201202636 六、發明說明： 【發明所屬之技術領域】 本發明係有關於一種固體吸附式製冷系統，特別為一種分 離型固體吸附式製冷系統。 【先前技術】 近年來因臭氧層被破壞、溫室效應等問題對於環境造成負 面影響，世界各國皆開始管制會散發溫室氣體的冷媒，並同時 開發出許多兼具環保及節能特點的技術。其中，固體吸附式製鲁 冷技術具有乾淨無污染、主機不需外來電源、結構簡單、使用 壽命長、無動件及噪音等優點，而且還具有可以利用廢熱（例 如工業廢熱、太陽能專低溫熱源）驅動等特性，因此被認為是 能同時兼顧節能及環境保護的有效關鍵技術。 固體吸附式製冷技術的原理是利用吸附劑對冷媒的吸附 作用造成冷媒液體的蒸發，進而產生製冷效應。固體吸附式製 冷系統是由吸附床、蒸發器及冷凝器等三個主要元件所構成， 其基本原理為利用冷卻水及熱水以冷卻或是加熱吸附劑使冷籲 媒在吸附床進行吸附及脫附作用，再將冷媒引導至蒸發器及冷 凝器進行吸熱及放熱。 其中，吸附作用是藉由冷卻水或空氣等介質通過高溫的吸 附床，以帶走吸附劑（一般為矽膠、沸石、活性碳等）之顯熱及 吸附熱，並使吸附劑吸附冷媒（一般為水、曱醇、乙醇或氨等）。 又因氣相冷媒壓力降低，因此可使得與吸附床相連的蒸發器内 的冷媒条發吸熱而製冷。 4 201202636 脫附作用則是使高溫熱水通過吸附床，以挺4 托咼吸附劑之溫 度，並使得原本被吸附於^劑中的冷媒脫附出來，進而完成201202636 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a solid adsorption refrigeration system, and more particularly to a separate solid adsorption refrigeration system. [Prior Art] In recent years, problems such as the destruction of the ozone layer and the greenhouse effect have had a negative impact on the environment. Countries around the world have begun to control the refrigerants that emit greenhouse gases, and at the same time have developed many technologies that combine environmental protection and energy conservation. Among them, the solid adsorption type Luliang technology has the advantages of being clean and pollution-free, the host does not need external power supply, the structure is simple, the service life is long, the moving parts and the noise are not good, and the waste heat can be utilized (for example, industrial waste heat, solar energy special low temperature heat source). Driven and other characteristics, it is considered to be an effective key technology that can simultaneously consider energy conservation and environmental protection. The principle of the solid adsorption refrigeration technology is to use the adsorption of the adsorbent to the refrigerant to cause evaporation of the refrigerant liquid, thereby generating a refrigeration effect. The solid adsorption refrigeration system is composed of three main components, such as an adsorption bed, an evaporator and a condenser. The basic principle is to use cooling water and hot water to cool or heat the adsorbent to adsorb the cold solvent in the adsorption bed. Desorption, and then the refrigerant is directed to the evaporator and condenser for heat absorption and heat release. Among them, the adsorption is carried out by a medium such as cooling water or air through a high-temperature adsorption bed to take away the sensible heat and adsorption heat of the adsorbent (generally tannin, zeolite, activated carbon, etc.), and the adsorbent adsorbs the refrigerant (generally It is water, sterol, ethanol or ammonia, etc.). Further, since the pressure of the vapor phase refrigerant is lowered, the refrigerant strip in the evaporator connected to the adsorption bed can be made to absorb heat and be cooled. 4 201202636 The desorption function is to let the hot water of hot water pass through the adsorption bed, to warm the temperature of the adsorbent, and to desorb the refrigerant that was originally adsorbed into the agent, thereby completing
