JP6178382B2 - Cleaning composition for pump former - Google Patents
Cleaning composition for pump former Download PDFInfo
- Publication number
- JP6178382B2 JP6178382B2 JP2015221860A JP2015221860A JP6178382B2 JP 6178382 B2 JP6178382 B2 JP 6178382B2 JP 2015221860 A JP2015221860 A JP 2015221860A JP 2015221860 A JP2015221860 A JP 2015221860A JP 6178382 B2 JP6178382 B2 JP 6178382B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- fatty acid
- cleaning composition
- higher fatty
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000000203 mixture Substances 0.000 title claims description 49
- 238000004140 cleaning Methods 0.000 title claims description 36
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 78
- 229930195729 fatty acid Natural products 0.000 claims description 78
- 239000000194 fatty acid Substances 0.000 claims description 78
- 150000004665 fatty acids Chemical class 0.000 claims description 74
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 46
- 239000000344 soap Substances 0.000 claims description 43
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 24
- 235000021314 Palmitic acid Nutrition 0.000 claims description 23
- 235000021355 Stearic acid Nutrition 0.000 claims description 23
- 238000002156 mixing Methods 0.000 claims description 23
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 23
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 23
- 239000008117 stearic acid Substances 0.000 claims description 23
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 20
- 239000003599 detergent Substances 0.000 claims description 15
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 14
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 14
- 229960003237 betaine Drugs 0.000 claims description 14
- 150000005846 sugar alcohols Polymers 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 239000005639 Lauric acid Substances 0.000 claims description 10
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 claims description 9
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 claims description 6
- 235000021360 Myristic acid Nutrition 0.000 claims description 6
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims description 6
- 229940105990 diglycerin Drugs 0.000 claims description 3
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 3
- 239000006260 foam Substances 0.000 description 33
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- -1 fatty acid salts Chemical class 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 230000002688 persistence Effects 0.000 description 5
- 238000013329 compounding Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- KHAVLLBUVKBTBG-UHFFFAOYSA-N dec-9-enoic acid Chemical compound OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- BITHHVVYSMSWAG-KTKRTIGZSA-N (11Z)-icos-11-enoic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCC(O)=O BITHHVVYSMSWAG-KTKRTIGZSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- OXQGTIUCKGYOAA-UHFFFAOYSA-N 2-Ethylbutanoic acid Chemical compound CCC(CC)C(O)=O OXQGTIUCKGYOAA-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 235000019865 palm kernel oil Nutrition 0.000 description 2
- 239000003346 palm kernel oil Substances 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- HRLPTSDRCFNHPE-UHFFFAOYSA-N 2,2,3,3-tetramethylnonanoic acid Chemical compound CCCCCCC(C)(C)C(C)(C)C(O)=O HRLPTSDRCFNHPE-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- OILUAKBAMVLXGF-UHFFFAOYSA-N 3,5,5-trimethyl-hexanoic acid Chemical compound OC(=O)CC(C)CC(C)(C)C OILUAKBAMVLXGF-UHFFFAOYSA-N 0.000 description 1
- AWQSAIIDOMEEOD-UHFFFAOYSA-N 5,5-Dimethyl-4-(3-oxobutyl)dihydro-2(3H)-furanone Chemical compound CC(=O)CCC1CC(=O)OC1(C)C AWQSAIIDOMEEOD-UHFFFAOYSA-N 0.000 description 1
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- FKLSONDBCYHMOQ-UHFFFAOYSA-N 9E-dodecenoic acid Natural products CCC=CCCCCCCCC(O)=O FKLSONDBCYHMOQ-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Chemical class 0.000 description 1
- 235000021353 Lignoceric acid Nutrition 0.000 description 1
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical class CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021319 Palmitoleic acid Nutrition 0.000 description 1
- 239000005643 Pelargonic acid Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- BAZMYXGARXYAEQ-UHFFFAOYSA-N alpha-ethyl valeric acid Chemical compound CCCC(CC)C(O)=O BAZMYXGARXYAEQ-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940114079 arachidonic acid Drugs 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229920006319 cationized starch Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- XZJZNZATFHOMSJ-KTKRTIGZSA-N cis-3-dodecenoic acid Chemical compound CCCCCCCC\C=C/CC(O)=O XZJZNZATFHOMSJ-KTKRTIGZSA-N 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940108623 eicosenoic acid Drugs 0.000 description 1
- BITHHVVYSMSWAG-UHFFFAOYSA-N eicosenoic acid Natural products CCCCCCCCC=CCCCCCCCCCC(O)=O BITHHVVYSMSWAG-UHFFFAOYSA-N 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 235000021299 gondoic acid Nutrition 0.000 description 1
- JMOLZNNXZPAGBH-UHFFFAOYSA-N hexyldecanoic acid Chemical compound CCCCCCCCC(C(O)=O)CCCCCC JMOLZNNXZPAGBH-UHFFFAOYSA-N 0.000 description 1
- 229950004531 hexyldecanoic acid Drugs 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-AVQMFFATSA-N linoelaidic acid Chemical compound CCCCC\C=C\C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-AVQMFFATSA-N 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
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- C11D3/2003—Alcohols; Phenols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/42—Application of foam or a temporary coating on the surface to be cleaned
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Description
本発明は、ポンプフォーマー等の多孔質膜を有するノンガスタイプの泡吐出容器に収容され、使用時に前記多孔質膜を介して泡状に吐出される洗浄剤組成物に関する。より詳細には、泡の持続性及び泡の弾力性に優れ、なおかつ低温安定性が良好で目詰まりを生じないポンプフォーマー用洗浄剤組成物に関する。 The present invention relates to a cleaning composition that is accommodated in a non-gas type foam discharge container having a porous film such as a pump former, and is discharged in the form of foam through the porous film at the time of use. More specifically, the present invention relates to a cleaning composition for a pump former that is excellent in foam persistence and foam elasticity, has good low-temperature stability, and does not cause clogging.
