JP2003129097A - Cleaning agent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a cleaning agent composition for cleaning the skin and hairs of human beings, which is capable of keeping stable paste form or solid state in a wide range of temperatures, has a good foaming property without giving a slimy feeling when rinsing, and in addition to the above effects, does not give any irritative feeling at all, and also makes creamy foams. SOLUTION: The cleaning agent composition of paste form or solid state having the melting point of 40 deg.C or higher, contains (a) an anionic surface active agent having Krafft point of 40 deg.C or lower, (b) one or at least two ingredients selected from inorganic salts and organic salts, (c) a polyol having trivalent or higher valency, and (d) water, and in addition to the above ingredients of (a) to (d), the cleaning agent composition of paste form or solid state having the melting point of 45 deg.C or higher further contains (e) taurines, and one or more of non-ionic surface active agents selected from those having HLB of 10 or higher.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a paste-to-solid detergent composition for cleaning human skin, hair and the like. More specifically, the present invention relates to a paste-to-solid detergent composition having a refreshing feel, excellent stability, and sufficient foaming performance. The present invention also relates to a creamy foamy paste-to-solid detergent composition which has a refreshing feel, stability, sufficient foaming performance, and is free from the feeling of sticking during use.

[0002]

2. Description of the Related Art A detergent composition usually has a foaming property,
An anionic surfactant is incorporated as a main component from the viewpoint of excellent detergency. In order for such a detergent composition to have a paste form, the anionic surfactant used has a high Kraft point (the temperature at which the hydrated crystals of the surfactant dissolve in water) and is in a hydrated crystalline state at room temperature. Need to be Anionic surfactants increase the Kraft point by increasing the carbon chain length of the hydrophobic group, and the detergent composition becomes a paste, but on the other hand, the foaming performance, which is an essential function as a detergent, Will be significantly reduced.

Anionic surfactants having good foaming properties and good detergency have a carbon number of 12 (lauryl).
And those having an alkyl chain length of about 14 (myristyl). Among the anionic surfactants having the above alkyl chain length, generally used sodium salts that show a paste state at room temperature include fatty acid salts (soaps), acylglutamates, acylglycine salts, acylisethionates, and alkyls. Examples thereof include sulfosuccinate, but the number thereof is extremely small when viewed from the whole.

In many anionic surfactants,
When the alkyl chain length is about 12 or 14 carbon atoms, the Kraft point is lower than room temperature, and the paste-like detergent composition cannot be prepared as it is. By adding a solidifying agent such as ethylene glycol distearate, it can be forced into a paste, but in this case, foaming is low, and the hydrophilic group is a group other than a carboxyl group, for example, a sulfate group or a sulfone group. In such cases, there is a problem in that the skin feels very slimy during rinsing and is difficult to wash off, so that the feeling of use is not sufficient.

[0005]

DISCLOSURE OF THE INVENTION The present invention solves the above-mentioned problems of the prior art, exhibits a paste form to a solid form in a wide temperature range, has good foaming, and has a feeling of use without slimyness even during rinsing. It is an object of the present invention to provide a detergent composition having excellent stability. Another object of the present invention is to provide, in addition to the above effects, a creamy detergent composition which does not have a feeling of sticking during use and is creamy.

[0006]

In order to solve the above problems, the present invention is selected from (a) an anionic surfactant having a Kraft point of 40 ° C. or less, and (b) an inorganic salt and an organic salt. Provided is a paste-like or solid detergent composition containing one or more kinds, (c) a polyol having a valence of 3 or more, and (d) water and having a melting point of 40 ° C. or more.

In the present invention, the component (a) has the following general formula (I):

R ₁ CO—NR ₂ —CH ₂ CH ₂ SO ₃ M (I)

(Wherein R ₁ represents a saturated or unsaturated hydrocarbon group having an average of 7 to 19 carbon atoms; R ₂ represents a hydrogen atom or an alkyl group having an average of 1 to 3 carbon atoms; The above-mentioned detergent composition is one kind or two or more kinds selected from the long-chain acyltaurine salts represented by alkali metal, alkaline earth metal, ammonium or organic amines).