吸附劑的再生。而脫附出來的冷媒則會流動氣a $ M 7錢器，並由冷 凝器中的冷卻水使其冷卻凝結成液態冷媒。因此 通入冷卻水及熱水於謂床巾，以使得吸 彳透過父互 脫附冷媒，並再配合蒸發器及冷凝器之作用，^反覆吸附及 果。 而達到製冷的效 而固體吸附式製冷技術可應用在空調 空調系統中之壓縮機。鈇 系统中以取代現有 …、而，目刖固體吸附式制 吸附劑材料及工作流體的選擇，吸附與脫_冷系統受限於 麼力下進行’因此各Μ及連接管路、Μ^要在真空 求，並且系統的整體體積皆極為龐大。聲達到耐高壓的要 此外，由於吸附床、蒸發二凝 腔體内’吸附、脫附、蒸發及冷凝也=整合於同-真空 便是將蒸發器與冷凝器整合成同=壓力環境中進 ;!=小_附式製冷系統的體積器，也仍舊是 發态及冷凝态功能的熱交換 者，習知整合蒸 的熱傳特性進行設計，因此不。;實並，針對蒸發與冷凝 造成本也無法有效降低 :、法提升製冷致能，系統的製 有效地運用在空㈣蛛巾。、ϋ將固體吸附式製冷系統 【發明内容】 ㈣⑽$ t冷系統，其係藉由將 冷的7L件，不但可抑殼管式熱交 本發明係為一種分離型 殼管式熱交換器作為蒸發製 201202636 換器具有的熱傳特性提升製冷效果，而且還可以降低固體吸附 式製冷系統之製作成本。 本發明係為一種分離型固體吸附式製冷系統，由於殼管式 熱父換器可無需設置在真空環境下，因此可與真空腔室分離設 置，以達到減少系統整體體積之功效。 ^為達上述功效，本發明係提供一種分離型固體吸附式製冷 系統，其包括：-第一吸附單元，其包括一第一真空腔室、一 f吸附床及第一冷凝器，其中第一吸附床及第一冷凝器係 D 又置於第真空腔室中，且第—吸附床包含—第—人水口及一 第;"出水口，第一冷凝器包含一第一冷媒入口及一第一冷媒出 口丄第—吸附單元，其包括—第二真空腔室、—第二吸附床 ，办第—冷凝11 ’其中第二賴床及第二冷凝器係設置於第二 口 Γί-至中’且第二吸附床包含一第二入水口及-第二出水 一私放_^凝器包含一第二冷媒入口及一第二冷媒出口；以及 =式熱交換器，其具有：—殼體，其包含—冰水入Regeneration of the adsorbent. The desorbed refrigerant flows into the gas a $ M 7 and is cooled by the cooling water in the condenser to form a liquid refrigerant. Therefore, the cooling water and the hot water are introduced into the bed towel so that the suction is removed from the parent through the refrigerant, and the effect of the evaporator and the condenser is combined with the effect of the evaporator and the condenser. The cooling effect is achieved and the solid adsorption refrigeration technology can be applied to compressors in air conditioning systems. In the 鈇 system to replace the existing ..., and to see the choice of solid adsorption sorbent materials and working fluids, the adsorption and de-cooling system is limited by the force of the force 'so each Μ and connecting pipelines, Μ ^ In the vacuum, and the overall size of the system is extremely large. In addition, the sound reaches the high pressure resistance. In addition, the adsorption, desorption, evaporation and condensation in the adsorption bed and the evaporating two condensation chamber are also integrated into the same vacuum, which integrates the evaporator and the condenser into the same pressure environment. ;! = small _ attached refrigeration system volume, is still a heat exchanger for the function of the state of the state and the condensed state, the heat transfer characteristics of the integrated steam is designed to be designed, so no. In fact, the evaporation and condensation can not be effectively reduced: the method improves the cooling capacity, and the system is effectively used in the air (four) spider. ϋ 固体 solid adsorption refrigeration system [Summary of the invention] (4) (10) $ t cold system, which is based on a cold 7L piece, not only can suppress the shell-type heat transfer Evaporation system 201202636 The heat transfer characteristics of the converter improve the cooling effect, and can also reduce the manufacturing cost of the solid adsorption refrigeration system. The present invention is a separate type solid adsorption refrigeration system. Since the shell-and-tube type hot parent converter can be disposed in a vacuum environment without being disposed in a vacuum environment, the vacuum chamber can be separately disposed to reduce the overall volume of the system. In order to achieve the above effects, the present invention provides a separate solid adsorption refrigeration system, comprising: a first adsorption unit comprising a first vacuum chamber, an f adsorption bed and a first condenser, wherein the first The adsorption bed and the first condenser system D are further disposed in the first