ポンプフォーマー等のノンガスタイプの泡吐出容器に収容され、使用時に該容器から泡状に吐出される液状洗浄剤組成物が知られている。このタイプの洗浄剤組成物は、容器に備えられた多孔質膜を通過する際に空気と混合されて泡状に吐出される。しかしながら、洗浄成分として汎用されている高級脂肪酸石鹸は起泡性と洗浄性に優れるものの、特に炭素数12を超える長鎖高級脂肪酸塩は低温下で結晶析出を生じポンプフォーマーの多孔質膜の目詰まりを起こすという問題があった。 There is known a liquid detergent composition that is contained in a non-gas type foam discharge container such as a pump former and discharged from the container in a foam state when used. This type of cleaning composition is mixed with air and discharged in the form of foam when passing through the porous membrane provided in the container. However, although higher fatty acid soaps that are widely used as cleaning components are excellent in foaming properties and detergency, long chain higher fatty acid salts having more than 12 carbon atoms cause crystal precipitation at a low temperature, and the porous film of the pump former There was a problem of causing clogging.
特許文献1には、洗浄成分として高級脂肪酸石鹸を含まず、(a)短鎖長のアシルタウリン塩、(b)両性界面活性剤、及び(c)カチオン化デンプンを配合することにより、容器の目詰まりがなく、低温下でもクリーミーな泡質が安定して得られ、コンディショニング効果も得られるポンプフォーマー用の液状洗浄剤組成物が開示されている。 Patent Document 1 does not contain a higher fatty acid soap as a cleaning component, and contains (a) a short chain length acyltaurine salt, (b) an amphoteric surfactant, and (c) a cationized starch. There is disclosed a liquid detergent composition for a pump former that is free from clogging, stably obtains a creamy foam quality even at a low temperature, and has a conditioning effect.
洗浄成分として高級脂肪酸石鹸を用いた例では、イオン性界面活性剤(その90質量%を高級脂肪酸石鹸が占める)の配合量を2〜5質量%に抑制し、20〜60質量%の多価アルコール(20質量%未満のプロピレングリコールを含む)を配合したポンプフォーマー用の洗浄剤組成物がある(特許文献2)。特許文献2の洗浄剤組成物は、泡質及び低温安定性に優れるのみならず、少量の水で容易に洗い流すことができることを特徴としている。 In the example using the higher fatty acid soap as the cleaning component, the blending amount of the ionic surfactant (90% by mass of the higher fatty acid soap) is suppressed to 2 to 5% by mass, and the polyvalent amount of 20 to 60% by mass is controlled. There is a cleaning composition for pump formers containing alcohol (including propylene glycol of less than 20% by mass) (Patent Document 2). The cleaning composition of Patent Document 2 is characterized by not only excellent foam quality and low-temperature stability, but also can be easily washed away with a small amount of water.
本発明は、上記の従来技術を更に改善し、高級脂肪酸石鹸の配合量を抑制せずに十分な洗浄効果を発揮し、なおかつ低温保存しても結晶析出による目詰まりを生じない安定性を有し、特に持続性及び弾力性に優れた泡質が得られるポンプフォーマー用の洗浄剤組成物を提供することを目的とする。 The present invention further improves the above-described conventional technology, exhibits a sufficient cleaning effect without suppressing the blending amount of the higher fatty acid soap, and has stability that does not cause clogging due to crystal precipitation even when stored at a low temperature. It is an object of the present invention to provide a cleaning composition for a pump former that can obtain a foam having excellent durability and elasticity.
上記の課題を解決すべく、本発明者等は鋭意研究を行った結果、鎖長の異なる高級脂肪酸石鹸を所定比率で組み合わせて配合することにより、持続性及び弾力性に優れた泡質を有し、低温でも目詰まりを生じない洗浄剤組成物を得ることができることを見出し、本発明を完成するに至った。 In order to solve the above-mentioned problems, the present inventors have conducted intensive research, and as a result, blended high-grade fatty acid soaps having different chain lengths in a predetermined ratio so as to have a foam quality excellent in sustainability and elasticity. The inventors have found that it is possible to obtain a cleaning composition that does not clog even at low temperatures, and have completed the present invention.
