TW201107437A - Adhesive compositions and adhesive, adhesive for optical members and optical member with adhesive layer using it - Google Patents

Abstract

This invention provides an adhesive that is characterized by being produced by crosslinking adhesive compositions comprising acrylic resin (A) and ionic compound (B) which includes bis (fluorosulfonyl) imide anion and is solid state at room temperature. The adhesive of this invention can be favorably used, especially for optical film, being excellent in balance between adhesive property and antistatic property, and also being excellent in adhering optical layer, especially polarizing film to glass substrates under high temperature and high humidity. Therefore, the invention can produce liquid crystal display panels with great durability that can prevent the light-leaking phenomenon caused by the shrink of polarizing films, in addition to avoid occurrence of blister or peeling-off between a adhesive layer and a glass substrate.

Description

201107437 • VI. Description of the Invention: [Technical Field] The present invention relates to a bonding composition and a dopant, and an optical structure, and an optical layer having an adhesive layer obtained by using an adhesive for the optical member 'About liquid crystal display device, organic electroluminescence display device, Qing & rise film 4) especially frequency (four) will be polarized age three pieces of ί ϊϊ adhesive layer with adhesive for this optical component The optical components of the ride, especially the polarized light with the sister. Layer [Prior Art] The light f is, for example, a polarizing plate coated with a right-handed 9 y ^ cellulose film coated with a polarizing polyvinyl alcohol-based film, etc., laminated on a liquid crystal display panel. = the surface of the liquid crystal cell 'and the surface of the liquid crystal' and == the first plate to stop the injury or the second layer of the adhesive layer on the surface of the optical component 'to prevent injury ίίίΊΓΪ' or to prevent processing and shipping This process does not require this division but 'when it is attached to the liquid crystal cell, etc., the _ surface protective film: Γ! ίί, and peeled off. When the separation piece is electrically caused by dust, ":: Structure:: When it is separated: Static electricity will be generated, due to the static phenomenon of the static destruction of the component, etc.. If foreign matter is mixed in or out of school, the above is the same as =t= In addition, the countermeasures for the occurrence of undesirable phenomena are, for example, the early or double-sided formation of the 'sub-members' has a glass transition temperature of (TC to 201107437 J· polymer and ionicity) The liquid adhesive layer is obtained (for example, the tea patent document). #接孓先子部件 Further, it is proposed to contain an acrylic polymer and an antistatic impurity for the sulphuric acid. The composition of the agent is resistant to the use of a surface protective film (for example, Yuan Zhaozhuo (a polymer which is less than 砰 砰 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. 2006-45475. SUMMARY OF THE INVENTION (Problems to be Solved by the Invention) 2. The technical street γ a / polymer disclosed in the above Patent Document 1 is only ion-matched. Sex, although it is optimized for C-type, hide疋The type of ionic liquid used is not =£=====1 yuan is not tested at all 3SiiSSF== using electrolytic fluorination method, g made in the middle of the replacement of silk need to take a look, Wei m difficult / And costly. Or LCD TV, car guide r is often harsh in personal computers, required in the above: harsh: f: This, the environment has become not even in the harsh environment of high temperature, high humidity, the adhesive layer and = between ^^ 4 201107437, or the phenomenon of peeling, and in a high-temperature, high-humidity environment, * occurs as a so-called light leakage phenomenon that follows the contraction of the polarized light, and light leaks from the peripheral portion of the liquid crystal display panel. In the context of the second one, the purpose is to provide antistatic properties*. Even under the conditions of moisture and humidity, it has excellent adhesion to the optical Nieshengjiu County. The adhesive layer and the glass are the same. ; ; ; ; ; 剂 ; 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 剂 编 编 编 编 编 编 编 编 编 编 编 编 编 编 编 编 编Invented. The main purpose of this book is about a glued sword, j: Laluo face person = double (fluoro paste Lion example ===== The agent is laminated on the optical member. The reduction is: bonding the optical member (the effect of the invention). The physical properties and resistance are suitable for use as an optical member, and the adhesive stack can be obtained. Excellent in the body's chattering under high temperature and high humidity conditions, between the light and the glass substrate: the adhesion of the board is excellent, the door of the adhesive layer is not peeled off, and it can prevent the light leakage caused by the polarized smashing 201107437 siiHSSCl? Durable material is also an excellent liquid crystal display panel; polarizing plate or: ===: film, polypropylene, for example, assembled into a liquid crystal display, etc. for 0 '2, ^ _ _ tab, usually, stripping removal In the following, the liquid crystal substrate or the embodiment of the present invention will be described in the following description. (4) 嶋 fine;, ^:: ί: ΐ ^ First of 5 children to illustrate the adhesive composition of the present invention. . The viewpoint of being more resistant to static energy is preferred.

Ri 10) 1Γ (1) is hydrogen iii methyl, aryl or aryl, Rl 201107437 or block. In addition, in the above formula (1), γ is a hydrogen atom or a compound in the above formula (1). Among these, the hydrogen atom thiol group; ^ base =, === 任-hyun group, phenyl 'from the acrylic resin (4) made of ruthenium atom, liter's view is better for silk, especially Jia is a base. Easiness or anti-cardiac ability 1~10TM MS ^, base is preferred, especially methyl is preferred: J: number = γ is methyl, ethyl, propyl, anti-static performance decreased HLB Decreasing becomes a lipophilic aryl group, usually using a carbon number of 6 to 20, preferably 6 to 15, and Qiu and t, preferably. In situ, a methyl group, a tolyl group, a biphenyl group, a naphthyl group, etc., such as a phenyl group, for example, a wire, usually a carbon number of 7 is preferably M5, in particular, usually a dimer, an alkoxy group, Silk, hetero-ulfanyl) i. J ^ In the above formula (1), it is a hydrogen atom or a methyl group. In the above formula (1), n is an integer of 1 or more, and preferably H0 is low. If the Ω value is too large, the acryl resistance of the acrylic resin tends to be </ RTI> and the amount of the raw material that can be supplied is less than that of the ruthenium resin. When γ is a hydrogen atom in the above formula (1), n=1 single t-based propyl ketone, butyl vinegar, (methyl; fluorene (methyl) propyl 6-hexyl hexyl ester, (A) Acrylic acid 8, octyl vinegar $ base) acrylic acid 10-pyridyl ester, methyl propyl benzoic acid (4) via methyl hexyl vinegar), etc. (alkene 201107437 acid hydroxyalkyl ester containing 1 hydroxy group Monomer; (mercapto) acrylic acid 2-hydroxypropyl ester, methacrylic acid 2-silyl vinegar, (mercapto) propyl 2_ thiol_3_phenoxy propyl vinegar, etc. Monomer; (meth)acrylic acid 2, 2-diindenyl-2-bromo-based monomer containing a 3-stage radical. a monomer having η of 2 or more, for example, a polyethylene glycol derivative such as polyethylene glycol mono(mercapto)acrylic acid vinegar, a polypropylene glycol derivative such as polypropylene glycol mono(indenyl)acrylic acid, or the like. Alcohol-polypropylene glycol-mono(meth)acrylic acid vinegar, poly(ethylene glycol-tetradecyl diol) J (mercapto) acryl vinegar, poly(propylene glycol-tetradecyl diol) mono(fluorenyl) Propylene sulphuric acid vinegar. When the hydrazine in the above formula (1) is an alkyl group, for example, methyl acrylate 2-methoxy acetonate, (mercapto) acrylate 2-ethoxyethyl acetonate, (meth) acrylate 3 methoxy group Butyric acid, 2-butoxyethyl (meth)acrylate, 2-butoxydiethylenediester (meth)acrylic acid decyloxydiethylene glycol vinegar, (mercapto)propyl Glycolic acid methoxy triethylene glycol vinegar, (mercapto)acrylic acid ethoxy diethylene glycol §, (mercapto) acrylic acid methoxy dipropylene glycol vinegar, (mercapto) acrylic acid decyloxy Polyethylene diol, octyloxy polyethylene glycol - polypropylene glycol: mono(indenyl) acrylate, lauric oxoethylene glycol mono(methyl) acrylate bismuth, stearoxy polyethylene Mono (meth) acrylate to aliphatic (meth) propionate. When the hydrazine in the above formula (1) is an aryl group, for example, (fluorenyl) phenoxy acrylate phenoxy diethylene glycol vinegar, oxyethylene oxime decyl benzene (meth) propyl Fine acid S is intended. When Y in the above formula (1) is an aralkyl group, for example, ethyl methacrylate or benzyloxy diethylene glycol (meth) acrylate is used. Among the acrylic monomers (al), it is difficult to reduce the monomer or the monomer containing a methoxy group by a point effective to impart hydrophilicity, especially a monomer containing a few groups or containing a methoxy group. Preferably, the monomer is more preferred, and it is more preferred to be 2-ethylenic acid or 2-methoxyethyl acrylate. Further, it is preferable to use two or more kinds of the above monomers in combination, and it is preferable to use two kinds in particular. = (meth)acrylic acid monomer (al), and the copolymerization component of the bupropion acid resin (4) is preferably 5 to 10% by weight, particularly preferably 8 to 7 based on the total amount of the copolymerization component. 〇201107437 The weight is preferably 10~50% by weight, especially preferably 2〇~40% by weight. When the content of the (fluorenyl) acryl-based monomer (al) is too small, the antistatic property tends to be insufficient. The copolymerization component other than the above (meth)acrylic monomer (al), for example, a (meth)acrylic acid monomer (10), and optionally a functional component other than the (meth)acrylic monomer (al) Base monomer (a3) or other copolymerizable monomer (^). Acrylic vinegar is based on (10), for example: (meth)acrylic acid. Regarding the (mercapto)acrylic acid, the carbon number of the base is usually 12, and particularly preferably 1 L is more preferably 4 8 'specifically, for example: (meth)acrylic acid vinegar, (曱) Baked sour vinegar, n-butyl sulphate, sulphate, acetoin, butyl ketone, (meth) acrylate, propylene, (meth) acrylate, ί 乙基 ethyl ethyl hexyl ester, n-octyl (meth) acrylate, succinic acid (meth) acrylate sulphuric acid; (methyl) acrylic acid recorded pterine vinegar, (mercapto) acrylic acid available decenoic acid Cyclohexyl ester, isobornyl (meth)acrylate, etc. These are used alone or in combination of two or more. 卞作容 = raw carboxylic acid vinegar (a2), by copolymerization, adhesion properties, f From the viewpoint of ease of use, it is preferable to use (meth)acrylic acid n-butyl; (曱Wi2 positive = (10), more preferably excellent in antistatic properties, Malay contains ίίίϊ monomer (,: acrylic acid, methacrylic acid) Acid, (Ami-deficient, itaconic acid, fumaric acid, acrylamide N-glycolic acid, cinnabar acrylonitrile-salt-capped Mlchae 丨 adduct (for example, propylene) Acid dimer, mercapto propylene® ruthenium, acrylate acrylate, methacrylate, methacrylic acid tetramer ❾, :*, propylene glycol tetramer (for example, 2-propene oxime 7 ^ 2 i methyl) propyl xiang &amp; oxyethyl dicarboxylic acid monoester monoester, 2- propylene ethoxylate ethyl vinegar, 2-methyl propylene oxy-oxyethyl phthalic acid S dicarboxylic acid Monoester, 2-methylpropionyl-oxyethyl o-oxygenate hexaphthalate monoacetate, 2-methylpropionic acid epoxidation, etc.) t-Nuyl monomer; Base) propylene methacryl _, propyl group-containing monomer; acrylamide, methacrylamide, N ί, tyrosine, N-(n-butoxy silk) soil (meth) propylene 酉 &amp; Amine, hydrazine, hydrazine-diethyl fluorenylamine phthalate Monoamine, dimethylamine propylamine, dimethylaminomethylmethylamine amide group containing guanamine group; (meth)acrylic acid bisfylamino group Methyl) ethyl silk b § 1 and other silk-containing monomers; C-based base Lin and other nitrogen-containing compounds; ethylene tartaric acid, rare a sulfonic acid group-containing monomer such as a sulfonic acid, a decyl allyl or a fluorenyl phthalic acid, a 2- propyl sulfonamide, a 2-methyl propyl sulphate, a phenyl sulfonate or a salt thereof 'Alone or two or more types may be used alone. Among the monomers (a3) having a fluorenyl group, a monomer having a carboxyl group, a monomer having a group, a monomer having a radical, and a nitrogen-containing monomer may be used. The monomer is preferred, and it is excellent in peeling properties and also has a thief for durability, and is particularly preferably a monomer containing a ketone group. - Its copolymerizable monomer (a4), for example, acryl guess, methyl Acrylic guess, benzene, bismuth benzene, vinyl acetate, vinyl vinegar, ethyl vinegar stearate, ethylene, vinyl chloride, vinyl acetate 〇 咬 、, 乙 炼 ^ each =, clothing and practice two silk g, fumaric acid two silk _, 蝉 醇 、 丙 丙 丙 甲基 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Monomer trimethyl chloride, dimercaptopropyl vinyl ketone and other monomers. Further, when it is intended for high molecular weight, it is also possible to use together with ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, and triethylene glycol di(meth)acrylate. The base is a polyethylene glycol acrylate, a propylene glycol di(meth)acrylate, a compound having two or more ethylenically unsaturated groups, and the like. In the system, the propylene enamel resin (A) is polymerized by polymerizing the copolymerization component containing the above (5) to (10). However, the polymerization can be carried out by a conventionally known method: for example, mixing in an organic solvent Or a polymerization monomer such as the above (meth)acrylic monomer (al), (meth)acrylic acid vine monomer (tetra), a monomer containing another functional group, or a polymerizable monomer (a4), and polymerization initiation Agent (azobisisobutyronitrile, nitrogen and isovaleronitrile, benzoquinone peroxide, etc.), and in the reflux state or 卯 it 八 2~20 hours. Come to the mouth and then 'on the (meth) acrylic acid system The content of the polymerization component other than the monomer (ai) and the ly-(methyl) acrylate vinegar monomer (10) is 〇~95% by weight, especially 3〇~92 weight 10 201107437% by volume, more preferably 50-90% The weight % ' is more preferably 6 〇 to 85% by weight, and the functional group-containing monomer (a3) other than the (mercapto) acrylic acid monomer (al) is 〇 40 weight%. /, particularly preferably 0. ～30% by weight, more preferably 0 to 20% by weight, and the other copolymerizable monomer (34) is % by weight, particularly preferably 〇4% by weight, particularly preferably 〇30% by weight. The glass transition temperature (Tg) of the resin (A) is preferably 〇t: the following is more preferably 15 C or less, and the alumina is below 30 C. The lower limit of the glass transition temperature (Tg) is usually -75°. C. Also 'glass transfer> the degree of profit (Tg) is calculated by the following Fox formula 丄A ^

