TW201017045A - High-performance heat dissipation device and method for manufacturing the same - Google Patents
High-performance heat dissipation device and method for manufacturing the same Download PDFInfo
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201017045 六、發明說明: 【發明所屬之技術領域】 本發明係有關於一種具有良好散熱效果的高效能散熱裝 置’特別是有關於一種包含有由導電層及高導熱高絕緣層所組 成之高效能散熱性基板的高效能散熱裝置,以提供電子零件及 裝置之高效能散熱效果。本發明亦提供一種用以製造該高效 散熱裝置的製造方法。 b 【先前技術】201017045 VI. Description of the Invention: [Technical Field] The present invention relates to a high-efficiency heat dissipating device having a good heat dissipating effect, particularly relating to a high-performance energy comprising a conductive layer and a high thermal conductivity and high insulating layer. A high-efficiency heat sink for the heat-dissipating substrate to provide efficient heat dissipation of electronic components and devices. The present invention also provides a method of manufacturing the high efficiency heat sink. b [prior art]
巧為年3C產業隨著電子晶片不斷往高性能化、高速度化 及輕薄短小化發展,使電子元件的發熱量(p〇werDissipati〇n) 及相對熱流量(HeatFlux)愈來愈高,電子散熱問題變成電子 產業首要克服的問題。 實務上’電子元件的散熱常利用熱對流佳、高表面積的散 熱褒置(Heat Sink)或散熱鰭片(Heat Fin)來進行,透過將 3裝置賴以φ接觸財式裝設於發熱的電子元件或電 “置上,即可將電子元件產生的熱量經由散鱗>1發散至外 =境内。但是基於製程上酿制,散鋪置或鰭#的表面並 f期的平整,目此在以面接觸方式與發熱的電子元件組裝 ,時,二者間互相接_表面之雜往存在著空隙,而由 空隙的存在’會大財崎低餘的絲,因為存在於 =2隙⑽空氣的導熱絲約為1(r4 w/mK,通常是被視為 盆矣f μ方面,承載著發鱗子元件的絲,例如金屬基板, ^面^會做過表面處理’但其表面平整度也砂預期般的 整’因此亦會構成散熱過程中的另一項障礙。 熱的^上^、困擾’現有技術的因應之道是在發熱體(如發 、’、、凡件)及散熱鰭片間填充軟性的導熱介質材料 3 201017045 (Thermal Interface Material) ’例如導熱斧、導熱朦等,這此導 熱介質材料雖可達到空隙填充的目的,但導熱膏(或導熱膠) 會因低溫而ϋ化收縮,並會因高溫而蒸發’並無法滿足產品耐 久性的需求。再者,組裝過程的緊鎖正向力大小、導熱介質材 料之厚度的控制等因素也都會造成使用上及效能上的困^或 問題。As the electronic chip continues to become high-performance, high-speed, and light and thin, the heat generation of electronic components and the relative heat flow (HeatFlux) are getting higher and higher. The heat issue has become the primary problem that the electronics industry has overcome. In practice, the heat dissipation of electronic components is often carried out by using a heat convection, a high surface area heat sink or a heat sink (Heat Fin), and the heat is mounted on the heat by using the 3 device. The component or electricity is "set", and the heat generated by the electronic component can be diverged to the outside by the scaly > 1. However, based on the process, the surface of the spread or fin # is flattened, f When it is assembled in a surface contact manner with a hot electronic component, the two are connected to each other. There is a gap in the surface of the surface, and the presence of the gap will be the result of the large amount of silk, because it exists in the =2 gap (10). The heat conducting wire of air is about 1 (r4 w/mK, usually regarded as the basin f μ, which carries the filament of the scale element, such as a metal substrate, and the surface will be surface treated 'but the surface is flat The sand is expected to be the same as the other ones. Therefore, it will constitute another obstacle in the heat dissipation process. The heat of the ^, the troubles of the prior art is in the heating body (such as hair, ',, and everything) and Thermally conductive medium filled with heat-dissipating fins 3 201017045 (Thermal Int Erface Material) 'For example, heat-conducting axe, thermal conductive raft, etc., although the thermal conductive material can achieve the purpose of void filling, but the thermal paste (or thermal adhesive) will shrink and shrink due to low temperature, and will evaporate due to high temperature' To meet the requirements of product durability. Furthermore, factors such as the tightness of the assembly process and the thickness of the heat transfer medium material can also cause difficulties in use and performance.
❹ 第1圖中所示即為前述習用的散熱結構及其組裴應用。以 發光二極體(Light-Emitting Diode,LED)照明為例來說明, 其中是以LED晶>}1〇()賴電後發絲產生照明效果,惟當 LED晶片1〇〇通電發光時’亦同時會發射出相當多的熱量。此 LED晶片1〇〇是裝設於一基板1〇2上。此基板包含有、一金屬❹ The first example of the heat dissipation structure and its application are shown in Figure 1. Taking Light-Emitting Diode (LED) illumination as an example, the LED crystal is used to generate illumination after the LED is used, but when the LED chip is powered on. 'At the same time, it will emit a lot of heat. The LED chip 1 is mounted on a substrate 1〇2. The substrate contains a metal
=1,貝i附魏曾緣的導熱材料底部上,該絕緣導熱熱材料基 ,係由一層絕、緣導熱層⑽及⑽(例如有機絕緣導敎材料)依 序疊置而構成的。該金屬⑽何經由適當的加工過程 曝光及侧等已知的製程’來形成所_線路,㈣ 片100以適當的方式接著至其上。 A ♦二102上的金賴通常綠或銅或其等的合 金,具有良好的導電性能,以供供應電力至LED晶片上,=1, on the bottom of the heat-conducting material of Wei Zengwei, the insulating heat-conducting thermal material base is composed of a layer of insulating and thermal conductive layers (10) and (10) (for example, organic insulating conductive materials). The metal (10) is formed into a line by a known process such as exposure and side known processes, and (iv) the sheet 100 is subsequently attached thereto in an appropriate manner. A ♦ Gold on the 102 is usually green or copper or its alloy, which has good electrical conductivity for supplying electricity to the LED chip.