即ち本発明は、
(a)ラウリルジメチルアミノ酢酸ベタインと、
(b)炭素数5〜25の脂肪酸から形成される高級脂肪酸石鹸4〜15質量%と、
を含有するフォーマー容器で吐出される洗浄料組成物であって、
前記炭素数5〜25の脂肪酸が、
(b−1)高級脂肪酸石鹸を形成する脂肪酸全重量に対して30〜80質量%のラウリン酸、
(b−2)高級脂肪酸石鹸を形成する脂肪酸全重量に対して5〜30質量%のミリスチン酸、及び
(b−3)高級脂肪酸石鹸を形成する脂肪酸全重量に対して5〜35質量%の、パルミチン酸及びステアリン酸から選択される少なくとも一種を含み、
前記(a)ラウリルジメチルアミノ酢酸ベタインの配合量と(b)高級脂肪酸石鹸の配合量との比率[(a)/(b)]が0.4〜1.5の範囲内であることを特徴とする洗浄剤組成物を提供する。
That is, the present invention
(A) lauryldimethylaminoacetic acid betaine;
(B) 4 to 15% by mass of a higher fatty acid soap formed from a fatty acid having 5 to 25 carbon atoms;
A cleaning composition discharged in a former container containing
The fatty acid having 5 to 25 carbon atoms is
(B-1) 30 to 80% by mass of lauric acid based on the total weight of fatty acids forming the higher fatty acid soap,
(B-2) 5-30 mass% of myristic acid with respect to the total weight of fatty acids forming the higher fatty acid soap, and (b-3) 5-35 mass% with respect to the total weight of fatty acids forming the higher fatty acid soap. Including at least one selected from palmitic acid and stearic acid,
The ratio [(a) / (b)] of the blending amount of the (a) lauryldimethylaminoacetic acid betaine and the blending amount of the (b) higher fatty acid soap is in the range of 0.4 to 1.5. A cleaning composition is provided.
本発明の洗浄剤組成物は、泡の持続性に優れ、泡の弾力性に富んだ良好な泡質を有し、低温安定性に優れ、低温保存した場合でもポンプフォーマーの目詰まりを起こさない。
本明細書における「泡の持続性」とは、フォーマー容器から吐出された洗浄剤の泡が、肌に塗布して馴染ませる際に、直ぐにつぶれずに泡形状を持続する性質を意味し、「泡の弾力性」とはフォーマー容器から吐出された洗浄剤の泡が適度な弾力を有するもちもちした感触を呈することを意味する。
The cleaning composition of the present invention has good foam quality with excellent foam persistence, high foam elasticity, excellent low-temperature stability, and causes clogging of the pump former even when stored at low temperatures. Absent.
As used herein, “foam persistence” means the property that the foam of the detergent discharged from the former container maintains the foam shape without being immediately crushed when applied to the skin and acclimatized. The term “foam elasticity” means that the foam of the cleaning agent discharged from the former container has a moist feeling with an appropriate elasticity.
以下、本発明について詳細に説明する。
(a)ラウリルジメチルアミノ酢酸ベタイン
本発明で用いられるラウリルジメチルアミノ酢酸ベタイン(N−ラウリルジメチルアミノ酢酸ベタインとも表記する)は、下記式(1)で表される構造を有する化合物である。
C12H25−N+(CH3)2−CH2COO− …(1)
Hereinafter, the present invention will be described in detail.
(A) Lauryldimethylaminoacetic acid betaine Lauryldimethylaminoacetic acid betaine (also referred to as N-lauryldimethylaminoacetic acid betaine) used in the present invention is a compound having a structure represented by the following formula (1).
C 12 H 25 -N + (CH 3) 2 -CH 2 COO - ... (1)
本発明の洗浄剤組成物におけるラウリルジメチルアミノ酢酸ベタインの配合量は、後述する高級脂肪酸石鹸の配合量を基準として決定されるが、通常は2〜20質量%、好ましくは2.5〜18質量%、より好ましくは3〜15質量%であるが、これらに限定されず、前記範囲に含まれる範囲、例えば、2〜9質量%、3〜8質量%、又は4〜7質量%等の範囲とすることもできる。 The blending amount of lauryldimethylaminoacetic acid betaine in the cleaning composition of the present invention is determined based on the blending amount of the higher fatty acid soap described later, but is usually 2 to 20% by mass, preferably 2.5 to 18% by mass. %, More preferably 3 to 15% by mass, but not limited thereto, the range included in the above range, for example, 2 to 9% by mass, 3 to 8% by mass, or 4 to 7% by mass, etc. It can also be.
(b)高級脂肪酸石鹸
本発明の洗浄剤組成物は、洗浄成分として高級脂肪酸石鹸を含有する。本発明における高級脂肪酸石鹸は、炭素数5〜25の脂肪酸アニオンと対カチオンとの塩から形成される。
炭素数5〜25の脂肪酸は、直鎖状又は分岐鎖状の飽和又は不飽和の一価炭化水素基、例えばアルキル基、アルキレン基等にカルボキシル基が結合した構造を有するカルボン酸であり、前記炭化水素基は任意に水酸基等で置換されていてもよい。
(B) Higher fatty acid soap The cleaning composition of the present invention contains a higher fatty acid soap as a cleaning component. The higher fatty acid soap in the present invention is formed from a salt of a fatty acid anion having 5 to 25 carbon atoms and a counter cation.
The fatty acid having 5 to 25 carbon atoms is a carboxylic acid having a structure in which a carboxyl group is bonded to a linear or branched saturated or unsaturated monovalent hydrocarbon group such as an alkyl group or an alkylene group, The hydrocarbon group may be optionally substituted with a hydroxyl group or the like.