Fox formula: take 驷耿 ^ .

Tg: glass transition temperature of copolymer (K)

Tga: glass transition temperature (K) of homopolymer of monomer A Wa: monomer A content rate

Tgb: glass transition temperature (κ) of the homopolymer of monomer B shame: weight fraction of monomer B... Tgn: glass transition temperature (k) of homopolymer of monomer N wn: weight fraction of monomer n For example, the value of the glass transition temperature of the acrylic resin (A) can be changed to the type and ratio of the acrylic monomer used for the copolymerization component. Adjustment. About the weight average molecular weight of the acrylic enamel resin (A) | 10,000 to 30. 10,000' is preferably 3Q~25. Wan, especially good for 6Q million ~ coffee - hang more ^: Wan Wan. If the weight average molecular weight is too small, there is a case where it is impossible to obtain a foot gap of 1 = excessively large, and a large amount of a solvent is required to be used, and the degree of dispersion (weight average molecular weight / number average molecular weight) of the acrylic resin (4) in terms of coatability and cost Further, it is 20 or less, and particularly preferably 15 or less. More preferably, if it is less than 1 inch, if the degree of deterioration is too high, the effect of the female agent, the weather resistance, or the leak resistance is likely to be changed. In addition, the lower limit of the greenness is from the viewpoint of the limit of the production. In general, 11 201107437, the average molecular weight and the number average molecular weight of the f-number are used, and the standard polystyrene molecular weight is used for high-speed liquid chromatography (manufactured by Waters Corporation of Japan). Test (10)

2695 (body) and "Waters 2414 (detector)" use column: Sh〇dex GPC KF-806L (excluding the limit molecular weight: 2Xl (y, separation range: .2χΐ() 7, theoretical number of segments: surface Q segment / Root, filler material: stupid ethylene _ divinyl styrene copolymer, filler particle size: 10 #m) three tandem measurement, in addition, the degree of dispersion is determined by the weight average molecular weight and the number average molecular weight. Further, the glass transition temperature is calculated by the F〇x formula. Further, the acrylic resin (4) is preferably used in the case of the HLB value of 6.8, and more preferably 6 H0, more preferably 7.2. It is 7. 2~8. 〇. If the value of (4) is too high, the antistatic property tends to decrease. Moreover, if the value of the brain is too large, the heat resistance of the acrylic acid tree has a tendency to decrease. (Hydrophllle~LiP〇Phile Balance) ^ Davies ^jil Brain value, Σ Σ (base of hydrophilic group) + Σ (base of lipophilic group) +7, type of hydrophilic group, lipophilic group, hydrophilic group, lipophilic group Example of the value of ^, the person who recorded in [Table 1], the details are described in the document "The new version of the surfactant agent ^ (Japan Oil Moon) stock company 'Working books (shares) company version ) of the 234th ίλ 1. 5.~5. 1. 7. [Table 1]

