KR101379303B1 - Spray type of form cleanser composition - Google Patents

Abstract

The present invention relates to a spray-type foam cleaner composition, wherein the foam-type skin cleaner composition according to the present invention is a mono C1-C4 alkyl ether of ethylene glycol oligomer and a mono C1-C4 alkyl ether of propylene glycol oligomer in a foam forming container. It comprises a liquid cosmetic composition comprising a first component selected from one or more selected from the group consisting of, and a second component selected from one or more selected from a polyol, such a cleaning composition can exhibit an excellent cleaning power even without using a surfactant, in particular It is effective for cleaning cosmetics such as makeup and color cosmetics, which are difficult to clean by using a silicone-based compound as a main material.

Description

SPRAY TYPE OF FORM CLEANSER COMPOSITION

The present invention relates to a spray type foam cleaner composition. More specifically, the present invention relates to a spray-type foam cleaner composition which can clean cosmetics such as makeup and color cosmetics, which are difficult to clean using a silicone-based compound as a main material, as well as functions of general cleaning without using a surfactant.

Most modern women accept makeup in general, and it is important to remove makeup rather than wearing it because they realize that they do not achieve the pursuit of beauty, which is the original purpose of makeup, unless it is cleaned. I recognize it.

In general, make-up removal is simply wiped out with a cosmetic tissue or cotton ball, and then secondly removed with a make-up oil or a cleansing cream that can dissolve the make-up. The method is very time consuming and requires several steps of cleaning.

In addition, soaps or cleansers used for cleaning contain a surfactant, and thus the surfactants remaining on the skin after washing may cause skin troubles such as itching and atopy, or may have harmful effects on the human body.

Commercially available products such as cleansing foams, face creams, and foams are easily used by discharging them using containers or aerosol mousse-type containers, but these products are color cosmetics, make-up, and sunscreen mixed with silicone compounds. It has a disadvantage that it does not wash well.

In order to clean, most of the cleaners must be foamed beforehand, and it is a hassle to clean the entire area of the area to be cleaned regardless of the lot of makeup applied and to concentrate the parts that are not cleaned again. There is a feeling.

Thus, even without the use of a surfactant, it can exert excellent cleaning power, can be cleaned at once without cumbersome cleaning for 2 or 3 times, and foams when discharged from the container without having to make foam for effective cleaning power. Therefore, it is easy to use by the user, and when applied to the cleaning site, the cleaner composition and formulation that the consumer can immediately know the degree of cleaning and the site is required.

The problem to be solved by the present invention is to provide a spray-type foam cleaner composition that can clean cosmetics, such as makeup and color cosmetics difficult to clean at the same time using a silicone-based compound as a main material as well as the function of general cleaning without using a surfactant. It is.

In order to solve the above problems,

In foam forming containers,

A liquid cosmetic composition comprising a first component selected from at least one selected from the group consisting of a mono C1-C4 alkyl ether of an ethylene glycol oligomer and a mono C1-C4 alkyl ether from a propylene glycol oligomer, and a second component selected from at least one selected from a polyol. Spray foam cleaning composition.

In the sprayable foam cleaner composition according to the invention, the foam forming container is preferably of an aerosol type or a pump type.

In addition, the aerosol-type foam forming container is 70 to 99.9% by weight of the liquid cosmetic composition; And 0.1 to 30% by weight of propellant.

In the sprayable foam type cleaning composition according to the present invention, the first component of the liquid cosmetic composition includes 0.5 to 10% by weight and the second component in the range of 1 to 40% by weight based on the total weight of the liquid cosmetic composition. It is desirable to be.

Mono C1-C4 alkyl ethers of the ethylene glycol oligomers and mono C1-C4 alkyl ethers of the propylene glycol oligomers which are the first components of the liquid cosmetic composition are ethoxydiglycol, diethoxydiglycol, methoxydiglycol, dimethoxydi It may be selected from glycol, butoxydiglycol, methoxytriglycol or ethoxytriglycol.