炭素数5〜25の脂肪酸の例としては、カプロン酸、ヘプタン酸、カプリル酸、ペラルゴン酸、カプリン酸、ウンデカン酸、ラウリン酸、カプロレイン酸、ウンデシレン酸、ラウロレイン酸、2−エチルブタン酸、イソペンタン酸、2−エチルペンタン酸、2−エチルヘキサン酸、イソノナン酸、3,5,5−トリメチルヘキサン酸、トリデカン酸、テトラメチルノナン酸、ミリスチン酸、ペンタデカン酸、パルミチン酸、ステアリン酸、アラキン酸、ベヘン酸、リグノセリン酸、セロチン酸、ミリストレイン酸、パルミトレイン酸、オレイン酸、エライジン酸、ゴンドイン酸、エルカ酸、セラコレイン酸、リノール酸、リノエライジン酸、リノレン酸、アラキドン酸、2−ヘキシルデカン酸、イソステアリン酸、12−ヒドロキシステアリン酸、ヤシ油脂肪酸、硬化ヤシ油脂肪酸、パーム油脂肪酸、硬化パーム油脂肪酸、パーム核油脂肪酸、硬化パーム核油脂肪酸、牛脂脂肪酸、硬化牛脂脂肪酸等が挙げられる。 Examples of fatty acids having 5 to 25 carbon atoms include caproic acid, heptanoic acid, caprylic acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, caproleic acid, undecylenic acid, lauroleic acid, 2-ethylbutanoic acid, isopentanoic acid, 2-ethylpentanoic acid, 2-ethylhexanoic acid, isononanoic acid, 3,5,5-trimethylhexanoic acid, tridecanoic acid, tetramethylnonanoic acid, myristic acid, pentadecanoic acid, palmitic acid, stearic acid, arachidic acid, behenic acid , Lignoceric acid, serotic acid, myristic acid, palmitoleic acid, oleic acid, elaidic acid, gondoic acid, erucic acid, cerakoleic acid, linoleic acid, linoelaidic acid, linolenic acid, arachidonic acid, 2-hexyldecanoic acid, isostearic acid, 12-hydroxy steari Acid, coconut oil fatty acid, hardened coconut oil fatty acid, palm oil fatty acid, hydrogenated palm oil fatty acids, palm kernel oil fatty acid, hardened palm kernel oil fatty acid, tallow fatty acid, hardened tallow fatty acid, and the like.
本発明では、炭素数5〜25の脂肪酸の中でも、炭素数8〜20、あるいは炭素数12〜18の直鎖状飽和脂肪酸から形成される高級脂肪酸を用いるのが好ましい。即ち、本発明で用いられる脂肪酸石鹸は、分岐鎖状脂肪酸又は不飽和脂肪酸から形成される脂肪酸石鹸を含まない態様を包含する。 In the present invention, among fatty acids having 5 to 25 carbon atoms, higher fatty acids formed from linear saturated fatty acids having 8 to 20 carbon atoms or 12 to 18 carbon atoms are preferably used. That is, the fatty acid soap used in the present invention includes an embodiment that does not include a fatty acid soap formed from a branched chain fatty acid or an unsaturated fatty acid.
本発明の洗浄剤組成物は、(b−1)ラウリン酸及び(b−2)ミリスチン酸及び(b−3)パルミチン酸及びステアリン酸から選択される少なくとも1種を含む直鎖状飽和脂肪酸から形成される高級脂肪酸石鹸を含有する。 The detergent composition of the present invention comprises (b-1) lauric acid and (b-2) myristic acid and (b-3) a linear saturated fatty acid containing at least one selected from palmitic acid and stearic acid. Contains higher fatty acid soaps that are formed.
(b−1)ラウリン酸
本発明における高級脂肪酸石鹸は、ラウリン酸から形成される脂肪酸石鹸を、高級脂肪酸石鹸を形成する脂肪酸全重量に対して30〜80質量%含有する。
(b−2)ミリスチン酸
本発明における高級脂肪酸石鹸は、ラウリン酸から形成される脂肪酸石鹸を、高級脂肪酸石鹸を形成する脂肪酸全重量に対して5〜30質量%含有する。
(B-1) Lauric acid The higher fatty acid soap in the present invention contains a fatty acid soap formed from lauric acid in an amount of 30 to 80% by mass based on the total weight of fatty acids forming the higher fatty acid soap.
(B-2) Myristic acid The higher fatty acid soap in this invention contains 5-30 mass% of fatty acid soap formed from lauric acid with respect to the total weight of fatty acids forming the higher fatty acid soap.
(b−3)パルミチン酸及びステアリン酸
本発明における高級脂肪酸石鹸は、パルミチン酸及びステアリン酸から選択される少なくとも一種から形成される脂肪酸石鹸を、高級脂肪酸石鹸を形成する脂肪酸全重量に対して5〜35質量%含有する。パルミチン酸及びステアリン酸の合計配合量が35質量%を超えると十分な低温安定性が得られない場合がある。冬季の寒冷地等の低温安定性が特に求められる環境で使用する場合には、パルミチン酸及び/又はステアリン酸の配合量を5〜30質量%とするのが好ましく、より好ましくは5〜25質量%、さらに好ましくは5〜20質量%である。
(B-3) Palmitic acid and stearic acid The higher fatty acid soap in the present invention is a fatty acid soap formed of at least one selected from palmitic acid and stearic acid, and is 5 relative to the total weight of fatty acids forming the higher fatty acid soap. Contains ~ 35% by mass. If the total amount of palmitic acid and stearic acid exceeds 35% by mass, sufficient low temperature stability may not be obtained. When used in an environment where low temperature stability is particularly required, such as in cold regions in winter, the blending amount of palmitic acid and / or stearic acid is preferably 5 to 30% by mass, more preferably 5 to 25% by mass. %, More preferably 5 to 20% by mass.
