TW201039361A - Polyurethane materials comprising carbon nanotubes - Google Patents
Polyurethane materials comprising carbon nanotubes Download PDFInfo
- Publication number
- TW201039361A TW201039361A TW099107182A TW99107182A TW201039361A TW 201039361 A TW201039361 A TW 201039361A TW 099107182 A TW099107182 A TW 099107182A TW 99107182 A TW99107182 A TW 99107182A TW 201039361 A TW201039361 A TW 201039361A
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- Taiwan
- Prior art keywords
- acid
- carbon
- polyurethane
- weight
- crystalline
- Prior art date
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 104
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 83
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 81
- 239000004814 polyurethane Substances 0.000 title claims abstract description 29
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 27
- 239000000463 material Substances 0.000 title description 10
- 239000000203 mixture Substances 0.000 claims abstract description 65
- 238000000034 method Methods 0.000 claims abstract description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000006185 dispersion Substances 0.000 claims description 28
- 229920000642 polymer Polymers 0.000 claims description 24
- 239000002253 acid Substances 0.000 claims description 21
- 229920000768 polyamine Polymers 0.000 claims description 21
- 229920005862 polyol Polymers 0.000 claims description 21
- 150000003077 polyols Chemical class 0.000 claims description 21
- 238000004519 manufacturing process Methods 0.000 claims description 20
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 18
- -1 phthalic acid yttrium Chemical compound 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 125000001931 aliphatic group Chemical group 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 11
- 230000008018 melting Effects 0.000 claims description 11
- 229920005906 polyester polyol Polymers 0.000 claims description 11
- 238000002425 crystallisation Methods 0.000 claims description 9
- 230000008025 crystallization Effects 0.000 claims description 9
- 150000001412 amines Chemical group 0.000 claims description 8
- 239000011852 carbon nanoparticle Substances 0.000 claims description 8
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 7
- 239000004970 Chain extender Substances 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 239000002105 nanoparticle Substances 0.000 claims description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 239000000052 vinegar Substances 0.000 claims description 5
- 235000021419 vinegar Nutrition 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000011149 active material Substances 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 239000005056 polyisocyanate Substances 0.000 claims description 3
- 229920001228 polyisocyanate Polymers 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000012360 testing method Methods 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000010276 construction Methods 0.000 claims description 2
- 229920003009 polyurethane dispersion Polymers 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- 229920001400 block copolymer Polymers 0.000 claims 1
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- 239000008187 granular material Substances 0.000 claims 1
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- 239000012744 reinforcing agent Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 claims 1
- 229920000126 latex Polymers 0.000 abstract description 12
- 238000012545 processing Methods 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 6
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- 238000005266 casting Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 description 18
