TW201111397A - Vinyl chloride-based resin emulsion, water-based ink and recording paper - Google Patents
Vinyl chloride-based resin emulsion, water-based ink and recording paper Download PDFInfo
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- TW201111397A TW201111397A TW099117931A TW99117931A TW201111397A TW 201111397 A TW201111397 A TW 201111397A TW 099117931 A TW099117931 A TW 099117931A TW 99117931 A TW99117931 A TW 99117931A TW 201111397 A TW201111397 A TW 201111397A
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- TW
- Taiwan
- Prior art keywords
- mass
- water
- vinyl chloride
- monomer
- recording paper
- Prior art date
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- 239000011347 resin Substances 0.000 title claims abstract description 57
- 229920005989 resin Polymers 0.000 title claims abstract description 57
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000000839 emulsion Substances 0.000 title claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 47
- 239000000178 monomer Substances 0.000 claims abstract description 48
- 239000000203 mixture Substances 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 12
- 239000004816 latex Substances 0.000 claims description 28
- 229920000126 latex Polymers 0.000 claims description 28
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 12
- 239000000049 pigment Substances 0.000 claims description 11
- 239000002250 absorbent Substances 0.000 claims description 9
- 230000002745 absorbent Effects 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 8
- 239000003086 colorant Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000976 ink Substances 0.000 description 49
- 238000007639 printing Methods 0.000 description 23
- -1 and the like Substances 0.000 description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 229920005692 JONCRYL® Polymers 0.000 description 15
- 239000010410 layer Substances 0.000 description 14
- 239000000523 sample Substances 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
- 239000000853 adhesive Substances 0.000 description 9
- 230000001070 adhesive effect Effects 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 238000009877 rendering Methods 0.000 description 9
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000007720 emulsion polymerization reaction Methods 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 230000035515 penetration Effects 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 3
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 239000012874 anionic emulsifier Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000001139 pH measurement Methods 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- XLYMOEINVGRTEX-ONEGZZNKSA-N (e)-4-ethoxy-4-oxobut-2-enoic acid Chemical compound CCOC(=O)\C=C\C(O)=O XLYMOEINVGRTEX-ONEGZZNKSA-N 0.000 description 1
