TWI259813B - Image-forming material - Google Patents

Image-forming material Download PDF

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Publication number
TWI259813B
TWI259813B TW091135908A TW91135908A TWI259813B TW I259813 B TWI259813 B TW I259813B TW 091135908 A TW091135908 A TW 091135908A TW 91135908 A TW91135908 A TW 91135908A TW I259813 B TWI259813 B TW I259813B
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TW
Taiwan
Prior art keywords
resin layer
photosensitive resin
coating liquid
thermoplastic resin
forming
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TW091135908A
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Chinese (zh)
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TW200301196A (en
Inventor
Tamotsu Suzuki
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Fuji Photo Film Co Ltd
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Priority claimed from JP2001380283A external-priority patent/JP3800512B2/en
Priority claimed from JP2001380058A external-priority patent/JP3806028B2/en
Priority claimed from JP2001380147A external-priority patent/JP3767807B2/en
Priority claimed from JP2001380059A external-priority patent/JP3767806B2/en
Priority claimed from JP2001380291A external-priority patent/JP3800513B2/en
Application filed by Fuji Photo Film Co Ltd filed Critical Fuji Photo Film Co Ltd
Publication of TW200301196A publication Critical patent/TW200301196A/en
Application granted granted Critical
Publication of TWI259813B publication Critical patent/TWI259813B/en

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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/0046—Photosensitive materials with perfluoro compounds, e.g. for dry lithography
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/075—Silicon-containing compounds
    • G03F7/0752—Silicon-containing compounds in non photosensitive layers or as additives, e.g. for dry lithography
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/075—Silicon-containing compounds
    • G03F7/0757—Macromolecular compounds containing Si-O, Si-C or Si-N bonds
    • G03F7/0758—Macromolecular compounds containing Si-O, Si-C or Si-N bonds with silicon- containing groups in the side chains
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
    • G03F7/11—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having cover layers or intermediate layers, e.g. subbing layers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0005—Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
    • G03F7/0007—Filters, e.g. additive colour filters; Components for display devices

Abstract

By using an image-forming material which comprises at least an alkali-soluble thermoplastic resin layer and an photosensitive resin layer successively disposed on a support a and at least one of the thermoplastic resin layer and the photosensitive resin layer containing a copolymer having a specific monomer, an image-forming material has little coating uneveness, smooth coating surface, excellent adhesion to a glass substrate and the like can be provided. Furthermore, an image-forming material having properties such as uniform thickness of the layer, no color uneveness, no foaming, excellent antifoaming property, and no cissing, or no pinhole can be provided.

Description

1259813 玖、發明說明 (發明說明應敘明：發明所屬之技術領域、先前技術、內容、實施方式及圖式簡單旨兌0月） (一） 發明所屬之技術領域 本發明係有關一種製作彩色液晶顯示器等使用的濾色片 製作等、有利於使用於藉由轉印形成影像之影像形成材料 〇 (二） 先前技術 對載體上設置的感光性樹脂層作轉印，而在作爲被轉印 體的基體上形成感光性樹脂層之影像形成材料係已知，例 如見日本特公昭5 6 - 40824號。該影像形成材料可使用於製 造印刷配線、凹版凸版印刷板、商標、多色試驗印刷試樣 、平版印刷版或絲網印刷模板等。上述影像形成材料通常 由載體、中間層（分離層）或中間層與鹼可溶熱可塑性樹脂 層及感光性樹脂層所成，在被轉印體上形成影像時使該影 像形成材料之感光性樹脂層面與被轉印體之基體密接，僅 使載體剝離後使中間層通過予以曝光，再藉由顯像處理在 基體上形成影像。此時，上述中間層可達成阻氧效果，且 在空氣中對曝光而言極爲有利，由於層厚爲0.5〜5μπι之極 薄値，在解像力面上特別無法達成障礙之效果。藉由上述 鹼可溶性熱塑性樹脂層，可吸收底層之凹凸（即因已經形成 的影像之凹凸）。 例如彩色液晶顯示器等使用的濾色片，一般而言具有R 、G、Β (紅、綠、藍）之各畫素、於其間隙具有以提高顯示 1259813 對比等爲目的之黑色矩陣（κ)之基本構成。濾色片中此等之 R、G、B、各畫素及κ之表面要求具高平滑性。換言之，使 用上述影像形成材料’使感光性樹脂層轉印於濾色片用基 板表面’於形成影像時感光性樹脂層之平滑性不佳（即會有 I旲厚斑）、會產生畫素之色斑。使用具有該色斑之濾色片製 造彩色液晶顯示器時，由於爲使彩色液晶顯示器所得的纖 素不會產生色斑’於塗覆時必須在不會產生塗覆斑（即塗覆 不均）、縮邊的情形下進行塗覆。 而且’於下層之鹼可溶性熱塑性樹脂層中亦相同地，就 對感光性樹脂層之塗覆性影響而言，另須具確保使熱塑性 樹脂層均勻曝光之平滑性，於塗覆時必須不會產生塗覆斑 、縮邊情形。 對該問題而言，於日本特公平8 - 3 6 3 0號公報中，提案於 塗覆形成感光性樹脂層時，於該塗覆液中添加氟系界面活 性劑使用。氟系界面活性劑係爲具有碳數3〜20且含有40 質量％以上氟原子且末端至少3個碳原子上連接的氫原子以 氟取代之具氟脂肪族基的丙烯酸酯或甲基丙烯酸酯；與（環 氧烷基）丙烯酸酯或聚（環氧烷基）甲基丙烯酸酯之共聚物、 在共聚物中含有40〜70質量％具有氟脂肪族基之丙烯酸酯 或甲基丙烯酸酯單位的聚合物。在多數實施例中使用的氟 系界面活性劑，聚（環氧烷基）（甲基）丙烯酸酯之環氧院基 使用環氧乙烷、環氧三乙烷、環氧四乙烷’且以質量平均 分子量爲1 . 5萬者爲中心。 在特公平8-3630號公報之實施例中使用的上述氟系界面 1259813 活丨主係爲R]使感光性樹脂層表面平滑者，惟依然有輿 墓板之挖ί女性不充分問題’特別是轉印於玻璃基板或具備 半“體之基板上時’與基板之密接性不充分。 (三）發明內容 本發明之目的係提供一種沒有塗覆斑、塗覆面狀平滑、 層厚均句且沒有色斑情形、不會發泡且消泡性優異、且玻 璃基板密接性優異的影像形成材料。1259813 玖 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明A color filter used for a display or the like is used to form a material for forming an image by transfer. (2) The prior art is used to transfer a photosensitive resin layer provided on a carrier, and is used as a transfer target. An image forming material in which a photosensitive resin layer is formed on a substrate is known, for example, see Japanese Patent Publication No. 5-6-40824. The image forming material can be used to produce printed wiring, gravure printing plates, trademarks, multicolor test printed samples, lithographic printing plates or screen printing templates, and the like. The image forming material is usually formed of a carrier, an intermediate layer (separation layer) or an intermediate layer, an alkali-soluble thermoplastic resin layer, and a photosensitive resin layer, and the image forming material is made photosensitive when an image is formed on the transfer target. The resin layer is in close contact with the substrate of the transfer target, and only the carrier is peeled off, and the intermediate layer is exposed to light, and an image is formed on the substrate by a developing process. At this time, the intermediate layer can achieve an oxygen barrier effect, and is extremely advantageous for exposure in air. Since the layer thickness is extremely thin, the thickness is 0.5 to 5 μm, and the effect of the obstacle is not particularly attained on the resolution surface. By the above-mentioned alkali-soluble thermoplastic resin layer, the unevenness of the underlayer (i.e., the unevenness of the image which has been formed) can be absorbed. For example, a color filter used in a color liquid crystal display or the like generally has a pixel of R, G, Β (red, green, and blue), and has a black matrix (κ) for the purpose of improving display 1259813 contrast in the gap. The basic composition. The surface of these R, G, B, each pixel and κ in the color filter is required to have high smoothness. In other words, when the image forming material 'the photosensitive resin layer is transferred onto the surface of the color filter substrate', the smoothness of the photosensitive resin layer is poor (that is, there is a thick spot), and a pixel is generated. The color spots. When a color liquid crystal display is manufactured using a color filter having the color spot, since the pigment obtained by the color liquid crystal display does not generate color spots, it is necessary to prevent coating spots (ie, uneven coating) during coating. Coating is carried out in the case of shrinking. Further, in the same manner as in the alkali-soluble thermoplastic resin layer of the lower layer, in terms of the influence on the coatability of the photosensitive resin layer, it is necessary to ensure the smoothness of uniform exposure of the thermoplastic resin layer, and it is not necessary to be coated. Produce coating spots and shrinkage. In the case of the application of the photosensitive resin layer, it is proposed to add a fluorine-based interface active agent to the coating liquid in the Japanese Patent Publication No. Hei 8-63. The fluorine-based surfactant is an acrylate or methacrylate having a fluoroaliphatic group having a carbon number of 3 to 20 and containing 40% by mass or more of a fluorine atom and having a hydrogen atom bonded to at least 3 carbon atoms at the terminal, which is fluorine-substituted. a copolymer with (alkylene oxide) acrylate or poly(alkylene oxide) methacrylate, containing 40 to 70% by mass of a acrylate or methacrylate unit having a fluoroaliphatic group in the copolymer Polymer. The fluorine-based surfactant used in most of the examples, the epoxy epoxy group of poly(alkylene oxide) (meth) acrylate uses ethylene oxide, triethylene oxide, and ethylene tetrachloride. The center of mass average molecular weight is 15,000. The above-mentioned fluorine-based interface 1259813 used in the embodiment of the Japanese Patent Publication No. Hei 8-3630 has a living system of R) to smooth the surface of the photosensitive resin layer, but there is still a problem that the female tomb is not enough. When it is transferred to a glass substrate or a substrate having a semi-body, the adhesion to the substrate is insufficient. (III) SUMMARY OF THE INVENTION The object of the present invention is to provide a coating without a coating, a smooth coating surface, and a layer thickness sentence. Further, in the case of no stain, an image forming material which does not foam and has excellent defoaming property and is excellent in adhesion to a glass substrate.

另外’本發明之目的係提供一種除上述機能外顯像液溶 解性優異的影像形成材料。 而且，本發明之目的係提供一種沒有塗覆斑、塗覆面狀 平滑、層厚均句且沒有色斑、且玻璃基板密接性優異的影 像形成材料。 此外’本發明之目的係提供一種沒有塗覆斑、塗覆面狀 平滑層厚均勻且沒有色斑、沒有縮邊或針孔、玻璃基板 密接性優異的影像形成材料。Further, the object of the present invention is to provide an image forming material which is excellent in the solubility of a developing solution in addition to the above-described functions. Further, an object of the present invention is to provide an image forming material which is free from coating spots, has a smooth coating surface, is uniform in layer thickness, has no color spots, and is excellent in adhesion of a glass substrate. Further, the object of the present invention is to provide an image forming material which is free from coating spots, has a smooth coating layer, is uniform in color, has no color spots, has no shrinkage or pinholes, and is excellent in adhesion of a glass substrate.

^ «之’爲解決上述問題之方法係如下所述。 (1}〜種影像形成材料，其係爲在載體上至少依序設置 胃_ μ γ谷熱塑性樹脂層及感光性樹脂層所成塗覆層所成的 pj^7 ’、 /吹材料’其特徵爲熱塑性樹脂層及感光性樹脂層中 至^ 方含有通式（a)、通式（b)及通式（c)所示單體之共聚 物（1 )， 通式（a ) ·· H2C=(p—C〇〇 (CH2)7rR厂 -7- 1259813 式 通^ «之' is the solution to the above problem as described below. (1)~ an image forming material which is a pj^7', /blowing material formed by at least a coating layer of a stomach_μ γ valley thermoplastic resin layer and a photosensitive resin layer on a carrier a copolymer (1) containing a monomer represented by the general formula (a), the general formula (b) and the general formula (c) in a thermoplastic resin layer and a photosensitive resin layer, and the general formula (a) ·· H2C=(p-C〇〇(CH2)7rR Factory-7- 1259813

= 2C H= 2C H

2 J o 2 RIC—R 03o04 r3 式 通 2q 〇 05〇 RIC 丨c 06 (/、中’ RQ1〜R。6各表示獨立的氫原子或碳數1〜5之烷 基’ 1表示單鍵或至少含有一種氧原子、氮原子及硫原子 之連接基’ R2表示單鍵或至少含有一種碳原子、氧原子、 氮原子及硫原子之建接基，L表示氫原子、碳數1〜5之烷 基’ η表示丨〜"之整數，出表示2〜μ之整數，1表示〇 10之整數’ p表示1〜1〇〇之整數 (2 )—種影像形成材料，其係爲在載體上至少依序設置有 驗可、溶熱塑性樹脂層及感光性樹脂層所成塗覆層所成的影 像&成材料，其特徵爲熱塑性樹脂層及感光性樹脂層中至 少—方含有通式U)、通式（b)、通式（C)及通式（d)所示單 體之共聚物（2 )， 通式（a ) : h2C=? — COC^CH^R广(CH2)丨CmF2m+1 闩01 ^02 通式（b): H2c=c r03 r24-s\o^-r3 一 8 - 1259813 通式（C ) : R〇5 H2C^c COORoe 、 R07 通式（d ) : H2C^〇2 J o 2 RIC-R 03o04 r3 type pass 2q 〇05〇RIC 丨c 06 (/, 'RQ1~R.6 each represents an independent hydrogen atom or an alkyl group having a carbon number of 1 to 5' 1 means a single bond or a linking group containing at least one oxygen atom, a nitrogen atom and a sulfur atom ' R 2 represents a single bond or a substituent containing at least one carbon atom, an oxygen atom, a nitrogen atom and a sulfur atom, and L represents a hydrogen atom and has a carbon number of 1 to 5 The alkyl group 'η represents an integer of 丨~", an integer representing 2 to μ, and 1 represents an integer of 〇10' p represents an integer of 1 to 1 ( (2) - an image forming material, which is a carrier An image & a material formed by coating a coating layer of a thermoplastic resin layer and a photosensitive resin layer, at least in a thermoplastic resin layer and a photosensitive resin layer. U), copolymer of the formula (b), formula (C) and formula (d), (2), formula (a): h2C=? — COC^CH^R (CH2)丨CmF2m+1 Latch 01 ^02 General formula (b): H2c=c r03 r24-s\o^-r3 A-8-1259813 Formula (C): R〇5 H2C^c COORoe, R07 General formula (d) : H2C^〇

I C〇O(CrH2rO)q-R08 (其中’於通式（a )、通式（b )及通式（c )係與上述（1 )記載 、___ 者同我’ RQ 7〜R(u各表示獨立的氫原子或碳數1〜5之烷基 ，1表示2〜10之整數，q表示丄〜川之整數）。 (3 ) ®影像形成材料，其係爲在載體上至少依序設置有 _ $ & $ M性樹脂層及感光性樹脂層所成的塗覆層所成的 影丨象0 $材料’其特徵爲熱塑性樹脂層及感光性樹脂層中 至少—方含有通式（a)、通式（c)及通式（e)所示單體之共聚 物（3 )， 通式（a ) : H2C=9~C〇〇(CH2tRf(CHACmF2m+1 、 ^〇5 通式（c ) : H；>C=iIC〇O(CrH2rO)q-R08 (where 'in general formula (a), formula (b) and formula (c) are the same as those described in (1) above, and ___ are the same as I'RQ 7~R (u Represents an independent hydrogen atom or an alkyl group having 1 to 5 carbon atoms, 1 represents an integer of 2 to 10, and q represents an integer of 丄~川). (3) An image forming material which is disposed at least sequentially on a carrier. The coating layer formed by the _ $ & $ M resin layer and the photosensitive resin layer is 0. The material is characterized in that at least the thermoplastic resin layer and the photosensitive resin layer contain a general formula ( a) a copolymer of the monomer of the formula (c) and the formula (e), (H): H2C=9~C〇〇(CH2tRf(CHACmF2m+1 , ^〇5 (c) : H;>C=i

I COOR06 R〇9I COOR06 R〇9

通式（e ) : HpC=CGeneral formula (e ) : HpC=C

I C00CsH2s+1 (其中，於通式（a)及通式（c)係與上述（1)記載者同義，p 表示氫原子或碳數1〜5之烷基，s表示6〜20之整數）。 一 9- 1259813 (4)〜種影像形成材料，其係爲在載體上至少依序設置有 驗司丨合熱塑性樹脂層及感光性樹脂層所成的塗覆層所成的 # {象&成材料’其特徵爲熱塑性樹脂層及感光性樹脂層中 至+ —方含有通式（a)、通式（c)及通式（f)所示單體之共聚 物（4 )， ^ X a) · H2C=C-C00(CH2)irRi~(CH2),CmF2m+1 R〇1 ^05 h2c=cI C00CsH2s+1 (wherein, the general formula (a) and the general formula (c) are synonymous with those described in the above (1), p represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and s represents an integer of 6 to 20 ). A 9- 1259813 (4) image forming material which is formed by coating a coating layer formed by at least a thermoplastic resin layer and a photosensitive resin layer on a carrier. a material [characterized by a copolymer of a monomer represented by the general formula (a), the general formula (c) and the general formula (f) in a thermoplastic resin layer and a photosensitive resin layer, (4), ^ X a) · H2C=C-C00(CH2)irRi~(CH2), CmF2m+1 R〇1 ^05 h2c=c

I c〇〇r06 D R〇11\ /R〇12I c〇〇r06 D R〇11\ /R〇12

、、 | 0 通式（f ) : h2c=c,, | 0 general formula (f ) : h2c=c

I r2 R〇13 (其中’於通式（a)及通式（c)係與上述（1)記載者同義，r〇i〇 013各表不獨且的氫原子或碳數1〜5之院基，r2表示單 鍵或至少含有一種氧原子、氮原子及硫原子之連接基）。 (5 )〜種影像形成材料，其係爲在載體上至少依序設置有 _ t '溶熟塑性樹脂層及感光性樹脂層所成塗覆層所成的影 像形成材料，其特徵爲熱塑性樹脂層及感光性樹脂層中至 少—方含有通式（a)及通式（d)所示單體之共聚物（5)， 通式（a ) : H2C=〒一COqCh^tRHCh^C^FM, h2c=c C〇〇(CrH2r〇)q-R〇8 -10- 1259813 (其中’ &通式（a)及通式（d)係與上述m記載者同義卜 (6)如上述⑴〜（5)中任—項記載之影像形成材料，其中 於塗覆層內至少感光性樹脂層爲藉由㈣塗覆設置者 本發明所使用的影像形成材料係構成塗覆層之驗可溶熱 可塑性樹脂層（以下簡稱爲熱可塑性樹脂層）及在至少—個 感光性樹脂層上含有含通式(小通式⑻及通式(c)所示單 體之共聚物⑴’含通式（a)、通式（b)、通式⑷及通式⑷ 所示單體之共聚物（2)，含通式（a)、通式（c)及通式（e)所 7K單體之共聚物（3)，含通式（a)、通式（c)及通式（f)所示 單體之共聚物（4)，或含通式（a)及通式（(1)所示單體之共聚 物（5 )。 上述共聚物就界面活性機能而言共聚物（丨）稱爲本發明用 界面活性劑（1 )。其他共聚物（2 )〜（5 )同樣稱爲本發明用共 聚物（2 )〜（5 )。而且，含有共聚物（丨）之影像形成材料稱爲 稱爲影像形成材料（1 )。含其他共聚物（2 )〜（5 )之影像形成 材料同彳永地稱爲影像形成材料（2 )〜（5 )。影像形成材料（丄） 〜（5 )總稱時，稱爲「本發明」或「本發明之影像形成材料 本發明之影像形成材料係指至少使感光性樹脂層轉印於 任蒽部材表面上構成。任意部材表面亦稱爲底層表面。 本發明之影像形成材料藉由使本發明用界面活性劑含有 熱塑性樹脂層及/或感光性樹脂層，可改善熱塑性樹脂層及 /或感光性樹脂層之各塗覆液性能。 本發明之影像形成材料（1 )可提供沒有塗覆斑、塗覆面狀 -11- 1259813 平滑、層厚均勻且沒有任 _ _ _ ^ 又甸色斑、仅月發泡情形且消泡性優異 、玻璃基板密接性優異的影像形成材料。 本發月之以像开> 成材料（2)可提供除上述機能外另顯像液 溶解性優異的影像形成材·料_。 本發明之影像形成材料（3)可提供沒有塗覆斑、塗覆面狀 平滑、層厚均勻且沒有色斑、玻璃基板密接性優異的影像 形成材料。 本發明之影像形成材料（4 )及（5 )可提供沒有塗覆斑、塗 覆面狀平滑、層厚均勻且沒有色斑、沒有縮邊或針孔情形 且玻璃基板密接性優異的影像形成材料。 本發明之影像形成材料特別是對具備玻璃基板或半導體 之基板而Η黏接性優異。 於本發明中感光性樹脂層使用於影像形成，惟該影像包 含無色透明影像。製得色影像時含有著色劑。 於下述中說明有關本發明用界面活性劑。 本發明用界面活性劑（1 )〜（5 )之構成共通使用的通式（a ) 所示單體稱爲單體（a )。其他通式（b )〜（f )所示單體同樣地 稱爲單體（b)〜（f)。 本發明用界面活性劑（1 )係爲含有單體（a ) '單體（b )及單 體（c )之共聚物（1 )。 本發明用界面活性劑（3 )係爲含有單體（a )、單體（c )及單 體（e )之共聚物（3 )。 本發明用界面活性劑（4 )係爲含有單體（a )、單體（c )及單 體（f)之共聚物（4)。 -12 - 1259813 本發明用界面活性劑（5 )係μ < 、爲3有單體（a )及單體（d )之共 聚物（5 )。 茲說明有關單體（a )。I r2 R〇13 (wherein 'the general formula (a) and the general formula (c) are synonymous with the ones described in the above (1), and the r〇i〇013 is not uniquely represented by a hydrogen atom or a carbon number of 1 to 5 The group, r2 represents a single bond or a linking group containing at least one oxygen atom, a nitrogen atom and a sulfur atom). (5) An image forming material which is an image forming material formed by arranging at least a coating layer of a plastic resin layer and a photosensitive resin layer on a carrier, which is characterized by a thermoplastic resin. At least one of the layer and the photosensitive resin layer contains a copolymer (5) of a monomer represented by the general formula (a) and the general formula (d), and the general formula (a): H2C=〒一COqCh^tRHCh^C^FM , h2c=c C〇〇(CrH2r〇)qR〇8 -10- 1259813 (where ' & general formula (a) and formula (d) are synonymous with the above m record (6) as above (1) ~ ( 5) The image forming material according to the above-mentioned item, wherein at least the photosensitive resin layer in the coating layer is formed by the (4) coating set. The image forming material used in the present invention constitutes a coated layer. The resin layer (hereinafter simply referred to as a thermoplastic resin layer) and the copolymer (1)' containing a formula (1) and a monomer represented by the formula (c) are contained in at least one photosensitive resin layer. a copolymer (2) of a monomer represented by the formula (b), the formula (4) and the formula (4), which comprises copolymerization of a monomer of the formula (a), the formula (c) and the formula (e) Object (3), a copolymer (4) comprising a monomer of the formula (a), the formula (c) and the formula (f), or a copolymer comprising a monomer of the formula (a) and the formula ((1) (5) The copolymer of the above copolymer is referred to as the surfactant (1) for use in the present invention in terms of interface activity. The other copolymers (2) to (5) are also referred to as copolymers of the present invention (2). ) (5). Moreover, an image forming material containing a copolymer (丨) is called an image forming material (1), and an image forming material containing other copolymers (2) to (5) is also called Image forming materials (2) to (5). Image forming materials (丄) to (5) collectively referred to as "present invention" or "image forming material of the present invention" The image forming material of the present invention means at least photosensitive The resin layer is transferred onto the surface of the armor material. The surface of any of the components is also referred to as the bottom surface. The image forming material of the present invention can be improved by including the thermoplastic resin layer and/or the photosensitive resin layer in the surfactant of the present invention. Performance of each coating liquid of the thermoplastic resin layer and/or the photosensitive resin layer. Image of the present invention The material (1) can be provided without coating spots, coated surface-like -11-1205913 smooth, uniform layer thickness and no _ _ _ ^ 甸 色 spot, only monthly foaming and excellent defoaming property, glass substrate close An image forming material excellent in the image forming material of the present invention. The image forming material (3) which is excellent in solubility of the developing liquid in addition to the above functions can be provided. It is possible to provide an image forming material which is free from coating spots, smooth in coating surface, uniform in layer thickness, and free from color spots, and excellent in adhesion of a glass substrate. The image forming materials (4) and (5) of the present invention can provide no coating spots. An image forming material having a smooth coating surface, a uniform layer thickness, no color unevenness, no shrinkage or pinhole, and excellent glass substrate adhesion. The image-forming material of the present invention is particularly excellent in adhesion to a substrate having a glass substrate or a semiconductor. In the present invention, the photosensitive resin layer is used for image formation, but the image contains a colorless and transparent image. The color image is obtained when the color image is obtained. The surfactants used in the present invention are described below. The monomer represented by the formula (a) which is commonly used in the composition of the surfactants (1) to (5) of the present invention is referred to as a monomer (a). The other monomers represented by the general formulae (b) to (f) are similarly referred to as monomers (b) to (f). The surfactant (1) used in the present invention is a copolymer (1) containing a monomer (a) 'monomer (b) and a monomer (c). The surfactant (3) used in the present invention is a copolymer (3) containing a monomer (a), a monomer (c) and a monomer (e). The surfactant (4) used in the present invention is a copolymer (4) containing a monomer (a), a monomer (c) and a monomer (f). -12 - 1259813 The surfactant (5) used in the present invention is a copolymer (5) having a monomer (a) and a monomer (d). The relevant monomer (a) is explained.

CmF2m + 1表示直鏈或支鏈，較侔老@ m r P 人k者爲4〜1 2之整數。CmF2m+1 70質量％較佳，更佳者爲40 之含量對單體（a)而言以20 〜6〇質量％。 之院基，較佳者爲氫原子 RQ1表示氫原子或碳數1 碳數1〜3之院基。CmF2m + 1 means a straight chain or a branched chain, which is an integer of 4 to 1 2 than that of the old @ m r P person k. CmF2m+1 is preferably 70% by mass, more preferably 40% by weight of the monomer (a) is 20 to 6 % by mass. The hospital base, preferably a hydrogen atom RQ1 represents a hydrogen atom or a carbon number of 1 to 3 carbon atoms.

Rl表示單鍵或至少含有一個氧原子、氮原子及硫原子之 連接基，較佳者爲單鍵。 連接基例如-S〇2NR4_(R4係與rqi同 η表示1〜20、較佳者爲2〜1〇。 L表示0〜10、較佳者爲0〜5。 茲說明有關單體（b )。R1 represents a single bond or a linking group containing at least one of an oxygen atom, a nitrogen atom and a sulfur atom, and is preferably a single bond. The linking group is, for example, -S〇2NR4_ (R4 is the same as rqi and η is 1 to 20, preferably 2 to 1 Å. L is 0 to 10, preferably 0 to 5. The related monomer (b) is explained. .

