KR20180068998A - Cleaner composition for pump formers - Google Patents
Cleaner composition for pump formers Download PDFInfo
- Publication number
- KR20180068998A KR20180068998A KR1020187012301A KR20187012301A KR20180068998A KR 20180068998 A KR20180068998 A KR 20180068998A KR 1020187012301 A KR1020187012301 A KR 1020187012301A KR 20187012301 A KR20187012301 A KR 20187012301A KR 20180068998 A KR20180068998 A KR 20180068998A
- Authority
- KR
- South Korea
- Prior art keywords
- acid
- fatty acid
- mass
- soap
- higher fatty
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract description 40
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 86
- 229930195729 fatty acid Natural products 0.000 claims abstract description 86
- 239000000194 fatty acid Substances 0.000 claims abstract description 86
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 83
- 239000000344 soap Substances 0.000 claims abstract description 47
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims abstract description 44
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 23
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims abstract description 23
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 23
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000008117 stearic acid Substances 0.000 claims abstract description 23
- 235000021314 Palmitic acid Nutrition 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 17
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229960003237 betaine Drugs 0.000 claims abstract description 15
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims abstract description 14
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 claims abstract description 10
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 20
- 150000005846 sugar alcohols Polymers 0.000 claims description 13
- 239000005639 Lauric acid Substances 0.000 claims description 10
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 claims description 6
- 235000021360 Myristic acid Nutrition 0.000 claims description 6
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims description 6
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 3
- 229940105990 diglycerin Drugs 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 5
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 239000003599 detergent Substances 0.000 abstract description 37
- 238000004140 cleaning Methods 0.000 abstract description 7
- 239000006260 foam Substances 0.000 description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 235000019482 Palm oil Nutrition 0.000 description 7
- 239000002540 palm oil Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 230000002688 persistence Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- -1 fatty acid salt Chemical class 0.000 description 5
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 235000019865 palm kernel oil Nutrition 0.000 description 2
- 239000003346 palm kernel oil Substances 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- HRLPTSDRCFNHPE-UHFFFAOYSA-N 2,2,3,3-tetramethylnonanoic acid Chemical compound CCCCCCC(C)(C)C(C)(C)C(O)=O HRLPTSDRCFNHPE-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- OILUAKBAMVLXGF-UHFFFAOYSA-N 3,5,5-trimethyl-hexanoic acid Chemical compound OC(=O)CC(C)CC(C)(C)C OILUAKBAMVLXGF-UHFFFAOYSA-N 0.000 description 1
- AWQSAIIDOMEEOD-UHFFFAOYSA-N 5,5-Dimethyl-4-(3-oxobutyl)dihydro-2(3H)-furanone Chemical compound CC(=O)CCC1CC(=O)OC1(C)C AWQSAIIDOMEEOD-UHFFFAOYSA-N 0.000 description 1
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- PITXHRIPAZEREM-UHFFFAOYSA-N C(CCCCCCCCCCC)C(C(=O)O)N(C)C.[Ba] Chemical compound C(CCCCCCCCCCC)C(C(=O)O)N(C)C.[Ba] PITXHRIPAZEREM-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- 235000021353 Lignoceric acid Nutrition 0.000 description 1
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical class CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021319 Palmitoleic acid Nutrition 0.000 description 1
- 239000005643 Pelargonic acid Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- BAZMYXGARXYAEQ-UHFFFAOYSA-N alpha-ethyl valeric acid Chemical compound CCCC(CC)C(O)=O BAZMYXGARXYAEQ-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000001483 arginine derivatives Chemical class 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229920006319 cationized starch Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000005472 straight-chain saturated fatty acid group Chemical group 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C11D11/0058—
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/42—Application of foam or a temporary coating on the surface to be cleaned
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Emergency Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
본 발명은 거품질 및 저온 안정성을 더욱 개선하여 세정성도 우수한 펌프 포머용의 세정제 조성물을 제공하는 것을 목적으로 한다. 본 발명은 (a) 라우릴디메틸아미노아세트산 베타인과, (b) 탄소수 5~25개의 지방산으로부터 형성되는 고급 지방산 비누 4~15질량%를 함유하는 포머 용기에서 토출되는 세정료 조성물이며, 상기탄소수 5~25개의 지방산이 (b-1) 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 30~80질량%의 라우르산, (b-2) 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 5~30질량%의 미리스트산, 및 (b-3) 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 5~35질량%의 팔미트산 및 스테아르산으로부터 선택되는 적어도 1종을 포함하고, 상기 (a) 라우릴디메틸아미노아세트산 베타인의 배합량과 (b) 고급 지방산 비누의 배합량의 비율[(a)/(b)]이 0.4~1.5의 범위 내인 것을 특징으로 하는 세정제 조성물을 제공한다.It is an object of the present invention to provide a detergent composition for a pump former which is further improved in gingival quality and low-temperature stability and which is also excellent in cleaning property. The present invention relates to a detergent composition which is discharged from a former container containing (a) betaine lauryldimethylaminoacetic acid and (b) 4 to 15% by mass of a higher fatty acid soap formed from fatty acids having 5 to 25 carbon atoms, To 25% by weight, based on the total weight of the fatty acids forming the fatty acid soap (b-2), from 30 to 80% by weight, based on the total weight of fatty acids forming the fatty acid soap (b-1) And (b-3) at least one member selected from palmitic acid and stearic acid in an amount of 5 to 35 mass% based on the total weight of the fatty acid forming the higher fatty acid soap, wherein (a) Wherein the ratio [(a) / (b)] of the blending amount of lauryldimethylaminoacetic acid betaine to the blended amount of the (b) higher fatty acid soap is within a range of 0.4 to 1.5.
