201106983 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種清潔劑。 【先前技術】 先别，於皮膚清潔劑中，由於高氣泡性之特徵而廣泛利 用烷基硫酸鹽或磺酸鹽、高級脂肪酸鹽等陰離子界面活性 劑作為主成分。然而，該等陰離子界面活性劑雖然於清潔 後可獲得清爽之感覺，但存在感到緊繃或乾燥之問題。作 為降低清潔後之緊繃感而賦予濕潤之滋潤感之方法，提出 有不使局濃度地調配有多元醇之清潔劑起泡而直接塗佈於 肌膚上，並進行沖洗之皮膚清潔方法（專利文獻1)〇然而， 於皮膚清潔劑中，通常係於起泡後將泡狀之清潔劑塗佈於 臉上一面按摩一面清潔，故不實施不起泡而直接塗佈之原 本之使用方法，而無法發揮充分之效果的情形較多。 另一方面，由於將清潔料組合物填充至發泡容器中使其 以泡狀噴出而使用之「泡型清潔料」能夠以紋理細膩之泡 一面按摩一面清潔而對皮膚之摩擦較少、且相較以手使清 潔劑起泡更為簡便，因此廣泛使用。泡型清潔料亦為將自 發泡容器喷出之泡直接塗佈於皮膚上而使用者，因此若於 清潔料中調配多元醇，則可期待於清潔後獲得濕潤之滋潤 感。 然而，若於清潔料中高濃度地調配多元醇，則組合物之 黏度上升，於用於發泡容器之情形時，泡之噴出性變差。 特別是存在低溫下泡之紋理較粗，保形性變差之問題（專 149508.doc 201106983 利文獻2、專利文獻3)。因此，無法於填充至發泡 m 之清潔料組合物中高濃度地調配多元醇。 [先前技術文獻] [專利文獻] [專利文獻1 ]日本專利特開200 1 -1 72 1 68號公報 [專利文獻2]日本專利特開2004-137247號公報 [專利文獻3]日本專利特開2008-94903號公報 【發明内容】 [發明所欲解決之問題] 本發明之目的在於提供一種清潔劑’其大量含有多_ 醇’可實現清潔後之濕潤之滋潤清洗，同時清潔料之點户 較低’於填充至發泡容器之情形時，亦可於低溫下獲得紋 理細膩之良好之泡。 [解決問題之技術手段] 本發明者等人發現，藉由組合特定之陰離子界 四’舌性 劑’且組合使用 IOB(Inorganic Organic Balance)值；^ a +同之 多元醇等，可獲得解決上述課題之清潔劑。 本發明提供一種清潔劑’該清潔劑係將如下清潔料填充 至發泡容器中而成，該清潔料包含下述成分（A)〜. (A) 具有硫酸基之陰離子界面活性劑； (B) 高級脂肪酸鹽或醚羧酸型界面活性劑； (C) IOB值為3.4以上且未達6之多元醇； 示 (D) IOB值為0.1以上且未達3.4之多元醇或通式（^所 之醇： 149508.doc 201106983 R,-(OCH2CH2)n-〇H (1) (式中’ R1表示碳數1〜5之炫基或烯基，n表示2〜2 〇〇之 數）； (Ε) 水；且 成分（Α)〜(D)之重量比例為： {(Α)+(Β)} = 1 〜10重量％ ; (C) =30~60重量％ ; (D) /(C)=0.01 〜卜 [發明之效果] 本發明之清潔劑大量含有多元醇，可實現清潔後之濕潤 之滋湖 洗，同時清潔料之黏度較低，於填充至發泡容器 中使用之情形時’亦可於低溫下獲得紋理細膩之良好之 泡，清潔力及穩定性亦優異。 又，本發明之清潔劑可將自發泡容器嘴出之泡直接塗佈 於皮膚而使用’因此可發揮含有高濃度之多元醇之清潔料 之配方的特性。 【實施方式】 本發明中所使用之成分（A)之陰離子界面活性劑係具有 硫酸基者。 作為該陰離子界面活性劑，可列舉烷基硫酸醋、聚氧伸 烷基烷基醚硫酸酯或其鹽等。該等較佳為具有碳數6〜22之 直鏈或支鏈烷基者。該等之中，就低刺激性方面而言，較 佳為聚氧伸烷基醚硫酸酯’進而較佳為聚氧乙烯（平均加 成莫耳數〇·5〜8)院基鍵硫酸鹽。 149508.doc 201106983 又’作為成分（A)之鹽，可列舉鈉、鉀等鹼金屬；銨； 胺基甲基丙醇等炫醇胺；離胺酸、精胺酸等驗性胺基酸。 本發明中所使用之成分⑺）為高級脂肪酸鹽或醚羧酸型 界面活性劑。 高級脂肪酸較佳為具有碳數6〜22之直鏈或支鏈烷基者。 又，醚羧酸型界面活性劑係經由聚氧乙烯鏈或二醇醚單 元而具有疏水基與羧基之化合物群，例如可列舉烷基醚乙 酉文或/、〇»»_燒基羥基醚乙酸或其鹽、院基醯胺醚乙酸或其 鹽。分別較佳為以下之通式所示者。 [化1]201106983 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a cleaning agent. [Prior Art] In the skin cleansing agent, an anionic surfactant such as an alkyl sulfate or a sulfonate or a higher fatty acid salt is widely used as a main component due to the characteristics of high bubble. However, although these anionic surfactants have a refreshing feeling after cleaning, there are problems of feeling tight or dry. As a method of reducing the moisturizing feeling after cleaning, a moisturizing method is provided, and a skin cleaning method in which a detergent having a concentration of a polyol is not foamed and directly applied to the skin and rinsed is proposed (patent [1] However, in the skin cleansing agent, the foaming detergent is usually applied to the face after foaming and is cleaned by massage. Therefore, the original method of application without direct application of the foam is carried out. There are many situations in which sufficient effects cannot be achieved. On the other hand, the "bubble type cleaning material" which is used by filling the cleaning material composition into a foaming container and ejecting it in a bubble shape can be cleaned with a fine texture of the foam while being less rubbed against the skin, and It is widely used because it is easier to foam the detergent by hand. The foam type cleaning material is also applied directly to the skin by spraying the foam sprayed from the self-foaming container. Therefore, if the polyol is blended in the cleaning material, it is expected to obtain a moist moisturizing feeling after cleaning. However, when the polyol is blended at a high concentration in the cleaning material, the viscosity of the composition rises, and when it is used for a foamed container, the discharge property of the foam is deteriorated. In particular, there is a problem that the texture of the bubble at a low temperature is coarse and the shape retention property is deteriorated (prof. 149508.doc 201106983, and the patent document 3). Therefore, it is impossible to mix the polyol at a high concentration in the cleaning composition filled into the foaming m. [PRIOR ART DOCUMENT] [Patent Document 1] Japanese Patent Laid-Open Publication No. JP-A No. 2004-137247 [Patent Document 2] Japanese Patent Laid-Open Publication No. JP-A No. 2004-137247 SUMMARY OF THE INVENTION [Problem to be Solved by the Invention] An object of the present invention is to provide a cleaning agent which contains a large amount of poly-alcohol to achieve moisturizing and moisturizing after cleaning, and at the same time The lower 'in the case of filling to the foaming container, it is also possible to obtain a fine foam with good texture at a low temperature. [Technical means for solving the problem] The present inventors have found that a combination of a specific anionic four-tongue agent and a combination of IOB (Inorganic Organic Balance) value; A cleaning agent for the above problems. The present invention provides a cleaning agent which is obtained by filling a cleaning material comprising a following component (A) to (A) an anionic surfactant having a sulfate group; (B) a higher fatty acid salt or an ether carboxylic acid type surfactant; (C) a polyol having an IOB value of 3.4 or more and less than 6; (D) a polyol having a IOB value of 0.1 or more and less than 3.4 or a formula (^) Alcohol: 149508.doc 201106983 R,-(OCH2CH2)n-〇H (1) (wherein R1 represents a decyl or alkenyl group having a carbon number of 1 to 5, and n represents a number of 2 to 2 〇〇); (Ε) water; and the weight ratio of the ingredients (Α) to (D) is: {(Α)+(Β)} = 1 to 10% by weight; (C) = 30 to 60% by weight; (D) / ( C)=0.01 〜b [Effects of the Invention] The cleaning agent of the present invention contains a large amount of a polyhydric alcohol, which can achieve a moist moist lake washing after cleaning, and the viscosity of the cleaning material is low, and is used in filling into a foaming container. At the time of low temperature, it can also obtain a fine foam with good texture and excellent cleaning power and stability. Moreover, the cleaning agent of the present invention can directly apply the foam from the mouth of the foaming container to the skin and use it. Therefore, the characteristics of the formulation of the cleaning material containing a high concentration of the polyol can be exhibited. [Embodiment] The anionic surfactant of the component (A) used in the present invention has a sulfate group. Examples thereof include alkyl sulfate vinegar, polyoxyalkylene alkyl ether sulfate or a salt thereof, etc. These are preferably those having a linear or branched alkyl group having 6 to 22 carbon atoms. Among them, low stimulation In terms of properties, it is preferably polyoxyalkylene ether sulfate, and more preferably polyoxyethylene (average addition molar number 5·5~8) of hospital-based key sulfate. 149508.doc 201106983 The salt of the component (A) may, for example, be an alkali metal such as sodium or potassium; ammonium; an amine amine such as aminomethylpropanol; or an amino acid such as aminic acid or arginine. (7)) is a higher fatty acid salt or ether carboxylic acid type surfactant. The higher fatty acid is preferably a linear or branched alkyl group having a carbon number of 6 to 22. Further, the ether carboxylic acid type surfactant is a compound group having a hydrophobic group and a carboxyl group via a polyoxyethylene chain or a glycol ether unit, and examples thereof include an alkyl ether oxime or /, 〇»»-alkyl hydroxy ether acetic acid. Or a salt thereof, a hospital base of hydrazine ether acetate or a salt thereof. Each of them is preferably represented by the following general formula. [Chemical 1]
R2—0(CH2CH20)mCH2-C00XR2—0(CH2CH20)mCH2-C00X
R3—CHCH2OCH2 一 COOX OHR3—CHCH2OCH2 — COOX OH
