TW406148B - Crosslinkable fabric care compositions - Google Patents
Crosslinkable fabric care compositions Download PDFInfo
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- TW406148B TW406148B TW087115225A TW87115225A TW406148B TW 406148 B TW406148 B TW 406148B TW 087115225 A TW087115225 A TW 087115225A TW 87115225 A TW87115225 A TW 87115225A TW 406148 B TW406148 B TW 406148B
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
經濟部中央標準局貝工消費合作社印製 406148五、發明説明(1 ) 本發明有關使用各種包含多官能聚合物及聚(羥基) 交聯劑之可交聯組合物於織物之處理,以賦予暫時之抗皺 性及防汚性〇 含有各種添加物之澱粉及澱粉溶液已然用作家庭及商 業洗衣店織物調理應用方面之熨燙助劑超過60年之久。雖 然數十年來澱粉顯示乃作爲熨燙助劑之良好產品,其仍有 許多可將性能改進之領域。舉例言之,澱粉傾向於積留在 熨斗及衣裳上〇此外,澱粉不賦予長期之抗皺性,且澱粉 溶液可能傾向於阻塞噴嘴〇另一供改進之領域涉及澱粉殘 留物,其有時以片狀形式留在衣裳上,而在暗色織物上尤 其明顯〇本發明之組合物提供此等改進〇 '本發明有關各種織物處理組合物,含有一包含至少二 個由羧基、酐及胺組成集團中所選出官能基團之多官能分 子組合水液及一聚(羥基)交聯劑〇該織物處理組合物可 施加於衣裳及織物,然後熨燙,而在後績之洗滌週期內對 織物賦予暫時之抗皺性、防汚性及改善之防再沉積特性〇 此外,組合物不積留於衣裳或熨斗上,且無殘留片,縱於 暗色織物上亦然〇本發明亦針對各種處理織物之方法,包 含對織物施加一有效對其賦予暫時抗皺性及防汚性之織物 處理組合物量,及熨燙該織物以使聚(羥基)交聯劑與該 多官能分子交聯〇 本發明之織物處理組合物包含一種多官能分子(PFM) 〇如本文中所用,“分子〃包括非聚合分子、低分子量聚 合物或寡聚物(例如分子量約小於10,000)、及較高分子 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁) 406148 at B7 經濟部中央標準局員工消費合作社印装 五、發明説明(2 ) 量聚合物(例如分子量約大於10,000至大於1,000,000 ) 〇該分子之實際分子量對於本發明交聯劑之使用而言並非 限制性之因素〇 PFM必須含有至少二個由羧基、酐及胺組成集團中所 選出之官能基團〇可用於本發明之例示性分子包括而不限 於檸檬酸、I,2,4-苯三羧酸、1,2,4,5-苯四羧酸、1,2,3, 丁烷四羧酸、聚(丙烯酸)、羧酸官能化聚酯、羧酸官 能化聚胺基甲酸乙酯、聚乙烯亞胺、聚(乙烯胺一共一乙 烯醇)、聚(乙烯胺)、及由單體譬如乙烯(E)、乙酸乙 烯酯(VA)、(甲)丙烯酸(M)AA 、(甲)丙烯酸之匕-匕 烷酯、順丁烯二酸酑(MAnh)、順丁烯二酸、分解烏頭酸( IA)、巴豆酸(CA)、厶羧基乙基丙烯酸酯(BCEA)、丁二稀 及苯乙烯(STY)製備之聚合物〇 (甲)丙烯酸在本文中用 以指示丙烯酸及甲丙烯酸二者以及其等之酯類〇例示性共 聚物包括乙烯/乙酸乙烯酯/丙烯酸共聚物、乙酸乙烯酯 /丙烯酸共聚物、丙烯酸/順丁烯二酸酐共聚物、乙酸乙 烯酯/丙烯酸/順丁烯二酸酐共聚物、乙烯/丙烯酸共聚 物、乙烯/甲丙烯酸共聚物、乙烯/乙酸乙烯酯/丙烯酸 /順丁烯二酸酐共聚物、乙酸乙烯酯/順丁烯二酸酐共聚 物、乙烯/乙酸乙烯酯/順丁烯二酸酑共聚物、甲丙烯酸 甲酯/丙烯酸丁酯/丙烯酸共聚物、甲丙烯酸甲酯/丙稀 酸乙酯/丙烯酸共聚物、甲丙烯酸甲酯/丙烯酸丁酯/分 解烏頭酸共聚物、丙烯酸丁酯/丙烯酸共聚物、丙烯酸丁 