Description
본 발명은 펌프 포머 등의 다공질막을 갖는 논가스 타입의 거품 토출 용기에 수용되어 사용 시에 상기 다공질막을 통해 거품 형상으로 토출되는 세정제 조성물에 관한 것이다. 보다 상세하게는 거품의 지속성 및 거품의 탄력성이 우수하고, 또한 저온 안정성이 양호하며 눈 막힘을 발생시키지 않는 펌프 포머용 세정제 조성물에 관한 것이다. The present invention relates to a detergent composition which is accommodated in a non-gas type foam discharge container having a porous membrane such as a pump former and is discharged in a foam form through the porous membrane in use. More particularly, the present invention relates to a detergent composition for pump formers which is excellent in bubble persistence and foam elasticity, has good low-temperature stability and does not cause clogging.
펌프 포머 등의 논가스 타입의 거품 토출 용기에 수용되어 사용 시에 상기 용기로부터 거품 형상으로 토출되는 액상 세정제 조성물이 알려져 있다. 이 타입의 세정제 조성물은 용기에 구비된 다공질막을 통과할 때에 공기와 혼합되어서 거품 형상으로 토출된다. 그러나, 세정 성분으로서 범용되고 있는 고급 지방산 비누는 기포성과 세정성이 우수하지만 특히 탄소수 12개를 초과하는 장쇄 고급 지방산염은 저온 하에서 결정 석출을 발생시켜 펌프 포머의 다공질막의 눈 막힘을 일으킨다는 문제가 있었다.There is known a liquid detergent composition which is accommodated in a non-gas type foam discharge container such as a pump foamer and discharged in a foam form from the container when used. This type of detergent composition is mixed with air and discharged in the form of a foam when passing through the porous film provided in the container. However, the higher fatty acid soap which is generally used as a cleaning component is excellent in foaming property and cleaning property, but in particular, the long chain higher fatty acid salt having more than 12 carbon atoms causes crystal precipitation at a low temperature and clogs the porous membrane of the pump former there was.
특허문헌 1에는 세정 성분으로서 고급 지방산 비누를 포함하지 않고 (a) 단쇄장의 아실타우린염, (b) 양성 계면활성제, 및 (c) 양이온화 전분을 배합함으로써 용기의 눈 막힘이 없어 저온 하에서도 크리미한 거품질이 안정되게 얻어지고 컨디셔닝 효과도 얻어지는 펌프 포머용의 액상 세정제 조성물이 개시되어 있다.Patent Document 1 discloses that even if the high fatty acid soap is not contained as a cleaning component and the acyltaurine salt of the single-chain short chain, the amphoteric surfactant (b) and the cationized starch (c) Discloses a liquid detergent composition for a pump former in which a creamy quality is obtained stably and a conditioning effect is also obtained.
세정 성분으로서 고급 지방산 비누를 사용한 예에서는 이온성 계면활성제 (그 90질량%를 고급 지방산 비누가 차지한다)의 배합량을 2~5질량%로 억제하고, 20~60질량%의 다가 알코올(20질량% 미만의 프로필렌글리콜을 포함한다)을 배합한 펌프 포머용의 세정제 조성물이 있다(특허문헌 2). 특허문헌 2의 세정제 조성물은 거품질 및 저온 안정성이 우수할 뿐만 아니라 소량의 물로 용이하게 씻어낼 수 있는 것을 특징으로 하고 있다.In the example using the high fatty acid soap as a cleaning component, the blending amount of the ionic surfactant (90% by mass thereof is occupied by the high fatty acid soap) is suppressed to 2 to 5% by mass and 20 to 60% by mass of the polyhydric alcohol % Of propylene glycol) (Patent Document 2). The detergent composition of Patent Document 2 is characterized by being excellent in gag quality and low temperature stability and being easily washed with a small amount of water.
본 발명은 상기의 종래 기술을 더욱 개선하여 고급 지방산 비누의 배합량을 억제하지 않고 충분한 세정 효과를 발휘하고, 또한 저온 보존해도 결정 석출에 의한 눈 막힘을 발생시키지 않는 안정성을 갖고, 특히 지속성 및 탄력성이 우수한 거품질이 얻어지는 펌프 포머용의 세정제 조성물을 제공하는 것을 목적으로 한다. It is an object of the present invention to further improve the above-mentioned prior art, to exhibit a sufficient cleaning effect without inhibiting the amount of the higher fatty acid soap, to have stability not causing clogging due to crystal precipitation even at low temperature, And to provide a detergent composition for a pump former in which excellent quality can be obtained.
상기 과제를 해결하기 위해 본 발명자 등은 예의 연구를 행한 결과, 쇄장이 다른 고급 지방산 비누를 소정 비율로 조합하여 배합함으로써 지속성 및 탄력성이 우수한 거품질을 갖고, 저온에서도 눈 막힘을 발생시키지 않는 세정제 조성물을 얻을 수 있는 것을 찾아내어 본 발명을 완성하기에 이르렀다. In order to solve the above problems, the inventors of the present invention have conducted intensive studies, and as a result, they have found that a detergent composition having superior quality with excellent durability and elasticity and having no clogging even at a low temperature by combining high fatty acid soaps having different chain- The present invention has been accomplished on the basis of these findings.