同巧些金屬材料也具有良好的傳熱性f,例如說蹄的導熱 係數約為220W/Mk,銅材的導熱絲約為38〇w/mK =〇=〇所產生的熱傳遞至位於金屬綱下方的絕緣 爹閲第2圖,在使用上,此一裝設有 1〇2會另外裝設於-散熱器職一表面上,使 it熱裝置m的該表面之_成面接觸,* ,遞=齡置或則上,讀散發至外界環軸。如前戶 料細G8練錄置岐_導熱们 材科U2 ’如導熱膏,將基_2貼附組胁散熱器丨社,^ 201017045 降低基板102與散熱器110間的熱傳阻抗。 在經由金屬箱104所構成的線路施用電力至led晶片100 上後,LED晶片100即開始發光,同時產生熱量,其熱量會向 外傳遞’特別是會透過導熱介質材料112而傳送至散熱器no 内’並經由散熱器110上通常會設置的散熱鍺片116而逸散至外 界環境内,以達到散熱的目的。 雖然則述的結構表面上可以解決發熱元件的散熱,但仍存 在很多問題有待克服,例如: …The same metal material also has good heat transfer performance f. For example, the thermal conductivity of the shoe is about 220W/Mk, and the heat conduction wire of the copper material is about 38〇w/mK = 〇 = 〇 heat generated to the metal. Insulation below the outline refers to Figure 2, in use, this installation of 1〇2 will be additionally installed on the surface of the radiator, so that the surface of the heat device m is in surface contact, * , hand = age or then, read and distribute to the outer ring axis. For example, the former household material fine G8 practice recording _ heat conduction material material U2 ‘such as thermal paste, the base _2 attached to the group of heat sinks, ^ 201017045 reduce the heat transfer impedance between the substrate 102 and the heat sink 110. After applying power to the LED wafer 100 via the line formed by the metal box 104, the LED chip 100 begins to emit light while generating heat, and the heat is transferred outwards, particularly through the heat conductive medium material 112 to the heat sink. The inner portion is dissipated into the external environment via the heat dissipation fins 116 generally disposed on the heat sink 110 to achieve heat dissipation. Although the surface of the structure described above can solve the heat dissipation of the heating element, there are still many problems to be overcome, such as: ...
(1)散熱不足·第1圖及第2圖中所示的習知基板1〇2中包 含有二層絕緣導熱層106及108。以有機絕緣導熱材料為例,這 些絕緣導熱層106、108通常是由有機高分子材料製成,其十混 入導熱介質,以提供其導熱的性能。惟以此方法製成的絕緣導 熱材料的導熱係數大都落在1W/mK至7|/1111(:之間,遠不及鋁 材的220W/mK、銅材的380W/mK,因此會嚴重地增加熱傳遞 f礙,更何況習知之基_2中設有二層這鋪料,故在教 傳遞過程會遇到三次的熱障礙,使導熱效果大打折扣。 (2)基板與散熱裝置的表面不平整:由於加工誤差及精 之故’基板1G2之絕緣導熱層108的底面及散熱器110之 if ίΪ1。2的表面,雖_巨觀上的呈平整狀的表面,惟在 、角度上,此二表面均具有高低起伏的形態,相當的不平 基板1G2及散熱11110均為硬質結構,因此其間的 二表面做面接觸時,會在形成空隙,降低導熱效 66# ^ 1虽產品(如LED路燈)的面積變大時,兩個硬質 持良好的平行導熱介層於其間會更形困 並益更好的ϋ除ΓΙ上更厚的導熱介質材料(如導熱膠)外, 也會更差,因此形=^膠這類_介質材料愈厚其雜效果 ⑶另項困擾在於,前述的方法並無法應用於非平面 5 201017045 甚至是=置很多需要有散熱作用的應_是非平面的, 也並無解決之道=_產品以目_方法根本無法應付,因此 補界面文方向均往減少導熱層數 【發明内容】(1) Insufficient heat dissipation. The conventional substrate 1A shown in Figs. 1 and 2 includes two insulating heat conductive layers 106 and 108. Taking an organic insulating heat conductive material as an example, these insulating heat conductive layers 106, 108 are usually made of an organic polymer material, which is mixed with a heat conducting medium to provide heat conducting properties. However, the thermal conductivity of the insulating and thermally conductive materials produced by this method mostly falls between 1W/mK and 7|/1111 (:, far less than the 220W/mK of aluminum and 380W/mK of copper, so it will increase seriously. The heat transfer is impeded, not to mention the fact that there are two layers of the paving material in the base 2, so there are three thermal obstacles in the teaching transfer process, which greatly reduces the heat conduction effect. (2) The surface of the substrate and the heat sink is not Flatness: the surface of the insulating and thermally conductive layer 108 of the substrate 1G2 and the surface of the heat sink 110 of the heat sink 110 due to processing errors and fineness, although the surface of the heat sink 110 is flat, but at an angle Both surfaces have high and low undulations. The relatively uneven substrate 1G2 and heat dissipation 11110 are hard structures. Therefore, when the two surfaces are in surface contact, voids are formed and the heat conduction effect is reduced. 66# ^ 1 Although products (such as LED street lamps) When the area becomes larger, the two hard and good parallel heat conducting layers will be more trapped in the middle and will be better, and the thicker heat conductive material (such as thermal conductive glue) on the crucible will be worse. Therefore, the shape = ^ glue, such as _ dielectric material, the thicker the mixed effect (3) another The problem is that the above method can not be applied to non-planar 5 201017045 or even = a lot of need to have heat dissipation _ is non-planar, there is no solution = _ product can not cope with the method, so make up The number of thermal conductivity layers is reduced in the direction of the interface text [invention]
方法、製備來[直需要有-種實用施的 於提供-種而本發明之主要目的即是在 有-之7觀點:其提供i高效能散熱裝置,包含 軟高導执古祕一馬分子材料混合導熱粉末而製成的柔 層,其上可、fif步驟而製成具有適#電路紋路的導電The method, the preparation method [there is a need to have a practical application to provide - the species and the main purpose of the invention is to have a view of the 7: it provides i high-efficiency heat sink device, including a soft high guide a soft layer made of a material mixed with a heat conductive powder, which can be made into a conductive circuit having a suitable circuit trace
