TW201311802A - 樹脂組成物 - Google Patents
樹脂組成物 Download PDFInfo
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- TW201311802A TW201311802A TW101118772A TW101118772A TW201311802A TW 201311802 A TW201311802 A TW 201311802A TW 101118772 A TW101118772 A TW 101118772A TW 101118772 A TW101118772 A TW 101118772A TW 201311802 A TW201311802 A TW 201311802A
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- 239000011342 resin composition Substances 0.000 title claims abstract description 53
- -1 triazine compound Chemical class 0.000 claims abstract description 60
- 125000003118 aryl group Chemical group 0.000 claims abstract description 30
- 150000001875 compounds Chemical class 0.000 claims abstract description 30
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 22
- 125000000962 organic group Chemical group 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 13
- 125000004849 alkoxymethyl group Chemical group 0.000 claims abstract description 10
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 25
- 125000004432 carbon atom Chemical group C* 0.000 claims description 24
- 239000011248 coating agent Substances 0.000 claims description 16
- 238000000576 coating method Methods 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 125000001624 naphthyl group Chemical group 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 claims description 6
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 6
- 125000001188 haloalkyl group Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 125000005561 phenanthryl group Chemical group 0.000 claims description 4
- 125000005907 alkyl ester group Chemical group 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 3
- 125000001544 thienyl group Chemical group 0.000 claims description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000002541 furyl group Chemical group 0.000 claims description 2