즉, 본 발명은,That is,
(a) 라우릴디메틸아미노아세트산 베타인과,(a) lauryldimethylaminoacetic acid betaine,
(b) 탄소수 5~25개의 지방산으로부터 형성되는 고급 지방산 비누 4~15질량%를 함유하는 포머 용기에서 토출되는 세정료 조성물이며,(b) 4 to 15% by mass of a higher fatty acid soap formed from a fatty acid having 5 to 25 carbon atoms,
상기 탄소수 5~25개의 지방산이,The fatty acid having 5 to 25 carbon atoms,
(b-1) 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 30~80질량%의 라우르산,(b-1) 30 to 80 mass% of lauric acid based on the total weight of the fatty acids forming the higher fatty acid soap,
(b-2) 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 5~30질량%의 미리스트산, 및(b-2) 5 to 30 mass% of myristic acid with respect to the total fatty acid forming the higher fatty acid soap, and
(b-3) 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 5~35질량%의 팔미트산 및 스테아르산으로부터 선택되는 적어도 1종을 포함하고,(b-3) at least one selected from palmitic acid and stearic acid in an amount of 5 to 35 mass%, based on the total weight of the fatty acid forming the higher fatty acid soap,
상기 (a) 라우릴디메틸아미노아세트산 베타인의 배합량과 (b) 고급 지방산 비누의 배합량의 비율[(a)/(b)]이 0.4~1.5의 범위 내인 것을 특징으로 하는 세정제 조성물을 제공한다.Wherein the ratio [(a) / (b)] of the blending amount of (a) barium lauryldimethylaminoacetic acid and (b) the amount of the higher fatty acid soap is within a range of 0.4 to 1.5.
(발명의 효과)(Effects of the Invention)
본 발명의 세정제 조성물은 거품의 지속성이 우수하고, 거품의 탄력성이 풍부한 양호한 거품질을 갖고, 저온 안정성이 우수하고 저온 보존했을 경우이어도 펌프 포머의 눈 막힘을 일으키지 않는다.The detergent composition of the present invention is excellent in the persistence of bubbles, has good elasticity of foam, has excellent low temperature stability, and does not cause clogging of the pump former even when stored at low temperature.
본 명세서에 있어서의 「거품의 지속성」이란 포머 용기로부터 토출된 세정제의 거품이 피부에 도포되어 친숙해지게 할 때에 즉시 찌부러지지 않고 거품 형상을 지속하는 성질을 의미하고, 「거품의 탄력성」이란 포머 용기로부터 토출된 세정제의 거품이 적당한 탄력을 갖는 탱탱한 감촉을 나타내는 것을 의미한다.The term " bubble persistence " in the present specification means a property that the bubble of the cleaning agent discharged from the former container is applied to the skin and becomes familiar when it becomes familiar, Means that the foam of the cleansing agent discharged from the container exhibits a firm feel with appropriate elasticity.
이하, 본 발명에 대하여 상세히 설명한다.Hereinafter, the present invention will be described in detail.
(a) 라우릴디메틸아미노아세트산 베타인(a) lauryldimethylaminoacetic acid betaine
본 발명에서 사용되는 라우릴디메틸아미노아세트산 베타인(N-라우릴디메틸아미노아세트산 베타인으로도 표기한다)은 하기 식(1)으로 나타내어지는 구조를 갖는 화합물이다. The lauryldimethylaminoacetic acid betaine (also referred to as N-lauryldimethylaminoacetic acid betaine) used in the present invention is a compound having a structure represented by the following formula (1).
C12H25-N+(CH3)2-CH2COO- …(1)C 12 H 25 -N + (CH 3 ) 2 -CH 2 COO - ... (One)
본 발명의 세정제 조성물에 있어서의 라우릴디메틸아미노아세트산 베타인의 배합량은 후술하는 고급 지방산 비누의 배합량을 기준으로 해서 결정되지만 통상은 2~20질량%, 바람직하게는 2.5~18질량%, 보다 바람직하게는 3~15질량%이지만 이들에 한정되지 않고 상기 범위에 포함되는 범위, 예를 들면 2~9질량%, 3~8질량%, 또는 4~7질량% 등의 범위로 할 수도 있다.The blending amount of lauryldimethylaminoacetic acid betaine in the detergent composition of the present invention is determined based on the amount of the higher fatty acid soap to be described later, but is usually 2 to 20% by mass, preferably 2.5 to 18% by mass, Is 3 to 15% by mass, but is not limited thereto and may be in the range falling within the above range, for example, 2 to 9% by mass, 3 to 8% by mass, or 4 to 7% by mass.
(b) 고급 지방산 비누(b) High fatty acid soap
본 발명의 세정제 조성물은 세정 성분으로서 고급 지방산 비누를 함유한다. 본 발명에 있어서의 고급 지방산 비누는 탄소수 5~25개의 지방산 음이온과 카운터 양이온의 염으로부터 형성된다. 탄소수 5~25개의 지방산은 직쇄상 또는 분기쇄상의 포화 또는 불포화의 1가 탄화수소기, 예를 들면 알킬기, 알킬렌기 등에 카르복실 기가 결합한 구조를 갖는 카르복실산이며, 상기 탄화수소기는 임의로 수산기 등으로 치환되어 있어도 좋다.The detergent composition of the present invention contains a higher fatty acid soap as a cleaning component. The higher fatty acid soap in the present invention is formed from a salt of a fatty acid anion having 5 to 25 carbon atoms and a counter cation. The fatty acid having 5 to 25 carbon atoms is a linear or branched saturated or unsaturated monovalent hydrocarbon group, for example, a carboxylic acid having a structure in which a carboxyl group is bonded to an alkyl group or an alkylene group, and the hydrocarbon group is optionally substituted with a hydroxyl group .