The present invention also provides at least one of the components (b).
The above detergent composition, wherein the seed is a metal ion salt of the same species as the counter ion of the component (a).

The present invention also relates to the component (b),
The metal ion salt of the same kind as the counter ion of the component (a) is (a)
There is provided the above-mentioned detergent composition, which is contained in a ratio (molar ratio) of 1 or more with respect to the counterion of the component and a different metal ion salt.

In addition to the components (a) to (d), the present invention further comprises (e) one or more selected from the group consisting of taurines and HLB of 10 or more nonionic surfactants. The above cleaning composition is provided.

In the present invention, the nonionic surfactant having HLB of 10 or more used as the component (e) is POE.
The above-mentioned detergent composition is one or more selected from (= polyoxyethylene) glycerin monoisostearate, POE dialkyl ether, POE hydrogenated castor oil and its derivatives.

The present invention also provides the above-mentioned detergent composition, which has a melting point of 45 ° C. or higher in the system in which the components (a) to (e) are blended.

[0015]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.

The component (a) is an anionic surfactant having a Kraft point of 40 ° C. or lower. The anionic surfactant is not particularly limited as long as it is generally used for detergents, and examples thereof include fatty acid salt, α-acyl sulfonate, alkyl sulfonate, alkylallyl and alkylnaphthalene sulfonate. Salts, alkyl sulfates, polyoxyethylene alkyl ether sulfates, alkyl amide sulfates, alkyl phosphates, alkyl amide phosphates, N-long chain acyl amino acid salts, alkyl ether carboxylates, alkyl hydroxy ether carboxylates , The following general formula (I)

R ₁ CO—NR ₂ —CH ₂ CH ₂ SO ₃ M (I)

(Wherein R ₁ represents a saturated or unsaturated hydrocarbon group having an average carbon number of 7 to 19; R ₂ represents a hydrogen atom or an alkyl group having an average carbon number of 1 to 3; M represents Long-chain acyl taurine salt represented by alkali metal, alkaline earth metal, ammonium or organic amines).

Among them, long-chain acyl taurine salts represented by the above general formula (I), polyoxyethylene alkyl ether sulfates and the like are preferable, and particularly long chain acyl taurine salts represented by the above general formula (I) are most preferable. preferable. Examples of the long-chain acyl taurine salt represented by the above general formula (I) used in the present invention include lauroyl methyl taurine salt, myristoyl methyl taurine salt, coconut oil fatty acid methyl taurine salt,
Examples include lauroyl ethyl taurine salt, myristoyl ethyl taurine salt, coconut oil fatty acid ethyl taurine salt, lauroyl taurine salt, coconut oil fatty acid taurine salt, and the like,
Of course, it is not limited to these examples.

The counterion of the component (a) is an alkali metal (eg, lithium, potassium, sodium, etc.), an alkaline earth metal (eg, calcium, magnesium, etc.).
Etc.), ammonium, organic amines (eg, monoethanolamine, diethanolamine, triethanolamine, etc.), ammonium and the like. Of these, sodium and potassium are preferable.

From the viewpoint of foaming performance, the component (a) has 1 or less carbon atoms in the alkyl group or acyl group in the main chain.
2 or 14 are preferable, but not limited thereto. When a fatty acid salt is used as the component (a), an insoluble substance is formed when a calcium salt is mixed as the component (b) (described later), so it is preferable to use a sodium salt or a potassium salt together. As the component (a), one type or two or more types can be used.

The content of the component (a) is preferably 5% by mass or more in the detergent composition of the present invention in order to maintain the paste composition to the solid state of the detergent composition, and particularly 1
It is about 0 mass% or more.