In addition, the second component of the liquid cosmetic composition is a polyol comprising polyethylene glycol, polypropylene glycol, glycerin, diglycerol, propylene glycol, dipropylene glycol, butylene glycol, methylgluses-10, ethylene oxide and glycerin It is preferably selected from the group consisting of polyethylene glycol ethers and derivatives thereof.

The polyethylene glycol (H (OCH ₂ CH ₂ ) _n OH) and polypropylene glycol (H (OCH ₂ CH ₂ CH ₂ ) _n OH) is relatively easy to hydrate because n is difficult to hydrate when n is 1,000 or more A number of 1,000 or less may be used, and in the present invention, most preferably, 600 or less in a liquid state.

In addition, the polyethylene glycol ether of ethylene oxide and glycerin is glycerin (glycereth) -6, glycerin-7 glycerin-8, glycerin-12, glycerin-18, glycerin-20, glycerin-26 And glycerin-31, and derivatives thereof include glycerin-7 benzoate, glycerin-18 benzoate, glycerin-20 benzoate, glycerin-7 diisononanoate, glycerin-18 Ethylhexanoate, Glyceres-7 glycolate, Glyceres-8 hydroxystearate, Glyceres-6 tricocoate, Glyceres-6 triisostearate, Glyceres-7 trimethylether and Glycer-6 tri It is preferably selected from the group consisting of oleates.

In addition, the propellant is preferably selected from the group consisting of liquefied petroleum gas, dimethyl ether, n-butane, carbon dioxide and nitrogen.

The spray-type foam cleaner composition according to the present invention can exert an excellent cleaning power even without using a surfactant.

In addition, in the case of cleaning cosmetics such as makeup and color cosmetics, which are difficult to clean by using a silicone-based compound as a main material, the conventional cleaning agent requires a cumbersome cleaning for two or three times, whereas the spray-type foam cleaner according to the present invention. The composition can wash them off at one time.

1 is a photograph showing the results of testing the cleaning power of the spray-type foam cleaning composition according to the present invention.
Figure 2 is a photograph showing the results of testing the foam scavenging ability of the spray-type foam cleaner composition according to the present invention.

Hereinafter, the present invention will be described in more detail.

The present invention relates to a foam-forming container comprising a first component selected from at least one selected from the group consisting of mono C1-C4 alkyl ethers of ethylene glycol oligomers and mono C1-C4 alkyl ethers of propylene glycol oligomers, and a second component selected from at least one polyol. It is a spray foam detergent composition containing the liquid cosmetic composition containing.

The liquid cosmetic composition included in the spray-type foam cleaner composition according to the present invention comprises a mono C1-C4 alkyl ether of ethylene glycol oligomer and a mono C1-C4 alkyl ether of propylene glycol oligomer based on the total weight of the liquid cosmetic composition. 0.5 to 10% by weight of at least one first component selected from; And 1 to 40% by weight of the second component, polyol, based on the total weight of the liquid cosmetic composition.

In the spray-type foam cleaner composition according to the present invention, at least one component selected from the group consisting of mono C1-C4 alkyl ether of ethylene glycol oligomer and mono C1-C4 alkyl ether of propylene glycol oligomer which is the first component of the liquid cosmetic composition is As a solvent, it can remove oils, fatty acids, and silicone-based compounds mainly used in cosmetics by exerting cleaning power by acting on silicone-based compounds. In particular, it is possible to effectively remove silicone-based compounds that are difficult to remove with general cleaning agents.

The mono C1-C4 alkyl ether of the ethylene glycol oligomer and the mono C1-C4 alkyl ether of the propylene glycol oligomer are specifically ethoxydiglycol, diethoxydiglycol, methoxydiglycol, dimethoxydiglycol, butoxydiglycol, methoxy Triglycol, ethoxytriglycol, etc. may be used, but it is not limited to this.

In addition, the materials may be used alone or in combination of two or more, the amount thereof is preferably used in the range of 0.5 to 10% by weight based on the total weight of the liquid cosmetic composition. When used in less than 0.5% by weight, the removal ability of these silicone-based compounds may be inadequate, when used in excess of 10% by weight, there may be an inherent smell of the raw material, the product is too expensive to configure the product There is a problem.