탄소수 5~25개의 지방산의 예로서는 카프로산, 헵탄산, 카프릴산, 펠라르곤산, 카프르산, 운데칸산, 라우르산, 카프롤레산, 운데실렌산, 라우롤레산, 2-에틸 부탄산, 이소펜탄산, 2-에틸펜탄산, 2-에틸헥산산, 이소노난산, 3,5,5-트리메틸헥산산, 트리데칸산, 테트라메틸노난산, 미리스트산, 펜타데칸산, 팔미트산, 스테아르산, 아라크산, 베헨산, 리그노세르산, 세로트산, 미리스트올레산, 팔미톨레산, 올레산, 엘라이드산, 곤도인산, 에루크산, 셀라콜레산, 리놀산, 리노엘라이드산, 리놀레산, 아라키돈산, 2-헥실데칸산, 이소스테아르산, 12-히드록시스테아르산, 야자유 지방산, 경화 야자유 지방산, 팜유 지방산, 경화 팜유 지방산, 팜 핵유 지방산, 경화 팜 핵유 지방산, 우지 지방산, 경화 우지 지방산 등을 들 수 있다.Examples of the fatty acid having 5 to 25 carbon atoms include caproic acid, heptanoic acid, caprylic acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, caproic acid, undecylenic acid, laurolactic acid, , Isopentanoic acid, 2-ethylpentanoic acid, 2-ethylhexanoic acid, isononanoic acid, 3,5,5-trimethylhexanoic acid, tridecanoic acid, tetramethylnonanoic acid, myristic acid, pentadecanoic acid, There may be mentioned acid addition salts such as acetic acid, acetic acid, stearic acid, arachic acid, behenic acid, lignoceric acid, cetric acid, misteroolic acid, palmitoleic acid, oleic acid, elaidic acid, gondophosphoric acid, erucic acid, , Palm oil fatty acid, hard palm oil fatty acid, palm kernel oil fatty acid, hard palm kernel oil fatty acid, hard palm oil fatty acid, hardened palm oil fatty acid, hard palm oil fatty acid, hard palm oil fatty acid, Tallow fatty acid, and the like.
본 발명에서는 탄소수 5~25개의 지방산 중에서도 탄소수 8~20개, 또는 탄소수 12~18개의 직쇄상 포화 지방산으로부터 형성되는 고급 지방산을 사용하는 것이 바람직하다. 즉, 본 발명에서 사용되는 지방산 비누는 분기쇄상 지방산 또는 불포화 지방산으로부터 형성되는 지방산 비누를 포함하지 않는 실시형태를 포함한다.Among the fatty acids having 5 to 25 carbon atoms, it is preferable to use higher fatty acids formed from straight chain saturated fatty acids having 8 to 20 carbon atoms or 12 to 18 carbon atoms. That is, the fatty acid soap used in the present invention includes an embodiment that does not contain a fatty acid soap formed from a branched chain fatty acid or an unsaturated fatty acid.
본 발명의 세정제 조성물은 (b-1) 라우르산 및 (b-2) 미리스트산 및 (b-3) 팔미트산 및 스테아르산으로부터 선택되는 적어도 1종을 포함하는 직쇄상 포화 지방산으로부터 형성되는 고급 지방산 비누를 함유한다.The detergent composition of the present invention is formed from a linear saturated fatty acid containing at least one selected from (l-1) lauric acid and (b-2) myristic acid and (b-3) palmitic acid and stearic acid Of high fatty acid soap.
(b-1) 라우르산(b-1) Lauric acid
본 발명에 있어서의 고급 지방산 비누는 라우르산으로부터 형성되는 지방산비누를 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 30~80질량% 함유한다.The higher fatty acid soap in the present invention contains 30 to 80 mass% of the fatty acid soap formed from lauric acid based on the total weight of the fatty acid forming the higher fatty acid soap.
(b-2) 미리스트산(b-2) Myristic acid
본 발명에 있어서의 고급 지방산 비누는 라우르산으로부터 형성되는 지방산비누를 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 5~30질량% 함유한다.The higher fatty acid soap in the present invention contains 5 to 30 mass% of fatty acid soap formed from lauric acid based on the total weight of the fatty acid forming the higher fatty acid soap.
(b-3) 팔미트산 및 스테아르산(b-3) palmitic acid and stearic acid
본 발명에 있어서의 고급 지방산 비누는 팔미트산 및 스테아르산으로부터 선택되는 적어도 1종으로부터 형성되는 지방산 비누를 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 5~35질량% 함유한다. 팔미트산 및 스테아르산의 합계 배합량이 35질량%를 초과하면 충분한 저온 안정성이 얻어지지 않는 경우가 있다. 동계의 한랭지 등의 저온 안정성이 특히 요구되는 환경에서 사용하는 경우에는 팔미트산 및/또는 스테아르산의 배합량을 5~30질량%로 하는 것이 바람직하고, 보다 바람직하게는 5~25질량%, 또한 바람직하게는 5~20질량%이다.The higher fatty acid soap in the present invention contains 5 to 35 mass% of fatty acid soap formed from at least one selected from palmitic acid and stearic acid based on the total weight of the fatty acids forming the higher fatty acid soap. When the total amount of palmitic acid and stearic acid is more than 35% by mass, sufficient low-temperature stability may not be obtained. In the case of using in an environment where low temperature stability such as winter cold paper is particularly required, the blending amount of palmitic acid and / or stearic acid is preferably 5 to 30 mass%, more preferably 5 to 25 mass% And preferably 5 to 20% by mass.