酯/BCEA共聚物、丙烯酸乙酯/丙烯酸共聚物、2-乙基己 ----:---„----装-- (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS > A4規格(210X297公釐) —5— 經濟部中央樣準局員工消費合作杜印製 406148 a? ____B7五、發明説明(3 ) 基丙烯酸酯/丙烯酸共聚物、甲丙烯酸甲酯/(甲)丙稀 酸乙酯/分解烏頭酸共聚物、苯乙烯/(甲)丙烯酸共聚 物、苯乙烯/順丁烯二酸酐共聚物、苯乙稀</(甲)丙稀 酸/順丁烯二酸酐共聚物、苯乙烯/分解烏頭酸共聚物、 及苯乙烯/ 丁二烯共聚物〇此外,包含酐基團之聚合物可 於製備聚(丙烯酸)期間原位產生〇此等實例非屬限制性 ,而且本發明之(羥基烷基)尿素交聯劑可用以實際上與 任何包含至少二個由羧基、酐及胺組成集團中所選出之官 能基團之分子交聯〇(羥基烷基)尿素交聯劑極具多方面 用途,且可輕易用以與水液聚合物、有機溶液聚合物、聚 合物熔融液、乳液聚合物、聚合物之水性及非水性分散液 、以及粉末交聯〇 本發明之織物處理組合物亦包含含有至少二個羥基團 之聚(羥基)交聯劑,亦即多元醇。多元醇之實例包括乙 二醇、甘油、季戊四醇、花楸醇、澱粉及澱粉衍生物、二 乙醇胺、三乙醇胺、々羥基烷基醯胺譬如雙[Ν,Ν-二(/3經 基乙基)]己二醯二胺、聚乙烯醇以及尿素衍生物。 本發明之最佳聚(羥基)交聯劑爲衍生自尿素,僅包 含單一尿素基圑、至少二羥基圑、至少二個置於尿素基團 與每一羥基團間之碳原子,且可能包括以結構式(I )代表 之化合物〇該二置於羥基與尿素基團間之碳原子可能爲線 性、有支鏈或經取代之構形〇此等尿素衍生物可爲二甲基 醇二羥基乙基尿素(DMDHEU)、乙二醇化及甲基化DMDHEU、 羥基烷基尿素譬如Ν,Ν-雙(2-羥基乙基)尿素。最佳爲經 本紙張尺度適用中國國家標準(CNS > Α4规格(210X297公釐) -6- 1' ia^i ^ilf |>|^ ta^n >n m n_n ϋ^Ί— (請先閲讀背面之注意事項再填寫本頁) 406148 g 五、發明説明(Ο 基烷基尿素(HAU)譬如Ν,Ν-雙(2-羥基乙基)尿素。 R6 經濟部中央標準局員工消費合作社印裝 R6 R2 爲 Η 或 R6,R3 爲 氫或R6 9 而 R4爲氣、 R1 或以 9 其 中 R8 R9 R8 1 R9 R1 0 11 院 R6 爲 Η CH2 0Η CHCH0H CHCHCH0H或 -C 4 基 9 R8 R9 J | R8 R9 R" R6 爲 Η ch2 OH 、 CHCH0H Λ 1 1 1 CHCHCH0H或 -〇4 基 9 而 R8 R9 R8 Η9 R1 0 R7 爲 Η ch2 OH | | CHCH0H I 1 1 CHCHCH0H或 Cl —C 4 基 9 其中 R8 爲 Η 甲基或 乙 基,R9 爲 Η 、甲基或 乙 基, 而 R1 0 爲Η 甲 基 或 乙基〇 例 示 之ΗΑϋ 交 聯劑包 括 _而 不限於Ν , .雙(: 2- 羥 基 乙基 ) 尿 素 四(2- 羥 基乙基 ) 尿 素、三(2 - 羥基 :乙 基 ) 尿素 Ν, Ν, - 雙(2- 羥 基乙基 ) 尿 素、N,r 雙(: 3- 羥 基 :乙基 ) 尿 素 Ν,Ν'- 雙 (4-羥 基 ;乙 基)尿素 Λ 及2. -尿 素 -i 乙 基 -1 ,3 - 丙二醇 〇 &交聯 用 丨試 劑"與* ».i :* 父 聯齊 等 詞 Ϊ在本 文 中 可 互 換使用 〇 本 發 明施用 對 象之服 裝 衣裳及織 物 均儀 丨成 品 9 亦即 已 然 製 成 之服裝 或衣裳, 或已 製成且出 售 供製作衣 裳 丨一類 本紙張尺度適用中國固家標隼(CNS ) Α4规格(210 X297公釐) -7 — I ; I I 装 I I- I 訂 (請先聞讀背面之注意事項再.填寫本頁) 經濟部中央標準局員工消費合作社印裝 406148五、發明説明(5) 之織物0本發明不施用於染整程序中或者紡織原料或織物 製造程序中之紡織原料。以本發明之組合物處理織物獲得 表現良好手感之織物。