TWI253939B - Cleanser composition - Google Patents
Cleanser composition Download PDFInfo
- Publication number
- TWI253939B TWI253939B TW092126802A TW92126802A TWI253939B TW I253939 B TWI253939 B TW I253939B TW 092126802 A TW092126802 A TW 092126802A TW 92126802 A TW92126802 A TW 92126802A TW I253939 B TWI253939 B TW I253939B
- Authority
- TW
- Taiwan
- Prior art keywords
- surfactant
- detergent composition
- acid
- composition
- group
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 10
- -1 alkyl ether sulfates Chemical class 0.000 claims description 64
- 239000003599 detergent Substances 0.000 claims description 31
- 239000004094 surface-active agent Substances 0.000 claims description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 22
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 18
- 239000000194 fatty acid Substances 0.000 claims description 18
- 229930195729 fatty acid Natural products 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 11
- 150000004665 fatty acids Chemical class 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 7
- QIGCFPDRVPZWCY-UHFFFAOYSA-N 2-(tridecylazaniumyl)acetate Chemical compound CCCCCCCCCCCCCNCC(O)=O QIGCFPDRVPZWCY-UHFFFAOYSA-N 0.000 claims description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims description 4
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 claims description 3
- 239000003093 cationic surfactant Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- RSPCKAHMRANGJZ-UHFFFAOYSA-N thiohydroxylamine Chemical compound SN RSPCKAHMRANGJZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 claims 1
- 125000002467 phosphate group Chemical class [H]OP(=O)(O[H])O[*] 0.000 claims 1
- 229940104261 taurate Drugs 0.000 claims 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 abstract description 20
- 239000008213 purified water Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 23
- 229910052799 carbon Inorganic materials 0.000 description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 18
- 239000013589 supplement Substances 0.000 description 15
- 125000000217 alkyl group Chemical group 0.000 description 14
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 125000002947 alkylene group Chemical group 0.000 description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 235000001014 amino acid Nutrition 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000003240 coconut oil Substances 0.000 description 6
- 235000019864 coconut oil Nutrition 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- 239000002324 mouth wash Substances 0.000 description 6