R4H—(CH2CH20)mCH广COOX OH (式中’ R2、R3及R4分別表示碳數1〇〜18之燒基或稀基，@ 表示平均為0.5〜Η)之數，χ表示氫原子、驗金屬H 醇胺或驗性胺基酸） 同者， 胺；離 又，作為成分（B)之鹽，可列舉與成分（A)之鹽相 可列舉鈉、鉀等鹼金屬；銨；胺基甲基丙醇等=醇 胺酸、精胺酸等鹼性胺基酸。 作為成分（B)，就起泡性高且清潔中之泡之維持良 方：而言’較佳為高級脂肪酸鹽’進而較佳為碳數: 之南級脂肪酸鹽。 149508.doc 201106983 於本發明中，藉由組合使用（A)具有硫酸基之陰離子界 面活性劑、與⑻高級脂肪酸鹽或驗幾酸型界面活性劑， 可自發泡容器噴出紋理細腻之泡。 於本發明中，清潔财Μ分(A)與（B)之含量分別較佳為 〇.5〜10重量％，更佳為卜4重量％，進而較佳為】5〜3重量。 又，清潔料中之成分（A)與（B)之含量合計為1〜10重量 %’較佳為2〜8重量％，進而較佳為3〜5重量％。成分⑷與 (B)之合計含量為1ί4%以上時，清潔力與泡之維持性能 良好’為1〇重量％以下日夺，自低溫下之發泡容器之泡之喷 出性、低溫保存時之穩定性優異。 又，成分（Α)與（Β)之重量比例於（八)/(3)為〇丨以上時，低 溫保存時之穩定性良好，為9以下時，可獲得清潔後之濕 潤之滋满感，故而較佳。進而，就同時實現清爽感與濕潤 感之觀點而言，較佳為（A)/(B)=〇1〜4，進而較佳為 0.15〜3 ’更佳為〇.2〜2。 本發明中所使用之成分（C)之多元醇係I〇B值為34以上 且未達6’較佳為3.4〜5者。藉由使用該多元醇，可實現洗 完後之濕潤之滋潤感。 此處，所謂IOB，係表示依據有機概念圖（藤田穆，有機 化合物之預測與有機概念圖，化學領域v〇i u，n〇. 1〇 (1957) 719-725)而求出之無機性值及有機性值之比 (Inorganic Organic Balance)者，藉由下式而求出。 [數1] 149508.doc 201106983 IOB值=_無機性值 有機性值 作為成分（c)之具體例，可列舉：甘油（Ι〇Β=5 〇);山梨 糖醇（Ι〇Β = 5·0)、蔗糖（ΙΟΒ=4 4)、麥芽糖醇（ι〇β=4句甘 露糖醇（ΙΟΒ = 5.0)、木糖醇（Ι〇Β = 5 〇)等糖醇；聚氧乙烯 (2〇)曱基醣苷（Ι〇Β=3.4)等聚氧乙烯醣苷衍生物等。該等之 中，就使用後之肌膚觸感良好之方面而言，車交佳為甘油、 山梨糖醇、聚氧乙烯醣苷衍生物。其中，於使用甘油、山 梨糖醇之情形時，使用後之肌膚觸感不黏腻，1感到濕潤 之滋潤感。 於本發明中，清潔料中之成分（c)之含量為3〇〜6〇重量 %。為30重量％以上時，洗完後之滋潤感良好，為6〇重量 %以下時，自低溫下之發泡容器之泡之喷出性優異。進 而，就同時實現泡之噴出性與清潔後之滋潤感之方面而 吕，較佳為35〜50重量％，進而較佳為38〜48重量0/〇。 本發明中所使用之成分之多元醇及上述通式所示 之醇係IOB值為〇.1以上且未達3·4者。 該多元醇或醇（1)藉由與成分（c)之多元醇組合，可降低 清潔料之液體黏度、進而低溫下之液體黏度，而可自發泡 容器獲得紋理細腻之優質之泡。 成分（C)之多元醇係多元醇中亦可獲得更高保濕效果 者，但若調配於清潔料中，則黏度變高，低溫下噴出之泡 之紋理變粗。因此，難以單獨且大量地調配於清潔料中。 於本發明中’藉由組合成分（c)與成分（D)，可降低清潔料 之黏度，而可大量地調配成分（C)之多元醇。 I49508.doc 201106983 作為成分（D)之具體办 單烧基單、二、或可列舉直鏈或支鏈型之二醇、 氧乙稀二醇等。該等= 乙二醇、聚丙二醇、聚 s ,, 乂 ，較佳為 1，3_丁二醇（I〇B=2 5)、 異戊二醇（IOB=2.〇)、& ' ,ΤΠβ , )丙二醇（ΙΟΒ = 3.3)、二丙一醢 008=1.8)等碳數為2〜1〇二一） > 丙一醇 /γ „ 醇，·一乙—醇單己私中 卿=!.6)、分子量為⑽ ' 100〜1萬之繁&一 @ 4之聚丙二醇、分子量為 馬乙一醇、氧伸 之 虱伸乙基之平均加成莫耳數為4〜20 之艰氣乙烯二甘油醚 ^進而較佳為異戊二醇、丨，3· 丁二 醇、二乙二醇單乙醚。 一 於本發明中 〇_5〜30重量％， %。 ’清潔料中之成分（D)之含量合計較佳為 更佳為15重量°〆。，進而較佳為2〜10重量 一又’成分(D)之含量係根據與成分(c)之重量比例而決 定’為（D)/(C)=〇.〇1〜卜若於該範圍内則由多元醇⑹及 (D)之組合所產生之清潔料之黏度降低效果較大，自發泡 谷益獲得之泡紋理細腻，視認性良好。進而，就降低清潔 料之點度之效果較高之方面而言，較佳為重量比例 (D)/(C)=〇.〇5〜0.8 ’進而較佳為〇 !〜〇 5。 又’於成分（D)之中，組合使用（Dl)I〇B值為〇丨以上且 未達1.8之多元醇、與（D2)I〇B值為i 8以上且未達3 4之多 το醇可使降低清潔料之液體黏度之效果變得更大，與僅含 成分（D1)時相比，可抑制低溫下之沈澱生成及溶液之渾 濁，故較佳。 作為（D1)之具體例’可列舉二乙二醇單乙醚、分子量 149508.doc 201106983 400以上之聚丙二醇等，進而較佳為二乙二醇單乙醚 (IOB=1.6)、聚丙二醇-9(IOB = 0.67)。 又’作為（D2)之具體例，可列舉：1，3-丁二醇、異戊二 醇、丙二醇、二丙二醇、分子量未達4〇〇之聚丙二酵、分 子量為100〜1萬之聚乙二醇等，進而較佳為異戊二醇 (I〇B = 2.0)、1,3-丁二醇（l〇B = 2.5)。 關於成分（D1)與（D2)之重量比例’於（D1 )/(D2)為9以下 時，於低溫下保存時不易生成沈殿或引起溶液渾濁，為 〇. 1以上時’降低清潔料之液體黏度之效果變得充分。進 而較佳為（D1)/(D2)=0.2〜5，更佳為0.4〜1。 本發明中所使用之清潔料可進而含有（F)兩性界面 /¾ 劑，可提高清潔中之泡之維持性能，使按摩感變得良好( 作為該兩性界面活性劑之具體例，較佳為具有碳數7〜: 之烴基的羰基甜菜鹼系、磺基甜菜鹼系、咪唑鑌甜菜$ 系、酿胺甜菜鹼系、磷酸酯 *夂恥甜菜鹼系、氧化胺系等兩性, 面活性劑。該等之中，較佔焱糾甘a分 杈佳為斂基甜菜鹼系、磺基甜菜^ 系、醯胺甜菜驗系、氧化脸备 ._ 胺糸，進而較佳為月桂醯胺丙； 甜采鹼、月桂基羥基磺基甜菜鹼。 成分（F)較佳為於清潔料中 〇 1 C ^ θ 0/ 3有1〜20重罝〇/〇，更佳為含3 3〜15重,進而較佳為 ί ♦ ^ -Γ ^ ^ 有7〜13重。於成分（F)為2 ^ 為枓之黏度較低，自發泡容ΙΜ 出之泡之紋理細腻良好， 之裎古峙罢& 马1重量％以上時，泡之維持七 之提间效果明顯’由清潔. 本發明中所使用之清^^按摩感良好。 叶進而可含有（G)具有葡萄糖| 149508.doc -10· 201106983 架之非離子界面活性劑，可提高清潔力。作為成分（G)之 具體例’可列舉下述通式（2)所示之烷基醣苷。 R5-(OR6)x-Gy (2) [式中’ R5表示直鏈或支鏈之破數8~18之院基、烯基或院 基苯基’ R6表示碳數2〜4之伸烷基，G表示葡萄糖骨架之殘 基’ x表示其平均值達到0〜5之數，y表示其平均值達到 1〜10之數]» 就溶解性、起泡性及清潔性而言，R5較佳為碳數 10〜14。又，R6為碳數2〜4之伸烷基，就對水之溶解性等方 面而言，較佳為碳數2〜3之伸烷基。 成分（G)較佳為於清潔料中含有〇 5〜5重量％，含有〇 8〜4 重量％、進而含有1〜3重量％可使清潔力之提高變得明顯， 故更佳。 本發明中所使用之清潔料進而可含有（H)具有支鏈烷基 之非離子界面活性劑，可抑制低溫保存時之沈澱之生成及 溶液之渾濁。 具體可列舉單、二、三脂肪酸聚氧伸烷基甘油、聚氧乙 烯蓖麻油（包括氫化蓖麻油）、單、二、三脂肪酸聚氧乙烯 蓖麻油（包括氫化蓖麻油）等。作為該等中之脂肪酸，較佳 為具有碳數6〜22之支鏈烷基者。作為聚氧伸烷基，可列舉 聚氧乙烯、聚氧丙烯，較佳為聚氧乙烯。 較佳為脂肪酸聚氧乙烯氫化藥麻油、脂肪酸聚氧乙烯甘 油，進而較佳為聚氧乙烯之重複單元之合計平均為3〜3〇的 異硬脂酸聚氧乙烯氫化萬麻油、異硬脂酸聚氧乙烯甘油。 149508.doc 201106983 成分（Η)較佳為於清潔料中含有〇]〜3重量％，含有〇丨〜2 重S %、進而含有Ojq重量％可改善清潔料於低溫下之穩 定性，故更佳。 於本發明中，（E)水較佳為於清潔料中含有3〇〜6〇重量 %，進而較佳為含有40〜50重量％。若於該範圍内，則於低 溫下自發泡容器噴出之泡之紋理細腻，可獲得洗完後之濕 潤之滋潤感。 本發明中所使用之清潔料中除上述成分以外，亦可視需 要於不損及本發明之效果之範圍内進而調配通常之清潔劑 組合物中所使用之成分，例如：羊毛脂及其衍生物、肉豆 蔻酸異丙酯等酯類、椰子油等三酸甘油酯等油分；聚甘油 脂肪酸酯等保濕劑；三氯生、三氣對稱二苯脲等殺菌劑； 甘草酸二鉀、醋酸維生素E等抗炎症劑；吡啶硫酮辞、吡 啶酮乙醇胺鹽等抗頭屑劑；對羥基苯曱酸曱酯、對羥基苯 甲酸丁醋等防腐劑；乙二胺四乙酸或其鹽、羥基乙烷二膦 酸或其鹽等螯合劑；檸檬酸、琥珀酸等pH值調整劑；氣化 鈉等鹽類；其他珠光劑、香料、色素、紫外線吸收劑、抗 氧化劑等。 本發明中所使用之清潔料可藉由利用通常之方法將所有 成分混合而製造。5。(：下之黏度較佳為6〇 mpa_s以下，為 5〜50 mPa.s、進而為5〜30 mPa.s可使自發泡容器喷出之泡 紋理細腻，保形性良好，故較佳。 再者，於本發明中，黏度係於5它下使用BS(Br〇〇kfieid) 黏度计，以特定之轉速（100 mPa.sU下時為6〇 149508.doc • 12- 201106983 mPa.s以上時為3Qrpm)、i分鐘之測定時間進行測定。 、上述方式所知之清潔料填充至發泡容器中。發泡 器係具有多孔質膜者，作為多孔質膜，例如可列舉海綿、 燒^體、網狀物等。該等多孔質膜中，於附著殘存於膜上 之清潔液乾燥固化而引起堵塞之情形時，可於下次喷出時 f由泡之流動立即將固化物溶解而消除堵塞，故較佳為薄 之網狀物。作為網狀物，較佳為5g〜5_格者 :彻網格者會生成良好之泡，故較佳。又，作為此^ .才之材質而較佳者可列舉尼龍、聚酯等。 較佳為於容器中含有複數片此種膜，特別是就經濟性、 泡之穩定性等方面而言，較佳為2片。 "作為《泡今态，只要為將一定量之清潔液與—定量 氣力以混合’並以泡狀態使其喷出者，則可為任意 1如可列舉.日本專利實開昭58·17‘4272號公報、日 /利實開昭62·42787號公報、日本專利特公昭52·16567 夕公報等中記載之藉由以手指擠壓軟質容器之主體部而使 齊堅起泡器’例如曰本專利實開平3_7963號公報、曰 2^_62.1G3458號公報、日本專利㈣平'3⑽3 而^等中所記載之藉由以手指擠壓具有栗機構之蓋之頭 而使用之泵發泡器。 