此外,已用本發明組合物處理並熨 燙之衣裳傾向於較以習用織物處理組合物所處理者保留折 皺之時間爲久0此抗皺性爲暫時性,因爲膜在洗衣機內溶 解〇以本發明之組合物處理織物亦使織物表現出優於習用 織物處理組合物之改善防汚性。舉例言之,加之於以本發 明組合物所處理織物之汚點傾向固定;亦即與加之於以習 用組合物所處理織物之汚點相較,整個織物無顯著之汚點 移動〇此外,與加於以習用織物處理組合物所處理織物之 汚點相較,加於該織物之汚點易以習用洗滌工作去除ο此 外,該聚合物在後績洗滌中亦作用如抗沉積劑〇因此,此 一系統可供出租洗衣店或清洗伙食及餐飮機構用亞麻布製 品之公司使用〇出人意表,本發明之水處理組合物可在洗 滌中對其所處理之織物提供暫時防皺及防汚性與抗沉積性 之組合特性0 本發明織物處理組合物包含PFM與聚(羥基)交聯劑 組合之水溶液,其相對量爲PFM內所含官能基團之等似物 總合數對聚(羥基)交聯劑內所含羥基團之等似物數量之 比例範圍約1:1至100 :1 〇PFM內所含官能基團之等似物 總合數對聚(羥基)交聯劑內所含羥基團之等似物數量之 比例範圍較佳爲約5 : 4至1 0 : 1 〇 在本發明之一具體形式中,織物處理組合物可以細霧 之形式塗敷於織物作爲熨燙助劑,例如藉泵或霧劑噴灑, 本紙張尺度適用中國國家標準(CNS〉A4規格(210X297公釐) ~ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印装 406148 a?五、發明説明(6) 然後施加熱及壓力並隨意用蒸氣變烫織物0本文中所用織 物包括服裝、衣裳及其他本文中所述之成品〇該塗敷或變 燙工作可在商用洗衣店操作中執行,或可在家務操作中執 行,譬如用熨斗,不論有無蒸氣〇熨斗之熱導致PFM之交 聯因聚(羥基)交聯劑而發生於織物之表面上〇有一看不 到之薄膜留下,對織物提供暫時之防皺及防汚性〇雖然無 意受以下所約束,一般相信交聯劑亦可能傾向將纖維素纖 維本身內之黏合體交聯〇 在譬如上述之應用中,織物處理組合物必需不含有高 位準之PFM與交聯劑組合〇—般認爲高位準之PFM與交聯 劑組合在20重量%之譜及更高。熨烫助劑之黏滯度必須充 份低,以便該熨燙助劑經由泵或霧劑噴灑塗敷。若固質含 量變太高,黏滯度可能過高而可能遭育噴灑塗敷問題〇因 此,熨烫助劑包含總共約0.1至10重量%之上述相對比例 之PFM與交聯劑組合,以熨燙助劑成份之總重爲準。 將織物處理組合物塗敷於織物之一替代方法爲將該組 合物引進洗衣機之清洗循環內。雖然在上述噴灑塗敷中必 需使用較低位準之織物處理組合物,但黏滯度及噴灑並非 清洗循環應用中之關鍵。因此,若有需要,可使用較高濃 度之織物處理組合物,雖然獲致本發明之利益應無必要以 約大於10重量%之濃度塗敷該組合物。然後,殘餘量之織 物處理組合物以於熨烫時對服裝有效提供暫時防皺性及防 汚之量沉積於已洗滌之服裝上〇然後可直接熨燙已處理之 服裝,或者於熨燙前予以乾燥。乾燥工作將過量之水移離 本紙張尺度適用中國國家標準{ CNS )八4规格(210X297公嫠) ---^---_----装------—訂 1 (請先閱讀背面之注意事項再€寫本页) 406148 b; 經濟部中央標準局貝工消費合作社印装 五、發明説明 (7) 1 1 1 服裝而 留下 PFM 及 交 聯 劑 ,然 後 熨 燙 而 產 生 上 述 之 所需 特 1 性0 請 1 1 _. 般已 知將水 溶 性 澱 粉用 於 商 用 洗 衣店 〇 澱 粉係於 洗 先 閲 滌作業 結束 前引 進 槽或 甕 內〇 然後將過 量 之水排 出 而沉 積 讀 背 面 | 於織物 上之 殘餘 澱 粉在 熨 燙時對 服 裝 提供所 需 之 硬挺度 〇 之 注 杳 1 此一應 用中 之水 溶 性 澱 粉可置 換以 本 發 明 之 織 物 處 理組合 事 項 1 1 物〇殘 餘量 之PFM 及 交 聯 劑在 水 清 除 後 再 次 沉 積 於 織物 上 填 寫 本 1 Ά C若有 需要 ,額 外 之 織 物 處理 組 合 物 可 在 洗 滌 後 以 噴霧 熨 頁 1 1 燙助劑 形式 塗敷 9 狄 後 熨 燙0 1 1 —► 較佳 之織 物 處 理 組 合物 包 含 聚 ( 丙 烯 酸 ) 與 二羥 基 1 | 乙基尿 