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical group NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- HFCUBKYHMMPGBY-UHFFFAOYSA-N 2-methoxyethyl prop-2-enoate Chemical compound COCCOC(=O)C=C HFCUBKYHMMPGBY-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
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- JWTFTHRVRFLGSL-UHFFFAOYSA-N acetic acid;styrene Chemical compound CC(O)=O.C=CC1=CC=CC=C1 JWTFTHRVRFLGSL-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
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- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
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- 125000003277 amino group Chemical group 0.000 description 1
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- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
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- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
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- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
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- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
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- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
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- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
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- C08F214/08—Vinylidene chloride
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- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
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Description
201111397 六、發明說明: 【發明所屬之技術領域】 本發明係關於可有效地運用在油墨、塗料、無機物質 分散等之黏合劑、記錄用紙的吸收層,纖維的處理劑等之 氯化乙烯系樹脂乳膠。尤其關於當使用在水性油墨時,可 發揮較佳的耐水性、耐濕性、高光澤、耐醇性,當使用在 記錄用紙時,可發揮較佳的顯色性、耐水性、耐濕性、色 彩的觀看性、高光澤等之氯化乙烯系樹脂乳膠。 【先前技術】 首先探討凹版印刷油墨,一般的印刷中,係因印刷油 墨所具有之印刷適性與印刷效果來決定其優劣。所謂印刷 適性,爲關於印刷機上的油墨被轉印至被印刷物並形成印 刷面爲止之油墨的特性之性質,主要的特性有油墨的流動 性、界面適性、乾燥性等。另一方面,所謂印刷效果,爲 形成印刷面之油墨所顯示出之印刷的完成度,該特性有色 調、光澤、耐水性、耐結塊性等。油墨的基本組成,係由 色料(染料、顔料)、展色劑、輔助劑(流動性調整劑、 乾燥性調整劑等)所構成,當中,展色劑對印刷適性與印 刷效果會產生較大影響。展色劑的基本組成爲黏合劑、蠟 、溶劑等,因此,黏合劑的不同選擇會使展色劑的性質產 生大幅變化,並因此大幅地影響印刷適性與印刷效果之優 劣。 黏合劑可大致區分爲溶劑型黏合劑與水性黏合劑。溶 -5- 201111397 劑型黏合劑,可列舉出日本特開平9 - 1 2 9 5 6號公報(專利 文獻1)所提出之胺基甲酸酯樹脂。然而,近年來考量到 大氣污染、火災的危險性、作業衛生方面等,水性黏合劑 乃逐漸受到矚目。 水性黏合劑’可大致區分爲以苯乙烧.丙稀酸系爲代 表之鹼可溶性樹脂、以聚乙烯醇爲代表之水溶性樹脂以及 以胺基甲酸酯乳膠(專利文獻2:日本特開平2-238015號 公報)、丙烯酸系乳膠爲代表之水分散型樹脂。 —般而言,當使用以水分散型樹脂作爲黏合劑之水性 油墨進行印刷時,係在室溫下於印刷機上將油墨塗佈於被 印刷面,然後乾燥至水分散型樹脂的玻璃轉移溫度以上來 完成。當加溫至此般玻璃轉移溫度以上時,樹脂粒子彼此 會產生全體熔著,均一地覆膜化而顯現出耐水性並逐漸提 升。當著眼於印刷適性中之印刷機上的乾燥性時,印刷油 墨在印刷機上必須盡可能的長時間不會乾燥並保持流動性 ,溶劑型樹脂、鹼可溶性樹脂與水溶性樹脂,即使一旦乾 燥而覆膜化,亦可溶解於溶劑、鹼水溶液與水而回復原先 的流動性,故不會有問題,但是水分散型樹脂,當進行乾 燥使樹脂粒子彼此的表面產生熔著時,在水中亦無法回復 原先狀態,而有無法印刷之問題。另一方面,鹼可溶性樹 脂具有耐鹼性差之問題,水溶性樹脂具有耐水性差之問題 ,因此,以往的黏合劑有時會倂用鹼可溶性樹脂或水溶性 樹脂與水溶性樹脂來調製出,然而,現況仍是當欲改良印 刷適性時,耐鹼性與耐水性惡化,欲改良耐鹼性與耐水性 -6 - 201111397 時,印刷適性變得不足。 爲了解決此問題,日本特開平1 0- 1 76 1 32號公報(專 利文獻3 )中,係提出一種水性油墨用黏合劑,其係由: 選自氯化乙烯、烷基的碳數1~18之(甲基)丙烯酸烷酯類 及單烯基苯類之單體,及選自具有官能基之乙烯性不飽和 單體之單體,及其他乙烯性不飽和單體所構成。然而,就 耐濕性與光澤之觀點來看,仍具有問題。 