vacuum chamber, and the first adsorption bed comprises a first-person nozzle and a first outlet; the first condenser comprises a first refrigerant inlet and a first condenser a first refrigerant outlet 丄 first-adsorption unit, comprising: a second vacuum chamber, a second adsorption bed, a first-condensation 11', wherein the second bed and the second condenser are disposed at the second port Γί-to And the second adsorbent bed comprises a second water inlet and - the second water outlet - the private condenser comprises a second refrigerant inlet and a second refrigerant outlet; and the = heat exchanger has: - shell Body, which contains - ice water into
，水水出口；至Φ 一笙放U 部，其中第一㈠ 吕路’其具有-第一端部及一第二端 、帛W係透過-第—閥件組與第 :一第;端:則透過-第二闕件組與第二冷一^ 係透過―:路’其具有一第三端部及一第四端部，且第三端部 ' =閥件組與第二冷媒出σ連通第 —第四闕件組與第-冷媒入Π連通。 透過 一、實施’至少可達到下列進步功效： 1用咸管式熱交換H原有的熱傳特性’崎升製冷效 201202636 二、 可將殼管式熱交換器與真空腔室分離設置，以降低整體系 統的製作成本。 三、 由於殼管式熱交換器係設置於真空腔室外，因此可達到減 少整體系統體積之功效。 為了使任何熟習相關技藝者了解本發明之技術内容並據 以實施，且根據本說明書所揭露之内容、申請專利範圍及圖 式，任何熟習相關技藝者可輕易地理解本發明相關之目的及優 點，因此將在實施方式中詳細敘述本發明之詳細特徵以及優 【實施方式】 第1圖係為本發明實施例之一種分離型固體吸附式製冷系 統100之架構示意圖。第2圖及第3圖分別為本發明實施例之 一種分離型固體吸附式製冷系統100之作動示意圖。 如第1圖所示，本實施例係為一種分離型固體吸附.式製冷 _ 系統100，其包括：一第一吸附單元10 ; —第二吸附單元20 ; 以及一殼管式熱交換器30。 其中，第一吸附單元10,其包括一第一真空腔室11、一 第一吸附床12及一第一冷凝器13,並且第一吸附床12與第一 冷凝器13係設置於第一真空腔室11中。第一吸附床12包含 一第一入水口 121及一第一出水口 122，可視需要使熱水或冷 卻水由第一入水口 121流入再由第一出水口 122流出，以使得 熱水或冷卻水得以通入第一吸附床12。而第一冷凝器13亦包 含一第一冷媒入口 131及一第一冷媒出口 132，以提供冷媒流 201202636 入及流出第一冷凝器13。 第一吸附單元20，其包括一第二真空腔室21、一第二吸 附床22及一第二冷凝器23。第二吸附床22及第二冷凝器23 亦没置於第二真空腔室21中，且第二吸附床22包含一第二入 水口 221及一第二出水口 222，以供熱水或冷卻水由第二入水 口 221流入第二吸附床22，並再由第二出水口 222流出第二吸 附床22。第二冷凝器23同樣包含一第二冷媒入口 231及一第 二冷媒出口 232，用以提供冷媒進出第二冷凝器23。 上述之第一吸附床12及第二吸附床22係用以儲放一吸附 劑，例如：矽膠、沸石、活性碳等。第一冷凝器13及第二冷 凝器23則用以儲放一冷媒’例如：水、曱醇、乙醇或氨等。 此外，吸附劑與冷媒需配對使用，常用的吸附劑及冷媒係例如 活性碳-甲醇、沸石-水及矽膠-水。 殼管式熱交換器30,其具有：一殼體31 至少一第一管 路32 :以及至少一第二管路33。 其中，第一管路32及第二管路33係被包覆於殼管式熱交 換器30之殼體31中，而且第一管路32及第二管路33皆為一 真空管路。殼體31包含有一冰水入口 311及一冰水出口 312， 而且冰水入口 311及冰水出口 312可分設於殼體31之相對應 兩侧’以使得冰水可由冰水入口 311流入殼體31，再由冰水出 口 312流出。此外，殼管式熱交換器30可再與空調系統結合， 以提供低溫之冰水給空調系統使用。 再者，分離型固體吸附式製冷系統100可進一步包括一儲 存槽40,其可與殼體31之冰水入口 311及冰水出口 312連通， 201202636 用以儲存冰水，並提供冰水至殼管式熱交換器30。當冰水經過 殼管式熱交換器30並且配合第一吸附單元10及第二吸附單元 20作用後，可再降低冰水之溫度，而溫度更低之冰水可再儲存 於儲存槽40中，以供空調系統使用。 殼管式熱交換器30中之第一管路32係具有一第一端部 321及一第二端部322，而第一端部321係透過一第一閥件組 50與第一吸附單元10之第一冷媒出口 132連通，第二端部322 則透過一第二閥件組60與第二吸附單元20之第二冷媒入口 231連通。類似地，第二管路33係具有一第三端部331及一第 四端部332,且第三端部331係透過一第三閥件組70與第二吸 附單元20之第二冷媒出口 232連通，而第四端部332則透過 一第四閥件組80與第一吸附單元10之第一冷媒入口 131連通。 上述之第一閥件組50係包括一第一膨脹閥51及一第一逆 止閥52。其中，第一膨脹閥51之一端係連接於第一冷凝器13 之第一冷媒出口 132，而另一端則連接於第一逆止閥52之一 鲁端，並且第一逆止閥52之另一端又連接於第一管路32之第一 端部321。第二閥件組60係包括一第二逆止閥61，其一端係 連接於第一管路32之第二端部322,另一端則連接第二吸附單 元20之第二冷媒入口 231。其中，第一逆止閥52只允許冷媒 自第一冷媒出口 132流向第一管路32，而第二逆止閥61只允 許冷媒自第一管路32流向第二冷媒入口 231。 上述之第三閥件組70係包括一第二膨脹閥71及一第三逆 止閥72。其中，第二膨脹閥71之一端係連接於第二冷凝器23 之第二冷媒出口 232，而另一端則連接於第三逆止閥72之一 201202636 :部並33^第:逆止閥72之另—端又連接於第二管路33之第三 連接於第二其四闊件組8〇係包括一第四逆止闕81 ’其一端係 單元ίο之"V路33之第四端部332,且另一端則連接第一吸附 早凡1〇之第一冷媒入口 131。 媒自第二冷媒出口 232以@ 帛二逆止閥72只允許冷 允,A媒白楚、拉⑺向第一管路33’而第四逆止閥81只 允♦冷媒自第二管路33流向第一冷媒入口⑶。 作動將說明本實施例之分離型固體吸附式製冷系統100之 進行脫瞻 中，以使得第—吸附單元10内 ^附作用，而第二吸附單元2〇内可進行吸附作用。 :第-韻單元1G進行職作㈣，原本被吸附於第一 # 12之吸附劑内的冷媒將會被脫附 冷凝器13中。由於挤拄筮古咖— 工桃動至第 境下，M d 室11係處在高溫高壓的環 一真空腔室21則是處在低溫低壓的 闕^此，—冷媒會從第—冷媒出口. 132流出，並經過第一膨服 、、,入第〜止闊52後，再由第一管路32的第一端部321 ^二官路^之後，冷媒係在第一管路％内流動並由第 二端部322流出至第二逆止閥61，再透過第二 閥61由第二冷媒入口 231流入第二真空腔室η中。