素混 合物 之 水 溶 液 〇該 織 物 處 理 組 合 物 塗 敷 於織 物 訂 之方法 爲噴 灑此 混 合 物 之 4重 量 % 溶 液 ( 以 該 溶 液 之總 重 1 爲準) 於織 物上 f 狄 後 熨 燙織 物 0 熨 斗 之 熱 導 致 聚 合物 交 1 1 聯入一 幾乎 看不 見 之 薄 膜 內, 縱 令於 里 色 織 物 上 亦然〇 1 I 實例: \ 1 \ 實例1 :主 觀之 防 皺 性 將 一包含182 克 水 、 16 .7克 A1 C 0 sp e r s e 602N 聚( 丙 1 I 烯酸) (田 納西 州 Ch at t ano og a 市 A1 CO 化 學 公 司 ) (45 % 1 活性) 及1 . 〇克 二 羥 基 乙 基尿 素 ( 85 % 活性) 之 熨 燙助 劑 1 1 組合物拌合 30分 鐘 9 直 到 形成 溶 液 爲 止 〇 此 爲 織 物 處理 組 1 合物之 4 % 溶液 0 1 I 由 -組 使用 者 於 實 際 之日 常 條 件 中 測 試 實 例 1 之配 方 1 1 1 0將該 溶液 噴灑 於 織 物 上 ,狹 *\\\ 後 穿 著 該 衣 裳 達 *— 整 天〇 表 1 1 1列出 該組使用 者 對 受 試 組合 物 防 皺 性之 觀 察 結果 〇 1 1 1 尺 张 紙 本 通 準 標 冢 rr.» 公- 7 9 2 406148 A7 B7五、發明説明(8 ) 表 1 測試人員編號 被熨燙之服裝 防皺性 1 白色洋裝襯衫 是 2 亞麻套裝 是 3 棉及人造絲褲 是 4 黑色棉褲 經濟部中央樣準局員工消費合作社印策 如數據所示,實例1之織物處理組合物對其所處理之 織物提供優異之防皺性〇 實例2 :測量硬挺度之試驗 進行第191A號聯邦測試方法標準以測量經該織物處理 組合物所處理小塊樣布之硬挺度〇該試樣之硬挺度與交聯 劑之有效性成正比0試驗係由以該織物處理組合物處理10 吋XI吋之長方形小塊棉樣布〇然後用二塊黏接用膠帶將 該小塊樣布附接於一水平桿上,以使該小塊樣布下懸成環 形。於是,於1分鐘後測量該桿頂部至成環形小塊樣布底 部之距離〇此距離與該小塊樣布之硬挺度成反比〇 測量一系列經Alcosperse 602A聚(丙嫌酸)(田納 西州Chattanooga市Alco化學公司)及多種交聯劑處理之 小塊樣布之硬挺度,並報導於表2中〇 表 2 交聯劑 1分鐘後所測與 熨燙難易 _ 提_之距離(臺来) 度之評語 無聚合物或交聯劑 11.3 本紙張尺度適用中國國家棣準(CNS ) A4规格(210X297公釐) -11- I ^ ! 裝 - 訂^~ (請先閲讀背面之注意事項<^$寫本頁) 406148 A7 _B7五、發明説明(9 ) 聚合物單項 10.0 容易平順 羥基乙基尿素 9.0 容易 DMDHEU 9.0 困難 乙二醇化DMDHEU 9.65 容易 Filmkote 54 9.7 極困難 —羥基乙基尿素 10.0 容易 三乙醇胺 9.7 容易 (請先閲讀背面之注意事項再填寫本頁} 經濟部中失標準局貞工消費合作社印製 所有織物處理組合物均以Alcosperse 602A聚(丙烯 酸)之4重量%水溶液,而交聯劑以聚(丙烯酸)之重量 爲準之利用位準爲12重量% 〇 Fi lmkote 54係一種可得自 紐澤西州Bridgewater市National搬粉及化學公司之水溶 性澱粉,可用作交聯劑〇 —羥基乙基尿素在本發明中非有 效之交聯劑。出人意表,聚(丙烯酸)之三乙胺鹽爲良好 之交聯劑〇此等系統可藉酸譬如硫酸尿素予以催化0 實例3 :防汚性 評估多種商用織物處理組合物以及實例1織物處理組 合物之防汚性〇對小塊樣布上之2吋直徑圓施加橡樹葉沒 食子皮脂污點,然後於75eC烘箱內將該小塊樣布烘焙5日 〇移離烘箱時,目視各小塊樣布以注意汚點在小塊樣布上 之任何橫向移動〇然後在特戈清潔力計內用〇.9克/升之 商用Pur ex粉末清潔劑洗滌各小塊樣布,並再次觀察各小 塊樣布之沾汚情形〇 本紙張尺度適用t國國家標準(CNS ) A4規格(210X297公釐) -12- A7 __daaus____ 五、發明説明(10) 表 3 熨烫助劑 