此外,亦有提出氟樹脂者(專利文獻4 :日本特開平 1 1 -3 5 8 66號公報)。氟樹脂,在耐氣候性、耐腐蝕性等之 種種方面來看爲較佳,但仍存在有成本面的問題。 接著探討噴墨用油墨。噴墨記錄方式,其靜肅性、記 錄速度、列印品質、學習成本較佳,故廣泛地普及。此方 式所用之油墨,就油墨物性、安全性、處理容易度等觀點 來看,係使用水性油墨。此般油墨,爲人所知者有將酸性 染料、直接染料、鹼基性染料等之水溶性染料溶解於二醇 系溶劑與水者(專利文獻5〜7 :日本特開昭5 3 - 6 1 4 1 2號公 報、日本特開昭54-89811號公報、日本特開昭55-65269號 公報),但仍有耐水性差之缺點。 因此’亦有探討使用顔料作爲著色成分者,爲了分散 顏料,係使用導入有羧基之丙烯酸系樹脂與苯乙烯.丙烯 酸酯等(專利文獻8 :日本特開昭61_23 547 8號公報),或 是由丙烯酸、苯乙烯、α甲基苯乙烯所構成之三元共聚物 水性樹脂(專利文獻9 :日本特開平8 - 2 5 3 7 1 6號公報)。 然而,雖然可看到耐水性與耐氣候性的提升,但就顏料分 201111397 散性(隨時間之變化)之觀點來看,仍有改善的空間。 接著探討記錄用紙的吸收層,尤其是噴墨記錄用紙。 近年來’個人電腦等之OA機器用的印表機中,使用水性 油墨之記錄方式之比率逐年提高,對記錄材料的需求亦隨 之擴大’另一方面,爲了更進一步改良列印品質、色彩度 、外觀、圖像,係逐漸要求具有更優良特性之記錄材料。 該使用用途亦逐漸多樣化,使得耐水性、顯色性等之要求 特性更加嚴苛。此般吸收層,係有人提出將非晶質二氧化 矽與聚乙烯醇等之黏結劑調配並塗佈於基礎紙之記錄薄片 (專利文獻10 :日本特開昭55-5 1 5 83號公報),或是將含 有多孔質顏料粒子之油墨吸收層設置在基礎紙的表內面之 記錄薄片(專利文獻11:日本特開昭56-148584號公報) 。與以往使用上等紙張之記錄薄片相比,雖可大幅地提升 色彩鮮豔度,但當塗佈量較少時,油墨會不規則地擴散, 導致列印的滲透量增大,當增加塗佈量時,雖然滲透量較 少,但有塗佈層剝離而產生粉體脫落之問題。 此外,係有人提出一種使用使聚乙烯醇與丙烯酸與甲 基丙烯酸甲酯反應所得之水不溶性樹脂,來改善黏結強度 之記錄薄片(專利文獻12:日本特開昭62-288076號公報 ),但由於水不溶性樹脂爲陰離子性,所以與同爲陰離子 性之水性油墨的固定性差,至今仍未解決油墨的滲出或耐 水性的提升。 再者,亦有人提出含有聚陽離子高分子電解質之記錄 薄片(專利文獻13 :日本特開昭56-84992號公報)與設置 -8- 201111397 有以具有油墨吸附性之陽離子性高分子黏結劑爲主成分之 吸收層之記錄薄片(專利文獻14 :日本特開昭5 8-24493號 公報)’以及含有陽離子性丙烯酸樹脂乳膠之記錄薄片( 專利文獻1 5、1 6 :日本特開平1 1 _ 1 2 3 8 6 7號公報、日本特 開2 0 0 1 - 1 9 9 1 5 2號公報),但就顯色性與耐水性之觀點來 看,並不令人滿意。 〔先前技術文獻〕 〔專利文獻〕 〔專利文獻1〕日本特開平9 - 1 2 9 5 6號公報 〔專利文獻2〕日本特開平2-23 80 1 5號公報 〔專利文獻3〕日本特開平ι〇_ 1 76 1 3 2號公報 〔專利文獻4〕日本特開平U_3 5866號公報 〔專利文獻5〕日本特開昭53_61412號公報 〔專利文獻6〕曰本特開昭5 4 _ 8 9 8丨丨號公報 〔專利文獻7〕日本特開昭55_6 5269號公報 〔專利文獻8〕日本特開昭61—235478號公報 〔專利文獻9〕日本特開平8_253716號公報 〔專利文獻10〕日本特開昭55_51583號公報 〔專利文獻1 1〕日本特開昭5 6 - 1 4 8 5 8 4號公報 〔專利文獻12〕日本特開昭62-288076號公報 〔專利文獻I3〕日本特開昭56_84992號公報 〔專利文獻14〕日本特開昭58_24493號公報 〔專利文獻丨5〕日本特開平n_123867號公報 〔專利文獻16〕日本特開2〇〇卜199152號公報 201111397 【發明內容】 (發明所欲解決之課題) 本發明係鑒於上述情形而創作出之發明,其目的係提 供一種當使用在水性油墨時,可發揮較佳的耐水性、耐濕 性、高光澤、耐醇性,當使用在記錄用紙時,可發揮較佳 的顯色性、耐水性、耐濕性、色彩的觀看性、高光澤等, 可有效地運用在油墨、塗料、無機物質分散等之黏合劑、 記錄用紙的吸收層,纖維的處理劑等之氯化乙烯系樹脂乳 膠。 (用以解決課題之手段). 本發明者們係爲了達成上述目的而進行精心探討,結 果發現到,藉由將(A)數量平均分子量爲500 0〜50000之 苯乙烯·丙烯酸酯低聚物及/或丙烯酸酯低聚物,在相對 於含有(B)氯化乙烯單體、或是(B)氯化乙烯單體及可 與其共聚合之(C)含乙烯性不飽和基的單體之單體組成 物100質量份而言爲40〜5 00質量份的存在下進行乳化聚合 所得之氯化乙烯系樹脂乳膠,能夠克服前述課題,因而完 成本發明。 因此,本發明係提供下列發明。 申請專利範圍第1項: —種氯化乙烯系樹脂乳膠,其係將(A)數量平均分 子量爲5000〜50000之苯乙烯·丙烯酸酯低聚物及/或丙烯 -10- 201111397 酸酯低聚物,在相對於含有(B)氯化乙烯單體、或是(B )氯化乙烯單體及可與其共聚合之(C)含乙烯性不飽和 基的單體之單體組成物1〇〇質量份而言爲4〇〜500質量份的 存在下,進行乳化聚合而得。 申I靑專利範圍第2項: 如申請專利範圍第1項之氯化乙烯系樹脂乳膠,其中 (B)成分與(C)成分之比率以質量比計爲50: 50〜100: 0 ° 申請專利範圍第3項: 一種水性油墨,其係含有申請專利範圍第1或2項之氯 化乙烯系樹脂乳膠。 申請專利範圍第4項: 如申請專利範圍第3項之水性油墨,其中氯化乙烯系 樹脂乳膠的含量以固形份計爲2〜3 0質量%,且尙含有著色 劑3〜40質量%,水可溶性有機溶劑〇〜50質量%,以及水 5~95質量%而成。 申請專利範圍第5項: 一種記錄用紙,其係具有申請專利範圍第1或2項之氣 化乙烯系樹脂乳膠的塗膜。 申請專利範圍第6項: 如申請專利範圍第5項之記錄用紙,其中上述塗膜係 形成吸收層。 申請專利範圍第7項: 如申請專利範圍第5或6項之記錄用紙,其中上述塗膜 -11 - 201111397 係含有氯化乙烯系樹脂乳膠的固形份2〜3 0質量%,且以尙 含有顔料0〜3 0質量%、剩餘部分爲水或水可溶性有機溶劑 之組成物所形成。 發明之效果: 本發明之氯化乙烯系樹脂乳膠,當使用在水性油墨時 ’可發揮較佳的耐水性、耐濕性、高光澤、耐醇性,當使 用在記錄用紙時,可發揮較佳的顯色性、耐水性、耐濕性 、色彩的觀看性、高光澤等,可有效地運用在油墨、塗料 、無機物質分散等之黏合劑、記錄用紙的吸收層,纖維的 處理劑等。 