ΐInventive bis(gas-Wei-based) ionic compound (8) (hereinafter sometimes referred to as "ionic compound (8) body 12 201107437 has bis(fluoro) quinone imine anion (yan 4 parts can be ' The _ sub-portion seems to have a 5-fold anion (2) transitional soil-like metal, a cation of a compound, a chain-like 4th-order or a heterocyclic ring of a metal atom, Ϊ It is especially suitable for the detection of metal cations. It is a % material, a soil-based metal cation, and a metal cation. For m, especially for propylene_polymerization, it is preferably Ga+, Mg+. (5) The cations, preferably rust cations, especially good for cations, cations, showing good antistatic properties.峨 ί ί 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑 骑And the base of the smell of rust and rust is, if it is easy to make high-purity ionic compounds The cause of the problem is that the price of the lion is not resistant to damp heat. In the present invention, the normal temperature means 2 (TCil5t: (5~35. 〇. 13 201107437 sub-example compound (8) has _, the test metal cation sulfonate base double ^ Yellow brewed fine _, double (fluorine), 3 =, etc., from the viewpoint of good antistatic performance ί; comparison: base) Noron: dimer (8), can be used alone or in combination of two or more. ^ ^ ^ 0. 01^ it;: « Particularly good is 2 to 5 parts by weight. If there is too much tendency to resist one, if too little, the antistatic performance tends to be insufficient....,, low (8) 峨 A A) 姊子Compound: Sil't system: in addition to the above-mentioned (Α) and (8) components containing the above-mentioned acrylic acid-based resin (4) and ionization, the inclusion of the above-mentioned unsaturated content is further improved. The cross-linking agent (8), is also a health-resistant product. (1) The adhesive of the present invention will be described below. The hair-drying agent is obtained by crosslinking the above-mentioned mixed-age product (1). , the sister "made as the acrylic resin (4) as the adhesive composition (1) full amount, the propionic acid resin (4) relative to i ====[:=. First of the 'good to [α] method 'that is, containing compound (6) containing an unsaturated group and poly 14 201107437, starting agent (D) and crosslinking the adhesive composition [丨] with active energy rays and/or heat (active energy ray and/or heating) Method of using the active energy ray and/or heat (active energy ray irradiation and/or addition), the adhesive composition [I], in addition to the aforementioned acrylic resin (Α) and ionic compound (Β) other than the compound containing an unsaturated group ((:) and polymerization initiation, (D). In this way, by containing a compound containing an unsaturated group, the parent can be adjusted to achieve an optical member The adhesive properties of the use. Further, by containing the above polymerization initiator (D), the reaction at the time of irradiation with active energy rays and/or at the time of heating can be stabilized. In the above cross-linking, the unsaturated group-containing compound (c) is crosslinked with the acrylic resin (A) by physical energy ray and/or thermal polymerization (polymerization)' (physical exotherm). When the acrylic resin (a) is an unsaturated group-containing acrylic resin, it is not limited to the use of an active energy ray and/or heat to carry out an unsaturated group-containing compound ((:) polymerization, which is accompanied by The polymerization of the saturated acrylic compound (A) and the unsaturated group-containing compound (C) is crosslinked. The unsaturated group-containing compound (C) which can be used in the present invention may have one in one molecule. The saturated monofunctional unsaturated group-containing compound may be a polyfunctional unsaturated group-containing compound having 2 or more unsaturated groups per molecule, preferably having two or more unsaturated groups. The compound having an unsaturated group, more preferably an unsaturated group-containing compound having three or more unsaturated groups, is preferred from the viewpoint of curability at the time of active energy ray irradiation. The above unsaturated group-containing compound (C) The structure is, for example, an amino phthalic acid (T-based) acrylic vinegar compound, an epoxy (meth) acrylate compound, a polyester (meth) acrylate vine compound, or one molecule per molecule. Above ethyl unsaturated group As the ethylenically unsaturated monomer, for example, a monofunctional monomer, a dimercapto, or a trifunctional or higher monomer can be used. Among them, an amino phthalate (acrylic) acrylate is used. The compound (cl) and the ethylenically unsaturated monomer (c2) are preferred from the viewpoint of excellent curing rate or stability to physical properties. Further, the unsaturated group-containing compound (C) contains an oxygen-extended alkyl chain. Or a hydroxyl group or a quinone-based ion pair and/or a beet test structure, etc., showing a hydrophilic structure site, which is particularly preferable from the viewpoint of the electrical properties of anti-static 15 201107437. The above-mentioned amino citrate (meth) acetoacetate g The compound (cl) is a (meth)acrylic acid g-based compound having a bond in the molecule, and a (meth)acrylic compound containing a silk and a polyvalent isocyanate compound can be used. (Polyol oxime compound) is obtained by a known method, and the weight average molecular weight is usually 300 to 4,000. The urethane (meth) acrylate type compound is not particularly limited. But not containing more το alcohol compounds Preferably, the polyvalent isocyanate compound is directly reacted with a hydroxyl group-containing (meth) acrylate compound. The above hydroxyl group-containing (meth)acrylic compound, for example, methyl acrylate 2: hydroxyethyl ester, (A) 2-hydroxypropyl acrylate, 2-hydroxybutyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, 6-hydroxyhexyl (meth) acrylate, 2 - (meth) propylene oxime Ethyl-2-hydroxypropyl phthalate, 2-hydroxy-3-(methyl)propene 1 propyl propyl acrylate, caprolactone denaturing (mercapto) acrylate 2 hydroxy ethane Vinegar, pentaerythritol vinegar tris(meth)acrylate, dipentaerythritol vinegar penta(indenyl) acrylate, deuterated pentaerythritol diacetate dicaptanol ester 'caprolactone denatured tris(fluorenyl), alkene Pentaerythritol ester, oxyethylene-denatured pentaerythritol vinegar vinegar, oxyethylene-denatured pentaerythritol tris(fluorenyl) acrylate, etc., in which a hydroxyl group-containing (fluorenyl) acrylate having 3 or more acryl fluorenyl groups Preferably, the compound can be used Among one kind or in combination of two or more thereof. The above polyvalent isocyanate compound, for example, an aromatic, aliphatic, alicyclic, or the like polyisocyanate, wherein toluene diisocyanate, diphenylmethane diisocyanate, hydrogenated diphenylnonane diisocyanate, poly Phenyl decane polyisocyanate, k-diphenyl sulfonium diisocyanate, hydrogenated diphenylene diisocyanate, dinonyl diisocyanate, hexamethylene diisocyanate, trimethyl hexamethylene diisocyanate, fluorenyl Monophenylene diisocyanate, isophorone diisocyanate, norbornene diisophthalate, 1,3-bis(isocyanium decyl)cyclohexane, phenylene diisocyanate, lysine monoisocyanate, A polyisocyanate such as a dicar triisocyanate or a naphthalene diisocyanate or a trimer compound or a polymer compound of the polyisocyanate, a diurea type polyisocyanate, or a water-dispersible polyisocyanate (for example, Japan Polyure^ane Industrial Co., Ltd. 16 201107437 ATnate 1 〇〇J''Acuanate 110-J'TAcuanate 200 j^Acuanate", or the reaction product of these polyisocyanates with polyols. :Exo- _ diisocyanate g, 曱 二 diisocyanate § |, hexamethylene diisocyanide oxime ester, these trimer compounds or multi-polymer compounds. : If the unsaturated monomer ((2), a monofunctional monomer, a bifunctional monomer, a trifunctional monomer, etc. may be used. The coffee is as early as possible, as long as it contains one ethylenicity. The saturated monomer is L, for example: styrene, vinyl benzene, chlorostyrene, α-methyl styrene (A, yttrium acrylate, ethyl (meth) acrylate, propylene, ethylene acetate) Vinegar, (methane) 2-hydroxyethyl acrylate, 2-(hydroxy) acrylate, (meth) propylene oxime 2: hydroxy butyl acrylate, phenoxyethyl (meth) acrylate, (A) 2-phenoxy-2-hydroxypropyl acrylate, 2-hydroxy-3-p- oxypropyl (meth) acrylate, (fluorenyl) propionic acid-3-chloro-2-hydroxypropyl ester, Mono (meth) acrylate, (meth) methacrylate, (mercapto) laurate, (cyclohexyl) hexyl hexyl acrylate, (fluorenyl), dilute borneol vinegar,曱基)丙Acid tricyclic 癸g, (mercapto) acrylic acid bicyclic bismuth vinegar, (mercapto) acrylic acid n-butyl ketone, (mercapto) hexyl acrylate vinegar, (methyl) propyl p-heptanoate, (a Octyl acrylate, decyl (meth) acrylate, decyl (meth) acrylate, isodecyl (meth) acrylate, dodecyl (meth) acrylate, n-stearyl methacrylate , (fluorenyl) benzyl acrylate, phenol oxyethylene denatured (meth) acrylate, nonylphenol oxypropylene denatured (fluorenyl) acrylic acid, 2_(indenyl) propylene oxime 2 _ propyl propyl A half ester (mercapto) acrylate of a phthalic acid derivative such as phthalic acid ester, a furyl (meth) acrylate, a carbitol (mercapto) acrylate, a (meth) acrylate, (a) Base) acrylic butyrate, (meth)acrylic acid, propylene, ketone, 2-ethylidene propyl amide, N- thiol-(methyl) propylamine .. N_Bichylpyrrolidone, 2-vinylpyridine, 2-(meth)acryloyloxyethyl acid disc acid monoester, and the like. In addition to the above, the above-mentioned ethylenically unsaturated monomer is, for example, a Michael addition product of acrylic acid or a 2-propenyl oxiranyl dicarboxylic acid monoester, a Michael addition product of the above acrylic acid, for example, an acrylic acid dimer, Mercaptoacrylic acid dimer, olefinic acid dimer, methacrylic acid terpolymer, acrylic acid tetramer, tetramethic acid methacrylate 17 201107437 ester also ί·! carboxylic acid having a propyl group The above 2, olefin oxyethyl dicarboxyl number - single = 2 ethyl acetonitrile monomethyl, 2-methyl propyloxyethyl ethyl phthalic acid # this dicarboxylic acid mono s, thiol propylene Oxime propylene _ethyl hexahydrogen = A, 2-, 2-ester. w This is an early knowledge. Further, for example, an oligoester acrylic acid, 2 2-^if, as long as it is a monomer containing two ethylenically unsaturated groups: (A·: :?) ethylene glycol propionate, di(methyl) ) diethylene glycol bis(mercapto)acrylic acid butanediol, dibasic; (acrylic upper double: Ti, -= denatured double-type A di(meth)acrylic acid vinegar, oxypropylene change] R_P 曱Acrylate, I6-hexanediol bis(indenyl) acrylate, vinegar, two "A:", bis (曱5) propyl vinegar, di(methyl) acrylate glycerin; acid r, Di-decanoic acid t-tetradecyl alcohol, ethylene glycol diepoxy propylene di(methyl) propyl = mono-epoxypropyl ether bis(indenyl) acrylate, bismuth phthalate, " Methyl 1 - acetonitrile, trans-trimethylacetic acid-denatured neopentyl glycol 2 (A = Ganzi Day, lytic acid oxyethylene diacetate vinegar, 2 - (methyl) propyl ketone An acid bisulphate diester or the like. The trifunctional or higher monomer 'supplements contain three or more ethylenically unsaturated groups H. For example, tris-methyl propyl tris(methyl) propylene or tris(indenyl) propyl hydrazine Pentaerythritol, _, tetra (indenyl) acrylic acid pentaerythritol Dimethyl] propylene dipentaerythritol, §, four (fluorenyl) dipentaerythritol acrylate, penta(indenyl) acrylate acid season, tetragen, hexa(indenyl)acrylic acid dipentaerythritol g (曱基) propylene broth ethoxylated triploid, glycerol polyepoxy lysine (f-based) propyl vinegar, isocyanuric acid oxyethylene tris(decyl) propylene _, oxyethylene denaturation Diquat quinoneol penta(indenyl) acrylate, oxyethylene-denatured dipentaerythritol hexa(meth) acrylate vinegar, oxyethylene-modified pentaerythritol tris(mercapto) acrylate, oxyethylene-denatured pentaerythritol tetra(meth) acrylate, Succinic acid denatures pentaerythritol tris(fluorenyl) acrylate, etc. Further, the use of the above-mentioned ethylenically unsaturated monomer (c2) contains an oxygen-extended alkyl chain

