to 3 0 > λ. Start the reaction and keep the temperature below 7 0 t: 〇 Then £ P m Compound to 1 5 X: and 30 grams of methyl 4 —amino — 3 —nitrobenzoate are added within 2 hours and 1 I of period 1 1 | between 1 5 — 2 0 t: Cool the mixture to 0 r: > and add 1 1 into 2000 g of ice to make this solvent suitable for the coupling reaction K to DPT 単 azo 1 (compound 0IC) single I. nitrogen M-. Gong 1 1 in a 2 liter 3 —m and equipped with a mechanical stirrer and a funnel to add a 1! I bottle is added V 5 2 grams of 2 —α-cumyl — 4 tert. Monooctylphenol> 2 〇1 grams of water 1 3 1 5 grams of methanol * 7 grams of dimethylbenzyl and 150 grams of hydrogen! Sodium oxide 〇 The mixture was cooled to-5 t: t and under cooling for 2 hours The temperature of the diazonium salt solution f obtained in step b) added during 1 I was kept below 3 1 1 〇 After the diazonium toilet solution was added, the P Η value was adjusted to 6 4 5 — 1 75-one one-I Paper size applies Chinese National Standard (CNS) Λ4 specification (210X297 mm) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 67 93 2 V. Description of the invention (). 7 · 0, pour the mixture into 500 ml of xylene And K500 ml of water under 60t; wash and irrigate twice. The xylene was removed by distillation to obtain 186 g of a monoazo adduct containing residual xylene. d) The hydrazone reaction of the nitrogen adduct is added to a 500 ml flask equipped with a mechanical stirrer, and 186 g of the monoazo adduct prepared in step c) is added, 125 g of 2-butane. Alcohol and 1.7 g of 2,3-digas-1,4 ~ perylene. The mixture was heated to 90 ° * and the resulting solution was added to an addition funnel on a different flask. In a second flask, 175 g of 2-butanol and 18.6 g of sodium oxide were added. The flask was heated to 95 ° F, and the monofluoride nitrogen was added within 2 hours, during which time it was distilled off at the same time. Methyl ethyl ketone and 2-butanol. Add 2-butanol (100 g) * and distill off the azeotropic mixture. The mixture was then cooled, and 300 g of xylene and 200 ml of water were added. 20% sulfuric acid adjusts the pH to 7-7 · 5. At 6002, the aqueous phase was separated, the organic phase was washed twice with 200 ml of water, and the xylene was removed by distillation. The residual bamboo formed was crystallized from methanol * to obtain 8'8 g of the title compound. Melting point: 141 — 143Ό 〇 Example 3 7 5-[N 'N-di-n-butyl-carbamidine-2-(2-hydroxy-3 -α-fluorenyl-5 -t-octyl) phenyl] -2H -Preparation of benzotriazole-7 6 — This paper size applies to the Chinese national standard (<: milk) 6 4 cells (2! 0 \ 297 gong) (Please read the notes on the back first and then Γ ' " This page) equipment ', 1T 467932 Λ 7 Β7 V. Description of the invention () a) 5 —Carbonmethoxy — 2 — (2 —Hydroxy — 3 — ct —Cumyl — 5 (Please read the pit on the back first) Please fill in this page if you want to know) 1 t-octyl benzyl) 2 2 Η —Saponification of benzotriazole in a 250 ml 3 -neck and equipped with a mechanical stirrer, thermocouple * condenser and nitrogen inlet pipe Add 1-8 grams of potassium hydroxide and 40 ml of methanol to the flask. The mixture was heated to 40 M to dissolve potassium hydroxide ib * and to this solution was added 2.7 grams of 5 -carbomethoxy-2-(2-hydroxy-3- ct -cumyl-5-tert-octyl Phenyl) -2H-benzotriazole (prepared in Example 36) was dissolved in 40 ml of a methanol solution. The reaction mixture was heated at reflux for 6 hours | Then the mixture was cooled and the mixture was acidified with HCl. Ether and ethyl acetate were added, and the organic layer was separated and dried over anhydrous sodium sulfate. After stripping the solvent in vacuum, 2.5 g of 5-pyridyl-2 — (2-pyridyl — 3 — ot —cumyl — 5 —tert-octylphenyl) —2Η-benzotriene can be isolated. Azole. b) 5-Carbonyl chloride 2- (2-hydroxy-3. — α-fluorenyl-5 5-tert-octylbenzyl) _2fluorene-benzoxazole Step a) Preparation of 2.5 grams of 5-carboxyl— 2 — (2 —Hydroxy — printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs — 3 —α —cumyl — 5 —tert-octylphenyl) — 2Η—benzotriazole placed in a 250 ml device with Stirrer, thermocouple, reflux condenser, Dean-Stark trap and flask with nitrogen inlet. Toluene (100 mL) was added and the mixture was refluxed to remove any remaining water. The mixture was then cooled and added with 15 ml of ethylenedichloride. Slowly heat the reaction mixture to 60 ° C, and maintain it at 60-6 5 ° C for 8 hours until chlorinated-Ί Ί ~ This paper size applies Chinese National Standard (CNS) A4 specifications (2IOX297 public trend) 6 4 Ministry of Economic Affairs "7 ^ 32 a 7 _B7____" printed by the Central Standards Bureau's Consumer Cooperatives V. Description of the invention () The hydrogen can be discharged to obtain the title compound of the acid-flavored compound. c) 5-[N * N—Di-n-butyl carbon to 2— (2-hydroxy-3—α—cumyl—5—tert-octyl) phenyl] _2Η—benzotriazole in one 5 0 liter device has a mechanical stirrer, a drying tube, a thermocouple and a drop funnel flask filled with 0.8 grams of di-n-butylamine. 6 ml of pyridine and 25 ml of toluene . The mixture was cooled to OTC, and the acid-aqueous solution prepared in step b) was placed in a dropper and within 30 minutes, and added to the reaction mixture at a temperature ranging from 51C to 1 °. The reaction mixture was stirred at this temperature for 1.5 hours * and then kept at room temperature overnight. The warm compound was filtered and then vacuum stripped to give 3'0 g of crude product as a solid. Chromatography of this solid product gave 1.2 g of the title compound as a beige solid, melting at 1 3 1-1 33C. The structure is consistent with nmr and 霣 spectrum m / z596. Example 3 8 5-trifluoromethyl- 2- (2-hydroxy-5-tert-octylphenyl)-2 fluorene-benzotriazole This title compound can be prepared from 4-amine according to the procedure of Example 1 The reaction is based on the reaction of the radical _3 mononitrobenzotrifluoride with 4-tert-octylphenol, which is prepared after purification on silica gel. The product was recrystallized from heptane or methanol 'to give a nearly white title solid compound with a melting point of 80-8. _ 7 8-This paper size is in accordance with Chinese National Standard (CNS) Α4 size (210x197 ^) (please read the following ^ items before filling out this page) ", 11 Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 467932 Λ7. B7 V. Description of the invention () Application example 3 9 In order to determine the heat-durability of 2 fluorene-benzotriazole UV absorbers for high solidity thermosetting acrylic coatings, which are substituted by different electrons and electron groups. The following tests were carried out for the effects of properties and loss rate. A high-solids thermosetting acrylic resin transparent coating is prepared by mixing experimental grade acrylic polyol resin and hexamethoxymethylmelamine (Resimene® 747, Monsanto) in a solid ratio of 60/40. Add 0.70% by weight of + benzene sulfonic acid catalyst (hcure® 5 2 2 5; King Industries) and 0. 25% by weight of flow aid Modaflow® (Monsanto) to form a standard System of acrylic melamine resin.

This standard clear coating reduces the viscosity with xylene to 2 6 — 2 7 seconds (using a Zahn # 2 cup), and then via a conventional air spray (50 psi (3.5 kg / cmz)) at: 1 " x3 " (2. 54 cm X 7 * 62 cm) on a quartz plate. This quartz plate was bake hardened at 260 ° F (1271) for 30 minutes. This transparent coating is a 1% by weight sterically hindered amine light stabilizer, bis- (1 -octyloxy_2,2,6,6-tetramethyltonidine_4 -yl) decanoate ( TINUVIN® 123, Ciba-Geigy). Various test benzotriazole UV absorbers were added to this transparent coating at 5 millieurs weight percent, and the thickness of the film on the quartz plate was from 1 '15 to 1 _41mi 1 (0 * 029 to 0' 036mm). The film on the quartz plate is in a Xenon Arc Weather-Oraeter-79- This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (21〇ϋ Splash) (please read the precautions on the back before