【實施方式】 本發明之氯化乙烯系水性油墨用黏合劑,爲將(A ) 數量平均分子量爲5000-5 0000之苯乙烯·丙烯酸酯低聚物 及/或丙烯酸酯低聚物,在相對於含有(B)氯化乙烯單體 、或是(B)氯化乙烯單體及可與其共聚合之(C)含乙烯 性不飽和基的單體之單體組成物100質量份而言爲40~5 00 質量份的存在下,進行乳化聚合而得之氯化乙烯系樹脂乳 膠。 (A)苯乙烯·丙烯酸酯低聚物、丙烯酸酯低聚物中 所使用之丙烯酸酯單體,可列舉出甲基(丙烯酸)甲酯、 甲基(丙烯酸)乙酯、甲基(丙烯酸)丁酯等。甲基(丙 烯酸)爲丙烯酸與甲基丙烯酸之總稱。市售品可列舉出 -12- 201111397 JONCRYL JDX-6500、JONCRYL JDX-61 02B、JONCRYL HPD-96J ' JONCRYL 52J (均爲BASF公司製)等,但並不 限定於此,可使用1種或2種以上。該用量,相對於含有( B)氯化乙烯單體、或是(B)氯化乙烯單體及可與其共聚 合之(C )含乙烯性不飽和基的單體之單體組成物1 00質量 份而言,較佳爲含有40~5 00質量份,更佳爲含有100〜300 質量份。當.未達40質量份時,可能有產生凝聚物之缺失, 當超過5 00質量份時,反應呈非活化,可能有產生無法安 定生產之缺失。 (A)苯乙烯·丙烯酸酯低聚物、丙烯酸酯低聚物的 數量平均分子量,較佳爲5000〜50000,更佳爲8000〜20000 。當分子量未達5 000時,可能有產生凝聚物之缺失,當超 過5 0000時,凝聚物多量地產生,最差的情況可能會產生 膠體化之缺失。數量平均分子量,爲經以GPC所測定之聚 苯乙烯的換算値,本發明中,係將5 0000以下者稱爲低聚 物。 此外,(C)可與氯化乙烯單體共聚合之含乙烯性不 飽和基的單體,除了乙酸乙烯酯、乙烯、丙烯、偏二氯化 乙烯之外,可列舉出丙酸乙烯酯等之羧酸乙烯酯單體類; 苯乙烯、α-甲基苯乙烯等之芳香族乙烯單體類;1,3-丁二 烯、2-甲基-1,3-丁二烯等之共軛二烯系單體類;丙烯酸甲 酯、丙烯酸乙酯、丙烯酸丁酯、丙烯酸2-乙基己酯、甲基 丙烯酸甲酯等之乙烯性不飽和單羧酸酯類;衣康酸二甲酯 、馬來酸二甲酯、馬來酸單丁酯、富馬酸單乙酯、富馬酸 -13- 201111397 二丁酯等之乙烯性不飽和聚羧酸酯類;丙烯酸、甲基丙烯 酸、巴豆酸等之乙烯性不飽和單羧酸類;衣康酸、馬來酸 、富馬酸等之乙烯性不飽和二羧酸類;甲基丙烯酸縮水甘 油酯等之含環氧基的單體類;甲基丙烯酸2-羥乙酯等之含 醇性羥基的單體類;丙烯酸甲氧基乙酯等之含烷氧基的單 體類;丙烯腈等之含腈基的單體類:丙烯醯胺等之含醯胺 基的單體類;甲基丙烯酸二甲基胺乙酯等之含胺基的單體 類;二乙烯苯、甲基丙烯酸烯丙酯等之於1分子中具有2個 以上的乙烯性不飽和基之單體,當中可選擇1種或2種以上 ,較佳爲乙酸乙烯酯、乙烯性不飽和單羧酸酯類、乙烯性 不飽和單羧酸類。 此時,(B)氯化乙烯單體及可與其共聚合之(C)含 乙烯性不飽和基的單體之比率,以質量比計爲50 : 50〜100 :〇,特佳爲70: 3 0〜100: 0。當氯化乙烯量過少時,可能 會有凝聚物產生之缺失。 上述乳化聚合,可採用一般所知的所有乳化聚合法。 可在最初即整體地添加單體及其他聚合助劑(例如烷基硫 酸酯鹽等之乳化劑、過硫酸銨等之聚合起始劑、硫醇等之 連鎖轉移劑、碳酸鈉等之pH調整劑、各種消泡劑及其他) ,或是連續地添加,或是在聚合中連續地或分批地添加其 一部分。 此外,在不損及本發明之效果的範圍內,亦可倂用非 離子系界面活性劑與陰離子系乳化劑。例如有聚氧乙烯院 基苯醚、聚氧乙烯烷醚、聚氧乙烯脂肪酸酯、山梨醇酐脂 -14- 201111397 肪酸酯、聚氧乙烯山梨醇酐脂肪酸酯、聚氧化伸 、聚氧乙烯衍生物、甘油脂肪酸酯、聚氧乙烯硬 、聚氧乙烯烷基胺、烷基烷醇醯胺、或乙炔醇、 及此等之環氧乙烷加成物等之界面活性劑。 上述乳化聚合中所用之聚合起始劑,可列舉 、過硫酸鉀等之過硫酸鹽,2,2’-二眯-2,2’-偶氮 酸鹽、偶氮雙異丁腈等之偶氮化合物,異丙苯基 、苯甲基過氧化氫、過氧化氫等之過氧化物,酒 此外,亦可一般所知的還原氧化系起始劑,例如 與亞硫酸氫鈉等。聚合起始劑的用量,相對於上 言通常爲0.1〜2.0質量%,較佳爲0.2〜1.0質量。/。。 進行上述乳化聚合之聚合溫度,通常爲40~ 佳爲50〜7〇°C。聚合時間可適當地設定,較佳爲1 。此聚合較佳係在氮氣等之非活性氣體的環境中 蒸發殘留份較佳爲10~50質量%,更佳爲20. 。當未達1 0質量%時,可能會產生凝聚物,當超 %時,可能會大量地產生凝聚物。 聚合結束後,在不損及本發明之水性油墨用 性能之範圍內,亦可添加可塑劑、無機或有機塡 黏劑等。 可獲得乳膠的平均粒徑爲10〜lOOOnm 20〜800nm,黏度爲5〜1800mPa. s者。 本發明之樹脂乳膠,可使用在種種用途中, 用在記錄用紙時,可發揮較佳的顯色性、耐水性 院基i完醒 化蓖麻油 乙炔二醇 過硫酸銨 丙烷二鹽 過氧化氫 石酸等。 過硫酸鉀 述單體而 8 0 °C ,較 0~1 5小時 進行。 ~40質量% 過5 0質量 黏合劑的 充劑、增 ,較佳爲 尤其當使 、耐濕性 -15- 201111397 、高光澤等,當使用在水性油墨時,可賦予較佳的耐水性 、耐濕性、色彩的觀看性、高光澤、較佳的耐醇性。 此時,當將本發明之氯化乙烯系樹脂乳膠使用在水性 油墨時,可將著色劑、水可溶性有機溶劑、各種添加劑、 水等調配於此氯化乙烯系樹脂乳膠,並藉由一般所知的分 散機、混合機、捏合機等予以分散、混合而製造出。氯化 乙烯系樹脂乳膠在水性油墨中之含量,以固形份計爲2〜3 0 質量%,特佳爲5~20質量%。著色劑可使用染料、顏料等 ,在水性油墨中可含有3〜40質量%,特佳爲5〜30質量%。 水可溶性有機溶劑,可使用乙二醇單醚、二乙二醇單醚、 丙二醇單醚、乙二醇二甲醚、二乙二醇二甲醚、乙二醇、 二乙二醇、丙二醇、甘油、甲醇、乙醇、異丙醇、丁酮、 甲基溶纖劑、乙基溶纖劑、丙酮、乙酸乙酯、二丙酮醇等 ’在水性油墨中可含有0〜60質量%,特佳爲〇~50質量% » 水在水性油墨中可含有5~95質量%,特佳爲1〇〜90質量%。 添加劑可列舉出顏料分散劑、平坦劑、消泡劑等,此等添 加劑,在水性油墨中可以常用量來使用。 此外’當將本發明之氯化乙烯系樹脂乳膠使用在記錄 用紙時’可適當地使用在記錄用紙之吸收層的形成。可將 顏料、水可溶性有機溶劑、各種添加劑、水等調配於此氯 化乙烯系樹脂乳膠’並藉由一般所知的分散機、混合機、 捏合機等予以分散' 混合而製造出。此時,含有吸收層的 形成中所用之氯化乙烯系樹脂乳膠之吸收層形成用組成物 中’係含有2〜3 0質量%之氯化乙烯系樹脂乳膠的固形份, -16- 201111397 特佳爲5~20質量%。