填 可行性改善之 ’二=黏著特性’藉_著特性及絕緣材料層的柔 ίίϋ電路板可以緊密地貼附至一散熱器件上,藉之 ====電子元件的熱量傳遞至該散熱器件上,進而 康ί發明的另一觀點’其提供一種高性能散熱裝置的製 ’/、主要的步驟在於首先製備—高導熱的軟性線路板, f性線路板是由—高導熱的絕緣層及—高導電特性的金屬 治、且成’該金屬紐加工,如曝光及侧,可形成適當的電路 ,路:可供焊接發熱電子元件於其上,製做該絕緣層的材料可 為適當的柔軟高分子材料,具有lw/mK至7W/mK的導熱係 數’並可以承f金屬狀線路製作過㈣侧破壞,本發明的 方法另包含有於該絕緣層上與金屬箔相反的一側上設置導熱 201017045 法 明 將該軟性線路緊密地結合至散熱器件上:_層之錄性質而 法另外,下面崎細說财轉出數個範例來具想解說=發 【實施方式】 參Filling in the feasibility improvement of the 'two = adhesive characteristics' borrowed - the characteristics of the flexible layer of the insulating material can be closely attached to a heat sink, by ==== the heat of the electronic component is transferred to the heat sink In addition, another aspect of the invention is that it provides a high-performance heat-dissipating device. The main steps are to first prepare a high-thermal-conducting flexible circuit board. The f-type circuit board is made of a highly thermally conductive insulating layer. - high-conductivity metal treatment, and into the metal processing, such as exposure and side, can form a suitable circuit, the circuit: can be used to solder the heating electronic components, the material of the insulating layer can be suitable a soft polymer material having a thermal conductivity of from 1 w/mK to 7 W/mK and which may be subjected to (four) side damage by a metal line, and the method of the present invention further comprises on the opposite side of the insulating layer from the metal foil Set the heat conduction 201017045 to clearly bind the soft circuit to the heat sink: _ layer of the nature of the record and the law, the following is a fine example of the financial transfer out of several examples to explain = send [implementation]
本發明係有關於—種高性能散熱裝置,以及 高性能散熱裝置係應用於會產生熱f的電子元 如^請-生的裝置,賴以高效率賴量加以移除。 iii圖本發明的高性能散熱健在結構上係製做成-The present invention relates to a high-performance heat sink, and a high-performance heat sink is applied to an electronic component that generates heat f, such as a device, which is removed by high efficiency. Iii. The high-performance heat-dissipation of the present invention is structurally made -
;^),將敎H2G(y以做為—基板(下文亦稱為軟性基 板)以供將熱量自一裝設於其上的發熱體202,例如一 LED f,内加以移除。如圖所示的本發.佳實施例,該高導孰 ί 含有—導電層204及—高導熱高絕緣材料ΐ 二中該ί電層2〇4係由具有高導電性的金屬簿所構成,例 =泊或㈣’其底縣面上結合該高導熱高絕緣材料層 ’且該金賤可以適度的加卫,例如透過光料行曝光及 =刻,而形成有所需的導電線路,以做為供發熱體2〇2 (即本 實施例中的LED晶片)焊接至其上。林發㈣較佳實施例 中’該用來構成導電層204的金屬箱的厚度是約3师至14〇阿。 在本^施例中,高導熱高絕緣材料層2〇6是由具有高絕緣 性的有機高分子基材混入具有高導熱性質的粉末,例如氧化 鋁、氮化硼等,透過一般的混煉技術將導熱粉末與高分子基材 結合在一起,以形成該高導熱高絕緣材料層2〇6,而該等導熱 粉末即可在該高導熱高絕緣材料層2〇6内構成良好的導敎^ # 0 ”、 201017045 較佳實施例,該高分子基材可以是一财高溫 選自包含有全芳香族高分子材料、芳脂肪族 麵高分子材料、或含芳香族結構的共聚合物 ,科在内之族群’也包财魏触* (EpGxy)、妙立康系 ,力型(切1⑹、聚氨酯型(蜂娜_;^), 敎H2G (y is used as a substrate (hereinafter also referred to as a flexible substrate) for removing heat from a heating element 202, such as an LED f, mounted thereon, as shown in the figure. In the preferred embodiment of the present invention, the high conductivity 含有 含有 includes a conductive layer 204 and a high thermal conductivity high insulating material ΐ 2. The electrical layer 2 〇 4 is composed of a metal book having high conductivity, for example =Pool or (4) 'The bottom of the county is combined with the layer of high thermal conductivity and high insulation material' and the metal enamel can be moderately reinforced, for example, by light exposure and = engraving, to form the desired conductive line to do The heat generating body 2〇2 (i.e., the LED chip in this embodiment) is soldered thereto. In the preferred embodiment, the thickness of the metal case used to form the conductive layer 204 is about 3 divisions to 14 inches. In the present embodiment, the high thermal conductive high insulating material layer 2〇6 is mixed with a highly conductive organic polymer substrate into a powder having high thermal conductivity, such as alumina, boron nitride, etc., through a general The mixing technology combines the thermal conductive powder with the polymer substrate to form the high thermal conductive high insulating material layer 2〇6 And the thermally conductive powder can form a good guide in the high thermal conductive high-insulation material layer 2〇6, 201017045. In the preferred embodiment, the polymer substrate can be selected from a high temperature All-aromatic polymer materials, aromatic fatty surface polymer materials, or copolymers containing aromatic structures, and the ethnic group in the group 'EpGxy, Miao Likang, and force type (cut 1 (6) , polyurethane type (bee _