1S 201107437 is also preferred. The above unsaturated group-containing compound (in the case of oxime, the use of an oxygen-containing extended alkyl group of amino acetoic acid (tetra)methyl) acetophenone oxime (cl) or ethylenically unsaturated monomer (C2) is also preferred. In particular, an unsaturated group-containing compound having a / chain and containing 3 or more unsaturated groups is preferred. Further, the compound (6) containing an unsaturated group, and a (meth)acrylic acid g-based compound having an acid test group and/or a beet-containing structure in the molecule, is preferred from the viewpoint of further improving the resistance. on. These unsaturated group-containing compounds (C) may be used singly or in combination of two kinds of compounds (C) having an alkyl group as an unsaturated group, and the amount of the compound (C) is preferably 2% with respect to the acrylic resin (). 99 parts by weight, more preferably 5 to 5 parts by weight. When the content of the unsaturated group-containing compound (6) is too large, the miscibility with the tree sap is deteriorated, and the coating film tends to be whitened, or the adhesion is excessively decreased, and the peeling tends to occur in the enemy test. $, ΪΪί Insufficient agent has insufficient crosslink density, and has a preventive property or a reduced durability. The polymerization initiator (W, for example, a photopolymerization initiator (dl), an armor bastard initiator (d2), etc. can be used. Various polymerization initiators are preferred from the viewpoint of being able to be crosslinked (hardened) by irradiation with an active energy ray such as ultraviolet rays in a very short time, in particular, by photopolymerization. When the above photopolymerization initiator (dl) is used, 'there is an active energy ray to make the viscosity = cross-linking, and when the thermal polymerization initiator (4) is used, the adhesion is made by heating, and the product [I] is affixed to the parent, but also Use both if you need to. A photopolymerization initiator (dl), for example, diethoxyacetophenone, 2-hydroxy-2-phenylpropanone-ketone, benzyldidecyl ketal, 4_(2_ Hydroxyethoxy)phenylpropyl)one, 1-hydroxycyclohexyl phenyl ketone, 2-fluorenyl-2-mylinyl (4-2-methylindolyl)propan-1-one, 2-benzyl-one Benzene-isoindole such as 2~ mercaptoamino-mono-phenyl-phenyl)butane/methyl-H4-(I-methylethlyl)phenyl]propene-iso oligomer; benzoin and benzoin Ether ether, benzoin ether, benzoin isopropyl ether, benzo couple 19 201107437 butyl epoxide such as dibutyl ether; diphenyl ketone, o-phenylene fine, 4-phenyl fluorene-4, bis, 4 -Phenyldidimethyl--a,oxy I-//oxy-basic)=t benzene cap base (Me_aminium) desert, (4_ phenyl yin yin «chemical tetra-famine, · 2- different Propyl-iso-, 4-isopropyldiphenyl ketone)- 3,4-di-T-yl-9H-thioxanthone-9-one mesn^ servant wild soil female base 2 hydroxy tri-T-based benzene f Brewing it - two mf vaporization special 0 plug °_ class; 2, 4, 6_ its V9 /1 / &lt; - soil one soil emulsified phosphine, bis (2, 6-di-f-butyl bromide, 4 - dimethyl-pentyl phosphine oxide, double (2, 4 three # base oxidized lining, etc. Phosphine oxides, etc. Alternatively, it may be used alone or in combination of two or more such "initiators (6), and only such adjuvants may be used, for example, triethoxydigamyl diphenyl ketone ( Michler's ketone), 4 US 7 Λ 一 一 f 基 胺 胺 胺 胺 、 4 4 4 4 f f f f f f 4 4 4 基本 基本 基本 基本 基本 基本 基本 基本 基本 基本 基本 基本 基本 基本 基本 基本 基本Aminoamine 芏 芏 羊 羊 曰 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 In the 4-diisopropylthiazolidine, it is preferred to use (tetra) dimethyl ketal as a small cyclohexyl benzophenone, a side-growth-cafe, a catechol, the above thermal polymerization initiator (IV), for example, methyl ethyl ketone. Peroxide, cyclohexanone oxime 7 points, methyl hexanyl peroxide with peroxide, mercaptoacetic acid hydrazine peroxide, ethyl acetate acetate peroxide, U-double (third hexyl peroxide) )_3, 3, 5-trimethyl ring: 1'' bis (third hexyl peroxide) _ cyclohexane, hydrazine, bis (tertiary butylperoxy', 5-trimethylcyclohexane,丨,丨—bis(t-butylperoxy)_2_methylcyclohexene jH 'double (t-butyl) Oxidation)-cyclohexene, U-double (t-butyl peroxy) = calcination, 1,1-bis(t-butyl peroxy) butadiene, 2,2-bis (4,4_di_ Tributyl sulphate 1 Cyclohexyl}propane, hydrogen peroxide, diisopropylbenzene hydroperoxide, 3, tetradecyl butyl hydroperoxide, cumene hydroperoxide, Trihexylperoxy 20 201107437 ί hydrogen nitride, α, bis(t-butylperoxy) diisopropyl? appearance 7 2' 5~ dimethyl ~ 2,5_ bis (tert-butyl peroxidation ), 5~ (dibutyl peroxy) hexyne-3, isobutyl hydrazine peroxide, hydrazide peroxide, succinate peroxide, peroxide 'di-n-propyl propylene dimer One cymbal ester, bis(4-tert-butylcyclohexyl) bismuth subdiformate, one &quot;~2~ethoxyethyl peroxydicarbonate, di-2-ethoxy dextran Served dicarbonic acid vinegar, bis(3-methyl-3-methoxybutyl)peroxidized HU oxygen^-double (new broth base peroxidation) diisopropylbenzene, cumene hydroperoxide, U,3,3-tetramethylhexylperoxy neodecanoic acid = new; acid = A butyl peroxy neodecanoate awake, the first = ^ fa brother Hexylperoxyperoxyacetate, tert-butylperoxysulphate, 2?雔々L 3 , wide methyl butyl peroxide, ethyl iodide (10), 2, 5', 2 k cerium oxide Peroxidic hexanoic acid, hexacyclohexyl-b-methylethylperoxy-2-ethylhexanoate, third hexylperoxy-2-ethylhexanoate, third butyl hydrazine Sour, third hexylperoxy isopropyl monocarbonate, the first: ΐ ^ butyl oxidized apple, the third butyl | the servant is obvious, the second butyl peroxy laurate, Tert-butylperoxybutane: ester, tert-butylperoxy-2-ethylhexyl monocarbonate, ί ΐ ΐ ϋ 、, butyl butyl peroxybenzhydryl benzoic acid Ester, ΐ, 二, bis (t-butyl peroxy) isophthalic _, 2, 5 5 methyl ketone peroxidation) hexane, third hexyl peroxide benzoate, 5 bis (benzamide) Brewed base peroxidation) calcined, tert-butyl over 四 η ^ ^ ^ ^, butyl butyl tridecyl sulphate peroxide, 3, 3, 4, 4, - (dibutyl butyl Oxidized carbonyl)diphenyl ketone, 2,3-dimethyl-2 3-di-butyl oxo = initiator; 2-benzene Base - azo + methoxy:: two; 』 nitrile, Hd-gas + methyl ethyl) azo] formate, amine, i, N, 21, 201107437, alkal-1-carbonitrile, 2, 2'-azobis(2-f-butyronitrile), 2,2,-azobisisobutyronitrile, 2,2'-azobis(2,4-dimethylvaleronitrile), 2, 2 ' ~ azobis(2-methylpropionamidine) dihydrogen chloride, 2, 2'-azobis(2-methyl-N-phenylpropionamidine) dihydrogen chloride, 2, 2,-azobis[N -(4-chlorophenyl)-2-methylpropane]hydrogen dichloride, 2, 2,-azo[2-(4-indolyl)-2-methylpropionamidine dihydrochloride, 2 , 2'-azobis[2-.f-N-(phenylmethyl)propanthene]hydrogen dichloride, 2, 2'-azobis[2-methyl-N-(2-propenyl) ) 脒 脒 了 了 了 了 了 了 了 了 了 了 了 氯化 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 -2-. Rice hydrazin-2-yl)propane]hydrogen dichloride, 2,2-azobis[2-(imidazolin-2-yl)propane]hydrogen dichloride, 2, 2' _azo double [2-(4 ,5,6,7-tetrahydro-111-1,3-diazepin-2-yl)propane]hydrogen dichloride, 22,_ azobis[2-(3, 4, 5, 6-tetrahydrogen spray Bite-2-yl)propane]hydrogen dichloride, 2, 2,-azobis[2-(5-hydroxy-3,4,5,6-tetrahydropyrimidin-2-yl)propane]hydrogen dichloride, 2 , 2, _ 匕 双 bis-ethylidene imidazolin-2-yl]propane] dihydrogen chloride, 2,2-buto-bis[2-(2-isosalin-2-yl)propane], 2,2 , _ azobis [(---l-l-bis(hydroxymethyl)_2-hydroxyethyl] propyl] 1 : propylamine], 2,2'-even 11 double (2_A Propionamide, 22,-methylpentaphan, 2'2'-azobis(2-methylpropanone), 'dimercapto 2,2 even bis(2-methylpropionate) 3, 4, _ 匕 [2 - (silk methyl) propionitrile] and other azo-based initiators, etc. 3, ^ isothermal agent may be used alone or in combination of two or more (A) l 〇tίΪΓΠ ί starter (heart volume ^ = lack = ϊ: there is a certain tendency) If too much, there will be no more knowledge, when shooting the above active energy ray, External light, infrared light, etc., χ 1 outer line, near purple use electron shot, line, proton to shoot green, ": electromagnetic wave, in addition, can be Ψ ^ Μ, , ' neutral strand 荨, but from hardening fast production, clothing From the point of view of the profitability, price, etc., use ultraviolet radiation to enter 22 201107437 = Huaer Naqing, more than a paste (10) _ 2, when? J Yuanjin: use high-light, no black light, etc. The shape of the mercury lamp, the chemical lamp, and the helmet in innn T/ 2 t can be carried out, for example, at 5 to 300 〇mJ/cm 2 , preferably 10 to 1000 mJ/cm 。. Further, the above-mentioned benefit 1 is leaked in 2] W, recorded as (4) - the distance of the coatable surface, the coating thickness, the other strips, the different U is a few seconds to tens of seconds, depending on the situation, the electron beam can be tens of ί ΐ 5 50^οοοκ- It can be set to 2~5〇Mrad. The force initiator (8), when using the thermal polymerization initiator (d2), is different depending on the type of the thermal polymerization initiator (4), usually, by ΐΐϊ ί ί ΐ Period f calculation 'processing temperature overnight is 7 (rc ~ 17 (rc, processing ^ ^ book is 0. 2~20 minutes is better, especially 〇 · 5~1〇 Next, the method of the above [々] is explained, that is, the crosslinking method is carried out using the crosslinking agent (8). When the crosslinking agent (E) is used for crosslinking, the binder composition (1) is used, except The above-mentioned acid pure lipid (4)-sub-compound (8) still contains the cross-linking (E). When the above-mentioned cross-linking agent (E) is used, the acrylic resin (A) is preferably a functional beauty, and the parent is associated with It is carried out by reacting this functional group with a crosslinking agent. The above-mentioned parent-linking agent (E)' may be a compound having a functional group reactive with the ruthenium group contained in the acrylic resin (A), for example, an isocyanate compound, an epoxy compound, or an aziridine system. A compound, a melamine-based compound, an aldehyde-based compound, a compound, or a metal chelate compound. Among them, an isocyanate compound is preferably used from the viewpoint of being able to adhere well to the substrate or the reactivity with the base polymer.曰y' The above isocyanate-based compound, for example, 2, 4-nonylbenzene diisocyanate ' 2, 6_甲 23 201107437 ι'4 曱 一 一 八 曱 二 二 diisocyanate, diphenyl bisisophthalic acid § Isophorone ketone diisocyanate g, L 3 bis (isocyanatomethyl) cyclohexyl, decyl xylene = isocyanate s, l55_naphthalene diisocyanate, triphenyl · Cyanic acid, and the addition of such polyisocyanate compounds to tris-methyl propyl compounds, diurea or hetero-adenine of these polyisocyanuric compounds Now, ♦ Ethylene diacetate propylene, glycerol propylene oxide, diglyceryl di 1,6-hexanediol dipropoxypropyl ether, trishydroxypropyl propane tri-propyl ether, mountain 4 Reduced propyl ether, polyglycerol polyepoxy secret, pentaerythritol, diglycerol polyepoxypropylation. Heart weineryl red The above aziridine compound, for example, tetrahydrofurfuryl methane _ tri-propionate, dihydroxy guanidinium-triazine. Alkyl propionate, a group N, dimethesin-4,4,-bis-oxaziridine carboxamide, hydrazine, _hexamethylene fluorenyl 6-cone ^ = carboxylamidine) and the like. , 、1虱内&quot;The above melamine-based compounds, such as: hexamethoxy fluorenyl melamine, hexaethoxy decyl melamine, hexapropoxy decyl melamine, hexabutoxymethyl dicyanamide, Hexapentyl decyl melamine, hexahexyloxymethyl melamine: f amine resin, and the like. - chaosing the above aldehyde-based compound, for example, glyoxal, malondialdehyde, succinic acid, maleic aldehyde, glutaraldehyde, furfural, acetaldehyde, benzofural or the like. ^ One of the above amine compounds, for example: hexamethylenediamine, triethyldiamine, polyethyleneimine, hexamethylenetetramine, diethylenetriamine, triethylenetetramine, isophorone Resin, polyamide, etc. Bases are complex compounds of acetophenone or acetoacetate in many metals such as Lv, iron, copper, zinc, tin, chin, recorded, recorded, town, hunger, collateral, and wrong. Further, these crosslinking agents (Ε) may be used singly or in combination of two or more. The content of the above-mentioned crosslinking agent (Ε) can be appropriately selected depending on the amount of the functional group contained in the oxime (the amount of the functional group contained in the oxime, the molecular weight of the acrylic resin (Α), and the purpose of use, and 24 201107437 propylene f-based resin (A) 5〜3重份 Li Li,, (E), the weight of the G. 1~15 parts by weight, more preferably ^ 2 weight injury, especially preferably 1. 5~10 parts by weight, and more preferably 0. 5~3 weight ί Li,, (E) If it is too small, the cohesive force is insufficient, and it is not possible to make it sufficient. If the capacity is too large, the flexibility is lowered and the adhesiveness is lowered, the durability is deteriorated, and the peeling is easy. Therefore, it is observed that it is difficult to bond with the optical film. The tendency of the anti-static property: the second part of the agent for the adhesion of the composition of the adhesive [1] is used as a part of the agent to have an antistatic spray ΐπν only 1 with the above [α] Active energy ray and/or heat (active energy ΐίίΐϋ) cross-linking is also sufficient, but more than (4) 'can improve the crosslink density of the binder, improve the cohesive force' to get more information about preventing light leakage and durability. Excellent. The ancient ϋ&quot; invention towel' is the adhesive composition of the adhesive material (1) and the two oxygen The compound (F) of the stretching group (but not (c)) (hereinafter sometimes referred to as ί ii ' is preferable from the viewpoint of further improving the antistatic function or improving the adhesion to the member. The oxygen-containing compound (F) contains 4, 1 part, 5 is usually set to ° 1 to 9 parts by weight, preferably parts by weight, and the second upper part is particularly preferably 5 to 10 parts by weight. The above-mentioned oxygen-containing stretching group j (F: if the amount is too small, the effect of the static level is high, and if it is too large, the adhesive property tends to be deteriorated. The oxygen-containing stretching base used in the present invention. The compound (8) may be a compound having an oxygen-extension group, except for a compound (except a compound containing an unsaturated group), that is, a compound having an oxygen-containing alkylene group. Among them, the viewpoint that the degree of freedom of the molecular chain is high and the antistatic function is improved is not included in the cross-linking system, and it is preferable to contain the oxygen-extension-based structure, and the J_ molecular chain-end material is contained, and it is particularly preferable. It is preferable to use a compound of the following formula (3) to further improve the antistatic ability. Y "(HX-0) 7^Y2 ... (3) 25 201 107437 (wherein X is one of alkylene, Yl, Y4, η is an integer of 1 or more.)", '70 earth-based, quaternary alkyl, amine group, X in the above formula (3) In order to stretch the base, especially the extension of the ethyl group, the extension of the propyl group, the "extension" of the carbon number of the carbon number 10 is particularly preferable. Further, η is 2 =, and the stretching base of the cloth 4 is preferred. When the homopolymer of the oxygen-extension base chain is not a chain part, it may be a phase copolymerizer. The different alkyl groups are randomly or block-like in the above formula (3), and γ2 , one of them may be the same or different from each other. The weight of the f-based alkyl group and the amine group, and the degree of freedom of the operation of the base chain, contributes to the static electricity, and the carbon number of the above-mentioned base is not hindered. = View = You Jia. Good, M0 is better, 1~6 is better. In the case of the body 5, the number of turns is M5, for example, ΐί方ί ί is often used as A=6'', preferably 6~15, specifically, preferably. a methyl group - a methyl group, a biphenyl group, a naphthyl group, etc., wherein a phenyl group is used, for example, a calcining group, and usually a carbon number