此外,顏料可調配非晶質合成二氧化 砂、砂酸銘、砂酸鎂、丨几降性碳酸耗、重碳酸銘、砂酸耗 、氫氧化鋁、沸石、燒結土、高嶺土、滑石、白碳等。此 等成分的調配量爲0〜30質量%,特佳爲〇〜20質量%。水可 溶性有機溶劑,可使用乙二醇單醚、二乙二醇單醚、丙二 醇單醚、乙二醇二甲醚、二乙二醇二甲醚、乙二醇、二乙 二醇、丙二醇、甘油、甲醇、乙醇、異丙醇、丁酮、甲基 溶纖劑、乙基溶纖劑、丙酮 '乙酸乙酯、二丙酮醇等,在 水性油墨中可含有0〜60質量%,特佳爲〇〜5〇質量%。水在 水性油墨中可含有5~98質量%,特佳爲1 〇〜90質量%。其他 添加劑可列舉出顏料分散劑、消泡劑、著色劑、抗氧化劑 、紫外線吸收劑、黏度調整劑、脫模劑等。 上述吸收層形成用組成物,可刷毛塗佈於市售的紙等 之支撐體,並藉由板片塗佈機、空氣刀塗佈機、淋幕式塗 佈機、繞線塗佈機、凹版塗佈機、輥塗佈機等之塗佈方式 ,以塗佈量成爲0.5〜25 g/m2 (乾燥聚合固形份),較佳爲 1〜10 g/m2之方式,塗佈並乾燥而製造出。 〔實施例〕 以下係顯示出製造例與實施例及比較例’來具體地說 明本發明,但本發明並不限定於下列實施例。下列例子中 ’份及%分別表示質量份、質量%。 〔實施例1〕
S -17- 201111397 於具備攪拌機、冷凝器、溫度計及氮氣導入口之聚合 容器中,進行氮氣取代後,裝入脫離子水33份、氯化乙烯 15份、JONCRYL JDX-6500 (BASF公司製丙烯酸低聚物) 50質量份(有效成分30% ),一邊攪拌一邊加溫至60°C。 再將過硫酸銨(起始劑)0.1份溶解於脫離子水1份並添加 至此以進行聚合反應。 在聚合內壓成爲OMP a之時點,在真空中將殘存單體去 除至100Oppm爲止,然後冷卻至40°C以下而得聚合物。爲 固形份30%、ρΗ7·5、B型黏度計黏度(23°C ) lOmPa _ s。 第1表係顯示該結果。可藉由GPC來測定出所得之乳膠爲 氯化乙烯樹脂者。 〔實施例2〜7,比較例1〜7〕 以第1表、第2表所示之組成,與實施例1相同來實施 聚合,而得氯化乙烯系樹脂乳膠。 〔評估方法〕 <固形份測定方法> 將氯化乙烯系樹脂乳膠約lg量取至鋁箔製的皿,放入 於保持在105〜1 10°C之乾燥器中進行1小時的加熱後,從乾 燥器中取出’並在乾燥皿中放置冷卻。量秤試樣於乾燥後 的重量,並藉由下列式計算出固形份。 在此,R :固形份(% ) -18- 201111397 w _裝入乾燥則的試樣之鋁箔皿的質量(g) A :鋁箔皿的質量(g ) D·裝入乾燥後的試樣之鋁箔皿的質量(g) 銘范皿的尺寸:70φ · 〇2h) < pH測定方法> 依據JIS Z8 8 02 ( pH測定方法),使用pH計直接測定 氯化乙烯系樹脂乳膠。 < B型黏度計黏度測定方法> 將氯化乙稀系樹脂乳膠的液溫保持在2 3 ± 〇 5 〇c,並藉 由BM型黏度計(No. Rotor,6rpm)進行測定。 <平均粒徑> 使用光散射型粒徑測定裝置進行測定。 樣本調製 1 .將樣本採集至取樣杯,以25。(:的純水稀釋。 2.以3 00網目的濾布過濾經稀釋的樣本。 測定液溫 2 5 t 積算次數 100次 測定次數 1次 測定 確認出適當濃度,並以上述測定條件進行測定。 -19- 201111397 可確認出測定結果良好。 <聚合安定性> 以6厘的板片將氯化乙烯系樹脂乳膠塗佈於玻璃板上 ,並以目視方式確認是否產生凝聚物。 〇:無法確認到凝聚物 X :產生凝聚物 I.作爲凹版印刷油墨之性能評估 將氯化乙烯系樹脂乳膠的含量以固形份計設定爲20% ,並混合5%的DISPERS RED SD-1011以及75%的水,將此 構成爲試樣A。 將試樣A設置在桌上型印刷機(GRAVO-PROOF CM, 日商Gravure公司製),將印刷輥旋轉1圏並印刷至市售的 紙上。 a.耐水性 將印刷後的紙設置在學振形染色摩擦堅牢度試驗機( 安田精機製作所公司製),使用經水潤濕後的棉紗,實施 25次的摩擦試驗,並依循下列基準來判定。 〇:未產生對棉紗之色移 △:觀察到色移 X :完全地色移,印刷面的色彩脫落 -20- 201111397 b. 耐濕性 在5 0°C、濕度90%下將印刷後的紙靜置1天,並依循下 列基準來判定。 〇:印刷部位無滲透 △:觀察到印刷部位少量滲透 X :完全滲透 c. 光澤 藉由光澤計(日本電色工業公司製)來測定印刷後的 部位,讀取60°之値,並依循下列基準來判定。 〇:光澤値爲90以上 △:光澤値爲70以上且未達90 X :光澤値未達7 0 d. 耐醇性 將印刷後的紙設置在學振形染色摩擦堅牢度試驗機( 安田精機製作所公司製),使用經乙醇潤濕後的棉紗’實 施25次的摩擦試驗,並依循下列基準來判定。 〇:未產生對棉紗之色移 △:觀察到色移 X :完全地色移,印刷面的色彩脫落 11.作爲噴墨用油墨之性能評估 〔油墨的調製〕 -21 - 201111397 將氯化乙烯系樹脂乳膠的含量以固形份計設定爲2 0 % ,並混合20%的碳黑ΜΑ1 00 (三菱製紙公司製)以及60% 的水,將此構成爲試樣Β。 e. 色調 藉由棒塗佈機No .4 ’以乾燥重量成爲4g/m2之方式將 調製後的試樣B塗佈於市售的紙上,在40 °C下乾燥30秒。 依循下列基準,以目視方式來判定所得之塗佈紙與調製後 之試樣的外觀。 〇:色調爲同等 △:黑色濃度不足 X :色調產生變化 f. 密著性 藉由棒塗佈機N0.4,以乾燥重量成爲4g/m2之方式將 調製後的試樣B塗佈於軟質氯化乙烯薄膜· Super Film Non-Tack ( Okamoto公司製)上,在40 °C下乾燥30秒。將 玻璃紙(Nichiban公司製,註冊商標)貼著於所得之塗佈 品後予以剝離,並依循下列基準來判定。 〇:無剝離 △:有一部分剝離 X :完全剝離 g. 分散性(隨時間之安定性) 在常溫下將調製後的試樣B放置1星期,依循下列基準 -22- 201111397 ,以目視方式來判定隨時間之沉降。 〇:無沉降 △:雖產生沉降但可進行再攪拌 X ‘·產生沉降無法復原 III.作爲記錄用紙的吸收層之性能評估 [吸收層的調製] 藉由棒塗佈機No _ 1 2 3 4,將各氯化乙烯系樹脂乳膠’缱佈 於市售的紙上,在40 °C下乾燥30秒而構成試樣C ° h. 顯色性 藉由EPSON PM- 800C將黃、靛、洋紅3色印刷於試樣c ,依循下列基準,以目視方式來判定各色的色濃度。 〇:無脫色且可鮮明地印刷 △:有一部分脫色 X :有脫色且褪色 -23- 1 油墨的吸收性 2 將印刷後的紙設置在學振形染色摩擦堅牢度試驗機( 安田精機製作所公司製)’使用經水潤濕後的棉紗,實施 2 5次的摩擦試驗,並依循下列基準來判定。 3 〇:未產生對棉紗之色移 △:觀察到色移 4 X :完全地色移,印刷面的色彩脫落 201111397 j.耐濕性 在5 0°C、濕度90%下將前述印刷後的紙靜置1天,依循 下列基準,以目視方式來判定。 