另卜,分子基材的選用必須要具有能承受前述對於金 ,,所,行之加工製程的物理及化學性質,亦即高分子基材必 須能承受金屬箔之加工所造成的物理及化學性破 箱加工後維持其所需有的性質。 碾於金屬 另外,根據本發明之實施例,混合於該高分子基材内的導 熱粉末可以是各類的氧化物驗(如氧化々峨、氧化辞 等)、氮化物顆粒(氮化铭A1N3、氮化删BN等)、碳化物(石 墨、碳黑、碳管、碳纖維、碳化矽)、以及金屬顆粒等,也可 以包含有則娜法(Sd_Gel)㈣制氧化物或氮化物顆 粒。在本發明的一實施例中,這些導熱粉末的顆粒大小是從 Ο.ΟΙμπι至ΙΟΟμπι ’而其形狀則無限制,可以是平面狀、 等。 > , 另外,尚導熱高絕緣材料層206之結合於導電層2〇4的底 面,可由任何已知的適當方法為之。例如可以將該高導熱高絕 緣材料層206之液態原材料,以例如塗佈法、溶液鑄膜法、及 網版印刷法等,直接成型於該導電層2〇4的金屬箔的底面上。 或者,可以先將高導熱高絕緣材料層206的原材料製做成一熱 可塑膜,再利用高溫高壓的製程將該熱可塑膜結合至該金屬箔 的底面上。當然,本發明的實施並不僅限於前述的這些材料及 製程,其他可以達成本發明之功效的等效材料或製程亦可加以 應用。 如有需要亦利用前述的方法或材料,在導電層204的底面 201017045 上加設另一層高絕緣材料層(未顯示),此另一高絕緣材料層 可以是由前述的高分子材料,利用前述的各種製程加以製做於 導電層204的底面上’例如此另一高絕緣材料層可形成於該高 導熱高絕緣材料層206的底面。此另一高絕緣材料層可由高分 子基材混合其他功能的材料,例如電磁波的材料或其顆粒或粉 末,或者此另一高絕緣材料層可以混入或由適當的材料加以製 做,以增進熱傳遞效能。 根據本發明的另一實施例,高導熱軟性線路板2〇〇進一步 包含有一層導熱膠層208,塗佈於高導熱高絕緣材料層20ό (或 是前述的該另一層高絕緣材料層)上與導電層204相對的一 面,亦即高導熱高絕緣材料層206上未設置由該金屬箔構成之 線路(即導電層204)的一側表面上,而使得該導電層2〇4與該 導熱膠層208分別位於該高導熱高絕緣材料層2〇6的頂側及底 側表面上。此f熱膠層208可提供高導熱軟性線路板200黏著的 特性,以供將高導熱軟性線路板200輕易地貼附至散熱鰭片或 其他的散熱器210 (見第4圖)上。 * 根據本發明的較佳實施例,該導熱膠層208可由導熱性的 感壓膠(Pressure Sensitive Adhesive)所製成(下文中稱感壓導 ,膠)’其可在施加外力下產生黏著性,或者亦可由可在加熱 後固化而產生,著性的固化型導熱膠(下文中稱固化型導熱 膠)所製成。當然,本發明並不僅限於這些黏膠例子而已。 根據本發明的再另一實施例,在使用感壓導熱膠來做為導 熱膠層208^情形中’或是其他適當的應用中,在導熱膠層2〇8 外露之黏著性表面上可貼附一層離型紙或離型膜212。此離型 膜212可輕易地自導鱗層挪上撕離,以供導娜層2〇8之黏 ^至散熱器2io上,同時在未撕離時,可保護該導熱膠層2〇8的 外路表面免於受到污損或意外地沾黏至其他物體上。如此,有 助於此高導熱軟性線路板2〇〇的運送、儲存、以及使用。 201017045 根據本發明之較佳實施例,在感壓導熱膠製成導敎膠層 208的情形中,該感壓導熱膠可以是環氧樹脂型、矽立、 壓克力型、聚氨酯型,或上述這些膠的混合型。 藉由前述本發明之高導熱軟性線路板2〇〇的軟性特色,本 〒明的高祕雌線雜2〇(mx更纽的錄細片 器210緊密結合,大幅度甚或完全消除習用基板與散埶^間之 面接觸區域内的空隙,可有效地改良導熱效果,同時 鍺片的面積多大、多不平整其至是斜面,基於軟性的特色,^ 參In addition, the selection of the molecular substrate must have the physical and chemical properties that can withstand the above-mentioned processing processes for gold, and the process, that is, the polymer substrate must be able to withstand the physical and chemical properties caused by the processing of the metal foil. Maintain the desired properties after breaking the box. Grinding in metal In addition, according to an embodiment of the present invention, the thermally conductive powder mixed in the polymer substrate may be various oxides (such as yttrium oxide, oxidized, etc.), nitride particles (nitriding Ming A1N3) , nitriding BN, etc.), carbide (graphite, carbon black, carbon tube, carbon fiber, niobium carbide), and metal particles, etc., may also contain oxide or nitride particles made by Sd_Gel (4). In an embodiment of the present invention, the particle size of the thermally conductive powder is from Ο.ΟΙμπι to ΙΟΟμπι ′ and its shape is not limited, and may be planar, or the like. > In addition, the thermal conductive high-insulation material layer 206 is bonded to the bottom surface of the conductive layer 2〇4, and may be any known suitable method. For example, the liquid material of the high thermal conductive high-insulating material layer 206 can be directly molded on the bottom surface of the metal foil of the conductive layer 2〇4 by, for example, a coating method, a solution casting method, or a screen printing method. Alternatively, the raw material of the high thermal conductive high insulating material layer 206 may be first formed into a thermoplastic film, and the hot plastic film may be bonded to the bottom surface of the metal foil by a high temperature and high pressure process. Of course, the practice of the present invention is not limited to the foregoing materials and processes, and other equivalent materials or processes that can achieve the effects of the present invention can be applied. If necessary, another layer of high-insulation material (not shown) may be added to the bottom surface 201017045 of the conductive layer 204 by using the foregoing method or material. The other high-insulation material layer may be formed by the foregoing polymer material. Various processes are formed on the bottom surface of the conductive layer 204. For example, another layer of high insulating material may be formed on the bottom surface of the high thermal conductive high insulating material layer 206. The other layer of high insulating material may be mixed with a polymer substrate by other functional materials, such as electromagnetic wave materials or particles or powder thereof, or the other high insulating material layer may be mixed or made of a suitable material to enhance heat. Pass performance. According to another embodiment of the present invention, the high thermal conductive flexible circuit board 2 further includes a thermal conductive adhesive layer 208 coated on the high thermal conductive high insulating material layer 20 (or the other high insulating material layer as described above). The side opposite to the conductive layer 204, that is, the side of the high thermal conductive high insulating material layer 206 on which the wiring formed of the metal foil (ie, the conductive layer 204) is not disposed, so that the conductive layer 2〇4 and the heat conduction The glue layers 208 are respectively located on the top side and the bottom side surfaces of the high thermal conductive high insulating material layer 2〇6. The f-thermal adhesive layer 208 can provide the adhesion of the high thermal conductive flexible wiring board 200 for easily attaching the high thermal conductive flexible wiring board 200 to the heat dissipating fins or other heat sinks 210 (see Fig. 4). According to a preferred embodiment of the present invention, the