TW381069B - Fertilizer absorbency enhancing composition and fertilizer composition - Google Patents
Fertilizer absorbency enhancing composition and fertilizer composition Download PDFInfo
- Publication number
- TW381069B TW381069B TW086111309A TW86111309A TW381069B TW 381069 B TW381069 B TW 381069B TW 086111309 A TW086111309 A TW 086111309A TW 86111309 A TW86111309 A TW 86111309A TW 381069 B TW381069 B TW 381069B
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- Prior art keywords
- acid
- salt
- fertilizer
- surfactant
- weight
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- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 230000002708 enhancing effect Effects 0.000 title abstract 3
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- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 claims description 30
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 230000003248 secreting effect Effects 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- CBXWGGFGZDVPNV-UHFFFAOYSA-N so4-so4 Chemical compound OS(O)(=O)=O.OS(O)(=O)=O CBXWGGFGZDVPNV-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000021012 strawberries Nutrition 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000008400 supply water Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000005580 triphenylene group Chemical group 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/70—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting wettability, e.g. drying agents
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S71/00—Chemistry: fertilizers
- Y10S71/903—Soil conditioner
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
發明説明( 一本發明係關於肥料吸收促進劑及肥料組k物 經濟部中央標準局貞工消費合作社印裝 ,更詳而 言之,係關於-種以防止由植物之營養素缺乏症所引起之 生理障礙為目的’而施肥或散布於植物的根 實而使用之肥料中所添加之肥料吸收促進劑植物成長時必須有各種的營養成份,若........^ ’會造成植物生育H例如,肥料三大要素,氮為蛋 白質之成分7L素,碟不僅為核酸或填脂質之構成元素,亦 於能量代謝或物質合成分解反應發揮重要的肖色,又,卸 具有物質代謝或物質移動的生理作用。因此^主要成分之 不足-般植物之生育會祠萎。又,妈係構成P物體及細胞 之重要成分’為維持代謝系統均衡亦發揮重要的功用,但 呈現鈣之缺乏症狀,會引起生理障礙例如蕃茄之爛尾、白 菜、包心菜等之爛芯、蘋果之苦坑⑽ter pit)、草莓之焦 葉(tip burn)等。 土壤中此等成分未必充分存在,故為補_營養成分, 可使用各種肥料。例如對於氮、麟、鉀之欠^症係以將化 學肥料施肥於土壤中來實施。 又,關於鈣缺乏引起之生理障礙,為防^此,大多嘗 試將石灰等施肥於土壤巾而齒供給,但,〖供給之石灰 的一部份會與大氣中的二氧化碳反應,形成+酸鈣而流入 地下,或與所施肥之其他化學肥料反應而不+化,又,化 學肥料與糾分之施肥均衡报差,常無法充供給至植物 體内。繼而,即使從植物之根吸收,鈣係於^物體内非常 難移動之元素’貫際上無法到達生理障礙發f之部位的情 莖、葉面或果 鼪成物。 f養成份不足 ---------JL.笨-- (請先閱讀背面之注意事項再填寫本頁) ,ιτ II 8 · « — - an
- ·- I 本紙張纽適财關家兩(CNS ) Α4胁(210χ_;97公釐) 4 A7 B7 乃目前的現狀 五、發明説明(2 ) 形很多。即使達到亦要相當時間,無即效性 因此,近年特別是以水溶液之形態散布於因缺乏鈣而 引起的生輯礙易顯現之葉面或果實,使之避免生 理障礙(即所謂之葉面散布)。 利用此等葉面散布之技術,使用於弼肥料之化合物已 知有.蟻酸舞(特開昭59_137384號)、醋酸两(特開昭6〇_ 260487號)、丙酸鈣(特願平4_2〇2〇8〇號)等之水溶性转鹽。 又,妈肥料(特開平7-1〇666號)已知乃溶解度高之約鹽與 溶解度低之鈣鹽組合面成。 、 然而’約從葉面或果實吸收一般乃很低,即使直接散 鈣鹽之水溶液,從吸收效率之方面而言亦有問題。又,若 欲提高吸收量,散布N,P.K或Ca鹽等之過剩;巴料成分,反 而對於植物會施予應力,成為產生藥害之結果。因此,期 盼-種以#5為f,使各種肥料成分有效地被祕體吸收之 方法。 .本發明人等為解決此等問題,經銳意研究結果,發現 藉由組合界面活性劑與庚糖酸或其鹽,可有效率地吸收肥 料成分,進而使含有界面活植劑與庚糖酸或其鹽之肥料組 成物形成水溶液而散布於植物的根或葉面,植物内可有效 地吸收營養素,終完成本發明。 亦即,本發明係提供一種肥料吸收促進劑組成物,其 特徵在於:含有界面活性劑與庚糖酸或其鹽作為必要成分 。又,本發明係提供一種肥料組成物,其特徵在於含有肥 I--------1笨------訂 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印製 本紙張尺度適WSiST CNS)八娜( 210x297公釐〉 A7 經 央 標 準 局 員 X 消 費 合 作 社 印 裝 五 發明説明( 料成分與該肥料吸收促進_⑽ 人進而’本發明係提供一種促進植物育成 Γ有界面活性劑及庚糖酸或其鹽之水溶液、 乳化液供給至植物。 本發明係提供-種促進植物吸收肥料成 將含有肥料成分以及界面活性劑、庚糖酸或 、水性分散液或乳化液供給至植物。 本發明所使用之界面活性劑可舉例如下 非離子界面活性劑可舉出:山梨聚糖脂酸醋、聚氧 伸垸基山梨聚糖脂肪酸酿、聚氧伸院基脂肪酸醋、甘油腊 肪酸s曰' 聚氧伸院基甘油酸醋、聚甘油脂肪酸醋、聚氧伸 烷基聚甘油脂肪酸酯、蘼糖脂肪酸酯、樹脂睃酯、聚氧伸 烧基樹脂酸酿、聚氧伸烧基烧基謎、聚氧伸院基院基苯基 醚、烷基(聚)糖苷、聚氧伸烷基烷基(聚)糖苷等。 陰離子界面活性劑可舉例:羧酸系、磺酸系、硫酸酯 系及碟酸酯系界面活性劑。 •綾酸系界面活性劑可舉出:碳數6〜30之脂肪酸或其 鹽、多價羧酸或其鹽、聚氧伸烷基烷基醚羧酸或其鹽、聚 氧伸烷基烷基酿胺醚羧酸或莫、鹽、酯膠酸或^鹽、二元酸 或其鹽、多元酸或其、松油脂肪酸或其鹽等 磺酸系統界面活性劑可舉出:烷基苯磺 基績酸或其鹽、烷基萘磺酸或其鹽、萘磺酸^其鹽、二苯 基越續酸或其鹽、烷基萘磺酸之縮合物或其^、萎續酸之 縮合物或其鹽等 的方法,乃將 水性分散液或 分之方法,乃 其鹽之水溶液 或其鹽 烷 (請先閱讀背面之注意事項再填寫本頁) 裟 本紙張尺度適用中國國家樣牟(CNS) Α4·《21〇χ297公釐) 6 經濟部中央標準局負工消費合作社印聚 、烷基二乙酵 五、發明説明(4 ) 硫酸醋系界面活性劑可舉出如:院基硫μ旨或其鹽、 聚氧伸烧基烧基硫酸醋或其鹽、聚氧伸烧基g基苯基謎硫 酸或其鹽、三苯乙稀化齡硫酸醋或其鹽、聚氣伸烧基二苯 乙稀化紛硫酸醋或其鹽等。 