〇:印刷部位無滲透 △:觀察到印刷部位少量滲透 X :完全滲透 -24- 201111397 【第1表】 成分(質量份) 實施例 1 實施例 2 實施例 3 實施例 4 實施例 5 實施例 6 實:施例 7 ㈧ JONCRYL JDX-6500 50 100 300 100 100 100 JONCRYL JDX-6102B JONCRYL HPD-96J 100 JONCRYL 52J (B) 氯化乙烯 100 100 100 100 80 80 75 (C) 乙酸乙烯酯 20 丙烯酸乙酯 20 20 丙烯酸 5 水溶性 高分子 PVA-117 PVA-617 乳化劑 NOIGEN XL-6190 PELEX SS-L 固形份(%) 30 30 30 30 30 30 30 pH 7.5 7.5 7.5 7.5 6.5 7.5 4.5 黏度(mPa · s) 10 10 10 300 1000 500 1500 平均粒徑(nm) 80 30 30 150 400 300 600 III的塗佈量(g/m2) 3.4 3.3 3.7 3.3 4.0 3.4 3.0 聚合安定性 〇 〇 〇 〇 〇 〇 〇 性 能 評 估 I a.耐水性 〇 〇 〇 〇 〇 〇 〇 b.耐濕性 〇 〇 〇 〇 〇 〇 〇 C.光澤 〇 〇 〇 〇 〇 〇 〇 d.耐醇性 〇 〇 Δ Δ Δ Δ △ II e.色調 〇 〇 〇 〇 〇 〇 〇 f.密著性 〇 〇 Δ 〇 〇 Δ △ g.分散性(隨時間之 安定性) 〇 〇 〇 〇 〇 〇 〇 III h.顯色性 〇 〇 Δ 〇 〇 Δ △ i.油墨的吸收性(耐 水性) 〇 〇 〇 Δ Δ 〇 〇 j.油墨的吸收性(耐 濕性) 〇 〇 〇 〇 〇 〇 〇
C -25- 201111397 【第2表】
成分(質量份) 比較例 1 比較例 2 比較例 3 比較例 4 比較例 5 比較例 6 比較例 7 ㈧ JONCRYL JDX-6500 30 525 JONCRYL JDX-6102B 100 JONCRYL HPD-96J JONCRYL 52J 100 (B) 氯化乙烯 100 100 100 100 75 100 100 (C) 乙酸乙烯酯 丙烯酸乙酯 20 丙烯酸 5 水溶性 高分子 PVA-117 10 PVA-617 10 乳化劑 NOIGENXL-6190 3 PELEX SS-L 3 固形份(%) 29 28 30 30 30 25 26 pH 7.5 7.5 6.5 6.5 5 7.5 7.5 黏度(mPa · s) 10 50 2000 3000 100 10 300 平均粒徑(nm) 500 30 500 600 250 150 200 III的塗佈量(g/m2) 3.2 3.4 3.5 3.3 3.2 3.7 3.4 聚合安定性 X X 〇 〇 〇 X X 性 能 評 估 I a.耐水性 Δ Δ Δ Δ X X Δ b.耐濕性 Δ Δ Δ Δ X Δ Δ C.光澤 X Δ X X X Δ X d.耐醇性 Δ X Δ Δ Δ X Δ II e_色調 X X X X X Δ Δ f.密著性 X X X X X X X g.分散性(隨時間 之安定性) X Δ X X △ X X III h.顯色性 Δ X Δ Δ Δ Δ Δ i.油墨的吸收性( 耐水性) Δ Δ Δ Δ X X X j.油墨的吸收性( 耐濕性) Δ Δ Δ Δ X X X -26- 201111397 JONCRYL JDX-6 500 : B ASF公司製丙烯酸低聚物,數 量平均分子量1 〇〇〇〇 JONCRYL JDX-6102B : BASF公司製丙烯酸低聚物, 數量平均分子量60000 JONCRYL HPD-96J : B A S F公司製苯乙烯丙烯酸低聚 物,數量平均分子量1 6500 JONCRYL 52J: BASF公司製苯乙烯丙綠酸低聚物,數 量平均分子量1700 ?乂八-117:1<:11^^丫公司製,鹼化度985,聚合度17〇〇 PVA-617 : Kuraray公司製,鹼化度95.〇,聚合度17〇〇 NOIGEN XL-6190:第一工業製藥公司製,非離子系 乳化劑 PELEX SS-L :花王公司製,陰離子系乳化劑 -27-
Claims (1)
- 201111397 七、申請專利範圍: 1. 一種氯化乙烯系樹脂乳膠,其係將(A)數量平均 分子量爲5000-50000之苯乙烯·丙烯酸酯低聚物及/或丙 烯酸酯低聚物,在相對於含有(B)氯化乙烯單體、或是 (B)氯化乙烯單體及可與其共聚合之(C)含乙烯性不飽 和基的單體之單體組成物1〇〇質量份而言爲40〜500質量份 的存在下,進行乳化聚合而得。 2. 如申請專利範圍第1項之氯化乙烯系樹脂乳膠,其 中(B)成分與(C)成分之比率以質量比計爲5〇: 50〜100 :0 ° 3 . —種水性油墨,其係含有申請專利範圍第1或2項 之氯化乙烯系樹脂乳膠。 4. 如申請專利範圍第3項之水性油墨’其中氯化乙烯 系樹脂乳膠的含量以固形份計爲2〜3 0質量%,且尙含有著 色劑3~40質量%,水可溶性有機溶劑〇~60質量%,以及水 5〜95質量%而成。 5. 一種記錄用紙,其係具有申請專利範圍第1或2項 之氯化乙烯系樹脂乳膠的塗膜。 6. 如申請專利範圍第5項之記錄用紙’其中上述塗膜 係形成吸收層》 7. 如申請專利範圍第5或ό項之記錄用紙,其中上 述塗膜係含有氯化乙烯系樹脂乳膠的固形份2~3 〇質量%, 且以尙含有顏料0〜3 0質量%、剩餘部分爲水或水可溶性有 機溶劑之組成物所形成。 -28- 201111397 四 指定代表圖: (一) 本案指定代表圖為:無 (二) 本代表圖之元件符號簡單說明:無 201111397 五 本案若有化學式時,請揭示最能顯示發明特徵的化學 式:無
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI758421B (zh) * | 2017-02-23 | 2022-03-21 | 日商日信化學工業股份有限公司 | 活性光線硬化型組成物、活性光線硬化型塗料組成物、及此等之製造方法 |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103443153B (zh) * | 2011-03-18 | 2015-12-09 | 日信化学工业株式会社 | 氯乙烯系树脂乳液及其制造方法以及水性墨和记录用纸 |
WO2013179839A1 (ja) * | 2012-05-30 | 2013-12-05 | Dic株式会社 | 水性インクジェット記録用インクおよび積層体の製造方法 |
JP6071826B2 (ja) | 2012-10-05 | 2017-02-01 | 花王株式会社 | 電子写真用トナーの製造方法 |