thermal conductive adhesive layer 208 can be made of a thermal Sensitive Adhesive (hereinafter referred to as a pressure sensitive adhesive, glue) which can be adhesive under application of an external force. Alternatively, it may be made of a curable thermal conductive adhesive (hereinafter referred to as a curable thermal conductive adhesive) which can be produced by curing after heating. Of course, the invention is not limited to these examples of adhesives. According to still another embodiment of the present invention, in the case where the pressure sensitive thermal conductive adhesive is used as the thermal conductive adhesive layer 208, or in other suitable applications, the adhesive surface exposed on the thermal conductive adhesive layer 2〇8 can be attached. A release paper or release film 212 is attached. The release film 212 can be easily peeled off from the guide scale layer for bonding the adhesive layer 2 to 8 to the heat sink 2io, and at the same time, the heat conductive adhesive layer can be protected when not peeled off. The outer surface is protected from dirt or accidental adhesion to other objects. In this way, it facilitates the transportation, storage, and use of the high thermal conductivity flexible circuit board. 201017045 According to a preferred embodiment of the present invention, in the case where the pressure sensitive thermal adhesive is made into the conductive layer 208, the pressure sensitive adhesive may be epoxy type, erect, acrylic type, polyurethane type, or A hybrid type of these gums. By the soft features of the high thermal conductive flexible circuit board 2 of the present invention, the high-definition female line of the present invention is closely combined, and the micro-chip 210 of the mx-newer is tightly combined to substantially eliminate or completely eliminate the conventional substrate and The gap in the contact area between the two sides can effectively improve the heat conduction effect, and the area of the cymbal is too large, and the unevenness is the slope. Based on the characteristics of softness, ^ ginseng
發明的高導熱軟性線路板200均可完美的結合其導熱界 效的改善導熱途徑。 ' 本發明之高性錄絲置的製做方法,其主要的步驟在於 ^先有製備高導熱性能的軟性基板,即高祕軟性線路板 而後再利用習知的貫光钱刻製程在高導熱軟性線路板獅 之導電層2G4的金上製作出所需的線路或電路,缺後 所需的電子零件或發熱體2G2 (例如LED晶粒)焊接於該導電 ΐίίΜ1 ’最後翻用導誠轉208 (如有需要可先撕離離型 =12)結合至散熱器21()上而完雜合。以下將 驟來加以說明: 少 JLl製做高導熱款性總踗;^ 首先製備高導熱軟性基板200,包含有導電層204及高導孰 ί 2ϋ電層204主要由高導電性的金屬 $ Μ i高導熱高絕緣材㈣2G6為具高絕緣性而 ί 中混入料熱粉末(如氧脑、氮化硼等), 的ϋϊΓ馳練_換高奸紐結合,並形成良好 結合②Si圭一實:中 可以(例如頂面)上,而其結合方式 、適田方法為之。例如可以將該高導熱高絕緣材料層 201017045 206之液態原材料’以例如塗佈法、溶液鑄臈法、及網版印刷 法等,直接成型於該導電層204的金屬箔的底面上。或者,可 以先將高導熱高絕緣材料層206的原材料製做成一熱可塑臈, 再利用高溫高壓的製程將該熱可塑膜結合至該金屬箔的底面 上。 ~ ❹ ❹ 在本發明的較佳實施例中,該高分子基材可以是一耐高、σ 的高分子材料,係選自包含有全芳香族高分子材料、芳脂肪: 料族高分子(Ar〇mati〇材料、或含芳香族結 ”物材料在内之族群’也包括有環氧樹脂系 石夕立康系(silicone)、壓克力型(Acr>iic)、聚氨 酉曰型(Polyurethane)等高分子材料。 於太的較佳實施射,混合於該高分子基材内的導熱 f H的氧化物雛(如氧化石夕_、氧化鋅齡 雾、Λ物=(氮化銘細3、氮化硼bn等)、碳化物(石 墨厌黑、妷管、碳纖維、碳化矽)、以及金屬顆棱孳, :包:=rrs—製備的==化= 〇〇ΐμίΐϋ f射,這解熱粉末的齡大小是從 等。 帅’而其形狀則無限制,可以是平面狀、纖維狀 及適的金屬箱上,配合光罩 加工所造成的破i的同刀子材料必須要能承受金屬箱之 膠)以膠或固化導熱膠或其他的導熱 204相對的另導熱高絕緣材料層206上與導電層 (列如底面)上,以形成導熱膠層208, 201017045 姑田可為任何已知的適當製程,例如以'塗佈的方式 ϊ =^=Π4ί2()6上不設有有_綱的底面 _ 有需要可選擇性地在導熱膠層208上 貼附一離型膜,以供保護該導熱膠層208。 在本發明之較佳實施例中,該導熱膠層挪可以 =、教康型、壓克力型、聚氨醋型,或上述這些膠的混合 4、組裝應用 ❻ 如咖晶片)焊接於上述高導熱軟性線路 層204上,並將高導熱軟性線路板的自黏性導 熱面(即導祕層⑽)_至—雜n上,如齡完成 1合導 伽t所製備的高導熱軟性線路板來取 的金屬基板’將發熱元侧定於其上,絲取其此軟性 ^路板的雛’以供與散熱驗緊密地結合,其優點包括 了一 層錢導舰騎,比_般習知的結構少 0 ㈤時亦有效的降低成本。 又《具導熱效果’ 胖iL)人利用,線路板柔軟的特點,可以更有效的與散熱 器緊氹、、,σ σ,不管散熱器的面積多大、或其表 =二、 ΪίΪΐί是呈斜面’本發明的軟性線路板柔軟:性:可達ί 緊禮、地結合至散熱器之表面上,可有效的改善導熱途徑。 非平面的高導熱軟性線路板可因應實際需求,而與 以下將舉_細來更频地_本㈣ 是這些範綱僅是肖來_本發狀綠_子方 用來對本發明的範圍加以限制。 並非是 12 201017045 範例一 選用聚酿亞胺酸溶液(PolyamicAcid),加入了 70%的Ιμπι 的氧化鋁粉末,經過適當混練後,製備成高導熱的聚醯亞胺酸 膠水’再將該膠水塗佈在1盎司(35μπ〇的金屬箔(在此範例 中為鋼箔)上’經過350°C的高溫烘烤後去除溶劑,而同時聚 酿亞胺酸結構將進一步脫水,形成高導熱聚醯亞胺高分子 (Polyimide,PI) ’完成高導熱軟性銅箔基板的製做。 在此範例中所使用的聚醯亞胺酸溶液是由雙酐及雙胺兩 類原料在強極性溶劑中反應而成,此反應為一般習知的聚合反 ❹ 應工程’若需了解類似反應的詳細聚合反應過程請參考美國專 利US5,152,947及US4,473,523所揭露的技術。 . 利用壓膜機將乾膜光阻(如長春的AF-5000系)貼覆在此 高導熱軟性線路板的金屬箔層上,配合曝光機及氣化鐡系蝕刻 液完成餘刻工藝,清洗後ll〇°C烘乾1〇分鐘後待用。 再將感壓導熱膠塗佈於無線路面上,200°C烘烤30分鐘後 結束,以形成導熱膠層,並與離型膜組合,完成自黏特性的賦 予0 將白光LED晶片利用焊接或適當的黏著技術固定在蝕刻 攀 完成的導電線路上,再將具自黏性之表面上的離型紙撕下,以 供黏附至散熱器上,完成具尚導熱效率的led發光元件的製 造。 範例二 選用熱可塑性t醯亞胺酸溶液(Therm〇piastic p〇iyamic Acid) ’加入了70%的Ιμϊη的氧化銘粉末,經過適當混練後, 製備成高導熱的熱可塑性聚醢亞胺酸膠水,再將該膠水塗佈適 當的載板,如玻璃或不锈鋼板(輪)上,經過35〇〇c的高溫烘 烤後形成熱可塑性聚醯亞胺高分子(p〇lyimide,pi)薄膜。^ 13 201017045 在此範例中’熱可塑性聚醯亞胺酸溶液的配製,也是由雙 肝及雙胺兩類原料在強極性溶劑中反應而成,在此我們可選用 一般習知的化學結構的熱可塑性聚醯亞胺高分子材料,類似反 應的詳細聚合反應過程可參考Kaneka公司的熱塑性聚醯亞胺 TPI 製造(ThermoplasticPolyimide,美國專利 US5,621,068)。 將上述的熱可塑性聚醯亞胺高分子薄膜,與1盎司(35μηι) 的銅箔,在350°C的高溫下壓合,完成高導熱軟性銅箔基板的 製做。 其他後續的線路餘刻、自黏性與組裝應用,與範例一同, 不再贅述。 範例三 選用熱可塑性聚醯亞胺酸溶液,加入了7〇%的1μιη的氧化 鋁粉末,經過適當混練後,製備成高導熱的熱可塑性聚醯亞胺 酸膠水,再將該膠水塗佈在適當載板,如玻璃或不锈鋼板上, 經過350°C的高溫烘烤後形成高導熱熱可塑性聚醯亞胺高 (TPI)薄膜。 將上述的熱可塑性聚醯亞胺高分子薄膜,與2片丨盎司(35 =m)的銅箔,中間夾層一層上述的熱可塑性聚醯亞胺高分子 薄膜,在350°C的高溫下壓合,完成高導熱軟性銅箔基板的製 做。在本範例中,亦可製作了一面鋁箔一面銅箔的結構。在此 種結構中,其一面的金屬箔(銅箔或鋁箔)是用來製作線路, 而另一面的金屬箔(銅箔或鋁箔)則是用來增加導熱的效率。 利用壓膜機將乾膜光阻(如長春的Αρ·_5〇〇〇系)貼覆在高 導熱軟性線路板上用來做為線路的金屬箔上,配合曝光機及氯 化鐡系蝕刻液完成蝕刻工藝,清洗後^^^烘乾1〇分鐘完成: 而在進行蝕刻步驟前,另一面的金屬箔需以適當的膠臈或光阻 保遵起來’並在钱刻結束後移除。 