팔미트산 및 스테아르산으로부터 선택되는 적어도 1종이란 팔미트산 또는 스테아르산의 한쪽만을 포함하는 실시형태와, 팔미트산과 스테아르산의 양쪽을 포함하는 실시형태를 포함한다. 팔미트산과 스테아르산의 양쪽을 포함하는 실시형태에서는 팔미트산과 스테아르산의 배합량 비율[팔미트산/스테아르산]을 0.4~2.5의 범위로 하는 것이 바람직하다. 이 수치 범위는, 0.4~2.5에 포함되는 임의의 범위(예를 들면, 0.4~2.0 또는 1.0~2.0 등) 및 상기 범위에 포함되는 모든 수치를 포함한다.At least one species selected from palmitic acid and stearic acid includes an embodiment including only one of palmitic acid and stearic acid and an embodiment including both palmitic acid and stearic acid. In the embodiment including both palmitic acid and stearic acid, it is preferable that the blending amount ratio of palmitic acid and stearic acid [palmitic acid / stearic acid] is in the range of 0.4 to 2.5. This numerical value range includes an arbitrary range included in 0.4 to 2.5 (for example, 0.4 to 2.0 or 1.0 to 2.0, etc.) and all numerical values included in the above range.
본 발명의 세정제 조성물은 라우르산(탄소수 12개) 및 미리스트산(탄소수 14개)에 추가하여 팔미트산(탄소수 16개) 및/또는 스테아르산(탄소수 18개)을 배합함으로써 지속성이 양호한 거품질이 얻어짐과 아울러 저온 안정성도 우수하다.The detergent composition of the present invention can be obtained by blending palmitic acid (16 carbon atoms) and / or stearic acid (18 carbon atoms) in addition to lauric acid (12 carbon atoms) and myristic acid (14 carbon atoms) And the low temperature stability is excellent.
일반적으로 고급 지방산의 쇄장(탄소수)가 증가하면 결정 석출이 일어나기 쉽다고 여겨지고 있는 것을 감안하면 종래부터 범용되고 있었던 라우르산 및 미리스트산에 추가하여 탄소수가 많은 팔미트산 및/또는 스테아르산을 배합함으로써 저온안정성이 향상된 것은 당업자가 예측할 수 없는 효과이다.In view of the fact that crystallization is likely to occur when the chain length (carbon number) of the higher fatty acid is increased, in general, palmitic acid and / or stearic acid having a large number of carbon atoms are added in addition to lauric acid and myristic acid, It is an unpredictable effect to those skilled in the art that the low temperature stability is improved.
고급 지방산 음이온을 중화하는 카운터 양이온으로서는 알칼리 금속 양이온, 특히 칼륨 양이온으로 하는 것이 바람직하다. 본 발명에 있어서의 (a) 고급 지방산 비누에는 지방산의 아르기닌염 및 메틸타우린염은 포함되지 않는다.The counter cation for neutralizing the higher fatty acid anion is preferably an alkali metal cation, particularly a potassium cation. The (a) high fatty acid soap in the present invention does not include the arginine salt of the fatty acid and the methyltaurine salt.
본 발명의 세정제 조성물에 있어서의 (b) 고급 지방산 비누의 배합량은 4~15질량%이며, 바람직하게는 5~12질량%, 보다 바람직하게는 5~10질량%, 더욱 바람직하게는 6~8질량%이다. 여기서, 고급 지방산 비누의 배합량이란 고급 지방산과 중화제(예를 들면, 수산화칼륨)의 합계 배합량을 의미한다.The blending amount of the higher fatty acid soap (b) in the detergent composition of the present invention is 4 to 15 mass%, preferably 5 to 12 mass%, more preferably 5 to 10 mass%, and still more preferably 6 to 8 mass% Mass%. Here, the blending amount of the higher fatty acid soap means the total amount of the higher fatty acid and the neutralizing agent (for example, potassium hydroxide).
본 발명의 세정제 조성물에 있어서는 (a) 라우릴디메틸아미노아세트산 베타인의 배합량과 (b) 고급 지방산 비누의 배합량의 비율[(a)/(b)]은 0.4~1.5이며, 이 배합량 비율은 0.5~1.2의 범위 내로 하는 것이 더욱 바람직하다. 이 배합량 비율이 0.4 미만이면 충분한 저온 안정성이 얻어지지 않는다. In the detergent composition of the present invention, the ratio [(a) / (b)] of (a) the amount of lauryldimethylaminoacetic acid betaine to (b) the amount of the higher fatty acid soap is 0.4 to 1.5, And more preferably within the range of 1.2. If the blending amount ratio is less than 0.4, sufficient low temperature stability can not be obtained.
(c) 다가 알코올(c) a polyhydric alcohol
본 발명의 세정제 조성물은 (a) 라우릴디메틸아미노아세트산 베타인, 및 (b) 고급 지방산 비누라는 필수 성분에 추가하여 다가 알코올을 배합하는 것이 바람직하다. The detergent composition of the present invention is preferably blended with a polyhydric alcohol in addition to the essential components of (a) lauryldimethylaminoacetic acid betaine and (b) higher fatty acid soap.
배합될 수 있는 다가 알코올은 화장료 등에 통상 배합되는 것으로부터 선택할 수 있고, 예를 들면 글리세린, 프로필렌글리콜, 디프로필렌글리콜, 1, 3-부틸렌글리콜, 에틸렌글리콜, 폴리에틸렌글리콜, 소르비톨 등을 들 수 있다.Polyhydric alcohols that can be formulated can be selected from those ordinarily compounded in cosmetics and the like, and examples thereof include glycerin, propylene glycol, dipropylene glycol, 1, 3-butylene glycol, ethylene glycol, polyethylene glycol and sorbitol .
다가 알코올의 배합량은 특별히 한정되지 않지만 통상은 10~50질량%, 바람직하게는 20~50질량%, 보다 바람직하게는 25~40질량%이다.The blending amount of the polyhydric alcohol is not particularly limited, but is usually 10 to 50 mass%, preferably 20 to 50 mass%, and more preferably 25 to 40 mass%.