JP6034688B2 (ja) * | 2012-12-14 | 2016-11-30 | 花王株式会社 | 電子写真用トナー |
US8895658B2 (en) | 2012-12-18 | 2014-11-25 | Columbia Insurance Company | Grafted pigment dispersing polymeric additive and paint employing the same with improved hiding |
FR3001733B1 (fr) * | 2013-02-01 | 2015-03-20 | Markem Imaje | Composition d'encre pour l'impression par jet de liquide. |
KR102148528B1 (ko) | 2013-02-07 | 2020-08-26 | 닛신 가가꾸 고교 가부시끼가이샤 | 폴리머 코어 셸 구조를 가진 양이온성 에멀션, 수성 잉크 및 기록매체 |
JP6523950B2 (ja) * | 2013-05-22 | 2019-06-05 | 積水化学工業株式会社 | 塩化ビニル系共重合体、塩化ビニル系樹脂組成物及び成形体 |
BR112016011861B1 (pt) * | 2013-11-28 | 2021-10-13 | Hanwha Chemical Corporation | Método para preparar resina a base de cloreto de vinila |
KR20160146825A (ko) | 2014-04-15 | 2016-12-21 | 허니웰 인터내셔널 인코포레이티드 | 고성능 수계 접착 조성물 및 어플리케이션 |
CN104140713A (zh) * | 2014-08-05 | 2014-11-12 | 厦门格林泰新材料科技有限公司 | 一种水性油墨及其制备方法与应用 |
CN105111349B (zh) * | 2015-08-19 | 2017-08-11 | 江苏科技大学 | 一种含有非离子乳化剂的三元共聚物乳液及其制备方法 |
KR101729299B1 (ko) * | 2015-12-09 | 2017-04-21 | 한화케미칼 주식회사 | 염화비닐계 수지 조성물 및 그 제조 방법 |
EP3466707B1 (en) | 2016-06-01 | 2022-08-10 | Kao Corporation | Inkjet recording method |
JP6874154B2 (ja) * | 2017-04-28 | 2021-05-19 | ハンワ ソリューションズ コーポレイションHanwha Solutions Corporation | 塩化ビニル系樹脂ラテックス組成物およびその製造方法 |
CN107886549B (zh) * | 2017-10-18 | 2021-07-30 | 浙江工业大学之江学院 | 一种基于编织纹理细节增强的织物纹样色彩转移方法 |
US20200332135A1 (en) | 2017-12-28 | 2020-10-22 | Kao Corporation | Aqueous pigment dispersion |
CN109535825A (zh) * | 2018-11-09 | 2019-03-29 | 镇江恒昌彩艺科技有限公司 | 一种用于pvc凹版的水性油墨组合物 |
TWI836004B (zh) * | 2019-02-15 | 2024-03-21 | 日商日信化學工業股份有限公司 | 氯乙烯系樹脂乳液、水性墨水及記錄用紙 |
CN112549803A (zh) * | 2020-11-25 | 2021-03-26 | 无锡市华美达印刷有限公司 | 一种凹版印刷方法 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5274406A (en) | 1975-12-05 | 1977-06-22 | Dainippon Toryo Kk | Ink for ink jet recording |
JPS5361412A (en) | 1976-11-12 | 1978-06-01 | Matsushita Electric Ind Co Ltd | Ink jet recording ink |
JPS5489811A (en) | 1977-12-27 | 1979-07-17 | Toyo Ink Mfg Co | Color jet printing method |
JPS5551583A (en) | 1978-10-09 | 1980-04-15 | Ricoh Co Ltd | Ink-jet recording paper |
JPS5565269A (en) | 1978-11-10 | 1980-05-16 | Seiko Epson Corp | Quick drying ink for ink jet recording |
JPS5684992A (en) | 1979-12-15 | 1981-07-10 | Ricoh Co Ltd | Ink jet recording method |
JPS56148584A (en) | 1980-04-21 | 1981-11-18 | Canon Inc | Recording material |
US4517244A (en) * | 1981-08-06 | 1985-05-14 | Canon Kabushiki Kaisha | Recording medium and ink jet recording paper |
JPS5824493A (ja) | 1981-08-06 | 1983-02-14 | Canon Inc | 記録材 |
JPS61235478A (ja) | 1985-04-11 | 1986-10-20 | Dainichi Seika Kogyo Kk | 筆記および記録用水性顔料インキ組成物 |
US4647612A (en) * | 1985-12-30 | 1987-03-03 | Ppg Industries, Inc. | Polymer emulsion products |
JPS62288076A (ja) | 1986-06-06 | 1987-12-14 | Honshu Paper Co Ltd | インクジエツト記録用シ−ト |