魏醋系界面活性劑可舉例如:烧基碟酸醋或其鹽、 烧基苯基碟酸醋或其鹽、聚氧伸燒基烧基峨酸醋或其鹽、 聚氧伸烧基烧基苯基鱗酸g旨或其癦。 此等化合物之鹽可舉例如:金屬鹽Wa、K、Ca、Mg、 Zn等)、銨鹽、烷醇胺鹽、脂肪族胺鹽等。 兩性界面活性劑可舉例胺基酸系、甜菜鹼系、咪唑啉 系、胺氧化物系。 胺基酸系可舉例:醯基胺基酸鹽、醯基肌胺酸鹽、醯 氧基甲基胺基丙酸鹽、烷基銨基丙酸鹽、醯基醯胺基乙基 羥基乙基甲基羧酸鹽等。 甜菜鹼系可舉例如:烷基二甲基甜菜鹼、烷基羥基乙 基甜菜鹼、醯基醢胺丙基羥基丙基氨磺甜菜鹼、醢基醯胺 丙基經基丙基氨確鹼菜鹼、乾麻油酸醯胺基丙基二甲基羧 基甲基氨甜菜鹼等。 味唾琳系可舉例烷基羧塞曱基羥基乙基咪唑啉鍇甜菜 驗、烷基乙氧基叛基甲基咪唆琳鐵甜菜驗等 胺氧化物系可舉例烷基二甲基胺氧化物 胺氧化物、烷基醯胺基丙基胺氧化物等。 上述界面活性劑可只使用一種,亦可使用混合2種以 上。又,上述界面活性劑含有聚氧伸烷基時,宜為聚氡伸 本紙張尺度適用中國國家標率(CNS ) Α4規格(210X297公瘦) ---------1 、装------訂 (請先閱讀背面之注意事項再填寫本頁) 、發明説明( 乙基’平均加成莫耳數宜為I〜50。 本發明中所使用之庚糖酸或其鹽可舉例 甘露庚糖酸、半乳庚糖酸等、及此等之鉀鹽 :葡庚糖酸、 鈉鹽、鈣鹽 烷醇胺鹽、脂肪族胺鹽等。較佳係葡庚糖“鈉鹽。又 庚糖酸雖存在異性體,但亦可使用同分異 刀異構物之任一者。 本發明之肥料吸收促進劑組成物係可含有上述界面活 性劑與庚糖酸或其鹽作為必要成分,其餘部份為水,依需 要可調配其他之任意成分。 本發明之肥料組成物係含有上述界面活性劑及庚糖酸 或其鹽,進一步可含有肥料成分。肥料成分可舉例含有1<[ 、Ρ、Κ、Ca、Mg、S、Β、Fe、Mn、Cu、Ζώ、Mo、C1、 Si、Na等之元素的無機物或有機物,但較佳係含有Ca之 化合物。使用於齊肥料组成物中之转化合物可舉例:氣化 鈣、硝酸鈣、碳酸鈣、硫酸鈣、生石灰、消石灰等之無機 構物、/β -同 (請先閲讀背面之注意事項再填寫本頁) " 訂 經濟部中央標準局員工消費合作社印裝 鈣鹽或醋酸、蟻酸、草酸、乳酸、羥基乙酸 檬酸、酒石酸、蘋果酸、庚糖酸、葡萄糖酸 二酸、乙二胺四醋酸等之有機酸的鈣鹽等, 混合2種以上。較佳係調配1#或2種之鈣化合 於本發明中,依需要可變更界面活性劑 鹽、肥料成分之調配比率,但一般,最終肥科組成物中之 量為界面活性劑0.1〜30重量份、庚糖酸或#鹽0.01〜20 重量份、肥料料成分1〜60重量份’依需要可含有水及/ 或溶劑。 琥珀酸、檸 甘胺酸、己 可使用1種或 物。 庚糖酸或其 本紙張尺度適用中國國家標準(CNS ) A4規格(210x29?公釐) 五、發明説明(6) A7 B7 本發明之肥料組成物的形態可為液體、充動劑、水和 劑、粒劑、粉劑等之任一者,一般,稀釋成50〜1000倍, 形成水溶液、水性分散液或乳化液而散布於植物的葉面或 根。尤佳者係含有界面活性劑5〜20重量%、庚糖酸或其 經濟部中央標準局員工消費合作社印装 鹽0·5〜10重量%、肥料成分10〜60重量% 媒介之液體製劑。 本發明之肥料組成物對植物的供給方法可使用各種手 段。例如,將所稀釋之水溶液散布於葉面、 接植物,或注入土壌中之方法;或,如水耕栽培或石棉般 ’稀釋混合成接觸於根之水耕液或供給水而^給的方法 本發明之肥料吸收促進劑組成物及肥料服成物乃對於 植物無藥害’且鈣等肥料成分可有效地被攝入植物體内 可使用散布於各種農作物。 實施例 以下,以實施例說明本發明,但本發明$限於此等實 施例。 製劑例 以下表示本發明品(1)之製劑例。關於—發明品 (6)亦依同樣步驟調製。 、 於適量之自來水中添加溶解CaCl2 · 2H2|)呈製劑最終 濃度40重量%,α-葡庚糖酸Na( _ 劑最終濃度重量%以作為鈣源。以0_1N鹽 ,且以水作為