- 229940051866 mouthwash Drugs 0.000 description 6
- 239000004475 Arginine Substances 0.000 description 5
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 5
- 229960003237 betaine Drugs 0.000 description 5
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 238000007429 general method Methods 0.000 description 5
- 239000006210 lotion Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 235000016068 Berberis vulgaris Nutrition 0.000 description 4
- 241000335053 Beta vulgaris Species 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 4
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 4
- 239000004472 Lysine Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- 235000010356 sorbitol Nutrition 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 3
- 244000147568 Laurus nobilis Species 0.000 description 3
- 235000017858 Laurus nobilis Nutrition 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 230000001815 facial effect Effects 0.000 description 3
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 3
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 3
- 239000001630 malic acid Substances 0.000 description 3
- 235000011090 malic acid Nutrition 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 239000011550 stock solution Substances 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 2
- UUWJHAWPCRFDHZ-UHFFFAOYSA-N 1-dodecoxydodecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC UUWJHAWPCRFDHZ-UHFFFAOYSA-N 0.000 description 2
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 244000014047 Polianthes tuberosa Species 0.000 description 2
- 235000016067 Polianthes tuberosa Nutrition 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- GWTCIAGIKURVBJ-UHFFFAOYSA-L dipotassium;dodecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCOP([O-])([O-])=O GWTCIAGIKURVBJ-UHFFFAOYSA-L 0.000 description 2
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- RGXWDWUGBIJHDO-UHFFFAOYSA-N ethyl decanoate Chemical compound CCCCCCCCCC(=O)OCC RGXWDWUGBIJHDO-UHFFFAOYSA-N 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 229930182470 glycoside Natural products 0.000 description 2
- 229960004949 glycyrrhizic acid Drugs 0.000 description 2
- 235000019410 glycyrrhizin Nutrition 0.000 description 2
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 230000035807 sensation Effects 0.000 description 2
