TWI343296B - Abrasive-free polishing system - Google Patents
Abrasive-free polishing system Download PDFInfo
- Publication number
- TWI343296B TWI343296B TW095130290A TW95130290A TWI343296B TW I343296 B TWI343296 B TW I343296B TW 095130290 A TW095130290 A TW 095130290A TW 95130290 A TW95130290 A TW 95130290A TW I343296 B TWI343296 B TW I343296B
- Authority
- TW
- Taiwan
- Prior art keywords
- polishing
- polishing system
- water
- potassium
- substrate
- Prior art date
Links
- 238000005498 polishing Methods 0.000 title claims abstract description 158
- 239000000758 substrate Substances 0.000 claims abstract description 58
- -1 silicate compound Chemical class 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 25
- 239000007800 oxidant agent Substances 0.000 claims abstract description 20
- 239000002245 particle Substances 0.000 claims abstract description 9
- 239000001508 potassium citrate Substances 0.000 claims description 27
- 229960002635 potassium citrate Drugs 0.000 claims description 27
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 27
- 235000011082 potassium citrates Nutrition 0.000 claims description 27
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- 230000001590 oxidative effect Effects 0.000 claims description 9
- 238000007517 polishing process Methods 0.000 claims description 9
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 8
- 229910001424 calcium ion Inorganic materials 0.000 claims description 8
- 239000001509 sodium citrate Substances 0.000 claims description 5
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- 235000011083 sodium citrates Nutrition 0.000 claims description 3
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 claims description 2
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 229960001790 sodium citrate Drugs 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims 2
- 239000011609 ammonium molybdate Substances 0.000 claims 2
- 235000018660 ammonium molybdate Nutrition 0.000 claims 2
- 229940010552 ammonium molybdate Drugs 0.000 claims 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims 2
- 235000010333 potassium nitrate Nutrition 0.000 claims 2
- 239000004323 potassium nitrate Substances 0.000 claims 2
- 239000012286 potassium permanganate Substances 0.000 claims 2
- OKBMCNHOEMXPTM-UHFFFAOYSA-M potassium peroxymonosulfate Chemical compound [K+].OOS([O-])(=O)=O OKBMCNHOEMXPTM-UHFFFAOYSA-M 0.000 claims 2
- YPQJHZKJHIBJAP-UHFFFAOYSA-N [K].[Bi] Chemical compound [K].[Bi] YPQJHZKJHIBJAP-UHFFFAOYSA-N 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- JLKDVMWYMMLWTI-UHFFFAOYSA-M potassium iodate Chemical compound [K+].[O-]I(=O)=O JLKDVMWYMMLWTI-UHFFFAOYSA-M 0.000 claims 1
- 239000001230 potassium iodate Substances 0.000 claims 1
- 235000006666 potassium iodate Nutrition 0.000 claims 1
- 229940093930 potassium iodate Drugs 0.000 claims 1
- 229910052715 tantalum Inorganic materials 0.000 abstract description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 22
- 239000010410 layer Substances 0.000 description 21
- 239000002253 acid Substances 0.000 description 13
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 11
- 229910052802 copper Inorganic materials 0.000 description 11
- 239000010949 copper Substances 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000003860 storage Methods 0.000 description 6
- 239000003082 abrasive agent Substances 0.000 description 5
- 229910000420 cerium oxide Inorganic materials 0.000 description 5
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