製)呈製 酸調製成pH 7.0後’添加非離子界面活性劑即聚氧伸乙基(平均加成莫 耳數= 20)山梨聚糖油酸酯(花王(株)製、 -丁界- (請先閱讀背面之注意事項再填寫本頁) 装· 訂 本紙張尺度通用τ國國豕標率(CNS)从娜(21Gx297公幻 A7 B7 五、發明説明( 0120)呈製劑最終濃度1G重量%,溶解後,於自來水中授 拌c本製劑為弱黃色透明之水溶液。 為了比較乃提供了比較品(7)CaCl2 · 2t[2〇與α葡庚 糖酸Na之系統、比較品⑻CaCl2 · 2Η20之單濁系、比較品 (9)CaCl2 · 2Η2〇與葡萄糖酸Na之系、統、比棱器(1〇)CaC1: • 2ΙΪ2〇與抗壞血酸Na之系統、比較品(ll)C;iCl2 · 2H20、 上述非離子界面活性劑之系統、比較品(12)蟻酸Ca粉末作 為試驗β 各_製劑之處方表示於表1中。 (請先閲讀背面之注意事項再填寫本頁) 装. 訂 經濟部中央標準局員工消費合作社印製 本紙張尺度適財11¾¾ ( CNS ) “冗2lQx297公羡)-- -10 - 五、發明説明(8 ) A7 B7 表 1 製劑Να 配合康料 配合量(%) C a CU · 2Η?〇 4 0 (1) α —庚糖 10 · P〇E (20)山梨聚糖單油酸S睹; 10 本 C a Ch · 2H2O 4 0 (2) a —庚糖83^3 5 發 ? 0 E (25)硬化其麻油 10 C a Ch · 2HiO 4 0 明 (3) a 1 〇 P ◦ E (15)甘油牛脂脂肪酸a裔 2 〇 品 C a Ch · 2Η:0 4 0 (4) α - 5 P〇£ (3)月棟基鹿之Na.iM: 5 Ca(NO,) · 4H2〇 4 0 (5) a - 2 0 月桂甲基 5 蟻酸Ca - 4 0 (6) σ 10 聚甘油單油酸疲(縮合度5) 2 0 (7) C a Ch · 2 HzO 4 0 比 β 10 (8) C aCh · 2H2〇 4 0 較 (9) C aCh · 2Hs〇 4 0 葡萄糖酸Na 1 〇 品 (10) C a Cl* · 2H2〇 4 0 ^Sljk^Na. 10 (11) C a Ch · 2 HjO 4 0 • P 0 E (20)山梨聚糖油酸鹿 1 〇 (12) 蟻於 4 0 (請先閱讀背面之注意事項再填寫本頁) 裝. 訂 經濟部中央標準局員工消費合作社印製 調配物之其餘部份為水。 (注)表中,POE為聚氧伸乙烷之簡略,()内之數字為 環氧乙烷平均加成莫耳數。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 11 A7 B7 以11cm花盆 0.2Kg/cm3 五、發明説明(9 實施例1 <對白菜葉之鈣補給試驗> 白菜係使用「無雙」夕丰彳種苗(股)) 播種。施肥量設定成N : P205 : K2O=0.2 : 0.2 。從第2葉展開後,以每週一次之比例散布上述製劑例所 得到之各Ca製劑4次。散布濃度係以200倍稀釋使用各製 劑,散布量係以每一植物體約20ml散布於葉子上達充分 潤濕的程度。散布終了後,採取苐2葉,表面充分洗淨後 乾燥,以3N鹽酸熱處理萃取Ca後,藉ICP(感應結合電衆 分析法)進行定量。乾物重量每lg之白菜的_内〇&濃度表 示於表2中。 表 2 1 袈-- (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製
Ca製劑No·1 葉内 CaM* (%) 本 發 明 〇i (1) 3. 8 5 (2) 3.8 0 (3) 3.7 8 (4) 3.8 4 (5) 3.8 0 (6) 3. 8 5 比 較 品 (7) 3 . 2 9 (8) 3 . 15 (9) 、' 3 · 4 9 (10) 3.44 (11) 3.41 (12) 3 . 2 3 對 昭 t 水散布系 2.81 白菜乾物重量每lg之濃度
、1T 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) 12 五、發明説明(10) A7 B7 從此結果,可知藉由混合本發明之界面活性劑與庚糖 酸Na,與各較品比較,可更進一步促進(:&被 又,與葡萄糖酸Na或抗壞血酸Na相比 提高。 實施例 < 對缺鈣症大豆之鈣葉面散布試驗〉 對蛭石播種大豆「3牛厶只/」〔夕牛 後,以人工氣象器進行水耕栽培1〇日的幼苗 於500ml三角玻璃瓶,同時以空氣泵浦進行^氣,在23。〔 、1萬勒(Lux)的條件下實施。水耕栽培乃使用表3所示之 Jacobson培養基,並使用硝酸Na代替硝酸以,以引起c 缺乏症。水耕栽培開始後,以每4日3次之比 劑例所得到的各種Ca製劑。散布濃度稀釋成2〇〇倍,一谊 散布葉面一面留意避免喷灑於水耕液。葉面^布量係以啕 一植物體10ml左右充分潤濕葉子。然後,_定大豆全遛 之满濕重量’比較躲乏症之回避性。又,以不缺約之培 養基(表3)進行栽培(一般栽培),比較對缺乏^之鈣葉面^ 布效果。其結果表示於表4中 白疾攝入。 ^其致果明顯 <種苗(股)〕 水耕栽培係 例散布上述製 (#先閲讀背面之注意事項再填寫本頁) 袈 訂 經濟部中央標準局員工消費合作社印聚 本紙張尺度適財關家縣(CNS) A视格(2丨0><297公着) 13 五、發明説明(11) A7 B7 經濟部中央標準局員工消費合作社印製 表 3