filling in this page) ./ k. Ding-'s 467932 Λ 7 Β7__ 5. Description of the invention () According to the following conditions, the controlled ray intensity of 650 watts' and the internal quartz and external brominated silicate S-type chirped mirror Weathering test. The irradiation cycle is as follows: 40 minutes of strong irradiation without water spray 'followed by 20 minutes of light irradiation plus water in front, followed by 60 minutes of light irradiation' in the last 60 minutes of darkness plus water in the back (Condensation) 'The setting value is 0' 5 5 W / m 2 (3 4 0 nm) '1 · 98 仟 Joules / hour. During photoperiod irradiation, the temperature of the blackboard is controlled at 70 ± 2Ό and the relative humidity is 50 — 55%, and 100% after the dark period. The absorption of long-wavelength UV bands (as a function of xenon arc weathering hours) is recorded in the table below. In order to determine the UV absorber from the transparent coating Loss' is measured at the beginning and at regular intervals after the weathering test. The UV spectrum is measured. This UV light The spectrometer uses a reference beam attenuation technique to measure linear absorption up to 5.5. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 11 (Please read the precautions on the back before filling this page) Assume that the product is produced by Degradation in the UV absorber has no effect on the UV spectrum * and it is tested by the ratio of absorption in the approximately 300 nm spectral band and absorption in the approximately 300 nm spectral band. This ratio does not affect the weathering test samples. Will change, which means that the UV spectrum after the weathering test is equivalent to the amount of UV absorber remaining in the film, and even if the photodegradant has any effect on the spectrum, its value is very small. The data in the following table is based on the structural formula A After 1 2 1 hours of transparent coating with test benzotriazole UV absorber: The unit absorption loss of the compound G2 R 1 R 2 -8 〇- This paper size applies Chinese National Standard (CNS) Ad specifications (21 OX297) 467932 Λ7 B7 V. Description of the invention () Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A 1.7982 Hydrogen-P 0 (0 E t) Z Syrian-octyl B 1.6 3 0 0 -Octyl C 1.486 3 phenyl-s--tert-butyl-CHz -CHZ COO C8 Η! 7 D 1.4 0 0 2 Hydrogen-CHz -CH2 COO ch3 E 1,1872 methoxy-tert-butylmethyl F 0.5259 hydrogen G 0 · 4 5 2 7 Hydrogen C (-cumyl hydrazone 0.4420 Hydrogen tert-butyl-CHz -CH2 COO Cs Ht 7 I 0-4299 Hydrogen tert-octyl ct-cumyl J 0.4134 Hydrogen-octyl-octyl κ 0.3777 hydrogen Tert-octyl tert-octyl L 0.3712 hydrogen tert-butyl-cm ch2 M 0.3433 M CC -cumyl-CHz CH2 COO- ch3 S 0.3098 nitrogen tert-butyl-t-butyl 0 0.2689 phenyl-S 02 -Uncle_ Ding: S -CH2 CHz CO Ca H i 7 P 0. 2 5 7 8 Hydrogen CC -cumyl cc -cumyl-8 1- (Please read the precautions on the back before filling this page) --- --1 order—— j --- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 male 埯) 4 6 7 93 2 Λ 7 Β7 V. Description of the invention () Q 0.2 4 9 2 Hydrogen α- 祜Tert-octyl (please read the precautions on the back before filling out this page) View these data for the light stability of 2 Η-benzotriazole UV absorbers and the properties of qualitative substituents that can affect the light spike can get some clarity Conclusion. When Ri is C (monocumyl or phenyl and G2 is an electron-drawing group (such as phenylsulfonyl or gas group), the photostability can be increased. The properties of the group of TR2 are for benzotriazole UV absorbers. The effect of light stability is small. From these observations, it can be concluded that the ideal benzotriazole UV absorber can theoretically be designed such that G2 is an electron-drawing group, Ri has a sufficiently large volume * and R2 is a heat A stable group. This ideal compound is a benzotriazole in which G2 is phenylsulfonyl * is £ -fluorenyl and R2 is tert-octyl. This monobenzotriazole has been generally