201017045 將具感壓導熱膠塗佈於另一面無線路的金屬落上 烘烤30分鐘,結,’並與離型敝合,完成自轉性 此類的做法疋械複合材·構,_料鱗之導 遠不及金屬,故此類做法將會有助後續應用上的散熱。 將白光LED晶片_縣或適當齡著技術岐在線路 上’再將具自黏表面上的離型紙撕下,與散熱器組合,完成且 高導熱效率的LED發光元件的製造。 70成- 範例四 ΟThe invented high thermal conductivity flexible circuit board 200 can perfectly combine the heat conduction efficiency to improve the thermal conduction path. The main method of the method for manufacturing the high-performance recording wire of the present invention is to prepare a flexible substrate with high thermal conductivity, that is, a high-flexible circuit board, and then use a conventional transparent optical circuit to process a high thermal conductive flexible circuit. The lion's conductive layer 2G4 is made of gold on the required line or circuit. After the missing electronic parts or heating element 2G2 (such as LED die) is soldered to the conductive ΐ ίίΜ1 'finally turn the guide 208 (such as If necessary, it can be peeled off and the release type = 12) combined with the heat sink 21 () to complete the hybrid. The following will be explained: Less JLl is made for high thermal conductivity; ^ First, a highly thermally conductive flexible substrate 200 is prepared, which comprises a conductive layer 204 and a high conductivity layer. The electrical layer 204 is mainly composed of a highly conductive metal. i high thermal conductivity and high insulation material (4) 2G6 is high insulation and ί mixed with hot powder (such as oxygen brain, boron nitride, etc.), the ϋϊΓ 练 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ It can be (for example, the top surface), and its combination method, the field method is the same. For example, the liquid raw material ' of the high thermal conductive high insulating material layer 201017045 206 can be directly molded on the bottom surface of the metal foil of the conductive layer 204 by, for example, a coating method, a solution casting method, a screen printing method, or the like. Alternatively, the raw material of the high thermal conductive high insulating material layer 206 may be made into a thermoplastic mold, and the hot plastic film may be bonded to the bottom surface of the metal foil by a high temperature and high pressure process. In the preferred embodiment of the present invention, the polymer substrate may be a high-strength, σ-resistant polymer material selected from the group consisting of wholly aromatic polymer materials, aromatic fats: material group polymers ( Ar〇mati〇 materials, or groups containing aromatic "materials" also include epoxy resin, silicone, acrylic (Acr > iic), and polyamine (type) Polyurethane) and other polymer materials. It is better to use it to spray, and to conduct heat-conducting f H oxides in the polymer substrate (such as oxidized stone _ _, zinc oxide age fog, cockroach = nitrite Fine 3, boron nitride bn, etc., carbide (graphite black, crucible, carbon fiber, niobium carbide), and metal ribs, : package: =rrs - prepared == chemical = 〇〇ΐμίΐϋ f shot, The age of the antipyretic powder is from the same. Handsome and its shape is unlimited, it can be flat, fibrous and suitable metal box, with the knives processing caused by the same knife material must be able to withstand Metal box glue) with rubber or cured thermal conductive glue or other thermal conduction 204 opposite thermal conductivity and high insulation The material layer 206 is on the conductive layer (such as the bottom surface) to form the thermal conductive adhesive layer 208, 201017045. The field can be any known suitable process, for example, in the form of 'coating ϊ=^=Π4ί2()6 The bottom surface is provided with a detachable film 208. Optionally, a release film is attached to the thermal conductive adhesive layer 208 for protecting the thermal conductive adhesive layer 208. In a preferred embodiment of the present invention, the thermal conductive adhesive layer Movable =, teaching Kang type, acrylic type, polyurethane type, or a mixture of the above-mentioned glues 4, assembly application, such as coffee wafers, soldered to the above high thermal conductive flexible circuit layer 204, and high thermal conductivity soft lines The self-adhesive heat-conducting surface of the board (ie, the guiding layer (10))_to-m-n, the metal substrate taken from the high thermal conductive flexible circuit board prepared by the age of 1 combined gamma t is set to the side of the heating element On the top, it takes the softness of the soft board to be closely combined with the heat test, and its advantages include a layer of money to guide the ship, which is also effective in reducing costs compared with the conventional structure of 0 (five). "With thermal conductivity" fat iL) people use, the softness of the circuit board, can be more effective and heat The device is close to, σ σ, regardless of the area of the heat sink, or its surface = 2, Ϊ Ϊΐ Ϊΐ 是 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜 斜On the top, it can effectively improve the heat conduction path. Non-planar high thermal conductivity flexible circuit boards can be used according to the actual needs, and the following will be more detailed _ this (four) is that these classes are only Xiao Lai _ this hair green _ The sub-party is used to limit the scope of the invention. It is not 12 201017045 Example 1 PolyamicAcid is added, 70% of Ιμπι alumina powder is added, and after proper mixing, a highly thermally conductive polymer is prepared.