烘焙後及洗滌 洗滌後之汚 洗滌後之汚 前之汚點目視 點目視評等 點目視說明 _ 說明 (1 =最佳) _ 實例1織物 處理組合物 汚點不擴散於 整個小塊樣布 1 潔白外觀 Ni agara 源 汚點擴散於整 2 黃色皮脂 粉噴劑 個小塊樣布 汚點 無疵點澱粉 汚點擴散於整 個小塊樣布 4 黃色皮脂 汚點 織物整理劑 汚點擴散於整 個小塊樣布 3 黃色皮脂 汚點 經濟部中央標準局貝工消費合作社印褽 表3中之資料指示實例1之織物處理組合物優於習用 織物處理組合物之原因爲其不僅防止汚點擴散於整個小塊 樣布,且亦使汚點在傳統洗滌時可移除;因此,其傾向於 防汚。以實例1組合物處理之白色小塊樣布在特戈清潔力 計內洗滌之後完全潔白。反之,汚點擴散於以商用物質所 處理比較用小塊樣布整個之上,且所有比較用小塊樣布表 現特徵之黃色汚點,縱令於洗滌之後亦然〇 實例4 本紙張尺度適用中國國家標準(CNS )八4規格(210X297公釐) -13 - __ 406148 m_;_ 五、發明説明(11) 使用比例爲2 : 1之橄欖油:Bandy黑色黏土重複實例 3之此等試驗0 表 4 τ ^ 装 .~ 訂 {請先閱讀背面之注$項再填寫本頁) 經濟部中央標準局貝工消費合作社印装 粉 (1) A L =洗滌前及洗滌後沾汚小塊樣布之反射比差,係由 Minolta CM 525色度計測量〇 實例1之織物處理組合物提供優異之防汚性且不呈顯 任何再沉積問題。此外,其縱使在黑色織物上亦不顯示任 何目視沉積物oNiagara澱粉及織物整理劑之表現較本發 明組合物爲劣,並顯現大量之再沉積。此外,織物整理劑 溶液難以於較高之濃度噴灑,且傾向於織物上形成黏性之 殘餘物〇 熨燙助劑 目視評等 (1 =最佳) 預熨燙小塊 樣布之平均 Λ T山 Δ L 黑色織物 上之可見 沉積 再沉積 實例1織物 處理組合物 1 20.5 川、 無 織物整理劑 2 13.1 有 大量 N i a g a r a 澱 3 0.7 有 大量 本紙張尺度適用中國國家標準(CNS )八4規格(210X297公釐) -14 —
Claims (1)
- 公 (88 2土· _ 正) 406148 Λ8 Β8 C8 D8 六、申請專利範圍 Γ~ 1 1.一種織物處理組合物,包含: (請先閱讀背面之注意事項再填寫本頁) 由0.1至10重量% (以該織物處理組合物之總重爲 準)之以下之組合: —多官能分子,包含至少二個由羧基、酑及胺 組成集團中所選出官能基團;與 !—聚(羥基)交聯劑,其中多官能分子內所含 官能基團之等似物總合數對聚(羥基)交聯劑內所含羥.基 團之等似物數量之比例範圍爲1:1至100:1 ;以及 水, 其中該多官能分子及聚(羥基)交聯劑均溶於水中。 2 .如申請專利範圍第1項之組合物,其中多官能分子 內所含官能基團之等似物總合數對聚(羥基)交#劑內所 含羥基團之等似物總數之比例範圍爲5:4至10:1。 經濟部智慧財產局員工消費合作社印製 3 .如申請專利範圍第1項之組合物,其中所述交聯劑 係由Ν,Ν-雙(2_羥基乙基)尿素、四(2-羥基乙基)尿素 、三(2-羥基乙基)尿素、Ν,Ν’-雙(2-羥基乙基)尿素 、Ν,Ν’-雙(3_羥基乙基)尿素、Ν,Ν1-雙(4-羥基乙基 )尿素、及2-尿素-2-乙基-1,3-丙二醇所組成集團中選本紙張尺度適用t國國家標準(CNS)A4规格(210 X 297公沒)
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GB2084597B (en) * | 1980-09-24 | 1984-09-19 | Sandoz Ltd | Quaternary polyalkylene polyamine n-methylol resin reaction products and dye after-treatments |
CH672388B5 (zh) * | 1981-05-16 | 1990-05-31 | Sandoz Ag | |
EP0109214B1 (en) * | 1982-11-16 | 1986-06-25 | Dow Corning Limited | Organosiloxane polymers and treatment of fibres therewith |