パルミチン酸及びステアリン酸から選択される少なくとも一種とは、パルミチン酸又はステアリン酸の一方のみを含む態様と、パルミチン酸とステアリン酸の両方を含む態様とを包含する。パルミチン酸とステアリン酸の両方を含む態様では、パリミチン酸とステアリン酸との配合量比率[パルミチン酸/ステアリン酸]を0.4〜2.5の範囲とするのが好ましい。この数値範囲は、0.4〜2.5に含まれる任意の範囲(例えば0.4〜2.0又は1.0〜2.0等)及び当該範囲に含まれる全ての数値を包含する。 The at least one selected from palmitic acid and stearic acid includes an embodiment containing only one of palmitic acid or stearic acid and an embodiment containing both palmitic acid and stearic acid. In an embodiment containing both palmitic acid and stearic acid, the blending ratio of palmitic acid and stearic acid [palmitic acid / stearic acid] is preferably in the range of 0.4 to 2.5. This numerical range includes an arbitrary range included in 0.4 to 2.5 (for example, 0.4 to 2.0 or 1.0 to 2.0) and all numerical values included in the range.
本発明の洗浄剤組成物は、ラウリン酸(炭素数12)及びミリスチン酸(炭素数14)に加えて、パルミチン酸(炭素数16)及び/又はステアリン酸(炭素数18)を配合することにより、持続性が良好な泡質が得られるとともに低温安定性にも優れている。
一般に、高級脂肪酸の鎖長(炭素数)が増加すると結晶析出が起こりやすいと考えられていることに鑑みれば、従来から汎用されていたラウリン酸及びミリスチン酸に加えて炭素数の多いパルミチン酸及び/又はステアリン酸を配合することにより低温安定性が向上したことは当業者が予測できない効果である。
In addition to lauric acid (carbon number 12) and myristic acid (carbon number 14), the detergent composition of the present invention contains palmitic acid (carbon number 16) and / or stearic acid (carbon number 18). In addition, a foam having good sustainability can be obtained and the low temperature stability is also excellent.
In general, in view of the fact that crystallization is likely to occur when the chain length (carbon number) of higher fatty acids increases, palmitic acid having a large number of carbons in addition to lauric acid and myristic acid that have been conventionally used and The improvement in low-temperature stability by adding stearic acid is an effect that cannot be predicted by those skilled in the art.
高級脂肪酸アニオンを中和する対カチオンとしては、アルカリ金属カチオン、特にカリウムカチオンとするのが好ましい。本発明における(a)高級脂肪酸石鹸には、脂肪酸のアルギニン塩及びメチルタウリン塩は含まれない。 The counter cation for neutralizing the higher fatty acid anion is preferably an alkali metal cation, particularly a potassium cation. The (a) higher fatty acid soap in the present invention does not contain fatty acid arginine salts and methyl taurine salts.
本発明の洗浄剤組成物における(b)高級脂肪酸石鹸の配合量は4〜15質量%であり、好ましくは5〜12質量%、より好ましくは5〜10質量%、さらに好ましくは6〜8質量%である。ここで、高級脂肪酸石鹸の配合量とは、高級脂肪酸と中和剤(例えば水酸化カリウム)の合計配合量を意味する。 The blending amount of (b) higher fatty acid soap in the cleaning composition of the present invention is 4 to 15% by mass, preferably 5 to 12% by mass, more preferably 5 to 10% by mass, and further preferably 6 to 8% by mass. %. Here, the compounding quantity of a higher fatty acid soap means the total compounding quantity of a higher fatty acid and a neutralizing agent (for example, potassium hydroxide).
本発明の洗浄剤組成物においては、(a)ラウリルジメチルアミノ酢酸ベタインの配合量と(b)高級脂肪酸石鹸の配合量との比率[(a)/(b)]は0.4〜1.5であり、この配合量比率は、0.5〜1.2の範囲内とするのが更に好ましい。この配合量比率が0.4未満であると十分な低温安定性が得られない。 In the cleaning composition of the present invention, the ratio [(a) / (b)] of (a) the blending amount of lauryldimethylaminoacetic acid betaine and (b) the blending amount of higher fatty acid soap is 0.4 to 1. The blending ratio is more preferably within the range of 0.5 to 1.2. When the blending ratio is less than 0.4, sufficient low temperature stability cannot be obtained.
(c)多価アルコール
本発明の洗浄剤組成物は、(a)ラウリルジメチルアミノ酢酸ベタイン、及び(b)高級脂肪酸石鹸という必須成分に加えて、多価アルコールを配合するのが好ましい。
配合され得る多価アルコールは、化粧料等に通常配合されるものから選択することができ、例えば、グリセリン、プロピレングリコール、ジプロピレングリコール、1,3−ブチレングリコール、エチレングリコール、ポリエチレングリコール、ソルビトール等が挙げられる。
(C) Polyhydric alcohol The detergent composition of the present invention preferably contains a polyhydric alcohol in addition to the essential components (a) lauryldimethylaminoacetic acid betaine and (b) higher fatty acid soap.
The polyhydric alcohol that can be blended can be selected from those usually blended in cosmetics and the like, such as glycerin, propylene glycol, dipropylene glycol, 1,3-butylene glycol, ethylene glycol, polyethylene glycol, sorbitol, and the like. Is mentioned.