- 235000019615 sensations Nutrition 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 229940079781 sodium cocoyl glutamate Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical group 0.000 description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- PHIQHXFUZVPYII-ZCFIWIBFSA-O (R)-carnitinium Chemical compound C[N+](C)(C)C[C@H](O)CC(O)=O PHIQHXFUZVPYII-ZCFIWIBFSA-O 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- GODZNYBQGNSJJN-UHFFFAOYSA-N 1-aminoethane-1,2-diol Chemical compound NC(O)CO GODZNYBQGNSJJN-UHFFFAOYSA-N 0.000 description 1
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- KPOYDLLPVNBIGV-UHFFFAOYSA-N 1-phenyl-3-(2,3,4-trichlorophenyl)urea Chemical compound ClC1=C(Cl)C(Cl)=CC=C1NC(=O)NC1=CC=CC=C1 KPOYDLLPVNBIGV-UHFFFAOYSA-N 0.000 description 1
- VULQAGPYFSUFCA-UHFFFAOYSA-N 16-methylheptadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CC(C)CCCCCCCCCCCCCCC(O)=O VULQAGPYFSUFCA-UHFFFAOYSA-N 0.000 description 1
- BDOYKFSQFYNPKF-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O BDOYKFSQFYNPKF-UHFFFAOYSA-N 0.000 description 1
- LODHFNUFVRVKTH-ZHACJKMWSA-N 2-hydroxy-n'-[(e)-3-phenylprop-2-enoyl]benzohydrazide Chemical compound OC1=CC=CC=C1C(=O)NNC(=O)\C=C\C1=CC=CC=C1 LODHFNUFVRVKTH-ZHACJKMWSA-N 0.000 description 1
- NCZPCONIKBICGS-UHFFFAOYSA-N 3-(2-ethylhexoxy)propane-1,2-diol Chemical compound CCCCC(CC)COCC(O)CO NCZPCONIKBICGS-UHFFFAOYSA-N 0.000 description 1
- YHCCCMIWRBJYHG-UHFFFAOYSA-N 3-(2-ethylhexoxymethyl)heptane Chemical compound CCCCC(CC)COCC(CC)CCCC YHCCCMIWRBJYHG-UHFFFAOYSA-N 0.000 description 1
- WQPMYSHJKXVTME-UHFFFAOYSA-N 3-hydroxypropane-1-sulfonic acid Chemical compound OCCCS(O)(=O)=O WQPMYSHJKXVTME-UHFFFAOYSA-N 0.000 description 1
- DYYQCJKVIWOCEO-UHFFFAOYSA-N 3-phenylprop-2-enoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.OC(=O)C=CC1=CC=CC=C1 DYYQCJKVIWOCEO-UHFFFAOYSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
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Description
1253939 玖、發明說明： 【發明所屬之技術領域】 本發明係關於一種安定性優異，且用於皮膚之時，洗淨 後的肌膚可保濕潤、沒有緊繃感或乾澀感，且於用於毛髮 時，洗髮時的指間觸感滑順、沒有硬澀感的洗淨劑組成物。 【先前技術】 過去，用於皮膚與毛髮的洗淨劑組成物中，由於具有高 起泡性的特徵，而廣泛地使用高級脂肪酸鹽、烷基硫酸酯 鹽、烷基苯磺酸鹽、α -伸烷磺酸鹽等陰離子界面活性劑。 此等界面活性劑之洗淨力強，洗淨後雖可得到清爽的感 覺，但皮膚有緊繃感為其問題。另一方面，作為所謂之低 刺激性的界面活性劑，曾被提議者有：磺酸基琥珀酸鹽系 界面活性劑、醚羧酸鹽系界面活性劑、醯胺基醚羧酸鹽系 界面活性劑、Ν -烧基醯胺基烧醇硫酸酯鹽等，但，此等界 面活性劑在單獨使用時，於起泡性與泡質等方面並非十分 理想。 因此，作為有良好的起泡性且使用感優異的洗淨劑組成 物，使用（A / )陰離子界面活性劑與（Β ')三甲基甘胺酸，並 以（A ' ) / ( B ’）= 1 0 0 / 1〜4 / 1的比例組合之皮膚洗淨劑組成物 曾被提出（日本專利特開平1 1 - 1 8 0 8 5 5號公報）。然而，此 組成物雖於起泡性與泡質方面有改善，但仍有洗淨後殘存 有肌膚的緊繃感與毛髮之硬澀感存在之問題，故未臻理想。 又，三曱基甘胺酸若調配到化妝材料中，可減低對皮膚 的刺激性（W 0 9 1 / 1 8 5 8 8 )，而含有三曱基甘胺酸與脂肪族有 312/發明說明書(補件)/92_ 12/921268〇2 1253939 機酸的毛髮調整用組成物（W Ο 8 2 / Ο 2 3 3 7 )、含有三甲基甘胺 酸與珍珠化劑的珍珠狀液體洗淨劑組成物（日本專利特開 平7 - 2 5 8 6 9 9號公報）亦為眾所周知者。 