In the spray-type foam cleaner composition according to the present invention, the polyol which is the second component of the liquid cosmetic composition refers to a polyhydric alcohol, that is, an aliphatic compound having two or more hydroxyl groups (-OH), and having two hydroxyl groups. It is called glycol or diol, and diethylene glycol, dipropylene glycol, and polyethylene glycol obtained by etherification of ethylene glycol or propylene glycol, and glycerol, which has three hydroxyl groups, is penta. There is erythritol.

The polyols used in the present invention are preferably short-chain alcohols, which are typically polyols which can be used as organic solvents that are soluble in both water and oil, and they can be mixed with oils that are not removed with ordinary water to perform cleaning. Specifically, there are polyethylene glycol, polypropylene glycol, polyethylene glycol ethers of ethylene oxide and glycerin, and derivatives thereof, and they show better mixing performance with oils.

The polyethylene glycol (H (OCH ₂ CH ₂ ) _n OH) and polypropylene glycol (H (OCH ₂ CH ₂ CH ₂ ) _n OH) is relatively easy to hydrate because it is difficult to hydrate the water when n is 1,000 or more The number of n can be used 1,000 or less, and in the present invention is most preferably 600 or less in the liquid state.

The polyethylene glycol ethers of ethylene oxide and glycerin may be glycerin (glycereth) -6, glycerin-7, glycerin-8, glycerin-12, glycerin-18, glycerin- depending on the number of moles of ethylene oxide. 20, Glyceres-26 and Glyceres-31, and derivatives thereof are Glyceres-7 benzoate, Glyceres-18 benzoate, Glyceres-20 benzoate, Glyceres-7 diisononano Ethyl, Glyceres-18 Ethylhexanoate, Glyceres-7 Glycolate, Glyceres-8 Hydroxystearate, Glyceres-6 Tricocoate, Glyceres-6 Triisostearate, Glyceres-7 Trimethylether Or glycerin-6 trioleate and the like, but is not limited thereto.

In addition, glycerin, diglycerin, propylene glycol, butylene glycol, dipropylene glycol, methylgluses-10 and the like may be used as a polyol that may be used in cosmetics as a single component.

The amount of such polyol is preferably used in the range of 1 to 40% by weight based on the total weight of the liquid cosmetic composition. When used in less than 1% by weight, the cleaning action of oils and makeup cosmetics may be inadequate, and when used in excess of 40% by weight, the viscosity of the content is high, it may cause difficulty in spraying the content, the price is It is too expensive to make a product.

Specifically, the polyol as the second component is 0.5 to 15% by weight of polypropylene glycol or polyethylene glycol, 0.5 to 5% by weight of polyethylene glycol ethers of ethylene oxide and glycerin, based on the total weight of the liquid cosmetic composition, And 10 to 20% by weight of glycerin, diglycerin, butylene glycol, dipropylene glycol or methylgluses-10, which may be used as a single component, is most preferably used.

In the liquid cosmetic composition, a formulation stabilizer or moisturizing component and other additives may be used in addition to the above components.

The formulation stabilizer is used to prevent separation, precipitation, etc. of the contents in the composition of the present invention and to maintain a stable foam, acrylamide, acrylic acid and polysaccharide-based polymers or copolymers thereof, etc. It may be used in the range of 0.01 to 3.0% by weight based on the total weight of the liquid detergent composition. When the formulation stabilizer is used at less than 0.01% by weight, its effect is insignificant, and when used in excess of 3.0% by weight, the viscosity of the content is high, making it difficult to formulate. Specific examples include carbomer, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, hydroxypropyl cellulose, hydroxypropyl guar, and the like, and one or more thereof may be selected.

In addition, other additives that may be used in the cosmetic field, such as preservatives, antifoams, skin conditioning agents, antioxidants, and the like, may be used within a range that does not adversely affect the cleaning composition of the present invention.