醯imino acid glue' then apply the glue to 1 ounce (35μπ〇 metal foil (in this example, steel foil) to remove the solvent after baking at a high temperature of 350 ° C, while simultaneously brewing the imine The acid structure will be further dehydrated to form a highly thermally conductive polyimine polymer (Polyimide, PI)' to complete the fabrication of a highly thermally conductive flexible copper foil substrate. The polyamido acid solution used in this example is a reaction of a bis-anhydride and a bisamine in a strong polar solvent. This reaction is a conventional polymerization reaction. For a detailed description of the polymerization process, reference is made to the techniques disclosed in U.S. Patent Nos. 5,152,947 and 4,473,523. Dry film photoresist (such as Changchun AF-5000 series) is attached to the metal foil layer of the high thermal conductive flexible circuit board by a laminating machine, and the residual process is completed by using an exposure machine and a vaporized lanthanide etching solution. After ll 〇 ° C drying for 1 〇 minutes, stand by. The pressure sensitive thermal adhesive is coated on a wireless road surface, baked at 200 ° C for 30 minutes, and then finished to form a thermal conductive adhesive layer, and combined with the release film to complete the self-adhesive property of 0. The white LED chip is soldered or Appropriate adhesive technology is fixed on the conductive line of the etched climbing, and then the release paper on the self-adhesive surface is torn off for adhesion to the heat sink to complete the manufacture of the LED light-emitting element with thermal conductivity. In the second example, the Thermoplastic piazide acid solution (Therm〇piastic p〇iyamic Acid) was used to add 70% Ιμϊη oxidized powder. After proper mixing, a highly thermally conductive thermoplastic polyimide glue was prepared. Then, the glue is coated on a suitable carrier, such as a glass or stainless steel plate (wheel), and baked at a high temperature of 35 〇〇c to form a thermoplastic polyimine polymer (p). ^ 13 201017045 In this example, the preparation of a thermoplastic polyisic acid solution is also carried out by reacting both hepatic and diamine raw materials in a strong polar solvent. Here we can use a conventional chemical structure. Thermoplastic polyimine polymer materials, a detailed polymerization process similar to the reaction can be referred to Kaneka's thermoplastic polyimine TPI (Thermoplastic Polyimide, US Patent 5,621,068). The above thermoplastic polyimide film was laminated with a 1 ounce (35 μm) copper foil at a high temperature of 350 ° C to complete the production of a highly thermally conductive flexible copper foil substrate. Other subsequent line remnants, self-adhesiveness, and assembly applications, along with examples, are not described again. In the third example, a thermoplastic polyacrylic acid solution was added, and 7% by weight of 1 μm of alumina powder was added. After appropriate mixing, a highly thermally conductive thermoplastic polyimine glue was prepared, and the glue was coated thereon. A suitable carrier, such as a glass or stainless steel plate, is baked at a high temperature of 350 ° C to form a highly thermally conductive thermoplastic polyimine high (TPI) film. The above thermoplastic polyimine polymer film is laminated with two sheets of 丨 ounce (35 = m) copper foil, and the above thermoplastic polyimide film is laminated at a high temperature of 350 ° C. In combination, the fabrication of a highly thermally conductive flexible copper foil substrate is completed. In this example, a structure of a copper foil on one side of the aluminum foil can also be fabricated. In this structure, one side of the metal foil (copper foil or aluminum foil) is used to make the wiring, and the other side of the metal foil (copper foil or aluminum foil) is used to increase the efficiency of heat conduction. Dry film photoresist (such as Changchun's Αρ·_5 〇〇〇) is coated on a metal foil used as a line on a high thermal conductive flexible circuit board with a laminator, with an exposure machine and a lanthanum chloride etchant. The etching process is completed, and the cleaning is completed after drying for 1 minute: and before the etching step, the metal foil on the other side is to be adhered with the appropriate glue or photoresist, and removed after the end of the money. 201017045 Applying a pressure sensitive thermal paste to the metal of the other side of the wireless road for 30 minutes, knot, 'and mix with the release type, complete the rotation of such a method of mechanical composites · structure, _ scales The guide is far less than metal, so such practices will help heat dissipation in subsequent applications. The white LED chip is used to remove the release paper on the self-adhesive surface and is combined with the heat sink to complete the manufacture of the LED light-emitting element with high thermal conductivity. 70% - Example 4 Ο