本發明之目的在於提供一種安定性優異，且用於皮膚之 時，洗淨後的肌膚可保濕潤、沒有緊繃感或乾澀感，且於 用於毛髮時，洗髮時的指間觸感滑順、沒有硬澀感的洗淨 劑組成物。 【發明内容】 本發明者等發現，藉由將陰離子界面活性劑與三曱基甘 胺酸以特定的比例使用，同時調整為弱酸性，可解決上述 的問題。 本發明為含有（A )陰離子界面活性劑及（B )三曱基甘胺酸 之洗淨劑組成物，其特徵在於，成分（A )及（B )的重量比為 (Α)/(Β) = 1/ 3.5以上、未滿4/1，且該組成物本身的pH或 以純水稀釋成使用濃度時的 pH值係調整為 2以上、未滿 6.5° 【實施方式】 作為本發明中所用的成分（A )之陰離子界面活性劑，只要 是使用於通常洗淨劑中且可將組成物的 pH調整於前述的 範圍内者皆可，並無特別限制。可舉出例如：（1 )烷基醚硫 酸鹽、（2 )烯屬烴基醚硫酸鹽、（3 )醚羧酸鹽型界面活性劑、 (4 )醯胺基醚羧酸鹽型界面活性劑、（5 )磷酸酯鹽型界面活 性劑、（6 ) N -醯基胺基酸鹽型界面活性劑、（7 )聚氧化烯脂 肪酸醯胺醚硫酸鹽、（8 )醯化羥乙磺酸鹽、（9 )醯化牛磺酸 6 312/發明說明書(補件)/92-12/92126802 1253939 酯、（1 Ο ) N -烷基醯胺基烷醇硫酸酯鹽等作為較佳者。 更具體而言，作為（1 )烷基醚硫酸鹽或（2 )烯屬烴基醚硫 酸鹽，可舉出例如：具有平均碳數1 0〜2 0的直鏈或分枝鏈 的烷基或烯屬烴基，並於1分子内加成有平均0 . 5〜8莫耳 的環氧烷類者。此處，作為環氧烷類，可單獨使用或適當 地組合使用環氧乙烷、環氧丙烷及環氧丁烷。 作為（3 )醚羧酸鹽型界面活性劑或（4 )醯胺基醚羧酸鹽型 界面活性劑，可舉出例如以下述通式（1 )所表示者。 R1-(0C3H6)a-(0C2H4)b-0CH2-C00A (1) [式中，R1為直鏈或分枝鏈的碳數 8〜2 2的烷基或烯屬烴 基，烷（C、8〜C22)苯基或R2C0NH-CH2-CH2-基（R2為碳數11〜21 的直鏈或分枝鏈的烧基或烤屬烴基），a為0〜6的數，b為 2〜2 4的數，A為鹼金屬、驗土金屬、單乙醇胺、二乙醇胺、 三乙醇胺等之烷醇胺鹽殘基] 作為（5 )麟酸酯鹽型界面活性劑，可舉出碳數8〜3 6的烧 基或烯屬烴基或具有其等之環氧烷類加成基之磷酸單酯或 雙酯鹽型界面活性劑，可舉出例如以下述通式（2 )所表示 者。 〇 R3—(〇CH2CH2)ir 〇 —P—OX1 ( 2 ) OX2 [式中，R3為烴基，X1為氫原子、驗金屬、錢、驗性胺基 酸鹽或烷醇胺鹽，X2為氫原子、鹼金屬、銨、鹼性胺基酸 鹽、烷醇胺鹽或R 3 - ( 0 C Η 2 C Η 2 ) m -的基，m為0〜5的數] 7 312/發明說明書(補件)/92-12/92126802 1253939 式中，作為以 R1表示之烴基，可舉出碳數 或分枝鏈的烷基或烯屬烴基，尤以碳數8〜2 0的 鏈的烷基為佳。具體而言，可舉出辛基、壬基 一烧基、十二烧基、十四烧基、十五院基、十 八烧基、二十烧基等。 又，X1及X2中，作為驗金屬為例如裡、鈉、 鹼性胺基酸為精胺酸、離胺酸、組胺酸等；作 具有碳數2〜3的羥烷基者為佳，可舉出例如三 乙醇胺、單乙醇胺等。 又，m表示0〜5的數，尤以0〜2為特佳。 作為如此的磷酸酯鹽型界面活性劑，尤以磷 磷酸肉豆蔻酯、磷酸棕櫚酯或2 -己基磷酸的精 鹽或三乙醇胺鹽為佳。 作為（6 ) N -醯基胺基酸鹽型界面活性劑， 8〜24的醯基者為佳，具體而言，可舉出N -醯基 鹽、N -醯基肉胺酸鹽、N -醯基麩胺酸鹽等，尤 基-/3 -丙胺酸精胺酸、N -月桂醯基-々-丙胺酸 醯基-/3 -丙胺酸三乙醇胺、椰油基麩胺酸鈉、 -N -羧甲基- /?-丙胺酸鈉為佳。 作為（7 )聚氧化烯脂肪酸醯胺醚硫酸鹽，可舉 述通式（3)所表示者。 〇 R4
5 II I / ο X R —c—y—ch2ch2o—(ch2cho)厂so3m1 ^ ό ^ 8〜3 6的直鏈 直鏈或分枝 、癸基、十 六烧基、十 鉀等；作為 為烷醇胺以 乙醇胺、二 酸月桂酯、 •胺酸酯、鉀 以具有碳數 - /3 -丙胺酸 以Ν -月桂醯 钟、Ν -月桂 Ν -月桂醯基 出例如以下 1 12/發明說明書(補件)/92-12/921268〇2 1253939 [R4為氫原子或甲基，R5為碳數7〜23的直鏈或分枝鏈 基或烯屬烴基，R6為碳數 8〜24的直鏈或分枝鏈的烧 稀屬烴基，η為0〜20的數，M1為硫酸殘基的對離子] 作為（8 )醯化羥乙磺酸鹽，可舉出例如具有碳數8〜 直鏈或分枝鏈的飽和或不飽和之脂肪酸殘基的醯化羥 酸鹽。 作為（9 )醯化牛磺酸酯，可舉出例如具有碳數8〜2 4 鏈或分枝鏈的飽和或不飽和之脂肪酸殘基的醯化牛 酉旨。 作為（1 0 ) Ν -烷基醯胺基烷醇硫酸酯鹽，可舉出例如 述通式（4)所表示者。 r7x fi .N—C—R90—(R10O)d—S03M2 ( 4 ) (式中，R7為碳數 6〜22的直鏈或分枝鏈的烷基或烯 基，R8為碳數 1〜22的烷基、烯屬烴基或氫原子，R9 數1〜5的直鏈或分枝鏈的伸烷基，1^°0為碳數2〜3的 烷基，d為0〜20的任意的數，d個R1()0可為相同，亦 不同。M2為氫原子、鹼金屬、鹼土金屬、銨、總碳數 的烷醇銨，總碳數 1〜2 2的烷基銨或脂烯銨、以碳數 的烷基或烯屬烴基取代的吼啶鹽，或鹼性胺基酸。） 作為此等陰離子界面活性劑的陰離子性殘基的對離 可舉出：鈉、鉀等之鹼金屬離子；鈣、鎂等之鹼土金 子；精胺酸、離胺酸、組胺酸等之鹼性胺基酸；銨離 312/發明說明書(補件)/92-12/92126802 的烧 基或 24的 乙磺 的直 續酸 以下 屬烴 為碳 環氧 可為 2〜9 卜1 8 子， 屬離 子； 9 1253939 具有碳數2或3的烷醇基之烷醇胺（例如，單乙醇胺、二 醇胺、三乙醇胺、三異丙醇胺等。） 又，此等以外的界面活性劑，於組成物可維持於弱酸 的範圍内亦可併用。例如於高級脂肪酸鹽的情況，以平 碳數1 0〜2 4的飽和或不飽和之脂肪酸鹽為佳，而於其對 子的選擇必須注意。