R〇2、R〇3及R。4係各表示獨立的氫原子或碳數1〜5之烷 基’較佳者爲氫原子、碳數1〜3之烷基。Rq2係以氫原子 或碳數1〜3之烷基較佳。RQ3及rG4係以碳數1〜3之烷基 R2表示單鍵或至少含有一個氧原子、氮原子及硫原子之 連接基，較佳者爲單鍵。 連接基例如-(CH2)q-(q表示1〜1〇之整數）、_s〇2NR4-(R4 係與R〇iR義）、-NH-、-0-、-S-等、或此等之組合。 R3表示氫原子、碳數1〜5之烷基，較佳者爲甲基。l表 -13- 1259813 示1〜1 00之整數’較佳者爲丨〜5〇。 茲說明有關單體（c )。 R〇5及R〇6係各表示獨立的氫原子或碳數丨〜5之烷基，較 佳者爲氫原子、碳數1〜3之烷基。R()5係以氫原子或碳數 1〜3之烷基較佳。係以碳數1〜3之烷基較佳。 茲說明有關單體（d )。 R〇7及R〇8係各表示獨立的氫原子或碳數丨〜5之烷基，較 佳者爲氫原子、碳數〜之烷基。更佳的1^7爲甲基及 RQ8爲氫原子。 R係爲2〜10之整數，較佳者爲2〜3。〇表示1〜3〇之 整數、較佳者爲1〜25。特別是單體（d )係以具有r爲2者 或r爲3者之共聚物混合物較佳，對前者之該混合物而言 比率爲1〜20質量％、較佳者爲1〜1〇質量％。此時，兩者 之q共同爲9〜22較佳。 茲說明有關單體（e )。 R〇9表不氣原子或碳數1〜5之院基，較佳者爲氫原子或 碳數1〜3之烷基。 S表示6〜20之整數，較佳者爲6〜15之整數。 茲說明有關單體（f )。 R〇1Q、R〇U、R(H2及R(H3係各表示獨立的氫原子或碳數丄 〜5之烷基，較佳者爲氫原子、碳數1〜3之院基。 R2表示單鍵或至少含有一個碳原子、氧原子、氮原子及 硫原子之連接基，較佳者爲單鍵。 連接基例如- (CH2)q-(q表示1〜10之整數）、_s〇2NR4-(r4 一 14 一 1259813 係與R 〇!问義）、-Ν Η -、- Ο -、- S -等、或此寺之組合。 本發明用界面活性劑之質量平均分子量M w係以i 〇 〇 〇〜 40000較佳、更佳者爲5000〜20000。 1 00質量份本發明用界面活性劑（1 )係以由5〜80質量％ 單體（a )、0 · 1〜50質量％單體（b)、1〜70質量％單體（c )及 殘餘質量份爲其他任意單體所成者較佳，更佳者爲由1 〇〜 60質量％單體（a)、0.5〜10質量％單體（b)、2〜50質量％單 體（c )及殘餘質量份爲其他任意單體所成者。 1 0 0質量份本發明用界面活性劑（2 )係以由5〜8 0質量％ 單體（a)、0 . 1〜50質量％單體（b)、1〜70質量％單體（c )、1 〜70質量％單體（d)、及殘餘質量份爲其他任意單體所成者 較佳，更佳者爲由10〜60質量％單體U)、0.5〜10質量？ 單體（b)、10〜40質量％單體（c)、10〜40質量％單體（d)、 及殘餘質量份爲其他任意單體所成者。 1 00質量份本發明用界面活性劑（3 )係以由5〜80管_ -、恿％ 單體（a)、1〜70質量％單體（c)、0.1〜50質量％單體（6)及 殘餘質量份爲其他任意單體所成者較佳，更佳者爲由^ 〇 60質量％單體（a)、1〜60質量％單體（c)、1〜50質量％璧 ;體 (e )及殘餘質量份爲其他任意單體所成者。 1 0 0質量份本發明用界面活性劑（4 )係以由5〜8 0督咳 具裏％ 單體（a)、1〜70質量％單體（c)、0.1〜5〇質量％單體（〖）及 殘餘質量份爲其他任意單體所成者較佳，更佳者爲由丄〇 60質量％單體（a)、2〜50質量％單體（c)、〇.5〜1〇暂歲“ 〜屢％單 體（f )及殘餘質量份爲其他任意單體所成者。 1259813 1 〇 〇質量份本發明用界面活性劑（5 )係以由5〜8 0質量％ 單體（a)、〇·1〜50質量％單體（d)及殘餘質量份爲其他任意 單體所成者較佳’更佳者爲由10〜60質量％單體U)、10〜 40質量％單體（c)及殘餘質量份爲其他任意單體所成者。單 體（a )、（ d )以外可共聚的單體以上述單體（c )較佳。 於本發明用共聚物中除上述特定的單體外可共聚合的單 體例如苯乙烯、乙烯基甲苯、α -甲基苯乙烯、2 -甲基苯乙 烯、氯化苯乙烯、乙烯基苯甲酸、乙烯基苯磺酸鈉、胺基 苯乙烯等之苯乙烯及其衍生物、取代物、丁二烯、異戊烯 等之二烯類、丙烯腈、乙烯醚類、馬來酸及馬來酸酯類、 馬來酸酐、肉桂酸、氯乙烯、醋酸乙烯酯等之乙烯系單體 等。 本發明用界面活性劑係爲單體（a )、單體（b )、單體（c )等 之共聚物，惟該單體排列沒有特別的限制，可以爲無規、 規則，例如嵌段或接枝。 而且，本發明用界面活性劑一分子中所含的單體（a )可以 互相爲相同的構造，亦可以使用在上述定義範圍中不同的 構造者。有關該單體（a)係爲共聚物（1)〜（5)之其他單體成 分、即單體（b )〜（f )中亦相同。 另外，本發明用界面活性劑（1 )可以使用2種以上分子構 造及/或單體組成不同者混合。本發明用界面活性劑（2 )〜（5 ) 中亦相同。 本發明用界面活性劑之含量對熱塑性樹脂層或感光性樹 脂層全部固成分而言以〇 · 〇 1〜1 〇質量％較佳、更佳者爲〇 .丄 - 16- 1259813 〜6質量％。本發明用界面活性劑使用熱塑性樹脂層及感光 性樹脂層兩者更爲有效。 於下述中，本發明影像形成材料之塗覆層構成只要是至 少具有上述熱塑性樹脂層及感光性樹脂層之構成即可，沒 有特別的限制’參照圖式詳細說明。而且，本發明影像形 成材料之層構成不受限於下述具體例。 第1圖所示影像形成材料係在載體1上依序形成鹼可溶 性熱塑性樹脂層2、阻氧層3及感光性樹脂層4。鹼可溶性 熱塑性樹脂層2及感光性樹脂層4中任一方含有本發明用 界面活性劑。 載體爲鹼可溶性樹脂層時，具有良好的剝離性、且化學 安定及熱安定’且以彎曲性物質構成較佳。具體例以鐵氟 龍、聚對酞酸乙二酯（PET )、聚碳酸酯、聚乙烯、聚丙烯等 薄片板或此等之積層物較佳。 爲確保在載體與熱塑性樹脂層間良好的剝離性時，一般 不須電暈放電等之表面處理、且沒有設置明膠等之底塗層 。載體之厚度爲5〜300 μπι.、較佳者爲20〜150 μιτι。 鹼可溶性熱塑性樹脂層由於具有可以吸收底層表面之凹 凸（亦包含因已經形成的影像等之凹凸等）之護墊材效果， 視該凹凸而定具有變形的性質較佳。 鹼可溶性熱塑性樹脂層中所含的樹脂以至少一種選自於 乙烯與丙烯酸共聚物之皂化物、苯乙烯與（甲基）丙烯酸酯 共聚物之皂化物、聚（甲基）丙烯酸酯、及（甲基）丙烯酸丁 酯與醋酸乙烯酯等之（甲基）丙烯酸酯共聚物等之皂化物等 -17- 1259813 較佳，亦可使用「塑膠性能便覽」（日本塑膠工業聯盟、全 日本塑膠成型工業聯合會編著、工業調查會發行、1 9 6 8年 1 0月2 5日發行）之有機高分子中可溶於鹼水溶液者。而且 ，此等之熱塑性樹脂中以軟化點爲8 0 °C以下者較佳。另外 ，於本說明書中「（甲基）丙烯酸」總稱丙烯酸及甲基丙烯 酸，且其衍生物時亦相同。 於此等之樹脂中可選自於質量平均分子量5萬〜50萬 (Tg = 0〜140°C)之範圍較佳，更佳者爲質量平均分子量爲6 萬〜20萬（Tg = 30〜1 1(TC )之範圍。此等樹脂之具體例如特 公昭5 4 · 3 4 3 2 7號、特公昭5 5 - 3 8 9 6 1號、特公昭5 8 - 1 2 5 7 7 號、特公昭5 4 - 2 5 92 5 7、特開昭61 - 13 47 5 6號、特公昭59-446 1 5號、特開昭54 - 92723號、特開昭54- 994 1 8號、特 開昭5 4 - 1 3 7 0 8 5號、特開昭5 7 - 2 0 7 3 2號、特開昭5 8 - 9 3 0 4 6 號、特開昭 5 9 - 9 7 1 3 5 號、特開昭 60- 1 5 9 74 3 號、OLS 3 5042 5 4 號、特開昭6 0 - 2 4 7 6 3 8號、特開昭6 0 - 2 0 8 7 4 8號、特開昭 60-214354 號、特開昭 60-230135 號、特開昭 60-258539 號、特開昭6 1 - 1 6 9 8 2 9、特開昭6 1 - 1 2 1 3 2 1 3、特開昭6 3 -1 47 1 5 9號、特開昭6 3 - 2 1 3 8 3 7號、特開昭6 3 - 26 6448號、 特開昭6 4 - 5 5 5 5 1號、特開昭64 - 5 5 5 50號、特開平2 - 191955 號、特開平2 _ 1 9 9 4 0 3號、特開平2 - 1 9 9 4 0 4號、特開平2 -20 8 6 02號、特願平4 - 3 9 6 5 3號各說明書中記載的可溶於鹼 水溶液的樹脂。更佳者爲特開昭6 3 - 1 4 7 1 5 9號說明書中記 載的甲基丙烯酸/ 2 -乙基己基丙烯酸酯/甲基丙烯酸苯甲酯/ 甲基丙烯酸甲酯共聚物。 -18- 1259813 另外’於上述各種樹脂中較佳者選自於質量平均分子量 3千〜3萬（Tg = 3 0〜170°C )之範圍、更佳者質量平均分子量 4千〜2萬（Tg = 60〜140°C )之範圍。較佳的具體例可選自於 上述專利說明書記載者，更佳者例如特公昭55- 3 89 6 1號、 特開平5 - 24 1 3 40號說明書中記載的苯乙烯/(甲基）丙烯酸 共聚物。 此外，爲調節此等有機高分子物質中載體與黏合物之黏 合力時，可添加各種可塑劑、各種聚合物或過冷卻物質、 密接改良劑或界面活性劑、脫模劑等。較佳的可塑劑之具 體例如聚丙二醇、聚乙二醇二辛基酞酸酯、二庚基酞酸酯 、二丁基酞酸酯、三環氧丙基磷酸酯、環氧丙基二苯基磷 酸酯、聚乙二醇單（甲基）丙烯酸酯、聚乙二醇二（甲基）丙 烯酸酯、聚丙二醇單（甲基）丙烯酸酯、聚丙二醇二（甲基） 丙烯酸酯、環氧樹脂與聚乙二醇單（甲基）丙烯酸酯之加成 反應生成物、有機二異氰酸酯與聚乙二醇單（甲基）丙燒酸 酯之加成反應生成物、有機二異氰酸酯與聚丙二醇單（甲基） 丙烯酸酯之加成反應生成物、雙酚A與聚乙二醇單（甲基） 丙;^希酸酯之縮合反應生成物等。鹼可溶熱可塑性樹脂層_ φ 可塑劑之量對該熱可塑性樹脂而言一般爲2〇〇質量％以τ、 較佳者爲2 0〜1 0 0質量％。鹼可溶熱可塑性樹脂層之厚度爲 6μπι以上較佳。熱可塑性樹脂之厚度小於6μπι時，不易使Ιμπι 以上之底層表面凹凸完全吸收°而且，有關上限時，就顯 像性、製造適性而言一般約爲1 〇 〇 μ m以下，較佳者約爲5 〇 μ 以下。 一 1 9 - 1259813 阻氧層係爲具有阻氧之機能層，藉此可使感光性樹脂層 緒由曝光之聚合，即使在空氣中聚合仍不會受到妨礙下進 ίτ °而且’由於膜厚較薄（〇 . 〇 5〜5卜⑽），對解像力沒有不良 影#。阻氧層之形成材料只要是可分散或溶解於水或鹼水 溶液中、且具有低透氧性者即可，可使用習知者。例如特 開昭46-2 121號或特公昭56_4〇8 24號記載的聚乙烯醚/馬 來酸酐聚合物、羧基烷基纖維素之水溶性鹽、水溶性纖維 素醚類、羧基烷基澱粉之水溶性鹽、聚乙烯醇、聚乙烯基 Dtt咯院酮、各種聚丙烯醯胺類、各種水溶性聚醯胺、聚丙 烯酸之水溶性鹽、明膠、環氧乙烷聚合物、各種澱粉及其 類似物任一種水溶性鹽、苯乙烯/馬來酸酐之共聚物、馬來 酸酯樹脂、以及此等2種以上之組合。 尤以聚乙烯醇與聚乙烯基吡咯烷酮之組合較佳。聚乙烯 醇以鹼化率爲80%以上者較佳，聚乙烯醇吡咯烷酮之含有 率對阻氧層之固成分而言一般爲1〜75質量％、較佳者爲1 〜60質量％、更佳者爲10〜50質量％。該含有率小於1質 量％時無法得到與感光性樹脂層之充分黏合性，若大於7 5 質量％時會降低阻氧能力。阻氧層之厚度非常薄’約爲0 . 1 〜5 μ m、較佳者爲〇 · 5〜2 μ m。若小於〇 · 1 μ m時氧之透過性 過高，而若大於5 μπι時顯像時或除去阻氧層時所需時間過 長。 感光性樹脂層爲可鹼水溶液顯像者、與可以有機溶劑顯 像者，就安全性與顯像液之成本而言以可驗水溶液顯像者 較佳。 -20- 1259813 感光性樹脂可以爲容受電子線等放射線部分硬化的負型 ，可以爲放射線未容受部硬化的正型。 負型感光性樹脂例如酚醛淸漆系樹脂。例如可使用特開 平7 - 4 3 8 8 9 9號公報記載的鹼可溶性酚醛淸漆樹脂系。而且 ，特開平6 - 1 488 88號公報記載之正型感光性樹脂層、即可 使用含有該公報記載的鹼可溶性樹脂與感光劑之1，2 -萘醌 二疊氮磺酸酯與該公報記載熱硬化劑的混合物之感光性樹 脂層。而且，可活用特開平5 - 26 2 8 50號公報記載的組成物 〇 負型感光性樹脂例如由負型二偶氮樹脂與黏合劑所成的 感光性樹脂、光聚合性組成物、由重氮化合物與黏合劑所 成的感光性樹脂組成物、肉桂酸型感光性樹脂組成物等。 其中，更佳者爲含有以光聚合起始劑、光聚合性單體及黏 合劑爲基本構成要素之感光性樹脂。該感光性樹脂層可利 用特開平1 1 - 1 3 3 6 0 0號公報記載的「聚合性化合物B」「 聚合起始劑C」「界面活性劑」「黏合劑」、或其他組成 物。 例如負型感光性樹脂中可鹼水溶液的感光性樹脂含有主 成分之含羧酸基的黏合劑（上述鹼可溶性熱塑性樹脂等）與 藉由光照射加成聚合的含乙烯性不飽和雙鍵之單體與光聚 合起始劑。 鹼可溶的黏合劑係爲在側鏈具有羧酸基之聚合物’例如 特開昭5 9 - 4 4 6 1 5號公報、特公昭5 4 - 3 4 3 2 7號公報、特公 昭58 - 1 2 5 7 7號公報、特公昭5 4 - 2 5 9 5 7號公報、特開昭 1259813 59- 5 3 8 36號公報、及特開昭5 9 - 7 1 048號公報記載的甲基 丙烯酸共聚物、丙烯酸共聚物、衣康酸共聚物、檸康酸共 聚物、馬來酸共聚物、部分酯化馬來酸共聚物等、另外， 在具有羥基之聚合物中加成有環狀酸酐者較佳。特別是美 國專利第4 1 3 9 3 9 1號說明書中記載的苯甲基（甲基）丙烯酸 酯與（甲基）丙烯酸共聚物或苯甲基（甲基）丙烯酸酯與（甲基） 丙烯酸與其他單體之多元共聚物。 感光性樹脂層所使用的鹼可溶性黏合劑可使用選自具有 30〜400mgKOH/g之酸價與1〇〇〇〜3 00000範圍之質量平均 分子量者。除上述外，各種性能例如爲改良硬化膜之強度 時，在不會對顯像性等有不良影響範圍內可添加鹼不溶性 聚合物。此等之聚合物例如醇可溶性耐龍或環氧樹脂。 鹼可溶性黏合劑對感光性樹脂組成物之全部固成分而言 ，通常爲10〜95質量％、較佳者爲20〜90質量％。若小於 1 0質量％時感光性樹脂層之黏合性過高，若大於9 5質量％ 時所形成的層之強度及光感度而言不佳。 光聚合起始劑例如美國專利第2 3 6 7 6 6 0號說明書揭示的 連位聚縮酮腈化合物、美國專利第2448828號說明書記載 的偶姻醚化合物、美國專利第27225 1 2號說明書記載的α-烴基取代的芳香族偶姻化合物、美國專利第3 0 4 6 1 2 7號及 同第295 1 7 5 8號各說明書記載的多合醌化合物、美國專利 第3 5 4 9 3 6 7號說明書記載的三方基咪唑二聚物與對-胺基酮 之組合、特公昭5 1 - 4 8 5 1 6號公報中記載的苯并噻唑化合物 與三鹵化甲基-s -三畊化合物、美國專利第4 2 3 9 8 5 0號說明 -22 - 1259813 書記載的三鹵化甲基-s -三阱化合物、美國專利第42 1 2 9 7 6 號說明書中記載的三鹵化甲基噁二唑化合物等。較佳者爲 三鹵化甲基-s -三畊、三鹵化甲基噁二唑、三芳基咪唑二聚 物。 於感光性樹脂層中對全部固成分而言光聚合起始劑之含 量一般爲0 . 5〜2 0質量％、較佳者爲1〜1 5質量％。若小於 0.5質量％時光感度或影像強度低，而若大於20質量％時即 使添加仍沒有提高性能之效果。 可藉由光照射加成聚合的含乙烯性不飽和雙鍵之單體， 例如在常壓下沸點爲1 00°C以上之化合物。例如聚乙二醇單 (甲基）丙烯酸酯、聚丙二醇單（甲基）、丙烯酸酯及苯氧基 乙基（甲基）丙烯酸酯等之單官能（甲基）丙烯酸酯；聚乙二 醇二（甲基）丙烯酸酯、聚丙二醇二（甲基）丙烯酸酯、三趣 甲基乙烷三丙烯酸酯、三羥甲基丙烷三丙烯酸酯、三羥甲 基丙烷二丙烯酸酯、新戊醇二（甲基）丙烯酸酯、季戊四醇 四（甲基）丙烯酸酯、季戊四醇三（甲基）丙烯酸酯、二季戊 四醇六（甲基）丙烯酸酯、二季戊四醇五（甲基）丙烯酸酯、 己二醇二（甲基）丙烯酸酯、三羥甲基丙烷三（丙烯醯氧基汽 基）醚、三（丙烯醯氧基乙基）異氰酸酯、三（丙烯醯氧基乙 基）氰酸酯、丙三醇三（甲基）丙烯酸酯、三羥甲基丙烷或汽 三醇等多官能醇中使環氧乙烷或環氧丙烷加成反應後（甲_ 丙烯酸酯化者等之多官能（甲基）丙烯酸酯。另外，特公日§ 4 8 - 4 1 7 0 8號、同5 0 - 6 0 3 4號、特開昭5 1 - 3 7 1 9 3號各公報 中揭示的胺基甲酸酯丙烯酸酯類、特開昭48 - 64 1 8 3號、特 -23- 1259813 公昭4 9 - 4 3 1 9 1號、同5 2 - 3 Ο 4 9 0號各公報中揭示的聚酯丙 烯酸酯類、環氧樹脂與（甲基）丙烯酸之反應生成物的環氧 基丙烯酸酯類等多官能丙烯酸酯或甲基丙烯酸酯。於此等 之中，以三羥甲基丙烷三（甲基）丙烯酸酯、季戊四醇四（甲 基）丙烯酸酯、二季戊四醇六（甲基）丙烯酸酯、二季戊四醇 五（甲基）丙烯酸酯較佳。此等單體可以單獨使用或2種以 上混合使用，對該感光性樹脂組成物全部固成分之含量而 言一般爲5〜5 0質量％，較佳者爲1 〇〜4 0質量％。若小於5 質量％時光感度或影像之強度降低，而若大於5 0質量％時感 光性樹脂層之黏合性過剩，故不爲企求。 感光性樹脂層爲在被轉印體上形成著色影像時，含有少 許顏料或染料。 一般顏料分爲有機顏料與無機顏料，由於前者之塗膜透 明性特優、後者一般具有優異的隱避性等特性，視其用途 可適當地選擇。而且，其他可使用金屬粉、氧化金屬粉、 螢光顏料等。適合使用的顏料例如偶氮系顏料、酞菁系顏 料、蒽醌系顏料、二噁哄系顏料、喹吖酮系顏料、異吲Β朵 滿酮系顏料、硝基系顏料等。感光性樹脂層使用的顏料以 色相別區分，例如下述列舉，惟不受此等所限制。此等顏 料或染料可以單獨使用或數種組合使用。 1 )紅色顏料 C · 1 .顏料紅97、C · I .顏料紅122、C . I ·顏料紅149、c . I . 顏料紅168、C.I.顏料紅177、C.I.顏料紅180、C.I.顏料 紅 192、C · I ·顏料紅 21 5、C · I . No · 1 20 8 5、C . I · NO · 1 21 20、 -24- 1259813 C . I · Ν ο . 1 2 1 4 Ο、C . I · N 〇 · 1 2 3 1 5 等之有機 _ 料 2 )綠色顏料 C . I ·顏料綠 7、c . I .顏料綠 3 6、c . I . N 〇 . 4 2 0 5 3、 (：·Ι·Ν〇·42085、C.I.n〇.4 2 095 等之有機顏料 3 )藍色顏料 C · I .顏料藍1 5 : 1、c ·丨.顏料藍丨5 : 4、C .〗.顏料藍1 5 :6、C . I ·顏料藍2 2、c · I .顏料藍6 0、C . I ·顏料藍6 4、 (：·Ι·Μ〇·42052、（：·Ι·ν〇·42090 等之有機顏料 4 )黃色顏料R〇2, R〇3 and R. Each of the 4 series represents an independent hydrogen atom or an alkyl group having 1 to 5 carbon atoms. A preferred one is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms. Rq2 is preferably a hydrogen atom or an alkyl group having 1 to 3 carbon atoms. RQ3 and rG4 are an alkyl group having a carbon number of 1 to 3, and R2 represents a single bond or a linking group containing at least one of an oxygen atom, a nitrogen atom and a sulfur atom, and is preferably a single bond. A linking group such as -(CH2)q- (q represents an integer of 1 to 1 )), _s〇2NR4-(R4 system and R〇iR), -NH-, -0-, -S-, etc., or the like The combination. R3 represents a hydrogen atom and an alkyl group having 1 to 5 carbon atoms, preferably a methyl group. l Table -13- 1259813 shows an integer from 1 to 00', preferably 丨~5〇. The relevant monomer (c) is explained. Each of R〇5 and R〇6 represents an independent hydrogen atom or an alkyl group having a carbon number of 丨5, and preferably a hydrogen atom or an alkyl group having 1 to 3 carbon atoms. R()5 is preferably a hydrogen atom or an alkyl group having 1 to 3 carbon atoms. It is preferred to use an alkyl group having 1 to 3 carbon atoms. The relevant monomer (d) is explained. R〇7 and R〇8 each represent an independent hydrogen atom or an alkyl group having a carbon number of 丨5, and preferably a hydrogen atom or an alkyl group having a carbon number of ～. More preferably, 1^7 is a methyl group and RQ8 is a hydrogen atom. R is an integer of 2 to 10, preferably 2 to 3. 〇 denotes an integer of 1 to 3 、, preferably 1 to 25. In particular, the monomer (d) is preferably a copolymer mixture having a ratio of r of 2 or r of 3, and the ratio of the mixture to the former is 1 to 20% by mass, preferably 1 to 1% by mass. %. At this time, it is preferable that the two q are common to 9 to 22. The relevant monomer (e) is explained. R 〇 9 represents a gas atom or a group having a carbon number of 1 to 5, preferably a hydrogen atom or an alkyl group having 1 to 3 carbon atoms. S represents an integer of 6 to 20, preferably an integer of 6 to 15. The relevant monomer (f) is explained. R〇1Q, R〇U, R (H2 and R (H3 each represents an independent hydrogen atom or an alkyl group having a carbon number of 55, preferably a hydrogen atom or a carbon number of 1 to 3). R2 represents a single bond or a linking group containing at least one carbon atom, oxygen atom, nitrogen atom and sulfur atom, preferably a single bond. The linking group is, for example, -(CH2)q- (q represents an integer of 1 to 10), _s〇2NR4 - (r4 - 14 - 1259813 and R 〇! question), -Ν Η -, - Ο -, - S -, etc., or a combination of the temples. The mass average molecular weight M w of the surfactant used in the present invention is i 〇〇〇 〜 40000 preferably, more preferably 5000 to 20000. 100 00 parts by mass of the surfactant (1) used in the invention is from 5 to 80% by mass of monomer (a), 0 · 1 to 50 mass % monomer (b), 1 to 70% by mass of the monomer (c) and the residual mass part are preferably those of any other monomer, more preferably from 1 〇 to 60% by mass of the monomer (a), 0.5. ～10% by mass of the monomer (b), 2 to 50% by mass of the monomer (c) and the residual mass parts are those of any other monomer. 100 parts by mass of the surfactant (2) of the present invention is 5~80% by mass monomer (a), 0. 1~50 The amount of monomer (b), 1 to 70% by mass of the monomer (c), 1 to 70% by mass of the monomer (d), and the residual mass are preferably those of any other monomer, and more preferably 10 to 60% by mass of the monomer U), 0.5 to 10 parts by mass? Monomer (b), 10 to 40% by mass of the monomer (c), 10 to 40% by mass of the monomer (d), and residual mass parts are optional 100% by mass of the surfactant (3) of the present invention is composed of 5 to 80 tubes _ -, 恿% monomer (a), 1 to 70% by mass of the monomer (c), 0.1~ 50% by mass of the monomer (6) and the residual mass part are preferably those of any other monomer, more preferably 60% by mass of the monomer (a), 1 to 60% by mass of the monomer (c), 1 to 50% by mass of 璧; body (e) and residual mass parts are those of any other monomer. 100 parts by mass of the surfactant (4) used in the present invention is from 5 to 80% of the cough. The monomer (a), 1 to 70% by mass of the monomer (c), 0.1 to 5 % by mass of the monomer (%), and the residual mass are preferably those of any other monomer, and more preferably 60% by mass of monomer (a), 2 to 50% by mass of monomer (c), 〇.5~1〇 The monomer (f) and the residual mass are all other monomers. 1259813 1 〇〇 by mass of the surfactant (5) of the present invention is composed of 5 to 80% by mass of the monomer (a), 〇·1 to 50% by mass of the monomer (d) and the residual mass part are preferably those of any other monomer. More preferably, it is 10 to 60% by mass of the monomer U), and 10 to 40% by mass of the monomer ( c) and the residual mass parts are those formed by any other monomer. The monomer copolymerizable other than the monomers (a) and (d) is preferably the above monomer (c). Monomer copolymerizable in the copolymer of the present invention in addition to the above specific monomers such as styrene, vinyl toluene, α-methylstyrene, 2-methylstyrene, styrene chloride, vinylbenzene Styrene and its derivatives, substitutes, butadiene, isopentene, etc., formic acid, sodium vinylbenzenesulfonate, aminostyrene, etc., acrylonitrile, vinyl ether, maleic acid and horse A vinyl monomer such as an acid ester, maleic anhydride, cinnamic acid, vinyl chloride or vinyl acetate. The surfactant used in the present invention is a copolymer of the monomer (a), the monomer (b), the monomer (c), etc., but the monomer arrangement is not particularly limited and may be random, regular, for example, a block. Or grafted. Further, the monomer (a) contained in one molecule of the surfactant of the present invention may have the same structure as each other, and a structure different from the above defined range may also be used. The monomer (a) is the same as the other monomer components of the copolymers (1) to (5), that is, the monomers (b) to (f). Further, the surfactant (1) of the present invention may be used in a mixture of two or more kinds of molecular structures and/or different monomer compositions. The same applies to the surfactants (2) to (5) used in the present invention. In the present invention, the content of the surfactant is preferably 〇·〇1 to 1 〇% by mass based on the total solid content of the thermoplastic resin layer or the photosensitive resin layer, and more preferably 〇.丄-16- 1259813 ～6 mass% . The use of the surfactant in the present invention is more effective in using both the thermoplastic resin layer and the photosensitive resin layer. In the following, the coating layer of the image forming material of the present invention is not particularly limited as long as it has at least the thermoplastic resin layer and the photosensitive resin layer, and will be described in detail with reference to the drawings. Further, the layer constitution of the image forming material of the present invention is not limited to the following specific examples. The image forming material shown in Fig. 1 sequentially forms an alkali-soluble thermoplastic resin layer 2, an oxygen barrier layer 3, and a photosensitive resin layer 4 on the carrier 1. One of the alkali-soluble thermoplastic resin layer 2 and the photosensitive resin layer 4 contains the surfactant of the present invention. When the carrier is an alkali-soluble resin layer, it has good releasability, chemical stability and thermal stability, and is preferably composed of a flexible material. Specific examples thereof are a sheet of Teflon, polyethylene terephthalate (PET), polycarbonate, polyethylene, polypropylene or the like, or a laminate of the above. In order to ensure good peeling property between the carrier and the thermoplastic resin layer, surface treatment such as corona discharge is not required, and an undercoat layer such as gelatin is not provided. The thickness of the carrier is 5 to 300 μπι., preferably 20 to 150 μιτι. The alkali-soluble thermoplastic resin layer has a property of being able to absorb the convexities and convexities of the underlying surface (including the unevenness of the image or the like which has already been formed), and is preferably deformed depending on the unevenness. The resin contained in the alkali-soluble thermoplastic resin layer is at least one selected from the group consisting of a saponified product of an ethylene-acrylic acid copolymer, a saponified product of a styrene-(meth)acrylate copolymer, a poly(meth)acrylate, and A saponified product such as a methacrylate acrylate and a (meth) acrylate copolymer such as vinyl acetate, etc. -17-1259813 is preferred, and a "Plastic Performance Handbook" (Japan Plastics Industry Alliance, Japan Plastic Molding Industry) can also be used. It is a soluble in organic polymer in the organic polymer produced by the Federation, published by the Industrial Investigation Association, issued on October 25, 1868. Further, among these thermoplastic resins, a softening point of 80 ° C or less is preferred. Further, in the present specification, "(meth)acrylic acid" is collectively referred to as acrylic acid and methacrylic acid, and the derivatives thereof are also the same. The resin may be selected from the group consisting of a mass average molecular weight of 50,000 to 500,000 (Tg = 0 to 140 ° C), and more preferably a mass average molecular weight of 60,000 to 200,000 (Tg = 30~). The range of 1 1 (TC ). The specifics of these resins are, for example, Special Gong Zhao 5 4 · 3 4 3 2 7 , Special Gong Zhao 5 5 - 3 8 9 6 1 , Special Gong Zhao 5 8 - 1 2 5 7 7 Special public Zhao 5 4 - 2 5 92 5 7 , Special opening 61 - 13 47 5 6 , Special public Zhao 59-446 1 5, Special opening 54-92723, Special opening 54-994 1 8 Kaizhao 5 4 - 1 3 7 0 8 5, Special Open 5 7 - 2 0 7 3 2, Special Open 5 8 - 9 3 0 4 6 , Special Open 5 9 - 9 7 1 3 5 No., No. 60- 1 5 9 74 No. 3, OLS 3 5042 5 No. 4, Special Open No. 6 0 - 2 4 7 6 3 8 , Special Open No. 6 0 - 2 0 8 7 4 8 Kaizhao 60-214354, Special Opening 60-230135, Special Opening 60-258539, Special Opening 6 1 - 1 6 9 8 2 9 , Special Opening 6 1 - 1 2 1 3 2 1 3, Special opening 6 3 -1 47 1 5 9 , special opening 6 3 - 2 1 3 8 3 7 , special opening 6 3 - 26 6448, special opening 6 4 - 5 5 5 5 1 Special opening 64 - 5 5 5 50, special Kaiping 2 - 191955, special opening 2 _ 1 9 9 4 0 No. 3, Special Kaiping 2 - 1 9 9 4 0 4, Special Kaiping 2 -20 8 6 02, Special Peace 4 - 3 9 6 5 No. 3, soluble in the instructions A resin in an aqueous alkali solution. More preferably, it is methacrylic acid / 2-ethylhexyl acrylate / benzyl methacrylate / methacrylic acid described in JP-A-63-1749. Ester copolymer. -18- 1259813 Further, among the above various resins, it is preferably selected from the range of mass average molecular weight of 3,000 to 30,000 (Tg = 30 to 170 ° C), and more preferably mass average molecular weight of 4,000. a range of 20,000 (Tg = 60 to 140 ° C). A preferred specific example may be selected from those described in the above patent specification, and more preferably, for example, Japanese Patent Publication No. 55- 3 89 6 1 , Special Kaiping 5 - 24 1 3. Styrene/(meth)acrylic acid copolymer described in the specification No. 40. In addition, various plasticizers, various polymers or supercooling may be added to adjust the adhesion of the carrier to the binder in these organic polymer materials. Substance, adhesion improver or surfactant, release agent, etc. Specific examples of preferred plasticizers such as polypropylene glycol, polyethylene glycol dioctyl phthalate, diheptyl phthalate, dibutyl phthalate, triepoxypropyl phosphate, epoxypropyl diphenyl Phosphate, polyethylene glycol mono (meth) acrylate, polyethylene glycol di (meth) acrylate, polypropylene glycol mono (meth) acrylate, polypropylene glycol di (meth) acrylate, epoxy Addition reaction product of resin and polyethylene glycol mono(meth)acrylate, addition reaction product of organic diisocyanate and polyethylene glycol mono(methyl)propionate, organic diisocyanate and polypropylene glycol A condensation reaction product of a mono(meth)acrylate, a condensation reaction product of bisphenol A with polyethylene glycol mono(methyl)propene; The amount of the alkali-soluble thermoplastic resin layer _ φ plasticizer is generally 2 〇〇 mass% to τ, preferably 20 to 100% by mass, for the thermoplastic resin. The thickness of the alkali-soluble thermoplastic resin layer is preferably 6 μm or more. When the thickness of the thermoplastic resin is less than 6 μm, it is difficult to completely absorb the unevenness of the surface of the underlayer of Ιμπι or more. Further, when the upper limit is concerned, the development property and the manufacturing suitability are generally about 1 μm or less, preferably about 5 〇μ or less. A 1 9 - 1259813 oxygen barrier layer is a functional layer with oxygen barrier, whereby the photosensitive resin layer can be polymerized by exposure, even if it is polymerized in air, it will not be hindered from being pushed down and 'because of the film thickness Thinner (〇. 〇5~5 Bu (10)), there is no bad shadow on the resolution. The material for forming the oxygen barrier layer may be any one which can be dispersed or dissolved in water or an alkaline water solution and has low oxygen permeability. For example, polyvinyl ether/maleic anhydride polymer, water-soluble salt of carboxyalkyl cellulose, water-soluble cellulose ether, carboxyalkyl starch described in JP-A-46-2 121 or JP-A-56_4〇8 24 Water-soluble salts, polyvinyl alcohol, polyvinyl Dtt oxolone, various polyacrylamides, various water-soluble polyamines, water-soluble salts of polyacrylic acid, gelatin, ethylene oxide polymers, various starches and Any of the analogues, a water-soluble salt, a copolymer of styrene/maleic anhydride, a maleate resin, and a combination of two or more thereof. In particular, a combination of polyvinyl alcohol and polyvinylpyrrolidone is preferred. The polyvinyl alcohol has an alkalinization ratio of 80% or more, and the polyvinyl alcohol pyrrolidone content is usually from 1 to 75% by mass, preferably from 1 to 60% by mass, based on the solid content of the oxygen barrier layer. The best is 10 to 50% by mass. When the content is less than 1% by mass, sufficient adhesion to the photosensitive resin layer cannot be obtained, and when it is more than 75 % by mass, the oxygen barrier ability is lowered. The thickness of the oxygen barrier layer is very thin 'about 0.1 to 5 μ m, preferably 〇 5 to 2 μ m. If the permeability is less than 〇 · 1 μ m, the oxygen permeability is too high, and if it is greater than 5 μm, the time required for development or removal of the oxygen barrier layer is too long. The photosensitive resin layer is an alkali-soluble aqueous solution developer and an organic solvent-developable image, and it is preferable to use an aqueous solution for the safety and the cost of the developing solution. -20- 1259813 The photosensitive resin may be a negative type that is hardened by radiation such as an electron beam, and may be a positive type in which radiation is not hardened. A negative photosensitive resin such as a novolac lacquer resin. For example, an alkali-soluble novolac lacquer resin described in JP-A-7-48 88.9 can be used. In the positive photosensitive resin layer described in JP-A-6-14888, the 1,2-naphthoquinonediazidesulfonate containing the alkali-soluble resin and the sensitizer described in the publication can be used. A photosensitive resin layer of a mixture of thermosetting agents is described. In addition, the composition-sensitive photosensitive resin described in JP-A No. 5-26 2 8 50, for example, a photosensitive resin composed of a negative-type diazo resin and a binder, a photopolymerizable composition, and a heavy weight A photosensitive resin composition formed of a nitrogen compound and a binder, a cinnamic acid type photosensitive resin composition, or the like. Among them, a photosensitive resin containing a photopolymerization initiator, a photopolymerizable monomer, and a binder as a basic component is more preferable. As the photosensitive resin layer, "polymerizable compound B", "polymerization initiator C", "surfactant", "adhesive", or other components described in JP-A No. 1 1 - 1 3 3 0 0 0 can be used. For example, the photosensitive resin containing an alkali aqueous solution in the negative photosensitive resin contains a carboxylic acid group-containing binder (the above-mentioned alkali-soluble thermoplastic resin or the like) having a main component and an ethylenically unsaturated double bond which is subjected to addition polymerization by light irradiation. Monomer and photopolymerization initiator. The alkali-soluble binder is a polymer having a carboxylic acid group in a side chain. For example, JP-A-59- 4 4 6 1 5, JP-A-54-3-4, and JP-A-58 - 1 2 5 7 7 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , a base acrylic copolymer, an acrylic copolymer, an itaconic acid copolymer, a citraconic acid copolymer, a maleic acid copolymer, a partially esterified maleic acid copolymer, etc., and additionally, a ring having a hydroxyl group added thereto The anhydride is preferred. In particular, the benzyl (meth) acrylate and (meth) acrylate copolymer or benzyl (meth) acrylate and (meth) acrylate described in the specification of U.S. Patent No. 4 1 3 9 3 9 1 A multicomponent copolymer with other monomers. The alkali-soluble binder used for the photosensitive resin layer can be selected from those having an acid value of 30 to 400 mgKOH/g and a mass average molecular weight of 1 to 300,000. In addition to the above, when the properties of the cured film are improved, for example, an alkali-insoluble polymer can be added in a range which does not adversely affect the development properties. Such polymers are, for example, alcohol soluble nylon or epoxy resins. The alkali-soluble binder is usually 10 to 95% by mass, preferably 20 to 90% by mass based on the total solid content of the photosensitive resin composition. When the amount is less than 10% by mass, the adhesion of the photosensitive resin layer is too high, and when it is more than 95% by mass, the strength and light sensitivity of the layer formed are not good. A photopolymerization initiator such as the vicinal polyketal nitrile compound disclosed in the specification of U.S. Patent No. 2 3 6 6 6 0, the acylate ether compound described in the specification of U.S. Patent No. 2,448,828, and the specification of U.S. Patent No. 27225 1 2 The α-hydrocarbyl-substituted aromatic cryptic compound, the conjugated compound described in each of the specifications of U.S. Patent No. 3,046, and the disclosure of U.S. Patent No. 2,591,058, U.S. Patent No. 3 5 4 9 3 6 a combination of a trigonal imidazole dimer and a p-amino ketone described in the specification No. 7, a benzothiazole compound described in Japanese Patent Publication No. 5 1 - 4 8 5 16 and a trihalogenated methyl-s-three-till compound , the trihalogenated methyl-s-tripper compound described in the specification of U.S. Patent No. 4 2 3 9 8 0, and the trihalogenated methyl ester described in the specification of U.S. Patent No. 4,021,978. Diazole compounds and the like. Preferred are trihalogenated methyl-s-three tillage, trihalogenated methyl oxadiazole, and triaryl imidazole dimer. The content of the photopolymerization initiator in the photosensitive resin layer is generally from 0.5 to 2% by mass, preferably from 1 to 15% by mass, based on the total solid content. If it is less than 0.5% by mass, the light sensitivity or image intensity is low, and if it is more than 20% by mass, the effect of improving the performance is not obtained. The monomer having an ethylenically unsaturated double bond which is subjected to addition polymerization by light irradiation, for example, a compound having a boiling point of 100 ° C or more at normal pressure. For example, monofunctional (meth) acrylates such as polyethylene glycol mono(meth)acrylate, polypropylene glycol mono(methyl), acrylate, and phenoxyethyl (meth) acrylate; polyethylene glycol Di(meth)acrylate, polypropylene glycol di(meth)acrylate, trimethylethane triacrylate, trimethylolpropane triacrylate, trimethylolpropane diacrylate, neopentyl alcohol (meth) acrylate, pentaerythritol tetra (meth) acrylate, pentaerythritol tri (meth) acrylate, dipentaerythritol hexa (meth) acrylate, dipentaerythritol penta (meth) acrylate, hexane diol di ( Methyl) acrylate, trimethylolpropane tris(propylene decyloxy) ether, tris(propylene methoxyethyl) isocyanate, tris(propylene oxyethyl) cyanate, glycerol A polyfunctional (meth)acrylic acid such as an alkyl acrylate or a propylene oxide is added to a polyfunctional alcohol such as (meth) acrylate, trimethylolpropane or trimethylol. Ester. In addition, special day § 4 8 - 4 1 7 The urethane acrylates disclosed in each of the publications of No. 0, No. 5 0 - 6 0 3 4, and JP-A-Open No. 5 1 - 3 7 1 9 3, JP-A-48-64 1 8 3 , -23- 1259813 Gong Zhao 4 9 - 4 3 1 9 1 , the same as 5 2 - 3 Ο 4 9 0 disclosed in the publication of the reaction of polyester acrylates, epoxy resins and (meth)acrylic acid a polyfunctional acrylate or methacrylate such as an epoxy acrylate. Among these, trimethylolpropane tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, dipentaerythritol It is preferable to use hexa(meth) acrylate or dipentaerythritol penta (meth) acrylate. These monomers may be used singly or in combination of two or more kinds, and the content of all solid components of the photosensitive resin composition is generally 5 to 50% by mass, preferably 1 〇 to 40% by mass. When the amount is less than 5% by mass, the light sensitivity or the image strength is lowered, and if it is more than 50% by mass, the adhesion of the photosensitive resin layer is excessive, so It is not required. The photosensitive resin layer contains a little color when forming a colored image on the transfer target. Ordinary pigments are classified into organic pigments and inorganic pigments. The coating film of the former is excellent in transparency, and the latter generally has excellent hiding properties, etc., and can be appropriately selected depending on the application. Moreover, other metal powders can be used. Oxidized metal powder, fluorescent pigment, etc. Suitable pigments such as azo pigments, phthalocyanine pigments, anthraquinone pigments, dioxin pigments, quinophthalone pigments, isoindolinone pigments, A nitro-based pigment, etc. The pigment used for the photosensitive resin layer is distinguished by a hue, and is exemplified below, but is not limited thereto. These pigments or dyes may be used singly or in combination of several kinds. · 1. Pigment Red 97, C · I. Pigment Red 122, C. I · Pigment Red 149, c. I. Pigment Red 168, CI Pigment Red 177, CI Pigment Red 180, CI Pigment Red 192, C · I Pigment Red 21 5, C · I . No · 1 20 8 5, C. I · NO · 1 21 20, -24- 1259813 C. I · Ν ο . 1 2 1 4 Ο, C . I · N 〇· 1 2 3 1 5 etc. Organic material 2) Green pigment C. I · Pigment green 7, c. I. Pigment green 3 6、c I. N 〇. 4 2 0 5 3, (:·Ι·Ν〇·42085, CIn〇.4 2 095 and other organic pigments 3) Blue pigment C · I. Pigment blue 1 5 : 1, c ·颜料.Pigment Blue 丨5: 4, C.〗. Pigment Blue 1 5 : 6, C. I · Pigment Blue 2 2, c · I. Pigment Blue 6 0, C. I · Pigment Blue 6 4, (:· Ι·Μ〇·42052, (:·Ι·ν〇·42090 and other organic pigments 4) yellow pigment