In the component (b), as the inorganic salt, chlorides, sulfates, bromides, etc. of sodium, potassium, magnesium, calcium are preferably used. As the organic salt, citric acid, succinic acid, lactic acid or sodium, potassium, magnesium and calcium salts of acidic amino acids such as glutamic acid and aspartic acid are preferably used.

As the component (b), one kind or two or more kinds can be used, but it is preferable that at least one kind of the component (b) is a metal ion salt of the same kind as the counter ion of the above-mentioned component (a). In the component (b), the ratio of the metal ion salt of the same kind as the counter ion of the component (a) to the counter ion of the component (a) and a different metal ion salt is 1 or more (molar ratio).
Is preferably contained in If the "(a) component counterion is the same metal ion salt / (a) component counterion and a different metal ion salt" (molar ratio) is less than 1, the kraft point of the (a) component causes It may not rise sufficiently and the stability may deteriorate. In the present invention, as the metal ion salt of the same kind as the counter ion of the component (a), sodium salt, potassium salt and the like are preferable.

The blending amount of the component (b) is not particularly limited as long as the melting point of the composition can be 40 ° C. or more in the coexistence with other blending components, but it is about 1 to 10% by mass. preferable. If the component (b) is excessive, it may cause a feeling of scratching during use.

As the component (c), in order to maintain a paste-solid state which is more stable at high temperature, the component (c) is replaced with water to obtain 3
A polyol having a valency or more is blended. Examples of such polyols include polyhydric alcohols such as glycerin, sorbitol, xylitol, and erythritol, sugar alcohols,
Examples of sugars such as sucrose and trehalose are preferably used. As the component (c), one type or two or more types can be used.

The content of the component (c) is preferably about 2 to 40% by mass in the detergent composition of the present invention.

Water as the component (d) can be blended in the detergent composition of the present invention in an amount of about 5 to 60% by mass.

The detergent composition of the present invention comprises the above (a) to (a).
It contains the component (d) as an essential component, has a melting point of 40 ° C. or higher, and has a paste or solid form. The term "paste-like" in the present invention means a state in which hydrated crystals of component (a) are deposited, and therefore the appearance is cloudy and the hardness thereof is 3000 mPa · s (30 ° C. B type viscometer) or more. preferable.

In the present invention, by adding the components (b) to (d) to the component (a) having a Kraft point of 40 ° C. or lower, the salting out effect mainly due to the component (b) and (c) ) Component changes the hydrogen bonding state of water, component (a) present in the composition system gradually becomes difficult to dissolve,
The melting point of the system of the finally obtained composition is higher than 40 ° C.

In the present invention, in addition to the above-mentioned components (a) to (d), taurines and HLB as components (e) are 1
One or more selected from 0 or more nonionic surfactants may be blended.

As the taurines, the following general formula (II)

N (R ₃ ) (R ₄ ) CH ₂ CH ₂ SO ₃ M (II)

(In the formula, R ₃ and R ₄ each independently represent a hydrogen atom or an alkyl group having an average carbon number of 1 to 3;
M represents an alkali metal, an alkaline earth metal, ammonium or an organic amine). Specific examples include taurine, methyl taurine, methyl taurine sodium, dimethyl taurine sodium, ethyl taurine sodium, and methyl taurine potassium.

As the nonionic surfactant, HLB10 is used.
The above-mentioned ones are used, but those having HLBs 10 to 18 are particularly preferable from the viewpoints of appearance stability and foam quality. The nonionic surfactant that can be used in the present invention is not particularly limited as long as HLB is within the above range,
For example, POE (= polyoxyethylene) (15) glycerin monoisostearate (HLB = 12), POE
(25) Glycerin monoisostearate (HLB = 1
5), POE (30) glycerin monoisostearate (HLB = 18), POE (60) glycerin monoisostearate (HLB = 19), POE (90) glycerin monoisostearate (HLB = 22), etc.
Glycerin monoisostearate; POE (25) octyldodecyl ether (HLB = 14), POE (1
6) Octyl dodecyl ether (HLB = 12), PO
E (25) decyl tetradecyl ether (HLB = 1
POE dialkyl ethers such as 4); POE (60) hydrogenated castor oil (HLB = 14), POE (40) hydrogenated castor oil (HLB = 12), POE (80) hydrogenated castor oil (HLB = 16), etc. Examples include castor oil and its derivatives, but are not limited to these examples.