of 7 to 20, preferably (d), specifically, the above-mentioned alkyl group , aryl group, amine group, also = base,: fluorine atom, gas atom 'indifferent atom two' through the earth ϊΐΐ Γ Γ φ base, sulfanyi (sulfanyi), aryl, heteroaryl and the like. More preferably, it n is an integer of 1 or more, preferably 10, and particularly preferably 2, (n) is a compound represented by the compound (8) other than the compound represented by (3), for example, polyoxygen Anionic surfactants such as N. sylvestris (IV), alkyl alkyl ether phosphates, polyoxyalkylene alkyl phenyl ether sulfates, polyoxyalkylene alkyl phenyl ether phosphates, etc. Oxyalkylene group 26 201107437 cationic surfactant or two miscellaneous::; cool, polyoxygen monoethanolic liver fatty acid: containing =: = ethyl iL specific to the base, for example: polyoxygen oxide基二帅鲜# ^卿ethyl "§|secretimine, alkyl alkyl phenyl ether, polyoxyl extension two pears = anhydride fatty acid vinegar, polyoxyethylene extension B is better." Solvents _ balance, alcohol ▲ ♦ propylene-alcohol-polyethylene glycol block copolymer, polyethylene conjugated ruthenium and other filaments, polypropylene glycol-polyethylene glycol random chain of hydrazine polypropanol Random copolymer or block copolymer. The end of the diol chain can be converted into silk, or substituted for silk, phenyl, etc. Random copolymer or post-copolymerization of diol and polypropylene glycol It is 5 to 75% by weight, more preferably 10 to 70% by weight. If it is mixed with an ionic liquid, it is not easy to get rich. The electrical drop: The crystallinity is increased, and the mutual melting of the acrylic polymer tends to be low, and the antistatic property tends to be insufficient. The compound may be used singly or in combination of two or more kinds. The above-mentioned content, _ "Silk thief high resistance Electrostatics, the genomics of polyoxoethyl (4), for example: diethylene glycol dimethyl (tetra), diethylene glycol acetonide, ethylene glycol diethyl ether and other repeating numbers of 2, triethylene glycol The repeating number of diethyl ether, tri-tdiol 5-based alpha scale, triethylene glycol diethyl hydrazine, etc. is 3, triethylene glycol oxime-methyl, ethylene glycol ethyl ketone, triethylene glycol bis (10), more In the present invention, the oxygen-containing alkyl group is contained in the above-mentioned oxygen-containing alkyl group-containing compound (1?). The ratio is preferably 5 to 85% by weight, more preferably 7 to 8 % by weight, and more preferably 9 to 75% by weight. 27 201107437 If the content is too low, the anti-static stagnation If it is too much, if the content of the hydrophilic-to-wet coupling agent (6) is too small, the miscibility with the acrylic resin (1) is lowered. There is a tendency to not receive the force or cohesive force. Cattle sucking lion 矽 = 嶋), for example: epoxy decane coupling agent, acrylic bismuth: two "wei coupling agent, base system coupling agent, carboxyl group Shixi Burning House is occasionally burned, and the agent, the amine-based Wei coupling agent, and the isocyanuric acid ester-based stone preparation soil can be used alone or in combination of two or more. Among them, the household '·,, use the shouting Shi Xi burning coupling agent, the peek system Shi Xi burning coupling agent, and use epoxy = ===_agent 'in the wet heat durability and adhesion force Specific examples of the coupling agent of Shi Xi-burn, for example: 1 glycidoxypropyl-based Wei-dodecyloxypropyl-triethoxy-Wei, r- ς-propylmethyldiethoxylate, r_ring Oxypropoxypropyl decyl dimethoxy hydrazine 1 methyl tris(epoxypropyl) sulphur, s-(3,4 epoxycyclohexyl)ethyltrioxo-cyclopropoxypropane Trimethoxy-Wei, r-epoxypropene^(3 ΓϋΓ,r-glycidoxypropylmethyldiethoxy oxime, θ(Λ 4 % 虱裱hexyl)ethyltridecyloxy Preferably, decane is a specific example of the above fluorenyl decane coupling agent, for example, 7*-weiylpropyltrimethoxy sulphate-7-succinylpropyltriethoxy sulphuric acid, τ-succinylpropyl fluorenyl In the present invention, the adhesive composition [I] which is a binder forming material further contains an antistatic agent (Η) other than the above ionic compound (Β), so that the adhesion is obtained. Agent 28 201107437 anti-month f · turtle birth % is more excellent The point is preferred. The cerium salt C does not contain (8)), the tetrahydrofuranyl tartaric acid _^, the agent (H), such as &quot; rice electrostatic agent, aliphatic, higher alcohol sulfur §;;; === The content of the above-mentioned antistatic agent (H) is usually G.GG1, parts by weight, and more preferably Α η ηι ^ (4) (10) weighs 1 0.02 to 5 parts by weight. The above-mentioned 浐 〇 〇 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 Damage to the binder, urethane beryllic acid, rosin ester propylene adhesive 'other oleoresin, styrene resin, dimethyst, alicyclic stone addition agent, or due to ultraviolet or radiation exposure In addition to the above additives, a small amount of compound can be produced. Impurities and the like contained in the raw materials for the production of the components. s has the composition of the adhesive composition [I]. Thus, in the present invention, the adhesive compound (8) obtained by crosslinking the above-mentioned adhesive composition (1) can be obtained as a result of the combination of the resin (4) and the ionic adhesive (1). Dilute (four), can also use the method of shooting active energy ray to make the cross-linking agent composition [I] according to the cross-linking agent (E), the oxygen-containing extended alkyl group containing the polymerization initiator (D ), the reason is also better. The oxime coupling agent (G) is the same as the above (the optical laminate It is laminated on the optical member to the optical member having the adhesive layer. 29 201107437 The above-mentioned optical layer having an adhesive layer Adhesive composition (1) is applied to the member of the component. G clothing: [1] In the optical ίί==substance (1), the side of the dry-disclosed optical member. = The method of making, the paste is at least one kind of optical: (1) 'When the active energy ray is used to illuminate and heat the middle and the seed, the following methods can be used. "1. The wind is taken, the S? track is at least attached to the optical member, and the active energy ray is used. Add [, ϊι, i go, [3] apply the adhesive composition on the optical member, apply the active energy ray and heat at least the towel, and then, [4] apply on the release sheet. The cloth adhesive composition (1), after drying and drying at least one of them - after the treatment, the light is bonded to the case where the method of [2] is applied and only the active energy ray is irradiated, and the substrate is not damaged. The viewpoint of viewpoint, workability, or stable manufacturing is preferred. The composition of the composition (1) is coated. The adhesive composition [1] is preferably diluted with a solution d, and the dilution concentration is preferably 5 to 60% by weight, particularly preferably 10 to 30% by weight. f, the above solvent can be composed of an adhesive. The compound [I] can be dissolved, and is not particularly limited to t = for example, acetic acid, g-ethyl acetate, ethyl acetate, acetic acid, ethyl acetate, acetone, methyl ethyl ketone, decyl isobutyl ketone, etc. An ketone solvent, an aromatic solvent such as toluene or bismuth-benzene, or an alcohol solvent such as methanol, ethanol or propanol. In view of the solubility, drying property, and price, it is preferable to use acetic acid, methyl hydrazine, and hydrazine. : 中中岭, Further, regarding the coating of the above-mentioned adhesive composition [I], a conventional method such as a roll coating method, a die coating method, a gravure coating method, a comma coating method, or a screen printing method can be used. 。 30201107437 The gel fraction of the hetero (4) produced by the method described in the above, the pure agent containing the unsaturated red compound (c), the polymerization initiator (9), and the use of live ray and/or thermal crosslinking From the durability and the prevention of leakage, it can be more than 70%', especially better than 観. If the gel fraction is too low, the cohesive force is insufficient. Insufficient longness or light leakage will have a tendency to deteriorate. The limit is 臓. The upper part of the toweling knife, the adhesive composition (1) contains the crosslinking agent (8), and the use of the hand: about the above: 4 methods The gel fraction of the manufactured miscellaneous is determined by the durability: the gel fraction is too high, and the gel fraction is adjusted to the above range. For example, LI, energy Irradiation amount or irradiation intensity of the amount of radiation 1 2: The type and amount of the compound of the saturated group, the adjustment of the amount of the compounding, the adjustment of the amount of the polymerization initiator, the combination of the class and the ratio of the compound, and the above-mentioned materials The ratio of the addition and the amount of addition will be determined by the composition of each of the 4 J 2 J initiators. W Saki &lt; Turning, it is necessary to take the above gel fraction, which is the degree of crosslinking. It will be calculated on the polymer sheet that becomes the substrate (for example, the two = column method. Adhesive sheet made of the adhesive layer (not provided with grade) SUS metal mesh wrapped, in the toluene in the 20〇mesh net, the insoluble adhesive composition will remain in the metal The substrate weight is first deducted. The white knife and the sheep are shouting the glue rate. However, in the optical member with the adhesive layer served by the fire, Le 卞, = and $ 5, 〇 _, especially preferably 1 〇 ~ 5 〇 _, more: the thickness of the layer is passed, the thickness is over Thin, the adhesion properties will be difficult. The thickness of the entire adhesive member has a tendency to increase too much:,, if the thickness is too thick, the wire member having the reducing layer of the present invention has a _ piece, and the release type 201107437 will be bonded. The agent layer is attached to the glass substrate, for example, as a liquid crystal display panel. 5N/25mm~10N。 The N. 5N/25mm~10N /25mm adhesion. The initial adhesion of the palpitations can be calculated, for example, in the following manner. Regarding the sheet with the adhesive agent 'cut to width 25_, peel off the release film: 2i: ^^iormng 1 rc〇rmng 1737^5 ^ χΐ ί °, then carry out the treatment of ClaVe) (5G ° C, G. 5MPa, test ^ 23 ° C, _. H. After standing for 24 hours, carry out (10) peeling, make money, optical components are not special Ma Ding 'liquid crystal display device, organic electro-optical, PDP and other image display skirts are applicable The silk film, for example, a polarizing plate iiii, an ellipsoidal deviation, an optical compensation film, a brightness enhancement film, and the like are laminated. Among them, especially a polarizing plate is effective in the present invention. A fine two-sided laminated triacetate fiber 10^000 - rr 85'1 〇 potassium aqueous solution or a two-color uniaxial I stretch (opening, stretching ratio of 2 to 1 〇, preferably 3~ It is about 7 times.) B, "2 ethoxylated resin" is usually produced by polymerizing acetic acid into a polyacetic acid. However, it may contain a small amount of unsaturated orthoic acid (salt and salt). , a class, an ethylene group, an unsaturated salt, etc., may be combined with a component of acetic acid, ruthenium, ketone, and the like. Further, the polyvinyl alcohol is 盥 in the presence of an acid. Polyethylene condensate and other so-called polyethylene-based shrinkage are intended to be used in detail in the case where the adhesive of the present invention is used for an optical member. (4) The adhesive is used in temporary surface protection applications. Temporary protection use m month. The adhesive of the present invention is used for temporary surface protection 32 201107437 - When used as a temporary surface protection adhesive, the adhesive composition [丨] can contain the above acrylic system The ionic compound (B) component of the resin (A) or bis(fluorosulfonyl) quinone imine is hardened by electron rays, and further, it is preferred to contain the unsaturated group-containing compound (C) and polymerize. At least one of the components of the initiator (D) and the crosslinking agent (E) is used as a woven age [I] 'crosslinking to make it easy to turn over, and more preferably, it is a propionate, a propionic acid resin, In addition to the ionic compound (8) and the crosslinking agent (E) component of the bis(fluorocontinuum) anionic anion, the binder composition of the unsaturated group-containing compound (6) and the polymerization initiator (D) is also available [ I] cross-linking into an adhesive. As a temporary surface protection eluent, the acrylic resin (1) can be used with the above-mentioned C. Acid-based resin (the same as the magical one. As a temporary surface-protecting compound, the unsaturated group-containing compound used in the adhesive is the same as the above-mentioned unsaturated group-containing compound (the same, but among them) „ Crosslinking density, it is preferable to use a polyfunctional one, that is, a compound having two or more unsaturations. More preferably, it is a diene having three or more unsaturated groups: 匕 is preferably an unsaturated group having four or more unsaturated groups. , ^, an unsaturated group-containing compound having 5 or more unsaturated groups in the cage. = group; ri: group) propylene riding compound or fortunately, especially containing a stretching diol chain and containing the right It is preferred to use a sulfonate (meth)acrylic acid vinegar compound. l and the weight of the amine of the soil is not: ί content 'relative to the content of the acrylic resin (Α) 100 is too small, the failure of the combination is insufficient, the compound of the saturated group (the original ==, if too much, there is stickiness: The reduced ί is used as a polymerization start-up for use in the case of contamination of the adherend, and the cross-linking agent (8) at the time of the above-mentioned service can be used, and the adhesive composition (1) can be used for curing. Adhesive for surface protection 33 201107437 It is useful to use a protective adhesive sheet. Dimethyl: ts is not limited to ^^^, for example, polynaphthalene polyethylene, polypropylene, polyfluorene is used as a polyester resin; ethylene, polyglycol, etc. Polyvinyl fluoride?, ethylene, polyvinyl chloride/vinyl acetate s ugly polymer, B, '6, etc. polyamine; polychloroethylene-vinyl alcohol copolymer, polyvinyl alcohol:; 1 acid ethyl _ copolymer, material, · cellulose triacetate, cellulose and other fibers ^ ln ^ one) and other vinyl polymerized polyethyl methacrylate, polyacrylic acid poly 3 :: methyl methacrylate, f = acetamidine; a woven fabric composed of polycarbonate, polyaryl I, or synthetic fibers, or a nonwoven fabric or a laminate of two or more layers. The special base is used for the early layer body. For the western coffin, if the price is considered, it is preferable to use a synthetic resin film or sheet of polyethylene terephthalate-formic acid-sigu, polyethylene, polypropylene or the like. Ding Ben-Jia Yi Yi B-Zizi w i1ί improved the misidentification of the adhesive to the substrate, but also for its good 矣 &amp; ^ power-on military discharge treatment, plasma treatment on the substrate surface treatment and other improvements Easy-adhesive treatment, and rough surface electrical layer. The horse is resistant to electric stagnation, and the thickness of the substrate can be set to be antistatic. The thickness of the substrate is not particularly limited. Preferably, it is 5 to 2 (K) Am, especially = 2 is 0, and the The thickness of the adhesive composition (1) of the above substrate is the right thickness. After drying, for example, a boat A 1 ± dryness, not particularly limited, dry