- 125000005499 phosphonyl group Chemical group 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 5
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- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 3
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
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- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
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- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 3
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- 229920003270 Cymel® Polymers 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
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- XYVQFUJDGOBPQI-UHFFFAOYSA-N Methyl-2-hydoxyisobutyric acid Chemical compound COC(=O)C(C)(C)O XYVQFUJDGOBPQI-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 2
- 239000004147 Sorbitan trioleate Substances 0.000 description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
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- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
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- 125000001072 heteroaryl group Chemical group 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
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- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
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- PNBCGVPSRHMZDO-UHFFFAOYSA-N 1-(1-propoxypropan-2-yloxy)propan-2-yl acetate Chemical compound CCCOCC(C)OCC(C)OC(C)=O PNBCGVPSRHMZDO-UHFFFAOYSA-N 0.000 description 1
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- SMLNDVNTPWRZJH-UHFFFAOYSA-N 1-chloro-4-(trimethoxymethyl)dodecane Chemical compound ClCCCC(C(OC)(OC)OC)CCCCCCCC SMLNDVNTPWRZJH-UHFFFAOYSA-N 0.000 description 1
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Abstract
本發明之課題為,提供可形成具有優良耐光性、高透明性且高折射率之硬化膜之樹脂組成物。解決方法為,含有下述(A)成分、(B)成分及(C)成分之組成物中,將該組成物製膜後藉由150℃以上加熱,而發現1.65以上之折射率之樹脂組成物。(A)成分:具有被羥基甲基及/或烷氧基甲基取代之至少2個氮原子之三□化合物(B)成分:持有至少1個丙烯酸基部位,且具有被有機基取代之芳香族基或縮合環之芳香族基的乙二醇化合物(C)成分:pKa為2以下之酸化合物。
Description
本發明係有關樹脂組成物,詳細為係有關可形成具有優良耐光性、高透明性且高折射率之硬化膜之樹脂組成物。
近年來高折射率之塑膠材料明顯朝向光學用物品發展,而盛行檢討使用於眼鏡透鏡、菲湼耳透鏡、凹凸透鏡、非球面透鏡、光碟、光纖、光波導等。又,電子材料領域中,液晶顯示器之防反射塗覆劑、太陽能電池用透明塗覆劑、發光二極管、CCD及CMOS感應器之受光部等之光學電子材料用途常使用透明性樹脂。該類光學電子材料用途中,除了透明性外,多數要求具有提升光取出率及提升集光性用之高折射率。現在所使用之具有高折射率之透明性樹脂為丙烯酸系樹脂、胺基甲酸酯系樹脂,或環氧系樹脂。
但先前之透明性樹脂中,可藉由交聯等之方法控制某程度機械物性之物於有關光學特性,特別是折射率方面,需備有特殊提升之技術。
例如專利文獻1及2曾提案,有機樹脂大量鍵結溴及硫等之重原子以提升其折射率之方法。
又,專利文獻3及4曾提案,將高折射率之無機氧化物微粒子分散於有機樹脂以提升其折射率之方法。
[專利文獻1]日本特開平5-164901號公報
[專利文獻2]日本特開2005-350531號公報
[專利文獻3]日本特開2007-270099號公報
[專利文獻4]日本特開2007-308631號公報
上述專利文獻1及2之方法中,一般所得之有機樹脂相對於熱及光具有不安定性,而有長期使用時易產生變色等之變質問題,故該樹脂使用於電子材料構件用途時,恐有電極腐蝕等之問題。
另外專利文獻3及4中,所得之微粒子分散樹脂含有長期保存安定性等之問題,又,為了改善無機氧化物微粒子於樹脂中之分散安定性需大量分散安定劑,故有難取得折射率與分散安定性之平衡等課題。
有鑑於上述事情,本發明之目的為,提供既使不使用重原子及無機氧化物微粒子,也可形成具有優良耐光性、高透明性且高折射率之硬化膜之樹脂組成物。
為了達成上述目的經本發明者專心檢討後發現,藉由樹脂組成物中添加持有至少1個丙烯酸基部位,且具有被
有機基取代之芳香族基或縮合環之芳香族基之乙二醇化合物,可由該樹脂組成物得到具有優良耐光性、高透明性且高折射率之硬化膜,而完成本發明。
即,本發明之第1觀點係有關一種樹脂組成物,其為含有下述(A)成分、(B)成分及(C)成分之組成物,該組成物製膜後藉由150℃以上之加熱,而產生1.65以上之折射率。
(A)成分:具有被羥基甲基及/或烷氧基甲基取代之至少2個氮原子之三化合物
(B)成分:持有至少1個丙烯酸基部位,且具有被有機基取代之芳香族基或縮合環之芳香族基之乙二醇化合物
(C)成分:pKa為2以下之酸化合物
第2觀點係有關第1觀點所記載之樹脂組成物,其中前述(B)成分中被有機基取代之芳香族基為被有機基取代之碳單環之芳香族基。
第3觀點係有關第2觀點所記載之樹脂組成物,其中前述(B)成分中被有機基取代之碳單環之芳香族基為被苯基取代之苯基。
第4觀點係有關第1觀點所記載之樹脂組成物,其中前述(B)成分中縮合環之芳香族基為萘基、蒽基、菲基或芘基。
第5觀點係有關第3觀點所記載之樹脂組成物,其中前述(B)成分之乙二醇化合物為下述式(1)所表示之化合物
(式中,R1表示氫原子或甲基,m表示自然數)。
第6觀點係有關第5觀點所記載之樹脂組成物,其中前述m為10以下。
第7觀點係有關第1至6觀點中任何1項所記載之樹脂組成物,其中前述(A)成分之三化合物為具有芳香族基之化合物。
第8觀點係有關第1至7觀點中任何1項所記載之樹脂組成物,其中前述(C)成分之酸化合物為磺酸化合物。
第9觀點係有關第8觀點所記載之樹脂組成物,其中前述磺酸化合物為下述式(2)或式(3)所表示之化合物