- 239000002131 composite material Substances 0.000 description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 14
- 239000002048 multi walled nanotube Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 12
- 239000004816 latex Substances 0.000 description 11
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 10
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 229920000728 polyester Polymers 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 7
- 239000001361 adipic acid Substances 0.000 description 7
- 235000011037 adipic acid Nutrition 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 6
- 125000005442 diisocyanate group Chemical group 0.000 description 6
- 229910021389 graphene Inorganic materials 0.000 description 6
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229920000515 polycarbonate Polymers 0.000 description 6
- 239000004417 polycarbonate Substances 0.000 description 6
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 5
- 229920003232 aliphatic polyester Polymers 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 239000002109 single walled nanotube Substances 0.000 description 5
- WXUAQHNMJWJLTG-UHFFFAOYSA-N 2-methylbutanedioic acid Chemical compound OC(=O)C(C)CC(O)=O WXUAQHNMJWJLTG-UHFFFAOYSA-N 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000010891 electric arc Methods 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 3
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 3
- 241000234282 Allium Species 0.000 description 3
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 3
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 3
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 3
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
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- 238000007306 functionalization reaction Methods 0.000 description 3
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- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 3
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- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
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- 150000005846 sugar alcohols Polymers 0.000 description 3
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 3
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- IVGRSQBDVIJNDA-UHFFFAOYSA-N 2-(2-aminoethylamino)ethanesulfonic acid Chemical compound NCCNCCS(O)(=O)=O IVGRSQBDVIJNDA-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
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- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 2
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- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- OGZLYMDUHZLBOY-UHFFFAOYSA-N 2,2-bis(sulfanyl)propane-1,3-diol Chemical compound OCC(S)(S)CO OGZLYMDUHZLBOY-UHFFFAOYSA-N 0.000 description 1
- JOTMFOWEVMXFHO-UHFFFAOYSA-N 2-aminoethyl benzoate Chemical compound NCCOC(=O)C1=CC=CC=C1 JOTMFOWEVMXFHO-UHFFFAOYSA-N 0.000 description 1
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
- C08J3/21—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
- C08J3/215—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase at least one additive being also premixed with a liquid phase
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/041—Carbon nanotubes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Carbon And Carbon Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009012674A DE102009012674A1 (de) | 2009-03-13 | 2009-03-13 | Polyurethanmassen mit Kohlenstoffnanoröhrchen |
Publications (1)
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| TW201039361A true TW201039361A (en) | 2010-11-01 |
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| TW099107182A TW201039361A (en) | 2009-03-13 | 2010-03-12 | Polyurethane materials comprising carbon nanotubes |