Vs;;: ' = The right is too thin, then the adhesion to the attached body = S is combined with the attached body, there will be attachments and temporary debris when the temperature is high, temporary surface protection miscellaneous (four) turn Problem ^ 34 201107437 ' Until the temporary surface protection bonding sheet is attached to the adherend, in order to protect the adhesive from contamination, a separator may be laminated on the surface of the adhesive. As the separator, a synthetic resin film or sheet, paper, cloth, or woven material exemplified above may be subjected to release treatment. When the adhesive composition [1] is provided on the above substrate, generally, in the case of the solution of the adhesive composition and L], especially after adjusting the viscosity of the solvent, it is suitable for coating and coating on Into the dry. The coating method, for example, a direct coating method of a solution-like adhesive composition green cloth on a substrate, or a solution-like adhesive composition [I] k is attached to the substrate and then attached to the substrate. Combined transfer coating method and the like. In the coating method, for example, a method of applying an adhesive composition (1) to a substrate and heating it to dry, and then irradiating the active energy ray, and then adhering the separator, or a composition of the splicing agent, I] and after heating, the separator is attached, and then: according to two = shot, _ method, and the like. The coating can be carried out, for example, by a method such as a co-coating method, a die coating method, a gravure strip method, a comma coating method, or screen printing. The soil is from the "Λ-face, in the transfer coating, for example: the age-old coating adhesive composition of the ancient LSf heat dry test, according to the energy energy ray, the method of the later age substrate, ^ two * piece coating The agent shouts &quot;] and heats the drying 彳 ", the method of bonding the substrate, the ί = active energy ray, etc. The coating method can be used and directly coated with the temporary surface protection adhesive sheet The type of the adherend is not particularly limited to the metal case, the synthetic tree or sheet, the paper, and the woven fabric listed in the above-mentioned substrate. Further, for example, a glass plate, a synthetic resin plate, or a metal plate. The initial adhesion force can be based on the attachment of the ΓΓμ寺 to the field, such as when attached to the SUS30 tear board, the official Chenggu 01N/25^50N/25mm