DE3837519A1 (de) | 1988-11-04 | 1990-05-10 | Basf Lacke & Farben | Lagerstabile vernetzbare waessrige polyurethandispersionen |
JPH04335039A (ja) * | 1991-05-10 | 1992-11-24 | Nippon Oil & Fats Co Ltd | ブローボトル |
GB9316221D0 (en) * | 1993-08-05 | 1993-09-22 | Zeneca Ltd | Production of polymer emulsions |
JP3453586B2 (ja) * | 1993-11-04 | 2003-10-06 | 一方社油脂工業株式会社 | 耐光性ラテックス組成物およびラテックスから製造される製品の耐光性改良方法 |
US5981642A (en) * | 1994-12-21 | 1999-11-09 | Zeneca Limited | Method of grafting |
JP3499953B2 (ja) | 1995-03-17 | 2004-02-23 | 東洋インキ製造株式会社 | インクジェット用インキおよびその製造方法 |
JPH0912956A (ja) | 1995-04-28 | 1997-01-14 | Nippon Polyurethane Ind Co Ltd | 印刷インキ用バインダー |
JPH1060059A (ja) * | 1996-08-19 | 1998-03-03 | Sekisui Chem Co Ltd | 塩化ビニル系グラフト共重合体の製造方法 |
JP3722397B2 (ja) | 1996-12-19 | 2005-11-30 | 日信化学工業株式会社 | 水性インキ用バインダー |
JPH10279879A (ja) * | 1997-04-10 | 1998-10-20 | Kanegafuchi Chem Ind Co Ltd | 水性艶消し剤組成物 |
US6040409A (en) * | 1997-05-21 | 2000-03-21 | Rohm And Haas Company | Polymer compositions |
JPH1135866A (ja) | 1997-07-24 | 1999-02-09 | Dainippon Ink & Chem Inc | フッ素樹脂印刷インキ組成物 |
JPH11123867A (ja) | 1997-10-23 | 1999-05-11 | Mitsubishi Paper Mills Ltd | インクジェット記録シート |
JP4203699B2 (ja) | 2000-01-18 | 2009-01-07 | 日信化学工業株式会社 | 記録シート用バインダー |
JP4167451B2 (ja) | 2001-05-29 | 2008-10-15 | 株式会社リコー | インクジェット記録用インク、インクジェット記録方法及びインクジェット記録用インクカートリッジ |
EP1262529A1 (en) * | 2001-05-29 | 2002-12-04 | Ricoh Company, Ltd. | Ink set for ink jet recording, method for ink jet recording |
US7513944B2 (en) * | 2002-11-28 | 2009-04-07 | Seiko Epson Corporation | Black ink composition, ink set, recording method and recorded matter |
TW200526737A (en) * | 2003-12-22 | 2005-08-16 | Kaneka Corp | Method for producing vinyl chloride copolymer resin |
JP2005206815A (ja) * | 2003-12-26 | 2005-08-04 | Kaneka Corp | 軟質塩化ビニル系共重合樹脂、樹脂組成物およびそれらの製造方法 |
JP2008156375A (ja) * | 2005-03-31 | 2008-07-10 | Kaneka Corp | 塩化ビニル系樹脂ドープ組成物 |
-
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---|---|---|---|---|
TWI758421B (zh) * | 2017-02-23 | 2022-03-21 | 日商日信化學工業股份有限公司 | 活性光線硬化型組成物、活性光線硬化型塗料組成物、及此等之製造方法 |
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JPWO2010140647A1 (ja) | 2012-11-22 |
KR101658119B1 (ko) | 2016-09-20 |
CN102421811B (zh) | 2016-05-18 |
EP2439217B1 (en) | 2015-09-16 |
WO2010140647A1 (ja) | 2010-12-09 |
JP5644762B2 (ja) | 2014-12-24 |
TWI477516B (zh) | 2015-03-21 |
CN102421811A (zh) | 2012-04-18 |
KR20140146667A (ko) | 2014-12-26 |
US8691888B2 (en) | 2014-04-08 |
KR101548361B1 (ko) | 2015-08-31 |
EP2439217A1 (en) | 2012-04-11 |
CN104892844B (zh) | 2017-07-28 |
KR20150111368A (ko) | 2015-10-05 |
US20110124801A1 (en) | 2011-05-26 |
EP2439217A4 (en) | 2012-10-24 |
CN104892844A (zh) | 2015-09-09 |
JP2014043585A (ja) | 2014-03-13 |
KR101643554B1 (ko) | 2016-07-29 |
JP5796617B2 (ja) | 2015-10-21 |
KR20120022856A (ko) | 2012-03-12 |
KR20150063580A (ko) | 2015-06-09 |
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