The HLB is calculated by the Kawakami equation represented by the following equation.

[0037]

However, in the above formula, MW represents the molecular weight of the hydrophilic group and MO represents the molecular weight of the lipophilic group.

By adding the component (e) to the components (a) to (d), a four-component system of the components (a) to (d) is obtained (b).
In the case where the components were blended in an amount of about 10% by mass, the blending amount could be suppressed to about 7% by mass or less, and in addition to the effects of foaming, stability and a refreshing feeling, the feeling of tingling during use was suppressed, In addition, a paste-to-solid detergent composition having a melting point of 45 ° C. or higher can be obtained.

The detergent composition of the present invention contains, if necessary, a detergent such as a polymer substance (water-soluble polymer etc.), a moisturizer, a fragrance, a preservative, a pigment, an antioxidant, a cosmetic ingredient, a powder and the like. An appropriate amount of a component that can be usually added to the composition may be added. In particular, when a water-soluble polymer is added, the foam quality and usability can be further improved. As the water-soluble polymer, cationized cellulose, cationized guar gum, cationized starch, cationized locust bean gum, polyquaternium-6, polyquaternium-7, polyquaternium-3.
Preferred examples include 9, hydroxyethyl cellulose, celtrol, carboxyvinyl polymer, and the like, but are not limited to these examples. Further, there is no restriction due to their average molecular weight and charge density. The blending amount of the water-soluble polymer is preferably about 2% by mass or less in the detergent composition of the present invention.

The present invention relates to a skin cleanser (for example, a facial cleanser,
It is preferably used for body shampoo, etc.) and hair cleansing agent (for example, shampoo, etc.).

[0042]

EXAMPLES Next, the present invention will be described in more detail by way of examples, which should not be construed as limiting the invention thereto. In addition, all compounding amounts are mass%.

[Components (a) to (d) compounding system]:

Examples 1 to 6 and Comparative Examples 1 to 5 Cleaning agent compositions (samples) having the blending compositions (% by mass) shown in Tables 1 and 2 below were prepared. As for the preparation method, each component was dissolved by stirring at 75 ° C, and then cooled to 25 ° C at a constant rate. The obtained sample was evaluated for stability, foaming, and feeling of use (freshness). The results are shown in Tables 1 and 2.

The stability, foaming and feeling of use (freshness) were determined by the following test methods and evaluation methods.

[Stability] The appearance of each sample after storage for 2 months in a constant temperature bath at 40 ° C. was evaluated according to the following criteria. The viscosity was measured with a B-type viscometer. (Evaluation) ○: Viscosity is maintained at 3000 mPa · s or more even at 40 ° C and no separation is observed. △: Viscosity is 3000 mPa · s or less at 40 ° C, but no separation is observed ×: Separation at 40 ° C And a transparent layer is observed

[Bubbling] 100 ppm of calcium chloride
4 g of each sample was added to 400 mL of mixed distilled water (hard water. 30 ° C.), which was placed in a 2500 mL glass container, and the amount of bubbles was measured after stirring at 4500 rotations for 10 seconds by a mixer method. The evaluation was performed based on the following criteria. (Evaluation) ○: Good foaming (foam amount 1600 mL or more) Δ: Normal foaming (foam amount 1100 mL or more 1600 m)
Less than L) x: Poor foaming (foam amount less than 1100 mL)

[Refreshing when rinsing] Special panel (3
0 person), using 1 g of the sample, sensory-evaluated the freshness (non-slickness) at the time of rinsing when washing the face in the same manner as usual, based on the following criteria. (Evaluation) ◎: All 30 people answered that there was no slimyness during rinsing ○: 25-29 people answered that there was no slimyness during rinsing △: 15-24 people answered that there was no slimyness during rinsing ×: 14 Names below say no slimyness when rinsing

The melting point of the sample is measured by a differential thermal analyzer (DS
In C), the endothermic peak of the sample with respect to water at the time of temperature rise was measured, and the peak top was taken as the melting point.