DE3723349C1 (de) * | 1987-07-15 | 1988-08-11 | Goldschmidt Ag Th | Mittel zum Ausruesten von Fasern oder Faserprodukten |
CH678679B5 (zh) * | 1987-09-05 | 1992-04-30 | Sandoz Ag | |
KR910004341B1 (ko) * | 1988-03-26 | 1991-06-26 | 주식회사 코오롱 | 폴리에테르에스테르수지용 마스터뱃치 |
JPH02252923A (ja) * | 1989-03-24 | 1990-10-11 | Mazda Motor Corp | ロータリピストンエンジン |
US4978708A (en) * | 1989-04-25 | 1990-12-18 | Basf Corporation | Aqueous-based coating compositions comprising anionic polyurethane principal resin and anionic acrylic grind resin |
-
1997
- 1997-09-16 US US08/933,623 patent/US5879749A/en not_active Expired - Lifetime
-
1998
- 1998-08-18 EP EP98115528A patent/EP0908552A3/en not_active Withdrawn
- 1998-08-24 SG SG1998003276A patent/SG72857A1/en unknown
- 1998-08-27 AU AU81890/98A patent/AU751297B2/en not_active Ceased
- 1998-09-11 TW TW087115225A patent/TW406148B/zh not_active IP Right Cessation
- 1998-09-11 ID IDP981224A patent/ID20858A/id unknown
- 1998-09-15 MY MYPI98004203A patent/MY114601A/en unknown
- 1998-09-15 KR KR1019980037939A patent/KR100544215B1/ko not_active IP Right Cessation
- 1998-09-15 CA CA002247576A patent/CA2247576A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
MY114601A (en) | 2002-11-30 |
AU8189098A (en) | 1999-04-01 |
KR19990029799A (ko) | 1999-04-26 |
SG72857A1 (en) | 2000-05-23 |
EP0908552A3 (en) | 2000-05-17 |
US5879749A (en) | 1999-03-09 |
ID20858A (id) | 1999-03-18 |
CA2247576A1 (en) | 1999-03-16 |
EP0908552A2 (en) | 1999-04-14 |
KR100544215B1 (ko) | 2006-09-22 |
AU751297B2 (en) | 2002-08-08 |
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GD4A | Issue of patent certificate for granted invention patent | ||
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