applied In U.S. Patent No. 5,280 * 1 24. Example 4 under M will confirm that the Central Bureau of Standards of the Ministry of Economic Affairs has printed this work—a hypothesis, and that this idealized compound is more accurate than the current technical compound. There is a very low loss rate. Example 4 ◦ According to the procedure of Example 3 9, many other benzoxazole test compounds were added to the high solids thermosetting acrylic melamine resin. The concentration range was 193 and 3%. Between weight percentages, a uniform thickness can be obtained-8 2-this paper size Applicable to China National Standard (CNS) Λ4 specification (210 × 297 mm) 4 6 7 93 2 Λ7 137 V. Description of the invention () Testing of benzotriazole with equivalent molar concentration in degrees, and sufficient to give an initial absorption value of about 2 · 0 units. The test disc is placed in a Xenon-Arc Weather-Oraeter, MX180 cycle (0 · 45 Watt / meter 2) exposure, and the initial UV absorption measurement is approximately every 200 hours before. 250 hours, and every 500 hours thereafter. Each transparent coating also contains 1% by weight of cholestyridine, bis (1-octyloxy-2 * 2 * 6, 6-tetramethylpyridin-5-yl) sebacate. The data in the table below are based on exposure to a transparent coating containing the test benzotriazole UV absorber after 1 2 5 3 hours for the compound of formula A (式(Read the notes on the back before filling out this page)

I compound absorption loss per unit G 2 RXR 2 R 0.2424 hydrogen, radical 〇t _cumyl Q 0.2351 hydrogen α " cumyl • · tert-octyl S ~ 0.1271 cf3 α-fluorenyl tert-octyl T 0.1827 benzyl- S02 tert-butyl tert-butyl Ministry of Economic Affairs Central Standards Bureau Offset Consumer Cooperative Co., Ltd. The data in the following table is based on the formula after 1 4 8 9 hours of exposure to a transparent coating containing a test benzotriazole UV absorber. A compound compound unit absorption loss G2 R t R 2 -83- This paper size applies to Chinese national standards. (CMS) A4 size (210 X 297 mm). 467932 Λ7 B7 V. Description of the invention () R 0.3724 Hydrogen phenyl α -Fluorenyl Q 0.287 hydrogen α -cumyl tert-octyl S 0.1547 CF3 α -fluorenyl tert-octyl T 0.2654 phenyl-S 〇 2 tert-butyl tert-butyl The following data is based on exposure test Transparent coating of benzotriazole UV grazing agent 2 5 1 The compound of formula A after 2 hours (read on the back: read this matter and fill in this page) Compound unit absorption loss G z RXR 2 0.4824 Hydrogen A-cumyl Q. 4 0 5 4 hydrogen (X-cumyl tert-octyl 0.2192 cf3 Cf- Tert-octyl Q. 3 5 7 0 phenyl-S〇2 tert-butyl tert-butyl v Γ · * II II ···--I--m ^ i,-° Central standard of the Ministry of Economic Affairs Printed by the Consumer Cooperative of the Bureau. It can be clearly seen from the three tables on K that the compound S with an electron-drawing group at the 5th position of the pyrene benzo ring, especially the benzo that does not carry the group on the benzo ring. Triazole has better persistence. The data in the table below is based on exposure to the test containing benzotriazole UV absorber-84- This paper size applies to China National Standard (CNS) A4 (210X 297 mm) 467932 Λ7 B7 5 2. The transparent coating of the invention (1) The unit absorption loss of the compound of the compound of formula A after 1 2 6 4 hours G 2 R 1 RZQ 0.2 2 9 3 hydrogen cx -fluorenyl tert- -octyl S 0 .0 9 2 1 C f3 a -fluorenyl tert-yl T 0 .1965 phenyl-S〇2 tert-butyl tert. Butyl U 0 .0 9 4 4 Benzyl_ S〇 2 α-cumyl tert-octyl V 0 .1719 Chlorine α-fluorenyl tert-octyl W 0 .16 5 5 Fluorine Of -fluorenyl tert-octyl X 0 .1796 Hydrophenylphenyl tert-octyl (Read the precautions on the back before filling this page )---- *- ----—----- —-'- "--------__. The consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs has printed the following data. The transparent coating of the azole UV absorber 1 5 1 8 hours after the absorption loss of the compound of the formula A compound G2 R 1 R 2 0.2662 hydrogen 〇--taucusyl tert-octyl 0.1116 CF3 Cf -fluorenyl tert-octyl 0. 