而且， 吸附單元20係通入有冷卻水以進行吸附作用，因此 將導致第一管路32中的冷媒蒸發並吸熱，以進而降低第一管 201202636 路32之溫度。 又如第3圖所示，接著可再將熱水通入第二吸附單元20 中，並將冷卻水通入第一吸附單元10中，以使得第二吸附單 元20進行脫附作用，而第一吸附單元10可進行吸附作用。 同樣的，當第二吸附單元20進行脫附作用時，原本被吸 附於第二吸附床22之吸附劑内的冷媒將會被脫附出來，並流 動至第二冷凝器23中。由於此時第二真空腔室21係處在高溫 高壓的環境下，而第一真空腔室11則是處在低溫低壓的狀況， — 所以由第二吸附床22中脫附出的冷媒會因為兩真空腔室11、 21間之壓力差而被推入第一真空腔室11中。 所以，冷媒會由第二冷媒出口 232流出，並經過第二膨脹 閥71、第三逆止閥72後，再由第二管路33的第三端部331 流入第二管路33，並沿著第二管路33在殼管式熱交換器30 内流動。之後，冷媒會再由第二管路33的第四端部332流出 至第四逆止閥81，再經由第四逆止閥81自第一冷媒入口 131 籲流入第一真空腔室11中。 於此同時，第一吸附單元10内也通入有冷卻水並進行吸 附作用，因此第二管路33内之冷媒會被蒸發並吸熱，因此可 降低第二管路33之溫度。 藉由不斷使熱水及冷卻水交替通入第一吸附單元10及第 二吸附單元20，以使得第一吸附單元10及第二吸附單元20 可以連續地進行脫附作用及吸附作用，並且可以不間斷地使第 一管路32及第二管路33的溫度保持在低溫。因此，當冰水由 殼管式熱交換器30之冰水入口 311流入殼體31後，可藉由第 11 201202636 一管路32及第二管路33交替產生的製冷效果，以降低冰水的 溫度，而降溫後之冰水則可由冰水出口 312流出，並可提供給 空調系統使用。 藉此，利用殼管式熱交換器30可以使得固體吸附式製冷 系統不間斷地製冷，又由於殼管式熱交換器30無須設置在真 空環境中，因此可以移出真空腔室11、21之外，進而降低整 體系統的製作成本，並可減少整體系統的體積。 惟上述各實施例係用以說明本發明之特點，其目的在使熟 習該技術者能暸解本發明之内容並據以實施，而非限定本發明 之專利範圍，故凡其他未脫離本發明所揭示之精神而完成之等 效修飾或修改，仍應包含在以下所述之申請專利範圍中。 【圖式簡單說明】 第1圖係為本發明實施例之一種分離型固體吸附式製冷系統之 架構示意圖。 第2圖及第3圖分別為本發明實施例之一種分離型固體吸附式 製冷系統之作動示意圖。 【主要元件符號說明】 100..............分離型固體吸附式製冷系統 10 ................第一吸附單元 11 ................第一真空腔室 12 ................第一吸附床 121..............第一入水口 12 201202636 122..............第一出水口 13................第一冷凝器 131 ..............第一冷媒入口 132 ..............第一冷媒出口 20 ................第二吸附單元 21 ................第二真空腔室 22 ................第二吸附床 221 ..............第二入水口, water and water outlet; to Φ 笙 U U, the first (1) Lu Lu 'there has - first end and a second end, 帛 W system through - the first valve member group and the first: first; : passing through the second component group and the second cooling device through the ": road" having a third end portion and a fourth end portion, and the third end portion = the valve member group and the second refrigerant The σ-connected fourth-fourth component group is in communication with the first-refrigerant inlet. Through the implementation of one, at least the following advancements can be achieved: 1 The original heat transfer characteristics of the salt-tube type heat exchange H. The rugged cooling effect 201202636 2. The shell-and-tube heat exchanger can be separated from the vacuum chamber to Reduce the production cost of the overall system. Third, since the shell-and-tube heat exchanger is disposed outside the vacuum chamber, the effect of reducing the overall system volume can be achieved. In order to make those skilled in the art understand the technical content of the present invention and implement it, and according to the disclosure, the patent scope and the drawings, the related objects and advantages of the present invention can be easily understood by those skilled in the art. The detailed description of the present invention and the preferred embodiments thereof will be described in detail in the embodiments. FIG. 1 is a schematic view showing the structure of a separate solid adsorption refrigeration system 100 according to an embodiment of the present invention. 