Pigment Yellow(顏料黃）i2(C.I.No.21〇90) 例）Permanent Yellow(永久黃）DHG(克拉瑞日本（股）製） 、Lionol Yellow(里歐羅魯（譯音）黃）ι212Β(東洋油墨製 造（股）製）、Irgalite Yellow(衣魯卡賴頓（譯音）黃）LCT( 汽巴特殊化學（股）製）、Symuler Fast Yellow(西姆拉法史 頓（譯首）頁）GTF 219(大曰本油墨化學工業（股）製） Pigment Yellow(顏料黃）13(C i n〇.2u〇〇) 例）Permanent Ye ll〇w(永久黃）Gr(克拉瑞日本（股）製） 、L1〇n〇l Yellow(里歐羅魯（譯音）黃）ι313(東洋油墨製造 (股）製）、Pigment Yellow i2 (CINo.21〇90) Example) Permanent Yellow (permanent yellow) DHG (Clarence Japan), Lionol Yellow (Liuoluo (trans)) yellow ι212 Β (Toyo Ink Manufacturing (share) system, Irgalite Yellow (Linka Carreton (transliteration) yellow) LCT (Ciba special chemical (share) system), Symeler Fast Yellow (Simula Fasten (translation) page) GTF 219 (Otsuka Ink Chemical Industry Co., Ltd.) Pigment Yellow 13 (C in〇.2u〇〇) Example) Permanent Ye ll〇w (permanent yellow) Gr (Clarence Japan (share) system), L1〇n〇l Yellow (Lio Oro (trans) yellow) ι313 (Toyo Ink Manufacturing Co., Ltd.),

Pigment Yell〇w(顏料黃）No.21095) 例）Permanent Yen〇w(永久黃）G(克拉瑞日本（股）製）、 L1〇n〇l Yellow(里歐羅魯（譯音）黃）14〇1_G(東洋油墨製造 (股）製）、Seda Fast Yellow(西卡法史頓（譯音）黃）227〇( 大日精化工業（股）製）、Symuler Fas t YeU〇w(西姆拉法史 1259813 頓黃）4400 (大日本油墨化學工業（股）製）Pigment Yell〇w (Pigment Yellow) No. 21095) Example) Permanent Yen〇w (permanent yellow) G (Clarence Japan (share) system), L1〇n〇l Yellow (Lio Orolu (transliteration) yellow) 14 〇1_G (Toyo Ink Manufacturing Co., Ltd.), Seda Fast Yellow 227〇 (Daily Seiki Co., Ltd.), Symarer Fas t YeU〇w (Simula Fafa) History 1259813 Dunhuang) 4400 (Daily Ink Chemical Industry Co., Ltd.)

Pigment Yellow(顔料黃）17(C I N〇.2n〇5) 例）P e r m a n e n t Y e 1 1 0 w (永久黃）GG 〇 2 (克拉瑞日本（股）製） 、Symu 1 e 1； Fa s t Ye π 〇w (西姆拉法史頓黃）8GF (大日本油 墨化學工業（股）製） P 1 g m e n t Y e 1 1 〇 w (顏料黃）丄 5 5 例）G r a p h t ο 1 Y e 1 1 ◦ w (古拉夫頓魯（譯音）黃）3 Gp (克拉瑞 日本（股）製）Pigment Yellow 17 (CIN〇.2n〇5) Example) Human Y Y 1 1 0 w (permanent yellow) GG 〇 2 (Clarui Japan (stock) system), Symu 1 e 1; Fa st Ye π 〇w (Simla Fashen Yellow) 8GF (Daily Ink Chemical Industry Co., Ltd.) P 1 gment Y e 1 1 〇w (pigment yellow) 丄 5 5 cases) G rapht ο 1 Y e 1 1 ◦ w (Gulafton Lu (transliteration) Huang) 3 Gp (Clarence Japan (share) system)

Pigment Yellow(顏料黃）i80(c i n〇.2129〇) 例）Novoperm Yell〇w(羅伯帕姆（譯音）黃）p_HG(克拉瑞 日本（股）製）、PV Fas t Ye 1 1 〇w(法史頓（譯音）黃）HG(克拉 瑞日本（股）製）Pigment Yellow i80 (cin〇.2129〇) Example) Novoperm Yell〇w (Robo Pam) p_HG (Clarion Japan), PV Fas t Ye 1 1 〇w ( Fashton (transliteration) Huang) HG (Clarui Japan (share) system)

Pigment Yellow(顏料黃）^9((:.1^0.5 6 2 9 8 ) 例）Novoperm Yellow(羅伯帕姆（譯音）黃）M2R 70(克拉 瑞日本（股）製） 5 )品紅顏料Pigment Yellow (pigment yellow) ^9 ((:.1^0.5 6 2 9 8 ) Example) Novoperm Yellow (Rober Pam (trans) yellow) M2R 70 (Clarion Japan (share) system) 5) magenta pigment

Pigment Red(顏料紅）57: 1(C.I.No. 15850: 1) 例）Graphtol Yellow(古拉夫頓魯（譯音）黃）L6B(克拉 瑞日本（股）製）、Lionol Red(里歐羅魯（譯音）紅）6B-4290G( 東洋油墨製造（股）製）、I r g a 1 i t e R u b i n e (衣魯卡拉衣頓（ 譯音）紅）4BL(汽巴特殊化學（股）製）、Symuler Brilllant Carnune (西姆拉布里里恩頓卡敏（譯音））6B- 229 (大日本油 墨化學工業（股）製）Pigment Red 57: 1 (CINo. 15850: 1) Example) Graphtol Yellow L6B (Clarence Japan), Lionol Red (Lionol Red (Liuol Red) Transliteration) Red) 6B-4290G (Toyo Ink Manufacturing Co., Ltd.), Irga 1 ite R ubine (Italy Caraton), 4BL (Ciba Specialty Chemicals), Symeler Brilllant Carnune ( Simla Brienton Kamin (transliteration) 6B-229 (Daily Ink Chemical Industry Co., Ltd.)

Pigment Red(顏料紅）122(C.I.No.73915) 1259813 例）Η o s t e r p e r m P i n k (哈史塔帕姆（譯音）粉紅）E (克拉瑞 曰本（股）製）、L i ο η o g e η M a g e n t a (里歐羅肯馬雷塔（譯音）） 5 7 9 0 (東洋油墨製造（股）製）、F a s t 〇 g e n S u p e r M a g e n t a (法 史頓卡史帕馬雷塔（譯音））RH (大日本油墨化學工業（股）製 )Pigment Red 122 (CI No.73915) 1259813 Example) oster osterperm P ink (Hastak Pam) E (Clarion 曰本(股)), L i ο η oge η M Agenta (Lioren Kenemata) 5 7 9 0 (Toyo Ink Manufacturing Co., Ltd.), Fast 〇gen S uper M agenta (Faithonka Spar Maretta (transliteration)) RH (Daily Ink Chemical Industry Co., Ltd.)

Pigment Red(顏料紅）53: 1(C.I.No. 15585: 1)Pigment Red 53: 1 (C.I. No. 15585: 1)

例）Permanent Lake Red(永久湖紅）LCY(克拉瑞日本（ 股）製）、Symuler Lake Red(西姆拉法史湖紅）C cone(大 臼本油墨化學工業（股）製）Example) Permanent Lake Red (Permanent Lake Red) LCY (Clarence Japan (share) system), Symerer Lake Red (Simmuler Lake Red) C cone (made by Otsuka Ink Chemical Industry Co., Ltd.)

Pigment Red(顏料紅）48: l(C.I.No.l 5 8 6 5: 1 ) 例）Lionol Red(里歐羅魯（譯音）紅）2B 3 3 00 (東洋油墨 製造（股）製）、Symulei· Red(西姆拉雷頓（譯音）紅）NRY (大 日本油墨化學工業（股）製）Pigment Red 48: l (CINo.l 5 8 6 5: 1 ) Example) Lionol Red 2B 3 3 00 (Toyo Ink Manufacturing Co., Ltd.), Symulei · Red (Sim Lareton) NRY (Daily Ink Chemical Industry Co., Ltd.)

Pigment Red(顏料紅）48: 2(C.I.No.l 5 8 6 5: 2 )Pigment Red 48: 2 (C.I.No.l 5 8 6 5: 2 )

例）Permanent Red(永久紅）W2T(克拉瑞日本（股）製）、 Llon〇l Red(里歐羅魯（譯音）紅）LX2 3 5 (東洋油墨製造（股） 製）、Symuler Red(西姆拉雷頓（譯音）紅）3012(大日本油 馨化學工業（股）製）Example) Permanent Red W2T (Clarence Japan), Llon〇l Red LX2 3 5 (Toyo Ink Manufacturing Co., Ltd.), Symerer Red (West) Mla Layton (transliteration) red) 3012 (Daily Yuxin Chemical Industry Co., Ltd.)

Pigment Red(顏料紅）48: 3(C.I.No.l5865: 3) 例）Permanent Red(永久紅）3RL(克拉瑞日本（股）製）、 Symuler Red(西姆拉雷頓（譯音）紅）2BS(大曰本油墨化學 工業（股）製）Pigment Red 48: 3 (CINo.l5865: 3) Example) Permanent Red 3RL (Clarence Japan), Symuler Red 2BS (Otsuka Ink Chemical Industry Co., Ltd.)

Pigment Red(顏料紅）177(C.I.N〇.65300) 例）C r o m o p h t a 1 R e d (克羅麻夫塔魯（譯音）紅）A 2 B (汽巴 -27- 1259813 特殊化學（股）製） 6 )氰基顏料 竹監）1 5 ( C · I . 例）L i 〇 n 〇 1 B 1 i_i e (串阿 p ㈣一 、 里^維货、（自幸苜）藍）7 0 2 7 (東洋油墨製 造（股）製）、F a s t 〇 〇 e n R 〗Pigment Red 177 (CIN 〇.65300) Example) C romophta 1 R ed (Kroyavtaru (trans)) red A 2 B (Ciba -27-1259813 special chemical (share) system) 6 ) Cyan-based pigment bamboo) 1 5 (C · I. Example) L i 〇n 〇1 B 1 i_i e (string a p (four) one, Li ^ Wei goods, (self-fortunately) blue) 7 0 2 7 ( Toyo Ink Manufacturing Co., Ltd., Fast 〇〇en R 〗

Blue(法史頓肯（譯音）藍）Ββ(大日 本油墨化學工業（股）製）Blue (French Winken (transliteration) blue) Ββ (Daily Ink Chemical Industry Co., Ltd.)

Pigment Blue(顏料藍 ^ m ) 15. 1 (C . I . No . 74 1 60 ) 例)Η o s t e r P e r m b 1 ” ρ / 於出—仏丄Pigment Blue 15. 1 (C.I. No. 74 1 60 ) Example) Η o s t e r P e r m b 1 ” ρ / 于出—仏丄

Ue(哈史纟合帕姆（譯音）藍）A2R(克拉 瑞曰本（脸）製）、F a " t〇gen Blue(法史頓肯（譯音）藍）5〇5〇( 大日本油墨化學工檠（股）製）Ue (Ha Shi 纟 帕 帕 帕 译 译 ) ) ) ) ) ) ) ) ) A A 克拉 克拉 克拉 克拉 克拉 克拉 克拉 克拉 克拉 克拉 A 大 大 大 大 大 大 大 大 大 大 大 大 大 大 大 大 大 大 大 大 大 大 大 大Ink chemical industry (shares) system)

Pigment BUe(_ 料薜 忖皿）15 · 2(C· I ·ν〇.74 1 60 ) 例）Η o s t e r p e r πι β 1丨〗Ρ，岭出砍—… iue(哈史i合帕姆（譯音）藍）AFL(克拉 瑞日本（股）製）' I r α a〗彳t ρ β ] ( f y & a 1 i t e B 1 u e (衣魯卡拉衣頓（譯音）藍） BSP(汽巴特殊化學（脸）製、^ f 、收）衣）、Fas t0gen Blue(法史頓肯（譯 音）藍）GP(大日本油墨化學工業（股）製）Pigment BUe(_料薜忖)15 · 2(C· I ·ν〇.74 1 60 ) Example)Η osterper πι β 1丨〗 Ρ, 岭出砍—... iue (哈史i合帕姆(译音) ) blue) AFL (Clarui Japan (share) system) ' I r α a〗 彳t ρ β ] ( fy & a 1 ite B 1 ue (衣鲁卡拉衣顿(译音)蓝) BSP (Ciba special Chemical (face) system, ^ f , and collection), Fas t0gen Blue (Faithon Ken (trans)) GP (Daily Ink Chemical Industry Co., Ltd.)

Plgment BUe(彥頁料藍）15: 3(C i n〇 74i6〇) 例）Hosterperm Blue(哈史塔帕姆（譯音）藍）B2G(克拉 瑞日本（股）製）、L1〇nol Blue(里歐羅魯（譯音）藍）fg7 3 3 〇( 東洋油出衣® (I )製）、Cr〇m〇phtal β1μ(克羅麻夫塔魯（ 譯音）藍）4GNP(汽巴•特殊•化學（股）製）、Fast〇genBi^( 法史頓肯（譯音）藍）FGF(大日本油墨化學工業（股）製） Pigment BUe(顏料藍）15 : 4(C I n〇 74i6〇) 例）Hosterperm Blue(哈史塔帕姆（譯音）藍）（克拉 瑞日本（k )製）、Cyanine B1 ue(氰基藍）7〇〇_ i〇fg(東洋油 -28 - 1259813 墨製造（股）製）、T ^ . ώ 1 κ e B hi e (衣魯卡拉衣頓（譯音）藍） 細汽巴特殊化學(股)製）、Bue(法史頓肯(譯 音厂藍）FGS(大日本油墨化學工業（股）製）Plgment BUe (Yin page blue) 15: 3 (C in〇74i6〇) Example) Hosterperm Blue (Hastapram Blue) B2G (Clarence Japan (share) system), L1〇nol Blue (Li Euroru (French) Blue) fg7 3 3 〇 (Toyo Oil Apparel® (I)), Cr〇m〇phtal β1μ (Kroyavtaru (trans)) Blue 4GNP (Ciba • Special • Chemistry (share) system), Fast〇genBi^ (Faithonken (trans) blue) FGF (Daily Ink Chemical Industry Co., Ltd.) Pigment BUe (pigment blue) 15 : 4 (CI n〇74i6〇) Example) Hosterperm Blue (Hastakamp (trans) blue) (Clarence Japan (k) system), Cyanine B1 ue (cyano blue) 7〇〇_ i〇fg (Toyo Oil -28 - 1259813 ink manufacturing (shares) System), T ^ . ώ 1 κ e B hi e (Yelu Caraton (transliteration) blue) Fine Carat special chemical (share) system, Bue (Fa Shi Dunken (Transliteration Factory Blue) FGS (Greater Japan) Ink chemical industry (share) system)

Plgment BUe(顏料藍）丨 6(^^74160) 例）L 1 〇 n 〇 1 β 1 (股）製）Plgment BUe (pigment blue) 丨 6 (^^74160) Example) L 1 〇 n 〇 1 β 1 (share) system)

Ue(里歐羅魯（譯音）藍）ES(東洋油墨製 造 plg 紅 rn Blue(顏料藍）6〇(C i n〇.6 9 8〇〇) 例）Hosterpeim Blue(哈史塔帕姆（譯音）藍）rL〇1(克拉Ue (Lio Oro) ES (Toyo Ink plg red rn Blue (pigment blue) 6 〇 (C in 〇.6 9 8 〇〇))) Hosterpeim Blue (Hastrampam (transliteration) Blue)rL〇1 (carat

ί而曰本（&〇製）L1〇nogen BUe(里歐羅肯（譯音）藍）65〇1( 東洋油墨製造（股）製） 7 )黑色顏料曰和曰本(&〇)L1〇nogen BUe(里欧罗肯(译音)蓝)65〇1(Toyo Ink Manufacturing Co., Ltd.) 7) Black Pigment

Pigment BUck(顏料黑）7(碳黑 c.lno.77 266) 例）一變碳黑MA100(三菱化學（股）製）、三菱碳黑#5( 一羑化學（股）製）、B丨a c k p e r a 1 s (黑色帕魯斯（譯音）） 430(Cabot Co.(奇帕頓（譯音）製）Pigment BUck (pigment black) 7 (carbon black c.lno.77 266) Example) A carbon black MA100 (Mitsubishi Chemical Co., Ltd.), Mitsubishi Carbon Black #5 (one 羑Chemical (share) system), B丨Ackpera 1 s (Black Parus) 430 (Cabot Co.)