Typical detergent compositions usually have the form of creams, gels, powders, oils. The detergent compositions according to the invention may be prepared in a liquid form using a foam forming vessel, such as an aerosol type foam forming vessel or a pump type foam forming vessel. When the cosmetic composition is sprayed from the container, it is in the form of a foam, and there is no need to foam separately for cleaning.

When the foam thus produced comes into contact with the silicone-based compound mainly contained in the make-up product, the foam discharged by the foam-forming container is finer than the gel, cream or artificially generated foam, which is more than conventional gel and cream formulations. It has a large surface area, thereby maximizing the cleaning effect upon contact with the material to be cleaned.

In addition, the characteristics of these bubbles, when they come in contact with the silicone-based compounds that make-up or waterproofing products generally have, because of the effect of lowering their interfacial tension, which is a common feature, bubbles are quickly eliminated. Therefore, the bubbles are eliminated faster than the cleaning action, the user can see the degree of the bubbles are erased, there is an advantage that you can know the portion of the fine cleaning, the degree of cleaning.

The present invention preferably comprises a propellant when the liquid cosmetic composition having the composition described above is included in a foam forming container, for example, an aerosol-type foam forming container, in which case the liquid cosmetic composition is sprayed on 70 to 99.9% by weight of the liquid cosmetic composition. 0.1 to 30 weight percent of the agent. More preferably, the propellant is included in the range of 1 to 20% by weight.

As a propellant for discharging the contents from the container, it is filled with one selected from the group consisting of liquefied petroleum gas (LPG), dimethyl ether (DME), n-butane, carbon dioxide and nitrogen to have a finer, more dense and soft foam shape. A skin cleanser composition of the sprayable foam type can be obtained.

On the other hand, in the case of using the pump type as the foam forming container, the injection of the propellant is not required because the spraying of the foam can be performed by pumping without adding the propellant.

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail with reference to examples. However, the following examples are provided only to make the present invention easier to understand, and the present invention is not limited to these examples, and all percentages in the examples are by weight unless otherwise stated.

Example  1 to 3 and Comparative Example  1 to 3

The cosmetic compositions of each Example and Comparative Example were prepared from the components and the composition ratios as shown in Table 1 below. Specifically, diglycerin, glycerin, butylene glycol, dipropylene glycol, dimethyl glycol, methyl gluceth-10, and sebum 30 (PPG30). ), Fiji 150 (PEG150), Ethoxy Diglycol, Glycereth-12, and Diethoxydiglycol were dissolved, warmed and stirred to 70 ° C, and then cooled to room temperature. After adding a carbomer, a preservative, and a fragrance, the resultant was stirred for 30 minutes to prepare a mucus-like cosmetic composition having a slight viscosity (limited to a numerical value).

Ingredients Example Comparative Example One 2 3 One 2 3 Purified water To 100 To 100 To 100 To 100 To 100 To 100 glycerin 8 8 5 8 10 10 Diglycerin 1.5 4.5 4.5 4.5 4.5 5 Butylene glycol 3 - 3 3 2 - Dipropylene glycol 2 - - 2 - - Methylgluses-10 1.15 3.45 9.2 3.45 13.8 13.8 Fiji-30 0.75 2.25 6 2.25 9 9 Fiji-150 0.75 2.25 6 2.25 9 9 Ethoxydiglycol 0.25 0.75 2 - 3 3.5 Glyceres-12 0.25 0.75 2 0.75 3 3.5 Diethoxydiglycol 0.25 0.75 2 - 3 3.5 Carbomer 0.1 0.1 0.15 0.1 0.2 0.15 Preservative Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Spices Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount

Test Example

Detergency evaluation

After applying the commercially available SPF50 water proof sunscreen on the skin of the liquid skin cleanser composition prepared in Examples 1 to 3 and Comparative Example 1 and washed once with the same amount of composition for 1 minute The cleaning power was evaluated and the result is shown in FIG.

