SE9704086D0 - UV absorbers of benzotriazoles with improved stability - Google Patents

UV absorbers of benzotriazoles with improved stability

Info

Publication number
SE9704086D0
SE9704086D0 SE9704086A SE9704086A SE9704086D0 SE 9704086 D0 SE9704086 D0 SE 9704086D0 SE 9704086 A SE9704086 A SE 9704086A SE 9704086 A SE9704086 A SE 9704086A SE 9704086 D0 SE9704086 D0 SE 9704086D0
Authority
SE
Sweden
Prior art keywords
resins
acrylic
melamine
benzotriazoles
absorbers
Prior art date
Application number
SE9704086A
Other languages
Swedish (sv)
Other versions
SE9704086L (en
SE522379C2 (en
Inventor
Ramanathan Ravichandran
Anthony David Debellis
Revathi Iyengar
Joseph Suhadolnik
Jean-Pierre Wolf
Robert Edward Detlefsen
Mervin Gale Wood
Original Assignee
Ciba Geigy Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Publication of SE9704086D0 publication Critical patent/SE9704086D0/en
Publication of SE9704086L publication Critical patent/SE9704086L/en
Publication of SE522379C2 publication Critical patent/SE522379C2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32—Radiation-absorbing paints
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/16—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • C07D249/18—Benzotriazoles
    • C07D249/20—Benzotriazoles with aryl radicals directly attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having three nitrogen atoms as the only ring hetero atoms
    • C07F9/6518—Five-membered rings
    • C07F9/65188—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/48—Stabilisers against degradation by oxygen, light or heat

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Hydrogenated Pyridines (AREA)
  • Laminated Bodies (AREA)

Abstract

Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings. Some of the benzotriazoles are new and may be incorporated into any organic material, as stabilizers. The coating compositions are based on thermoset acrylic melamine resins, acrylic urethane resins, epoxy carboxy resins, silane modified acrylic melamine resins, acrylic resins with carbamate pendant groups crosslinked with melamine or acrylic polyol resins crosslinked with melamine containing carbamate groups.
SE9704086A 1996-11-07 1997-11-07 UV absorbers of benzotriazoles with improved stability SE522379C2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US74514696A 1996-11-07 1996-11-07

Publications (3)

Publication Number Publication Date
SE9704086D0 true SE9704086D0 (en) 1997-11-07
SE9704086L SE9704086L (en) 1998-05-08
SE522379C2 SE522379C2 (en) 2004-02-03

Family

ID=24995448

Family Applications (1)

Application Number Title Priority Date Filing Date
SE9704086A SE522379C2 (en) 1996-11-07 1997-11-07 UV absorbers of benzotriazoles with improved stability

Country Status (20)

Country Link
JP (1) JP4126364B2 (en)
KR (1) KR100488744B1 (en)
CN (1) CN1091127C (en)
AT (1) AT407642B (en)
AU (1) AU727301B2 (en)
BE (1) BE1011537A3 (en)
BR (1) BR9705437A (en)
CA (1) CA2220269A1 (en)
CH (1) CH693032A5 (en)
DE (1) DE19748658B4 (en)
DK (1) DK126697A (en)
ES (1) ES2134158B1 (en)
FR (1) FR2755444B1 (en)
GB (1) GB2319035B (en)
IT (1) IT1298471B1 (en)
NL (1) NL1007470C2 (en)
NO (1) NO975104L (en)
SE (1) SE522379C2 (en)
SG (1) SG71056A1 (en)
TW (1) TW467932B (en)