2 and 3 are schematic views showing the operation of a separate type solid adsorption refrigeration system 100 according to an embodiment of the present invention. As shown in FIG. 1, the present embodiment is a separate solid adsorption refrigeration system 100 comprising: a first adsorption unit 10; a second adsorption unit 20; and a shell and tube heat exchanger 30. . The first adsorption unit 10 includes a first vacuum chamber 11, a first adsorption bed 12, and a first condenser 13, and the first adsorption bed 12 and the first condenser 13 are disposed in the first vacuum. In the chamber 11. The first adsorption bed 12 includes a first water inlet 121 and a first water outlet 122. If necessary, hot water or cooling water flows from the first water inlet 121 and then flows out of the first water outlet 122 to make hot water or cool. Water is allowed to pass into the first adsorption bed 12. The first condenser 13 also includes a first refrigerant inlet 131 and a first refrigerant outlet 132 to provide a refrigerant flow 201202636 into and out of the first condenser 13. The first adsorption unit 20 includes a second vacuum chamber 21, a second adsorption bed 22, and a second condenser 23. The second adsorption bed 22 and the second condenser 23 are also not disposed in the second vacuum chamber 21, and the second adsorption bed 22 includes a second water inlet 221 and a second water outlet 222 for hot water or cooling. The water flows from the second water inlet 221 into the second adsorption bed 22, and then flows out of the second adsorption bed 22 from the second water outlet 222. The second condenser 23 also includes a second refrigerant inlet 231 and a second refrigerant outlet 232 for supplying refrigerant to and from the second condenser 23. The first adsorbent bed 12 and the second adsorbent bed 22 described above are used for storing an adsorbent such as silicone rubber, zeolite, activated carbon or the like. The first condenser 13 and the second condenser 23 are used to store a refrigerant such as water, methanol, ethanol or ammonia. Further, the adsorbent and the refrigerant are used in combination, and commonly used adsorbents and refrigerants are, for example, activated carbon-methanol, zeolite-water and silicone-water. The shell and tube heat exchanger 30 has a housing 31 at least a first tube 32: and at least a second line 33. The first line 32 and the second line 33 are wrapped in the casing 31 of the shell-and-tube heat exchanger 30, and the first line 32 and the second line 33 are both vacuum lines. The housing 31 includes an ice water inlet 311 and an ice water outlet 312, and the ice water inlet 311 and the ice water outlet 312 can be disposed on opposite sides of the housing 31 such that the ice water can flow into the shell from the ice water inlet 311. The body 31 is again discharged from the ice water outlet 312. In addition, the shell and tube heat exchanger 30 can be combined with an air conditioning system to provide low temperature ice water for use in the air conditioning system. Furthermore, the separation type solid adsorption refrigeration system 100 may further include a storage tank 40 that can communicate with the ice water inlet 311 and the ice water outlet 312 of the casing 31, and 201202636 for storing ice water and providing ice water to the shell. Tube heat exchanger 30. When the ice water passes through the shell-and-tube heat exchanger 30 and cooperates with the first adsorption unit 10 and the second adsorption unit 20, the temperature of the ice water can be further reduced, and the ice water with lower