(式中,R2至R9各自獨立表示氫原子、碳原子數1至10之烷基、碳原子數1至10之鹵烷基、碳原子數1至10之
烷氧基,可被鹵原子、硝基、甲醯基、氰基、羧基、膦醯(phosphonyl)基、磺醯基、W取代之苯基、可被W取代之萘基、可被W取代之噻吩基或可被W取代之呋喃基,W表示碳原子數1至10之烷基、碳原子數1至10之鹵烷基、碳原子數1至10之烷氧基、羥基、鹵原子、硝基、甲醯基、氰基或羧基)。
第10觀點係有關第9觀點所記載之樹脂組成物,其中前述式(2)所表示之化合物為甲苯磺酸。
第11觀點係有關第1至10觀點中任何1項所記載之樹脂組成物,其中含有(D)成分的由具有4個以上碳原子之醇或具有4個以上碳原子之烷基酯所成群所選出之至少1種之溶劑。
第12觀點係有關第1至11觀點中任何1項所記載之樹脂組成物,其中相對於前述(A)成分100質量份,含有300質量份以下之比例的前述(B)成分。
第13觀點係有關第1至12觀點中任何1項所記載之樹脂組成物,其中相對於前述(A)成分100質量份,含有10質量份以下之比例的前述(C)成分。
第14觀點係有關第11至13觀點中任何1項所記載之樹脂組成物,其中相對於前述(A)成分、前述(B)成分及前述(C)成分之合計質量份,含有0.1質量份以上之比例的前述(D)成分。
第15觀點係有關第1至14觀點中任何1項所記載之樹脂組成物,其中另含有(E)成分的具有矽烷基之密合
劑。
第16觀點係有關一種硬化膜,其為,由第1至15觀點中任何1項所記載之樹脂組成物所得。
第17觀點係有關一種太陽能電池,其為,於透明電極之表面上被覆第16觀點所記載之硬化膜所形成。
第18觀點係有關一種電子構件,其為,具有第16觀點所記載之硬化膜。
本發明之樹脂組成物可形成具有優良耐光性、高透明性且高折射率之硬化膜。
本發明係有關含有下述成分(A)、成分(B)及成分(C)之組成物,該組成物製膜後藉由150℃以上之加熱,而產生1.65以上之折射率之樹脂組成物。
(A)成分:具有被羥基甲基及/或烷氧基甲基取代之至少2個氮原子之三化合物
(B)成分:持有至少1個丙烯酸基部位,且具有被有機基取代之芳香族基或縮合環之芳香族基之乙二醇化合物
(C)成分:pKa為2以下之酸化合物
本發明之(A)成分為具有被羥基甲基及/或烷氧基甲基取代之至少2個氮原子之三化合物。
該等具有被羥基甲基及/或烷氧基甲基取代之至少2個氮原子之三化合物如,具有被羥基甲基或烷氧基甲基或雙方取代之氮原子之三聚氰胺化合物,及具有被羥基甲基羥基甲基或烷氧基甲基或雙方取代之氮原子之苯并鳥糞胺化合物。
上述具有被羥基甲基取代之氮原子之三聚氰胺化合物及苯并鳥糞胺化合物係藉由,例如於沸騰水中使三聚氰胺/苯并鳥糞胺與甲醛水反應而羥基甲基化所得。其次具有被烷氧基甲基取代之氮原子之三聚氰胺化合物及苯并鳥糞胺化合物係藉由,先使被羥基甲基取代之三聚氰胺/苯并鳥糞胺化合物與甲醇、乙醇、異丙基醇、正己醇等進行醇反應所得。
該等被羥基甲基及/或烷氧基甲基取代之三聚氰胺化合物及苯并鳥糞胺化合物可由市售品取得。上述三聚氰胺化合物如,日本山提因(股)製山美爾300、山美爾303、山美爾325、山美爾725、三和化學(股)製尼卡拉MW-30M、MW-30、MW-30HM、尼卡拉MW-390、尼卡拉MW-100LM(以上為甲氧基甲基化三聚氰胺化合物);日本山提因(股)製山美爾370、山美爾701(以上為甲基化甲氧基甲基化三聚氰胺化合物);山美爾266、山美爾285、山美爾212(以上為甲氧基甲基化丁氧基甲基化三聚氰胺化合物);山美爾272、山美爾202(以上為甲基化甲氧基甲基
化三聚氰胺化合物);山美爾238(甲氧基甲基化異丁氧基甲基化三聚氰胺化合物);日本山提因(股)麥可特506(丁氧基甲基化三聚氰胺化合物)。又,上述苯并鳥糞胺化合物如,日本山提因(股)製山美爾1123(甲氧基甲基化乙氧基甲基化苯并鳥糞胺化合物);山美爾1123-10、麥可卡30(以上為甲氧基甲基化丁氧基甲基化苯并鳥糞胺化合物);麥可卡105、麥可卡106(以上為甲氧基甲基化苯并鳥糞胺化合物);山美爾1128(丁氧基甲基化苯并鳥糞胺化合物);麥可卡102(甲基化甲氧基甲基化苯并鳥糞胺化合物)。
