TW425401B - Hexacoordinated ruthenium compounds - Google Patents

Hexacoordinated ruthenium compounds Download PDF

Info

Publication number
TW425401B
TW425401B TW087103105A TW87103105A TW425401B TW 425401 B TW425401 B TW 425401B TW 087103105 A TW087103105 A TW 087103105A TW 87103105 A TW87103105 A TW 87103105A TW 425401 B TW425401 B TW 425401B
Authority
TW
Taiwan
Prior art keywords
group
tert
butyl
substituted
aryl
Prior art date
Application number
TW087103105A
Other languages
English (en)
Chinese (zh)
Inventor
Der Schaaf Paul Adriaan Van
Andreas Hafner
Andreas Muehlebach
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Application granted granted Critical
Publication of TW425401B publication Critical patent/TW425401B/zh

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/002—Osmium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
TW087103105A 1997-03-06 1998-03-04 Hexacoordinated ruthenium compounds TW425401B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH52797 1997-03-06

Publications (1)

Publication Number Publication Date
TW425401B true TW425401B (en) 2001-03-11

Family

ID=4189054

Family Applications (1)

Application Number Title Priority Date Filing Date
TW087103105A TW425401B (en) 1997-03-06 1998-03-04 Hexacoordinated ruthenium compounds

Country Status (8)