다가 알코올 중에서도 IOB=3~4의 다가 알코올을 배합함으로써 포머로부터 토출되는 거품의 탄력성을 향상시킬 수 있으므로 바람직하다. IOB=3~4의 다가 알코올로서는 디글리세린, 프로필렌글리콜 등을 예시할 수 있다.Among the polyhydric alcohols, it is preferable to add a polyhydric alcohol having IOB = 3 to 4 so that the elasticity of the foam discharged from the foamer can be improved. Examples of polyhydric alcohols having IOB = 3 to 4 include diglycerin, propylene glycol and the like.
IOB=3~4의 다가 알코올의 배합량은 조성물 전체 중량에 대하여 통상은 0.1~10질량%, 바람직하게는 0.5~8질량%, 보다 바람직하게는 1~5질량%이다.The blending amount of polyhydric alcohol having IOB = 3 to 4 is usually 0.1 to 10 mass%, preferably 0.5 to 8 mass%, more preferably 1 to 5 mass%, based on the total weight of the composition.
본 발명의 세정제 조성물은 액체 세정제 조성물에 통상 사용되는 다른 임의 성분을 본 발명의 효과를 저해하지 않는 범위에서 함유해도 좋고, 다른 임의 성분의 구체예를 들면 유분, 실리콘류, 저급 또는 고급 알코올류, 라놀린 유도체, 단백 유도체, 각종 약제, 살균제, 방부제, pH 조정제, 산화 방지제, 금속 이온 봉쇄제, 킬레이트제, 동식물 추출물 또는 그 유도체, 색소, 향료, 안료, 유기 또는 무기 분체, 점토 광물 등을 들 수 있다. 이들의 1종 또는 2종 이상을 임의로 선택해서 배합할 수 있다.The detergent composition of the present invention may contain other optional components generally used in the liquid detergent composition within a range that does not impair the effect of the present invention. Specific examples of other optional components include oil, silicones, lower or higher alcohols, An antioxidant, a chelating agent, an animal or plant extract or a derivative thereof, a coloring matter, a flavoring agent, a pigment, an organic or inorganic powder, a clay mineral, etc. have. One or more of these may be arbitrarily selected and mixed.
본 발명의 세정제 조성물은 한정되지 않지만 예를 들면, B형 회전 점도계를 사용해서 30℃의 온도에서 측정한 점도가 40mPa·s 이하, 바람직하게는 30mPa·s 이하, 보다 바람직하게는 20mPa·s 정도의 저점도 액체로서 제공된다.The detergent composition of the present invention is not limited. For example, the detergent composition of the present invention has a viscosity of 40 mPa · s or less, preferably 30 mPa · s or less, more preferably 20 mPa · s or less As a low viscosity liquid.
본 발명의 세정제 조성물은 상술한 필수 성분 및 임의 성분을 사용하여 상법에 준하여 제조할 수 있다.The detergent composition of the present invention can be produced in accordance with the conventional method using the above-described essential components and optional components.
조제된 본 발명의 세정제 조성물은 다공질막을 갖는 논가스 타입의 거품 토출 용기에 수용된다. 본 발명에서 사용되는 논가스 타입의 거품 토출 용기는 일정량의 액체 세정제 조성물을 일정량의 공기와 혼합하여 거품 상태로 해서 사용 시에 용기로부터 토출시키는 것이면 공지의 어느 타입의 것이어도 좋다. 구체적으로는 예를 들면, 연질 용기의 몸통부를 손가락으로 압박함으로써 사용하는 스퀴즈 포머, 펌프 기구를 구비한 캡의 머리를 손가락으로 압박함으로써 사용되는 펌프 포머 등을 들 수 있다. 그리고 사용 시, 용기 내의 액체 세정제 조성물을 공기와 혼합한 혼합물을 다공질막(1매로부터 복수매)에 통과시킴으로써 상기 액체 세정제 조성물을 용기 토출구로부터 거품 형상으로 해서 토출시키도록 되어 있다. The detergent composition of the present invention thus prepared is accommodated in a non-gas type foam discharge container having a porous membrane. The non-gas type foam discharge container used in the present invention may be any known type as long as a certain amount of the liquid detergent composition is mixed with a certain amount of air to be foamed and discharged from the container in use. Specifically, for example, there can be mentioned a squeeze former used by pressing the trunk portion of the soft container with a finger, and a pump former used by pressing the head of the cap with a finger with a finger. When the liquid detergent composition is used, the liquid detergent composition is ejected in a foam form from the container discharge opening by passing a mixture obtained by mixing the liquid detergent composition in the container with air through a porous film (one to plural sheets).
펌프 포머 용기의 다공질막으로서는 예를 들면 스펀지, 소결체, 네트 등을 들 수 있지만 사용성 등의 점으로부터 박육인 네트가 바람직하다. 눈의 거칠기로서 는 30~400메시 정도의 것이 바람직하게 사용된다. 본 발명의 세정제 조성물에는 2매의 다공질막을 구비하는 용기를 사용하는 것이 바람직하고, 한쪽의 다공질막을 200메시, 다른 쪽의 다공질막을 305메시라는 미세한 망눈으로서도 눈 막힘을 발생시키기 않고 양호한 거품질을 얻을 수 있다.As the porous film of the pump former container, for example, a sponge, a sintered body, a net and the like can be mentioned, but a thin net is preferable from the viewpoint of usability and the like. The roughness of the eye is preferably about 30 to 400 mesh. It is preferable to use a container having two porous films in the detergent composition of the present invention. Even if fine mesh of one mesh of the porous membrane and mesh of the other porous membrane of 305 mesh is used, .
본 발명의 세정제 조성물은 펌프 포머 용기에 수용된 모발이나 피부의 세정제로서 세안료, 보디 소프, 핸드 소프, 샴푸 등의 형태로 바람직하게 제공된다.The detergent composition of the present invention is preferably provided as a detergent for hair or skin contained in a pump former container in the form of a detergent, a body soap, a hand soap, a shampoo and the like.