本發明之(B)成分為持有至少1個丙烯酸基部位,且具有被有機基取代之芳香族基或縮合環之芳香族基之乙二醇化合物。
又,本發明中被有機基取代之芳香族基非僅為被有機基取代之芳香族基,也包含被有機基取代之雜芳香族基。又,本發明中縮合環之芳香族基非僅為縮合環之芳香族基,也包含縮合環之雜芳香族基。
上述被有機基取代之芳香族基如,被苯基取代之苯基、被苯基取代之吡咯基、被苯基取代之吲哚基、被苯基取代之噻吩基、被苯基取代之膦醯(phosphoryl)基、被苯基取代之吡唑基、被苯基取代之噁唑基、被苯基取代之咪唑基、被苯基取代之噻唑基、被苯基取代之異噁唑基、被
苯基取代之吡啶基、被苯基取代之吡嗪基、被苯基取代之噠嗪基、被苯基取代之三基,但非限制於該等。
其中被有機基取代之芳香族基較佳為,被有機基取代之碳單環之芳香族基,就取得性之觀點特佳為被苯基取代之苯基。
又,上述縮合環之芳香族基如,萘基、蒽基、菲基或芘基、苯并呋喃基、異苯并呋喃基、異吲哚基、苯并硫苯基、苯并磷醯基、苯并咪唑基、吡喃基、吲唑基、苯并噁唑基、苯并異噁唑基、苯并噻唑基、苯并咪唑基等,但非限制於該等。
其中縮合環之芳香族基就取得性之觀點較佳為萘基、蒽基、菲基或芘基。
為了得到更高折射率之膜,前述(B)成分之乙二醇化合物較佳為,下述式(1)所表示之化合物。
又,前述式(1)中,m較佳為10以下。
本發明之樹脂組成物中(B)成分之乙二醇化合物之含
量,相對於上述(A)成分100質量份為300質量份以下,就所得之膜之特性較佳為200質量份以下,就保存安定性與製膜性之觀點更佳為100質量份以下。
本發明之(C)成分為pKa為2以下之酸化合物。
本發明中,酸解離定數pKa為,以pKa=log10Ka表示,將酸性化合物溶解於水溶液中之酸解離定數(Ka)之值。
酸化合物,可僅使用1種,或將2種以上組合使用亦可。
上述酸化合物如,p-甲苯磺酸(也稱為甲苯磺酸)、三氟甲烷磺酸,及吡啶鎓-p-甲苯磺酸鹽等之磺酸化合物、磺柳酸、三氟丁酸、富馬酸、馬來酸等之羧酸化合物。其中較佳為磺酸化合物,特佳為下述式(2)或式(3)所表示之磺酸化合物。
(式中,R2至R9各自獨立表示氫原子、碳原子數1至10之烷基、碳原子數1至10之鹵烷基、碳原子數1至10
之烷氧基、鹵原子、硝基、甲醯基、氰基、羧基、膦醯基、磺醯基、可被W取代之苯基、可被W取代之萘基、可被W取代之噻吩基或可被W取代之呋喃基,
W表示碳原子數1至10之烷基、碳原子數1至10之鹵烷基、碳原子數1至10之烷氧基、羥基、鹵原子、硝基、甲醯基、氰基或羧基。
本發明之(C)成分特佳為p-甲苯磺酸(也稱甲苯磺酸)。
本發明之樹脂組成物中(C)成分之酸化合物之含量,相對於上述(A)成分100質量份為10質量份以下,就所得膜之特性較佳為5質量份以下,就保存安定性之觀點更佳為3質量份以下。
本發明之樹脂組成物,可含有(D)成分的由具有4個以上碳原子之醇或具有4個以上碳原子之烷基酯所成群所選出之至少1種之溶劑。
溶劑可僅使用一種,或組合使用二種以上。
上述溶劑如,丁基溶纖劑、丙二醇單甲基醚乙酸酯、二丙二醇單甲基醚、γ-丁內酯、n-丁醇、sec-丁醇、t-丁醇、甲氧基甲基戊醇、甲基溶纖劑、乙基溶纖劑、甲基溶纖劑乙酸酯、乙基溶纖劑乙酸酯、丁基卡必醇、丁基卡必醇乙酸酯、乙基卡必醇、乙基卡必醇乙酸酯、乙二醇單異丙基醚、乙二醇單丁基醚、二丙二醇單乙酸酯單甲基醚、
二丙二醇單乙基醚、二丙二醇單乙酸酯單乙基醚、二丙二醇單丙基醚、二丙二醇單乙酸酯單丙基醚、2-乙氧基乙醇、2-丁氧基乙醇、乳酸甲酯、乳酸乙酯、乳酸丁酯、乙酸甲酯、乙酸乙酯、乙酸n-丁酯、乙酸己酯、2-羥基異丁酸甲酯、丙二醇單乙基醚乙酸酯、丙酮酸甲酯、丙酮酸乙酯、3-甲氧基丙酸甲酯、3-乙氧基丙酸甲基乙酯、3-甲氧基丙酸乙酯、3-甲氧基丙酸丙酯、3-甲氧基丙酸丁酯或丁基丁酸酯。
本發明之樹脂組成物中(D)成分之溶劑之含量,相對於上述(A)成分、(B)成分及(C)成分之合計質量份為0.1質量份以上。
本發明之樹脂組成物除了上述成分,可另含有(E)成分的具有矽烷基之密合劑。