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AU779934B2 (en) 1999-11-16 2005-02-17 Ciba Specialty Chemicals Holding Inc. Use of benzotriazole UV absorbers
AU780351B2 (en) * 2000-02-01 2005-03-17 Ciba Specialty Chemicals Holding Inc. Method of content protection with durable UV absorbers
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US6353113B1 (en) 2000-08-03 2002-03-05 Ciba Specialty Chemicals Corporation Process for the preparation of 5-perfluoroalkyl substituted benzotriazole UV absorbers
US6566507B2 (en) 2000-08-03 2003-05-20 Ciba Specialty Chemicals Corporation Processes for the preparation of benzotriazole UV absorbers
DE60107874T2 (en) * 2000-11-27 2005-05-19 Ciba Speciality Chemicals Holding Inc. SUBSTITUTED 5-ARYL AND 5-HETEROARYL-2- (2-HYDROXYPHENYL) -2H-BENZOTRIAZOLE DERIVATIVES AS UV-ABSORBING SUBSTANCES
US6649770B1 (en) 2000-11-27 2003-11-18 Ciba Specialty Chemicals Corporation Substituted 5-aryl-2-(2-hydroxyphenyl)-2H-benzotriazole UV absorbers, compositions stabilized therewith and process for preparation thereof
US6930136B2 (en) 2001-09-28 2005-08-16 National Starch And Chemical Investment Holding Corporation Adhesion promoters containing benzotriazoles
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US20090214874A1 (en) * 2008-02-27 2009-08-27 Gm Global Technology Operations, Inc. Enhanced coating or layer
JP5428412B2 (en) 2008-03-18 2014-02-26 株式会社リコー Heat resistance improver and reversible thermosensitive recording medium
JP5250289B2 (en) 2008-03-31 2013-07-31 富士フイルム株式会社 UV absorber composition
JP5244437B2 (en) 2008-03-31 2013-07-24 富士フイルム株式会社 UV absorber composition
JP2009270062A (en) 2008-05-09 2009-11-19 Fujifilm Corp Ultraviolet absorbent composition
EP2523943B1 (en) * 2010-01-15 2014-11-19 DSM IP Assets B.V. Process to make uv radiation absorbing 2-phenyl-1,2,3-benzotriazoles
CN102050823A (en) * 2010-10-27 2011-05-11 华东理工大学 Synthesis and representation of guanine analogue as novel light stabilizer
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US9227109B2 (en) * 2012-09-13 2016-01-05 Acushnet Company Golf ball compositions
US20160244592A1 (en) 2013-12-09 2016-08-25 Adeka Corporation Substrate with improved coatability
TWI483987B (en) * 2014-03-10 2015-05-11 Sino Japan Chemical Co Ltd Liquid-state reactive uv light absorber, method of producing the same and application thereof
EP3178898B1 (en) * 2014-08-05 2023-10-04 Miyoshi Oil & Fat Co., Ltd. Additive for imparting ultraviolet absorptivity and/or high refractive index to matrix, and resin member using same
CN104327002A (en) * 2014-09-16 2015-02-04 德州宏坤医药中间体有限公司 Producing technology of benzotriazole-typed ultraviolet absorber
KR102449955B1 (en) * 2015-04-30 2022-10-04 미요시 유시 가부시끼가이샤 plastic lens
CN106316970A (en) * 2016-08-11 2017-01-11 重庆大学 Bis-benzotriazole containing organic dyestuff with super thermal stability
US10035043B2 (en) 2016-12-15 2018-07-31 Acushnet Company Golf ball incorporating highly crosslinked thermoset fluorescent microspheres and methods of making same
US10252112B2 (en) 2017-03-20 2019-04-09 Acushnet Company Golf ball composition
US10752720B2 (en) * 2017-06-26 2020-08-25 Johnson & Johnson Vision Care, Inc. Polymerizable blockers of high energy light
US10526296B2 (en) 2017-06-30 2020-01-07 Johnson & Johnson Vision Care, Inc. Hydroxyphenyl naphthotriazoles as polymerizable blockers of high energy light
US10723732B2 (en) 2017-06-30 2020-07-28 Johnson & Johnson Vision Care, Inc. Hydroxyphenyl phenanthrolines as polymerizable blockers of high energy light
US10935695B2 (en) 2018-03-02 2021-03-02 Johnson & Johnson Vision Care, Inc. Polymerizable absorbers of UV and high energy visible light
CN108949008A (en) * 2018-08-09 2018-12-07 深圳市前海奇迹新材料有限公司 A kind of aqueous UV priming paint of tempered glass
US11958824B2 (en) 2019-06-28 2024-04-16 Johnson & Johnson Vision Care, Inc. Photostable mimics of macular pigment
CN110606984B (en) * 2019-07-29 2021-02-19 宿迁联盛科技股份有限公司 Light stabilizer and preparation method thereof
US11543683B2 (en) 2019-08-30 2023-01-03 Johnson & Johnson Vision Care, Inc. Multifocal contact lens displaying improved vision attributes
CN111205510A (en) * 2020-02-13 2020-05-29 西安工业大学 Dual-functional ultraviolet absorbent and preparation method thereof
CN111575097B (en) * 2020-06-15 2021-04-16 清华大学 Solution with optically variable viscosity and method for regulating fluid viscosity
CN112079787A (en) * 2020-08-27 2020-12-15 宿迁联盛科技股份有限公司 Reduction process of nitro diazonium salt coupling derivative
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Also Published As

Publication number Publication date
AT407642B (en) 2001-05-25
GB9723303D0 (en) 1998-01-07
NL1007470C2 (en) 1998-10-07
FR2755444A1 (en) 1998-05-07
NO975104L (en) 1998-05-08
CA2220269A1 (en) 1998-05-07
AU4436097A (en) 1998-05-14
ITMI972482A1 (en) 1998-05-07
AU727301B2 (en) 2000-12-07
KR100488744B1 (en) 2005-11-29
SG71056A1 (en) 2000-03-21
ES2134158B1 (en) 2000-05-01
CN1183442A (en) 1998-06-03
DK126697A (en) 1998-05-08
ES2134158A1 (en) 1999-09-16
CH693032A5 (en) 2003-01-31
FR2755444B1 (en) 2004-10-08
TW467932B (en) 2001-12-11
JPH10140089A (en) 1998-05-26
BE1011537A3 (en) 1999-10-05
NO975104D0 (en) 1997-11-05
DE19748658B4 (en) 2015-08-20
MX9708572A (en) 1998-09-30
ATA187497A (en) 2000-09-15
JP4126364B2 (en) 2008-07-30
DE19748658A1 (en) 1998-05-14
SE9704086L (en) 1998-05-08
GB2319035B (en) 2001-01-10
SE522379C2 (en) 2004-02-03
CN1091127C (en) 2002-09-18
GB2319035A (en) 1998-05-13
KR19980042141A (en) 1998-08-17
BR9705437A (en) 1999-05-18
NL1007470A1 (en) 1998-05-11
IT1298471B1 (en) 2000-01-10

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