2 4 2 3 Phenyl-S 02 tert-butyl tert-butyl 0.1114 phenyl-S 02 α-fluorenyl tert-octyl-85- This paper size applies Chinese National Standard (CNS) Λ4 specification (210X297 (Public) 467932 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Λ7 B7 V. Description of the invention () V 0.1955 Chlorine «-fluorenyl tert-octyl W 0.1668. Fluorine α _cumyl-octyl X 0.2 2 2 0 Hydrophenyl-tert-octyl The table above clearly shows benzotriazole substituted on the benzo ring via an electron-drawing group, especially one substituted with methyl trifluoride or phenyl-sulfonyl, The rate of loss of absorption value after actinic radiation exposure is very low and is therefore particularly persistent. The compounds S * U, V and W are particularly persistent and fit the above assumptions. The fact that the compound u is predicted to be particularly durable is due to the above data. Examining these data also shows that there are effective volume substituents at the R i position. Compounds 7 and U, such as α-cumyl, have better fluorenyl substituents at this position, and compounds like tert-butyl have better results. (Read the note on the back before filling in this page)

T -86- This paper size is applicable to China National Standard (C'NS) Λ4 specification (210 X 297 mm)

Claims (1)

announcement 6 7 9 3 2 | D8 Γ The scope of patent application 1 · A benzotriazole-stabilized coating composition. The benzotriazole has improved durability and low loss rate when added to the coating. The composition includes: (a)-a resin selected from the following groups: thermosetting acrylic melamine resin, acrylic urethane resin, epoxy carboxyl resin, silane modified acrylic melamine, and having a urethane side chain Acrylic resins crosslinked with melamine, or acrylic polybasic resins crosslinked with melamine groups having urethane groups, and (b) 0 0 1 to 5% by weight (calculated based on resin solid content) A 'benzotriazole: (Please read the notes on the back before filling this page) Λ 0H r2 (Ar) order --------- line · Printed by the consumer cooperation of the Intellectual Property Bureau of the Ministry of Economic Affairs where G2 is fluorine, cyano * R3 S 0 2-> c F -COO — G 3 or — CO — N (G 3) G 3 is an alkyl group of 1 to 12 carbon atoms, -1-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 467932 A8 B8 C8 D8 Six The scope of patent application R! Is argon, an alkyl group of 1 to 12 carbon atoms, phenylalkyl group of 7 to 15 carbon atoms, Rz is an alkyl group of 1 to 12 carbon atoms, or 7 to 1 5 carbon atoms phenylalkyl 'or one CH2 CH2 COQG4, where G4 is hydrogen: 1. to 12 carbon atoms alkyl, and R3 is 1 to 18 carbon atoms alkyl or phenyl, When the coating is exposed to actinic rays, this benzotriazole has improved durability and low loss rate, and it is less after 1 200 hours of exposure in a Xenon-Arc Weather -〇1 ^ 161 ' Loss of absorbing units at 0,22 'or less than 〇27 absorption positions after 1500 hours of exposure, or less than 0.40 absorption units after 2500 hours of exposure, provided that the benzotriazole Not a) 5.-positive-ten Alkylsulfonyl-2— (2-hydroxy-3,5—di-tert-butylbenzyl) —2H_benzytriazole; b) 5—n-dodecylsulfinyl-2— ( 2-Hydroxy-3,5-di-tert-butylphenyl) -2H-benzotriazole; c) 5-benzenesulfenamidine-2— (2—If group—3 * 5-di-tert-butyl Phenylbenzyl) -2H-benzotriazole; d) 5,5'-sulfofluorenebis (2- (2-hydroxy-3,5-di-tert-butylphenyl) -2H-benzotriazole ; E) 5 -benzenesulfonyl-2-(2-hydroxy-3-tert-butyl- 5-(2-octyloxycarbonylethyl) -phenyl-1-2H-benzotriazole; s) 3 — (5 —Cage obstacle_Tengyi 2 Η —Benzotrile 1 2 —.Base) 1 5 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back first Please fill in this page for more information) ^ --------- Order · -------- line v Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 4 6 7 93 2 Jaw C8 D8 VI. Patent Application Range—tert-butyl-4—hydroxyhydrocinnamic acid; h) 3— (5-benzenesulfonium—2H—benzotriazole—2 Yl) a 5 - a tert-butyl-4-hydroxy hydrocinnamate a mince amine. 