而且，本發明可使用的顏料可參照「顏料便覽、日本顏 料技術丨肋會；r扁、誠文堂新光社、1 9 8 9」、「（] 〇 l 0 U R I N D E X THE SOCIETY OF DYES & COLOURIST λ THIRD EDITION " 1987 」等選擇適當商品。 上述染料或顏料之平均粒徑通常爲5 μηι以下、較佳者爲 ΙμΐΏ以下。製作濾色片時以〇 . 5μπι以下較佳。 感光性樹脂組成物除上述成分外另以含有熱聚合防止劑 較佳。熱聚合防止劑例如氫醌、對-甲氧基苯酚、對-第3 -丁基兒茶酚、2，6 -二-第3 - 丁基-對-甲酚、β _萘酚、焦培 -29- 1259813 酚等芳香族羥基化合物、苯醌、對-甲苯醌等醌類、萘胺、 對-甲苯胺、吩噻畊等之胺類、N -硝基苯基羥基胺之鋁鹽或 銻鹽、氯醌、硝基苯、4 , 4，-硫化雙（3 -甲基-6 -第3 - 丁基 苯酚）、2，2，-伸甲基雙（4 -甲基-6 -第3 - 丁基苯酚）、2 -锍 基苯并咪唑等。 感光性樹脂組成物另視其所需可添加習知添加物’例如 可塑劑、本發明用界面活性劑外之界面活性劑、密接促進 劑、分散劑、可塑劑、防止垂下劑、均平劑、消泡劑、難 燃劑、光澤劑、溶劑等。 密接促進劑例如烷基苯酚/甲醛酚醛淸漆樹脂、聚乙烯基 乙醚、聚乙烯基異丁醚、聚乙烯基丁縮醒、聚異丁烯、苯 乙烯-丁二烯共聚物橡膠、丁基橡膠、氯乙烯-醋酸乙烯酯 共聚物、氯化橡膠、丙烯酸樹脂系黏合劑、芳香族系、脂 肪族系或脂環族系石油樹脂、矽烷偶合劑等。 藉由感光性樹脂組成物形成的感光性樹脂層之層厚以 0.5〜ΙΟμηι較佳、更佳者爲1〜5μπι。 感光性樹脂層例如藉由使著色劑與樹脂之混合物分散後 ，使其他材料混合製得者。 本發明之影像形成材料例如在上述載體上塗覆鹼可溶性 熱可塑性樹脂層形成用塗覆液、乾燥，設置熱可塑性樹脂 層，在該熱可塑性樹脂層上塗覆不會使熱可塑性樹脂層溶 解的感光性樹脂層形成用塗覆液、乾燥，設置感光性樹脂 層而製得。熱可塑性樹脂層與感光性樹脂層之間亦可設置 阻氧層。例如在載體上設置熱可塑性樹脂層，於其上塗覆 -30- 1259813 使用不會使熱可塑性樹脂層溶解的溶劑之阻氧層形成用塗 覆液、乾燥，設置阻氧層，另於該阻氧層上使用不會使阻 氧層溶解的溶劑塗覆感光性樹脂層形成用塗覆液、乾燥’ 設置感光性樹脂層予以形成。或藉由在下述被覆片板上設 置感光性樹脂層，另在載體上設置熱可塑性樹脂層與阻氧 層，各使阻氧層與感光性樹脂層接合下予以貼合’或藉由 在被覆片板上設置感光性樹脂層與阻氧層’另在載體上設 置熱可塑性樹脂層，與上述相同地各與阻氧層與感光性樹 脂層接合下予以貼合、製得。 上述鹼可溶性熱可塑性樹脂層、阻氧層、感光性樹脂層 之各層可以習知方法設置各層形成用塗覆液（通常使組成物 溶解於有機溶劑中）。例如使用旋轉塗覆器、輥塗覆器、簾 幕塗覆器、刀塗覆器、鐵線塗覆器、擠壓機等之塗覆機， 使各層形成用塗覆液塗覆、且藉由乾燥形成。 於本發明中，以至少感光性樹脂層藉由旋轉塗覆器旋轉 塗覆較佳，更佳者爲全部塗覆層藉由旋轉塗覆。塗覆條件 係視層厚、組成等而定予以適當設定，通常例如在1 m2中 於中央邰滴下10〜700ml之塗覆液，且在以100〜lOOOrpm 旋轉塗覆的方法。 製作各層形成用塗覆液所使用的溶劑例如甲基乙酮、丙 二醇單甲醚、丙二醇單甲醚乙酸酯、環己酮、環己醇、乳 酸乙酯、乳酸甲酯、己內酯等。 在感光性樹脂層上爲保護保管等時之污染或損傷時，以 設置薄的被覆片板較佳。被覆片板可以爲由與載體相同或 - 31- 1259813 類似材料所成者’可容易自感光性樹脂層分離者。被覆片 板所使用的材料例如聚矽氧烷紙、聚烯烴片板或聚四氟化 乙烷片板等較佳。被覆片板之厚度通常爲5〜1 〇 〇 μπι、較佳 者爲1 0〜3 Ο μ m。 通常，在玻璃基板等之永久載體上貼合影像形成材料之 感光性樹脂層、剝落載體時，帶電載體（薄膜）與人體受到 不快的靜電驚嚇，或在帶電的載體上附著塵埃等之問題產 生。因此，以在載體上設置導電層，且對載體本身施予具 有導電性處理較佳。而且，在載體反側（不具感光性樹脂層 之側）上設置時，爲提高耐傷性時以設置疏水性聚合物層較 佳。 使用本發明影像形成材料製造濾色片等之多色影像片板 ’例如可如下述進行。形成紅、綠、藍各畫素時，使用具 有紅色畫素用紅色感光性樹脂層之影像形成材料，使紅色 感光性樹脂層轉印於基板表面、如影像之曝光、顯像以形 成紅色畫素，有關綠、藍時亦相同地藉由形成各畫素進行 。配置紅、綠、監等二種畫素時，可以配置4畫素配置型 等任一種配置。 畫素片板之各畫素上面在各畫素間的隙間範圍使用具有 黑色感光性樹脂層之影像形成材料，使黑色感光性樹脂層 轉印於基板表面，且知面曝光（自不具畫素側）、顯像以形 成黑色矩陣。藉由使影像片板加熱，可使爲硬化部分硬化（ 有關各畫素各予以進行）。 本發明之影像形成材料貼合於基板表面時，一般係除去 — 32- 1259813 影像形成材料之感光性樹脂層上的被覆片板後，使影像形 成材料在基板表面上重疊，在加壓、加熱下進行。貼合可 使用積層器、真空積層器及可更爲提筒生產性之自動切斷 積層器等之習知積層器。然後，剝取載體後’經由所定光 罩、熱可塑性樹脂層及阻氧層以使感光性樹脂層曝光，再 除去未曝光範圍（顯像）。上述曝光所使用的光源係視感光 性樹脂層之感光性而定予以選擇。例如超高壓水銀燈、氙 氣燈、碳電弧燈、氬氣雷射光等習知者。特開平6 - 5 9 1 1 9 號公報中記載倂用400nm以上波長之光透過綠爲2%以下之 光學過濾器等。 感光性樹脂層之顯像液可使用鹼性物質之稀薄水溶液， 另可使用添加少量與水具混合性之有機溶劑者。適當的鹼 性物質例如鹼金屬氫氧化物類（例如氫氧化鈉、氫氧化鉀） 、鹼金屬碳酸鹽類（例如碳酸鈉、碳酸鉀）、鹼金屬重碳酸 鹽類（例如碳酸氫鈉、碳酸氫鉀）、鹼金屬矽酸鹽類（例如矽 酸鈉、矽酸鉀）、鹼金屬偏矽酸鹽類（例如偏矽酸鈉、偏矽 酸鉀）、三乙醇胺、二乙醇胺、單乙醇胺、嗎啉、四烷銨氫 氧化物類（例如四甲銨氫氧化物）或磷酸三鈉。鹼性物質之 濃度爲〇 . 01〜30質量％，pH以8〜14較佳。 與水具混合性之適當有機溶劑例如甲醇、乙醇、2 -丙醇 、1-丙醇、丁醇、二丙酮醇、乙二醇單甲醚、乙二醇單乙 醚、乙二醇單正丙醚、苯甲醇、丙酮、甲基乙酮、環己酮 、ε-己內酯、I丁內酯、二甲基甲醯胺、二甲基乙醯胺、 六甲基磷醯胺、乳酸乙酯、乳酸甲酯、ε -己內醯胺、Ν -甲 -33- 1259813 基吡咯烷酮。與水具混合性之有機溶劑的濃度一般爲〇 · 1 〜3 0質量％。 而且，顯像液中可添加習知的界面活性劑。 顯像亦可使用浴液、或作爲噴霧液使用。爲除去感光性 樹脂層之未硬化部分時可適當利用在顯像液中可以回轉刷 子擦拭或以濕潤海綿擦拭等方法、或利用噴霧顯像液時之 噴霧壓方法等。顯像液之液溫度通常爲室溫〜40 °C較佳。 顯像處理後可施予水洗工程。而且，顯像處理係可以一次 處理鹼可溶性熱可塑性樹脂層、阻氧層及感光性樹脂層’ 惟爲減少顯像斑或感光性樹脂層顯像時因顯像容易造成的 層惡化情形時，可先溶解除去鹼可溶性熱可塑性樹脂層及 阻氧層後，進行感光性樹脂層之顯像較佳。然後，進行感 光性樹脂層之顯像時，除去鹼可溶性熱可塑性樹脂層及阻 氧層時使用的顯像液以選擇不會使感光性樹脂層惡化者較 佳。該方法可就考慮鹼可溶性熱可塑性樹脂層及阻氧層、 與感光性樹脂層間溶解速度差時，藉由選擇顯像液、或藉 由適當組合噴霧壓、擦拭時之壓力等顯像處理條件予以進 行。藉由該方法可抑制顯像斑。 顯像工程後進行加熱處理。換言之，使具有藉由曝光硬 化的感光性樹脂層的載體在電爐、乾燥器中加熱，或在感 光性樹脂層上照射紅外線燈予以加熱。加熱溫度及時間與 感光性樹脂層之組成或厚度等有關，一般而言爲得到充分 耐溶劑性、耐鹼性時，較佳者爲在約1 2 0〜2 5 0 °C下加熱、 約10〜300分鐘。 -34- 1259813 本發明之影像形成材料基本上有利於使用製作濾色片 之多色影像，其他可使用於層間絕緣膜、印刷配線基 凹版凸版印刷版、商標、多色試驗印刷試樣、平版印r. 或絲網印刷模板等。製作印刷配線基板時通常使用習史：：、. 合有積層板作爲基板。 (四）實施方式 t施發明之最佳形熊 於下述中以實施例爲基準等更具體地說明本發明，惟本 發明不受此等實施例所限制。而且，文中沒有特別限_ _ ’ 「份」係指「質量份」。 實施例1 (實施例丨_ 1〜實施例丨-丨5 )、比較例（比較例1 -1〜i • / 1 )本發明用界面活性劑s 1 - 1〜S 1 - 5 (共聚物（1 ))之合成 使用表1-1所示單體（a)、單體（b)及單體（c)，合成同表 所示具有質量平均分子量之本發明用界面活性劑。 1259813 -—---- 單體(b) 單體(c) 共聚合比 (a) : (b) : (c) (質量比） 質量平均 分子量 --一 Rq4 r2 R3 P R〇5 R〇6 CHh -CH2- ch3 10 ch3 ch3 40:3:57 10000 CH^ -CH2- ch3 10 ch3 ch3 40:3:57 10000 Cl· -ch2- ch3 10 ch3 ch3 40:3:57 10000 ch3 -ch2- ch3 10 ch3 ch3 40:3:57 10000 CHi -ch2- ch3 10 ch3 ch3 40:3:57 10000 表1-1Further, the pigments which can be used in the present invention can be referred to "Pigment Fact Sheet, Japanese Pigment Technology, Rib Club; r flat, Cheng Wentang Xinguang Society, 189 9", "(] 〇l 0 URINDEX THE SOCIETY OF DYES & COLOURIST λ THIRD EDITION " 1987 ”, etc. The average particle size of the dye or pigment is usually 5 μηι or less, preferably ΙμΐΏ or less. When the color filter is prepared, it is preferably 5 μm or less. In addition to the above components, a thermal polymerization preventing agent is preferably contained. A thermal polymerization preventing agent such as hydroquinone, p-methoxyphenol, p-butyl 3-catechol, 2,6-di- 3 - Aromatic hydroxy compounds such as butyl-p-cresol, β-naphthol, pyrolysis -29- 1259813 phenol, anthracene such as benzoquinone or p-toluene, naphthylamine, p-toluidine, phenothiline, etc. An amine, an aluminum or cesium salt of N-nitrophenylhydroxylamine, chloranil, nitrobenzene, 4,4,-sulfurized bis(3-methyl-6-tert-butylphenol), 2, 2,-Extended methyl bis(4-methyl-6-tert-butylphenol), 2-mercaptobenzimidazole, etc. Photosensitive resin composition It is necessary to add a conventional additive such as a plasticizer, a surfactant other than the surfactant for use in the present invention, a adhesion promoter, a dispersant, a plasticizer, a drape preventer, a leveling agent, an antifoaming agent, and a flame retardant. Agent, brightener, solvent, etc. Adhesion promoter such as alkylphenol/formaldehyde phenolic enamel resin, polyvinyl ether, polyvinyl isobutyl ether, polyvinyl butyrate, polyisobutylene, styrene-butadiene Copolymer rubber, butyl rubber, vinyl chloride-vinyl acetate copolymer, chlorinated rubber, acrylic resin binder, aromatic, aliphatic or alicyclic petroleum resin, decane coupling agent, etc. The layer thickness of the photosensitive resin layer formed of the resin composition is preferably 0.5 to ΙΟμηι, more preferably 1 to 5 μm. The photosensitive resin layer is dispersed by mixing other materials, for example, by dispersing a mixture of the colorant and the resin. The image forming material of the present invention is coated with a coating liquid for forming an alkali-soluble thermoplastic resin layer on the carrier, and dried, and a thermoplastic resin layer is provided in the thermoplastic tree. The coating layer for forming a photosensitive resin layer which does not dissolve the thermoplastic resin layer is applied to the lipid layer, and is dried, and a photosensitive resin layer is provided, and an oxygen barrier can be provided between the thermoplastic resin layer and the photosensitive resin layer. For example, a thermoplastic resin layer is provided on a carrier, and a coating liquid for forming an oxygen barrier layer which is a solvent which does not dissolve the thermoplastic resin layer is used, and an oxygen barrier layer is provided, and an oxygen barrier layer is provided. The oxygen barrier layer is formed by applying a coating liquid for forming a photosensitive resin layer without dissolving the oxygen barrier layer, and drying the photosensitive resin layer. Or by providing a photosensitive resin layer on the following coated sheet, and further providing a thermoplastic resin layer and an oxygen barrier layer on the carrier, and bonding the oxygen barrier layer and the photosensitive resin layer to each other or by coating A photosensitive resin layer and an oxygen barrier layer are provided on the sheet. Further, a thermoplastic resin layer is provided on the carrier, and the oxygen barrier layer and the photosensitive resin layer are bonded to each other in the same manner as described above. Each of the alkali-soluble thermoplastic resin layer, the oxygen barrier layer, and the photosensitive resin layer may be provided with a coating liquid for forming each layer (usually, the composition is dissolved in an organic solvent) by a known method. For example, a coating machine for forming a layer is coated with a coating machine using a spin coater, a roll coater, a curtain coater, a knife coater, an iron coater, an extruder, or the like, and borrowed It is formed by drying. In the present invention, it is preferred to spin-coat at least the photosensitive resin layer by a spin coater, and more preferably all of the coating layers are spin-coated. The coating conditions are appropriately set depending on the thickness of the layer, the composition, and the like, and usually, for example, a coating liquid of 10 to 700 ml is dripped in the center crucible at 1 m 2 and spin-coated at 100 to 1000 rpm. A solvent used for producing the coating liquid for forming each layer, for example, methyl ethyl ketone, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, cyclohexanone, cyclohexanol, ethyl lactate, methyl lactate, caprolactone, or the like. . When the photosensitive resin layer is contaminated or damaged during storage or the like, it is preferable to provide a thin coated sheet. The coated sheet may be one which is free from the photosensitive resin layer by the same material as the carrier or the like - 31 - 1259813. Materials such as polysiloxane paper, polyolefin sheet or polytetrafluoroethylene sheet are preferably used for the coated sheet. The thickness of the coated sheet is usually 5 to 1 〇 〇 μπι, preferably 1 0 to 3 Ο μ m. In general, when a photosensitive resin layer or a peeling carrier of an image forming material is bonded to a permanent carrier such as a glass substrate, the charged carrier (film) and the human body are subjected to an unpleasant electrostatic shock, or a problem such as adhesion of dust to a charged carrier occurs. . Therefore, it is preferred to provide a conductive layer on the carrier and to impart a conductive treatment to the carrier itself. Further, when it is provided on the reverse side of the carrier (the side not having the photosensitive resin layer), it is preferable to provide a hydrophobic polymer layer in order to improve the scratch resistance. The production of a multicolor image sheet of a color filter or the like using the image forming material of the present invention can be carried out, for example, as follows. When red, green, and blue pixels are formed, an image forming material having a red photosensitive resin layer for red pixels is used, and the red photosensitive resin layer is transferred onto the surface of the substrate, such as image exposure and development to form a red color. In the case of green and blue, the same is done by forming each pixel. When configuring two types of pixels, such as red, green, and monitor, you can configure any of the four pixel configuration types. The image forming material having a black photosensitive resin layer is used in each of the pixels of the lithographic sheet, and the black photosensitive resin layer is transferred onto the surface of the substrate, and the surface is exposed (there is no pixel) Side), developed to form a black matrix. By hardening the image sheet, it is possible to harden the hardened portion (for each pixel). When the image forming material of the present invention is bonded to the surface of the substrate, the coated sheet on the photosensitive resin layer of the image forming material is removed, and the image forming material is superposed on the surface of the substrate, and pressurized and heated. Go on. For the lamination, a conventional laminator such as a laminator, a vacuum laminator, and an automatic cutting laminator which can further improve the productivity of the cartridge can be used. Then, after the carrier is peeled off, the photosensitive resin layer is exposed through the predetermined mask, the thermoplastic resin layer, and the oxygen barrier layer, and the unexposed range (development) is removed. The light source used for the above exposure is selected depending on the photosensitivity of the photosensitive resin layer. For example, ultrahigh pressure mercury lamps, xenon lamps, carbon arc lamps, argon lasers, and the like are well known. Japanese Laid-Open Patent Publication No. Hei 6-5-9 1-9 discloses an optical filter that transmits light having a wavelength of 400 nm or more and a green light of 2% or less. As the developing solution of the photosensitive resin layer, a thin aqueous solution of a basic substance can be used, and a small amount of an organic solvent which is miscible with the water can be used. Suitable basic substances such as alkali metal hydroxides (such as sodium hydroxide, potassium hydroxide), alkali metal carbonates (such as sodium carbonate, potassium carbonate), alkali metal bicarbonates (such as sodium bicarbonate, carbonic acid) Potassium hydrogen hydride, alkali metal silicates (such as sodium citrate, potassium citrate), alkali metal bismuth phthalates (such as sodium metasilicate, potassium metasilicate), triethanolamine, diethanolamine, monoethanolamine, Morpholine, tetraalkylammonium hydroxides (such as tetramethylammonium hydroxide) or trisodium phosphate. The concentration of the alkaline substance is 〇 01 to 30% by mass, and the pH is preferably 8 to 14. Suitable organic solvents mixed with water, such as methanol, ethanol, 2-propanol, 1-propanol, butanol, diacetone alcohol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol mono-propyl Ether, benzyl alcohol, acetone, methyl ethyl ketone, cyclohexanone, ε-caprolactone, l-butyrolactone, dimethylformamide, dimethylacetamide, hexamethylphosphoniumamine, lactate B Ester, methyl lactate, ε-caprolactam, Ν-甲-33-1205913-pyrrolidone. The concentration of the organic solvent to be mixed with the water is generally 〇 1 to 30% by mass. Further, a conventional surfactant may be added to the developing solution. The development can also be carried out using a bath or as a spray. In order to remove the unhardened portion of the photosensitive resin layer, a method in which a brush can be wiped by a rotary brush or a wet sponge in a developing solution, or a spray pressure method using a spray developing solution can be suitably used. The temperature of the liquid of the developing solution is usually from room temperature to 40 ° C. A water washing process can be applied after the development process. Further, in the development process, the alkali-soluble thermoplastic resin layer, the oxygen barrier layer, and the photosensitive resin layer can be treated at the same time. However, when the development of the image spot or the photosensitive resin layer is reduced, the layer deterioration is likely to occur due to development. After the alkali-soluble thermoplastic resin layer and the oxygen barrier layer are dissolved and removed, the development of the photosensitive resin layer is preferred. When the photosensitive resin layer is developed, the developer used in removing the alkali-soluble thermoplastic resin layer and the oxygen barrier layer is preferably selected so as not to deteriorate the photosensitive resin layer. In this method, when the dissolution rate of the alkali-soluble thermoplastic resin layer and the oxygen barrier layer and the photosensitive resin layer are inferior, the developing condition can be selected by selecting a developing solution or by appropriately combining a spray pressure or a pressure during wiping. To be carried out. By this method, the development spot can be suppressed. Heat treatment after the development project. In other words, the carrier having the photosensitive resin layer hardened by exposure is heated in an electric furnace or a drier, or is heated by irradiating an infrared lamp on the photosensitive resin layer. The heating temperature and time are related to the composition or thickness of the photosensitive resin layer, and generally, when sufficient solvent resistance and alkali resistance are obtained, it is preferably heated at about 1 2 0 to 250 ° C. 10 to 300 minutes. -34- 1259813 The image forming material of the present invention is basically advantageous for using a multicolor image for producing a color filter, and the other can be used for an interlayer insulating film, a printed wiring base gravure printing plate, a trademark, a multicolor test printing sample, a lithography plate. Print r. or screen printing template. When manufacturing a printed wiring board, it is common to use a history::,. A laminated board is used as a substrate. (4) Embodiments t The best shape of the invention is described in more detail below on the basis of the examples, but the invention is not limited by the embodiments. Moreover, there is no special limit in the text _ _ ′ “Parts” means “parts by mass”. Example 1 (Example 丨_1 to Example 丨-丨5), Comparative Example (Comparative Example 1-1~i • / 1) Surfactant s 1 - 1 to S 1 - 5 (copolymer) of the present invention (1)) Synthesis Using the monomer (a), the monomer (b) and the monomer (c) shown in Table 1-1, a surfactant of the present invention having a mass average molecular weight as shown in the above table was synthesized. 1259813 ------ Monomer (b) Monomer (c) Copolymerization ratio (a) : (b) : (c) (mass ratio) Mass average molecular weight - one Rq4 r2 R3 PR〇5 R〇6 CHh -CH2- ch3 10 ch3 ch3 40:3:57 10000 CH^ -CH2- ch3 10 ch3 ch3 40:3:57 10000 Cl· -ch2- ch3 10 ch3 ch3 40:3:57 10000 ch3 -ch2- ch3 10 Ch3 ch3 40:3:57 10000 CHi -ch2- ch3 10 ch3 ch3 40:3:57 10000 Table 1-1

2)熱塑性樹脂層形成用塗覆液之調製 熱塑性樹脂層形成用塗覆液c 1-1之5周製 調製由下述組成C 1 - 1所成的熱塑性樹脂層形成用塗覆液 熱塑性樹脂層形成用塗覆液之組成C 1 - 1 : •甲基丙烯酸甲酯/ 2-乙基甲基丙嫌酸酯/苯甲基甲基丙 烯酸酯/甲基丙烯酸共聚物 1 4 . 0份2) Preparation of a coating liquid for forming a thermoplastic resin layer, a coating liquid for forming a thermoplastic resin layer, and a coating liquid for forming a thermoplastic resin layer, which is formed by the following composition C 1 -1 Composition of layer forming coating liquid C 1 - 1: Methyl methacrylate / 2-ethylmethyl propyl acrylate / benzyl methacrylate / methacrylic acid copolymer 1 4 .

(共聚合組成比（莫耳比）= 55/30/10/5、質量平均分子量 二 1 0 萬、T g :約 7 0 °C ) •苯乙烯/丙烯酸共聚物 6 . 0份 (共聚合組成比（莫耳比）=65/35、質量平均分子量=ι萬 、Tg :約 10〇C ) •在雙酣A中使2當纛八乙二醇單甲基丙烯酸酯脫水縮 ^ Z it 5 ·0 份 (BPE- 5 00 :新中村化學（股）製） 50.0 份 •甲基乙酮 -36- 1259813 •甲醇 丨〇. 〇份 •本發明用界面活性劑S 1 -丨 3 . 〇份 (使用作爲20質量％甲基異丁酮、其溶質之份數） 熱塑性樹脂層形成用塗覆液C 1 - 2〜1 - 7之調製 於熱塑性樹脂層形成用塗覆液C 1 - 1之調製中，除本發明 用界面活性劑之種類、添加量變更成如表1 - 2所示。 熱塑性樹脂層形成用塗覆液C 1 - 8之調製 ‘ 於熱塑性樹脂層形成用塗覆液C 1 - 1之調製中，不須調製 本發明用界面活性劑予以調製。 Φ 熱塑性樹脂層形成用塗覆液c 1 - 9之調製 於熱塑性樹脂層形成用塗覆液C 1 - 1之調製中，除使用氟 系界面活性劑 A: C8F17S02N(C4H9)CH2CH20C0CH = CH2 6 0 質量 %與H(0(CH3)CHCH2)60C0CH = CH2 40重量％之共聚物（質量平 均分子量：3萬、甲基異丁酮20質量％溶液）取代本發明用 界面活性劑外，相同地調製。 熱塑性樹脂層形成用塗覆液C 1- 1 0之調製 於熱塑性樹脂層形成用塗覆液C 1 - 1之調製中，除以固成 份量使用等質量份梅卡法克F1 42-D(大日本油墨化學工業（ 股）製）取代本發明用界面活性劑外，相同地調製。 3 )紅色感光性樹脂層形成用塗覆液R 1 ( R 1 - 1〜R 1- 1 〇 ) 紅色感光性樹脂層形成用塗覆液之組成R 1 - 1 t胃_ 調製由下述組成R 1 - 1所成紅色感光性樹脂層形成用 '塗覆 液。 紅色感光性樹脂層形成用塗覆液R 1 - 1 - 3 7 - 1259813 •苯甲基甲基丙烯酸酯/甲基丙烯酸共聚物6 Ο . 0份 (莫耳比=73/27、酸價=73mgKOH/g、質量平均分子量二3 萬、黏度0 . 1 2 P a · s ) •季戊四醇四丙烯酸酯 4 3 . 2份 •米勒酮 2 . 4份 •2-(鄰氯苯基）-4,5 -二苯基咪唑二聚物 2.5份 •衣魯卡哄（譯音）紅色BPT 5 . 4份(copolymerization composition ratio (mole ratio) = 55/30/10/5, mass average molecular weight: 10,000, Tg: about 70 ° C) • styrene/acrylic acid copolymer 6.0 parts (copolymerization) Composition ratio (mol ratio) = 65/35, mass average molecular weight = 10,000, Tg: about 10 〇 C) • Dehydration of 2 纛 octaethylene glycol monomethacrylate in bismuth A 5 · 0 parts (BPE- 5 00: manufactured by Shin-Nakamura Chemical Co., Ltd.) 50.0 parts • Methyl ethyl ketone-36- 1259813 • Methanol 丨〇. • • • Surfactant S 1 -丨3 for the present invention 〇 a coating liquid C 1 -1 prepared by forming a thermoplastic resin layer forming coating liquid C 1 - 2 to 1 - 7 as a coating liquid for forming a thermoplastic resin layer. In the preparation, the type and amount of the surfactant used in the present invention were changed as shown in Table 1-2. Modification of the coating liquid C 1 - 8 for forming a thermoplastic resin layer In the preparation of the coating liquid C 1 -1 for forming a thermoplastic resin layer, it is not necessary to prepare a surfactant prepared by the present invention. Φ Preparation of coating liquid c 1 - 9 for forming a thermoplastic resin layer In the preparation of coating liquid C 1 -1 for forming a thermoplastic resin layer, except for using a fluorine-based surfactant A: C8F17S02N(C4H9)CH2CH20C0CH = CH2 6 0 Copolymer of mass % and H(0(CH3)CHCH2)60C0CH = CH2 40% by weight (mass average molecular weight: 30,000, methyl isobutyl ketone 20% by mass solution) is prepared in the same manner as the surfactant used in the present invention. . In the preparation of the coating liquid C 1 - 1 for forming a thermoplastic resin layer, in the preparation of the coating liquid C 1 -1 for forming a thermoplastic resin layer, the mass fraction of Mecak F1 42-D is used in addition to the solid content. The Dainippon Ink Chemical Industry Co., Ltd. is prepared in the same manner as the surfactant used in the present invention. 3) Coating liquid R 1 (R 1 -1 to R 1 - 1 〇) for forming a red photosensitive resin layer The composition of the coating liquid for forming a red photosensitive resin layer R 1 - 1 t stomach _ modulation consists of the following A coating liquid for forming a red photosensitive resin layer formed by R 1 -1. Red photosensitive resin layer forming coating liquid R 1 - 1 - 3 7 - 1259813 • Benzyl methacrylate / methacrylic acid copolymer 6 Ο . 0 parts (Mo Er ratio = 73 / 27, acid value = 73 mg KOH / g, mass average molecular weight 20,000, viscosity 0. 1 2 P a · s) • pentaerythritol tetraacrylate 4 3 . 2 parts • Millone 2. 4 parts • 2-(o-chlorophenyl)-4 , 5 - diphenylimidazole dimer 2.5 parts • 衣鲁卡哄 (transliteration) red BPT 5. 4 parts

•甲基溶纖劑乙酸酯 5 6 0份 •甲基乙酮 280份 •本發明用界面活性劑S 1 - 1 1 · 0份 (使用20質量％甲基異丁酮20質量％溶液，其溶質之份數） 紅色感光性樹脂層形成用塗覆液R 1 - 2〜1 - 7之調製• Methyl cellosolve acetate 605 parts • methoxyethyl ketone 280 parts • Surfactant S 1 - 1 1 · 0 parts of the present invention (using 20% by mass of methyl isobutyl ketone 20% by mass solution, The number of parts of the solute) The preparation of the coating liquid R 1 - 2 to 1 - 7 for forming a red photosensitive resin layer

於紅色感光性樹脂層形成用塗覆液R 1 - 1之調製中’除$ 發明用界面活性劑之種類、添加量變更成如表1 - 3所示° 紅色感光性樹脂層形成用塗覆液R 1 - 8之調製 於紅色感光性樹脂層形成用塗覆液R 1 - 1之調製中’不須 調製本發明用界面活性劑予以調製。 紅色感光性樹脂層形成用塗覆液R 1 - 9之調製 於紅色感光性樹脂層形成用塗覆液R1 -1之調製中’除使 用上述界面活性劑A取代本發明用界面活性劑外’相同_ 調製。 紅色感光性樹脂層形成用塗覆液R1 -1 0之調製 於紅色感光性樹脂層形成用塗覆液R1 -1之調製中’除以 固成份量使用等質量份梅卡法克F142-D(大日本油墨化學 - 38- 1259813 工業（股）製）取代本發明用界面活性劑外，相同地調製。 上述調製的熱塑性樹脂層形成用塗覆液及紅色感光性樹 脂層形成用塗覆液之性能藉由下述評估，結果如表1 - 2、1 - 3 所示。 (1 )塗覆面狀（塗覆斑） 使塗覆液以旋轉塗覆器以20ml /m2塗覆於載體（PET)上， 以5m/分鐘、60°C乾燥風乾燥30秒。以濃度計測定沒有斑 的部分、濃度高的部分與低的部分予以比較。 ◎:濃度變化爲1%以內 〇：濃度變化爲2%以內 △:濃度變化爲5 %以內 X :濃度變化大於5% (2 )表面凹凸 測定在載體上設置所定乾燥膜厚時之厚度的最大値、最 低値、與平均値之變化寬度。 ◎ : 3%以內 〇：5%以內 △ : 7%以內 X :此等以上 (3)發泡性 採取2 0 m 1塗覆液、置於1 〇 〇 m 1瓶子，強烈上下震動丄〇 次。然後觀察發泡的高度。 ◎:對最初的液深而言小於1 0 %之高度 〇：對最初的液深而言1 0〜1 5 % -39- 1259813 △:對最初的液深而言1 6〜2 0% X :對最初的液深而言21%以上 (4 )消泡性 採取2 0 m 1塗覆液、置於1 0 0 m 1瓶子，強烈上下震動1 0 次。然後測定直至氣泡消失之時間。 ◎:係爲沒有添加界面活性劑時之5倍以下 ◦:係爲沒有添加界面活性劑時之5〜1 0倍 △:係爲沒有添加界面活性劑時之1 〇〜2 0倍 X :係爲沒有添加界面活性劑時之2 1倍以上 表1 -2In the preparation of the coating liquid R 1 -1 for forming a red photosensitive resin layer, the type of the surfactant for the invention and the amount of addition are changed as shown in Table 3-1. The coating for forming the photosensitive resin layer is red. The preparation of the liquid R 1 - 8 in the preparation of the red photosensitive resin layer-forming coating liquid R 1 - 1 does not require preparation of the surfactant of the present invention. In the preparation of the red photosensitive resin layer-forming coating liquid R1 -1 in the preparation of the red photosensitive resin layer-forming coating liquid R 1 - 9 except that the above-mentioned surfactant A is used in place of the surfactant of the present invention. Same _ modulation. In the preparation of the red photosensitive resin layer-forming coating liquid R1 -1 in the preparation of the red photosensitive resin layer-forming coating liquid R1 -1 0, divided by the solid content, the mass fraction of Mekafak F142-D is used. (Daily Ink Chemistry - 38-1259813, manufactured by the company) is prepared in the same manner as the surfactant used in the present invention. The properties of the above-mentioned coating liquid for forming a thermoplastic resin layer and the coating liquid for forming a red photosensitive resin layer were evaluated by the following results, and the results are shown in Tables 1 - 2, 1 - 3. (1) Coating surface (coating spot) The coating liquid was applied onto a carrier (PET) at 20 ml/m 2 in a spin coater, and dried by drying air at 5 m/min, 60 ° C for 30 seconds. The portion having no plaque, the portion having a high concentration, and the portion having a low portion were measured by a concentration meter. ◎: The change in concentration is within 1% 〇: The change in concentration is within 2% Δ: The change in concentration is within 5% X: The change in concentration is greater than 5% (2) The surface roughness is determined by setting the maximum thickness of the dried film thickness on the carrier.变化, minimum 値, and the width of the change in average 値. ◎ : Within 3% 〇: Within 5% △ : Within 7% X: These and above (3) Foaming property is taken to be 20 m 1 coating liquid, placed in 1 〇〇m 1 bottle, strongly vibrating up and down times . Then observe the height of the foaming. ◎: a height of less than 10% for the initial liquid depth: 10 0 to 1 5 % -39 - 1259813 for the initial liquid depth △: 1 6 to 2 0% X for the initial liquid depth : For the initial liquid depth, 21% or more (4) defoaming property is taken to be 20 m 1 coating liquid, placed in a 1000 m 1 bottle, and strongly shaken up and down 10 times. Then, the time until the bubble disappears is measured. ◎: 5 times or less when no surfactant is added: 5 to 10 times when no surfactant is added △: 1 when the surfactant is not added 〇~2 0 times X: 2 times more than when no surfactant was added, Table 1-2

塗覆液C1之種類 組成C1之界面活性劑 塗覆液性能 種類 添加量（份） 塗覆面狀 表面之凹凸 發泡性 消泡性 C1-1 S1-1 3.0 △〜〇 △〜〇 〇 〇 C1-2 S1-2 3.0 ◎ ◎ 〇 〇 C1-3 S1-3 3.0 Δ Δ 〇 〇 C1-4 S1-4 3.0 〇 〇 〇 〇 C1-5 S1-5 3.0 ◎ ◎ 〇 〇 C1-6 S1-1 0.10 Δ Δ ◎ 〇 C1-7 S1-1 6.0 〇 〇 △〜〇 〇 C1-8 無添加 X X ◎ ◎ C1-9 界面活性劑A X X 〇 〇 C1-10 梅卡法克（譯音）142-D △〜X △〜X Δ ΔType of Coating Liquid C1 Composition of Surfactant Coating Liquid of C1 Addition Amount (Parts) Concavo-convex Foaming Defoaming Properties of Coated Surfaces C1-1 S1-1 3.0 △~〇△~〇〇〇C1 -2 S1-2 3.0 ◎ ◎ 〇〇C1-3 S1-3 3.0 Δ Δ 〇〇C1-4 S1-4 3.0 〇〇〇〇C1-5 S1-5 3.0 ◎ ◎ 〇〇C1-6 S1-1 0.10 Δ Δ ◎ 〇C1-7 S1-1 6.0 〇〇△~〇〇C1-8 No addition XX ◎ ◎ C1-9 Surfactant AXX 〇〇C1-10 Mekafak (transliteration) 142-D △~X △~X Δ Δ

