TWI325431B - Multifunctional monomers and their use in making cross-linked polymers and porous films - Google Patents

Multifunctional monomers and their use in making cross-linked polymers and porous films Download PDF

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Publication number
TWI325431B
TWI325431B TW092103132A TW92103132A TWI325431B TW I325431 B TWI325431 B TW I325431B TW 092103132 A TW092103132 A TW 092103132A TW 92103132 A TW92103132 A TW 92103132A TW I325431 B TWI325431 B TW I325431B
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TW
Taiwan
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page
monomer
product
reactor
bis
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TW092103132A
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English (en)
Chinese (zh)
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TW200415157A (en
Inventor
Shan J Niu Qing
E Hefner Robert Jr
P Godschalx James
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Dow Global Technologies Inc
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Publication of TW200415157A publication Critical patent/TW200415157A/zh
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Publication of TWI325431B publication Critical patent/TWI325431B/zh

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/753—Unsaturated compounds containing a keto groups being part of a ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/46—Friedel-Crafts reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/48—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation involving decarboxylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/683—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/34—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D309/36—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms
    • C07D309/38—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms one oxygen atom in position 2 or 4, e.g. pyrones
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W20/00—Interconnections in chips, wafers or substrates
    • H10W20/40—Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes
    • H10W20/45—Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes characterised by their insulating parts
    • H10W20/48—Insulating materials thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Pyrane Compounds (AREA)
TW092103132A 2002-02-15 2003-02-14 Multifunctional monomers and their use in making cross-linked polymers and porous films TWI325431B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US7820502A 2002-02-15 2002-02-15

Publications (2)

Publication Number Publication Date
TW200415157A TW200415157A (en) 2004-08-16
TWI325431B true TWI325431B (en) 2010-06-01

Family

ID=31990029

Family Applications (1)

Application Number Title Priority Date Filing Date
TW092103132A TWI325431B (en) 2002-02-15 2003-02-14 Multifunctional monomers and their use in making cross-linked polymers and porous films

Country Status (7)

Country Link
EP (1) EP1476416B1 (https=)
JP (1) JP4447923B2 (https=)
KR (1) KR100965394B1 (https=)
CN (1) CN100480226C (https=)
AU (1) AU2003215182A1 (https=)
TW (1) TWI325431B (https=)
WO (1) WO2003068825A2 (https=)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4765076B2 (ja) * 2003-02-20 2011-09-07 ダウ グローバル テクノロジーズ エルエルシー ポリアリーレンの合成方法及びその方法により製造されたポリアリーレン
WO2004090018A1 (en) * 2003-04-02 2004-10-21 Dow Global Technologies Inc. Multifunctional substituted monomers and polyarylene compositions therefrom
US7381850B2 (en) 2003-04-02 2008-06-03 Dow Global Technologies Inc. Multifunctional unsymmetrically substituted monomers and polyarylene compositions therefrom
JP2007505976A (ja) * 2003-09-19 2007-03-15 ダウ グローバル テクノロジーズ インコーポレイティド 結合ポラゲン含有多官能性モノマー及びそれからのポリアリーレン組成物
JP2007515501A (ja) * 2003-09-19 2007-06-14 ダウ グローバル テクノロジーズ インコーポレイティド 多官能性モノマー及びそれからのポリアリーレン組成物
US7585928B2 (en) 2003-10-21 2009-09-08 Dow Global Technologies Multifunctional monomers containing bound mesogenic poragen forming moieties and polyarylene compositions therefrom
US7626059B2 (en) 2003-10-21 2009-12-01 Dow Global Technologies Inc. Multifunctional ethynyl substituted monomers and polyarylene compositions therefrom
US20080090007A1 (en) * 2004-06-10 2008-04-17 Niu Q Jason Method Of Forming A Nanoporous Dielectric Film
US8399349B2 (en) * 2006-04-18 2013-03-19 Air Products And Chemicals, Inc. Materials and methods of forming controlled void
KR101045669B1 (ko) 2009-12-04 2011-07-01 광주과학기술원 다공성 유기물 박막의 제조방법 및 이에 의해 제조된 다공성 유기물 박막
US9868820B2 (en) * 2014-08-29 2018-01-16 Rohm And Haas Electronic Materials Llc Polyarylene materials
EP3825343A1 (en) * 2019-11-19 2021-05-26 Rohm and Haas Electronic Materials LLC Tunable refractive index polymers
CN118562127B (zh) * 2024-08-02 2024-10-11 中国科学技术大学 一种具有高Tg、低介电、本征阻燃型生物基苯并噁嗪树脂的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4400540A (en) * 1982-04-08 1983-08-23 The United States Of America As Represented By The Secretary Of The Air Force Oxy and thioaryl-phenylated aromatic biscyclopentadienones
US5965679A (en) * 1996-09-10 1999-10-12 The Dow Chemical Company Polyphenylene oligomers and polymers
WO2000031183A1 (en) * 1998-11-24 2000-06-02 The Dow Chemical Company A composition containing a cross-linkable matrix precursor and a poragen, and a porous matrix prepared therefrom
US6156812A (en) 1999-04-09 2000-12-05 Honeywell International Inc. Nanoporous material fabricated using polymeric template strands
US6172128B1 (en) 1999-04-09 2001-01-09 Honeywell International Inc. Nanoporous polymers crosslinked via cyclic structures
US6359091B1 (en) 1999-11-22 2002-03-19 The Dow Chemical Company Polyarylene compositions with enhanced modulus profiles

Also Published As

Publication number Publication date
JP4447923B2 (ja) 2010-04-07
CN1646463A (zh) 2005-07-27
KR100965394B1 (ko) 2010-06-24
CN100480226C (zh) 2009-04-22
AU2003215182A8 (en) 2003-09-04
EP1476416A2 (en) 2004-11-17
EP1476416B1 (en) 2015-12-30
KR20040086381A (ko) 2004-10-08
WO2003068825A8 (en) 2003-12-04
WO2003068825A3 (en) 2004-04-29
TW200415157A (en) 2004-08-16
AU2003215182A1 (en) 2003-09-04
JP2005517745A (ja) 2005-06-16
WO2003068825A2 (en) 2003-08-21

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