2 'As the composition in the first item of the scope of patent application, wherein the compound of formula A' 1 2 3 4 Gz is fluorine, iS, R3 S〇2 —, CF3 —, —COO-G3 or —CO_N (G 3) 2, G3 is an alkyl group of 1 to 8 carbon atoms, Ri is hydrogen, benzyl or α-fluorenyl, Rz is an alkyl or phenyl group of 4 to 12® carbon atoms, and R3 is phenyl or 8 to 12 Carbon atom alkyl. 3 · If the composition of the scope of application for the second item of the * * wherein is phenyl — S〇 2 —, octyl — S 02 —, fluorine or CF3 — 'Ri is of — fluorenyl or ceryl, and Rz is. Tert-butyl or tert-octyl 0J, II — — I ^, --- I I-«— 111 — II —, (谞 Please read the notes on the back before filling this page) Intellectual Property Bureau, Ministry of Economic Affairs Printed garments by employee consumer cooperatives 1. If the composition of the scope of patent application item 1, the component (a 2) is a resin, which is a thermosetting acrylic melamine resin or an acrylic urethane resin. 3 • 5 · If the composition of item 1 of the patent scope is Φ, it also contains a 4 paper size applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) A8 B8 C8 D8 46793 2 6. Apply for a patent A phenolic antioxidant in the range ¥ 定. Selected from the following groups: n-octadecyl 3 ′ 5-di-tert-butyl-4-hydroxyhydrocinnamate, neopentane tetrayl tetra ( 3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid fluorene), di-n-octadecyl__3,5-di-tert-butyl-4-hydroxybenzylphosphonium phosphate, 1, 3,5-tris (3,5-di-tert-butyl-4 "transylbenzyl) isocyanurate, thiodiethylenebis (3,5-di-tert-butyl-4_ Hydroxyhydrocinnamate), 1,3,5-trimethyl-1,2,4,6-tris (3,5-di-tert-butyl-1,4-benzyl) benzene, 3, dioxa Octamethylbis (3-methyl-1,5-iso-butyl-4 monohydroxyhydrocinnamate) * 2,6 ~ di-tert-butyl-1ρ-cresol, 2,2,-ethylidene Bis (4,6-di-tert-butylphenol), 1, 3, 5- Tris (2,6-dimethyl-1,4-tert-butyl.yl-3 -hydroxybenzyl) isocyanurate, 1,1,3-tris (2-methyl-4, 4-hydroxy-1, 5-tert. Monobutyl-phenyl) butane, 1,3,5-di- (3,5-di-tert-butyl-4-alkyl via hydrogen: naphthyloxy) ethyl] isocyanuric acid Ester, 3,5-di- (3 '5-di-tert-butyl-4 4-hydroxybenzyl) succinol * hexamethylene bis (3' 5-di-tert-butyl-1 4-hydroxyhydrogenated cinnamon Acid ester)., 1— (3,5—di-tert-butyl-4—hydroxyaniline) —3, bis (octylsulfan) —s—triazine, n, N′-hexamethylene double ( 3 '5 -Di-tert-butyl-4-hydroxyl-cinnamonamine), bis (ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate phosphonium), ethylenebis [ 3,3-bis (3_tert-butyl-4_hydroxybenzyl) butyric acid-4 ^ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (谙 Please read the note on the back first Please fill in this page for more details) -------- Order ·! —----- Line · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 4 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 6 7 9 3 bs C8 D8 6. The scope of the patent application is cool, octyl 3,5-di-tert-butyl-4 4-hydroxybenzylmercaptoacetate, bis (3 , 5 _di-tert-butyl-4Hydroxyhydrogenated cinnamon hydrazone) — 醻 胼, and Ν, Ν ′ — bis [2 — (3,5 —di-tert-butyl-4_Hydroxyhydrogenated cinnamon hydrazone) Group) -ethyl] -oxamine. 6. The composition according to item 5 of the scope of patent application, wherein the phosphonium antioxidant is neopentane tetrayl tetrakis (3,5-di-tert-butyl-4-hydroxyhydrocinnamate) * n-18 Alkyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid, 1,3,5-trimethyl-2,4,6-tri (3,5-di-tert-butyl- 4-monohydroxybenzyl) benzyl, 1,3,5-tris (3,5-di-tert-butyl-4-hydroxybenzyl) isofluurate, 2,6-di-tert-butyl-ρ —Cresol or 2,2-ethylidene-bis (4 > 6-di-tert-butyl). 