於鈉、鉀等之鹼金屬鹽的情況，由 其脂肪酸鹽呈現弱鹼性，故於本發明之組成物中無法多 地使用。另一方面，於離胺酸、精胺酸、組胺酸等之鹼 胺基酸鹽的情況，因該脂肪酸鹽的調配可抑制組成物之 性化，故可在較佳的pH區域中做配方設計。因而，於併 高級脂肪酸鹽的情況，以使用鹼性胺基酸鹽為佳。 成分（A )之陰離子界面活性劑，可使用1種以上，而就 泡性與洗淨後的清爽感考量，以在總組成中含有 0 . 1〜 重量％為佳，尤以0 . 3〜3 0重量％為特佳。 成分（B)之三甲基甘胺酸為亦稱作甘胺酸甜菜 (glycine betaine)的分子内鹽化合物，作為市售品有阿 諾扣特（旭化成公司）等。於本發明中，就洗淨後的使用 考量，其宜於總組成中含有0.1〜40重量％，尤以含有0.5〜 重量％為佳。 於本發明中，成分（A)及（B)的重量比為（A)/(B) =1/3 以上、未滿4 / 1，而以1 / 3以上、未滿4 /1為更佳。此 例若未滿 1 / 3 . 5，安定性差，且洗淨後之肌膚有黏腻感 於4 / 1以上則無法充分抑制洗淨後之乾澀感與毛髮之硬 感。 312/發明說明書(補件)/92-12/921268〇2 乙 性 均 離 於 量 性 驗 用 起 4 0 驗 米 感 30 .5 比 澀 10 1253939 又，本發明之洗淨劑組成物，該組成物本身纟 水稀釋為使用濃度時的pH係調整為2以上、；^ 以4〜6. 4為佳。於p Η未滿2時，安定性差， 以上時，洗淨後的肌膚之乾澀感與毛髮之硬澀 抑制。組成物的ρ Η，可用有機酸或無機酸，經 法調整於上述範圍中。作為有機酸，可舉出例 琥珀酸、乳酸、蘋果酸、麩胺酸、天門冬胺酸 羧酸、酒石酸、乙醇酸、抗壞血酸等。又，作 可舉出鹽酸、硫酸、磷酸等，尤以磷酸為佳。 又，本發明中之pH，有關漱口劑等以原液使 接測定；有關手或身體、臉、毛髮等之洗淨劑 稀釋而使用者，係將組成物以純水稀釋成使用 液一般而言為5重量％水溶液，於2 5 °C下，以 又，於如後述般的片材含浸型的製品之情況， 浸液作為原液測定，或以純水稀釋（通常為5重 涓|J定。 本發明之洗淨劑組成物中，亦可含有前述之 性劑，亦即，兩性界面活性劑、陽離子界面活 子界面活性劑。 作為兩性界面活性劑，可舉出例如脂肪酸醢 鹼、羥丙基磺酸甜菜鹼、經脫鹽處理之 2 (imidazolinium)甜菜驗等。 作為陽離子界面活性劑，可舉出例如碳數1 單烷基4級銨鹽、具有碳數2 0〜2 8的分枝烷基 312/發明說明書(補件)/92-12所1268〇2 4 pH或以純 ^滿6 . 5，又 於ρ Η為6 . 5 感無法充分 由一般的方 如檸檬酸、 、σ比洛烧 為無機酸， 用者，係直 之類的以水 濃度之水溶 pH計測定。 亦同樣以含 量％水溶液） 外的界面活 性劑、非離 胺丙基甜菜 ! 級_ σ坐鹽 2〜1 6的直鏈 之4級錄鹽 11 1253939 等。 作為非離子界面活性劑，可舉出胺氧化物類、單甘油酯 類、山梨糖醇酐脂肪酸酯類、烷基糖類、聚氧化烯烷基醚、 高級脂肪酸烷醇醯胺等。具體而言，較佳者可例示如：月 桂基二甲胺氧化物、肉豆蔻基二甲胺氧化物、異硬脂酸單 甘油S旨、油酸單甘油酯、辛烧酸單甘油S旨、山梨糖醇酐單 辛酸酯、山梨糖醇酐單月桂酸酯、山梨糖醇酐單油酸酯、 山梨糖醇酐倍半油酸酯、山梨糖醇酐單異硬脂酸酯、山梨 糖醇酐三油酸酯、椰子油脂肪酸單乙醇醯胺等。 此等兩性界面活性劑、陽離子界面活性劑、非離子界面 活性劑可使用1種以上，在總組成中含有合計為0 . 0 0 1〜3 0 重量％，尤以0 . 0 1〜2 0重量％為佳。 於本發明之洗淨劑組成物中，可進一步含有一般洗淨劑 組成物中所用的成分。具體而言有：羊毛脂及其衍生物、 肉豆蔻酸異丙酯等之酯類，椰子油、橄欖油等之油脂類等 的油性成分；聚甘油脂肪酸酯等之保濕劑；二氯苯氧氣酚 (t r i c 1 〇 s a η )、 三氯二苯脲等之殺菌劑；甘草酸 (glycyrrhizinic acid)if、醋酸生育S分等消炎劑；對羥基 苯甲酸曱酯、對羥基苯甲酸乙酯、對羥基苯甲酸丙酯、對 羥基苯曱酸丁酯等之防腐劑；乙二胺四乙酸或其鹽、羥基 乙烷二膦酸或其鹽等之螯合劑；羧基乙烯聚合物、鹿角菜 膠（c a r r a g e e n a η )、經乙基纖維素、陽離子化纖維素等之增 黏劑；丙二醇、1，3 - 丁二醇、甘油、山梨糖醇、麥芽醇 (maltitol)等之多醇類；氯化鈉等之鹽類；其他之珍珠化 12 312/發明說明書(補件)/92-12/92126802 1253939 劑、磨砂（s c r u b )劑、香料、色素、紫外線吸收劑、氧化防 止劑、植物萃取物等。 本發明之洗淨劑組成物，可使用通常的方法經由將前述 成分混合來製造。例如，作為液體劑型，可作成為洗面乳、 卸妝乳、沐浴乳、洗手乳等之皮膚洗淨劑組成物；或洗髮 精等之毛髮洗淨劑組成物；漱口水等之口腔内洗淨劑組成 物。又，可將織布、不織布、紙等的片狀基材含浸於液體 劑型的洗淨劑組成物，並視需要加以乾燥，作成含浸型之 洗淨用製品’例如’片狀洗面材料、片狀卸妝材料專。 實施例 (實施例1 ) 以一般的方法製造表1所示之組成的洗淨劑組成物，並 針對肌膚洗淨後之肌膚的無緊繃感、濕潤感、無乾澀感及 無黏腻感的程度，及於毛髮洗淨後之毛髮指間觸感及柔軟 性、以及安定性進行評價。將結果一併示於表1。 又，於實施例中，組成物的pH係將各組成物以純水稀釋 成5重量％之水溶液，對其使用Η 0 R I B A p Η計F - 2 2 (堀場製 作所公司製），於2 5 °C下進行測定。 (評價方法） (1 )將肌膚洗淨後的肌膚之無緊繃感、濕潤感、無乾澀感 及無黏腻感的程度： 由2 0〜3 0餘歲的日本人女性1 0名所組成之測試小組，使 各洗淨劑組成物1 g起泡後，對臉部整體做6 0秒鐘的按摩， 其後用水沖洗，以毛巾吸乾後，就肌膚無緊繃感的程度、 13 312/發明說明書(補件)/92-12/92126802 1253939