Jacobson水耕培養基
Ca⑽3)2 ·偏 708ppm kn〇3 303ppm MgS〇4 · 7H2〇 493ppm KH2PO4 272ddih FeCl3 5ppm 酒石酸 5ppm HsBOa 2. 5ppm CuCl2 · 2H2〇 0. 05ppm MnCh · 4H2〇 1. 5ppm Na2MoO, · 2H2〇 0. 025ppm ZnCh 0. lppm 表 4 Ca製獅. :大豆濕潤重量(g> ⑴ 12. 4 1 本 ⑵ 12. 3 3 (3) 1 2 . 10 明 (4) 1 2. 4 4 口i (5) 1 2. 3 5 (6) 12. 5 6 (7) 8. 7 0 比 (8) ' 7. 15 (9) 10. 18 (10) 10. 0 0 era! (11) 9. 3 4 (12) 8 . 2 8 水散布系丨 3 . 5 0 照 通常裁培系 13. 68 1 ( m. I- - - I —^ϋ 1^1 I! - —- - -·I- -f I II - (讀先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -14 - A7 B7 五、發明説明(12) 如上述所示可知,本發明品可得到與一般栽培同等的 大豆重量’故具有有效地回避Ca缺乏症之功能。與葡萄 糖酸Na或抗壤血酸Na比較’其效果明顯提昇。 實施例3 <對蕃茄果實之Ca攝入效果試驗> 蕃茄品種乃使用「/、々只桃太郎」。播種後,約一個 月後’種植本葉12片展開苗。其27日後,36 3後施予鈣葉 面散布處理。散布濃度係將上述製劑例所将到之各種(:& 製劑稀釋200倍,對第二果房與果房上下葉散布10〇1111量 俾充分潤濕。第二次散布後約35日後,收取第二果房,以 水洗淨表面後,再以3N鹽酸進行熱處理萃取Ca,藉ICP定 量Ca量。其結果表示於表5中。 結果可知藉由混合本發明所示之界面活,生劑與庚糖酸 Na ’並與各比較品比較,可更進一步促進Ca被蕃茄果實 攝取°又’比Ca源單獨、界面活性劑之組合或葡萄糖酸Na 或抗壞血酸Na之組合,其效果更顯著。 m · - HI - --- ml n ^ I—........ ^^1 ^^1 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印製 本紙張尺度適用中國國家榡準(CNS ) A4規格(210X297公釐) 15 五、發明説明 13 ) A7 B7 表 5 Ca製綱〇· 果實中Ca紐*(%) 本 發 -明 品 ⑴ 0. 13 5 ⑵ 0. 13 0 ⑶ 0. 12 4 ⑷ 0. 13 6 ⑸ 0. 13 2 ⑹ 0. 13 5 比 較 品 ⑺ 0. 0 8 4 ⑻ 0. 0 6 6 ⑼ 0. 10 5 (10) 0. 10 0 (11) 0. 0 9 6 (12) 0 . 0 7 7 對 昭 t :水散布系 0. 0 3 4 (請先閱讀背面之注意事項再填寫本頁) 裝. 訂 *蕃茄果實潤濕重量每Ig之濃度。 經濟部中央標隼局員工消費合作社印裝 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 16
Claims (1)