多価アルコールの配合量は、特に限定されないが、通常は10〜50質量%、好ましくは20〜50質量%、より好ましくは25〜40質量%である。 Although the compounding quantity of a polyhydric alcohol is not specifically limited, Usually, 10-50 mass%, Preferably it is 20-50 mass%, More preferably, it is 25-40 mass%.
多価アルコールの中でも、IOB=3〜4の多価アルコールを配合することにより、フォーマーから吐出される泡の弾力性を向上させることができるので好ましい。IOB=3〜4の多価アルコールとしては、ジグリセリン、プロピレングリコール等を例示することができる。 Among polyhydric alcohols, blending polyhydric alcohols with IOB = 3 to 4 is preferable because the elasticity of bubbles discharged from the former can be improved. Examples of the polyhydric alcohol with IOB = 3 to 4 include diglycerin and propylene glycol.
IOB=3〜4の多価アルコールの配合量は、組成物全重量に対して通常は0.1〜10質量%、好ましくは0.5〜8質量%、より好ましくは1〜5質量%である。 The blending amount of the polyhydric alcohol with IOB = 3 to 4 is usually 0.1 to 10% by mass, preferably 0.5 to 8% by mass, more preferably 1 to 5% by mass with respect to the total weight of the composition. is there.
本発明の洗浄剤組成物は、液体洗浄剤組成物に通常用いられる他の任意成分を、本発明の効果を阻害しない範囲で含有しても良い、他の任意成分の具体例を挙げれば、油分、シリコーン類、低級又は高級アルコール類、ラノリン誘導体、蛋白誘導体、各種薬剤、殺菌剤、防腐剤、pH調整剤、酸化防止剤、金属イオン封鎖剤、キレート剤、動植物抽出物又はその誘導体、色素、香料、顔料、有機又は無機粉体、粘土鉱物等が挙げられる。これらの1種または2種以上を任意に選択して配合できる。 The cleaning composition of the present invention may contain other optional components usually used in the liquid cleaning composition within a range that does not impair the effects of the present invention. Oils, silicones, lower or higher alcohols, lanolin derivatives, protein derivatives, various drugs, bactericides, preservatives, pH adjusters, antioxidants, sequestering agents, chelating agents, animal and plant extracts or their derivatives, pigments Fragrances, pigments, organic or inorganic powders, clay minerals and the like. These 1 type (s) or 2 or more types can be selected arbitrarily and can be mix | blended.
本発明の洗浄剤組成物は、限定されないが、例えば、B型回転粘度計を用いて30℃の温度で測定した粘度が40mPa・s以下、好ましくは30mPa・s以下、より好ましくは20mPa・s程度の低粘度液体として提供される。 The cleaning composition of the present invention is not limited. For example, the viscosity measured at a temperature of 30 ° C. using a B-type rotational viscometer is 40 mPa · s or less, preferably 30 mPa · s or less, more preferably 20 mPa · s. Provided as a low viscosity liquid to the extent.
本発明の洗浄剤組成物は、上述した必須成分及び任意成分を用いて、常法に準じて製造することができる。 The cleaning composition of the present invention can be produced according to a conventional method using the essential components and optional components described above.
調製された本発明の洗浄剤組成物は、多孔質膜を有するノンガスタイプの泡吐出容器に収容される。本発明で用いられるノンガスタイプの泡吐出容器は、一定量の液体洗浄剤組成物を一定量の空気と混合し、泡状態として使用時に容器より吐出させるものであれば公知のいずれのタイプのものでもよい。具体的には、例えば、軟質容器の胴部を手指で押圧することにより使用するスクイズフォーマー、ポンプ機構を備えたキャップの頭を指で押圧することにより使用されるポンプフォーマー等が挙げられる。そして使用時、容器内の液体洗浄剤組成物を空気と混合した混合物を多孔質膜(1枚から複数枚)に通すことによって、該液体洗浄剤組成物を容器吐出口から泡状として吐出させるようになっている。 The prepared cleaning composition of the present invention is accommodated in a non-gas type foam discharge container having a porous film. The non-gas type foam discharge container used in the present invention is of any known type as long as a certain amount of liquid detergent composition is mixed with a certain amount of air and discharged from the container at the time of use as a foam state. But you can. Specifically, for example, a squeeze foamer that is used by pressing the torso of a soft container with fingers, a pump former that is used by pressing the head of a cap equipped with a pump mechanism with fingers, and the like. . In use, the liquid detergent composition in the container is discharged from the container discharge port as a foam by passing a mixture obtained by mixing the liquid detergent composition with air through the porous membrane (one to a plurality of sheets). It is like that.
ポンプフォーマー容器の多孔質膜としては、例えばスポンジ、焼結体、ネットなどが挙げられるが、使用性等の点から薄肉であるネットが好ましい。目の粗さとしては30〜400メッシュ程度のものが好ましく用いられる。本発明の洗浄剤組成物には、2枚の多孔質膜を具備する容器を用いるのが好ましく、一方の多孔質膜を200メッシュ、他方の多孔質膜を305メッシュという細かい網目としても目詰まりを生じず、良好な泡質を得ることができる。 Examples of the porous film of the pump former container include a sponge, a sintered body, and a net, but a thin net is preferable from the viewpoint of usability. A coarseness of about 30 to 400 mesh is preferably used. In the cleaning composition of the present invention, it is preferable to use a container having two porous membranes. Even if one porous membrane is 200 mesh and the other porous membrane is 305 mesh, it is clogged. And good foam quality can be obtained.