〇.〇2N 25»ΧΗ). After the leg 'put it in 2 coincidence: 么' cut: 35 201107437 2kg rubber mixed back and forth twice as a quilt or acrylic sheet (PMMA board), made the tester steel plate (10) 3_ board), placed 30 After a minute, the stripping test is performed in the same gas atmosphere, and the measured adhesive force (N/25mm) is used as the initial entanglement [80 degree peeling test start" force speed stripping _ relay, usually for the film 'In 23t: The relative humidity of 50% of the body atmosphere method test in the same gas atmosphere, the peeling speed of 30m / ml = ^ 301 children. After that, it is not limited to the following embodiments in the case of (1). Also, in the examples, and unless otherwise specified, it means a weight basis. Know and "%" right Ι / / / as follows - prepared a variety of __, resin, various unsaturated &lt; Further, the weight average molecular weight, the degree of dispersion, and the temperature of the glass lion of the acrylic resin were measured in accordance with the methods described above. In addition, the viscosity is measured in accordance with JIS Κ5400Ο990) by the 4.5.3 rotary viscometer method: [, preparation of [acrylic resin (Α)] (refer to Table 2) [acrylic resin (Α-1)] A 4-point round bottom flask of a reflux condenser, a stirrer, a nitrogen gas inlet, and a thermometer was charged with 100 parts of ethyl acetate, and azobisisobutyronitrile (ΑΙΒΝ) 作为. 05 parts as a polymerization initiator was added. The mixture was heated while stirring, and a mixture of 30 parts of 2-hydroxyethyl acrylate (al), 69 parts of butyl acrylate (a2), and 1 part of acrylic acid (a3) was added dropwise at 78 °C for 2 hours. The polymerization starter liquid obtained by dissolving ΑΙΒΝ0. 05 parts of the ethyl acetate was added in one part of the polymerization, and the mixture was polymerized at the reflux temperature of ethyl acetate for 3.5 hours to obtain an acrylic resin (A). —i) Solution (weight average molecular weight (Mw) 800,000, dispersion (Mw/Mn) 4.5, glass transition temperature - 45 t: 35% solid content, viscosity 70 〇〇 1 ^ 3.3 (25 〇). In addition, the HLB of the acrylic resin (A-1) is calculated by the following calculation and is 7.42. 36 201107437 • When 2-hydroxyethyl acrylate at the time of polymerization is decomposed into each component, (CH2: -0) 475) (CH: -0.475) (C00:2.4) (CH2:-0. 475) (CH2:-〇. 475) (0H: L9), so the HLB value = the base of the hydrophobic group + The base of the hydrophilic group +7 = {(-0. 475X4) + {(2. 4) + (1. 9)) + 7-9. 4. Similarly 'if for acrylic acid (CH2: -0.475) (CH: -0.475) (C00H: 2.1) Also calculated, HLB value = {(-G. 475)X2} + (2.1) + 7 = 8.15. Similarly, for butyl acrylate (CH2:- 0. 475)(CH:-0.475) (C00:-2. 4)(CH2:-0. 475)(CH2:-0. 475)(CH2:-〇. 475)(CH3:-〇. 47 5 ) Also calculated, HLB value = {(-0. 475)X6} + (2. 4) + 7 = 6. 55 • The olefinic resin (Al) = BA / HEA / AAc = 69 / 30/1 ' Therefore, if the above calculated values are multiplied by the content ratio of each monomer, the HLB value: (6. 55X69 + 9. 4X3Q + 8.15 Xl)/lQQ=7. 42 [Acrylic Resin (A-2)] In a 4-neck round bottom flask equipped with a reflux condenser, a stirrer, a nitrogen gas inlet and a thermometer, 2-ethyl peracetate was added. (al) 10 parts, 40 parts of 2-methoxyethyl acrylate (al), 49 parts of butyl acrylate (a2), 1 part of acrylic acid (a3), 140 parts of ethyl acetate, and 45 parts of acetone 'heated After the refluxing was started, azobisisobutyronitrile (AIBN) 0.03 was added as a polymerization initiator, and after reacting at reflux temperature for 3 hours, it was diluted with ethyl acetate to obtain an acrylic resin (A-2) solution ( The weight average molecular weight (Mw) is 1,000,000, the degree of dispersion (Mw/Mn) is 4.3, the glass transition temperature is -49 ° C, the solid content is 20%, and the viscosity is 5000 mPa. s (25 ° C)). Further, the HLB of the acrylic resin (A-2) was 7.55. [Acrylic Resin (A-3)] In a 4-neck round bottom flask equipped with a reflux condenser, a stirrer, a nitrogen gas inlet, and a thermometer, 10 parts of 2-ethyl acrylate (al) was added. 40 parts of 2-methoxyethyl acrylate (al), 50 parts of butyl acrylate (a2), 140 parts of ethyl acetate, and 45 37 201107437 parts of propylene mesh. After heating and refluxing, azo was added as a polymerization initiator. Bis-isobutyronitrile (ΑΙΒΝ) 0·03 parts 'reacted at reflux temperature for 3 hours, and then diluted with ethyl acetate to obtain an acrylic resin (Α-3) solution (weight average molecular weight (Mw) 12 million, dispersion degree ( Mw/Mn) 4.6, glass transition temperature -5 (Tc, solid content 20%, viscosity 4700 mPa · s (25 ° C)). Further, the acrylic resin (A-3) has an HLB of 7,54. Acrylic resin (A-4)] In a 4-neck round bottom flask equipped with a reflux cooler, a scrambler, a nitrogen inlet, and a thermometer, 5 parts of 2-ethyl acrylate (ai) and butyl acrylate were added. (a2) 94. 5 parts, acrylic acid (a3) 0-5 parts, ethyl acetate 1 part, acetone 45 parts, after heating and refluxing, adding azobisisobutyronitrile (AIBN)O as a polymerization initiator . 03份, The dispersion of the acrylic resin (A-4) (weight average molecular weight (Mw) 1.58 million, dispersion (Mw / Mn) 3. 7 after the reaction was carried out at the reflux temperature of ethyl acetate for 3 hours. The glass transition temperature is _5 〇, the solid content is 18%, the viscosity is SOOOmPa. s (25 〇 C)), and the HLB of the acrylic resin (A-4) is 6.70. [Acrylic resin (A -5)] In a 4 ^ round flask equipped with a reflux condenser, a stirrer, a nitrogen gas inlet, and a thermometer, 'additional acid 2 - wire ethyl g (al) 1.5 parts, acrylic butyl brewing ^ 2 98 parts, acrylic acid (&amp;3) 〇. 5 parts and ethyl acetate period, 45 parts of acetone, do:, back &quot; after the start of IL, add azobisisobutyronitrile as a polymerization initiator (aibn) After reacting for 3 hours at reflux temperature, the solution was diluted with ethyl acetate to obtain a solution of 1 A to 5) (weight average 'molecular weight (Mw) 1.65 million, dispersed shoulder (M = Mn 5, glass transition temperature - 55). The solid content m, the viscosity _〇mpa s (25 C)). The HLB of the acrylic resin (A-5) is 6.60. [Table 2] 38 201107437 Acrylic resin (A) BA (part) HEA (part) AAc (part) MEA (part) weight average molecular weight (Mw) dispersion { M w / Μη) glass transition temperature ΓΟ HLB A-1 69 30 1 800,000 4. 5 — 4-5 7. 42 A—2 49 10 1 40 1.2 million 4. 3 -49 7. 55 A-3 60 10 40 1.2 million 4. 6 -50 7. 54 A—4 04. 5 5 0, B -----— 1.58 million 3. 7 -50 6. 70 A—5 98 1.5 0. 5 1.65 million 3. 5 —55 6. 60 (Note) BA: butyl acrylate HEA: 2-hydroxyethyl acrylate AAc: Acrylic acid MEA: 2-methoxyethyl acrylate [ Ionic compound (B)] The following ionic compound (B-1) was prepared. • Potassium bis(fluorosulfonyl) quinone The following ionic compound (B-2) was prepared. - Bis(fluorosulfonyl) quinone imine 1,3-dimercaptoimidazole rust salt The following ionic compound (B-3) was prepared. • Sodium bis(fluorosulfonyl) quinone The following ionic compound (B'-1) was prepared. • Potassium bis(trifluoromethylsulfonyl) phthalimide The following ionic compound (B' -2) was prepared. • Potassium bis(nonafluorobutylsulfonyl) phthalimide The following is prepared as an ionic compound (B' -3). • bis(nonafluorobutsulfonyl) quinone imine 1-ethyl-3-methylimidazolium salt and 'the above ionic compounds (B-1), (B-2), (B-3), B -1), (B -2) and (B, -3) are all solid at normal temperature. 2份。 Isophorone diisocyanate was added to a 4-neck round bottom flask equipped with a reflux cooler, a sandalizer, a nitrogen inlet and a thermometer 19.2 parts , bis-tert-butylhydroxy 39 201107437 phenol 0. 05 parts, dibutyl tin laurate 〇. 〇 2 parts, below 5 (TC, make quatar tetraol ester of tetrapropionic acid and pentaerythritol tetraacrylate 80.8 parts of a mixture (light acrylate PE-3A, hydroxyl value I20 mg KOH/g) manufactured by Kyoeisha Chemical Co., Ltd., and the reaction was continued at 70 ° C to obtain an unsaturated group-containing compound (C-1). [Photopolymerization initiator (D)] The following is prepared as a photopolymerization initiator (D-1). • A mixture of diphenyl ketone and 1-hydroxycyclohexyl ketone in a mass ratio of 1:1 ("Irgacure 500" manufactured by Chiba Speciality Chemicals Co., Ltd.) [Crosslinking agent (E)] The following is used as a crosslinking agent (E-1). • Ethyl phthalocyanine-added indole benzene diisocyanate adduct is dissolved in 55% ethyl acetate (manufactured by poly本polyurethane) "coronate L-55E") [Oxygen-containing alkyl group-containing compound (F)] The following compound (F-1) is prepared as an oxygen-containing alkylene group. Dioxin (His〇ive MTEM, manufactured by Toho Chemical Co., Ltd.) [Hydrane coupling agent (G)] The following is prepared as a decane compound (G-1). T-glycidoxypropyl trioxane Base decane (Shin-Etsu Chemical Co., Ltd., "KBM403") [Examples 1 to 6 and Comparative Examples 1 to 4] The respective components prepared and prepared as described above were blended at the ratios shown in Tables 3 and 4 below. The adhesive composition which is a material for forming an adhesive for an optical member is prepared, and is diluted with acetophenone (viscosity [1〇〇〇~1〇〇〇〇mPa.s (2' month for making an adhesive composition solution) c)]), then 'the above adhesive composition solution is coated on a polyester release sheet and dried to a thickness of 25/iin at 9 (after 3 minutes of TC drying, the resulting viscous composition) Layer-side transfer on polyethylene terephthalate (PET) 臈 (thickness &amp;, electrodeless lamp made by FUSION [LH6UV lamp ] bulb] ^ + degree: 600mW/cm2, cumulative exposure :24〇mJ/cni2 is UV=(120mJ/cm2 '2 pulses), and then at 23°C, 65%RH·, 成成201107437 ίο曰, to obtain an adhesive layer pET film. 1 [Examples 7 to 12, Comparative Examples 5 and 6] The respective components prepared and prepared in the above manner were prepared in the following table: kg = ratio, and were prepared as an adhesive forming material for optical members. The ^= f product is diluted with methyl ethyl hydrazine (viscosity [丨〇〇〇七〇〇〇〇必' month to make the adhesive composition solution. <AC)]), dry; ϊ ϊ? The binder composition solution is coated on a polyester release sheet to form a layer of a top alcohol SI (PET) film (thickness 38 eggs), so that it is aged for 1 G, and the adhesive is obtained. The PET film of the adhesive layer has a surface resistivity and a gel fraction according to the following. These results are combined and displayed in the column ^3 [surface resistivity], and the tantalum film is cut to a size of 4 〇 X 4 〇 mm, and the surface resistivity is measured. In addition, in Table 2: [gel fraction] type sheet, after the PET with the adhesive layer is cut into 4 〇 X40 faces, after peeling off the sus mesh (shen) from the 5QX1GGmm, Γ The weight change at the time of the table is used to determine the rate of condensation. 41 9 201107437 Acrylic resin (A) Ionic compound (B) Compound containing unsaturated group (C) Polymerization initiator (D) Crosslinking agent (E) Compound containing oxygen extended alkyl group (F) Coupling agent (G) Gel fraction (8) Surface resistivity (Ω/Π) A-1 B-1 C-1 D-1 E-1 G-1 Example 1 - 96 7X109 100 5 15 1.5 0.5 0. 2 A-2 B-1 C-1 D-1 E-1 GL Example 2 - 96 6X109 100 3 15 1.5 3 0.2 A-2 B-2 C-1 D-1 E-1 G-1 Example 3 - 96 5X109 100 3 15 1.5 3 0.2 A-3 B-2 C-1 D-1 E-1 G-1 Example 4 - 95 5X109 I 100 3 15 1.5 3 0.2 A-1 B-1 C-1 D -1 E-1 F-1 G-1 Example 5 91 3X109 100 5 15 1.5 0.5 5 0.2 A-2 B-1 C-1 D-1 E-1 F-1 G-1 Example 6 93 3X109 100 3 15 1.5 3 3 0.2 A-4 B-1 E-1 Example 7 - - - - 68 ιχιο1. 100 3 0.1 A-4 B-2 E-1 Example 8 - One - - 72 4X1010 100 3 0.1 Example 9 A-4 B-3 - - E-1 - - 71 6X103 42 201107437 100 3 0.1 Example A -2 B-1 E-1 F-1 60 8X108 10 100 3 0.2 3 Example A-4 B-1 E-1 F-1 69 ιχιο9 11 100 3 0.1 3 Example A-5 B-1 E-1 F-1 65 2X109 12 100 3 0.1 3 [Table 4] Acryl acrylate resin (A) Ionic compound (B) Compound containing not 1 package and group (C) Polymerization initiator (D) Crosslinking agent ( E) Oxygen-containing compound (F) Shixi burning coupling agent (G) Gel fraction (8) Surface resistivity (Ω/mouth) A-1 B,-1 C-1 D-1 E-1 G-1 Comparative Example 1 - 97 ιχιο10 100 5 15 1.5 3 0.2 A-1 B, -2 C-1 D-1 E-1 G-1 Comparative Example 2 - 96 4X1010 100 5 15 1.5 3 0.2 A-2 B ' -1 C-1 D-1 E-1 G-1 Comparative Example 3 - 96 2Χ1010 100 5 15 1.5 3 0.2 A-2 B,-3 C-1 D-1 E-1 G-1 Comparative Example 4 — 97 ιχιο10 100 5 15 1.5 3 0.2 Comparative Example 5 A-4 B,-2 - - E-1 - - 65 2Χ1011 43 201107437