[0050]

[Table 1]

The Kraft point of the mixed system of two anionic surfactants (lauroylmethyl taurine sodium + myristoyl methyl taurine sodium) as the component (a) is about 10 ° C. As is clear from the results of Table 1, sodium chloride of the same type as the counter ion metal ion of the component (a) was added to the system of the component (a) as the component (b), and as the component (c). By blending glycerin and water as the component (d), the melting point is 4
0 ° C or higher, paste-solid form with excellent stability,
In addition, it was possible to obtain a detergent composition having good foaming and refreshing properties.

In Comparative Example 4, the craft point is about 45 ° C.
The anionic surfactant (sodium myristoyl glutamate) alone was used, but the foaming was poor.

[0053]

[Table 2]

As the component (b), a mixed system of calcium chloride which is a metal salt different from the counter ion of the component (a) and sodium chloride which is the same metal salt as the counter ion of the component (a) was used. The number of moles of component (b) was kept constant at 0.15, and the ratio (molar ratio) of the above two kinds of inorganic salts was changed. When the ratio (molar ratio) of calcium chloride to sodium chloride was increased, the freshness was improved, but the melting point of the composition tended to be lowered.

The Kraft point of sodium lauroylmethyltaurine alone is 0 ° C. or lower.

(Example 7 Facial cleanser) (Composite component) (% by mass) Sodium lauroyl ether carboxylate (Craft point 5 ° C) 21 Magnesium chloride 4 Sodium chloride 8 Glycerin 15 pH adjuster Appropriate preservative Appropriate perfume Residual amount of ion-exchanged water (manufacturing method and evaluation) A detergent composition having the above composition was prepared by a conventional method. The obtained detergent composition has a melting point of 53 ° C.,
It was in the form of a paste to a solid, and was excellent in temperature stability (40 ° C), foaming, and refreshing at the time of use.

Example 8 Hair Shampoo (Composition) (Mass%) Polyoxyethylene (2 mol) Sodium Lauryl Sulfate (Craft Point 0 ° C. or Less) 5 Myristoylmethyltaurine Sodium (Craft Point 23 ° C.) 15 Quen Sodium acid 3 Citrate 2 Sorbitol 30 Preservative Appropriate amount Perfume Appropriate amount Ion-exchanged water Residue (Production method and evaluation) A detergent composition having the above composition was prepared by a conventional method. The obtained detergent composition has a melting point of 44 ° C.,
It was in the form of a paste to a solid, and was excellent in temperature stability (40 ° C), foaming, and refreshing at the time of use.

Example 9 Body Shampoo (Composition) (Mass%) Dodecane 1,2-diol acetic ether ether sodium (Craft point 0 ° C. or lower) 25 sodium chloride 9 calcium chloride 3 sodium citrate 1.6 cit Acid 1.4 Glycerin 10 Preservative Appropriate amount Perfume Appropriate amount Ion-exchanged water Residue (Production method and evaluation) A detergent composition having the above composition was prepared by a conventional method. The obtained detergent composition has a melting point of 43 ° C.
It was in the form of a paste to a solid, and was excellent in temperature stability (40 ° C), foaming, and refreshing at the time of use.

[Components (a) to (d) + component (e) blended system]:

(Examples I to III and Comparative Examples I to V) A cleaning composition (sample) having the blending composition (% by mass) shown in Tables 3 to 4 below was prepared. As for the preparation method, each component was dissolved by stirring at 75 ° C, and then cooled to 25 ° C at a constant rate. Using the obtained composition, stability, foaming, feeling of use (freshness), stability of appearance (45 ° C.), feeling of stickiness during use,
The foam quality was evaluated. The results are shown in Tables 3-4.