-40- 1259813 表1 - 3 塗覆液C1之種類 組成R1之界面活性劑 塗覆液性能 種類 添加量（份） 塗覆面狀 表面之凹凸 發泡性 消泡性 R1-1 S1-1 1.0 △〜〇 △〜〇 〇 〇 R1-2 S1-2 1.0 ◎ ◎ 〇 〇 R1-3 S1-3 1.0 Δ Δ 〇 〇 R1-4 S1-4 1.0 〇 〇 〇 〇 R1-5 S1-5 1.0 ◎ ◎ 〇 〇 R1-6 S1-1 0.03 Δ Δ ◎ 〇 R1-7 S1-1 2.0 〇 〇 △〜〇 〇 R1-8 無添加 X X ◎ ◎ R1-9 界面活性劑A X X 〇 〇 R1-10 梅卡法克（譯音）142-D △〜X △〜X Δ Δ 實施例1 - 1〜1 - 1 4、比較例1 - 1〜1 - 3 在厚度 50μπι聚對酞酸乙二酯薄膜之載體上旋轉塗覆表 1 - 4記載的熱塑性樹脂層形成用塗覆液，乾燥、設置乾燥 膜厚爲2 Ο μιτι之鹼可溶性熱塑性樹脂層。其次，在上述熱塑 性樹脂層上旋轉塗覆由下述組成Ρ 1所成的塗覆液，乾燥、 設置乾燥膜厚爲1 . 6 μιτι之阻氧層。 阻氧層形成用塗覆液之組成Ρ 1 : •聚乙烯醇 1 0 0份 (可樂麗（股）製PVA2 0 5、鹼化度·· 88%) •聚乙烯基比咯烷酮 5 0份 (CAF(股）製之 PVA、Κ-90) •氟系界面活性劑 2份 (旭玻璃（股）公司製之撒福龍（譯音）S - 1 3 1 ) 一 4 1 - 1259813 •蒸餾水 3 0 0 〇份 在具有上述熱塑性樹脂層及阻氧層之載體上旋轉塗覆表 1 - 4記載的紅色感光性樹脂層形成用塗覆液’乾燥、形成 乾燥膜厚爲2μιτι之紅色感光性樹脂層，且在該紅色感光性 樹脂層上使聚丙烯（厚度1 2 μπι )之被覆片板，製作影像形成 材料。 剝取所得影像形成材料之被覆片板，使紅色感光性樹脂 層表面在玻璃基板（厚度1 . 1 mm )上使用積層器（大成積層器 (股）製 VP - I I )加壓（l〇kg/ cm2)(与 980kPa )、加熱（l〇〇°C )， 以速度1 0m /分鐘貼合，再剝離載體與熱塑性樹脂層之界面 ，然後，在熱塑性樹脂層上黏合市售膠帶，以1 80度觀察 拉伸轉印層之剝離狀態，作爲玻璃基板密接性。結果如表 1 - 4所示。 ◎:完全不見剝離 〇：僅稍微剝離、實用上沒有問題 △:產生剝離 X :膜完全剝離 濾色片之製作 剝取所得影像形成材料之被覆片板，，使紅色感光性樹 脂層表面在玻璃基板（厚度1.1mm)上使用積層器（大成積層 益（股）製 VP-II)加壓（i〇kg/cm2)(#980kPa)、加熱（130°C) 貼合’再剝離載體與熱塑性樹脂層之界面，除去載體。 然後’通過光罩（一邊爲20〜60 μπι之正方形畫素之負影 像）’使用高壓水銀燈使紅色感光性樹脂層曝光。曝光量爲 -42- 1259813 2 OmJ / cm2。其次，使用1%三乙醇胺水溶液、以30秒溶解除 去熱塑性樹脂層及阻氧層。此時，感光性樹脂層實質上沒 有顯像。繼後，使用1 %碳酸鈉水溶液使感光性樹脂層顯像 以除去未曝光部，形成紅色畫素（R )之圖案。使具有紅色畫 素之玻璃基板在2 2 0 °C下加熱1 3 0分鐘，使畫素部分充分硬 ώ · 化，製得僅有紅色畫素之濾色片。 . 使所得濾色片表面各以目視或顯微鏡觀察’如下述# f古 。所得結果如表1 - 4所示。 A :完全沒有色斑。 B :僅稍有色斑。 C :有少許色斑。 D :有很多色斑。 E :全面有色斑。 實用水準爲C以上。 43- 1259813 表1-4-40- 1259813 Table 1 - 3 Types of Coating Liquid C1 Composition of R1 Surfactant Coating Liquid Performance Type Adding Amount (Parts) Concavo-convex Foaming Defoaming Properties of Coated Surfaces R1-1 S1-1 1.0 △ ~〇△~〇〇〇R1-2 S1-2 1.0 ◎ ◎ 〇〇R1-3 S1-3 1.0 Δ Δ 〇〇R1-4 S1-4 1.0 〇〇〇〇R1-5 S1-5 1.0 ◎ ◎ 〇 〇R1-6 S1-1 0.03 Δ Δ ◎ 〇R1-7 S1-1 2.0 〇〇△~〇〇R1-8 No addition XX ◎ ◎ R1-9 Surfactant AXX 〇〇R1-10 Mekafak ( Transliteration) 142-D Δ~X Δ~X Δ Δ Example 1 - 1 to 1 - 1 4, Comparative Example 1 - 1 to 1 - 3 Spin-coated on a carrier of a 50 μm thick polyethylene terephthalate film The coating liquid for forming a thermoplastic resin layer described in Table 1 - 4 was dried, and an alkali-soluble thermoplastic resin layer having a dry film thickness of 2 Ο μιτι was provided. Next, a coating liquid composed of the following composition Ρ 1 was spin-coated on the above-mentioned thermoplastic resin layer, and dried to provide an oxygen barrier layer having a dry film thickness of 1.6 μm. The composition of the coating liquid for forming an oxygen barrier layer Ρ 1 : • 100 parts of polyvinyl alcohol (PVA 2 0 5 made from Kuraray), alkalinity · 88%) • Polyvinylpyrrolidone 5 0 (PVA, Κ-90, manufactured by CAF Co., Ltd.) • 2 parts of fluorine-based surfactant (Safu (Sound) S - 1 3 1 by Asahi Glass Co., Ltd.) - 4 1 - 1259813 • Distilled water The coating liquid for forming a red photosensitive resin layer described in Table 1-4 is spin-coated on a carrier having the thermoplastic resin layer and the oxygen barrier layer to form a red photosensitive film having a dry film thickness of 2 μm. A resin layer was formed, and a coated sheet of polypropylene (thickness: 12 μm) was formed on the red photosensitive resin layer to prepare an image forming material. The coated sheet of the obtained image forming material was peeled off, and the surface of the red photosensitive resin layer was pressed on a glass substrate (thickness of 1.1 mm) using a laminate (VP-II manufactured by Dacheng Stacker Co., Ltd.) (l〇kg) / cm2) (with 980 kPa), heating (10 ° C), laminating at a speed of 10 m / min, and then peeling off the interface between the carrier and the thermoplastic resin layer, and then bonding a commercially available tape to the thermoplastic resin layer to 1 The peeling state of the stretched transfer layer was observed at 80 degrees as the adhesion of the glass substrate. The results are shown in Table 1-4. ◎: peeling flaw was not observed at all: only slightly peeled off, and there was no problem in practical use. Δ: peeling occurred X: the film was completely peeled off and the color filter was peeled off, and the coated sheet of the obtained image forming material was peeled off, so that the surface of the red photosensitive resin layer was made of glass. On the substrate (thickness 1.1 mm), pressurize (i〇kg/cm2) (#980kPa), heat (130 °C) with a laminate (large layer VP-II), and press the 're-stripping carrier and thermoplastic The interface of the resin layer removes the carrier. Then, the red photosensitive resin layer was exposed by a high-pressure mercury lamp through a photomask (a negative image of a square pixel of 20 to 60 μm). The exposure is -42 - 1259813 2 OmJ / cm2. Next, the thermoplastic resin layer and the oxygen barrier layer were removed by using a 1% aqueous solution of triethanolamine in 30 seconds. At this time, the photosensitive resin layer was substantially not developed. Thereafter, the photosensitive resin layer was developed using a 1% aqueous sodium carbonate solution to remove unexposed portions, thereby forming a pattern of red pixels (R). The glass substrate having the red color was heated at 260 ° C for 1300 minutes to sufficiently harden the pixel portion, and a color filter having only red pixels was obtained. The surface of the obtained color filter is visually or microscopically observed as follows. The results obtained are shown in Table 1-4. A: There is no stain at all. B: Only slightly stained. C: There is a little stain. D: There are many spots. E: There are all spots. The practical level is above C. 43- 1259813 Table 1-4

塗覆液C1之種類 塗覆液R1之種類 基板密接性 表面外觀 實施例1-1 C1-1 R1-9 〇 B 實施例1-2 C1-2 R1-9 〇 A 實施例1-3 C1-3 R1-9 〇 B 實施例丨-4 C1-4 R1-9 〇 A 實施例1-5 C1-5 R1-9 〇 A 實施例1-6 C1-6 R1-9 〇 C 實施例卜7 C1-7 R1-9 〇 B 比較例1-1 C1-8 R1-9 ◎ E 比較例1-2 C1-9 R1-9 〇 D 比較例1-3 C1-10 R1-10 〇 D 實施例卜8 C1-1 R1-1 〇 B 實施例1-9 C1-2 R1-2 〇 A 實施例卜10 C1-3 R1-3 〇 B 實施例1-11 C1-4 R1-4 〇 A 實施例1-12 C1-5 R1-5 〇 A 實施例1-13 C1-6 R1-6 〇 C 實施例1-14 C1-7 R1-7 〇 B 實施例1 -1 5 在厚度ΙΟΟμηι聚對酞酸乙二酯薄膜之載體上旋轉塗覆由 下述組成C 2所成的熱塑性樹脂層形成用塗覆液，乾燥、設 置乾燥膜厚爲20μηι之鹼可溶性熱塑性樹脂層。 熱塑性樹脂層形成用塗覆液之組成c 2 : •甲基丙烯酸甲酯/ 2-乙基甲基丙豨酸酯/苯甲基甲基丙 烯酸酯/甲基丙烯酸共聚物 1 5份 一 44- 1259813 (共聚合組成比（莫耳比）=5 5 / 2 8 . § / 1 1 . 7 / 4 . 5、質量平均 子量=9萬） •聚丙二醇二丙烯酸酯 6 · 5份 (質量平均分子量422) •四乙二醇二甲基丙烯酸酯 1 · 5份 •對甲苯碾醯胺 0 . 5份 •二苯甲酮 1 . 0份 •甲基乙酮 30份 然後，在上述熱塑性樹脂層上旋轉塗覆由上述組成P2所 成的塗覆液，乾燥、設置乾燥膜厚爲1 . 6 μπι之阻氧層。 阻氧層形成用塗覆液之組成Ρ 2 ·· •聚乙烯醇 100份 (可樂麗（股）製PVA2 0 5、鹼化度·· 88%) •聚乙烯基吡咯烷酮 5 0份 (CAF(股）製之 PVA、Κ-90) •氟系界面活性劑 2份 (旭玻璃（股）公司製之撒福龍（譯音）S - 1 3 1 ) •蒸餾水 3 0 0 0份 在具有3張上述熱塑性樹脂層及阻氧層之載體上各旋轉 塗覆由下述組成R 1 - 1 1所成的紅色感光性樹脂層形成用塗 覆液、由組成G 1所成的綠色感光性樹脂層形成用塗覆液、 由組成Β1所成的藍色感光性樹脂層形成用塗覆液、及由組 成Κ 1所成的黑色感光性樹脂層形成用塗覆液’乾燥、形成 乾燥膜厚爲2_之各色感光性樹脂層’且在該感光性樹脂 - 45- 1259813 層上使聚丙烯（厚度i 2 μηι )之被覆片板，製作影像形成材_ 〇 紅色感光性樹脂層形成用塗覆液R 1 - 1 1 •苯甲基甲基丙烯酸酯/甲基丙烯酸共聚物6 0 . 0份 (莫耳比=73/27、酸價=73mgKOH/g、質量平均分子量=3 萬、黏度=0 . 1 2Pa · s ) 季戊四醇四丙烯酸酯 43 .2 份 米勒酮 2 · 4份 2-(〇 -氯苯基）-4, 5 -二苯基咪唑二聚物 2 · 5份 衣魯卡畊（譯音）紅色BPT 5.4份 甲基溶纖劑乙酸酯 5 6 0份 甲基乙酮 2 80份 本發明用界面活性劑S 2 0 · 3份 (使用20質量％甲基異丁酮20質量％溶液，其溶質之份數） 綠色感光性樹脂層形成用塗覆液之組成G 1 : 於紅色感光性樹脂層形成用塗覆液之組成R 1 - 1 1中，使 用5 . 6份酮酞菁取代5 . 4份衣魯卡阱紅色BPT。 藍色感光性樹脂層形成用塗覆液之組成B 1 : 於紅色感光性樹脂層形成用塗覆液之組成R 1 - 1 1中，使 用5 . 2份蘇丹藍色取代5 . 4份衣魯卡畊紅色BPT。 黑色感光性樹脂層形成用塗覆液之組成K 1 : 於紅色感光性樹脂層形成用塗覆液之組成R 1 - 1 1中，使 用1 0 . 0份碳黑取代5 . 4份衣魯卡畊紅色BPT。 而且，上述各感光性樹脂層形成用塗覆液藉由下述方法 -46- 1259813 ill製。首先，以下述方法製作具有各色相之3種顏料分散 物°使3 6 0 g上述各顏料、3 6 g分散劑（索魯史帕史（譯音 )24〇〇〇、吉尼卡（譯音）公司製）、74〇g黏合樹脂溶液（上述 苯甲基甲基丙烯酸酯/甲基丙烯酸共聚物之甲基溶纖劑乙酸 酉旨溶液40質量％ )使用混練機（森山製作所s 1 - 1 )混練3 0分 鐘’製得顏料組成物。然後，添加9 0 0 g分散溶劑（甲基溶 纖劑乙酸酯）後，另在介質磨（烏里耶帕克黑（譯音）公司製 賴衣羅米魯（譯音）KDL-PIL0T)中進行分散3 6 0分鐘。在該 分散液中添加季戊四醇四丙烯酸酯、米勒酮等，形成上述 組成。 上述組成R 1 - 1 1、G 1、B 1或K 1之各塗覆液性能與上述相 同地評估，結果如表1 - 5所示。 使用上述影像形成材料以下述方法製作濾色片。 剝取所得紅色影像形成材料之被覆片板，使紅色感光性 樹脂層表面在玻璃基板（厚度1.1 mm)上使用積層器（大成積 層器（股）製 VP-II)加壓（l〇kg/cm2)(与 980kPa)、加熱（ 1 3 0 °C )後貼合，再剝離載體與熱塑性樹脂層之界面。然後 ’通過所定光罩予以曝光，使用1 %三乙醇胺水溶液除去熱 塑性樹脂層及阻氧層。此時，感光性樹脂層實質上沒有顯 像。繼後，使用1 %碳酸鈉水溶液使感光性樹脂層顯像以除 去未曝光部，形成紅色畫素（R )之圖案。然後，在形成有紅 色畫素之圖案影像形成材料的玻璃基板上使綠色影像形成 材料與上述相同地進行貼合、剝離、曝光、顯像，形成綠 色畫素圖案。以藍色影像形成材料及黑色影像形成材料重 -47 - 1259813 複同樣工程，在透明玻璃基板上形成濾色片。於此等工程 中，玻璃基板與感光性樹脂層之密接性佳。 比較例1 - 4 於實施例1 - 1 5之組成R 1 - 1 1、G 1、B 1及K 1中，調製沒 有添加本發明用界面活性劑之塗覆液R1 - 12、G2、B2及K2 ，與實施例1 - 1 5相同地製作濾色片。結果，產生塗覆斑。 而且’塗覆液R1 - 12、G2、B2及K2之性能與上述相同地予 以評估，如表1 - 5所示。Type of Coating Liquid C1 Type of Coating Liquid R1 Substrate Adhesive Surface Appearance Example 1-1 C1-1 R1-9 〇B Example 1-2 C1-2 R1-9 〇A Example 1-3 C1- 3 R1-9 〇B Example 丨-4 C1-4 R1-9 〇A Example 1-5 C1-5 R1-9 〇A Example 1-6 C1-6 R1-9 〇C Example VII 7 C1 -7 R1-9 〇B Comparative Example 1-1 C1-8 R1-9 ◎ E Comparative Example 1-2 C1-9 R1-9 〇D Comparative Example 1-3 C1-10 R1-10 〇D Example 8 C1-1 R1-1 〇B Example 1-9 C1-2 R1-2 〇A Example Example 10 C1-3 R1-3 〇B Example 1-11 C1-4 R1-4 〇A Example 1 12 C1-5 R1-5 〇A Example 1-13 C1-6 R1-6 〇C Example 1-14 C1-7 R1-7 〇B Example 1 -1 5 In the thickness ΙΟΟμηι poly phthalic acid On the carrier of the ester film, a coating liquid for forming a thermoplastic resin layer formed by the following composition C 2 was spin-coated, and dried, and an alkali-soluble thermoplastic resin layer having a dry film thickness of 20 μm was provided. Composition of coating liquid for forming a thermoplastic resin layer c 2 : • Methyl methacrylate / 2-ethylmethyl propyl phthalate / benzyl methacrylate / methacrylic acid copolymer 1 5 parts - 44 - 1259813 (combination composition ratio (Morby) = 5 5 / 2 8 . § / 1 1 . 7 / 4 . 5, mass average sub-quant = 90,000) • Polypropylene glycol diacrylate 6 · 5 parts (mass average Molecular weight 422) • Tetraethylene glycol dimethacrylate 1 · 5 parts • p-Toluene guanamine 0. 5 parts • Benzophenone 1.0 part • Methyl ethyl ketone 30 parts Then, in the above thermoplastic resin layer The coating liquid formed by the above composition P2 was spin-coated, and dried, and an oxygen barrier layer having a dry film thickness of 1.6 μm was provided. The composition of the coating liquid for forming an oxygen barrier layer Ρ 2 ···100 parts of polyvinyl alcohol (PVA2 0 5 made from Kuraray Co., Ltd., alkalinity · 88%) • Polyvinylpyrrolidone 50 parts (CAF ( PVA, Κ-90) of the company) • 2 parts of the fluorine-based surfactant (Safron (trans) S - 1 3 1 made by Asahi Glass Co., Ltd.) • 3 parts of distilled water with 3 sheets The coating layer for forming a red photosensitive resin layer formed by the following composition R 1 - 1 1 and the green photosensitive resin layer formed by the composition G 1 are spin-coated on the carrier of the thermoplastic resin layer and the oxygen barrier layer. The coating liquid for forming, the coating liquid for forming a blue photosensitive resin layer formed of the composition Β1, and the coating liquid for forming a black photosensitive resin layer formed of the composition '1 are dried to form a dry film thickness. a photosensitive resin layer of each color 2', and a coated sheet of polypropylene (thickness i 2 μηι) was formed on the photosensitive resin-45-1259813 layer to form an image forming material_coating for forming a magenta photosensitive resin layer Liquid R 1 - 1 1 • Benzyl methacrylate / methacrylic acid copolymer 6 0 . 0 parts (Mo Er ratio = 73 / 27, acid value = 73 mgK OH/g, mass average molecular weight = 30,000, viscosity = 0.12 Pa · s) pentaerythritol tetraacrylate 43.2 moles 2 · 4 parts 2-(〇-chlorophenyl)-4, 5 - two Phenyl imidazolium dimer 2 · 5 parts yyuka (transliteration) red BPT 5.4 parts of methyl cellosolve acetate 560 parts methyl ethyl ketone 2 80 parts of surfactant S 2 0 of the present invention 3 parts (using 20% by mass of methyl isobutyl ketone 20% by mass solution, the solute fraction thereof) The composition of the coating liquid for green photosensitive resin layer formation G 1 : The coating liquid for forming a red photosensitive resin layer In the composition R 1 -1 1 , 5.6 parts of ketone phthalocyanine was used instead of 5.4 parts of the ruthenium red BPT. The composition of the coating liquid for forming a blue photosensitive resin layer B 1 : In the composition R 1 - 1 1 of the coating liquid for forming a red photosensitive resin layer, 5.2 parts of Sudan blue is used instead of 5.4 parts. Luka plowed red BPT. The composition of the coating liquid for forming a black photosensitive resin layer K 1 : In the composition R 1 - 1 1 of the coating liquid for forming a red photosensitive resin layer, 10 parts of carbon black is used instead of 5.4 parts. Card ploughing red BPT. Further, each of the above-mentioned coating liquids for forming a photosensitive resin layer is produced by the following method -46-1259813 ill. First, three kinds of pigment dispersions having respective hues were prepared in the following manner: 460 g of each of the above pigments, and 36 g of dispersant (Sorrow Spah 24, Ginja) Co., Ltd., 74 〇g of a binder resin solution (the above-mentioned benzyl methacrylate/methacrylic acid copolymer, methyl cellosolve acetate solution, 40% by mass) was used as a kneading machine (Moriyama Seisakusho s 1 - 1) Mixing for 30 minutes' produces a pigment composition. Then, after adding 900 g of a dispersing solvent (methyl cellosolve acetate), it was further carried out in a media mill (Ulympus Black (trans) KL-PIL0T) Disperse for 3 60 minutes. Pentaerythritol tetraacrylate, munone or the like is added to the dispersion to form the above composition. The properties of the respective coating liquids of the above composition R 1 - 1 1 , G 1 , B 1 or K 1 were evaluated in the same manner as above, and the results are shown in Table 1-5. A color filter was produced by the following method using the above image forming material. The coated sheet of the obtained red image forming material was peeled off, and the surface of the red photosensitive resin layer was pressed on a glass substrate (thickness: 1.1 mm) using a laminate (VP-II manufactured by Dacheng Stacker Co., Ltd.) (l〇kg/ After cm2) (with 980 kPa) and heating (130 ° C), it is bonded, and the interface between the carrier and the thermoplastic resin layer is peeled off. Then, it was exposed by a predetermined mask, and the thermoplastic resin layer and the oxygen barrier layer were removed using a 1% aqueous solution of triethanolamine. At this time, the photosensitive resin layer was substantially not imaged. Thereafter, the photosensitive resin layer was developed using a 1% aqueous sodium carbonate solution to remove the unexposed portion to form a pattern of red pixels (R). Then, the green image forming material is bonded, peeled, exposed, and developed on the glass substrate on which the pattern image forming material of the red pixel is formed, in the same manner as described above to form a green pixel pattern. The blue image forming material and the black image forming material are -47 - 1259813. The same process is performed to form a color filter on the transparent glass substrate. In these works, the adhesion between the glass substrate and the photosensitive resin layer is good. Comparative Example 1 - 4 In the compositions R 1 - 1 1 , G 1 , B 1 and K 1 of Examples 1 - 15, the coating liquids R1 - 12, G2, B2 without the addition of the surfactant for use in the present invention were prepared. And K2, a color filter was produced in the same manner as in Example 1-5. As a result, a coating spot is produced. Further, the properties of the coating liquids R1 - 12, G2, B2 and K2 were evaluated in the same manner as described above, as shown in Table 1-5.

表1 - 5 塗覆液之種類 塗覆液性能 塗覆面狀 表面之凹凸 發泡性 消泡性 R1-11 〇 〇 〇 〇 G1 〇 〇 〇 〇 B1 〇 〇 〇 〇 K1 〇 〇 〇 〇 R1-12 X X ◎ ◎ G2 X X ◎ ◎ B2 X X ◎ ◎ K2 X X ◎ ◎Table 1 - 5 Types of coating liquid Coating liquid properties Concave-convex foaming defoaming property of coated surface surface R1-11 〇〇〇〇G1 〇〇〇〇B1 〇〇〇〇K1 〇〇〇〇R1-12 XX ◎ ◎ G2 XX ◎ ◎ B2 XX ◎ ◎ K2 XX ◎ ◎

上述藉由使用本發明用界面活性劑（丨），可提供沒有塗覆 斑、塗覆面狀平滑、層厚均勻且沒有色斑、不會發泡且消 '泡丨生優異、玻璃基板之密接性優異的塗覆液及載負它之影 像形成材料。 貫施例2 (實施例2 - 1〜實施例2 - 1 5 )、比較例2 (比較例 2 - 1〜比較例2 - 4 ) 1259813 1 )本發明用界面活性劑s 2 - 1〜S 2 - 5 (共聚物（2 ))之合成 或調製 使用表2 - 1所示單體（a )、單體（b )、單體（c )及單體（cl ) ’合成及調製具有同表所示質量平均分子量之本發明用界 面活性劑。 表2- 1 單體(a) 單體(b) 單體(C) 單體(d) 共聚合比~ (a) : (b): (c):(d) (質量比） 質量平ίί 分子量 R〇i Ri η 1 m R〇2 K〇3 R〇4 r2 r3 P R〇5 R〇6 R〇7 R〇8 r q S2-1 Η - 2 0 8 ch3 ch3 ch3 -ch2- ch3 10 ch3 ch3 ch3 H 2 15 60:5:5:30 10000 S2-2 Η - 2 0 8 ch3 ch3 ch3 -CHr ch3 10 ch3 ch3 ch3 H 3 15 60:5:5:30 10000 S2-3 ch3 - 2 0 8 ch3 ch3 ch3 -ch2- ch3 10 ch3 ch3 ch3 H 3 15 60:5:5:30 10000 S2-4___S2-1+S2-2(S2- 1/S2-2=10/50(質量比） S2-5__52-1+52-3(52-1/52-3=10/30(質量比)By using the surfactant (丨) of the present invention, it is possible to provide no coating spots, smooth coating surface, uniform layer thickness, no color spots, no foaming, excellent foaming, and close contact of glass substrates. Excellent coating liquid and image forming material carrying it. Example 2 (Example 2-1 to Example 2 - 15), Comparative Example 2 (Comparative Example 2-1 to Comparative Example 2 - 4) 1259813 1) Surfactant s 2 - 1 to S for use in the present invention 2 - 5 (copolymer (2)) is synthesized or prepared using the monomers (a), monomers (b), monomers (c) and monomers (cl) shown in Table 2-1. The surfactant of the present invention is used for the mass average molecular weight shown in the table. Table 2- 1 Monomer (a) Monomer (b) Monomer (C) Monomer (d) Copolymerization ratio ~ (a) : (b): (c): (d) (mass ratio) Mass ίί Molecular weight R〇i Ri η 1 m R〇2 K〇3 R〇4 r2 r3 PR〇5 R〇6 R〇7 R〇8 rq S2-1 Η - 2 0 8 ch3 ch3 ch3 -ch2- ch3 10 ch3 ch3 Ch3 H 2 15 60:5:5:30 10000 S2-2 Η - 2 0 8 ch3 ch3 ch3 -CHr ch3 10 ch3 ch3 ch3 H 3 15 60:5:5:30 10000 S2-3 ch3 - 2 0 8 ch3 Ch3 ch3 -ch2- ch3 10 ch3 ch3 ch3 H 3 15 60:5:5:30 10000 S2-4___S2-1+S2-2 (S2- 1/S2-2=10/50 (mass ratio) S2-5__52- 1+52-3 (52-1/52-3=10/30 (mass ratio)

2)熱塑性樹脂層形成用塗覆液C2(C2 - 1〜C2- 10)之調製 熱塑性樹脂層形成用塗覆液C2 - 1之調製 於熱塑性樹脂層形成用塗覆液之組成C 1 - 1中，除將本發 明用界面活性劑S 1 - 1改成本發明用界面活性劑S 2 - 1外， 相同地予以調製。 熱塑性樹脂層形成用塗覆液C2 - 2〜2 - 7之調製 於熱塑性樹脂層形成用塗覆液C 2 - 1之調製中，除本發明 用界面活性劑之種類、添加量變更成如表2 - 2所示。 熱塑性樹脂層形成用塗覆液C2 - 8之調製 於熱塑性樹脂層形成用塗覆液C 2 - 1之調製中，不使用本 發明用界面活性劑予以調製。 熱塑性樹脂層形成用塗覆液C2 - 9之調製 -49- 1259813 於熱塑性樹脂層形成用塗覆液C 2 -丨之調製中，除使用氟 系界面活性劑 A: CsF17S02N(C4H9)CH2CH20C0CH二CH2 6 0 質量 %與h(o(ch3)chch2)6ococh=ch2 4 0重量％之共聚物（質量平 均分子量：3萬、甲基異丁酮2 0質量％溶液）取代本發明用 界面活性劑外，相同地調製。 熱塑性樹脂層形成用塗覆液C2 - 1 0之調製 於熱塑性樹脂層形成用塗覆液C2 - 1之調製中，除以固成 份量使用等質量份梅卡法克F1 42-D(大日本油墨化學工業（ 股）製）取代本發明用界面活性劑外’相同地調製。 3 )紅色感光性樹脂層形成用塗覆液R2(R2 - 1〜R2 - 10) 紅色感光性樹脂層形成用塗覆液之組成R2 - 1之調製 於紅色感光性樹脂層形成用塗覆液之組成R 1 - 1中，除將 本發明用界面活性劑S 1 - 1改成本發明用界面活性劑S2 - 1 外，相同地予以調製。 紅色感光性樹脂層形成用塗覆液R2 - 2〜2 - 7之調製 於紅色感光性樹脂層形成用塗覆液R2 - 1之調製中，將本 發明用界面活性劑之種類、添加量變更成如表2 - 3所示。 紅色感光性樹脂層形成用塗覆液R 2 - 8之調製 於紅色感光性樹脂層形成用塗覆液R2 - 1之調製中，不使 用本發明用界面活性劑予以調製。 紅色感光性樹脂層形成用塗覆液R2 - 9之調製 於紅色感光性樹脂層形成用塗覆液R 2 - 1之調製中，除使 用上述界面活性劑A取代本發明用界面活性劑外，相同地 調製。 -50- 1259813 紅色感光性樹脂層形成用塗覆液R2 - 1 0之調製 於紅色感光性樹脂層形成用塗覆液R 2 之調製中’〖余& 固成份量使用等質量份梅卡法克F 1 4 2 - D (大日本油墨丨匕^ 工業（股）製）取代本發明用界面活性劑外’相同地調製° 上述調製的熱塑性樹脂層形成用塗覆液及紅色感光丨生^ 脂層形成用塗覆液之性能藉由下述評估’結果如表2 — 2 ' 所示。2) Coating liquid C2 (C2 - 1 to C2 - 10) of the coating liquid for forming a thermoplastic resin layer, the composition of the coating liquid for forming a thermoplastic resin layer, C 2 -1, and the composition of the coating liquid for forming a thermoplastic resin layer, C 1 - 1 In addition, the surfactant S 1 -1 of the present invention was modified in the same manner as the surfactant S 2 - 1 for the invention. In the preparation of the coating liquid for forming a thermoplastic resin layer C 2 -1 in the coating liquid C2 - 2 to 2 - 7 for forming a thermoplastic resin layer, the type and amount of the surfactant used in the present invention are changed to 2 - 2 is shown. The coating liquid C2-8 for forming a thermoplastic resin layer is prepared by preparing a coating liquid C 2 -1 for forming a thermoplastic resin layer, and is prepared without using the surfactant of the present invention. Preparation of Coating Liquid C2-9 for Forming Thermoplastic Resin Layer - 49- 1259813 In the preparation of coating liquid C 2 -丨 for forming a thermoplastic resin layer, except for using fluorine-based surfactant A: CsF17S02N(C4H9)CH2CH20C0CH2CH2 60% by mass and h(o(ch3)chch2)6ococh=ch2 40% by weight of copolymer (mass average molecular weight: 30,000, methyl isobutyl ketone 20% by mass solution) instead of the surfactant used in the present invention , the same modulation. In the preparation of the coating liquid C2 - 1 for forming a thermoplastic resin layer, in the preparation of the coating liquid C2 - 1 for forming a thermoplastic resin layer, the mass fraction is used in the amount of the solid component, Mekafak F1 42-D (Great Japan) Ink Chemical Industry (manufactured by the Ink Chemical Industry Co., Ltd.) is prepared in the same manner as the surfactant of the present invention. 3) Red photosensitive resin layer-forming coating liquid R2 (R2 - 1 to R2 - 10) Red photosensitive resin layer-forming coating liquid composition R2 - 1 is prepared in a red photosensitive resin layer-forming coating liquid The composition R 1 -1 was prepared in the same manner except that the surfactant S 1 -1 of the present invention was changed to the surfactant S2-1 for the invention. In the preparation of the red photosensitive resin layer-forming coating liquid R2 -1 in the preparation of the red photosensitive resin layer-forming coating liquid R2 - 2 to 2 - 7, the type and amount of the surfactant used in the present invention are changed. As shown in Table 2 - 3. The red photosensitive resin layer-forming coating liquid R 2 - 8 is prepared in the preparation of the red photosensitive resin layer-forming coating liquid R2 - 1, and is not prepared by using the surfactant of the present invention. In the preparation of the red photosensitive resin layer-forming coating liquid R 2 -1 in the preparation of the red photosensitive resin layer-forming coating liquid R2-9, in place of the surfactant A in place of the surfactant of the present invention, Modulate the same. -50- 1259813 Preparation of coating liquid R2 - 10 for red photosensitive resin layer formation In preparation of coating liquid R 2 for red photosensitive resin layer formation, 'The rest & FAK F 1 4 2 - D (Daily Ink 丨匕^ Industrial Co., Ltd.) is used in place of the surfactant of the present invention. The same preparation of the above-prepared coating liquid for forming a thermoplastic resin layer and red photosensitive growth ^ The properties of the coating liquid for forming a lipid layer are shown by the following evaluations. The results are shown in Table 2-2'.