7. The composition according to item 1 of the scope of patent application, which further comprises an effective stable dose of amine amine * selected from: bis (2,2,6,6-tetramethylpiperidine-4-yl) decane Acid acid, bis (1,2,2,6,6-pentamethylmethylpyridin-4-yl) sebacate, bis (1,2,2,6,, 6_pentamethylpyridine-4 (1-yl) (3,5-di-tert-butyl-1, 4-hydroxybenzyl) butylmalonate, 4-benzidine-2,2,2,6,6-tetramethylcididine, 4- Stearyloxy-2,2,6,6-tetramethylpiperidine, 3-n-octyl-yl-7, 7'9 τ9-tetramethylammonium-1, 3, 8-diisopropylamine Spiral L 4, 5 -5- This paper size applies to Chinese National Standard (CNS) A4 (2i0 X 297 mm) II 1 '^ _ II ------------ I r (please first Read the notes on the back and fill in this page again) A8 B8 C8 D8 467932, patent application scope] undecane-2,4-dione, tris (2,2,6,6-tetramethylmethylpyridine-4-yl ) Triazine triacetate, 1,2-bis (2,2,6,6-tetramethyl-3-oxoprazine-4-yl) ethane, 2,2,4, Tetramethyl-7-gas, 20-diazine-2 1-oxodispiro [5 · 1.. 1 1 '2] pyridine, 2 dichloro-6-tert-octylamino-s-triazine And 4,4'-hexamethylenebis (amino-2,2,6,6-tetramethylpiperidine) condensation product, 1- (2-hydroxyethyl) -2,2,6,6-6 Polycondensation product of methyl 4 ~ hydroxy # pyridine and succinic acid, 4,4'-hexamethylenebis (amino-1,2,2,6,6-tetramethylpiperidine) and 1,2-di The polycondensation product of bromoacetamidine, tetrakis (2,2,6,6-tetramethylpiperidine-4-yl) -1,2,3,4-butaneamidinetetracarboxylic acid ester, tetrakis (1,2, 2,6,6 —pentamethyl'pentidinyl-4-yl) 1,2,3,4 ~ butanetetracarboxylic acid, 2,4-dichloro-6-morpholinyl-s-triazine and 4,. 4'_hexamethylenebis (amino-2,2,6,6-tetramethylpiperidine) polycondensation product, N, N '* N ", N "' — tetra [. (4, 6 —Bis (butyl-2,2,6,6—tetramethyl monotonic radical // 3, / 3, / ϊ '* β / —tetramethyl-1 3-9 — (2,4, 8, 10-tetraoxa [5. 5] Undecane) diethyl] 1,2,3,4 monobutanetetracarboxylic acid ester, mixed with [1 * 2,2,6,6-pentamethylpiperidine- 4-yl / / 3, / 3, called ', / 9'-tetramethyl- 3, 9-(2,4,8,10 -tetraoxaspiro [5.5] undecane) diethyl] 1, 2, 3, 4 —butanetetracarboxylic acid ester, octadecyl bis 2, 2, 6, 6 -6- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) --- -^ --- I ----- Order --------- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 4 6 7 93 2 VI. Scope of patent application—tetramethylpyridine-4 monocarboxylic acid), 4,4′-ethylenebis (2 * 2 * 6,6-tetramethylpiperazine 3- Ketone), N-2,2,6,6-tetramethylpiperidine-4 4-yl-n-undecylbutanestilamine, N 1,2,2,2'6,6-pentamethyl Iridine-4-yl-n-eleventh, ketidine-fujita Sit, N-1-ethen-2, 2, S, 6-tetramethylpiperidine-4 4-yl-n-dodecyl Succinimide, 1 Monoethylammonium 3-dodecyl-7,7 * 9,9 tetramethyl-1,3,8-triacyl [4,5] decane-2,4-dicopper, di (1 Monooctylchloro-2,2,6,6-tetramethylpiperidine-4diyl sebacate, dione (1cyclohexyloxy-2,2,6,6-tetramethylpiperidine — 4-monoyl) succinate, 1-octyloxy-2,2,6,6-tetramethyl-1, 4-tetramethyl-one-ranan, poly {[.6-tert-octylamino-s-tri Azine—2 .., 4-diyl] [2- (1-cyclohexyloxy-2,2,6,6-tetramethylpiperidine-4-yl) imino-hexamethylene-1 [4 -(1-cyclohexyloxy-2,2,6 * 6-tetramethylpiperidine-4-yl) imino], and 2,4,6-tris [N — (1-cyclohexyloxy -2,2,6,6 ^ tetramethylamidine-4 -yl) -n-butylamino] -s -triazine 0 8 · The composition according to item 7 of the patent application, wherein the steric hindrance Amines are bis (2,2,6,6-tetramethylpiperidin-4-yl) sebacate, and bis (1,2,2,6,6-pentamethylpentamidine 4-yl) decan Diacid '2 (1' 2, 2, 6 * 6-pentamethylpyridin-4-yl; -7- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling (This page) --.------- Order --- III --- I. Consumption Cooperation with Employees of Intellectual Property Bureau, Ministry of Economic Affairs, Du Duan 467932 I D8 VI. Scope of Patent Application (3, 5 _ Uncle Eryi —Butyl-4—Hydroxybenzyl) butylmalonate, 1— (2-Hydroxyethyl) —2, 2,2,6,6-tetramethyl—4 On the one side, it ’s and _Γ — acid Polyfluorene isosynthesis products, 2,4-diaza-6-tert-octyl monoamino_s-triazine and 4,4v-hexamethylenebis (amino-2,2,6,6_tetramethyl Piperidine) polycondensation product, N, N, -N ^, "" one four [(4, 6_ bis (butyl-(2-2, 6, 6-tetramethylpiperidine ~ 4 a Aminyl) amino-s-triazine-2-yl] -1,10-diamino-4,7-diazecane, di (1-octyloxy-2,2,6,6-tetrakis Methyltonidine- 4-yl) sebacate, di- (1-cyclohexyloxy-2,2,6,6-tetramethylmethylpyridine-4 1-yl) Diacid-, 1-octyloxy-2,2,6,6 — tetramethyl-4-hydroxypyridine, poly ([6-tert-octylamino-s-triazine-2.2, 4 — Diyl] [2- — (1-cyclohexyloxy-2 * 2, 6,6,6-tetramethylpiperidine-4-yl) iminohexamethylene-1 [4- (1-cyclohexyloxy-2, 2,6,6 —tetramethyl pyridosis — 4-imido) imino], or 2,4,6-tritri [N — (1 —cyclohexyloxy 2 —---- I-- LI !, Today · -------- Order --------- J Τ {Please read the notes on the back before filling out this page) Positive-Basic I 4 I (€ # 基 ffl- 四I 6 6 Based on the intellectual property of the Intellectual Property Bureau of the Ministry of Economic Affairs, the employee's cooperative printed hydrazine tri IS. Its benzene contains phenanyl and other hydroxyl groups. The grass ester item * acid 1 oxazine tertiary propanol | Kifan S Chloride from I Special Selection e Please, and application esters such as acid harvesting • Suction A 9 V i U U, which is suitable for Chinese paper standards Standard (CNS) A4 specification (210 X 297 mm) 467932 § D8 VI. Patent application scope Intellectual Property Bureau of the Ministry of Economic Affairs employee consumer cooperative printed two groups one of the 4 I,-its 2 bases' I oxygen group 4 Xin Zhi, I item 24 9: | The first group selected from the hydroxyl group, I ¾I I group-based.} 2 ethyloxy I group oxyhexyl phenyl hydroxyhexanyloxy 1 ring 4 A I 2--two three ί '1 group i ten I one {hydroxy 4 \ 2--, i and N 2 2 two; I, I, L, benzene, benzene, 243, bis, one, two; I; 1 exobenzene-;. i C propyl} another hydrazine} _ bases methyltriyl 6 hydroxylamine S tri! SI t-ylamine \ — 'group ί 4 I piperidine methyl I 6 6 2 I dol 2 2 ° Rn-type compounds in hydrazine Of η— / E -.-------- Order --------- line. (Please read the precautions on the back before filling this page), N-based_cyano ο ° 2 ο S 3 Ε ZZ 3 3 FC 3 G 1 ο ο C This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 467932 A8 B8 C8 D8, the scope of patent application G 3 is 1 to 1 2 carbon atoms Alkyl group, E t is hydrogen, cage group, phenyl alkyl group of 7 to 15 carbon atoms, E2 is; alkyl group of 1 to 12 carbon atoms, benzyl group, of 7 to 15 carbon atoms Cage base, or a CH2 CHz COOG4, where G4 is hydrogen, an alkyl group of 1 to 24 carbon atoms, and E3 is an alkyl or phenyl group of 8 to 18 carbon atoms, but it is limited to when G2 is E3 S0Z —, Ei is not phenylfluorenyl 1 2. For example, the compound in the 11th scope of the patent application, wherein: is cyano 1 E_3 S〇2 —, CFs — or a CO — N f G 3) 2, G3 Yes. A radical of 1 to 8 carbon atoms, Ε is hydrogen, phenyl or α-cumyl, Ε2 is a radical of 4 to 12 carbon atoms, and Ε3 is phenyl or octyl, and its restrictions When G2 is E3 S02 —, Ei is not α —cumyl. (Please read the precautions on the back before filling this page) -------- Order --------- Online, printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -i 〇- -paper degree Applicable to China National Standard (CNS) A4 specification (210 X 297 mm> 1 3 'As for the compounds in the patent application No. 12 range, where: Cr2 is CF3 —, Ε 1 is 0 (—fluorenyl, and Ε2 is uncle —Butyl or tert-octyl. 6 7 9 3 2 | D8 Γ The scope of patent application 1 · A benzotriazole-stabilized coating composition. The benzotriazole has improved durability and low loss rate when added to the coating. The composition includes: (a)-a resin selected from the following groups: thermosetting acrylic melamine resin, acrylic urethane resin, epoxy carboxyl resin, silane modified acrylic melamine, and having a urethane side chain Acrylic resins crosslinked with melamine, or acrylic polybasic resins crosslinked with melamine groups having urethane groups, and (b) 0 0 1 to 5% by weight (calculated based on resin solid content) A 'benzotriazole: (Please read the notes on the back before filling this page) Λ 0H r2 (Ar) order --------- line · Printed by the consumer cooperation of the Intellectual Property Bureau of the Ministry of Economic Affairs where G2 is fluorine, cyano * R3 S 0 2-> c F -COO — G 3 or — CO — N (G 3) G 3 is an alkyl group of 1 to 12 carbon atoms, -1-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)