- 經濟部智慧財產局員工消費合作社印製 公告本i ' …申請專利範圍第801113〇9號專利申請案申請專利範圍修正本 修正日期:88年〇8月 1· -種肥料吸收促進劑組成物’其含有g]_3()重量份之 至少1種以上之為非離子界面活性劑、陰離子界面活性 劑、兩性界面活性劑的界面活性劑與〇 〇: 庚糖酸或其鹽作為必要成分。2·如申請專利範圍第1項之組成物,其 係選自葡庚糖酸、甘露庚糖酸、半乳庚糖酸、及此等 之舒鹽、納鹽、舞鹽、麟胺鹽以及脂肪族胺鹽。3.如申請專利範圍第1項之組成物,其中庚糖酸或其鹽為 葡庚糖酸納鹽。 一種肥料組成物,其含有肥料成分、至少丨種以上之為 非離子界面活性劑、陰離子界面活性劑,,兩性界面活 性劑的界面活性劑以及庚糖酸或其鹽作為必要成分,20重量份之 庚糖酸或其鹽 (請先閱讀背面之注意事項再填寫本頁) 裝. 4. 且其係含1-30重量份之該肥料成份係為 — 之該界面活性劑係,以及0.01_2〇重量份之該庚糖酸 5. 如申請專利範圍第4項之組成物,其中該肥料成分含有 形成转源之化合物。 6. 如申請專利範圍第5項之組'成物,其中該衫成辦源之化 合物乃選自氣化鈣、硝酸鈣、碳酸鈣、硫酸鈣、生石 灰、消石灰之無機約鹽或選自蟻酸、草酸、醋酸、乳 酸、經基乙酸、琥拍酸、檸檬酸、酒石酸、蘋果酸、 葡萄糖酸、庚糖酸、己二酸、甘胺酸及乙二胺四醋酸 之有機酸的妈鹽 0J-30重量份 -訂 良紙張尺度適用中國國家揉率(CNS ) A4规格(210X297公釐) 17 經濟部智慧財產局員工消費合作社印製 公告本i ' …申請專利範圍第801113〇9號專利申請案申請專利範圍修正本 修正日期:88年〇8月 1· -種肥料吸收促進劑組成物’其含有g]_3()重量份之 至少1種以上之為非離子界面活性劑、陰離子界面活性 劑、兩性界面活性劑的界面活性劑與〇 〇: 庚糖酸或其鹽作為必要成分。2·如申請專利範圍第1項之組成物,其 係選自葡庚糖酸、甘露庚糖酸、半乳庚糖酸、及此等 之舒鹽、納鹽、舞鹽、麟胺鹽以及脂肪族胺鹽。3.如申請專利範圍第1項之組成物,其中庚糖酸或其鹽為 葡庚糖酸納鹽。 一種肥料組成物,其含有肥料成分、至少丨種以上之為 非離子界面活性劑、陰離子界面活性劑,,兩性界面活 性劑的界面活性劑以及庚糖酸或其鹽作為必要成分,20重量份之 庚糖酸或其鹽 (請先閱讀背面之注意事項再填寫本頁) 裝. 4. 且其係含1-30重量份之該肥料成份係為 — 之該界面活性劑係,以及0.01_2〇重量份之該庚糖酸 5. 如申請專利範圍第4項之組成物,其中該肥料成分含有 形成转源之化合物。 6. 如申請專利範圍第5項之組'成物,其中該衫成辦源之化 合物乃選自氣化鈣、硝酸鈣、碳酸鈣、硫酸鈣、生石 灰、消石灰之無機約鹽或選自蟻酸、草酸、醋酸、乳 酸、經基乙酸、琥拍酸、檸檬酸、酒石酸、蘋果酸、 葡萄糖酸、庚糖酸、己二酸、甘胺酸及乙二胺四醋酸 之有機酸的妈鹽 0J-30重量份 -訂 良紙張尺度適用中國國家揉率(CNS ) A4规格(210X297公釐) 17 六、申請專利範圍 A8 B8 C8 D8 如申請專利範圍第4項之組成物,其係呈帙體、流動劑 、水和劑、粒劑或粉劑。 請 先 閱讀 背 ιέf. 項 再 填I裝 頁 訂 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 18
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JP08211118A JP3135503B2 (ja) | 1996-08-09 | 1996-08-09 | 肥料吸収促進剤組成物及び肥料組成物 |
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EP (1) | EP0860410B1 (zh) |
JP (1) | JP3135503B2 (zh) |
CN (1) | CN1184172C (zh) |
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JP3487752B2 (ja) | 1998-02-06 | 2004-01-19 | 花王株式会社 | 肥料組成物 |
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US6383245B1 (en) * | 2000-04-05 | 2002-05-07 | Thomas T. Yamashita | Aqueous mineral compositions and methods for their use |
ITLT20020003A1 (it) * | 2002-01-21 | 2003-07-21 | Domenico Terenzio | Elementi nutritivi sotto forma di gluconati, allo scopo di migliorarela nutrizione e la difesa delle piante, a salvaguardia dell'ambiente d |