Country Link
US (1) US6077805A (enExample)
EP (1) EP0971941B1 (enExample)
JP (1) JP2001513795A (enExample)
AU (1) AU6399798A (enExample)
CA (1) CA2280268C (enExample)
DE (1) DE69818240T2 (enExample)
TW (1) TW425401B (enExample)
WO (1) WO1998039346A1 (enExample)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6159890A (en) * 1996-04-30 2000-12-12 Bp Amoco Corporation Ruthenium-containing catalyst system for olefin metathesis
US6156692A (en) * 1996-04-30 2000-12-05 Bp Amoco Corporation Ruthenium-containing catalyst composition for olefin metathesis
EP0844263B1 (de) * 1996-11-15 2003-01-15 Ciba SC Holding AG Katalysatorgemisch für die ringöffnende Metathesepolymerisation
US6175047B1 (en) * 1997-12-26 2001-01-16 Takasago International Corporation Ruthenium metathesis catalyst and method for producing olefin reaction product by metathesis reaction using the same
TW495517B (en) * 1998-04-23 2002-07-21 Hitachi Chemical Co Ltd Curable molding material and method for producing molded article
KR100372985B1 (ko) * 1998-05-14 2003-02-25 히다치 가세고교 가부시끼가이샤 수지 조성물 및 이를 사용한 경화물의 제조법
US6696597B2 (en) 1998-09-01 2004-02-24 Tilliechem, Inc. Metathesis syntheses of pheromones or their components
US6900347B2 (en) 1998-09-01 2005-05-31 Tilliechem, Inc. Impurity inhibition in olefin metathesis reactions
US7507854B2 (en) 1998-09-01 2009-03-24 Materia, Inc. Impurity reduction in Olefin metathesis reactions
DE19840107A1 (de) * 1998-09-03 2000-03-09 Bayer Ag Verfahren zur Synthese alpha-substituierter Ringsysteme
WO2000015339A1 (en) 1998-09-10 2000-03-23 University Of New Orleans Foundation Catalyst complex with carbene ligand
US6888018B2 (en) 2000-08-31 2005-05-03 Sekisui Chemical Co., Ltd. Organometallic compound having high metathesis activity and method for preparation thereof, methathesis reaction catalyst comprising the compound, method of polymerization using the catalyst, and polymer produced by the method of polymerization
US6759537B2 (en) * 2001-03-23 2004-07-06 California Institute Of Technology Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
CN1911942B (zh) * 2001-08-01 2010-06-23 加州理工学院 六配位钌或锇金属卡宾易位催化剂
CN1265882C (zh) * 2001-08-01 2006-07-26 加州理工学院 六配位钌或锇金属卡宾易位催化剂
US6818586B2 (en) * 2001-08-01 2004-11-16 Cymetech, Llp Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
JP4643091B2 (ja) * 2001-08-24 2011-03-02 カリフォルニア インスティテュート オブ テクノロジー ６配位ルテニウムまたはオスミウム金属カルベンメタセシス触媒
WO2003027079A1 (en) * 2001-09-20 2003-04-03 Zeon Corporation Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymers of cycloolefins and hydrogenation products thereof by using the complexes as catalyst
WO2003093351A1 (en) 2002-05-06 2003-11-13 Kerr Corporation Composition curable by metathesis reaction
US7683148B2 (en) 2003-05-06 2010-03-23 Kerr Corporation Metathesis-curable composition with a reaction control agent
US7060770B2 (en) 2003-05-06 2006-06-13 Kerr Corporation Metathesis-curable composition with a reaction control agent
US7173097B2 (en) 2003-05-06 2007-02-06 Kerr Corporation Metathesis-curable composition with a reaction control agent
US7060769B2 (en) 2003-05-06 2006-06-13 Kerr Corporation Method of curing composition by metathesis reaction using reaction control agent
WO2005094345A2 (en) 2004-03-29 2005-10-13 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand
WO2006045070A2 (en) * 2004-10-20 2006-04-27 University Of Massachusetts Peg-substituted pyridine ligands and related water-soluble catalysts
US7960555B2 (en) * 2004-10-20 2011-06-14 University Of Massachusetts Substituted pyridine ligands and related water-soluble catalysts
US7625551B2 (en) 2004-11-15 2009-12-01 Kerr Corporation Polyether-based dental impression material curable by metathesis reaction
US7001590B1 (en) 2004-11-15 2006-02-21 Kerr Corporation Metathesis-curable composition
US7645443B2 (en) 2004-11-15 2010-01-12 Kerr Corporation Polyether-based composition curable by metathesis reaction
EP1847245A1 (en) 2006-02-21 2007-10-24 Kerr Corporation Method for making alkoxy-siloxane polyether carboxylates terminated with functional olefin groups
FR2900153B1 (fr) 2006-04-21 2008-07-18 Rhodia Recherches & Tech Procede de condensation de motifs silyles a l'aide d'un catalyseur de type carbene
US8241575B2 (en) 2008-01-28 2012-08-14 The Johns Hopkins University Molecularly imprinted polymer sensor device
US9499643B2 (en) 2010-01-08 2016-11-22 Bluestar Silicones France Sas Method for preparing carbene in solution, novel stable form of carbene obtained in particular by means of said method, and uses thereof in catalysis
EP3063592B1 (en) 2013-10-30 2021-04-07 California Institute of Technology Direct photopatterning of robust and diverse materials
MX2018003639A (es) * 2015-09-24 2019-04-25 Umicore Ag & Co Kg Catalizadores metálicos de metátesis olefínica de carbeno.