上述密合劑如,乙烯基三甲氧基矽烷、乙烯基三乙氧基矽烷、2-(3,4-環氧環己基)乙基三甲氧基矽烷、3-環氧丙氧基丙基甲基二甲氧基矽烷、3-環氧丙氧基丙基三甲氧基矽烷、3-環氧丙氧基丙基甲基二乙氧矽烷、3-環氧丙氧基丙基三乙氧基矽烷、p-苯乙烯基三甲氧基矽烷、3-甲基丙烯氧基丙基甲基二甲氧基矽烷、3-甲基丙烯氧基丙基三甲氧基矽烷、3-甲基丙烯氧基丙基甲基二乙氧基矽烷、3-甲基丙烯氧基丙基三乙氧基矽烷、3-丙烯氧基丙基三甲氧基矽烷、N-2-(胺基乙基)-3-胺基丙基甲基二甲氧基矽烷、
N-2-(胺基乙基)-3-胺基丙基三甲氧基矽烷、N-2-(胺基乙基)-3-胺基丙基三乙氧基矽烷、3-胺基丙基三甲氧基矽烷、3-胺基丙基三乙氧基矽烷、N-苯基-3-胺基丙基三甲氧基矽烷、3-脲基丙基三乙氧基矽烷、3-氯丙基三甲氧基矽烷、3-巰基丙基甲基二甲氧基矽烷、3-巰基丙基三甲氧基矽烷、雙(三乙氧基矽烷基丙基)四硫化物、3-異氰酸酯丙基三乙氧基矽烷、3-胺基丙基二乙氧基甲基矽烷等。
本發明中使用密合劑時,其添加量相對於上述成分(A)100質量份較佳為未達10質量份,就保存安定性之觀點更佳為5質量份以下。
本發明之樹脂組成物可添加其他慣用之添加劑,例如表面活性劑等。
前述表面活性劑如,聚環氧乙烷月桂醚、聚環氧乙烷硬脂醚、聚環氧乙烷鯨蠟醚、聚環氧乙烷油醚等之聚環氧乙烷烷基醚類、聚環氧乙烷辛基苯酚醚、聚環氧乙烷壬基苯酚醚等之聚環氧乙烷烷基烯丙醚類、聚環氧乙烷-聚環氧丙烷嵌段共聚物類、山梨糖醇酐單月桂酸酯、山梨糖醇酐單棕櫚酸酯、山梨糖醇酐單硬脂酸酯、山梨糖醇酐單油酸酯、山梨糖醇酐三油酸酯、山梨糖醇酐三硬脂酸酯等之山梨糖醇酐脂肪酸酯類、聚環氧乙烷山梨糖醇酐單月桂酸酯、聚環氧乙烷山梨糖醇酐單棕櫚酸酯、聚環氧乙烷山梨糖醇酐單硬脂酸酯、聚環氧乙烷山梨糖醇酐三油酸酯、聚
環氧乙烷山梨糖醇酐三硬脂酸酯等之聚環氧乙烷山梨糖醇酐脂肪酸酯類等之非離子系表面活性劑、耶佛特EF301、EF303、EF352(傑姆可股份公司(舊特肯姆(股))製)、美佳發F171、F173、R-30(DIC股份公司(舊大日本油墨化學工業(股))製)、佛洛拉FC430、FC431(住友3M(股)製)、阿薩面AG710、薩佛隆S-382、SC101、SC102、SC103、SC104、SC105、SC106(旭硝子(股)製)等之氟系表面活性劑、有機矽氧烷聚合物KP341(信越化學工業(股)製)等。
該等表面活性劑之添加量,於本發明之樹脂組成物之全體成分中一般為0.2質量%以下,較佳為0.1質量%以下。該等表面活性劑可單獨添加,或組合添加2種以上。
本發明之樹脂組成物適用為先前先所提案之各種矽系太陽能電池之材料。
太陽能電池一般係由透明電極(表面電極)一光電轉換層一背面電極所構成之太陽能電池,與搭載其之板材,即封裝單元組件之伸乙基乙酸乙烯共聚合樹脂(EVA)等之封裝劑,與保護單元組件及封裝劑之表面玻璃(強化玻璃)及保護薄膜(背膜)所構成。
本發明中,構成太陽能電池之各構成成分,即,太陽能電池單元(背面電極、光電轉換層、透明電極)、封裝劑、表面玻璃及保護薄膜,與各種電極保護材料,可使用目前所提案之各種之物。
實際上藉由將本發明之樹脂組成物塗佈於太陽能電池單元之透明電極之表面上,可形成電極表面包覆膜。其次依序層合強化玻璃-封裝劑-太陽能電池單元(電極表面包覆膜-透明電極-光電轉換層-背面電極)-封裝劑-背膜,製造太陽能電池。
下面將舉實施例更具體說明本發明,本發明非限定於下述實施例。
下面為實施例所使用之代號之含意。
Cymel 1123:日本山提因(股)製 三聚氰胺系化合物(甲氧基甲基化苯鳥糞胺化合物)
A-len-10:新中村化學工業(股)製 丙烯酸系化合物(乙氧基化O-苯基苯酚丙烯酸酯)
A-TMM-3LM-N:新中村化學工業(股)製 丙烯酸系化合物(季戊四醇三丙烯酸酯(三酯57%)
PGMEA:丙二醇單甲基醚乙酸酯
PGME:丙二醇單甲基醚
HBM:2-羥基異丁酸甲酯
NMP:N-甲基吡咯烷酮
CHN:環己酮
EL:乳酸乙酯
HA:乙酸己酯
PTA:P-甲苯磺酸
FTX-212P:那歐斯(股)製
FTX-220P:那歐斯(股)製
使用密卡薩(股)製旋塗機1H-DX2,將樹脂組成物塗佈於基板上。
使用島津製作所(股)製自記分光光度計UV-3100PC測定。又以400nm之透光率記載。
使用傑耶烏(股)製高速分光橢圓計器M-2000測定。又以633nm之折射率記載。
使用東洋精機製作所(股)製阿特拉老化計器Ci4000。又測定條件為,使用波氙弧燈以60w/m2(波長300-400nm)進行50小時,又使用黑板使溫度為63±3度。