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- 229910052786 argon Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
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- 150000003839 salts Chemical class 0.000 description 2
- RLQWHDODQVOVKU-UHFFFAOYSA-N tetrapotassium;silicate Chemical compound [K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])[O-] RLQWHDODQVOVKU-UHFFFAOYSA-N 0.000 description 2
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- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/304—Mechanical treatment, e.g. grinding, polishing, cutting
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/32115—Planarisation
- H01L21/3212—Planarisation by chemical mechanical polishing [CMP]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/04—Aqueous dispersions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Dispersion Chemistry (AREA)
- Organic Chemistry (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/205,428 US20070039926A1 (en) | 2005-08-17 | 2005-08-17 | Abrasive-free polishing system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200730298A TW200730298A (en) | 2007-08-16 |
| TWI343296B true TWI343296B (en) | 2011-06-11 |
Family
ID=37499371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW095130290A TWI343296B (en) | 2005-08-17 | 2006-08-17 | Abrasive-free polishing system |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20070039926A1 (enExample) |
| EP (1) | EP1924666B1 (enExample) |
| JP (1) | JP5144516B2 (enExample) |
| KR (1) | KR101109334B1 (enExample) |
| CN (1) | CN101263209B (enExample) |
| AT (1) | ATE528364T1 (enExample) |
| IL (1) | IL189504A (enExample) |
| MY (1) | MY146300A (enExample) |
| SG (1) | SG178632A1 (enExample) |
| TW (1) | TWI343296B (enExample) |
| WO (1) | WO2007021716A2 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070117497A1 (en) * | 2005-11-22 | 2007-05-24 | Cabot Microelectronics Corporation | Friction reducing aid for CMP |
| CN101333419B (zh) * | 2008-08-05 | 2011-06-29 | 清华大学 | 一种集成电路铜布线的无磨粒化学机械抛光液 |
| DE112012001891B4 (de) * | 2011-04-26 | 2016-09-15 | Asahi Glass Company, Limited | Verfahren zum Polieren eines nicht-Oxid-Einkristallsubstrats |
| JP5716838B2 (ja) * | 2011-10-07 | 2015-05-13 | 旭硝子株式会社 | 研磨液 |
| US11319460B2 (en) * | 2017-03-23 | 2022-05-03 | Fujimi Incorporated | Polishing composition |
| CN114286846B (zh) * | 2019-08-30 | 2023-06-06 | 圣戈本陶瓷及塑料股份有限公司 | 用于进行材料去除操作的流体组合物及方法 |
| US11499072B2 (en) | 2019-08-30 | 2022-11-15 | Saint-Gobain Ceramics & Plastics, Inc. | Composition and method for conducting a material removing operation |
| TWI873902B (zh) * | 2022-10-11 | 2025-02-21 | 美商Cmc材料有限責任公司 | 用於高度摻雜硼之矽膜之化學機械拋光組合物 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4277355A (en) * | 1979-09-28 | 1981-07-07 | Alexander Farcnik | Insulative fireproof textured coating |
| US5352277A (en) * | 1988-12-12 | 1994-10-04 | E. I. Du Pont De Nemours & Company | Final polishing composition |
| JPH09306881A (ja) * | 1996-05-15 | 1997-11-28 | Kobe Steel Ltd | シリコン用研磨液組成物および研磨方法 |
| MY133700A (en) * | 1996-05-15 | 2007-11-30 | Kobe Steel Ltd | Polishing fluid composition and polishing method |
| US20040134873A1 (en) * | 1996-07-25 | 2004-07-15 | Li Yao | Abrasive-free chemical mechanical polishing composition and polishing process containing same |
| SG54606A1 (en) * | 1996-12-05 | 1998-11-16 | Fujimi Inc | Polishing composition |