The stability, foaming and feeling of use (freshness) were evaluated by the methods described above. The melting point was also measured by the method described above. The appearance stability (45 ° C.), the feeling of scratching during use, and the foam quality were determined by the following test methods and evaluation methods.

[Exterior Stability] After the sample was prepared, a predetermined amount was filled in a glass bottle and stored in a thermostat at 45 ° C. for 1 week, and the appearance was evaluated according to the following criteria. (Evaluation) ◎: The whole is uniformly clouded and no transparent part is seen. ○: Transparent part is seen in less than 5% of the whole ○ △: Transparent part is seen in 5% or more and less than 10% of the whole. Yes: 10% or more and less than 40% of the whole has a transparent part. X: 40% or more of the whole has a transparent part.

[Feeling during use] Special panel (20
According to the name), 1 g of the sample was used to sensory-evaluate the tingling sensation when the sample was directly applied to the face and then the face was washed. (Evaluation) ◎: 18 people or more answered that there was no feeling of stickiness during use ○: 15 to 17 people answered that there was no feeling of stickiness during use ○ △: 12 to 14 people answered that there was no feeling of stickiness during use No: △: 9 to 11 people answered that they did not feel tingling when using ×: Less than 8 people answered that they did not feel tingling when used

[Foam quality (creaminess)] Special panel (2
0 people), using 1 g of the sample, sensory-evaluated the foam quality (creaminess) when the face was washed in the same manner as usual. (Evaluation) ◎: 16 or more people answered that they were creamy ○: 13-15 people answered that they were creamy ○ △: 10-12 people answered that they were creamy △: 7-9 people Responding to be creamy ×: 6 or less respondents to being creamy

[0065]

[Table 3]

[0066]

[Table 4]

In Tables 3 and 4, Comparative Examples I to V are (a) to
It was confirmed that the samples contained in the range of the present invention of the component (d) compounding system were all excellent in stability, foaming, and feeling of use (freshness), but they did not contain the component (e), and they were not used when being used. No effect on stickiness or foam quality (creaminess) was obtained. In contrast, the components (a) to (d) have (e)
In Examples I to III containing taurines as components, in addition to stability, foaming and feeling of use (freshness), appearance stability (45 ° C.), non-irritating feeling during use, foam quality (creamy). It was confirmed that the effect of being excellent is also exhibited.

(Examples IV to X, Comparative Examples VI to IX) Cleaning agent compositions (samples) having the blending compositions (% by mass) shown in Tables 5 to 7 below were prepared. As for the preparation method, each component was dissolved by stirring at 75 ° C, and then cooled to 25 ° C at a constant rate. The obtained composition was evaluated for stability, foaming, feeling of use (freshness), stability of appearance (45 ° C.), feeling of stickiness during use, and foam quality according to the above evaluation criteria. The results are shown in Table 5.
~ 7.

[0069]

[Table 5]

[0070]

[Table 6]

[0071]

[Table 7]

As is clear from the results of Tables 5 to 7,
The samples containing the components (a) to (d) all have excellent stability, foaming, and feeling of use (freshness), but the samples without the addition of the component (e) have a tingling sensation and foam quality (creamyness) during use. ) Etc. could not be obtained. In contrast,
The stability of the samples prepared by blending the components (a) to (d) with the nonionic surfactant having HLB of 10 or more as the component (e) was
It was confirmed that, in addition to foaming and feeling of use (freshness), excellent effects were obtained in terms of appearance stability (45 ° C.), no feeling of sticking during use, and foam quality (creamyness).

(Examples XI to XIV) A detergent composition (sample) having the composition (mass%) shown in Table 8 below was prepared. The preparation method is as follows:
It was cooled to 25 ° C. at a constant rate. The obtained composition was evaluated for stability, foaming, feeling of use (freshness), stability of appearance (45 ° C.), feeling of stickiness during use, and foam quality according to the above evaluation criteria. The results are shown in Table 8.

