TW200825130A - The rubber composition of modified polystyrene-based resin - Google Patents
The rubber composition of modified polystyrene-based resin Download PDFInfo
- Publication number
- TW200825130A TW200825130A TW95146960A TW95146960A TW200825130A TW 200825130 A TW200825130 A TW 200825130A TW 95146960 A TW95146960 A TW 95146960A TW 95146960 A TW95146960 A TW 95146960A TW 200825130 A TW200825130 A TW 200825130A
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- TW
- Taiwan
- Prior art keywords
- rubber
- weight
- parts
- resin composition
- monomer
- Prior art date
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 123
- 239000005060 rubber Substances 0.000 title claims abstract description 114
- 239000000203 mixture Substances 0.000 title claims abstract description 51
- 239000011347 resin Substances 0.000 title claims abstract description 19
- 229920005989 resin Polymers 0.000 title claims abstract description 19
- 239000004793 Polystyrene Substances 0.000 title abstract description 5
- 229920002223 polystyrene Polymers 0.000 title abstract description 5
- 239000002245 particle Substances 0.000 claims abstract description 114
- 239000000178 monomer Substances 0.000 claims abstract description 62
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 39
- 229920001577 copolymer Polymers 0.000 claims abstract description 28
- 238000009826 distribution Methods 0.000 claims abstract description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 11
- 239000011342 resin composition Substances 0.000 claims description 58
- 150000003440 styrenes Chemical class 0.000 claims description 38
- 229920002554 vinyl polymer Polymers 0.000 claims description 21
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 238000012986 modification Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 238000012360 testing method Methods 0.000 claims description 4
- 150000002825 nitriles Chemical class 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- 239000000126 substance Substances 0.000 claims 2
- 150000001555 benzenes Chemical class 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract description 7
- 241001237745 Salamis Species 0.000 abstract description 4
- 235000015175 salami Nutrition 0.000 abstract description 4
- 239000002932 luster Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 description 49
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 16
- 238000009472 formulation Methods 0.000 description 15
- 239000012986 chain transfer agent Substances 0.000 description 14
- -1 vinyl (Vinyl) Chemical group 0.000 description 14
- 230000000704 physical effect Effects 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
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- 239000000052 vinegar Substances 0.000 description 8
- 235000021419 vinegar Nutrition 0.000 description 8
- 238000012546 transfer Methods 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 5
- 230000001186 cumulative effect Effects 0.000 description 5
- 230000003247 decreasing effect Effects 0.000 description 5
- 229920003244 diene elastomer Polymers 0.000 description 5
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 5
- 238000004898 kneading Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 239000005062 Polybutadiene Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
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- DYXHYSXVVPLQBH-UHFFFAOYSA-N C(C1CCC(C(=O)O)CC1)(=O)O.C(C)(C)(C)OOC(C)(C)C Chemical compound C(C1CCC(C(=O)O)CC1)(=O)O.C(C)(C)(C)OOC(C)(C)C DYXHYSXVVPLQBH-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 3
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- 229920002943 EPDM rubber Polymers 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
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- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
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- FITUHHPILMJZMP-UHFFFAOYSA-N styrene;sulfuric acid Chemical class OS(O)(=O)=O.C=CC1=CC=CC=C1 FITUHHPILMJZMP-UHFFFAOYSA-N 0.000 description 1
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- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
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- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
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- GBABOYUKABKIAF-GHYRFKGUSA-N vinorelbine Chemical compound C1N(CC=2C3=CC=CC=C3NC=22)CC(CC)=C[C@H]1C[C@]2(C(=O)OC)C1=CC([C@]23[C@H]([C@]([C@H](OC(C)=O)[C@]4(CC)C=CCN([C@H]34)CC2)(O)C(=O)OC)N2C)=C2C=C1OC GBABOYUKABKIAF-GHYRFKGUSA-N 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Graft Or Block Polymers (AREA)
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Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW95146960A TW200825130A (en) | 2006-12-15 | 2006-12-15 | The rubber composition of modified polystyrene-based resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW95146960A TW200825130A (en) | 2006-12-15 | 2006-12-15 | The rubber composition of modified polystyrene-based resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200825130A true TW200825130A (en) | 2008-06-16 |
| TWI338018B TWI338018B (enrdf_load_stackoverflow) | 2011-03-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW95146960A TW200825130A (en) | 2006-12-15 | 2006-12-15 | The rubber composition of modified polystyrene-based resin |
Country Status (1)
| Country | Link |
|---|---|
| TW (1) | TW200825130A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103910834A (zh) * | 2012-12-28 | 2014-07-09 | 奇美实业股份有限公司 | 透明橡胶变性苯乙烯系树脂 |
| TWI481655B (zh) * | 2012-12-28 | 2015-04-21 | Chi Mei Corp | 橡膠改質甲基丙烯酸酯系樹脂組成物 |
-
2006
- 2006-12-15 TW TW95146960A patent/TW200825130A/zh unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103910834A (zh) * | 2012-12-28 | 2014-07-09 | 奇美实业股份有限公司 | 透明橡胶变性苯乙烯系树脂 |
| TWI481655B (zh) * | 2012-12-28 | 2015-04-21 | Chi Mei Corp | 橡膠改質甲基丙烯酸酯系樹脂組成物 |
| CN103910834B (zh) * | 2012-12-28 | 2016-09-21 | 奇美实业股份有限公司 | 透明橡胶变性苯乙烯系树脂 |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI338018B (enrdf_load_stackoverflow) | 2011-03-01 |
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