(1 )塗覆面狀（塗覆斑） 與實施例1相同地予以評估。 (2)表面凹凸 與實施例1相同地予以評估。 (3 )發泡性 與實施例1相同地予以評估。 (4 )消泡性(1) Coating surface (coating spot) was evaluated in the same manner as in Example 1. (2) Surface unevenness Evaluation was carried out in the same manner as in Example 1. (3) Foaming property Evaluation was carried out in the same manner as in Example 1. (4) defoaming

與實施例1相同地予以評估。 (5 )顯像液溶解性 在1 OOm 1富士照相軟片（股）製處理顯像液中添加 Λ ]η分鏐，％ 1 m丨2 0%Β I ΒΚ界面活性劑溶液，以啓動器攪拌1 U Χ 分鐘後以目視確認溶解狀況。 ◎:完全溶解成透明 〇：幾乎全部溶解，惟稍有混濁情形 △:有少許未溶解物殘留 X :完全不溶解 表2-2 1259813 塗覆液C2 組成C2之界面活性劑 塗覆液性能 之種類 種類 添加量（份） 塗覆面狀 表面之凹凸 發泡性 消泡性 顯像液 溶解性 C2-1 S2-1 3.0 ◎ ◎ 〇 〇 〇 C2-2 S2-2 3.0 ◎ ◎ 〇 〇 〇 C2-3 S2-3 3.0 ◎ ◎ 〇 〇 〇 C2-4 S2-4 3.0 ◎ ◎ 〇 〇 〇 C2-5 S2-5 3.0 ◎ ◎ 〇 〇 〇 C2-6 S2-1 0.10 △〜〇 △〜〇 〇 〇 〇 C2-7 S2-1 6.0 ◎ ◎ 〇 〇 〇 C2-8 無添加 X X ◎ ◎ — C2-9 界面活性劑A X X 〇 〇 〇 C2-10 梅卡法克（譯音）142-D △〜X △〜X Δ Δ Δ 表2 - 3 塗覆液R2 組成R2之界面活性劑 塗覆液性能 之種類 種類 添加量（份） 塗覆面狀 表面之凹凸 發泡性 消泡性 顯像液 溶解性 R2-1 S2-1 1.0 ◎ ◎ 〇 〇 〇 R2-2 S2-2 1.0 ◎ ◎ 〇 〇 〇 R2-3 S2-3 1.0 ◎ ◎ 〇 〇 〇 R2-4 S2-4 1.0 ◎ ◎ 〇 〇 〇 R2-5 S2-5 1.0 ◎ ◎ 〇 〇 〇 R2-6 S2-1 0.03 △〜〇 △〜〇 〇 〇 〇 R2-7 S2-1 2.0 ◎ ◎ 〇 〇 〇 R2-8 無添加 X X ◎ ◎ — R2-9 界面活性劑A X X 〇 〇 〇 R2-10 |梅卡法克（譯音）142-D △〜X △〜X Δ Δ Δ 實施例2 - 1〜2 - 1 4、比較例2 - 1〜2 - 3 -52- 1259813 在厚度50μπι聚對酞酸乙二酯薄膜之載體上旋轉塗覆表 2 - 4記載的熱塑性樹脂層形成用塗覆液’乾燥、設置乾 膜厚爲2 Ο μηα之鹼可溶性熱塑性樹脂層。其次，在上述熱塑 性樹脂層上旋轉塗覆由下述組成Ρ 1所成的塗覆液，乾燥、 δ又置乾燥0吴厚爲1 . 6 μ m之阻氧層。 在具有上述熱塑性樹脂層及阻氧層之載體上旋轉塗覆表 2 - 4記載的紅色感光性樹脂層形成用塗覆液，乾燥、形成 乾燥膜厚爲2μπι之紅色感光性樹脂層，且在該紅色感光性 樹脂層上使聚丙烯（厚度12μ[η)之被覆片板，製作影像形成 材料。 實施例1相同地觀察所得影像形成材料之紅色感光性樹 脂層的玻璃基板密接性。結果如表2-4所示。 濾色片之製作 使用所得影像形成材料，與實施例"目同地製得僅紅色 畫素之濾色片，相同地予以評估。所得結果如$ 2]所示 -53 - 1259813 表2-4It was evaluated in the same manner as in Example 1. (5) The solubility of the developing solution is added to the photographic solution of Fujifilm Photo Film Co., Ltd., which is added with Λ η 镠, % 1 m 丨 2 0% Β I ΒΚ surfactant solution, stirred with a starter After 1 U Χ minutes, the dissolution was visually confirmed. ◎: completely dissolved into transparent enamel: almost completely dissolved, but slightly turbid. △: there is little undissolved residue. X: completely insoluble. Table 2-2 1259813 Coating liquid C2 Composition of surfactant surfactant coating C2 Type and amount of addition (parts) Concavo-convex foaming defoaming liquid solution solubility on coated surface C2-1 S2-1 3.0 ◎ ◎ 〇〇〇C2-2 S2-2 3.0 ◎ ◎ 〇〇〇C2- 3 S2-3 3.0 ◎ ◎ 〇〇〇C2-4 S2-4 3.0 ◎ ◎ 〇〇〇C2-5 S2-5 3.0 ◎ ◎ 〇〇〇C2-6 S2-1 0.10 △~〇△~〇〇〇〇 C2-7 S2-1 6.0 ◎ ◎ 〇〇〇C2-8 No addition XX ◎ ◎ — C2-9 Surfactant AXX 〇〇〇C2-10 Mekafak (transliteration) 142-D △~X △~X Δ Δ Δ Table 2 - 3 Coating liquid R2 Composition of R2 surfactant surfactant coating properties Types Adding amount (parts) Coating surface-like surface Foaming foaming defoaming liquid solution Solubility R2-1 S2 -1 1.0 ◎ ◎ 〇〇〇R2-2 S2-2 1.0 ◎ ◎ 〇〇〇R2-3 S2-3 1.0 ◎ ◎ 〇〇〇R2-4 S2-4 1.0 ◎ ◎ 〇〇 R2-5 S2-5 1.0 ◎ ◎ 〇〇〇R2-6 S2-1 0.03 △~〇△~〇〇〇〇R2-7 S2-1 2.0 ◎ ◎ 〇〇〇R2-8 No addition XX ◎ ◎ — R2 -9 Surfactant AXX 〇〇〇R2-10 | Mecafak 142-D △~X △~X Δ Δ Δ Example 2 - 1~2 - 1 4, Comparative Example 2 - 1~2 - 3 -52- 1259813 Rotating and coating the carrier for forming a film of a polyethylene terephthalate film having a thickness of 50 μm on the surface of the film for forming a thermoplastic resin layer described in Table 2 - 4 to dry, and setting a base having a dry film thickness of 2 Ο μηα A layer of soluble thermoplastic resin. Next, a coating liquid composed of the following composition Ρ 1 was spin-coated on the above thermoplastic resin layer, and dried, and δ was further dried to a thickness of 0.6 μm. The coating liquid for forming a red photosensitive resin layer described in Table 2-4 is spin-coated on a carrier having the thermoplastic resin layer and the oxygen barrier layer, and dried to form a red photosensitive resin layer having a dry film thickness of 2 μm. On the red photosensitive resin layer, a coated sheet of polypropylene (thickness: 12 μ [η) was formed to prepare an image forming material. In the same manner as in Example 1, the glass substrate adhesion of the red photosensitive resin layer of the obtained image forming material was observed. The results are shown in Table 2-4. Production of color filter Using the obtained image forming material, a color filter of only red pixels was produced in the same manner as in the Example ", and evaluated in the same manner. The result is shown as $2] -53 - 1259813 Table 2-4

塗覆液C1之種類 塗覆液R1之種類 基板密接性 表面外觀 實施例2-1 C2-1 R2-9 〇 A 實施例2-2 C2-2 R2-9 〇 A 實施例2-3 C2-3 R2-9 〇 A 實施例2-4 C2-4 R2-9 〇 A 實施例2-5 C2-5 R2-9 〇 A 實施例2-6 C2-6 R2-9 〇 C 實施例2-7 C2-7 R2-9 〇 A 比較例2-1 C2-8 R2-9 ◎ E 比較例2-2 C2-9 R2-9 〇 D 比較例2-3 C2-10 R2-10 〇 D 實施例2-8 C2-1 R2-1 〇 A 實施例2-9 C2-2 R2-2 〇 A 實施例2-10 C2-3 R2-3 〇 A 實施例2-11 C2-4 R2-4 〇 A 實施例2-12 C2-5 R2-5 〇 A 實施例2-13 C2-6 R2-6 〇 C 實施例2-14 C2-7 R2-7 〇 B 實施例2 - 1 5 在厚度100 μηι聚對酞酸乙二酯薄膜之載體上旋轉塗覆由 下述組成C2所成的熱塑性樹脂層形成用塗覆液，乾燥、設 置乾燥膜厚爲20μηι之鹼可溶性熱塑性樹脂層。 然後，在上述熱塑性樹脂層上旋轉塗覆由上述組成Ρ2所 成的塗覆液，乾燥、設置乾燥膜厚爲1 . 6μιτι之阻氧層。 在具有3張上述熱塑性樹脂層及阻氧層之載體上各旋轉 -54- 1259813 塗覆由下述組成R2-U所成的紅色感光性樹脂層形成用塗 覆液、由組成G!所成的綠色感光性樹脂層形成用塗覆液' 由組成B 1所成的藍色感光性樹脂層形成用塗覆液、及由組 成K 1所成的黑色感光性樹脂層形成用塗覆液’乾燥、形成 乾燥膜厚爲2 μ m之各色感光性樹脂層’且在該感光性樹脂 層上使聚丙烯（厚度1 2 μ m )之被覆片板’製作影像形成材料 〇 紅色感光性樹脂層形成用塗覆液R2 -11 於紅色感光性樹脂層形成用塗覆液之組成R1-11中，除 將本發明用界面活性劑S 1 - 2改成本發明用界面活性劑 2外，相同地予以調製。 綠色感光性樹脂層形成用塗覆液之組成G 1 : 於紅色感光性樹脂層形成用塗覆液之組成R2 - 1丨中，使 用5 · 6份酮酞菁取代5 . 4份衣魯卡畊紅色BPT。 藍色感光性樹脂層形成用塗覆液之組成B 1 : 於紅色感光性樹脂層形成用塗覆液之組成R2 - 1丨中，使 用5 · 2份蘇丹藍取代5 . 4份衣魯卡畊紅色bpt。 黑色感光性樹脂層形成用塗覆液之組成K 1 : 於紅色感光性樹脂層形成用塗覆液之組成r2 _ u Ψ，使 用1 0 · 0份碳黑取代5 . 4份衣魯卡畊紅色BPT。 而且’上述各感光性樹脂層形成用塗覆液藉由_實施例 1 - 1 5相同得方法調製。 上述組成R 2 · 1 1、G 1、B 1或K 1之各塗覆液性能趣^ %上述相 同地評估，結果如袠2-5所示。 - 55- 1259813 使± @ 象形成材料以與實施例1 _ 1 5相同的方法製作 濾、色片’結果玻璃基板與感光性樹脂層之密接性佳。 比較例2 - 4 於實施例2 - 1 5之組成R2 - 1 1、G 1、B 1及K 1中，調製沒 有添加本發明用界面活性劑之塗覆液R2 _ 1 2、G2、B2及K2 ’與實施例2 - 1 5相同地製作濾色片。結果，產生塗覆斑。 而且’塗覆液R2 - 12、G2、B2及K2之性能與上述相同地予 以評估’如表2 - 5所示。Type of Coating Liquid C1 Type of Coating Liquid R1 Substrate Adhesive Surface Appearance Example 2-1 C2-1 R2-9 〇A Example 2-2 C2-2 R2-9 〇A Example 2-3 C2- 3 R2-9 〇A Example 2-4 C2-4 R2-9 〇A Example 2-5 C2-5 R2-9 〇A Example 2-6 C2-6 R2-9 〇C Example 2-7 C2-7 R2-9 〇A Comparative Example 2-1 C2-8 R2-9 ◎ E Comparative Example 2-2 C2-9 R2-9 〇D Comparative Example 2-3 C2-10 R2-10 〇D Example 2 -8 C2-1 R2-1 〇A Example 2-9 C2-2 R2-2 〇A Example 2-10 C2-3 R2-3 〇A Example 2-11 C2-4 R2-4 〇A Implementation Example 2-12 C2-5 R2-5 〇A Example 2-13 C2-6 R2-6 〇C Example 2-14 C2-7 R2-7 〇B Example 2 - 1 5 In a thickness of 100 μηι The coating liquid for forming a thermoplastic resin layer formed by the following composition C2 was spin-coated on a carrier of the ethylene phthalate film, and dried to provide an alkali-soluble thermoplastic resin layer having a dry film thickness of 20 μm. Then, a coating liquid composed of the above composition Ρ 2 was spin-coated on the above-mentioned thermoplastic resin layer, and dried to provide an oxygen barrier layer having a dry film thickness of 1.6 μm. The coating liquid for forming a red photosensitive resin layer formed by the following composition R2-U was coated on a carrier having three thermoplastic resin layers and an oxygen barrier layer, and each of the coatings was formed by the composition G! The coating liquid for forming a green photosensitive resin layer 'coating liquid for forming a blue photosensitive resin layer composed of the composition B 1 and the coating liquid for forming a black photosensitive resin layer formed of the composition K 1 ' Drying, forming a photosensitive resin layer of a color having a dry film thickness of 2 μm, and forming a cover sheet of polypropylene (thickness of 12 μm) on the photosensitive resin layer to form an image forming material, a magenta photosensitive resin layer In the composition R1-11 of the coating liquid for forming a red photosensitive resin layer for forming the coating liquid R2-11, the same is true except that the surfactant S1-2 of the present invention is changed to the surfactant 2 for the invention. Modulate the ground. The composition of the coating liquid for forming a green photosensitive resin layer G 1 : In the composition R 2 - 1 涂覆 of the coating liquid for forming a red photosensitive resin layer, 5.6 parts of ketone phthalocyanine is used instead of 5.4 parts of ruuka Plow the red BPT. The composition of the coating liquid for forming a blue photosensitive resin layer B 1 : In the composition R 2 - 1 涂覆 of the coating liquid for forming a red photosensitive resin layer, 5 2 parts of Sudan blue is used instead of 5.4 parts of ruuka Plowing red bpt. The composition of the coating liquid for forming a black photosensitive resin layer K 1 : the composition r2 _ u Ψ of the coating liquid for forming a red photosensitive resin layer, using 1 0 · 0 parts of carbon black instead of 5.4 parts Red BPT. Further, the above coating liquid for forming a photosensitive resin layer was prepared by the same method as in Example 1-5. The properties of the respective coating liquids of the above composition R 2 · 1 1 , G 1 , B 1 or K 1 were evaluated in the same manner as above, and the results are shown in 袠 2-5. - 55 - 1259813 The image forming material was produced in the same manner as in Example 1 - 15 except that the image forming material was excellent in the adhesion between the glass substrate and the photosensitive resin layer. Comparative Example 2 - 4 In the compositions R2 - 1 1 , G 1 , B 1 and K 1 of Examples 2 - 5 , the coating liquid R2 _ 1 2, G2, B2 without the surfactant of the present invention was prepared. And K2', a color filter was produced in the same manner as in Example 2 - 15. As a result, a coating spot is produced. Further, the properties of the coating liquids R2-12, G2, B2 and K2 were evaluated in the same manner as described above, as shown in Table 2-5.

表2 - 5 塗覆液之種類 - 塗覆液性能 塗覆面狀 表面之凹凸 發泡性 消泡性 顯像液溶解性 R2-11 〇 〇 〇 〇 〇 G1 〇 〇 〇 〇 〇 B1 〇 〇 〇 〇 〇 K1 〇 〇 〇 〇 〇 R2-12 X X ◎ ◎ 一 G2 X X ◎ ◎ 一 B2 X X ◎ ◎ — K2 X X ◎ ◎ —Table 2 - 5 Types of coating liquid - Coating liquid properties Coating surface-like surface Concavo-convex foaming Defoaming imaging solution Solubility R2-11 〇〇〇〇〇G1 〇〇〇〇〇B1 〇〇〇〇 〇K1 〇〇〇〇〇R2-12 XX ◎ ◎ One G2 XX ◎ ◎ One B2 XX ◎ ◎ — K2 XX ◎ ◎ —

上述藉由使用本發明用界面活性劑（2 )，可提供沒有塗覆 斑、塗覆面狀平滑、層厚均勻且沒有色斑、不會發泡且消 、泡性優異、玻璃基板之密接性優異的塗覆液及載負它之影 像形成材料。 實施例3 (實施例3 - 1〜實施例3 - 1 5 )、比較例3 (比較例 3 — 1〜比較例3 - 4 ) -56- 1259813 1 )本發明用界面活性劑S 3 -丨〜S 3 - 5 (共聚物（3 ))之合成或 調製 使用表3 - 1所示單體（a )、單體（c )及單體（e )，合成或調 製具有同表所示質量平均分子量之本發明用界面活性劑。 表3 '1 -—_ 一 --—-- 單體（a) 單體（c) 單體（e) 共聚合比 (a) · (c) : (e) (質量比） 質量平均 分子量 R〇i Ri 11 1 m R〇5 R〇6 R〇9 s ^3-1 Η 一 2 0 4 ch3 ch3 H 8 60:20:20 10000 S3-2 Η 一 2 0 6 ch3 ch3 H 8 60:20:20 10000 S3-3 Η 一 2 0 8 ch3 ch3 H 8 60:20:20 10000 ^S3-4 ch3 — 2 0 4 ch3 ch3 H 8 60:20:20 10000 S3-5 ch3 — 2 0 8 ch3 ch3 H 8 60:20:20 10000 2 )熱塑性樹脂層形成用塗覆液C 3 ( C 3 - 1〜C 3 - 1 0 )之調製 熱塑性樹脂層形成用塗覆液C3 - 1之調製 於熱塑性樹脂層形成用塗覆液之組成C 1 - 1中，除將本發 明用界面活性劑S 1 - 1改成本發明用界面活性劑S 3 - 1外， 相同地予以調製。 熱塑性樹脂層形成用塗覆液C3 - 2〜3 - 7之調製 於熱塑性樹脂層形成用塗覆液C 3 - 1之調製中，將本發明 用界面活性劑之種類、添加量變更成如表3 - 2所示。 熱塑性樹脂層形成用塗覆液C3 - 8之調製 於熱塑性樹脂層形成用塗覆液C3 - 1之調製中，不使用本 發明用界面活性劑予以調製。 熱塑性樹脂層形成用塗覆液C3 - 9之調製 1259813 於熱塑性樹脂層形成用塗覆液c 3 - 1之調製中，使用氟系 界面活性劑A取代本發明用界面活性劑，相同地調製。 熱塑性樹脂層形成用塗覆液C 3 - 1 0之調製 於熱塑性樹脂層形成用塗覆液C 3 - 1之調製中，以固成份 量使用等質量份梅卡法克F 1 42 - D (大日本油墨化學工業（股） 製）取代本發明用界面活性劑，相同地調製。 3 )紅色感光性樹脂層形成用塗覆液R3 ( R3 -1〜R3 - 1 0 )之調劑 紅色感光性樹脂層形成用塗覆液之組成R3 - 1之調製 於紅色感光性樹脂層形成用塗覆液之組成R 1 - 1中，除將 本發明用界面活性劑S 1 - 1改成本發明用界面活性劑S 3 - 1 外，相同地予以調製。 紅色感光性樹脂層形成用塗覆液R3 - 2〜3 - 7之調製 於紅色感光性樹脂層形成用塗覆液R 3 - 1之調製中，本發 明用界面活性劑之種類、添加量變更成如表3 - 3所示。 紅色感光性樹脂層形成用塗覆液R3 - 8之調製 於紅色感光性樹脂層形成用塗覆液R 3 - 1之調製中，不使 用本發明用界面活性劑予以調製。 紅色感光性樹脂層形成用塗覆液R3 - 9之調製 於紅色感光性樹脂層形成用塗覆液R 3 - 1之調製中，使用 界面活性劑A取代本發明用界面活性劑，相同地調製。 紅色感光性樹脂層形成用塗覆液R 3 - 1 0之調製 於紅色感光性樹脂層形成用塗覆液R3 - 1之調製中，以固 成份量使用等質量份梅卡法克F142-D(大日本油裹化學工 業（股）製）取代本發明用界面活性劑，相同地調製。 - 58- 1259813 上述調製的熱塑性樹脂層形成用塗覆液及紅色感光性樹 脂層形成用塗覆液之性能藉由下述評估，結果如表3 - 2、3 - 3 所示。 (1 )塗覆面狀（塗覆斑） 與實施例1相同地予以評估。 (2)表面凹凸 與實施例1相同地予以評估。 表3-2By using the surfactant (2) of the present invention, it is possible to provide no coating spots, smooth coating surface, uniform layer thickness, no color unevenness, no foaming, excellent foaming property, and good adhesion of the glass substrate. Excellent coating liquid and image forming material carrying it. Example 3 (Examples 3-1 to 3 - 15), Comparative Example 3 (Comparative Example 3-1 to Comparative Example 3 - 4) -56- 1259813 1) Surfactant S 3 -丨 used in the present invention Synthesis or preparation of ~S 3 - 5 (copolymer (3 )) using the monomer (a), monomer (c) and monomer (e) shown in Table 3-1, synthesized or prepared to have the mass shown in the same table The surfactant of the present invention is an average molecular weight. Table 3 '1 -—_ One----- Monomer (a) Monomer (c) Monomer (e) Copolymerization ratio (a) · (c) : (e) (mass ratio) Mass average molecular weight R 〇i Ri 11 1 m R〇5 R〇6 R〇9 s ^3-1 Η one 2 0 4 ch3 ch3 H 8 60:20:20 10000 S3-2 Η one 2 0 6 ch3 ch3 H 8 60:20 :20 10000 S3-3 Η one 2 0 8 ch3 ch3 H 8 60:20:20 10000 ^S3-4 ch3 — 2 0 4 ch3 ch3 H 8 60:20:20 10000 S3-5 ch3 — 2 0 8 ch3 ch3 H 8 60:20:20 10000 2 ) A coating liquid for forming a thermoplastic resin layer C 3 (C 3 -1 to C 3 - 10 ), a coating liquid for forming a thermoplastic resin layer, and a coating liquid C3 -1 The composition C 1 -1 of the coating liquid for layer formation was prepared in the same manner except that the surfactant S 1 -1 of the present invention was changed to the surfactant S 3 - 1 for the invention. In the preparation of the coating liquid for forming a thermoplastic resin layer C 3 - 1 in the coating liquid C3 - 2 to 3 - 7 for forming a thermoplastic resin layer, the type and amount of the surfactant used in the present invention are changed as shown in the table. 3 - 2 are shown. The coating liquid C3-8 for forming a thermoplastic resin layer is prepared by preparing a coating liquid C3-1 for forming a thermoplastic resin layer, and is prepared without using the surfactant of the present invention. Preparation of Coating Liquid C3 - 9 for Forming Thermoplastic Resin Layer 1259813 In the preparation of coating liquid c 3 - 1 for forming a thermoplastic resin layer, a fluorine-based surfactant A is used instead of the surfactant for use in the present invention, and the same is prepared. In the preparation of the coating liquid C 3 - 1 for forming a thermoplastic resin layer, in the preparation of the coating liquid C 3 -1 for forming a thermoplastic resin layer, an equal mass part of Mekafak F 1 42 - D is used as the solid content. The Dainippon Ink Chemical Industry Co., Ltd. is prepared in the same manner as the surfactant used in the present invention. 3) Red liquid photosensitive resin layer-forming coating liquid R3 (R3 -1 to R3 - 1 0 ) Preparation of red photosensitive resin layer forming coating liquid composition R3 - 1 is prepared for red photosensitive resin layer formation The composition R 1 -1 of the coating liquid was prepared in the same manner except that the surfactant S 1 -1 of the present invention was changed to the surfactant S 3 - 1 for the invention. In the preparation of the red photosensitive resin layer-forming coating liquid R 3 -1 in the preparation of the red photosensitive resin layer-forming coating liquid R3 - 2 to 3 - 7, the type and amount of the surfactant used in the present invention are changed. As shown in Table 3 - 3. The red photosensitive resin layer-forming coating liquid R3-8 is prepared by preparing the red photosensitive resin layer-forming coating liquid R 3 -1 without using the surfactant of the present invention. In the preparation of the red photosensitive resin layer-forming coating liquid R 3 - 1 in the preparation of the red photosensitive resin layer-forming coating liquid R3 - 9, the surfactant A is used in place of the surfactant of the present invention, and the same is prepared. . The red photosensitive resin layer-forming coating liquid R 3 - 10 is prepared in the preparation of the red photosensitive resin layer-forming coating liquid R3 - 1, and the mass fraction is used in the mass fraction of the Mekafak F142-D. (Major Nippon Oil Chemical Industry Co., Ltd.) is prepared in the same manner as the surfactant used in the present invention. - 58- 1259813 The properties of the above-mentioned coating liquid for forming a thermoplastic resin layer and the coating liquid for forming a red photosensitive resin layer were evaluated by the following, and the results are shown in Tables 3 - 2, 3 - 3. (1) Coating surface (coating spot) was evaluated in the same manner as in Example 1. (2) Surface unevenness Evaluation was carried out in the same manner as in Example 1. Table 3-2

塗覆液C3之種類 組成C3之界面活性劑 塗覆液性能 種類 添加量（份） 塗覆面狀 表面之凹凸 C3-1 S3-1 3.0 △〜〇 △〜〇 C3-2 S3-2 3.0 〇 〇 C3-3 S3-3 3.0 〇 〇 C3-4 S3-4 3.0 〇 〇 C3-5 S3-5 3.0 〇 〇 C3-6 S3-1 0.10 Δ △ C3-7 S3-1 6.0 〇 〇 C3-8 無添加 X X C3-9 界面活性劑A X X C3-10 梅卡法克（譯音）142-D △〜X △〜X 1259813 表3-3Type of coating liquid C3 Composition of surfactant composition of C3 Performance type Adding amount (parts) Concavity and convexity of coated surface surface C3-1 S3-1 3.0 △~〇△~〇C3-2 S3-2 3.0 〇〇 C3-3 S3-3 3.0 〇〇C3-4 S3-4 3.0 〇〇C3-5 S3-5 3.0 〇〇C3-6 S3-1 0.10 Δ △ C3-7 S3-1 6.0 〇〇C3-8 No added XX C3-9 Surfactant AXX C3-10 Mekafak (transliteration) 142-D △~X △~X 1259813 Table 3-3

塗覆液R3之種類 組成R3之界面活性劑 塗覆液性能 種類 添加量（份） 塗覆面狀 表面之凹凸 R3-1 S3-1 1.0 △〜〇 △〜〇 R3-2 S3-2 1.0 〇 〇 R3-3 S3-3 1.0 〇 〇 R3-4 S3-4 1.0 〇 〇 R3-5 S3-5 1.0 〇 〇 R3-6 S3-1 0.03 Δ Δ R3-7 S3-1 2.0 Δ 〇 R3-8 無添加 X X R3-9 界面活性劑A X X R3-10 梅卡法克（譯音）142-D △〜X △〜X 實施例3 - 1〜3 - 1 4、比較例3 - 1〜3 - 3Type of coating liquid R3 Composition of surfactant composition of R3 Performance type Adding amount (parts) Concavity and convexity of coated surface surface R3-1 S3-1 1.0 △~〇△~〇R3-2 S3-2 1.0 〇〇 R3-3 S3-3 1.0 〇〇R3-4 S3-4 1.0 〇〇R3-5 S3-5 1.0 〇〇R3-6 S3-1 0.03 Δ Δ R3-7 S3-1 2.0 Δ 〇R3-8 No added XX R3-9 surfactant AXX R3-10 Mekafak (transliteration) 142-D △~X △~X Example 3 - 1~3 - 1 4, Comparative Example 3 - 1~3 - 3

在厚度50μηι聚對酞酸乙二酯薄膜之載體上旋轉塗覆表 3 - 4記載的熱塑性樹脂層形成用塗覆液，乾燥、設置乾燥 膜厚爲2 Ο μ m之驗可溶性熱塑性樹脂層。其次，在上述熱塑 性樹脂層上旋轉塗覆由下述組成P 1所成的塗覆液，乾燥、 設置乾燥膜厚爲1 . 6μΐϊΐ之阻氧層。 在具有上述熱塑性樹脂層及阻氧層之載體上旋轉塗覆表 3 - 4記載的紅色感光性樹脂層形成用塗覆液，乾燥、形成 乾燥膜厚爲2 μπι之紅色感光性樹脂層，且在該紅色感光性 樹脂層上使聚丙烯（厚度1 2 μπι)之被覆片板，製作影像形成 材料。 與實施例1相同地觀察所得影像形成材料之紅色感光性 樹脂層的玻璃基板密接性。結果如表3 - 4所$。 -60- 1259813 濾色片之製作 使用所得影像形成材料，與實施例1相同地製得僅紅色 畫素之濾色片’相同地予以評估。所得結果如表3 - 4所示 表3-4 塗覆液C3之種類 塗覆液R3之種類 基板密接性 表面外觀 實施例3-1 C3-1 R3-9 〇 Β 實施例3-2 C3-2 R3-9 〇 A 實施例3-3 C3-3 R3-9 〇 B 實施例3-4 C3-4 R3-9 〇 A 實施例3-5 C3-5 R3-9 〇 A 實施例3-6 C3-6 R3-9 〇 Β 實施例3-7 C3-7 R3-9 〇 Β 比較例3-1 C3-8 R3-9 ◎ Ε 比較例3-2 C3-9 R3-9 〇 D 比較例3-3 C3-10 R3-10 〇 D 實施例3-8 C3-1 R3-1 〇 Β 實施例3-9 C3-2 R3-2 〇 A 實施例3-10 C3-3 R3-3 〇 Β 實施例3-11 C3-4 R3-4 〇 A 實施例3-12 C3-5 R3-5 〇 A 實施例3-13 C3-6 R3-6 〇 C 實施例3-14 C3-7 R3-7 〇 ΒThe coating liquid for forming a thermoplastic resin layer described in Table 3 - 4 was spin-coated on a carrier having a thickness of 50 μm of a polyethylene terephthalate film, and dried to provide a dry thermoplastic resin layer having a dry film thickness of 2 μm. Next, a coating liquid composed of the following composition P 1 was spin-coated on the above-mentioned thermoplastic resin layer, and dried, and an oxygen barrier layer having a dry film thickness of 1.6 μm was provided. The coating liquid for forming a red photosensitive resin layer described in Table 3-4 is spin-coated on a carrier having the thermoplastic resin layer and the oxygen barrier layer, and dried to form a red photosensitive resin layer having a dry film thickness of 2 μm. A coated sheet of polypropylene (thickness: 12 μm) was formed on the red photosensitive resin layer to prepare an image forming material. The glass substrate adhesion of the red photosensitive resin layer of the obtained image forming material was observed in the same manner as in Example 1. The results are as shown in Table 3 - 4. -60- 1259813 Preparation of color filter Using the obtained image forming material, a color filter of only red pixels was produced in the same manner as in Example 1 and evaluated in the same manner. The results obtained are shown in Table 3-4. Table 3-4. Types of Coating Liquid C3 Coating Liquid R3 Type Substrate Adhesive Surface Appearance Example 3-1 C3-1 R3-9 实施 Example 3-2 C3- 2 R3-9 〇A Example 3-3 C3-3 R3-9 〇B Example 3-4 C3-4 R3-9 〇A Example 3-5 C3-5 R3-9 〇A Example 3-6 C3-6 R3-9 实施 Example 3-7 C3-7 R3-9 〇Β Comparative Example 3-1 C3-8 R3-9 ◎ Ε Comparative Example 3-2 C3-9 R3-9 〇D Comparative Example 3 -3 C3-10 R3-10 〇D Example 3-8 C3-1 R3-1 实施 Example 3-9 C3-2 R3-2 〇A Example 3-10 C3-3 R3-3 实施 Implementation Example 3-11 C3-4 R3-4 〇A Example 3-12 C3-5 R3-5 〇A Example 3-13 C3-6 R3-6 〇C Example 3-14 C3-7 R3-7 〇 Β