[0074]

[Table 8]

As is clear from the results of Table 8, (a)-
Taurines and HLB10 as the component (e) in the component (d)
The sample prepared by using the above non-ionic surfactant in combination, in addition to stability, foaming and feeling of use (freshness), appearance stability (45 ° C.), no feeling of tingling during use, It was confirmed that the effect of extremely excellent foam quality (creaminess) was exhibited.

[0076]   (Example XV body shampoo)       (Composition component) (Mass%)   Coconut oil fatty acid methyl taurine sodium (Craft point 12 ℃) 20   Glycerin 20   Sorbitol 5   Sodium chloride 5   L-Glutamate sodium 0.4   L-glutamic acid 0.8   Taurine 4   POE (60) glycerin monoisostearate (HLB = 19) 0.5   POE (25) octyldodecyl ether (HLB = 14) 1   Behenic acid 1.5   2-octyldodecanol 0.1   Cationized polymer ("Mercoat 100"; Nalco, 0.3         Polyquaternium-6 40% aqueous solution)   Silica (spherical, average particle size 2μm) 0.5   Trehalose 0.2   Phenoxyethanol 0.1   Perfume 0.1   Ion-exchanged water residue

[0077]   (Example XVI face wash)       (Composition component) (Mass%)   Coconut oil fatty acid sodium taurine (Craft point 23 ℃) 10   Glycerin 15   Sorbitol 8   Sodium chloride 4   Sodium tartrate 0.6   Tartaric acid 0.4   Taurine 4   POE (20) glycerin monoisostearate (HLB = 14) 2   POE (60) hydrogenated castor oil (HLB = 14) 1   Stearic acid monoglyceride 0.5   Cationized polymer ("Mercote 550"; Nalco, 1         Polyquaternium-7 10% aqueous solution)   Mica 0.5   Methylparaben 0.1   L-hydroxyproline 0.1   Perfume 0.1   Ion-exchanged water residue

[0078]   (Example XVII hair shampoo)       (Composition component) (Mass%)   Palm oil fatty acid potassium taurine (Craft point 34 ° C) 15   Glycerin 10   Sorbitol 10   Potassium chloride 4   Sodium citrate 0.6   Citric acid 2.4   N-methyl taurine sodium 3   POE (25) / POP (30) Copolymer ("Pluronic L-64") 0.5   12-hydroxystearic acid 0.4   Cationized cellulose (“Polymer JR”; Toho Kagaku) 0.4   Cationized guar gum ("Jaguar C-13S") 0.4   Dimethyl silicone (Preparation of 10,000 cs silicone to 30 nm particle size) 0.2   Talc 1   Salamander extract 1   Sodium benzoate 0.2   Perfume 0.1   Ion-exchanged water residue

[0079]   (Example XIII face wash)       (Composition component) (Mass%)   Coconut oil fatty acid methyl taurine sodium (Craft point 12 ℃) 10   Coconut oil sodium isethionate 10   Glycerin 15   Sorbitol 10   Sodium sulfate 4   Sodium malate 0.6   Malic acid 2.4   N-methyl taurine sodium 3   POE (60) hydrogenated castor oil (HLB = 14) 1   12-hydroxystearic acid 0.4   Amphoteric polymer ("Mercote 3300"; Nalco, 0.4         Polyquaternium-39 10% aqueous solution)   Cationized Locust Bean Gum 0.2   2-ethylhexanoic acid triglyceride 0.2   Talc 0.2   Sodium benzoate 0.2   Dimethyl silicone (Preparation of 4000cs silicone to 200nm particle size) 0.2   Perfume 0.1   Ion-exchanged water residue