temperature can be stored in the storage tank 40 again. For use in air conditioning systems. The first pipe 32 of the shell and tube heat exchanger 30 has a first end portion 321 and a second end portion 322, and the first end portion 321 is transmitted through a first valve member group 50 and a first adsorption unit. The first refrigerant outlet 132 of 10 is in communication, and the second end portion 322 is in communication with the second refrigerant inlet 231 of the second adsorption unit 20 through a second valve member group 60. Similarly, the second conduit 33 has a third end portion 331 and a fourth end portion 332, and the third end portion 331 is transmitted through a third valve member group 70 and a second refrigerant outlet of the second adsorption unit 20. The second end portion 332 communicates with the first refrigerant inlet 131 of the first adsorption unit 10 through a fourth valve member group 80. The first valve member group 50 described above includes a first expansion valve 51 and a first check valve 52. Wherein, one end of the first expansion valve 51 is connected to the first refrigerant outlet 132 of the first condenser 13, and the other end is connected to one end of the first check valve 52, and the other of the first check valve 52 One end is in turn connected to the first end 321 of the first conduit 32. The second valve member set 60 includes a second check valve 61 having one end coupled to the second end 322 of the first conduit 32 and the other end coupled to the second refrigerant inlet 231 of the second adsorbing unit 20. Among them, the first check valve 52 only allows the refrigerant to flow from the first refrigerant outlet 132 to the first line 32, and the second check valve 61 only allows the refrigerant to flow from the first line 32 to the second refrigerant inlet 231. The third valve member group 70 described above includes a second expansion valve 71 and a third check valve 72. Wherein, one end of the second expansion valve 71 is connected to the second refrigerant outlet 232 of the second condenser 23, and the other end is connected to one of the third check valves 72201202636: and 33^: check valve 72 The other end connected to the second conduit 33 is connected to the second four-piece group 8 and includes a fourth reverse stop 81', one end of which is the fourth unit of the unit ίο "V road 33 The end portion 332 is connected to the first refrigerant inlet 131 of the first adsorption. The medium is supplied from the second refrigerant outlet 232 to the @ 帛2 check valve 72, which only allows cold letting, A medium white, pull (7) to the first line 33' and the fourth check valve 81 only allows the refrigerant to pass from the second line. 33 flows to the first refrigerant inlet (3). The operation will explain the separation of the separation type solid adsorption refrigeration system 100 of the present embodiment so that the first adsorption unit 10 can be attached, and the second adsorption unit 2 can be adsorbed. : The first rhyme unit 1G performs the work (4), and the refrigerant originally adsorbed in the adsorbent of the first #12 will be desorbed in the condenser 13. Due to the squeezing of the ancient coffee - the working peach is moved to the first level, the 11th chamber of the M d chamber is in the high temperature and high pressure, and the vacuum chamber 21 is in the low temperature and low pressure. The refrigerant will be discharged from the first refrigerant. 