本発明の洗浄剤組成物は、ポンプフォーマー容器に収容された毛髪や皮膚の洗浄剤として、洗顔料、ボディソープ、ハンドソープ、シャンプーなどの形態で好適に提供される。 The cleaning composition of the present invention is suitably provided in the form of a facial cleanser, body soap, hand soap, shampoo and the like as a cleaning agent for hair and skin contained in a pump former container.
以下、具体例を挙げて本発明を更に詳細に説明するが、これらは本発明の技術的範囲を何ら限定するものではない。
なお、以下の実施例等における配合量は特記しない限り質量%である。
Hereinafter, the present invention will be described in more detail with reference to specific examples, but these do not limit the technical scope of the present invention.
In addition, the compounding quantity in a following example etc. is the mass% unless it mentions specially.
下記表の各例に記載した組成で洗浄剤を常法に従って調製した。
各例で得られた洗浄剤について、以下の項目について下記の基準に従って評価した。
(1)低温安定性
調製した洗浄剤組成物を硬質ガラスのバイアルビンに充填し、各温度(−10〜5℃)に保持された評価室において24時間及び1週間保存させた後、洗浄剤組成物の低温安定性を目視で観察し、下記評価基準で評価した。
○:良好(析出物・沈殿物がなく外観の変化がない。目詰まりを起こす可能性が無い)
×:不良(析出物・沈殿物があり品質上問題がある。目詰まりを起こす可能性がある)
通常の使用環境であれば、少なくとも−5℃〜+5℃で24時間及び+5℃で1週間の保存を終えた時点での評価が「○」であれば商品として提供できる十分な特性を備えている。
A detergent was prepared according to a conventional method with the composition described in each example of the following table.
About the cleaning agent obtained in each case, the following items were evaluated according to the following criteria.
(1) Stability at low temperature After the prepared detergent composition is filled in a vial of hard glass and stored in an evaluation room maintained at each temperature (-10 to 5 ° C) for 24 hours and one week, the detergent The low temperature stability of the composition was visually observed and evaluated according to the following evaluation criteria.
○: Good (no deposits / precipitates, no change in appearance, no possibility of clogging)
×: Defect (There are deposits and deposits, which causes quality problems. Clogging may occur)
If it is a normal use environment, if it is evaluated as “◯” at the end of storage for at least −5 ° C. to + 5 ° C. for 24 hours and + 5 ° C. for 1 week, it has sufficient characteristics that can be provided as a product. Yes.
(2)使用性試験
ポンプフォーマー容器(メッシュ200×305)に収容した各例の洗浄剤組成物を泡状に吐出させて実使用した際の泡質(泡の持続性、泡の弾力性)について専門パネルが評価した。評価は以下の基準に従って実施した。
[評価基準]
A:非常に優れている
B:優れている
C:劣っている
なお、評価結果がA又はBであるものは、商品として提供するのに十分な特性を備えている。
(2) Usability test Foam quality (foam durability, foam elasticity, when the detergent composition of each example contained in a pump former container (mesh 200 × 305) is discharged in the form of foam and actually used. ) Was evaluated by the expert panel. Evaluation was performed according to the following criteria.
[Evaluation criteria]
A: Very good B: Excellent C: Inferior In addition, the thing whose evaluation result is A or B is equipped with the characteristic sufficient to provide as goods.
(3)粘度測定
各例で調製した洗浄剤組成物について、B型粘度計(ローターNo.1、60rpm)を用い、30℃の粘度を測定した。測定結果を各表に示す。
(3) Viscosity measurement About the detergent composition prepared in each example, the viscosity at 30 ° C. was measured using a B-type viscometer (rotor No. 1, 60 rpm). The measurement results are shown in each table.
上記の表1〜4に示した結果から、ラウリン酸及びミリスチン酸、及びパルミチン酸及び/又はステアリン酸を、本発明所定の比率で含む高級脂肪酸を含有し、なおかつN−ラウリルジメチルアミノ酢酸ベタインを所定比率で含有する実施例の洗浄剤組成物は、低温安定性に優れておりフォーマー容器の目詰まりを起こすことがないのみならず、生成される泡の持続性にも優れている。一方、パルミチン酸もステアリン酸も含まない比較例1は泡の持続性が劣る。脂肪酸の配合比率が本発明の要件を満たさない(パルミチン酸及びステアリン酸の合計配合量が35質量%を超える)比較例2〜4、及びN−ラウリルジメチルアミノ酢酸ベタインと高級脂肪酸石鹸との配合量比率が本発明の範囲(0.4〜1.5)から外れる比較例5では十分な低温安定性が得られなかった。 From the results shown in Tables 1 to 4 above, the present invention contains higher fatty acids containing lauric acid and myristic acid, and palmitic acid and / or stearic acid at a predetermined ratio of the present invention, and N-lauryldimethylaminoacetic acid betaine. The cleaning compositions of Examples contained at a predetermined ratio are excellent in low-temperature stability and do not cause clogging of the former container, and are excellent in the sustainability of the generated foam. On the other hand, Comparative Example 1 containing neither palmitic acid nor stearic acid has poor foam persistence. The blending ratio of the fatty acid does not satisfy the requirements of the present invention (the total blending amount of palmitic acid and stearic acid exceeds 35% by mass) and Comparative Examples 2 to 4, and blending of N-lauryldimethylaminoacetic acid betaine and higher fatty acid soap In Comparative Example 5 in which the amount ratio is out of the range (0.4 to 1.5) of the present invention, sufficient low temperature stability was not obtained.