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| Country | Link |
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| EP (1) | EP2406311A1 (enExample) |
| JP (1) | JP2012520356A (enExample) |
| KR (1) | KR20110134910A (enExample) |
| CN (1) | CN102421838A (enExample) |
| DE (1) | DE102009012674A1 (enExample) |
| TW (1) | TW201039361A (enExample) |
| WO (1) | WO2010102763A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103383868A (zh) * | 2012-05-04 | 2013-11-06 | 远东新世纪股份有限公司 | 透明导电积层体 |
| CN103842290A (zh) * | 2011-09-29 | 2014-06-04 | 独立行政法人产业技术综合研究所 | 碳纳米管复合材料 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2010135335A1 (en) * | 2009-05-18 | 2010-11-25 | Ppg Industries Ohio, Inc. | Aqueous dispersions, conductive fiber glass strands, and composites comprising the same |
| GB201015027D0 (en) | 2010-09-10 | 2010-10-20 | Ineos Norge Holdings As | Polymer composition and method of making the same |
| DE102011009469B4 (de) | 2011-01-21 | 2013-04-18 | Innovent E.V. | Verfahren zur Herstellung von polymerfunktionalisierten Kohlenstoffnanoröhren |
| JP5859277B2 (ja) * | 2011-11-02 | 2016-02-10 | ニッタ株式会社 | カーボンナノチューブ複合材およびカーボンナノチューブ複合材の製造方法 |
| US9879131B2 (en) | 2012-08-31 | 2018-01-30 | Soucy Techno Inc. | Rubber compositions and uses thereof |
| CN104718170A (zh) | 2012-09-04 | 2015-06-17 | Ocv智识资本有限责任公司 | 碳强化的增强纤维在含水或非水介质内的分散 |
| JP6120134B2 (ja) * | 2012-12-26 | 2017-04-26 | 伊藤 彰彦 | 導電性フィルム |
| CN103173003B (zh) * | 2013-02-27 | 2015-05-20 | 国家纳米科学中心 | 一种碳纳米管-水溶性聚合物复合柔性电热薄膜、制备方法及其用途 |
| JP6426738B2 (ja) | 2013-07-30 | 2018-11-21 | エイチ．ビー．フラー カンパニー | ポリウレタン接着フィルム |
| US10640702B2 (en) | 2013-08-01 | 2020-05-05 | Covestro Llc | Coated particles and methods for their manufacture and use |
| CA2925928C (en) | 2013-10-18 | 2018-06-19 | Soucy Techno Inc. | Rubber compositions and uses thereof |
| CA2925929C (en) | 2013-12-19 | 2018-12-04 | Soucy Techno Inc. | Rubber compositions and uses thereof |
| US9545042B2 (en) * | 2014-03-14 | 2017-01-10 | Ppg Industries Ohio, Inc. | P-static charge drain layer including carbon nanotubes |
| CN107075096B (zh) * | 2014-08-14 | 2019-08-20 | 米兰理工大学 | 包含由取代的吡咯环组成的重复单元的聚合物及将该聚合物与碳同素异形体结合获得的产物 |
| WO2016050887A1 (en) | 2014-10-01 | 2016-04-07 | Politecnico Di Milano | Adducts between carbon allotropes and serinol derivatives |
| TWI696677B (zh) | 2014-12-15 | 2020-06-21 | 美商Ｈ Ｂ 富勒公司 | 具有強化對金屬表面之黏著性的反應性膜黏著劑 |
| DE102015102553A1 (de) | 2015-02-23 | 2016-08-25 | Technische Hochschule Nürnberg Georg Simon Ohm | Dispergier-Additiv |
| US10442549B2 (en) | 2015-04-02 | 2019-10-15 | Ppg Industries Ohio, Inc. | Liner-type, antistatic topcoat system for aircraft canopies and windshields |
| US11414383B2 (en) | 2016-11-09 | 2022-08-16 | Pirelli Tyre S.P.A. | Adducts formed from primary amines, dicarbonyl derivatives, inorganic oxide hydroxydes and sp2-hybridized carbon allotropes |
| KR20210106184A (ko) | 2020-02-20 | 2021-08-30 | 한국전기연구원 | 탄소나노튜브가 고분산된 폴리우레탄 폼 복합체의 제조방법 및 이로부터 제조되는 탄소나노튜브가 고분산된 폴리우레탄 폼 복합체 |
| CN115551925A (zh) * | 2020-05-19 | 2022-12-30 | 科思创德国股份有限公司 | 制备含填料的聚氨酯粒子的方法 |
| JP6856812B1 (ja) * | 2020-10-21 | 2021-04-14 | 第一工業製薬株式会社 | 電極用結着剤組成物、電極用塗工液組成物、蓄電デバイス用電極及び蓄電デバイス |
| CN113527869B (zh) * | 2021-07-05 | 2022-07-01 | 青岛科技大学 | 一种碳纳米管改性聚氨酯热塑性硫化胶及其制备方法 |
| KR102697984B1 (ko) * | 2021-11-22 | 2024-08-26 | 주식회사 디에이치오토리드 | 차량 스티어링 휠용 면상발열 조성물 및 이를 이용한 차량 스티어링 휠용 면상발열패드 제조방법 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1469930A (en) | 1974-10-11 | 1977-04-06 | Atomic Energy Authority Uk | Carbon filaments |
| CA1175616A (en) | 1981-01-05 | 1984-10-09 | Exxon Research And Engineering Company | Production of iron monoxide and carbon filaments therefrom |