將5.00g之Cymel 1123及5.00g之A-len-10及表面活性劑0.0002g加入HBM 40.1g中溶解p-甲苯磺酸(甲苯磺酸)0.15g之100mL茄型燒瓶內,以室溫(約25℃)攪拌3小時以上形成均勻溶液,得樹脂組成物。所得之溶液為無色透明。
依下述表1所示之組成,混合(A)成分之三聚氰胺系化合物、(B)成分:丙烯酸系化合物、(C)成分:酸化合物、(D)成分:有機溶劑及表面活性劑0.0002g後,以室溫(約25℃)攪拌3小時以上形成均勻溶液,得樹脂組成物。各成分與表面活性劑之種類如下所記載。
將上述所製作之塗料1塗佈於矽基板與石英玻璃上,以180度固化10分鐘,各自製作0.3μm與1.0μm之塗佈膜。其後測定耐光性試驗前後之透光率及折射率,確認試驗前後之透光率與折射率變化(圖1、圖2)。結果透光率為,由97.4%至98.6%維持高透明性。又,折射率維持1.66。故確認無大改變。
使用旋塗機將上述表1所製作之塗料塗佈於Si基板上,以表2所示之固化條件製膜後,測定折射率。
將上述所製作之塗料10與11塗佈於矽基板與石英玻璃上,以180度固化10分鐘,各自製作0.3μm之塗佈膜。其後測定折射率,結果為1.64與1.59(比較例1.2)。故增加丙烯酸基部位會降低折射率。
[圖1]圖1為表示於實施例1中,耐光性試驗前後的透光率之測定結果。
[圖2]圖2為表示於實施例1中,耐光性試驗前後的折射率之測定結果。
Claims (18)
- 一種樹脂組成物,其為含有下述(A)成分、(B)成分及(C)成分之組成物,該組成物製膜後藉由150℃以上之加熱,而產生1.65以上之折射率,(A)成分:具有被羥基甲基及/或烷氧基甲基取代之至少2個氮原子之三化合物(B)成分:持有至少1個丙烯酸基部位,且具有被有機基取代之芳香族基或縮合環之芳香族基之乙二醇化合物(C)成分:pKa為2以下之酸化合物。
- 如申請專利範圍第1項之樹脂組成物,其中前述(B)成分中被有機基取代之芳香族基為被有機基取代之碳單環之芳香族基。
- 如申請專利範圍第2項之樹脂組成物,其中前述(B)成分中被有機基取代之碳單環之芳香族基為被苯基取代之苯基。
- 如申請專利範圍第1項之樹脂組成物,其中前述(B)成分中縮合環之芳香族基為萘基、蒽基、菲基或芘基。
- 如申請專利範圍第3項之樹脂組成物,其中前述(B)成分之乙二醇化合物為下述式(1)所表示之化合物,
- 如申請專利範圍第5項之樹脂組成物,其中前述m為10以下。
- 如申請專利範圍第1至6項中任何1項之樹脂組成物,其中前述(A)成分之三化合物為具有芳香族基之化合物。
- 如申請專利範圍第1至7項中任何1項之樹脂組成物,其中前述(C)成分之酸化合物為磺酸化合物。
- 如申請專利範圍第8項之樹脂組成物,其中前述磺酸化合物為下述式(2)或式(3)所表示之化合物,
- 如申請專利範圍第9項之樹脂組成物,其中前述式(2)所表示之化合物為甲苯磺酸(tosylic acid)。
- 如申請專利範圍第1至10項中任何1項之樹脂組成物,其中含有(D)成分的由具有4個以上碳原子之醇或具有4個以上碳原子之烷基酯所成群中所選出之至少1種之溶劑。
- 如申請專利範圍第1至11項中任何1項之樹脂組成物,其中相對於前述(A)成分100質量份,含有300質量份以下之比例之前述(B)成分。
- 如申請專利範圍第1至12項中任何1項之樹脂組成物,其中相對於前述(A)成分100質量份,含有10質量份以下之比例之前述(C)成分。
- 如申請專利範圍第11至13項中任何1項之樹脂組成物,其中相對於前述(A)成分、前述(B)成分及前述(C)成分之合計質量份,含有0.1質量份以上之比例之前述(D)成分。
- 如申請專利範圍第1至14項中任何1項之樹脂組成物,其中另含有(E)成分的具有矽烷基之密合劑。
- 一種硬化膜,其為由如申請專利範圍第1至15項中任何1項之樹脂組成物所得。
- 一種太陽能電池,其為於透明電極之表面上被覆如申請專利範圍第16項之硬化膜而成。
- 一種電子構件,其為具有如申請專利範圍第16項之硬化膜。
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