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198511A (en) * 1991-12-20 1993-03-30 Minnesota Mining And Manufacturing Company Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor
EP0773948A4 (en) * 1992-04-03 1998-09-02 California Inst Of Techn HIGHLY ACTIVE RUTHENIUM OR OSMIUM METAL CARBEN COMPLEXES FOR OLEFIN METHETHESE REACTIONS AND THEIR SYNTHESIS
US5710298A (en) * 1992-04-03 1998-01-20 California Institute Of Technology Method of preparing ruthenium and osmium carbene complexes
US5312940A (en) * 1992-04-03 1994-05-17 California Institute Of Technology Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
US5599962A (en) * 1995-01-31 1997-02-04 E. I. Du Pont De Nemours And Company Process for the preparation of ruthenium hydrogenation catalysts and products thereof
US5554778A (en) * 1995-01-31 1996-09-10 E. I. Du Pont De Nemours And Company Ruthenium hydrogenation catalysts
US5811515A (en) * 1995-06-12 1998-09-22 California Institute Of Technology Synthesis of conformationally restricted amino acids, peptides, and peptidomimetics by catalytic ring closing metathesis
US5831108A (en) * 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
US5939504A (en) * 1995-12-07 1999-08-17 Advanced Polymer Technologies Method for extending the pot life of an olefin metathesis polymerization reaction
US5780701A (en) * 1996-07-26 1998-07-14 The Regents Of The University Of California Process for alkane group dehydrogenation with organometallic catalyst
JP3445074B2 (ja) * 1996-09-20 2003-09-08 高砂香料工業株式会社 ルテニウム−ホスフィン錯体の製造方法
DE59708768D1 (de) * 1996-11-01 2003-01-02 Ciba Sc Holding Ag Verfahren zur Herstellung von Katalysatoren
US5917071A (en) * 1996-11-15 1999-06-29 California Institute Of Technology Synthesis of ruthenium or osmium metathesis catalysts
US5977393A (en) * 1997-11-21 1999-11-02 California Institute Of Technology Schiff base derivatives of ruthenium and osmium olefin metathesis catalysts

Also Published As

Publication number Publication date
DE69818240T2 (de) 2004-07-01
AU6399798A (en) 1998-09-22
US6077805A (en) 2000-06-20
EP0971941A1 (en) 2000-01-19
JP2001513795A (ja) 2001-09-04
DE69818240D1 (de) 2003-10-23
CA2280268C (en) 2007-11-20
WO1998039346A1 (en) 1998-09-11
EP0971941B1 (en) 2003-09-17
CA2280268A1 (en) 1998-09-11

Similar Documents

Publication Publication Date Title
TW425401B (en) Hexacoordinated ruthenium compounds
TW308602B (enExample)
TW438850B (en) Stabilization of polyolefin composition in permanent contact with extracting media
TW449610B (en) Hydroxyphenyltriazines
TW477803B (en) Stabilization of phenol-free polyolefin fibres
TW467932B (en) Benzotriazole UV absorbers having enhanced durability
TW522150B (en) Triazine compounds and stabilizing compositions and methods utilizing the same
TW308601B (enExample)
TW513476B (en) Stabilized adhesive compositions containing highly soluble high extinction, photostable hydroxyphenyl-s-triazine UV absorbers
TW452575B (en) New Α-aminoacetophenone photoinitiators and photopolymerizable compositions comprising these photoinitiators
TW440564B (en) Polyoxyalkylene substituted and bridged triazine, benzotriazole and benzophenone derivatives
BR9810341B1 (pt) catalisadores de carbeno de rutênio e composição compreendendo os mesmos.
TW466255B (en) Photoactivatable nitrogen-contained bases on Α-amino alkenes
TW406127B (en) Novel liquid phenolic antioxidants
KR20010014234A (ko) 루테늄 및 오스뮴 촉매
JPH10509453A (ja) 架橋可能なモノマーおよび組成物、および架橋されたポリマー
TW200530313A (en) Flame retardant compositions
KR20020072795A (ko) 하나 이상의 알콕시 에테르 기가 올리고머 잔기에 부착된화합물 및 그를 포함하는 조성물
JP4197578B2 (ja) ルテニウム及びオスミウム触媒を含有するヘテロシクリルリガンド
TW467931B (en) Stabilizer mixtures
US3563959A (en) Process for the production of transparent polyamides which are resistant to boiling
JP2002509960A (ja) ルテニウムおよびオスミウムカルベンカルボニル触媒
TW464670B (en) Stabilizer mixtures containing a hindered amine
TW391972B (en) Cycloolefin
TW409132B (en) Composition comprising polysilanes

Legal Events

Date Code Title Description
GD4A Issue of patent certificate for granted invention patent
MM4A Annulment or lapse of patent due to non-payment of fees