실시예Example
이하, 구체예를 들어서 본 발명을 더욱 상세히 설명하지만 이들은 본 발명의 기술적 범위를 하등 한정하는 것은 아니다. Hereinafter, the present invention will be described in more detail by way of specific examples, but they should not be construed as limiting the technical scope of the present invention.
또한, 이하의 실시예 등에 있어서의 배합량은 특기하지 않는 한 질량%이다.In the following examples and the like, the blending amount is, unless otherwise specified, in mass%.
하기 표의 각 예에 기재한 조성으로 세정제를 상법에 따라서 조제했다.A cleaning agent was prepared according to the conventional method in the composition described in each example of the following table.
각 예에서 얻어진 세정제에 대하여 이하의 항목에 대해 하기의 기준에 따라 평가했다.With respect to the cleaning agent obtained in each example, the following items were evaluated according to the following criteria.
(1) 저온 안정성(1) Low temperature stability
조제한 세정제 조성물을 경질 유리의 바이알 병에 충전하고, 각 온도(-10~5℃)로 유지된 평가실에 있어서 24시간 및 1주간 보존시킨 후, 세정제 조성물의 저온 안정성을 육안으로 관찰하고 하기 평가 기준으로 평가했다.The prepared detergent composition was filled in a vial bottle made of hard glass and stored in an evaluation room maintained at each temperature (-10 to 5 ° C) for 24 hours and 1 week. Then, the low temperature stability of the detergent composition was visually observed, Respectively.
A: 양호(석출물·침전물이 없어 외관의 변화가 없다. 눈 막힘을 일으킬 가능성이 없다)A: Good (there is no change in appearance because there is no precipitate or sediment, there is no possibility of clogging)
B: 불량(석출물·침전물이 있어 품질상 문제가 있다. 눈 막힘을 일으킬 가능성이 있다)B: Bad (there is a quality problem due to precipitates and sediments, which may cause clogging)
통상의 사용 환경이면 적어도 -5℃~+5℃에서 24시간 및 +5℃에서 1주간의 보존을 종료한 시점에서의 평가가 「A」이면 상품으로서 제공할 수 있는 충분한 특성을 구비하고 있다.If the evaluation is "A" for at least 24 hours at -5 ° C to + 5 ° C and at the end of one week's storage at + 5 ° C, it has sufficient characteristics that can be provided as a product.
(2) 사용성 시험(2) Usability test
펌프 포머 용기(메시 200×305)에 수용된 각 예의 세정제 조성물을 거품 형상으로 토출시켜서 실사용했을 때의 거품질(거품의 지속성, 거품의 탄력성)에 대하여 전문 패널이 평가했다. 평가는 이하의 기준에 따라 실시했다.Expert panels evaluated the quality (bubble durability, bubble resilience) of the detergent compositions contained in the pump former container (mesh 200 × 305) discharged in the form of foam in the form of foam. Evaluation was conducted according to the following criteria.
[평가 기준][Evaluation standard]
A: 매우 우수하다 A: Very good.
B: 우수하다B: Excellent
C: 열화되어 있다C: It is deteriorating.
또한, 평가 결과가 A 또는 B인 것은 상품으로서 제공하는데에 충분한 특성을 구비하고 있다. In addition, when the evaluation result is A or B, it has sufficient characteristics to provide it as a commodity.
(3) 점도 측정(3) Viscosity measurement
각 예에서 조제한 세정제 조성물에 대하여 B형 점도계(로터 No. 1, 60rpm)을 사용하여 30℃의 점도를 측정했다. 측정 결과를 각 표에 나타낸다.The viscosity of the detergent composition prepared in each Example was measured at 30 캜 using a B-type viscometer (rotor No. 1, 60 rpm). The measurement results are shown in the respective tables.
상기 표 1~4에 나타낸 결과로부터 라우르산 및 미리스트산, 및 팔미트산 및/또는 스테아르산을 본 발명 소정의 비율로 포함하는 고급 지방산을 함유하고, 또한 N-라우릴디메틸아미노아세트산 베타인을 소정 비율로 함유하는 실시예의 세정제 조성물은 저온 안정성이 우수하여 포머 용기의 눈 막힘을 일으킬 일이 없을 뿐만 아니라 생성되는 거품의 지속성도 우수하다. 한편, 팔미트산도 스테아르산도 포함하지 않는 비교예 1은 거품의 지속성이 열화된다. 지방산의 배합 비율이 본 발명의 요건을 만족하지 않는(팔미트산 및 스테아르산의 합계 배합량이 35질량%를 초과한다) 비교예 2~4, 및 N-라우릴디메틸아미노아세트산 베타인과 고급 지방산 비누의 배합량 비율이 본 발명의 범위(0.4~1.5)로부터 벗어하는 비교예 5에서는 충분한 저온 안정성이 얻어지지 않았다. From the results shown in Tables 1 to 4, it was confirmed that the compositions containing higher fatty acids containing lauric acid and myristic acid and palmitic acid and / or stearic acid in a predetermined ratio of the present invention, and also containing N-lauryldimethylaminoacetic acid betaine In a predetermined ratio is excellent in low-temperature stability, so that it does not cause clogging of the formatter container, and also the persistence of foam produced is excellent. On the other hand, in Comparative Example 1, which does not include palmitoyl stearate, the persistence of foam is deteriorated. Comparative Examples 2 to 4 in which the blending ratios of fatty acids do not satisfy the requirements of the present invention (the total blending amount of palmitic acid and stearic acid exceeds 35 mass%), and N-lauryldimethylaminoacetic acid betaine and higher fatty acid soap Of the present invention deviates from the range of the present invention (0.4 to 1.5), sufficient low temperature stability was not obtained.