本發明之清潔劑可形成洗顏泡沫、潔面泡沫、卸妝泡 絮弟J須泡沐、洗髮泡珠、身體清潔泡沫等。特別是作為 春面泡沫、卸妝泡沫而有用。 本發明之清潔劑係藉由以下方式而使用：將自發泡容器 149508.doc •13· 201106983 喷出之泡取至手中，不以水稀釋而直接塗佈於皮膚上，充 分地融合按摩後，以水進行沖洗。 [實施例] 實施例1〜28、比較例卜9 製備表1〜表3所示組成之液體清潔料組合物，將其填充 至發泡容器（160 mL[YF_9413、吉野工業公司製造])中，而 衣造β潔劑。對於所得之清潔劑，藉由下述方法評價液體 黏度、低溫下之噴出性、低溫下之溶液狀態、清潔後之肌 膚觸感、清潔中之泡之維持及清潔力。將結果一併示於表 1〜表3中。 (評價方法） (1) 液體黏度： 於5C下’使用Β型（Br〇〇kfieid)黏度計（τνΒ1〇形黏度 。十東機產業股份有限公司製造），利用轉子βμ No. 1，以 特定之轉速（1〇〇 mPa.sa下時為6〇 rpm，l〇〇 mpas以上時 為30 rpm)，用i分鐘之測定時間測定液體黏度。 (2) 低溫下之噴出性： 1〇名專業評價者利用以下（1)5個階段評價基準，藉由目 視而評價於5°C下自發泡容器喷出之泡之狀態，以評分之 平均值，根1(11)4個階段判定基準來判定低溫下之泡之喷 出性。 (I) 5個階段評價基準： 評分4 :泡之紋理細腻，整體均勻。 評分3 :泡之紋理細腻，但混有微量粗氣泡。 149508.doc 201106983 評分2 :泡之紋理細腻，但稍混有粗氣泡。 評分1 :泡之紋理細腻，但混有大量粗氣泡。 評分0 :泡之紋理粗大。 (II) 4個階段判定基準： ◎:評分平均為3.0以上。 〇：評分平均為2.0以上且未達3.0。 △:評分平均為1.0以上且未達2.0。 X :評分平均未達1.0。 (3) 低溫下之溶液狀態： 將各清潔料於1C下保存i週後，藉由目視評價溶液狀 態，依照以下4個階段判定基準來進行判定。 ◎:不產生渾濁或析出。 〇：產生微量渾濁，但不產生析出。 △:產生渾濁，但不產生析出。 X :產生析出。 (4) 清潔後之肌膚觸感： 讓10名專業評價者實際使用清潔劑，利用以下（1)5個階 段評價基準來官能評價清潔後之肌膚觸感，以評分之平均 值，依照（11)4個階段判定基準而判定虮膚觸感°刀 (I) 5個階段評價基準： 評分4 :感到滋潤感。 評分3 :有些感到滋潤感。 評分2 :稍感到滋潤感。 評分1 :略微感到滋潤感。 I49508.doc 201106983 評分〇.未感到滋潤感。 (II) 4個階段判定基準： ◎:評分平均為3.0以上。 〇：評分平均為2·0以上且未達3.0。 △:評分平均為1,〇以上且未達2.〇。 X :評分平均未達1. 〇。 (5) 清潔中之泡之維持： 讓10名專業評價者實際使用各清潔劑，根據回答按摩時 之泡之觸感良好之評價者之人數，依照以下評價基準進行 判定。 ◎ : 8名以上。 〇：6〜7名。 △ : 3〜5名。 X : 2名以下。 (6) 清潔力（卸妝）： 將以〗0 mg/5 cm2之比例塗佈有油性固形口紅之前腕部， 以自發泡容器喷出之泡1 g清潔3〇秒，依照以下評價美 準，以目視判定殘留之口紅量。 土 ◎ :大致完全脫落。 〇 :大致脫落。 △ :稍有脫落。 X :完全未脫落。 I49508.doc -16* 201106983R4H—(CH2CH20)mCH broad COOX OH (wherein R2, R3 and R4 represent the alkyl or dilute group of carbon number 1〇~18, respectively, @ represents an average of 0.5~Η), χ denotes hydrogen atom, test The metal H alcohol amine or the test amine acid), the amine; as the salt of the component (B), the salt phase of the component (A) may, for example, be an alkali metal such as sodium or potassium; ammonium; Methyl propanol and the like = basic amino acid such as alkanol acid or arginine. As the component (B), the foaming property is high and the foam in the cleansing is good: a 'preferred fatty acid salt' is further preferably a carbon number: a south fatty acid salt. In the present invention, by using (A) an anionic surfactant having a sulfate group in combination with (8) a higher fatty acid salt or a hydrochloric acid type surfactant, a fine texture bubble can be ejected from the foamed container. In the present invention, the contents of the cleaning fractions (A) and (B) are preferably 5% to 10% by weight, more preferably 4% by weight, and still more preferably 5% by weight. Further, the total content of the components (A) and (B) in the cleaning material is 1 to 10% by weight, preferably 2 to 8% by weight, and more preferably 3 to 5% by weight. When the total content of the components (4) and (B) is 1 4 4% or more, the cleaning power and the maintenance performance of the foam are good, which is 1% by weight or less, and the foaming property of the foamed container from a low temperature is stored at a low temperature. Excellent stability. Further, when the weight ratio of the component (Α) to (Β) is 〇丨 or more, the stability at the time of storage at a low temperature is good, and when it is 9 or less, the moisturizing feeling after cleansing can be obtained. Therefore, it is better. Further, from the viewpoint of achieving both a refreshing feeling and a moist feeling, it is preferably (A) / (B) = 〇 1 to 4, more preferably 0.15 to 3 ', more preferably 〇. 2 to 2. The polyol (I) of the component (C) used in the present invention has a value of 34 or more and less than 6' is preferably 3.4 to 5. By using the polyol, the moisturizing feeling after the washing can be achieved. Here, the term "IOB" refers to the inorganic value obtained from the organic concept map (Fuji Mumu, prediction of organic compounds and organic concept map, chemical field v〇iu, n〇. 1〇 (1957) 719-725). The ratio of the organic value (Inorganic Organic Balance) is obtained by the following formula. [Number 1] 149508.doc 201106983 IOB value = _ inorganic value organic value As a