I < 比較品 CD CD LO LO LO LO 適量 適量 餘量 LO LO 3/11 〇 〇 〇 X < 〇 X LO LO CO LO 適量 適量 餘量 LO LTD 1 1 \ LO < < < < < <1 〇 寸 ◦ L〇 寸 適量 適量 餘量 ① CD 15/4 < < X 〇 < X <1 CO CD LO LTD LO 適量 適量 餘量 〇〇 卜· 〇〇 < 〇 < 〇 <1 X <3 οα LO LO ◦ 適量 適量 餘量 οα 卜· CO \ < <1 < 〇 〇 <1 <1 Τ < CNI LO οα 適量 適量 餘量 〇〇 CO 12/5 <1 < X 〇 〇 < <1 本發明品 CO Ο LO CD LO 適量 適量 餘量 LO LO Cvl 〇 〇 〇 〇 〇 〇 〇 LO LO 〇> LO 適量 適量 餘量 LO LO CNI \ CQ 〇 〇 〇 〇 〇 〇 〇 呀 CO LO 適量 適量 餘量 寸 CO 15/4 〇 〇 〇 〇 〇 〇 〇 CO 〇> LO LO LO 適量 適量 餘量 ◦ CO CO CNI 〇 〇 〇 〇 〇 〇 〇 οα L〇 LO cr> 適量 適量 餘量 LO LO r-H 〇 〇 〇 〇 〇 〇 〇 τ—Η <NI LTD οα 適量 適量 餘量 ◦ LO 12/5 〇 〇 〇 〇 〇 〇 〇 成分（重量％) 烷基（Cll，13, 15)磷酸鉀 月桂基磷酸鉀 聚氧乙烯（2)月桂基醚硫酸鈉 鵷 π << 2 V 嗲 CNI (XI 硪朱 t W N-月桂醯基N-羧甲基-)S -丙胺酸鈉 三曱基甘胺酸 甘油單-2-乙基己基醚 /^Ν 誠 << m ，丨丨Η 03 Ο •rH s CD β 〇 ^ § ^ ^ 〇 · i-H t ^ 月桂酸醯胺丙基甜菜鹼 檸檬酸 氫氧化鉀液 純水 pH (5重量％) (A)/(B)重量比 洗淨後肌膚的無緊繃感的程度 洗淨後肌膚的濕潤感 洗淨後肌膚的無乾澀感之程度 洗淨後肌膚的不黏腻感 洗淨後毛髮的指間觸感 洗淨後毛髮的柔軟性 安定性 DQ ς i —91 -ζ:6/(ΦΜ)_κ_Η^/πε 1253939 (實施例2 )洗面材料 以一般的方法製得以下所示之組成的洗面材料。 (成分）烷基（C 1 1，1 3，1 5 )磷酸鉀 1 5 (重量％ ) 三甲基甘胺酸 20 甘油單-2 -乙基己基醚 5 聚氧乙烯（9)十三烷基醚 5 椰油醯胺丙基甜菜鹼 5 椰子油脂肪酸二乙醇醯胺 1 羧基乙稀基聚合物 0.5 聚乙二醇（ALKOX E-1 00，明成化學工業公司製） 0. 5 甘油 10 丙二醇 磷酸 氧化鈦 對羥基苯甲酸甲酯 香料 二丁基羥基曱苯 10 適量0.01 適量 純水 餘量 (p Η ( 5 重量 °/◦水溶液）=5 · 5，（ A ) / ( B ) = 3 / 4 ) (貫施例3 )洗面材料 以一般的方法製得以下所示之組成的洗面材料。 (成分） 312/發明說明書(補件)/92-12/92126802 16 1253939 聚氧乙烯（2 )月桂基醚磷酸鈉 1 0 (重量％ ) 椰油基麩胺酸鈉 5 (阿米索夫特CS-11，味之素· Taraka公司製） 三甲基甘胺酸 5 月桂醯基羥基磺酸甜菜鹼 5 經乙基纖維素 0.5 陽離子型聚合物 0.5 (瑪扣特550，Matsumoto交商公司製） 二硬脂酸乙二醇酯 3 山梨糖醇 10 異戊二醇 10 乳酸納 1 鈦雲母 0.01 (Timiron Starluster MP-115，Merck · Japan 公司製） 苯曱酸鈉 0.2 聚乙稀珠（polyethylene beads) 0.8 1 -薄荷腦 0.05 香料 適量 滑石 3 伸乙二胺四乙酸二鈉 0.1 純水 餘量 (p Η ( 5 重量 ％ 水溶液）=5 . 0，（ A ) Λ B ) = 3 / 1 ) (實施例4 ) 沐浴乳 以一般的方法製得以下所示之組成的沐浴乳。 312/發明說明書(補件)/92-12/92126802 17 1253939 (成分） %) 聚氧乙烯（2)月桂基醚磷酸鈉 20(重量 三甲基甘胺酸 10 烷基聚葡萄糖苷（AG- 1 0LK，花王公司製）5 聚氧乙烯（16)月桂基醚 2 月桂醯基羥基磺酸甜菜鹼 5 精胺酸 0.5 羥丙基甲基纖維素 0.5 兩性聚合物 0.5 (瑪扣特普拉斯3300，Matsumoto交商公司製） 山梨糠醇 10 二丙二醇 10 蘋果酸 適量 1 -薄荷腦 0.1 苯曱酸鈉 0.2 香料 適$ 二硬脂酸乙二醇酯 3 1-羥基乙烷-1,1-二膦酸 0.1 (迪奎斯特2010CS，三菱孟山都公司製） 色料（藍色1號） 0.0 0 0 2 純水 餘量 (pH(5 重量 ％水溶液）= 6. 4，（A)MB) = 2/1 ) (實施例5 )洗髮精 以一般的方法製得以下所示之組成的洗髮精。 18 312/發明說明書(補件)/92-12/92126802 1253939 (成分 聚氧乙烯（2 )月桂基醚硫酸鈉 15( ί 三甲基甘胺酸 5 椰子油脂肪酸單乙醇醯胺 5 牛磺酸醯胺丙基甜菜鹼 5 2-月桂基-N-羧曱基-N-羥乙基 味σ坐鹽甜菜驗 5 絲胺酸 0. 5 聚醚變性聚矽氧 0. 5 (SILICONE SH-3771E ，東麗· 製） Dowcorning · Si 二曱基聚矽氧烷 0. 5 (SILICONE SH-200C(5000cs)， 製） Dowcorning · Si 丙二醇 10 乙醇 1 無水矽酸 0. 2 對羥基苯甲酸曱酯 0. 2 氯化鄰[2 -羥基-3-（三甲基銨） 丙基]羥乙基纖多 0.1 Hiba arborvitae 萃取物 0. 1 香料 適量 檸檬酸 適量 純水 餘量 312/發明說明書(補件)/92-12/92126802 19 1253939 (ρ Η ( 5 重量 °/◦水溶液）=5 . Ο，（ A )八 B ) = 3 / 1 ) (實施例6 )洗手乳 以一般的方法製得以下所示之組成的洗手乳。 (成分） 月桂基磷酸鉀 5 (重量％ ) 三甲基甘胺酸 2 椰子油脂肪酸二乙醇醯胺 3 聚氧乙稀（4)聚氧丙稀（7) 丁基醚 5 聚氧乙稀（8 0 )硬化蓖麻油 0.5 月桂基二曱基胺氧化物 5 椰油醯胺丙基甜菜驗 5 麥芽醇 0.5 甘油 10 乙醇 1 晚香玉（Polianthes tuberosa)多糖化物 0.5 異丙基甲基酚 0.01 (比歐佐爾，大阪化成公司製） 脫氫醋酸鈉 0.2 香料 適量 純水 餘量 (p Η ( 5 重量 ％ 水溶液）=5 . 5，（ A )以 B ) = 5 / 2 ) (實施例7 )藥用洗手乳 以一般的方法製得以下所示之組成的藥用洗手乳。 (成分） 20 312/發明說明書(補件)/92-12/92126802 1253939 聚氧乙烯（2 )月桂基醚硫酸鈉 1 0 (重量％ ) 三甲基甘胺酸 20 烷基糖苷（A G - 1 0 L K，花王公司製） 10 聚氧乙烯（2 0 )椰子油脂肪酸山梨糖醇酐 1 (RHEODOL TW-L120，花王公司製） 聚氧乙烯（6 0 )硬化蓖麻油 0.5 甘草酸離胺酸二鉀 1 氯化月桂基三甲基銨 10 甘油 10 乙醇 1 香料 適量 色料（黃色1號） 0.0 0 0 1 伸乙二胺四乙酸二鈉 0.1 對羥基苯曱酸曱酯 0.1 號拍酸 適量 純水 餘量 (p Η ( 5 重量 ％ 水溶液）=4 . 5，（ A ) / ( B ) = 1 / 2 ) (實施例8 ) 漱口水 一 般 的 方 法 製 得 以下所示之組成的漱 口水 。 (成分） 肉 豆 謹 酸 精 胺 酸 酯 0 · 5 (重量％ ) 三 甲 基 甘 胺 酸 0.5 乙 醇 5 山 梨 糖 醇 10 312/發明說明書(補件)/92-12/92126802 21 1253939 對羥基苯曱酸曱酯 0.1 聚氧乙烯·曱基聚矽氧烷共聚合物 0.03 (KHF-4，信越化學工業公司製） 苯索氯銨（benzethonium chloride) 0.01 糖精鈉 0.001 香料、調味料 適量 純水 餘量 〇11(原液）=6.0，（八）/(8) = 1/1) (實施例9 )片狀含浸洗面材料 以一般的方法製得以下所示之組成的片狀洗面材料，適 量含浸到不織布中之後，經由在8 0 °C下乾燥1分鐘，製得 片狀乾式擦拭巾。於使用時，以水濡濕使其起泡而使用。 (成分） 聚氧乙烯（2 )月桂基醚硫酸鈉 2 0 (重量％ ) 三曱基甘胺酸 10 椰油醯胺丙基甜菜鹼 10 烷基糖苷（AG-1 0LK，花王公司製） 10 2 10 0.05 適量 聚乙二醇1 500 1，3- 丁二醇 尤加利樹萃取物 對羥基苯曱酸曱酯 伸乙二胺四乙酸二鈉 1 -薄荷腦 蘋果酸 22 312/發明說明書(補件)/92-12/921268〇2 1253939 聚乙二醇4 0 0 餘量 (ρ Η ( 5 重量 ％ 水溶液）=5 · 5，（ A ) / ( B ) = 2 / 1 ) 實施例 2〜9 所得之洗淨劑組成物皆為安定性優 又，實施例2〜4、6、7及9的皮膚洗淨劑組成物， 肌膚後均沒有緊繃感、感覺濕潤、且無乾澀感；實 的毛髮洗淨劑組成物，洗髮後的毛髮之指間觸感順 軟；實施例8的口腔内洗淨劑組成物，於漱口後之 覺滑溜，且有持續的清爽感。 (產業上之可利用性） 本發明之洗淨劑組成物安定性優異，於洗淨肌膚 端感、感覺濕潤、且無乾溫感與黏腻感；於洗淨毛 毛髮的指間觸感順暢且柔軟；於洗淨口腔内時，牙 滑溜且可持續有清爽感。 312/發明說明書(補件)/92-12/92126802 異者。 於洗淨 施例 5 暢且柔 牙齒感 時無緊 髮時， 齒感覺 23
Claims (1)
1253939拾、申請專利範圍： 94. 12. 2 - 94 12, - 2 替換本 1 . 一種洗淨劑組成物，其係含有（A )陰離子界面活性劑 及（B )三曱基甘胺酸，其特徵在於，成分（A )及（B )的重量比 為（A )八B ) = 1 / 3 . 5以上、未滿 4 / 1，且該組成物本身的p Η 或以純水稀釋成使用濃度時的pH值係調整為2以上、未滿 2 .如申請專利範圍第1項之洗淨劑組成物，其中，成分 (A )之陰離子界面活性劑係選自烷基醚硫酸鹽、烯屬烴基醚 硫酸鹽、醚羧酸型鹽界面活性劑、醯胺基醚羧酸鹽型界面 活性劑、磷酸酯鹽型界面活性劑、N -醯基胺基酸鹽型界面 活性劑、聚氧化烯脂肪酸醯胺醚硫酸鹽、醯化羥乙磺酸鹽、 醯化牛磺酸酯及N -烷基醯胺基烷醇硫酸酯鹽。 3 .如申請專利範圍第1或2項之洗淨劑組成物，其中， 含有0 · 1〜4 0重量％之成分（A )。 4.如申請專利範圍第3項之洗淨劑組成物，其中，含有 0 . 1〜4 0重量％之成分（B )。 5 .如申請專利範圍第1項之洗淨劑組成物，其中，更進 一步含有0 . 0 0 1〜3 0重量％之選自兩性界面活性劑、陽離子 界面活性劑及非離子界面活性劑之界面活性劑。 6 .如申請專利範圍第1項之洗淨劑組成物，其為一種皮 膚洗淨劑組成物。 7 .如申請專利範圍第1項之洗淨劑組成物，其為一種洗 面劑。 24 326\總檔\92\92126802\92126802(替換)-2
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| JP2007176864A (ja) * | 2005-12-28 | 2007-07-12 | Kao Corp | 水性液体皮膚洗浄剤 |
| JP2008174502A (ja) * | 2007-01-19 | 2008-07-31 | Kao Corp | 皮膚洗浄剤組成物 |
| JP5022154B2 (ja) * | 2007-09-11 | 2012-09-12 | ライオン株式会社 | 皮膚洗浄剤組成物 |
| US10689280B2 (en) * | 2009-12-31 | 2020-06-23 | Ecolab Usa Inc. | Method for the removing and reducing scaling |
| US8119584B2 (en) * | 2010-07-19 | 2012-02-21 | Rovcal, Inc. | Universal aqueous cleaning solution for electric shavers |