As can be seen in Figure 1, in Examples 1 to 3 was able to remove the residual sunscreen by exerting a cleaning power, on the contrary, in Comparative Example 1 without using ethoxydiglycol and diethoxydiglycol due to lack of cleaning power Due to the sunscreen remaining on the skin could be confirmed. Therefore, the composition of the present invention can exhibit sufficient detergency without using a surfactant.

bubble Scatters

The compositions prepared in Examples 1 to 3 and Comparative Examples 2 to 3 were placed in a 120 ml aerosol container and filled with 10% by weight of liquefied petroleum gas (LPG). Subsequently, SPF50 water proof sunscreen was applied to one skin and the same amount of the composition was applied to the other side without the sunscreen applied to evaluate the extent of foaming after 10 seconds. Shown in

As can be seen in FIG. 2, in Examples 1 to 3, the foam scavenging ability was observed on the side where the sunscreen was applied, and the foam was not erased on the side not coated. On the other hand, Comparative Examples 2 and 3 in which the total amount of polyol exceeded 50% by weight were pumped, but foam was not eliminated on both the side to which the sunscreen was applied and the side to which the sunscreen was not applied. Therefore, the cosmetic composition of the present invention can be effectively cleaned by allowing the user to know the area to be carefully cleaned by removing the foam in response to the makeup.

Claims (9)

In foam forming containers,
A liquid cosmetic composition comprising a first component selected from at least one selected from the group consisting of a mono C1-C4 alkyl ether of an ethylene glycol oligomer and a mono C1-C4 alkyl ether from a propylene glycol oligomer, and a second component selected from at least one selected from a polyol. and,
In the liquid cosmetic composition, the first component is 0.5 to 10% by weight based on the total weight of the liquid cosmetic composition and the second component is a spray type foam cleaning composition, characterized in that included in the range of 1 to 40% by weight. .
The method of claim 1,
The foam forming container is an aerosol type or pump type of the spray type foam cleaner composition.
3. The method of claim 2,
The aerosol-type foam forming container is 70 to 99.9% by weight of the liquid cosmetic composition; And 0.1 to 30% by weight of a propellant.
delete The method of claim 1,
Mono C1-C4 alkyl ethers of ethylene glycol oligomers and mono C1-C4 alkyl ethers of propylene glycol oligomers as the first component in the liquid cosmetic composition are ethoxydiglycol, diethoxydiglycol, methoxydiglycol and dimethoxydiglycol. , Butoxydiglycol, methoxytriglycol or ethoxytriglycol, the foam-type foam cleaning composition characterized by the above-mentioned.
The method of claim 1,
As the second polyol in the liquid cosmetic composition, polyethylene glycol, polypropylene glycol, glycerin, diglycerin, propylene glycol, butylene glycol, dipropylene glycol, methylgluses-10, Foam spray composition of the spray type, characterized in that selected from the group consisting of polyethylene glycol ethers and derivatives thereof of ethylene oxide and glycerin.
The method according to claim 6,
The polyethylene glycol is n is less than 1000 in the following structural formula, H (OCH ₂ CH ₂ ) _n OH, The polypropylene glycol is n is less than 1000 in the following structural formula, H (OCH ₂ CH ₂ CH ₂ ) _n OH Foam cleaning composition of the spray type.
The method according to claim 6,
Polyethylene glycol ethers of ethylene oxide and glycerin are glycerin (glycereth) -7, glycerin-8, glycerin-12, glycerin-18, glycerin-20, glycerin-26 and glycerin-31. It is selected from the group consisting of, the derivatives thereof are glycerin-7 benzoate, glycerin-18 benzoate, glycerin-20 benzoate, glycerin-7 diisononanoate, glycerin-18 ethylhexanoate, glycerol In the group consisting of les-7 glycolate, glycerine-8 hydroxystearate, glycerine-6 tricocoate, glycerine-6 triisostearate, glycerine-7 trimethylether and glycerine-6 trioleate A spray-type foam cleaner composition, characterized in that selected.
The method of claim 3,
Wherein the propellant is liquefied petroleum gas, dimethyl ether, n-butane, carbon dioxide and nitrogen, characterized in that the spray type skin cleanser composition, characterized in that selected from the group consisting of.

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