[0080]   (Example XIX face wash)       (Composition component) (Mass%)   Palm oil fatty acid sodium taurine (Craft point 23 ℃) 13   Stearoyl methyl taurine sodium 1   Myristolyl L-Glutamate Sodium 5   Glycerin 10   Sorbitol 10   Sodium sulfate 4   L-Glutamate sodium 0.6   L-glutamic acid 2.4   N-methyl taurine sodium 3   POE (60) hydrogenated castor oil (HLB = 14) 1   Stearic acid 0.2   Carboxy vinyl polymer 0.2   Batyl alcohol 0.2   Ethylene glycol distearate 0.2   Talc 1   Sodium benzoate 0.2   Pentaerythrityl tetraoctanoate 0.1   Perfume 0.1   Ion-exchanged water residue

[0081]

As described in detail above, according to the present invention, a detergent composition which stably exhibits a paste form to a solid form in a wide temperature range, has a good foaming property, and has a feeling of use without slimyness even during rinsing. Things are offered. Further, according to the present invention, a refreshing feel, a foamy paste-like detergent having a creamy foamy property, which has a sufficient foaming performance, exhibits higher stability, and does not have a feeling of sticking during use. A composition is provided.

─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. ⁷ Identification code FI theme code (reference) A61K 7/075 A61K 7/075 7/50 7/50 C11D 1/28 C11D 1/28 1/72 1 / 72 1/74 1/74 (72) Koichi Kinoshita Koichi Kinoshita 2-2-1, Hayabuchi, Tsuzuki-ku, Yokohama-shi, Kanagawa Within Shiseido Research Center Co., Ltd. (Shin-Yokohama) (72) Tomohiko Kimura Hayabuchi, Tsuzuki-ku, Yokohama, Kanagawa 2-2-1 F-Term (Reference) in Shiseido Research Center (Shin-Yokohama), a stock company 4C083 AA112 AB051 AB052 AB172 AB271 AB332 AB342 AB352 AB432 AC072 AC111 AC122 AC132 AC172 AC182 AC242 AC302 AC392 AC422 AC432 AC442 AC582 AC662 AC782 AC791 AC792 AD042 AD092 AD132 AD152 AD212 BB05 CC23 CC38 DD21 DD22 EE01 EE03 EE06 4H003 AA03 AB23 AC08 AC10 AC12 BA01 BA15 DA02 EA19 EB04 EB05 EB08 EB22

Claims (7)

[Claims] 1. An (a) anionic surfactant having a Kraft point of 40 ° C. or lower, (b) one or more selected from an inorganic salt and an organic salt, and (c) a trivalent or more. A paste or solid detergent composition containing a polyol and (d) water and having a system melting point of 40 ° C. or higher. 2. The component (a) is represented by the following general formula (I) R ₁ CO—NR ₂ —CH ₂ CH ₂ SO ₃ M (I) (wherein R ₁ is saturated with an average number of carbon atoms of 7 to 19 or Represents an unsaturated hydrocarbon group; R ₂ represents a hydrogen atom or an alkyl group having an average number of carbon atoms of 1 to 3; and M represents an alkali metal, an alkaline earth metal, ammonium or an organic amine). The cleaning composition according to claim 1, which is one or more selected from long-chain acyltaurine salts. 3. At least one of the components (b) is (a)
The metal ion salt of the same kind as the counterion of the component, 2.
Or the cleaning composition according to 2. 4. In the component (b), a ratio of the metal ion salt of the same kind as the counter ion of the component (a) to the counter ion of the component (a) and a different metal ion salt is 1 or more (molar ratio). The cleaning composition according to claim 3, which is contained in 5. The cleaning agent according to claim 1, further comprising (e) one or two or more selected from taurines and nonionic surfactants having an HLB of 10 or more. Composition. 6. The HLB10 used as the component (e)
The above nonionic surfactant is one or more selected from the group consisting of POE (= polyoxyethylene) glycerin monoisostearate, POE dialkyl ether, POE hydrogenated castor oil and its derivatives. The cleaning composition according to 5. 7. The melting point of the system is 45 ° C. or higher.
Or the detergent composition according to the item 6.