(b) 고급 지방산 비누의 배합량이 4질량%에 만족하지 않는 비교예 6도 비교예 1과 마찬가지로 거품의 지속성이 열화되고, 조성물의 점도가 30mPa·s를 초과하는 비교예 7은 펌프 포머에서 토출되는 것이 곤란했다. 또한, N-라우릴디메틸아미노아세트산 베타인을 코카미도프로필베타인(야자유 지방산 아미도프로필베타인)으로 치환한 비교예 8은 저온 안정성이 열화되는 것이 되었다. 또한, 고급 지방산 비누를 형성하는 지방산으로서 팔미트산 및 스테아르산을 합계로 30질량% 이상 포함하는 실시예 9에 비교하면 그 배합량이 20~30질량%인 실시예 4 및 6~8, 또한 20질량% 이하인 실시예 2, 3 및 5에서는 보다 과혹한 저온 조건이어도 석출 등이 생기지 않게 되어 동계의 한랭지 등에서의 사용에 특히 적합한 것으로 되는 것이 확인되었다.(b) Comparative Example 6 in which the amount of the higher fatty acid soap was not satisfied by 4 mass% also deteriorated the persistence of the foam in the same manner as in Comparative Example 1, and in Comparative Example 7 in which the viscosity of the composition exceeded 30 mPa · s, . Also, in Comparative Example 8 in which N-lauryldimethylaminoacetic acid betaine was replaced with cocamidopropyl betaine (palm oil fatty acid amidopropyl betaine), the low temperature stability was deteriorated. Further, as compared with Example 9 containing 30% by mass or more of palmitic acid and stearic acid in total as a fatty acid for forming a higher fatty acid soap, Examples 4 and 6 to 8 in which the blending amount is 20 to 30% by mass, and 20 In Examples 2, 3 and 5, in which the content is not more than 1 mass%, precipitation or the like does not occur even at a very severe low temperature condition, and it is confirmed to be particularly suitable for use in cold winter or the like.
표 5에 나타낸 결과에 의하면 IOB=3~4의 다가 알코올인 디글리세린(IOB=3.50)은 본 발명의 효과를 얻기 위해 필수는 아니지만(실시예 12), IOB=3~4의 다가 알코올의 배합이 포머로부터 토출되는 거품의 탄력성을 향상시키는 것이 확인되었다(실시예 13 및 14).According to the results shown in Table 5, diglycerol (IOB = 3.50), which is a polyhydric alcohol having IOB = 3 to 4, is not essential for obtaining the effect of the present invention (Example 12) It was confirmed that the elasticity of the foam discharged from the former was improved (Examples 13 and 14).
Claims (6)
(b) 탄소수 5~25개의 지방산으로부터 형성되는 고급 지방산 비누 4~15질량%를 함유하는 포머 용기에서 토출되는 세정료 조성물이며,
상기 탄소수 5~25개의 지방산이,
(b-1) 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 30~80질량%의 라우르산,
(b-2) 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 5~30질량%의 미리스트산, 및
(b-3) 고급 지방산 비누를 형성하는 지방산 전체 중량에 대하여 5~35질량%의 팔미트산 및 스테아르산으로부터 선택되는 적어도 1종을 포함하고,
상기 (a) 라우릴디메틸아미노아세트산 베타인의 배합량과 (b) 고급 지방산 비누의 배합량의 비율[(a)/(b)]이 0.4~1.5의 범위 내인 것을 특징으로 하는 세정제 조성물.(a) lauryldimethylaminoacetic acid betaine,
(b) 4 to 15% by mass of a higher fatty acid soap formed from a fatty acid having 5 to 25 carbon atoms,
The fatty acid having 5 to 25 carbon atoms,
(b-1) 30 to 80 mass% of lauric acid based on the total weight of the fatty acids forming the higher fatty acid soap,
(b-2) 5 to 30 mass% of myristic acid with respect to the total fatty acid forming the higher fatty acid soap, and
(b-3) at least one selected from palmitic acid and stearic acid in an amount of 5 to 35 mass%, based on the total weight of the fatty acid forming the higher fatty acid soap,
Wherein the ratio [(a) / (b)] of the amount of (a) the amount of lauryldimethylaminoacetic acid betaine to the amount of (b) the amount of the higher fatty acid soap is within a range of 0.4 to 1.5.
상기 (b-3)이 팔미트산 및 스테아르산의 양쪽을 포함하는 세정제 조성물.The method according to claim 1,
(B-3) comprises both palmitic acid and stearic acid.
팔미트산과 스테아르산의 배합량 비율[팔미트산/스테아르산]이 0.4~2.5의 범위 내인 세정제 조성물.3. The method of claim 2,
Wherein the blending amount ratio of palmitic acid and stearic acid [palmitic acid / stearic acid] is in the range of 0.4 to 2.5.
(c) 다가 알코올을 더 포함하는 세정제 조성물.4. The method according to any one of claims 1 to 3,
(c) a polyhydric alcohol.
상기 (c) 다가 알코올이 IOB=3~4의 다가 알코올을 포함하는 세정제 조성물.5. The method of claim 4,
Wherein the polyhydric alcohol (c) comprises a polyhydric alcohol having IOB = 3 to 4.
상기 IOB=3~4의 다가 알코올이 디글리세린인 세정제 조성물.6. The method of claim 5,
Wherein the polyol having IOB = 3 to 4 is diglycerin.
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| JP4964620B2 (en) * | 2006-03-03 | 2012-07-04 | ライオン株式会社 | Foam discharge container with liquid detergent composition |
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