(b)高級脂肪酸石鹸の配合量が4質量%に満たない比較例6も、比較例1と同様に泡の持続性が劣り、組成物の粘度が30mPa・sを超える比較例7はポンプフォーマーで吐出することが困難であった。また、N−ラウリルジメチルアミノ酢酸ベタインをコカミドプロピルベタイン(ヤシ油脂肪酸アミドプロピルベタイン)に置換した比較例8は低温安定性に劣るものとなった。また、高級脂肪酸石鹸を形成する脂肪酸としてパルミチン酸及びステアリン酸を合計で30質量%以上含む実施例9に比較すると、その配合量が20〜30質量%である実施例4及び6〜8、さらに20質量%以下である実施例2、3及び5では、より過酷な低温条件でも析出等が生じなくなり、冬季の寒冷地等での使用に特に適したものとなることが確認された。 (B) Comparative Example 6 in which the blending amount of the higher fatty acid soap is less than 4% by mass is inferior in the persistence of the foam as in Comparative Example 1, and Comparative Example 7 in which the viscosity of the composition exceeds 30 mPa · s is It was difficult to discharge with a mer. Further, Comparative Example 8 in which N-lauryldimethylaminoacetic acid betaine was substituted with cocamidopropyl betaine (coconut oil fatty acid amidopropyl betaine) was inferior in low-temperature stability. Moreover, when compared with Example 9 containing 30% by mass or more of palmitic acid and stearic acid as the fatty acids forming the higher fatty acid soap, Examples 4 and 6-8 having a blending amount of 20-30% by mass, In Examples 2, 3 and 5 which are 20% by mass or less, it was confirmed that precipitation or the like did not occur even under severer low temperature conditions, and that it was particularly suitable for use in cold regions in winter.
表5に示した結果によれば、IOB=3〜4の多価アルコールであるジグリセリン(IOB=3.50)は、本発明の効果を得るために必須ではないが(実施例12)、IOB=3〜4の多価アルコールの配合がフォーマーから吐出される泡の弾力性を向上させることが確認された(実施例13及び14)。 According to the results shown in Table 5, diglycerin (IOB = 3.50), which is a polyhydric alcohol with IOB = 3 to 4, is not essential for obtaining the effects of the present invention (Example 12). It was confirmed that the blending of polyhydric alcohols with IOB = 3-4 improves the elasticity of the foam discharged from the former (Examples 13 and 14).
Claims (7)
(b)炭素数5〜25の脂肪酸から形成される高級脂肪酸石鹸4〜15質量%と、
を含有するフォーマー容器で吐出される洗浄料組成物であって、
前記炭素数5〜25の脂肪酸が、
(b−1)高級脂肪酸石鹸を形成する脂肪酸全重量に対して30〜80質量%のラウリン酸、
(b−2)高級脂肪酸石鹸を形成する脂肪酸全重量に対して5〜30質量%のミリスチン酸、及び
(b−3)高級脂肪酸石鹸を形成する脂肪酸全重量に対して5〜20質量%の、パルミチン酸及びステアリン酸から選択される少なくとも一種を含み、
前記(a)ラウリルジメチルアミノ酢酸ベタインの配合量と(b)高級脂肪酸石鹸の配合量との比率[(a)/(b)]が0.76〜1.5の範囲内であり、
B型回転粘度計を用いて30℃の温度で測定した粘度が、30mPa・s以下であることを特徴とする洗浄剤組成物。 (A) lauryldimethylaminoacetic acid betaine;
(B) 4 to 15% by mass of a higher fatty acid soap formed from a fatty acid having 5 to 25 carbon atoms;
A cleaning composition discharged in a former container containing
The fatty acid having 5 to 25 carbon atoms is
(B-1) 30 to 80% by mass of lauric acid based on the total weight of fatty acids forming the higher fatty acid soap,
(B-2) myristic acid 5-30% by weight relative to the total fatty acid weight to form a higher fatty acid soap, and (b-3) 5~ 20 wt% relative to the total fatty acid weight to form a higher fatty acid soap Including at least one selected from palmitic acid and stearic acid,
Wherein (a) the ratio of the amount of lauryl dimethylamino acetic acid betaine and (b) the amount of the higher fatty acid soaps [(a) / (b)] is Ri Der range of 0.76 to 1.5,
B-type viscosity measured at a temperature of 30 ° C. using a rotary viscometer, the detergent composition characterized by the following der Rukoto 30 mPa · s.
質量%である、請求項1から6のいずれか一項に記載の洗浄剤組成物。The cleaning composition according to any one of claims 1 to 6, wherein the cleaning composition is in mass%.
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KR20180068998A (en) | 2018-06-22 |
CN108348430A (en) | 2018-07-31 |
TWI675912B (en) | 2019-11-01 |
TW201716564A (en) | 2017-05-16 |
CN108348430B (en) | 2022-02-15 |
KR102004746B1 (en) | 2019-07-29 |
SG11201803734XA (en) | 2018-06-28 |
WO2017081897A1 (en) | 2017-05-18 |
HK1251452A1 (en) | 2019-02-01 |
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