實施例3 - 1 5 在厚度ΙΟΟμπι聚對酞酸乙二酯薄膜之載體上旋轉塗覆由 下述組成C3所成的熱塑性樹脂層形成用塗覆液’乾燥、設 -61- 1259813 置乾燥膜厚爲2Ομπι之鹼可溶性熱塑性樹脂層。 然後’在上述熱塑性樹脂層上旋轉塗覆由上述組成ρ 2所 成的塗覆液，乾燥、設置乾燥膜厚爲1 ·6 μ m之阻氧層。 在具有3張上述熱塑性樹脂層及阻氧層之載體上各旋轉 塗覆由下述組成R 3 - 1 1所成的紅色感光性樹脂層形成用塗 覆液、由組成G 1所成的綠色感光性樹脂層形成用塗覆液、 由組成B 1所成的藍色感光性樹脂層形成用塗覆液、及由組 成K 1所成的黑色感光性樹脂層形成用塗覆液’乾燥、形成 乾燥膜厚爲2μπι之各色感光性樹脂層，且在該感光性樹脂 層上使聚丙烯（厚度1 2μπι)之被覆片板，製作影像形成材料 〇 紅色感光性樹脂層形成用塗覆液R3 - 1 1 於紅色感光性樹脂層形成用塗覆液之組成R1 -11中，除 將本發明用界面活性劑S 1 - 2改成本發明用界面活性劑s L 2外，相同地予以調製。 綠色感光性樹脂層形成用塗覆液之組成G 1 : 於紅色感光性樹脂層形成用塗覆液之組成R 3 - 1 1中，使 用5 . 6份酮酞菁取代5 . 4份衣魯卡畊紅色ΒΡΤ。 藍色感光性樹脂層形成用塗覆液之組成Β 1 : 於紅色感光性樹脂層形成用塗覆液之組成R 3 - 1 1中，使 用5 . 2份蘇丹藍取代5 . 4份衣魯卡阱紅色ΒΡΤ。 黑色感光性樹脂層形成用塗覆液之組成Κ 1 : 於紅色感光性樹脂層形成用塗覆液之組成R3-U中，使 用1 0 . 0份碳黑取代5 . 4份衣魯卡畊紅色ΒΡΤ。 -62- 1259813 而且’上述各感光性樹脂層形成用塗覆液藉由與實施例 1 -15相同得方法調製。 上述組成R3 - 1 1、G 1、B 1或Κ 1之各塗覆液性能與上述相 同地評估，結果如表3 - 5所示。 使用上述影像形成材料以與實施例1 5相同的方法製作 濾色片，結果玻璃基板與感光性樹脂層之密接性佳。 比較例3 - 4 於實施例3 - 1 5之組成R 3 - 1 1、G 1、B 1及K 1中，調製沒 有添加本發明用界面活性劑之塗覆液R 3 - 1 2、G 2、B 2及κ 2 ，與實施例3 - 1 5相同地製作濾色片。結果，產生塗覆斑。 而且，塗覆液R3- 12、G2、B2及K2之性能與上述相同地予 以評估，如表3-5所示。 表3 - 5Example 3 - 15 5 On a carrier of a thickness of ΙΟΟμπι polyethylene terephthalate film, a coating liquid for forming a thermoplastic resin layer formed by the following composition C3 was spin-coated, and a dry film was set to -61-1259813. A layer of a soluble thermoplastic resin layer having a thickness of 2 μm. Then, a coating liquid composed of the above composition ρ 2 was spin-coated on the above thermoplastic resin layer, and an oxygen barrier layer having a dry film thickness of 1.6 m was dried. The coating liquid for forming a red photosensitive resin layer formed by the following composition R 3 - 1 1 is spin-coated on a carrier having three thermoplastic resin layers and an oxygen barrier layer, and the green color of the composition G 1 is formed. The coating liquid for forming a photosensitive resin layer, the coating liquid for forming a blue photosensitive resin layer formed of the composition B 1 , and the coating liquid for forming a black photosensitive resin layer formed of the composition K 1 are dried. A photosensitive resin layer having a dry film thickness of 2 μm was formed, and a coated sheet of polypropylene (thickness: 12 μm) was formed on the photosensitive resin layer to prepare a coating liquid R3 for forming an image forming material of a magenta photosensitive resin layer. - 1 1 In the composition R1-11 of the coating liquid for forming a red photosensitive resin layer, the same is prepared except that the surfactant S 1 - 2 of the present invention is changed to the surfactant s L 2 for the invention. . The composition of the coating liquid for forming a green photosensitive resin layer G 1 : In the composition R 3 - 1 1 of the coating liquid for forming a red photosensitive resin layer, 5.6 parts of ketone phthalocyanine is used instead of 5. 4 parts of Yilu Card ploughing red. The composition of the coating liquid for forming a blue photosensitive resin layer Β 1 : In the composition R 3 - 1 1 of the coating liquid for forming a red photosensitive resin layer, 5.2 parts of Sudan blue is used instead of 5.4 parts of clothing The card trap is red. The composition of the coating liquid for forming a black photosensitive resin layer Κ 1 : In the composition R3-U of the coating liquid for forming a red photosensitive resin layer, 10 parts of carbon black is used instead of 5.4 parts of ruthenium Red dragonfly. Further, the above coating liquid for forming a photosensitive resin layer was prepared by the same method as in Example 1-15. The properties of the respective coating liquids of the above composition R3 - 1 1 , G 1 , B 1 or Κ 1 were evaluated in the same manner as above, and the results are shown in Table 3-5. Using the image forming material described above, a color filter was produced in the same manner as in Example 15. As a result, the adhesion between the glass substrate and the photosensitive resin layer was good. Comparative Example 3 - 4 In the compositions R 3 - 1 1 , G 1 , B 1 and K 1 of Examples 3 - 15, the coating liquid R 3 - 1 2, G which was not added with the surfactant of the present invention was prepared. 2. B 2 and κ 2 A color filter was produced in the same manner as in Example 3 - 15. As a result, a coating spot is produced. Further, the properties of the coating liquids R3-12, G2, B2 and K2 were evaluated in the same manner as described above, as shown in Table 3-5. Table 3 - 5

塗覆液之種類 塗覆名 g性能 塗覆面狀 表面之凹凸 R3-11 〇 〇 G1 〇 〇 B1 〇 〇 K1 〇 〇 R3-12 X X G2 X X B2 X X K2 X X 上述藉由本發明，可提供沒有塗覆斑、塗覆面狀平滑、 層厚均勻且沒有色斑、、玻璃基板之密接性優異的塗覆液 -63- 1259813 及載負它之影像形成材料u 實施例4 (實施例4 - 1〜實施例4 - 1 5 )、比較例4 (比較例 4 - 1〜比較例4 - 4 ) 1 )本發明用界面活性劑S 4 - 1〜S 4 - 5 (共聚物（4 ))之合成或 調製 使用表4 - 1所示單體（a )、單體（〇及單體（f )，合成或調 製具有同表所示質量平均分子量之本發明用界面活性劑。 一表 4 - 1 _ 單體（a) 單體（c) 單體c f) 共聚合比 (a):(c):(f) (質量比） 質量平均 分子量 .R〇i Ri n 1 m R〇5 R〇6 R〇io R〇n R〇l2 R〇l3 r2 S4-1 Η 2 0 4 ch3 ch3 ch3 H H H -ch2- 60:30:10 10000 S4-2 Η 2 0 8 ch3 ch3 ch3 H H H -ch2- 60:30:10 10000 S4-3 ch3 2 0 4 ch3 ch3 ch3 H H H -ch2- 60:30:10 10000 S4-4 ch3 2 0 6 ch3 ch3 ch3 H H H -ch2- 60:30:10 10000 S4-5 ch3 - 2 0 8 ch3 ch3 ch3 H H H -CH2- 60:30:10 10000 2 )熱塑性樹脂層形成用塗覆液C4(C4 - 1〜C4 - 10 )之調製 熱塑性樹脂層形成用塗覆液C4 - 1之調製 於熱塑性樹脂層形成用塗覆液之組成C 1 - 1中，除將本發 明用界面活性劑S 1- 1改成本發明用界面活性劑S4 - 1外， 相同地予以調製。 熱塑性樹脂層形成用塗覆液C4 - 2〜C4 - 7之調製 於熱塑性樹脂層形成用塗覆液C4 - 1之調製中，將本發明 用界面活性劑之種類、添加量變更成如表4 - 2所示。 熱塑性樹脂層形成用塗覆液C4 - 8之調製 -64- 1259813 於熱塑性樹脂層形成用塗覆液C4 - 1之調製中，不使用本 發明用界面活性劑予以調製。 熱塑性樹脂層形成用塗覆液C4 - 9之調製 於熱塑性樹脂層形成用塗覆液C4 - 1之調製中’除使用氟 系界面活性劑A取代本發明用界面活性劑外，相同地調製 〇 熱塑性樹脂層形成用塗覆液C4 - 1 0之調製 於熱塑性樹脂層形成用塗覆液C4 - 1之調製中，以固成份 量使用等質量份梅卡法克F 1 4 2 - D (大日本油墨化學工業（股） 製）取代本發明用界面活性劑’相同地調製。 3)紅色感光性樹脂層形成用塗覆液R4(R4 - 1〜R4 - 10) 紅色感光性樹脂層形成用塗覆液之組成R4 - 1之調製 於紅色感光性樹脂層形成用塗覆液之組成R 1 - 1中’除將 本發明用界面活性劑S 1 - 1改成本發明用界面活性劑S 4 - 1 外，相同地予以調製。 紅色感光性樹脂層形成用塗覆液R 4 - 2〜R 4 -7之調製 於紅色感光性樹脂層形成用塗覆液R4 - 1之調製中，將本 發明用界面活性劑之種類、添加量變更成如表4 - 3所示。 紅色感光性樹脂層形成用塗覆液R4 - 8之調製 於紅色感光性樹脂層形成用塗覆液R4 - 1之調製中，不使 用本發明用界面活性劑予以調製° 紅色感光性樹脂層形成用塗覆液R4 - 9之調製 於紅色感光性樹脂層形成用塗覆液R4 - 1之調製中，使用 上述界面活性劑A取代本發明用界面活性劑，相同地調製 -65- 1259813 紅色感光性樹脂層形成用塗覆液R4 - 1 0之調製 於紅色感光性樹脂層形成用塗覆液R4 - 1之調製中，以固 成份量使用等質量份梅卡法克F 1 4 2 - D (大日本油墨化學工 業（股）製）取代本發明用界面活性劑，相同地調製。 上述調製的熱塑性樹脂層形成用塗覆液及紅色感光性樹 脂層形成用塗覆液之性能藉由下述評估，結果如表4 - 2、4 - 3 所示。 (1 )塗覆面狀（塗覆斑） 與實施例1相同地予以評估。 (2 ) 表面凹凸 與實施例1相同地予以評估。 (3 )縮邊 塗覆一定面積’以目視或放大鏡觀察有無直徑爲2mm以 上之縮邊。 ◎:全無 〇：稍有’實用上沒有問題 △:少許 X :很多，無法使用 (4 )針孔 塗覆一定面積，計算直徑爲3mm以上之完全空孔數目。 ◎:全無 〇：稍有’實用上沒有問題 △:少許 -66- 1259813 X :很多，無法使用 表4-2 塗覆液C4 組成C4之界面活性劑 塗覆液性能 之種類 種類 添加量（份） 塗覆面狀 表面之凹凸 縮邊 針孔 C4-1 S4-1 3.0 △〜〇 △〜〇 〇 〇 C4-2 S4-2 3.0 ◎ ◎ 〇 〇 C4-3 S4-3 3.0 Δ Δ 〇 〇 C4-4 S4-4 3.0 〇 〇 〇 〇 C4-5 S4-5 3.0 ◎ ◎ 〇 〇 C4-6 S4-1 0.10 Δ Δ △〜〇 △〜〇 C4-7 S4-1 6.0 〇 〇 〇 〇 C4-8 無添加 X X X X C4-9 界面活性劑A X X △ Δ C4-10 梅卡法克（譯音）142-D △〜X △〜X Δ ΔType of coating liquid Coating name g property Coating uneven surface R3-11 〇〇G1 〇〇B1 〇〇K1 〇〇R3-12 XX G2 XX B2 XX K2 XX The above-mentioned invention can provide uncoated a coating liquid having a smooth spot, a smooth coating surface, a uniform layer thickness and no color unevenness, and excellent adhesion to a glass substrate - 63 - 1259813 and an image forming material loaded thereon. Example 4 (Example 4 - 1 to implementation) Example 4 - 15), Comparative Example 4 (Comparative Example 4-1 to Comparative Example 4-4) 1) The synthesis of the surfactant S 4 - 1 to S 4 - 5 (copolymer (4)) of the present invention or The monomer (a) and the monomer (〇 and monomer (f) shown in Table 4-1 are used for the preparation, and the surfactant of the present invention having the mass average molecular weight shown in the same table is synthesized or prepared. Table 4 - 1 _ Monomer (a) Monomer (c) Monomer cf) Copolymerization ratio (a): (c): (f) (mass ratio) Mass average molecular weight. R〇i Ri n 1 m R〇5 R〇6 R 〇io R〇n R〇l2 R〇l3 r2 S4-1 Η 2 0 4 ch3 ch3 ch3 HHH -ch2- 60:30:10 10000 S4-2 Η 2 0 8 ch3 ch3 ch3 HHH -ch2- 60:30: 10 10000 S4-3 ch3 2 0 4 ch3 ch3 ch3 HH H -ch2- 60:30:10 10000 S4-4 ch3 2 0 6 ch3 ch3 ch3 HHH -ch2- 60:30:10 10000 S4-5 ch3 - 2 0 8 ch3 ch3 ch3 HHH -CH2- 60:30:10 10000 2) The coating liquid C4 (1, C4 - 1 to C4 - 10 ) for forming a thermoplastic resin layer is prepared by preparing a coating liquid for forming a thermoplastic resin layer, and the composition of the coating liquid for forming a thermoplastic resin layer C 1 - In the first embodiment, the surfactant S 1- 1 of the present invention was modified in the same manner as the surfactant S 4 -1 for the invention. In the preparation of the coating liquid C4 - 2 to C4 - 7 for forming a thermoplastic resin layer, the coating liquid C4 - 1 for forming a thermoplastic resin layer is prepared, and the type and amount of the surfactant used in the present invention are changed as shown in Table 4. - 2 is shown. Preparation of Coating Liquid C4-8 for Forming Thermoplastic Resin Layer -64- 1259813 In the preparation of coating liquid C4-1 for forming a thermoplastic resin layer, it is prepared without using the surfactant of the present invention. In the preparation of the coating liquid C4-1 for forming a thermoplastic resin layer, the preparation of the coating liquid C4-1 for forming a thermoplastic resin layer is carried out in the same manner as in the case of using the surfactant of the present invention. The preparation liquid C4 - 10 for forming a thermoplastic resin layer is prepared in the preparation of the coating liquid C4 - 1 for forming a thermoplastic resin layer, and the mass fraction is used in the amount of the solid component of Mekafak F 1 4 2 - D (large The Japanese Ink Chemical Industry Co., Ltd.) is prepared in the same manner as the surfactant of the present invention. 3) Red photosensitive resin layer-forming coating liquid R4 (R4 - 1 to R4 - 10) Red photosensitive resin layer-forming coating liquid composition R4 - 1 is prepared in a red photosensitive resin layer-forming coating liquid The composition R 1 -1 was prepared in the same manner except that the surfactant S 1 -1 of the present invention was changed to the surfactant S 4 - 1 for the invention. In the preparation of the coating liquid R 4 - 2 to R 4 -7 for forming a red photosensitive resin layer, the coating liquid R4 - 1 for forming a red photosensitive resin layer is prepared, and the type of the surfactant used in the present invention is added. The quantity is changed as shown in Table 4-3. In the preparation of the red photosensitive resin layer-forming coating liquid R4-1, the preparation of the red photosensitive resin layer-forming coating liquid R4-8 is carried out without using the surfactant of the present invention. The red photosensitive resin layer is formed. In the preparation of the coating liquid R4-1 for the red photosensitive resin layer formation by the coating liquid R4-9, the surfactant A of the present invention is used instead of the surfactant for the present invention, and the -65-1265913 red photosensitive is similarly prepared. The coating liquid R4 - 10 for forming a resin layer is prepared in the preparation of the coating liquid R4 - 1 for forming a red photosensitive resin layer, and the mass fraction is used in the amount of solid components of Mekafak F 1 4 2 - D (Daily Ink Chemical Industry Co., Ltd.) is prepared in the same manner as the surfactant used in the present invention. The properties of the above-mentioned coating liquid for forming a thermoplastic resin layer and the coating liquid for forming a red photosensitive resin layer were evaluated by the following, and the results are shown in Tables 4 - 2, 4 - 3. (1) Coating surface (coating spot) was evaluated in the same manner as in Example 1. (2) Surface unevenness was evaluated in the same manner as in Example 1. (3) Shrinking a certain area is observed by visual or magnifying glass to see if there is a concavation with a diameter of 2 mm or more. ◎: Nothing 〇: Slightly there is no problem in practicality △: A little X: Many, can not be used (4) A pinhole is coated with a certain area, and the number of complete holes with a diameter of 3 mm or more is calculated. ◎: No flaws: Slightly 'practical problem △: A little -66- 1259813 X: Many, can not be used Table 4-2 Coating liquid C4 Composition of C4 surfactant spray coating properties Type of addition ( Parts) Concave-convex pinholes coated on the surface of the surface C4-1 S4-1 3.0 △~〇△~〇〇〇C4-2 S4-2 3.0 ◎ ◎ 〇〇C4-3 S4-3 3.0 Δ Δ 〇〇C4 -4 S4-4 3.0 〇〇〇〇C4-5 S4-5 3.0 ◎ ◎ 〇〇C4-6 S4-1 0.10 Δ Δ △~〇△~〇C4-7 S4-1 6.0 〇〇〇〇C4-8 No added XXXX C4-9 surfactant AXX △ Δ C4-10 Merkafak (transliteration) 142-D △~X △~X Δ Δ

表4 - 3 塗覆液R4 組成R4之界面活性劑 塗覆液性能 之種類 種類 添加量(份） 塗覆面狀 表面之凹凸 縮邊 針孔 R4-1 S4-1 1.0 △〜〇 △〜〇 〇 〇 R4-2 S4-2 1.0 ◎ ◎ 〇 〇 R4-3 S4-3 1.0 Δ Δ 〇 〇 R4-4 S4-4 1.0 〇 〇 〇 〇 R4-5 S4-5 1.0 ◎ ◎ 〇 〇 R4-6 S4-1 0.03 Δ Δ △〜〇 △〜〇 R4-7 S4-1 2.0 〇 〇 〇 〇 R4-8 無添加 X X X X R4-9 界面活性劑A X X Δ △ R4-10 梅卡法克（譯音）142-D △〜X △〜X Δ ΔTable 4 - 3 Coating Liquid R4 Composition of R4 Surfactant Coating Liquid Properties Type Addition Quantity (Parts) Coating Concave Surface Concave Holes R4-1 S4-1 1.0 △~〇△~〇〇 〇R4-2 S4-2 1.0 ◎ ◎ 〇〇R4-3 S4-3 1.0 Δ Δ 〇〇R4-4 S4-4 1.0 〇〇〇〇R4-5 S4-5 1.0 ◎ ◎ 〇〇R4-6 S4- 1 0.03 Δ Δ △~〇△~〇R4-7 S4-1 2.0 〇〇〇〇R4-8 No addition XXXX R4-9 Surfactant AXX Δ △ R4-10 Mekafak (transliteration) 142-D △ ~X △~X Δ Δ

- 67- 1259813 實施例4 - 1〜4 - 1 4、比較例4 - 1〜4 - 3 在厚度50_聚對酞酸乙二醋薄膜之載體上旋轉塗覆表 4-4記載的熱塑性樹脂層形成用塗覆液，乾燥、設置乾燥 膜厚爲20 μπι之鹼可溶性熱塑性樹脂層。其次’在上述熱塑 性樹脂層上旋轉塗覆由下述組成Ρ1所成的塗覆液’乾燥、 設置乾燥膜厚爲1 . 6μηι之阻氧層。 在具有上述熱塑性樹脂層及阻氧層之載體上旋轉塗覆表 4 - 4記載的紅色感光性樹脂層形成用塗覆液，乾燥、形成 乾燥膜厚爲2 μπι之紅色感光性樹脂層，且在該紅色感光性 樹脂層上使聚丙烯（厚度1 2μπι)之被覆片板，製作影像形成 材料。 與實施例j 1 f目同地觀察所得影像形成材料之紅色感光性 樹脂層的玻璃基板密接性。結果如表4 _ 4所示。 濾色片之製作 使用所得影像形成材料’與實施例"目同地製得僅紅色 畫素之濾色片’相同地予以評估。所得結果_ 口所示 -68- 1259813 表4-4- 67- 1259813 Example 4 - 1 to 4 - 1 4, Comparative Example 4 - 1 to 4 - 3 The thermoplastic resin described in Table 4-4 was spin-coated on a carrier having a thickness of 50_poly(ethylene terephthalate) film. The coating liquid for layer formation was dried, and an alkali-soluble thermoplastic resin layer having a dry film thickness of 20 μm was provided. Next, the coating liquid formed by the following composition Ρ1 was spin-coated on the above thermoplastic resin layer to dry, and an oxygen barrier layer having a dry film thickness of 1.6 μm was provided. The coating liquid for forming a red photosensitive resin layer described in Table 4-4 is spin-coated on a carrier having the thermoplastic resin layer and the oxygen barrier layer, and dried to form a red photosensitive resin layer having a dry film thickness of 2 μm. A coated sheet of polypropylene (thickness: 12 μm) was formed on the red photosensitive resin layer to prepare an image forming material. The glass substrate adhesion of the red photosensitive resin layer of the obtained image forming material was observed in the same manner as in the example j 1 f. The results are shown in Table 4_4. Production of Color Filters The obtained image-forming material was evaluated in the same manner as in the Example "Color-only color filter of the red pixel. The result is shown in the mouth -68- 1259813 Table 4-4

塗覆fe CM之種類 塗覆液R4之種類 基板密接性 表面外觀 實施例4 -1 C4-1 R4-9 〇 B 實施例4-2 C4-2 R4-9 〇 A 實施例4-3 C4-3 R4-9 〇 B 實施例4-4 C4-4 R4-9 〇 A 實施例4-5 C4-5 R4-9 〇 A 實施例4-6 C4-6 R4-9 ◎ C 實施例4-7 C4-7 R4-9 〇 B 實施例4-1 C4-8 R4-9 〇 E 實施例4 - 2 C4-9 R4-9 〇 D 實施例4-3 C4-10 R4-10 〇 D 實施例4-8 C4-1 R4-1 〇 B 實施例4-9 C4-2 R4-2 〇 A 實施例4-10 C4-3 R4-3 〇 B 實施例4-11 C4-4 R4-4 〇 A 實施例4-12 C4-5 R4-5 〇 A 實施例4-13 C4-6 R4-6 〇 C 實施例4-14 C4-7 R4-7 〇 B 實施例4 - 1 5 在厚度ΙΟΟμπι聚對酞酸乙二醋薄膜之載體上旋轉塗覆由 下述組成C4所成的熱塑性樹脂層形成用塗覆液，乾燥、設 置乾燥膜厚爲20μπι之鹼可溶性熱塑性樹脂層。 然後，在上述熱塑性樹脂層上旋轉塗覆由上述組成Ρ2所 成的塗覆液，乾燥、設置乾燥膜厚爲1 . 6 μη之阻氧層。 在具有3張上述熱塑性樹脂層及阻氧層之載體上各旋轉 -69- 1259813 塗覆由下述組成R 4 - 1 1所成的紅色感光性樹脂層形成用塗 覆液、由組成G 1所成的綠色感光性樹脂層形成用塗覆液、 由組成B 1所成的藍色感光性樹脂層形成用塗覆液、及由組 成K1所成的黑色感光性樹脂層形成用塗覆液，乾燥、形成 乾燥膜厚爲2μηι之各色感光性樹脂層，且在該感光性樹脂 層上使聚丙烯（厚度1 2μαι )之被覆片板’製作影像形成材料 〇 紅色感光性樹脂層形成用塗覆液R4 - 1 1 於紅色感光性樹脂層形成用塗覆液之組成R1 -11中，除 將本發明用界面活性劑S 1 - 2改成本發明用界面活性劑s ^ 2外，相同地予以調製。 綠色感光性樹脂層形成用塗覆液之組成G 1 : 於紅色感光性樹脂層形成用塗覆液之組成R4 · 1 1中，使 用5 . 6份酮酞菁取代5 . 4份衣魯卡畊紅色ΒΡΤ。 藍色感光性樹脂層形成用塗覆液之組成Β 1 : 於紅色感光性樹脂層形成用塗覆液之組成R4 - 1 1中，使 用5 . 2份蘇丹藍取代5 . 4份衣魯卡畊紅色ΒΡΤ。 黑色感光性樹脂層形成用塗覆液之組成Κ 1 : 於紅色感光性樹脂層形成用塗覆液之組成R4 - 1 1中，使 用1 〇 . 〇份碳黑取代5 . 4份衣魯卡畊紅色ΒΡΤ。 而且’上述各感光性樹脂層形成用塗覆液藉由與實施例 1 - 1 5相同得方法調製。 上述組成R4 - 1 1、G 1、β丨或κ 1之各塗覆液性能與上述相 同地評估，結果如表4 - 5所示。 -70- 1259813 使用上述影像形成材料以與實施例1 - 1 5相同的方法製作 濾、色片’結果玻璃基板與感光性樹脂層之密接性佳。 比較例4 - 4 於貫施例4 - 1 5之組成R4 - 1 1、G 1、B 1及K 1中’調製沒 有添加本發明用界面活性劑之塗覆液R4 - 12、G2、B2及K2 ’與實施例4 - 1 5相同地製作濾色片。結果，產生塗覆斑。 而且’塗覆液R4 - 1 2、G2、B2及K2之性能與上述相同地予 以評估，如表仁5所示。Type of coating liquid coated with Fe CM Type of substrate adhesion surface Appearance Example 4 -1 C4-1 R4-9 〇B Example 4-2 C4-2 R4-9 〇A Example 4-3 C4- 3 R4-9 〇B Example 4-4 C4-4 R4-9 〇A Example 4-5 C4-5 R4-9 〇A Example 4-6 C4-6 R4-9 ◎ C Example 4-7 C4-7 R4-9 〇B Example 4-1 C4-8 R4-9 〇E Example 4 - 2 C4-9 R4-9 〇D Example 4-3 C4-10 R4-10 〇D Example 4 -8 C4-1 R4-1 〇B Example 4-9 C4-2 R4-2 〇A Example 4-10 C4-3 R4-3 〇B Example 4-11 C4-4 R4-4 〇A Implementation Example 4-12 C4-5 R4-5 〇A Example 4-13 C4-6 R4-6 〇C Example 4-14 C4-7 R4-7 〇B Example 4 - 1 5 In the thickness ΙΟΟμπι poly 酞The coating liquid for forming a thermoplastic resin layer formed by the following composition C4 was spin-coated on a carrier of the acid acetonitrile film, and dried to provide an alkali-soluble thermoplastic resin layer having a dry film thickness of 20 μm. Then, a coating liquid composed of the above composition Ρ 2 was spin-coated on the above-mentioned thermoplastic resin layer, and dried, and an oxygen barrier layer having a dry film thickness of 1.6 μη was provided. The coating liquid for forming a red photosensitive resin layer formed by the following composition R 4 - 1 1 is coated on a carrier having three thermoplastic resin layers and an oxygen barrier layer, respectively, and is composed of a composition G 1 The coating liquid for forming a green photosensitive resin layer, the coating liquid for forming a blue photosensitive resin layer formed of the composition B 1 , and the coating liquid for forming a black photosensitive resin layer formed of the composition K1 Drying, forming a photosensitive resin layer having a dry film thickness of 2 μm, and forming a coating sheet of a polypropylene (thickness of 1 2 μαι) on the photosensitive resin layer to form an image forming material, a coating for forming a magenta photosensitive resin layer. The coating liquid R4 - 1 1 is the same as the composition R1 -11 of the coating liquid for forming a red photosensitive resin layer, except that the surfactant S 1 - 2 of the present invention is changed to the surfactant s ^ 2 for the invention. Modulate the ground. The composition of the coating liquid for forming a green photosensitive resin layer G 1 : In the composition R4 · 1 1 of the coating liquid for forming a red photosensitive resin layer, 5.6 parts of ketone phthalocyanine is used instead of 5.4 parts of ruuka Plow the red dragonfly. The composition of the coating liquid for forming a blue photosensitive resin layer Β 1 : In the composition R4 - 1 1 of the coating liquid for forming a red photosensitive resin layer, 5.2 parts of Sudan blue is used instead of 5.4 parts of ruuka Plow the red dragonfly. The composition of the coating liquid for forming a black photosensitive resin layer Κ 1 : In the composition R4 - 1 1 of the coating liquid for forming a red photosensitive resin layer, 1 〇. Plow the red dragonfly. Further, the above coating liquid for forming a photosensitive resin layer was prepared by the same method as in Example 1 - 15. The properties of the respective coating liquids of the above composition R4 - 1 1 , G 1 , β 丨 or κ 1 were evaluated in the same manner as above, and the results are shown in Table 4-5. -70- 1259813 Using the image forming material described above, a filter or a color paste was produced in the same manner as in Example 1 - 15. The result was excellent in adhesion between the glass substrate and the photosensitive resin layer. Comparative Example 4 - 4 In the composition of Examples 4 - 5, R4 - 1 1 , G 1 , B 1 and K 1 'modulation without the addition of the coating liquid for the surfactant of the present invention R4 - 12, G2, B2 And K2', a color filter was produced in the same manner as in Example 4 - 15. As a result, a coating spot is produced. Further, the properties of the coating liquids R4 - 2 2, G2, B2 and K2 were evaluated in the same manner as described above, as shown in Table 5.