| US6276996B1 (en) * | 1998-11-10 | 2001-08-21 | Micron Technology, Inc. | Copper chemical-mechanical polishing process using a fixed abrasive polishing pad and a copper layer chemical-mechanical polishing solution specifically adapted for chemical-mechanical polishing with a fixed abrasive pad |
| US6429133B1 (en) * | 1999-08-31 | 2002-08-06 | Micron Technology, Inc. | Composition compatible with aluminum planarization and methods therefore |
| WO2001019935A1 (en) * | 1999-09-15 | 2001-03-22 | Rodel Holdings, Inc. | Slurry for forming insoluble silicate during chemical-mechanical polishing |
| JP2001144042A (ja) * | 1999-11-11 | 2001-05-25 | Hitachi Chem Co Ltd | 金属研磨方法 |
| US6602117B1 (en) * | 2000-08-30 | 2003-08-05 | Micron Technology, Inc. | Slurry for use with fixed-abrasive polishing pads in polishing semiconductor device conductive structures that include copper and tungsten and polishing methods |
| US6551935B1 (en) * | 2000-08-31 | 2003-04-22 | Micron Technology, Inc. | Slurry for use in polishing semiconductor device conductive structures that include copper and tungsten and polishing methods |
| US6709316B1 (en) * | 2000-10-27 | 2004-03-23 | Applied Materials, Inc. | Method and apparatus for two-step barrier layer polishing |
| US6800218B2 (en) * | 2001-08-23 | 2004-10-05 | Advanced Technology Materials, Inc. | Abrasive free formulations for chemical mechanical polishing of copper and associated materials and method of using same |
| US20030189186A1 (en) * | 2002-03-29 | 2003-10-09 | Everlight Usa, Inc. | Chemical-mechanical polishing composition for metal layers |
| US6974777B2 (en) * | 2002-06-07 | 2005-12-13 | Cabot Microelectronics Corporation | CMP compositions for low-k dielectric materials |
| JP4152218B2 (ja) * | 2003-02-25 | 2008-09-17 | Necエレクトロニクス株式会社 | 化学的機械的研磨用スラリー |
| JP2004276219A (ja) * | 2003-03-18 | 2004-10-07 | Ebara Corp | 電解加工液、電解加工装置及び配線加工方法 |
| US7485241B2 (en) * | 2003-09-11 | 2009-02-03 | Cabot Microelectronics Corporation | Chemical-mechanical polishing composition and method for using the same |
-
2005
- 2005-08-17 US US11/205,428 patent/US20070039926A1/en not_active Abandoned
-
2006
- 2006-08-09 AT AT06813337T patent/ATE528364T1/de not_active IP Right Cessation
- 2006-08-09 JP JP2008526997A patent/JP5144516B2/ja not_active Expired - Fee Related
- 2006-08-09 WO PCT/US2006/030982 patent/WO2007021716A2/en not_active Ceased
- 2006-08-09 SG SG2010059459A patent/SG178632A1/en unknown
- 2006-08-09 CN CN200680033516XA patent/CN101263209B/zh not_active Expired - Fee Related
- 2006-08-09 KR KR1020087006318A patent/KR101109334B1/ko not_active Expired - Fee Related
- 2006-08-09 EP EP06813337A patent/EP1924666B1/en not_active Not-in-force
- 2006-08-15 MY MYPI20063944A patent/MY146300A/en unknown
- 2006-08-17 TW TW095130290A patent/TWI343296B/zh not_active IP Right Cessation
-
2008
- 2008-02-13 IL IL189504A patent/IL189504A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR20080035699A (ko) | 2008-04-23 |
| IL189504A (en) | 2012-12-31 |
| CN101263209B (zh) | 2011-07-13 |
| TW200730298A (en) | 2007-08-16 |
| IL189504A0 (en) | 2008-08-07 |
| JP5144516B2 (ja) | 2013-02-13 |
| WO2007021716A3 (en) | 2007-06-07 |
| US20070039926A1 (en) | 2007-02-22 |
| WO2007021716A2 (en) | 2007-02-22 |
| SG178632A1 (en) | 2012-03-29 |
| MY146300A (en) | 2012-07-31 |
| EP1924666B1 (en) | 2011-10-12 |
| EP1924666A2 (en) | 2008-05-28 |
| CN101263209A (zh) | 2008-09-10 |
| JP2009505423A (ja) | 2009-02-05 |
| ATE528364T1 (de) | 2011-10-15 |
| KR101109334B1 (ko) | 2012-01-31 |
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| MM4A | Annulment or lapse of patent due to non-payment of fees |