specific example of the component (c), glycerin (Ι〇Β = 5 〇); sorbitol (Ι〇Β = 5· 0), sucrose (ΙΟΒ=4 4), maltitol (ι〇β=4 mannitol (ΙΟΒ = 5.0), xylitol (Ι〇Β = 5 〇) and other sugar alcohols; polyoxyethylene (2〇 a polyoxyethylene glycoside derivative such as thioglycoside (Ι〇Β=3.4), etc. Among these, in terms of good skin feel after use, the car is preferably glycerin, sorbitol, polyoxygen In the case of using glycerin or sorbitol, the skin after use is not sticky, and the moisturizing feeling is moist. In the present invention, the content of the component (c) in the cleaning material is When it is 30% by weight or more, the moisturizing feeling after washing is good, and when it is 6% by weight or less, the foaming property of the foaming container from a low temperature is excellent. At the same time, the foaming property of the foam and the moisturizing feeling after cleaning are preferably 35 to 50% by weight, and more preferably 38 to 48% by weight. The polyol of the component to be used and the alcohol-based IOB of the above formula have a value of 〇.1 or more and less than 3.4. The polyol or alcohol (1) is combined with the polyol of the component (c). It can reduce the liquid viscosity of the cleaning material and the viscosity of the liquid at low temperature, and can obtain the fine texture of the foam from the foaming container. The polyol of the component (C) can also obtain higher moisturizing effect, but If it is formulated in a cleaning material, the viscosity becomes high, and the texture of the bubble ejected at a low temperature becomes coarse. Therefore, it is difficult to prepare the cleaning material separately and in a large amount. In the present invention, by combining the component (c) and the component ( D), the viscosity of the cleaning material can be reduced, and the polyol of the component (C) can be formulated in a large amount. I49508.doc 201106983 The specific single-single-single-single-single or two-segment as the component (D) can be exemplified by a straight chain or a branched chain. Type diol, oxyethylene glycol, etc. These = ethylene glycol, polypropylene glycol, poly s, hydrazine, preferably 1,3-butanediol (I 〇 B = 2 5), isoprene Alcohol (IOB=2.〇), & ', ΤΠβ, ) propylene glycol (ΙΟΒ = 3.3), dipropyl 醢 008 = 1.8) and other carbon numbers are 2~1〇2 > propanol / γ „ alcohol, · 乙-醇单己私中卿=!.6), molecular weight is (10) '100~1 million of the complex & a @ 4 of polypropylene glycol, molecular weight is Ma Yiyi The average addition of alcohol and oxygen to the ethyl group is 4 to 20, and the ethylene glycol diglyceride is further preferably isopentylene glycol, hydrazine, 3 · butanediol, diethylene glycol monoethyl ether. In the present invention, 〇5 to 30% by weight, %. The total content of the component (D) in the cleaning material is preferably 15 parts by weight or more. Further preferably, it is 2 to 10 parts by weight, and the content of the component (D) is determined according to the weight ratio of the component (c) to '(D)/(C)=〇.〇1~b if in the range In the inside, the viscosity of the cleaning material produced by the combination of the polyols (6) and (D) has a large effect, and the bubble obtained from the foaming valley is fine and has good visibility. Further, in terms of the effect of lowering the degree of cleaning of the cleaning material, the weight ratio (D) / (C) = 〇. 〇 5 to 0.8 Å is further preferably 〇 ! ~ 〇 5. Further, among the components (D), a combination of (D1) I 〇 B value of 〇丨 or more and less than 1.8, and (D2) I 〇 B value of i 8 or more and less than 3 4 are used in combination. The το alcohol can further reduce the effect of lowering the liquid viscosity of the cleaning material, and is preferable because it can suppress the formation of precipitate at a low temperature and the turbidity of the solution as compared with the case where only the component (D1) is contained. Specific examples of (D1) include diethylene glycol monoethyl ether, polypropylene glycol having a molecular weight of 149508.doc 201106983 400 or more, and