依範例一中所述,首先完成高導熱軟性銅箔基板的製做。 再利用壓雌將乾駐阻(如長春的.5_幻貼覆在 此高導熱軟性線路板的金屬箱層上,配合曝光機及氣化鐵系餘 刻液完成蝕刻工藝,清洗後丨⑺^^烘乾1〇分鐘後待用。 七、將白光LED晶片利用焊接或適當的黏著技術固定在蝕刻 完成的導電線路上;再將商業取得的固化型導熱膠均勻塗佈在 軟性導熱軟板或散熱器上,兩者結合後在適當的條件下固化完 ,(^化條請參考固化型導熱膠製造商所所提供固化的資 料)’完成具高導熱效率的LED發光元件的製造。 以上說明解釋本發明的製造流程,其中所揭示的相關說明 及圖式均巧是供閣述本發明之技術内容,以及此技術手段所為 之,佳的範例而已,並不因此而限制本發明之範疇。再者,舉 凡是針對本發明方法、比例或材料等的等效置換及變換,均應 係屬於下文中所述之本發明申請專利範圍所欲加以保護的範 圍。 【圖式簡單說明】 第1圖是一剖面圖,示意地顯示出習用的散熱基板結構。 第2圖是一剖面圖,示意地顯示出習用之散熱基板結合至 一散熱器上。 15 201017045 第3圖是一剖面圖,示意地顯示出本發明之高導熱軟性線 路板的結構。 第4圖是一剖面圖,示意地顯示出本發明之高導熱軟性線 路板結合至一散熱器上。 【主要元件符號說明】 100 LED晶片 102基板 104金屬箔 106絕緣導熱層 ❹ 108絕緣導熱層 110散熱器 112導熱介質材料 116散熱鍺片 200高導熱軟性線路板 202發熱體 204導電層 206高導熱高絕緣材料層 208導熱膠層 〇 210散熱器 U 212離型膜 16According to the first example, the fabrication of the high thermal conductive flexible copper foil substrate is first completed. Then use the pressing female to dry the resistance (such as Changchun's .5_ phantom paste on the metal box layer of this high thermal conductive flexible circuit board, with the exposure machine and gasification iron-based residual liquid to complete the etching process, after cleaning (7) ^^ After drying for 1 minute, it is ready for use. 7. The white LED chip is fixed on the etched conductive line by soldering or appropriate adhesion technology; then the commercially obtained cured heat conductive adhesive is evenly coated on the soft thermal conductive board. Or on the heat sink, after the combination of the two, the curing is completed under appropriate conditions. (Refer to the curing information provided by the curing type thermal conductive adhesive manufacturer.) Finish the manufacture of LED light-emitting elements with high thermal conductivity. The description of the manufacturing process of the present invention is intended to be illustrative of the technical content of the present invention and the preferred embodiments of the present invention are not intended to limit the scope of the present invention. Furthermore, equivalent substitutions and modifications to the methods, ratios, materials, and the like of the present invention are intended to be within the scope of the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional view schematically showing a conventional heat dissipating substrate structure. Fig. 2 is a cross-sectional view schematically showing a conventional heat dissipating substrate bonded to a heat sink. 15 201017045 3 BRIEF DESCRIPTION OF THE DRAWINGS Fig. 4 is a cross-sectional view schematically showing the structure of a highly thermally conductive flexible circuit board of the present invention. Fig. 4 is a cross-sectional view schematically showing the bonding of a highly thermally conductive flexible circuit board of the present invention to a heat sink. Component symbol description] 100 LED wafer 102 substrate 104 metal foil 106 insulation thermal layer ❹ 108 insulation thermal layer 110 heat sink 112 thermal medium material 116 heat sink 200 200 high thermal conductivity flexible circuit board 202 heating element 204 conductive layer 206 high thermal conductivity high insulation material Layer 208 thermal conductive layer 〇 210 heat sink U 212 release film 16
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Cited By (4)
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TWI384174B (en) * | 2010-07-30 | 2013-02-01 | ||
TWI573246B (en) * | 2012-08-20 | 2017-03-01 | 蘇州璨宇光學有限公司 | Light source module and manufacturing method of the same |
TWI616120B (en) * | 2014-06-09 | 2018-02-21 | Flexible circuit board structure combined with carrier board and manufacturing method thereof | |
CN113534525A (en) * | 2021-07-08 | 2021-10-22 | 深圳亿成光电科技有限公司 | Vehicle-mounted LED high-brightness backlight source |
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Publication number | Priority date | Publication date | Assignee | Title |
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TWI384174B (en) * | 2010-07-30 | 2013-02-01 | ||
TWI573246B (en) * | 2012-08-20 | 2017-03-01 | 蘇州璨宇光學有限公司 | Light source module and manufacturing method of the same |
TWI616120B (en) * | 2014-06-09 | 2018-02-21 | Flexible circuit board structure combined with carrier board and manufacturing method thereof | |
CN113534525A (en) * | 2021-07-08 | 2021-10-22 | 深圳亿成光电科技有限公司 | Vehicle-mounted LED high-brightness backlight source |
CN113534525B (en) * | 2021-07-08 | 2024-02-09 | 深圳亿成光电科技有限公司 | Vehicle-mounted LED high-brightness backlight source |
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