| US4663230A (en) | 1984-12-06 | 1987-05-05 | Hyperion Catalysis International, Inc. | Carbon fibrils, method for producing same and compositions containing same |
| EP1592732A1 (en) | 2003-02-13 | 2005-11-09 | Stichting Dutch Polymer Institute | Reinforced polymer |
| DE102004010455A1 (de) | 2004-03-01 | 2005-09-22 | Basf Ag | Thermoplastische Polyurethane enthaltend Kohlenstoffnanoröhren |
| DE102004054959A1 (de) | 2004-11-13 | 2006-05-18 | Bayer Technology Services Gmbh | Katalysator zur Herstellung von Kohlenstoffnanoröhrchen durch Zersetzung von gas-förmigen Kohlenverbindungen an einem heterogenen Katalysator |
| KR100642427B1 (ko) * | 2004-12-28 | 2006-11-08 | 제일모직주식회사 | 탄소 나노튜브를 이용한 전자파차폐용 조성물 |
| FR2883879B1 (fr) * | 2005-04-04 | 2007-05-25 | Arkema Sa | Materiaux polymeres contenant des nanotubes de carbone a dispersion amelioree leur procede de preparation |
| DE102006007147A1 (de) | 2006-02-16 | 2007-08-23 | Bayer Technology Services Gmbh | Verfahren zur kontinuierlichen Herstellung von Katalysatoren |
| WO2007121780A1 (en) | 2006-04-21 | 2007-11-01 | Stichting Dutch Polymer Institute | Carbon nanotube reinforced polymer |
| KR100793259B1 (ko) * | 2006-12-29 | 2008-01-10 | (주)디피아이 홀딩스 | 수분산 폴리우레탄 수지, 수분산 폴리우레탄 수지의 제조방법 및 이를 이용한 탄소나노튜브의 분산 방법 |
| DE102007042253A1 (de) * | 2007-09-06 | 2009-03-12 | Carl Freudenberg Kg | Druckfähige und leitfähige Paste und Verfahren zum Beschichten eines Materials mit der Paste |
| DE102007044031A1 (de) | 2007-09-14 | 2009-03-19 | Bayer Materialscience Ag | Kohlenstoffnanoröhrchenpulver, Kohlenstoffnanoröhrchen und Verfahren zu ihrer Herstellung |
| CN100575436C (zh) * | 2007-10-11 | 2009-12-30 | 同济大学 | 一种含碳纳米管水性聚氨酯导电涂料及其制备方法 |
| EP2186841A1 (de) * | 2008-11-14 | 2010-05-19 | Bayer MaterialScience AG | Vernetzbare Polyurethan-Dispersionen |
| US20100270055A1 (en) * | 2009-04-27 | 2010-10-28 | Air Products And Chemicals, Inc. | Electrically Conductive Films Formed From Dispersions Comprising Conductive Polymers and Polyurethanes |
| EP2430640B1 (en) * | 2009-05-14 | 2018-07-04 | Battelle Memorial Institute | Solventless methods of coating a carbon nanotube network and carbon nanotube networks coated with a polymer |
| WO2010135335A1 (en) * | 2009-05-18 | 2010-11-25 | Ppg Industries Ohio, Inc. | Aqueous dispersions, conductive fiber glass strands, and composites comprising the same |
-
2009
- 2009-03-13 DE DE102009012674A patent/DE102009012674A1/de not_active Withdrawn
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- 2010-03-05 WO PCT/EP2010/001397 patent/WO2010102763A1/de not_active Ceased
- 2010-03-05 CN CN2010800207295A patent/CN102421838A/zh active Pending
- 2010-03-05 KR KR1020117023978A patent/KR20110134910A/ko not_active Withdrawn
- 2010-03-05 EP EP10707229A patent/EP2406311A1/de not_active Withdrawn
- 2010-03-05 US US13/255,931 patent/US20120112133A1/en not_active Abandoned
- 2010-03-05 JP JP2011553336A patent/JP2012520356A/ja not_active Withdrawn
- 2010-03-12 TW TW099107182A patent/TW201039361A/zh unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103842290A (zh) * | 2011-09-29 | 2014-06-04 | 独立行政法人产业技术综合研究所 | 碳纳米管复合材料 |
| CN109911886A (zh) * | 2011-09-29 | 2019-06-21 | 独立行政法人产业技术综合研究所 | 碳纳米管分散液 |
| CN103383868A (zh) * | 2012-05-04 | 2013-11-06 | 远东新世纪股份有限公司 | 透明导电积层体 |
| CN103383868B (zh) * | 2012-05-04 | 2016-09-07 | 远东新世纪股份有限公司 | 透明导电积层体 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102421838A (zh) | 2012-04-18 |
| JP2012520356A (ja) | 2012-09-06 |
| KR20110134910A (ko) | 2011-12-15 |
| US20120112133A1 (en) | 2012-05-10 |
| WO2010102763A1 (de) | 2010-09-16 |
| EP2406311A1 (de) | 2012-01-18 |
| DE102009012674A1 (de) | 2010-09-16 |
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