US20030224939A1 (en) * | 2002-05-31 | 2003-12-04 | David Miles | Adjuvant for pesticides |
US20040138176A1 (en) * | 2002-05-31 | 2004-07-15 | Cjb Industries, Inc. | Adjuvant for pesticides |
US7637054B2 (en) * | 2003-06-05 | 2009-12-29 | Bio Magic, Inc. | Compositions and methods for enhancing plant growth by chemical oxygenation of soils |
US20080026944A1 (en) * | 2003-06-05 | 2008-01-31 | Biomagic, Inc. | Compositions and Methods For Enhancing Plant Growth by Chemical Oxygenation of Soils |
US7476646B1 (en) | 2004-09-27 | 2009-01-13 | Cjb Industries, Inc. | Agricultural promoters/active ingredients |
GB0503152D0 (en) * | 2005-02-16 | 2005-03-23 | Ciba Sc Holding Ag | Foliar feed compositions,their preparations and use |
US7879146B2 (en) * | 2005-08-01 | 2011-02-01 | National Research Council Of Canada | Controlled release of chemical admixtures |
US7569091B1 (en) | 2005-08-26 | 2009-08-04 | Peters Robert B | Compound fertilizers and method of producing them |
DE102006053539A1 (de) | 2006-11-14 | 2008-05-15 | Lanxess Deutschland Gmbh | Calciumformiat-Düngemittel |
JP2008092955A (ja) * | 2007-11-22 | 2008-04-24 | Kao Corp | 人工培養土 |
CN102659481A (zh) * | 2012-05-30 | 2012-09-12 | 广西新方向化学工业有限公司 | 一种新型高效离子保持剂及其制备方法 |
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CN103626790A (zh) * | 2013-12-13 | 2014-03-12 | 成都新朝阳作物科学有限公司 | 液体螯合钙及其制备方法和用途 |
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CN1184172C (zh) | 2005-01-12 |
US6206946B1 (en) | 2001-03-27 |
CN1198729A (zh) | 1998-11-11 |
DE69732282T2 (de) | 2006-01-12 |
DE69732282D1 (de) | 2005-02-24 |
EP0860410B1 (en) | 2005-01-19 |
EP0860410A1 (en) | 1998-08-26 |
WO1998006681A1 (fr) | 1998-02-19 |
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JP3135503B2 (ja) | 2001-02-19 |
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