$: The values in the tables in (A) to (G) are the parts by weight. Installed two J J glands '^ 士 Ο Ο &gt; 4 / / L. One time 'will be the solution of the adhesive composition of Examples 2 to 4, the type of month makes the thickness of the dry test 25 #m, at 9 (rc 3 a = the adhesive composition layer is transferred to the polarizing plate (thickness 19 = '= into r: should be r-free electrodeless lamp [face = lamp $ · 60 (Μ / αιι, cumulative exposure: 24 〇mJ/cm2 : , 2 pulses), after Yu Kai, _ pieces

10曰, a polarizing plate having an adhesive layer was obtained. H Take the person ί 'The above polarizing plate' is a film of a polyvinyl alcohol polarizing film (average 1·, average test degree 99 mol%, moth dyeing, 4 times extension) with a film thickness of 30 Å. A layered polarizing plate (the direction of the axis of extension of the polyvinyl alcohol polarizing film was inclined by 45 degrees and cut into 10 mm×10×mm). In this way, a polarizing plate having an adhesive layer was obtained, and the durability was measured and evaluated according to the following methods (heat and humidity resistance test, heat cycle test, heat test), and adhesion force. The results of these and the like are collectively described in Table 5 below. [Durability] The obtained release sheet of the polarizing plate having the adhesive layer was peeled off, and the adhesive layer was flanked by a glass plate (Corning, Inc., Corning 1737), and a polarizing plate and a glass plate were pressed. After the bonding, hot pressing treatment (5 〇〇 c, 〇. 5 MPa, 2 〇 minutes) was performed, and thereafter, foaming, peeling, and light leakage in the following endurance test (damp heat resistance test, heat cycle test, heat resistance test) were evaluated. phenomenon. Further, in the heat resistance test alone, the same sample was bonded to both the front and back surfaces, and the polarizing plate was crossed and crossed for observation of light leakage. Further, the size of the test piece used was 1 〇 cm X 10 cm for heat and humidity resistance, and 20 cm &lt; 15 cm for heat resistance test. [Endurance test] 44 201107437 (1) Heat and humidity resistance test 60 C, 90% R. Η., 1 hour endurance test (2) Thermal cycle test minute operation as 1 = placed at ~4〇ΐ for 3 minutes After placing 30 _ 亍 (10) cycles at 85 ° C _ long test (3) heat resistance test 8 〇 C, 1 〇〇 hours of endurance test [evaluation basis] (foaming) 〇 · ·. almost no foaming △ 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见 见The smear X··· has a peeling of 10 mm or more or a floating mark of 1 〇 or more (light leakage). The evaluation of light leakage was performed only for the above (3) heat resistance test. 〇······················································································································· The side of the adhesive layer is pressed against the glass plate (c 〇 〇 rningl737), and the polarizing plate is attached to the glass plate = 20 ^ &lt; 4) 24 away! The hope is that the bonding force is small, so that the future should be / 25mm is the target. [Table 5] 45 201107437

(Fluor: The sub-containing fine imine anion, that is, the double perfluorinated silk f-containing the ionic agent, contains an ion-bonding agent, and it is known that the antistatic property is effectively improved. Moreover, under the conditions of high temperature and high humidity, the optical laminate盥 璁 璁 璁 璁 璁 璁 璁 与 与 与 与 与 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁 璁It is very useful. [Industry Miscellaneous (4) A, Miscellaneous Wire is also excellent. The miscellaneous agent of the present invention does not (4) have static electricity generated in each step, [Simple description of the figure] No [Main component symbol description] Benefit * »&gt;&gt; 46

Claims (1)

201107437 VII. Patent application scope: The adhesive composition of the olefinic resin (4) and the resin item, wherein the acrylic 雔 (,ί, the adhesive composition of the first or second range, wherein The cation portion of the ionic compound (8) which is a cation of the cation of the cation of the genus is a metal cation or a conjugated cation of 3 (10). The subunit is a conversion product of the third item of H 申子利细, wherein the metal cation is 5. The adhesive composition of the third paragraph of the patent scope, wherein the cationic compound of the hetero-f compound contains an imidaZQlium cation. The adhesive is characterized by a patent application scope. The adhesive composition of any one of the first work is cross-linked. A, a person such as a towel, a special item, a sixth item, a towel, a compound of a binder composition (6) and The polymerization starts _) and is formed by active energy ray and/or thermal crosslinking. The adhesive of the invention is as claimed in claim 6 or claim 7, wherein the dopant composition further comprises a crosslinking agent (E) and is crosslinked by using the crosslinking agent (E). 9. An adhesive for an optical member, which is obtained by using the adhesive of any one of claims 6 to 8. 10. The adhesive for optical members according to claim 9 of the patent application, wherein the member is a polarizing plate. U.a. An optical member having an adhesive layer, which is obtained by laminating an optical member adhesive agent according to claim 9 or 10 to an optical member.廿12, an adhesive composition comprising an acrylic resin (a) and an ionic compound (B) having a bis(fluorosulfonyl I醯 imine anion), the characteristics of which are: The copolymerization component of the acrylic resin (A) contains an oxyalkylene-containing (fluorenyl)acrylic monomer (al) represented by the following general formula (1), and (al) 47 201107437 The content of 201107437 is 5 to 100% by weight Y (1) 々〇, (X-〇) r (wherein X is a stretching group, and hydrazine is a hydrogen atom, an alkyl group, an aryl group or An aryl group, Ri is a hydrogen atom or a fluorenyl group, and η is an integer of 1 or more. 13·--A binder composition contains an acrylic resin (a), and is chelated (ion ion of cerium ion) The compound (8), and the compound (8) having an oxygen-extended base structure and an oxygen-extension group are compounds containing a hydroxy group and a hydroxyl group-free compound. Fig.: * », 48