further preferably diethylene glycol monoethyl ether (IOB=1.6) or polypropylene glycol-9 ( IOB = 0.67). Further, as a specific example of (D2), 1,3-butanediol, isoprene glycol, propylene glycol, dipropylene glycol, polypropylene glycol having a molecular weight of less than 4, and a molecular weight of 100 to 10,000 are exemplified. Ethylene glycol or the like is further preferably isoprenediol (I〇B = 2.0) and 1,3-butanediol (l〇B = 2.5). When the weight ratio of the components (D1) to (D2) is 9 or less, when it is stored at a low temperature, it is difficult to form a hall or cause a turbidity of the solution, and when it is 1 or more, the amount of the cleaning material is lowered. The effect of the liquid viscosity becomes sufficient. Further, it is preferably (D1) / (D2) = 0.2 to 5, more preferably 0.4 to 1. The cleaning material used in the present invention may further contain (F) an amphoteric interface/3⁄4 agent, which can improve the maintenance performance of the foam during cleaning and improve the massage feeling (as a specific example of the amphoteric surfactant, preferably a carbonyl betaine system having a carbon number of 7 to: a sulfobetaine system, an imidazolium beet system, a sulphate betaine system, a phosphate ester, a sulphate betaine system, an amine oxide system, and the like. Among these, it is better to be a glycine-based betaine, a sulfo beetine, a guanamine beet, an oxidized face, an oxidized face, an amine, and preferably a laurel Sweet base, lauryl hydroxy sulfobetaine. The component (F) is preferably 1 to 20 罝〇/〇, more preferably 3 3 〜15 in the cleaning material 〇1 C ^ θ 0/3 It is preferably ί ♦ ^ - Γ ^ ^ which has a weight of 7 to 13. The viscosity of the component (F) is 2 ^, and the viscosity of the foam is fine and fine. When the horse is 1% by weight or more, the effect of maintaining the seven-story of the bubble is obvious 'by cleaning. The cleaning method used in the present invention has a good massage feeling. (G) has a nonionic surfactant having a glucose | 149508.doc -10·201106983, which can improve the cleaning power. Specific examples of the component (G) include an alkyl group represented by the following formula (2). Glycosides R5-(OR6)x-Gy (2) [In the formula, R5 represents a linear or branched chain of 8 to 18, or an alkenyl or a phenyl group. R6 represents a carbon number of 2 to 4. An alkyl group, G represents a residue of the glucose skeleton, where x represents an average value of 0 to 5, and y represents an average value of 1 to 10]» in terms of solubility, foaming and cleanliness, R5 is preferably a carbon number of 10 to 14. Further, R6 is an alkylene group having 2 to 4 carbon atoms, and is preferably an alkylene group having 2 to 3 carbon atoms in terms of solubility in water and the like. G) is preferably contained in the cleaning material in an amount of 5 to 5% by weight, more preferably 8 to 4% by weight, and further preferably 1 to 3 % by weight, so that the improvement in cleaning power is remarkable, which is more preferable. The cleaning material to be used may further contain (H) a nonionic surfactant having a branched alkyl group, which suppresses the formation of a precipitate at the time of low-temperature storage and the turbidity of the solution. Specific examples include single, di-, and tri-fat. Acid polyoxyalkylene glycerol, polyoxyethylene castor oil (including hydrogenated castor oil), mono-, di-, or tri-fatty fatty acid polyoxyethylene castor oil (including hydrogenated castor oil), etc., as such fatty acids, preferably having The branched alkyl group having a carbon number of 6 to 22. The polyoxyalkylene group may, for example, be polyoxyethylene or polyoxypropylene, preferably polyoxyethylene. Preferably, the fatty acid polyoxyethylene hydrogenated sesame oil, fatty acid polyoxygen The ethylene glycerin, and more preferably the polyoxyethylene repeating unit, has an average of 3 to 3 Å of isostearic acid polyoxyethylene hydrogenated perylene oil and isostearic acid polyoxyethylene glycerin. 