132 flows out and passes through the first expansion, and after entering the first to the wide 52, and then the first end 321 of the first conduit 32 is the second official, then the refrigerant is in the first conduit%. The flow flows out from the second end portion 322 to the second check valve 61, and then flows through the second valve 61 into the second vacuum chamber η through the second refrigerant inlet 231. Moreover, the adsorption unit 20 is supplied with cooling water for adsorption, thereby causing the refrigerant in the first line 32 to evaporate and absorb heat, thereby further reducing the temperature of the first pipe 201202636. As shown in FIG. 3, the hot water can be further introduced into the second adsorption unit 20, and the cooling water is introduced into the first adsorption unit 10, so that the second adsorption unit 20 performs desorption, and An adsorption unit 10 can perform adsorption. Similarly, when the second adsorption unit 20 performs the desorption, the refrigerant originally adsorbed into the adsorbent of the second adsorption bed 22 will be desorbed and flow into the second condenser 23. Since the second vacuum chamber 21 is in a high temperature and high pressure environment at this time, and the first vacuum chamber 11 is in a low temperature and low pressure state, the refrigerant desorbed from the second adsorption bed 22 may be The pressure difference between the two vacuum chambers 11, 21 is pushed into the first vacuum chamber 11. Therefore, the refrigerant flows out of the second refrigerant outlet 232 and passes through the second expansion valve 71 and the third check valve 72, and then flows into the second conduit 33 from the third end portion 331 of the second conduit 33, and along the The second line 33 flows in the shell and tube heat exchanger 30. Thereafter, the refrigerant flows out again from the fourth end portion 332 of the second line 33 to the fourth check valve 81, and then flows into the first vacuum chamber 11 from the first refrigerant inlet 131 via the fourth check valve 81. At the same time, the first adsorption unit 10 is also supplied with cooling water and adsorbed. Therefore, the refrigerant in the second line 33 is evaporated and absorbs heat, so that the temperature of the second line 33 can be lowered. The first adsorption unit 10 and the second adsorption unit 20 can continuously perform desorption and adsorption by continuously alternating hot water and cooling water into the first adsorption unit 10 and the second adsorption unit 20, and can The temperatures of the first line 32 and the second line 33 are kept at a low temperature without interruption. Therefore, when the ice water flows into the casing 31 from the ice water inlet 311 of the shell-and-tube heat exchanger 30, the cooling effect alternately generated by the pipe 32 and the second pipe 33 of the 11201202636 can be used to reduce the ice water. The temperature of the ice water after cooling can be discharged from the ice water outlet 312 and can be supplied to the air conditioning system. Thereby, the solid-state adsorption refrigeration