表4 - 5 塗覆液之種類 塗覆液性能 塗覆面狀 表面之凹凸 縮邊 針孔 R4-11 〇 〇 〇 〇 G1 〇 〇 〇 〇 B1 〇 〇 〇 〇 K1 〇 〇 〇 〇 R4-12 X X X X G2 X X X X B2 X X X X K2 X X X XTable 4 - 5 Types of Coating Liquid Coating Fluid Properties Rough and Concave Pinholes for Coating Surfaces R4-11 〇〇〇〇G1 〇〇〇〇B1 〇〇〇〇K1 〇〇〇〇R4-12 XXXX G2 XXXX B2 XXXX K2 XXXX

上述藉由使用本發明用界面活性劑（4 )，可提供沒有塗覆 斑、塗覆面狀平滑、層厚均勻且沒有色斑、沒有縮邊或針 孔情形、玻璃基板之密接性優異的塗覆液及載負它之影像 形成材料。 實施例5 (實施例5 - 1〜實施例5 - 1 5 )、比較例5 (比較例 5 - 1〜比較例5 - 4 ) -71- 1259813 1 )本發明用界面活性劑S 5 - 1〜S 5 - 5 (共聚物（5 ))之合成或 調製 使用表5 - 1所示單體（a )、單體（c )及單體（d )，合成或調 製具有同表所示質量平均分子量之本發明用界面活性劑。 表 5- 1 _ 一---- S5-1 單體(a) 單體(c) 單體(d) 共聚合比 (a) : (b) : (c) (質量比） 質量平均分子量~ R〇i Ri η 1 m R〇5 R〇6 R〇7 R〇8 r q Η - 2 0 8 ch3 ch3 ch3 H 2 15 60:10:30 10000 S5-2 Η - 2 0 8 ch3 ch3 ch3 H 3 15 60:10:30 10000 S5-3 ch3 - 2 0 8 ch3 ch3 ch3 H 3 15 60:10:30 10000 S5-4 _S5-1+S5-2(S5-1/S5-2=10/50(質量比) S5-5 _ S5-1+S5-3(S5-1/S5-3 = 10/30(質量比__By using the surfactant (4) of the present invention, it is possible to provide a coating having no coating spots, a smooth coating surface, a uniform layer thickness, no color unevenness, no shrinkage or pinhole, and excellent adhesion of a glass substrate. The liquid coating and the image forming material carrying it. Example 5 (Examples 5 - 1 to 5 - 15 ), Comparative Example 5 (Comparative Example 5 - 1 to Comparative Example 5 - 4 ) -71 - 1259813 1 ) Surfactant S 5 - 1 for use in the present invention Synthesis or preparation of ~S 5 - 5 (copolymer (5 )) using the monomers (a), monomers (c) and monomers (d) shown in Table 5-1, synthesized or prepared to have the mass shown in the same table The surfactant of the present invention is an average molecular weight. Table 5- 1 _ I---- S5-1 Monomer (a) Monomer (c) Monomer (d) Copolymerization ratio (a) : (b) : (c) (mass ratio) Mass average molecular weight ~ R〇i Ri η 1 m R〇5 R〇6 R〇7 R〇8 rq Η - 2 0 8 ch3 ch3 ch3 H 2 15 60:10:30 10000 S5-2 Η - 2 0 8 ch3 ch3 ch3 H 3 15 60:10:30 10000 S5-3 ch3 - 2 0 8 ch3 ch3 ch3 H 3 15 60:10:30 10000 S5-4 _S5-1+S5-2 (S5-1/S5-2=10/50( Mass ratio) S5-5 _ S5-1+S5-3 (S5-1/S5-3 = 10/30 (mass ratio __)

2)熱塑性樹脂層形成用塗覆液C5(C5-1〜C5-10)之調製 熱塑性樹脂層形成用塗覆液C5 - 1之調製 於熱塑性樹脂層形成用塗覆液之組成C 1 - 1中，將本發明 用界面活性劑S 1- 1改成本發明用界面活性劑S 5 -丨外，相 同地予以調製。2) The coating liquid C5 (C5-1 to C5-10) for forming a thermoplastic resin layer, and the coating liquid C5-1 for preparing a thermoplastic resin layer, the composition of the coating liquid for forming a thermoplastic resin layer, C 1 - 1 In the present invention, the surfactant S 1- 1 was changed to the surfactant S 5 -丨 of the invention, and the same was prepared.

熱塑性樹脂層形成用塗覆液C5 - 2〜5 - 7之調製 於熱塑性樹脂層形成用塗覆液C5-1之調製中，將本發明 用界面活性劑之種類、添加量變更成如表5 _ 2所示。 熱塑性樹脂層形成用塗覆液C5 - 8之調製 於熱塑性樹脂層形成用塗覆液C 5 - 1之調製中，不使用本 發明用界面活性劑予以調製。 熱塑性樹脂層形成用塗覆液C5 - 9之調製 於熱塑性樹脂層形成用塗覆液C 5 - 1之調製中，使用氟系 -72- 1259813 界面活性劑A取代本發明用界面活性劑，相同地調製。 熱塑性樹脂層形成用塗覆液C 5 - 1 0之g周製 於熱塑性樹脂層形成用塗覆液c 5 - 1之調製中，以固成份 量使用等質量份梅卡法克F 1 4 2 - D (大日本油墨化學工業（股） 製）取代本發明用界面活性劑’相同地調製。 3 )紅色感光性樹脂層形成用塗覆液R5(R5 - 1〜R5 - 10)之調製 紅色感光性樹脂層形成用塗覆液之組成R5 - 1之調製 於紅色感光性樹脂層形成用塗覆液之組成R 1 - 1中，除將 本發明用界面活性劑S 1 - 1改成本發明用界面活性劑S 5 - 1 外，相同地予以調製。 紅色感光性樹脂層形成用塗覆液R5 - 2〜5 - 7之調製 於紅色感光性樹脂層形成用塗覆液R5 - 1之調製中，將本 發明用界面活性劑之種類、添加量變更成如表5 - 3所示。 紅色感光性樹脂層形成用塗覆液R5 - 8之調製 於紅色感光性樹脂層形成用塗覆液R5 - 1之調製中，不使 用本發明用界面活性劑予以調製。 紅色感光性樹脂層形成用塗覆液R5 - 9之調製 於紅色感光性樹脂層形成用塗覆液R5 - 1之調製中，使用 上述界面活性劑A取代本發明用界面活性劑，相同地調製 〇 紅色感光性樹脂層形成用塗覆液R5 - 1 0之調製 於紅色感光性樹脂層形成用塗覆液R5 - 1之調製中，除以 固成份量使用等質量份梅卡法克F1 42-D(大日本油墨化學 工業（股）製）取代本發明用界面活性劑外，相同地調製。 -73 - 1259813 上述調製的熱塑性樹脂層形成用塗覆液及紅色感光性樹 脂層形成用塗覆液之性能藉由下述評估，結果如表5 - 2、5 - 3 所示。 (1 )塗覆面狀（塗覆斑） 與實施例1相同地予以評估。 (2 ) 表面凹凸 與實施例1相同地予以評估。 (3 )縮邊 與實施例4相同地予以評估。 (4 )針孔 與實施例4相同地予以評估。 表5-2In the preparation of the coating liquid for forming a thermoplastic resin layer C5-1 in the coating liquid C5-2 to 5-7 for the formation of the thermoplastic resin layer, the type and amount of the surfactant used in the present invention are changed as shown in Table 5. _ 2 is shown. The coating liquid C5-8 for forming a thermoplastic resin layer is prepared by preparing a coating liquid C 5 -1 for forming a thermoplastic resin layer, and is prepared without using the surfactant of the present invention. In the preparation of the coating liquid C 5 - 9 for forming a thermoplastic resin layer, in the preparation of the coating liquid C 5 -1 for forming a thermoplastic resin layer, the surfactant of the present invention is replaced with a fluorine-based -72-1259813 surfactant A, the same Ground modulation. The coating liquid for forming a thermoplastic resin layer C 5 - 10 is prepared in the preparation of the coating liquid c 5 - 1 for forming a thermoplastic resin layer, and the mass fraction is used in the amount of the solid component of Mekafak F 1 4 2 - D (manufactured by Dainippon Ink Chemical Industry Co., Ltd.) is prepared in the same manner as the surfactant of the present invention. 3) The coating liquid R5 (R5 - 1 to R5 - 10) for forming a red photosensitive resin layer, and the composition of the coating liquid for forming a red photosensitive resin layer, R5 - 1 , prepared by coating a red photosensitive resin layer The composition R 1 -1 of the coating liquid was prepared in the same manner except that the surfactant S 1 -1 of the present invention was changed to the surfactant S 5 - 1 for the invention. In the preparation of the red photosensitive resin layer-forming coating liquid R5-1, the coating liquid R5-2 to 5-7 of the red photosensitive resin layer is prepared, and the type and amount of the surfactant used in the present invention are changed. As shown in Table 5-3. The red photosensitive resin layer-forming coating liquid R5-8 is prepared in the preparation of the red photosensitive resin layer-forming coating liquid R5-1, and is not prepared by using the surfactant of the present invention. The preparation of the red photosensitive resin layer-forming coating liquid R5 - 9 in the preparation of the red photosensitive resin layer-forming coating liquid R5 - 1 is carried out, and the surfactant A is used in place of the surfactant of the present invention, and is prepared in the same manner. In the preparation of the red liquid photosensitive resin layer-forming coating liquid R5 - 1 0 in the preparation of the red photosensitive resin layer-forming coating liquid R5 - 1, the mass fraction is divided by the solid content, and the mass parts are used, Mekafak F1 42 -D (manufactured by Dainippon Ink Chemical Industry Co., Ltd.) was prepared in the same manner as the surfactant used in the present invention. -73 - 1259813 The properties of the above-mentioned coating liquid for forming a thermoplastic resin layer and the coating liquid for forming a red photosensitive resin layer were evaluated by the following, and the results are shown in Tables 5 - 2, 5 - 3. (1) Coating surface (coating spot) was evaluated in the same manner as in Example 1. (2) Surface unevenness was evaluated in the same manner as in Example 1. (3) Shrinkage was evaluated in the same manner as in Example 4. (4) Pinholes were evaluated in the same manner as in Example 4. Table 5-2

塗覆液C5 組成C5之界面活性劑 塗覆ί g性能 之種類 種類 添加量（份） 塗覆面狀 表面之凹凸 縮邊 針孔 C5-1 S5-1 3.0 ◎ ◎ 〇 〇 C5-2 S5-2 3.0 ◎ ◎ 〇 〇 C5-3 S5-3 3.0 ◎ ◎ 〇 〇 C5-4 S5 - 4 3.0 ◎ ◎ 〇 〇 C5-5 S5-5 3.0 ◎ ◎ 〇 〇 C5-6 S5-1 0.10 △〜〇 △〜〇 〇 〇 C5-7 S5-1 6.0 ◎ ◎ 〇 〇 C5-8 無添加 X X X X C5-9 界面活性劑A X X △〜X △〜X C5-10 梅卡法克（譯音）142-D △〜X △〜X △〜X △〜X 1259813 表5 - 3Coating liquid C5 Composition of C5 surfactant preparation ί g Type of product Type of addition (parts) Coated surface of the concave and convex pinhole C5-1 S5-1 3.0 ◎ ◎ 〇〇C5-2 S5-2 3.0 ◎ ◎ 〇〇C5-3 S5-3 3.0 ◎ ◎ 〇〇C5-4 S5 - 4 3.0 ◎ ◎ 〇〇C5-5 S5-5 3.0 ◎ ◎ 〇〇C5-6 S5-1 0.10 △~〇△~ 〇〇〇C5-7 S5-1 6.0 ◎ ◎ 〇〇C5-8 No added XXXX C5-9 Surfactant AXX △~X △~X C5-10 Mekafak (transliteration) 142-D △~X △ ~X △~X △~X 1259813 Table 5 - 3

塗覆液R5 組成R5之界面活性劑 塗覆液性能 之種類 種類 添加量（份） 塗覆面狀 表面之凹凸 縮邊 針孔 R5-1 S5-1 1.0 ◎ ◎ 〇 〇 R5-2 S5-2 1.0 ◎ ◎ 〇 〇 R5-3 S5-3 1.0 ◎ ◎ 〇 〇 R5-4 S5-4 1.0 ◎ ◎ 〇 〇 R5-5 S5-5 1.0 ◎ ◎ 〇 〇 R5-6 S5-1 0.03 △〜〇 △〜〇 〇 〇 R5-7 S5-1 2.0 ◎ ◎ 〇 〇 R5-8 無添加 X X X X R5-9 界面活性劑A X X △〜X △〜X R5-10 梅卡法克（譯音）142-D △〜X △〜X △〜X △〜X 實施例5 - 1〜5 - 1 4、比較例5 - 1〜5 - 3 在厚度50μηι聚對酞酸乙二酯薄膜之載體上旋轉塗覆表 5 - 4記載的熱塑性樹脂層形成用塗覆液，乾燥、設置乾燥 膜厚爲20μπι之鹼可溶性熱塑性樹脂層。其次，在上述熱塑 性樹脂層上旋轉塗覆由下述組成Ρ 1所成的塗覆液，乾燥、 設置乾燥膜厚爲1 . 6μπι之阻氧層。 在具有上述熱塑性樹脂層及阻氧層之載體上旋轉塗覆表 5 - 4記載的紅色感光性樹脂層形成用塗覆液，乾燥、形成 車乙燥i吴厚爲2 μ m之紅色感光性樹脂層，且在該紅色感光性 樹脂層上使聚丙烯（厚度1 2 μ m )之被覆片板，製作影像形成 材料。 與實施例1相同地觀察所得影像形成材料之紅色感光性 樹脂層的玻璃基板密接性。結果如表5 _ 4所示。 -75- ’、 1259813 濾色片之製作 使用所得影像形成好 既付枓，與實施例1相同地製得僅紅色 畫素之濾色片，相同地予以評估。所得結果如表5 “所示 表5-4Coating liquid R5 Composition of R5 surfactant spray coating properties Type of addition amount (parts) Coated surface of the surface of the concave and convex pinhole R5-1 S5-1 1.0 ◎ ◎ 〇〇R5-2 S5-2 1.0 ◎ ◎ 〇〇R5-3 S5-3 1.0 ◎ ◎ 〇〇R5-4 S5-4 1.0 ◎ ◎ 〇〇R5-5 S5-5 1.0 ◎ ◎ 〇〇R5-6 S5-1 0.03 △~〇△~〇 〇〇R5-7 S5-1 2.0 ◎ ◎ 〇〇R5-8 No added XXXX R5-9 Surfactant AXX △~X △~X R5-10 Mekafak (transliteration) 142-D △~X △~ X Δ~X △~X Example 5 - 1 to 5 - 1 4, Comparative Example 5 - 1 to 5 - 3 Spin-coated on a carrier of a 50 μηη polyethylene terephthalate film, as described in Table 5 - 4 The coating liquid for forming a thermoplastic resin layer was dried, and an alkali-soluble thermoplastic resin layer having a dry film thickness of 20 μm was provided. Next, a coating liquid composed of the following composition Ρ 1 was spin-coated on the above-mentioned thermoplastic resin layer, and dried, and an oxygen barrier layer having a dry film thickness of 1.6 μm was provided. The coating liquid for forming a red photosensitive resin layer described in Table 5.4 is spin-coated on a carrier having the thermoplastic resin layer and the oxygen barrier layer, and dried to form a red photosensitive resin layer having a thickness of 2 μm. A coated sheet of polypropylene (thickness: 12 μm) was formed on the red photosensitive resin layer to prepare an image forming material. The glass substrate adhesion of the red photosensitive resin layer of the obtained image forming material was observed in the same manner as in Example 1. The results are shown in Table 5-4. -75-', 1259813 Color filter production Using the obtained image, the color filter of only the red pixel was obtained in the same manner as in Example 1, and was evaluated in the same manner. The results obtained are shown in Table 5 “Table 5-4

實施例5-1 ·~~------ 種類 塗覆液R5之種類 基板密接性 表面外觀 C5-1 R5-9 〇 A 實施例5 - 2 C5-2 R5-9 〇 A 實施例5-3 C5-3 R5-9 〇 A 實施例5-4 C5-4 R5-9 〇 A 實施例5-5 C5-5 R5-9 〇 A 實施例5-6 C5-6 R5-9 〇 C 實施例5-7 C5-7 R5-9 〇 A 比較例5-1 C5-8 R5-9 ◎ E 比較例5-2 C5-9 R5-9 〇 D 比較例5-3 C5-10 R5-10 〇 D 實施例5-8 C5-1 R5-1 〇 A 實施例5-9 C5-2 R5-2 〇 A 實施例 C5-3 R5-3 〇 A 實施例5-11 C5-4 R5-4 〇 A 實施例5、12 C5-5 R5-5 〇 A 實施例5-U C5-6 R5-6 〇 C 實施例5 -14 C5-7 R5-7 〇 A 實施例5 _ 1 5 在厚度ΙΟΟμίΏ聚對酞酸乙二酯薄膜之載體上旋轉塗覆由 下述組成C5所成的熱塑性樹脂層形成用塗覆液，乾燥、設 - 76- 1259813 置乾燥膜厚爲2 Ο μ m之驗司溶性熱塑性樹脂層。 然後，在上述熱塑性樹脂層上旋轉塗覆由上述組成P 2戶斤 成的塗覆液，乾燥、設置乾丨采肖吴厚爲1 . 6 ^m之阻氧層° 在具有3張上述熱塑性樹脂層及阻氧層之載體上各旋轉 塗覆由下述組成R 5 - 1丨所成的紅色感光性樹脂層形成用塗 覆液、由組成G1所成的綠色感光性樹脂層形成用塗覆液' 由組成B 1所成的藍色感光性樹脂層形成用塗覆液、及由組 成K 1所成的黑色感光性樹脂層形成用塗覆液’乾燥、形成 乾燥膜厚爲2 μπι之各色感光性樹脂層’且在該感光性樹脂 層上使聚丙烯（厚度丄2!1111)之被覆片板’製作影像形成材料 〇 紅色感光性樹脂層形成用塗覆液R5 -丨1 : 於紅色感光性樹脂層形成用塗覆液之組成R1 -11中，除 將本發明用界面活性劑s 1 - 2改成本發明用界面活性劑s 5、 2外，相同地予以調製。 綠色感光性樹脂層形成用塗覆液之組成G 1 : 於紅色感光性樹脂層形成用塗覆液之組成R - 1 1中，使用 5 . 6份酮酞菁取代5 . 4份衣魯卡畊紅色BPT。 藍色感光性樹脂層形成用塗覆液之組成B 1 : 於紅色感光性樹脂層形成用塗覆液之組成R5-1 1中，使 用5 . 2份蘇丹藍取代5 . 4份衣魯卡畊紅色BPT。 黑色感光性樹脂層形成用塗覆液之組成K 1 : 於紅色感光性樹脂層形成用塗覆液之組成R5 - 1 1中，使 用1 0 . 0份碳黑取代5 . 4份衣魯卡哄紅色BPT。 -77- 1259813 而且’上述各感光性樹脂層形成用塗覆液藉由與實施例 1 -丨5相同的方法調製。 上述ώ成R 5 - 1 1、g 1、B 1或K 1之各塗覆液性能與上述相 同地評估，結果如表5 - 5所示。 使用上述影像形成材料以與實施例1 _ 1 5相同的方法製作 濾色片’結果玻璃基板與感光性樹脂層之密接性佳。 比較例5 - 4 於貫施例5 - 1 5之組成R 5 - 1 1、G 1、Β 1及Κ 1中，調製沒 有添加本發明用界面活性劑之塗覆液r 5 _丨2、G 2、Β 2及Κ 2 ’與貫施例5 - 1 5相同地製作濾色片。結果，產生塗覆斑。 而且’塗覆液R5 - 12、G2、Β2及Κ2之性能與上述相同地予 以評估’如表5 - 5所示。 表5-5Example 5-1 ·~~------ Type of Coating Liquid R5 Substrate Adhesive Surface Appearance C5-1 R5-9 〇A Example 5 - 2 C5-2 R5-9 〇A Example 5 -3 C5-3 R5-9 〇A Example 5-4 C5-4 R5-9 〇A Example 5-5 C5-5 R5-9 〇A Example 5-6 C5-6 R5-9 〇C Implementation Example 5-7 C5-7 R5-9 〇A Comparative Example 5-1 C5-8 R5-9 ◎ E Comparative Example 5-2 C5-9 R5-9 〇D Comparative Example 5-3 C5-10 R5-10 〇 D Example 5-8 C5-1 R5-1 〇A Example 5-9 C5-2 R5-2 〇A Example C5-3 R5-3 〇A Example 5-11 C5-4 R5-4 〇A Example 5, 12 C5-5 R5-5 〇A Example 5-U C5-6 R5-6 〇C Example 5 -14 C5-7 R5-7 〇A Example 5 _ 1 5 In the thickness ΙΟΟμίΏ On the carrier of the ethylene phthalate film, a coating liquid for forming a thermoplastic resin layer formed by the following composition C5 is spin-coated, and dried to provide a dry film thickness of 2 Ο μ m. Resin layer. Then, a coating liquid composed of the above-mentioned composition P 2 is spin-coated on the above-mentioned thermoplastic resin layer, and dried, and an oxygen barrier layer having a dry thickness of 1.6 μm is provided. And a coating liquid for forming a green photosensitive resin layer formed of the composition G1 and a coating liquid for forming a green photosensitive resin layer formed by the composition G1, each of which is spin-coated on the carrier of the oxygen barrier layer. The coating liquid for forming a blue photosensitive resin layer formed by the composition B 1 and the coating liquid for forming a black photosensitive resin layer formed of the composition K 1 are dried to form a color having a dry film thickness of 2 μm. A photosensitive resin layer 'and a coated sheet of polypropylene (thickness 丄 2! 1111) is formed on the photosensitive resin layer to form an image forming material, a coating liquid for forming a magenta photosensitive resin layer, R5 - 丨1 : in red The composition R1-11 of the coating liquid for forming a photosensitive resin layer was prepared in the same manner except that the surfactant s 1 - 2 of the present invention was changed to the surfactant s 5 and 2 for the invention. The composition of the coating liquid for forming a green photosensitive resin layer G 1 : In the composition R - 1 1 of the coating liquid for forming a red photosensitive resin layer, 5.6 parts of ketone phthalocyanine is used instead of 5.4 parts of ruuka Plow the red BPT. The composition of the coating liquid for forming a blue photosensitive resin layer B 1 : In the composition R5-1 1 of the coating liquid for forming a red photosensitive resin layer, 5.2 parts of Sudan blue is used instead of 5.4 parts of ruuka Plow the red BPT. The composition of the coating liquid for forming a black photosensitive resin layer K 1 : In the composition R5 - 1 1 of the coating liquid for forming a red photosensitive resin layer, 10 parts of carbon black is used instead of 5.4 parts of ruuka Crimson BPT. -77- 1259813 Further, the above coating liquids for forming a photosensitive resin layer were prepared by the same method as in Example 1 -5. The properties of each of the above coating liquids of R 5 - 1 1 , g 1 , B 1 or K 1 were evaluated in the same manner as above, and the results are shown in Table 5-5. A color filter was produced in the same manner as in Example 1 - 15 using the above image forming material. As a result, the adhesion between the glass substrate and the photosensitive resin layer was good. Comparative Example 5 - 4 In the compositions R 5 - 1 1 , G 1 , Β 1 and Κ 1 of the respective Examples 5 - 15, the coating liquid r 5 _ 丨 2 without the surfactant of the present invention was added. G 2, Β 2 and Κ 2 ' A color filter was produced in the same manner as in Example 5 - 15. As a result, a coating spot is produced. Further, the properties of the coating liquids R5 - 12, G2, Β2 and Κ2 were evaluated in the same manner as described above, as shown in Table 5-5. Table 5-5

塗覆液之種類 塗覆液性能 塗覆面狀 表面之凹凸 縮邊 針孔 R5-11 〇 〇 〇 〇 G1 〇 〇 〇 〇 Β1 〇 〇 〇 〇 Κ1 〇 〇 〇 〇 R5-12 X X X X G2 X X X X Β2 X X X X Κ2 X X X X 上述藉由使用本發明用界面活性劑（5 )，可提供沒有塗覆 斑、塗覆面狀平滑、層厚均勻且沒有色斑、不會有縮邊或 -78- 1259813 隹十？L情形、玻璃基板之密接性優異的塗覆液及載負 ^ <影 像形成材料。 本發明可提供一種至少沒有塗覆斑、塗覆面狀平滑且£ ί离基板黏合性優異的塗覆液及載負該液之影像形成材料， 以及可提供一種具有層厚均勻、沒有色斑、不會發泡且、消 泡性優異、不會有縮邊或針孔等特性之塗覆液及載負它之 影像形成材料。 (五）圖式簡單說明 第1圖係爲說明影像形 RH . / $材料之層構造例之截面圖。 付號說明· 1 載體 2 鹼可溶之熱塑性樹聘層 3 阻氧層 4 感光性樹脂層Type of coating liquid Coating liquid property Coating surface of the surface of the concave and convex pinhole R5-11 〇〇〇〇G1 〇〇〇〇Β1 〇〇〇〇Κ1 〇〇〇〇R5-12 XXXX G2 XXXX Β2 XXXX Κ2 XXXX By using the surfactant (5) of the present invention as described above, it is possible to provide no coating spots, smooth coating surface, uniform layer thickness, no color unevenness, no shrinkage, or -78- 1259813 隹10? In the case of L, the coating liquid having excellent adhesion to the glass substrate and the negative-loading <image forming material. The present invention can provide a coating liquid which is at least free from coating spots, has a smooth coating surface and is excellent in adhesion to a substrate, and an image forming material which carries the liquid, and can provide a layer thickness uniform and no color unevenness, A coating liquid that does not foam and has excellent defoaming properties, and which does not have characteristics such as shrinkage or pinholes, and an image forming material that carries it. (5) Brief description of the drawings Fig. 1 is a cross-sectional view showing an example of the structure of the image shape RH / / material. Description of the payment number 1 Carrier 2 Alkali soluble thermoplastic tree layer 3 Oxygen barrier layer 4 Photosensitive resin layer

、了9、9,

Claims (1)

1259813 拾、申請專利範圍 1 . 一種影像形成材料，其係爲在載體上至少依序設置有鹼 可丨容熱ί可塑性樹脂層及感光性樹脂層所成的塗覆層所成 的/影像形成材料，其特徵爲熱可塑性樹脂層及感光性樹 月曰層中至 >一方含有通式U)、通式（b)及通式（C)所示單 體之共聚物（丨）， 通式（a ) : H2C=(p—C〇〇（CH2)irR「(CH2)丨CmF2m+11259813 Pickup, Patent Application No. 1. An image forming material which is formed by image formation of a coating layer formed by at least an alkali-curable thermoplastic resin layer and a photosensitive resin layer on a carrier. a material characterized by comprising a copolymer of a monomer of the formula U), a formula (b) and a formula (C) in a thermoplastic resin layer and a photosensitive dendrimer layer. Formula (a) : H2C=(p—C〇〇(CH2)irR“(CH2)丨CmF2m+1 R〇2 通式（b ) : H2C=C R〇3 R2~(~Si〇4j~R3 --- 7 H2C=C I COOR06 (其中’ 〜RQ6各表示獨立的氫原子或碳數1〜5之R〇2 General formula (b): H2C=C R〇3 R2~(~Si〇4j~R3 --- 7 H2C=C I COOR06 (wherein each of '~RQ6 represents an independent hydrogen atom or a carbon number of 1 to 5 院基’ L表示單鍵或至少含有一種氧原子、氮原子及硫 原子之連接基，&表示單鍵或至少含有一種碳原子、氧 原子、氮原子及硫原子之連接基，R3表示氫原子、碳數 1〜5之丨元基’η表示1〜1〇之整數，m表示2〜14之整 數，丨表示0〜10之整數，P表示1〜100之整數）。 2 · —種影像形成材料，其係爲在載體上至少依序設置有鹼 可溶熱可塑性樹脂層及感光性樹脂層所成的塗覆層所成 的影像形成材料，其特徵爲熱可塑性樹脂層及感光性樹 脂層中至少—方含有通式（a)、通式（b)、通式（c)及通式 -80- 1259813 物 聚 共 之 體 單 示 所 式 通 h2c= (c 0( 〇c _01 C—R m F2 m 1C H2)(c T J— R 式 通 RIC—RII 2C H Q? 031004 RISIR 通式（C ) : R〇5 h2c=c COOR〇q R〇7 通式（d ) : H2C=C H2C-：(p—C〇〇(CH2：^-R广(CH^CmF^y 1259813 通式（C ) : r〇5 h2c~c I COOR〇6 通式（e ) : H2c=c I COOCsH2s+1 (Φ 0通式（a )及通式（c )係與申請專利範圍第1項 R己載^同我’ 表示氫原子或碳數1〜5之院基，s表 示6〜20之整數）。 ^種影像形成材料，其係爲在載體上至少依序設置有鹼 可溶熱可塑性樹脂層及感光性樹脂層所成的塗覆層所成 的影像形成材料，其特徵爲熱塑性樹脂層及感光性樹脂 層中至少一方含有通式（a)、通式（c)及通式（f)所示單體 之共聚物（4 )， 通式 U ) : Η2〇=(ρ—C〇0(CH2)irRf(CH2：hCmF2m+1 通式（c ): 05 R H2C=C I C〇〇R 06The hospital base 'L represents a single bond or a linking group containing at least one oxygen atom, a nitrogen atom and a sulfur atom, & represents a single bond or a linking group containing at least one carbon atom, oxygen atom, nitrogen atom and sulfur atom, and R3 represents hydrogen. The atomic number, the carbon number of 1 to 5, 'n represents an integer of 1 to 1 ,, m represents an integer of 2 to 14, 丨 represents an integer of 0 to 10, and P represents an integer of 1 to 100). 2. An image forming material which is an image forming material formed by coating a coating layer formed by at least an alkali-soluble thermoplastic resin layer and a photosensitive resin layer on a carrier, and is characterized by a thermoplastic resin. At least one of the layer and the photosensitive resin layer contains the general formula (a), the general formula (b), the general formula (c), and the general formula -80 to 1259813. ( 〇c _01 C—R m F2 m 1C H2)(c TJ— R type RIC—RII 2C HQ? 031004 RISIR general formula (C ) : R〇5 h2c=c COOR〇q R〇7 general formula (d ) : H2C=C H2C-:(p—C〇〇(CH2:^-R widely (CH^CmF^y 1259813 Formula (C): r〇5 h2c~c I COOR〇6 General formula (e): H2c=c I COOCsH2s+1 (Φ 0 Formula (a) and Formula (c) are related to the scope of the patent application. Item 1 R has the same as I. It represents a hydrogen atom or a carbon number of 1 to 5, s An integer forming material of 6 to 20) is an image forming material which is an image forming material formed by coating a coating layer formed by at least an alkali-soluble thermoplastic resin layer and a photosensitive resin layer on a carrier. Characterized by thermoplastic At least one of the resin layer and the photosensitive resin layer contains a copolymer (4) of a monomer represented by the general formula (a), the general formula (c) and the general formula (f), and the general formula U): Η2〇=(ρ- C〇0(CH2)irRf(CH2:hCmF2m+1 General formula (c ): 05 R H2C=CIC〇〇R 06 通式（f ): (其中，通式（a )及通式（c )係與申請專利範圍第1項記 載者同義，RQ1Q〜Rqi3各表示獨立的氫原子或碳數1〜5 之烷基，R2表示單鍵或至少含有一種氧原子、氮原子及 硫原子之連接基）。 -82- 1259813 5 . —種影像形成材料，其係爲在載體上至少依序設置有鹼 可溶熱可塑性樹脂層及感光性樹脂層所成的塗覆層所成 的影像形成材料，其特徵爲熱塑性樹脂層及感光性樹脂 層中至少一方含有通式（a )及通式（d )所示單體之共聚物 (5 )， fFormula (f): (wherein, the formula (a) and the formula (c) are synonymous with those described in the first paragraph of the patent application, and RQ1Q to Rqi3 each represent an independent hydrogen atom or an alkyl group having 1 to 5 carbon atoms. R2 represents a single bond or a linking group containing at least one oxygen atom, nitrogen atom and sulfur atom). -82- 1259813 5 . An image forming material which is an image forming material formed by coating a coating layer formed by at least an alkali-soluble thermoplastic resin layer and a photosensitive resin layer on a carrier. a copolymer (5) containing a monomer represented by the general formula (a) and the general formula (d) in at least one of a thermoplastic resin layer and a photosensitive resin layer, f 通式（a ) : H2C=? — (CHACmF^y R〇1 通式（d ) : P7General formula (a) : H2C=? — (CHACmF^y R〇1 general formula (d) : P7 h2c=c I COO(CrH2r〇)q~'R〇Q (其中，通式（a )及通式（d )係與申請專利範圍第2項記 載者同義）。 6 .如申請專利範圍第1至5項中任一項之影像形成材料， 其中於塗覆層內至少感光性樹脂層爲藉由旋轉塗覆設置 者。H2c = c I COO(CrH2r〇)q~'R〇Q (wherein, the general formulae (a) and (d) are synonymous with the second item of the patent application scope). The image forming material according to any one of claims 1 to 5, wherein at least the photosensitive resin layer is provided by spin coating in the coating layer. 83-83-
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