| US20130338227A1 (en) | 2012-06-13 | 2013-12-19 | Marie-Esther Saint Victor | Green Glycine Betaine Derivative Compounds And Compositions Containing Same |
| JP6001401B2 (ja) * | 2012-09-28 | 2016-10-05 | ユニ・チャーム株式会社 | ウェットティッシュ用薬液及びウェットティッシュ |
| CN104768523B (zh) | 2012-10-29 | 2017-08-15 | 宝洁公司 | 10℃下具有0.30或更大损耗角正切值的个人护理组合物 |
| EP2935549B1 (en) * | 2012-12-20 | 2018-09-26 | Unilever Plc. | Method for removing fat and/or oil stains |
| WO2015016037A1 (ja) * | 2013-08-02 | 2015-02-05 | 富士フイルム株式会社 | 液体洗浄剤組成物 |
| JP6206911B2 (ja) * | 2013-09-25 | 2017-10-04 | 株式会社マンダム | 皮膚洗浄用シート化粧料 |
| JP6394358B2 (ja) * | 2014-12-16 | 2018-09-26 | 日油株式会社 | シャンプー組成物 |
| JP2019081730A (ja) * | 2017-10-31 | 2019-05-30 | 阪本薬品工業株式会社 | 泡質改善剤及びそれを含有する皮膚洗浄料組成物 |
| CN108096120A (zh) * | 2018-02-07 | 2018-06-01 | 合肥华盖生物科技有限公司 | 一种护肤型杀菌消毒洗手液及其制备方法 |
| JP7309190B2 (ja) * | 2019-10-31 | 2023-07-18 | 株式会社アリミノ | 毛髪洗浄剤 |
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| DE3101011C2 (de) * | 1981-01-15 | 1985-06-05 | Wella Ag, 6100 Darmstadt | Haarbehandlungsmittel |
| US4554098A (en) * | 1982-02-19 | 1985-11-19 | Colgate-Palmolive Company | Mild liquid detergent compositions |
| WO1991018588A1 (en) * | 1990-06-05 | 1991-12-12 | Cultor Ltd. | A method of reducing the irritating properties of a cosmetic composition |
| US5858340A (en) * | 1992-05-22 | 1999-01-12 | The Procter & Gamble Company | Cosmetic compositions |
| JPH07258019A (ja) * | 1994-03-18 | 1995-10-09 | Ajinomoto Co Inc | 化粧料 |
| JP3405475B2 (ja) * | 1994-03-22 | 2003-05-12 | サンスター株式会社 | パール状液体洗浄剤組成物 |
| JP3525233B2 (ja) * | 1995-09-20 | 2004-05-10 | 味の素株式会社 | 化粧料 |
| DE19547679A1 (de) * | 1995-12-20 | 1997-06-26 | Wella Ag | Haarpflegemulsion |
| JPH11130652A (ja) * | 1997-10-24 | 1999-05-18 | Lion Corp | 皮膚化粧料 |
| JPH11180855A (ja) * | 1997-12-19 | 1999-07-06 | Kao Corp | 皮膚洗浄剤組成物 |
| JP2000038593A (ja) * | 1998-05-19 | 2000-02-08 | Kao Corp | 洗浄剤組成物 |
| US6677294B2 (en) * | 2000-11-29 | 2004-01-13 | The Procter & Gamble Company | Cleansing compositions |
| EP1266600A1 (en) * | 2001-06-13 | 2002-12-18 | The Procter & Gamble Company | Printed wet wipes |
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| EP1577373B1 (en) | 2006-11-29 |
| DE60310132D1 (de) | 2007-01-11 |
| AU2003266611A1 (en) | 2004-07-29 |
| TW200410727A (en) | 2004-07-01 |
| CN1292061C (zh) | 2006-12-27 |
| CN1714142A (zh) | 2005-12-28 |
| DE60310132T2 (de) | 2007-10-04 |
| JP2004217614A (ja) | 2004-08-05 |
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