149508.doc 201106983 Ingredients (Η) It is preferable to contain 〇]~3 wt% in the cleaning material, and to contain 〇丨~2 weight S%, and further contain Ojq% by weight to improve the stability of the cleaning material at low temperatures, which is more preferable. In the present invention, the (E) water is preferably contained in the cleaning material in an amount of from 3 to 6 % by weight, more preferably from 40 to 50% by weight. If it is within this range, the texture of the foam ejected from the foamed container at a low temperature is fine, and the moisturizing feeling after the washing is obtained. In addition to the above-mentioned components, the cleaning materials used in the present invention may be formulated to be used in a conventional detergent composition, such as lanolin and its derivatives, as needed within the range not impairing the effects of the present invention. An oil such as an ester such as isopropyl myristate or a triglyceride such as coconut oil; a moisturizing agent such as a polyglycerin fatty acid ester; a fungicide such as triclosan or a tri-gas symmetrical diphenylurea; dipotassium glycyrrhizinate and acetic acid Anti-inflammatory agents such as vitamin E; anti-dandruff agents such as pyrithione, pyridone and ethanolamine salts; anti-corrosive agents such as p-hydroxybenzoate or butyl hydroxybenzoate; ethylenediaminetetraacetic acid or its salt, hydroxyl a chelating agent such as ethane diphosphonic acid or a salt thereof; a pH adjusting agent such as citric acid or succinic acid; a salt such as sodium vaporification; other pearlizing agents, perfumes, pigments, ultraviolet absorbers, and antioxidants. The cleaning material used in the present invention can be produced by mixing all the components by a usual method. 5. (The viscosity underneath is preferably 6 〇mpa_s or less, 5 to 50 mPa.s, and further 5 to 30 mPa.s, so that the bubble formed by the self-foaming container is fine and has good shape retention, so it is preferable. Furthermore, in the present invention, the viscosity is based on a BS (Br〇〇kfieid) viscometer at a specific speed (6 〇 149508.doc • 12-201106983 mPa.s at 100 mPa.sU). In the above, it is measured at a measurement time of 3 minutes and a minute. The cleaning material known in the above aspect is filled in a foaming container. The foaming device has a porous film, and examples of the porous film include a sponge and a burning. In the porous film, when the cleaning liquid remaining on the film is dried and solidified to cause clogging, the solidified substance can be dissolved immediately by the flow of the bubble at the next discharge. And the clogging is eliminated, so it is preferably a thin mesh. As the mesh, it is preferably 5g~5_ lattice: the mesher will generate a good bubble, so it is better. Also, as this ^. Preferred examples of the material include nylon, polyester, etc. It is preferred to contain a plurality of such films in a container, particularly in terms of economy. In terms of the stability of the bubble, etc., it is preferably two pieces. "As a bubble state, as long as a certain amount of the cleaning liquid is mixed with the quantitative gas force" and is sprayed in a bubble state, It is described in Japanese Patent Laid-Open Publication No. SHO 58-17'4272, Japanese Patent Publication No. Sho 62.42787, Japanese Patent Publication No. SHO 52-16567, and the like. The body of the soft container is pressed to the body of the soft container, for example, as described in Japanese Patent Application Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. 