system can be used for the uninterrupted cooling by the shell-and-tube heat exchanger 30, and since the shell-and-tube heat exchanger 30 does not need to be disposed in a vacuum environment, it can be removed from the vacuum chambers 11, 21 , thereby reducing the overall system manufacturing costs and reducing the overall system size. The embodiments are described to illustrate the features of the present invention, and the purpose of the present invention is to enable those skilled in the art to understand the present invention and to implement the present invention without limiting the scope of the present invention. Equivalent modifications or modifications made by the spirit of the disclosure should still be included in the scope of the claims described below. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing the structure of a separate solid adsorption refrigeration system according to an embodiment of the present invention. Fig. 2 and Fig. 3 are respectively schematic views showing the operation of a separate type solid adsorption refrigeration system according to an embodiment of the present invention. [Description of main component symbols] 100..............Separate solid adsorption refrigeration system 10 ........... First adsorption unit 11 ................The first vacuum chamber 12 ...........the first adsorption bed 121....... .......first water inlet 12 201202636 122..............first water outlet 13................ a condenser 131..............the first refrigerant inlet 132.............the first refrigerant outlet 20 ........ ........Second adsorption unit 21 ................Second vacuum chamber 22 ............... .Second adsorption bed 221 ..............second water inlet
222 ..............第二出水口 23 ................第二冷凝器 231 ..............第二冷媒入口 232 ..............第二冷媒出口 30 ................殼管式熱交換器 31 ................殼體 311 ..............冰水入口 312 ..............冰水出口 32 ................第一管路 321 ..............第一端部 322 ..............第二端部 33 ................第二管路 331 ..............第三端部 332 ..............第四端部 40................儲存槽 50................第一閥件組 201202636 51 ................第一膨脹閥 52 ................第一逆止閥 60 ................第二閥件組 61 ................第二逆止閥 70 ................第三閥件組 71 ................第二膨脹閥 72 ................第三逆止閥 80 ................第四閥件組 81 ................第四逆止閥 參 14222 ..............Second water outlet 23 ................Second condenser 231 ......... ..... second refrigerant inlet 232..............second refrigerant outlet 30 ........... shell-and-tube heat exchange 31 ........... housing 311 ..............ice water inlet 312 ........... ...ice water outlet 32 ................first line 321 ........... first end 322 ... ........... second end 33 ................ second line 331 ............. .Third end portion 332 . . ....... fourth end portion 40..............storage slot 50... .......... First valve member group 201202636 51 ................ First expansion valve 52 ............ ....first check valve 60 ................ second valve member group 61 ................ second Check valve 70 ........... third valve member set 71 ........... second expansion valve 72 ... .............The third check valve 80 ................the fourth valve member group 81 ......... .......fourth check valve reference 14