3-7963, No. 2^_62.1G3458, Japanese Patent No. 4(10)3, and the like. The pump foaming device used for squeezing the head of the cap of the chest mechanism. The cleaning agent of the invention can form a facial cleansing foam, a cleansing foam, a makeup remover, a foaming bead, a foaming bead, a body cleansing foam, and the like. In particular, it is useful as a spring foam and a makeup remover foam. The detergent of the present invention is used by taking a bubble sprayed from a foam container 149508.doc •13·201106983 into the hand without directly diluting with water. Apply to the skin, after fully blending massage, The water was rinsed. [Examples] Examples 1 to 28, Comparative Example 9 Liquid cleaning compositions of the compositions shown in Tables 1 to 3 were prepared and filled into a foaming vessel (160 mL [YF_9413, Yoshino Industrial Co., Ltd. In the manufacture of the detergent, the liquid detergent, the squirting property at a low temperature, the state of the solution at a low temperature, the touch of the skin after cleaning, and the foam in the cleansing are evaluated by the following method. The maintenance and cleaning power are shown in Tables 1 to 3. (Evaluation method) (1) Liquid viscosity: At 5 C, 'Br〇〇kfieid viscometer (τνΒ1〇 viscosity) was used. It is manufactured by Shito Machine Industry Co., Ltd., using the rotor βμ No. 1, at a specific rotation speed (6 rpm at 1 〇〇 mPa.sa, 30 rpm at 10 mps or more), and i minutes. The measurement time is used to determine the viscosity of the liquid. (2) Ejection at low temperature: 1 专业 professional evaluator uses the following (1) 5 stage evaluation criteria to visually evaluate the state of the bubble ejected from the foaming container at 5 ° C, with an average of the scores. The value, the root 1 (11) four-stage determination criterion to determine the discharge property of the bubble at a low temperature. (I) Five-stage evaluation criteria: Score 4: The texture of the bubble is fine and uniform. Score 3: The texture of the bubble is fine, but it is mixed with a small amount of coarse bubbles. 149508.doc 201106983 Rating 2: The texture of the bubble is fine, but it is slightly mixed with coarse bubbles. Score 1: The texture of the bubble is fine, but it is mixed with a lot of coarse bubbles. Score 0: The texture of the bubble is coarse. (II) Four-stage judgment criteria: ◎: The average score is 3.0 or more. 〇: The average score is 2.0 or more and less than 3.0. △: The average score was 1.0 or more and less than 2.0. X: The average score is less than 1.0. (3) Solution state at a low temperature: After each cleaning material was stored at 1 C for one week, the solution state was visually evaluated, and the determination was made in accordance with the following four stages of determination criteria. ◎: No turbidity or precipitation occurred. 〇: A slight amount of turbidity is produced, but no precipitation occurs. △: turbidity was generated, but no precipitation occurred. X : Precipitation occurs. (4) Skin touch after cleansing: Let 10 professional evaluators actually use the cleansing agent, and use the following (1) five-stage evaluation criteria to functionally evaluate the skin feel after cleansing, based on the average of the scores, according to (11) ) The four-stage determination criteria were used to determine the skin feel. The knife (I) Five-stage evaluation criteria: Score 4: Feel the moisturizing feeling. Rating 3: Some feel moisturized. Score 2: Slightly moisturizing. Score 1: Slightly moisturized. I49508.doc 201106983 Rating 〇. No feeling of moisturizing. (II) Four-stage judgment criteria: ◎: The average score is 3.0 or more. 〇: The average score is above 2.0 and not above 3.0. △: The average score is 1, 〇 or more and less than 2. 〇. X: The average score is less than 1. 〇. (5) Maintenance of the foam in the cleaning: The number of evaluators who responded well to the sensation of the foam at the time of the massage was judged according to the following evaluation criteria. ◎ : 8 or more. 〇: 6~7. △ : 3 to 5 people. X : 2 or less. (6) Cleansing power (remove remover): The wrist before the oily solid lipstick is applied at a ratio of 〖0 mg/5 cm2, and the bubble spouted from the foaming container is cleaned for 3 sec., according to the following evaluation. The amount of residual lipstick was visually judged. Soil ◎ : It is almost completely detached. 〇 : It falls off. △ : Slightly falling off. X : Not falling off at all. I49508.doc -16* 201106983
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