TW200716658A - Control of N-(phosphonomethyl) iminodiacetic acid conversion in manufacture of glyphosate - Google Patents
Control of N-(phosphonomethyl) iminodiacetic acid conversion in manufacture of glyphosateInfo
- Publication number
- TW200716658A TW200716658A TW095111853A TW95111853A TW200716658A TW 200716658 A TW200716658 A TW 200716658A TW 095111853 A TW095111853 A TW 095111853A TW 95111853 A TW95111853 A TW 95111853A TW 200716658 A TW200716658 A TW 200716658A
- Authority
- TW
- Taiwan
- Prior art keywords
- phosphonomethyl
- glyphosate
- control
- iminodiacetic acid
- manufacture
- Prior art date
Links
- 238000006243 chemical reaction Methods 0.000 title abstract 4
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title abstract 4
- 239000005562 Glyphosate Substances 0.000 title abstract 3
- 229940097068 glyphosate Drugs 0.000 title abstract 3
- FDQQNNZKEJIHMS-UHFFFAOYSA-N 3,4,5-trimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1C FDQQNNZKEJIHMS-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- AZIHIQIVLANVKD-UHFFFAOYSA-N N-(phosphonomethyl)iminodiacetic acid Chemical compound OC(=O)CN(CC(O)=O)CP(O)(O)=O AZIHIQIVLANVKD-UHFFFAOYSA-N 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3577—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing liquids, e.g. polluted water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00193—Sensing a parameter
- B01J2219/00195—Sensing a parameter of the reaction system
- B01J2219/00202—Sensing a parameter of the reaction system at the reactor outlet
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N2021/3595—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using FTIR
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/12—Circuits of general importance; Signal processing
- G01N2201/122—Kinetic analysis; determining reaction rate
- G01N2201/1222—Endpoint determination; reaction time determination
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/16—Phosphorus containing
- Y10T436/163333—Organic [e.g., chemical warfare agents, insecticides, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/204998—Inorganic carbon compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/207497—Molecular oxygen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/207497—Molecular oxygen
- Y10T436/209163—Dissolved or trace oxygen or oxygen content of a sealed environment
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Organic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Biophysics (AREA)
- Combustion & Propulsion (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66778305P | 2005-04-01 | 2005-04-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200716658A true TW200716658A (en) | 2007-05-01 |
Family
ID=37027921
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW095111853A TW200716658A (en) | 2005-04-01 | 2006-04-03 | Control of N-(phosphonomethyl) iminodiacetic acid conversion in manufacture of glyphosate |
Country Status (11)
| Country | Link |
|---|---|
| US (5) | US7799571B2 (zh) |
| EP (2) | EP3159348A1 (zh) |
| CN (3) | CN101218242A (zh) |
| AR (3) | AR057271A1 (zh) |
| AU (1) | AU2006232348B2 (zh) |
| BR (1) | BRPI0607713A2 (zh) |
| CA (1) | CA2602200A1 (zh) |
| ES (1) | ES2611305T3 (zh) |
| MX (1) | MX2007012239A (zh) |
| TW (1) | TW200716658A (zh) |
| WO (1) | WO2006107824A2 (zh) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2006220768B2 (en) | 2005-03-04 | 2011-10-13 | Monsanto Technology Llc | Mitigating necrosis in transgenic glyphosate-tolerant cotton plants treated with herbicidal glyphosate formulations |
| ES2611305T3 (es) | 2005-04-01 | 2017-05-08 | Monsanto Technology, Llc | Control de la conversión de ácido N-(fosfonometil)iminodiacético en la fabricación de glifosato |
| US7603351B2 (en) * | 2006-04-19 | 2009-10-13 | Apple Inc. | Semantic reconstruction |
| JP4340814B2 (ja) * | 2007-02-16 | 2009-10-07 | 国立大学法人東京工業大学 | 分光解析装置及び分光解析方法 |
| EP2014641A3 (en) * | 2007-06-06 | 2009-03-18 | Huntsman International Llc | Process for preparing mixtures of diphenylmethane diisocyanates and polyphenyl polymethylene polyisocyanates |
| CN102649799B (zh) * | 2011-02-23 | 2015-02-04 | 重庆紫光化工股份有限公司 | 一种草甘膦的制备方法 |
| BR112015000995B1 (pt) | 2012-07-17 | 2020-04-28 | Monsanto Technology Llc | método para a síntese de n-(fosfonometil)glicina ou um de seus derivados selecionados a partir do grupo que consiste em seus sais, seus ésteres de fosfonato e seus sais de éster de fosfonato |
| US20150232493A1 (en) | 2012-07-17 | 2015-08-20 | Straitmark Holding Ag | Method for the synthesis of alpha-aminoalkylenephosphonic acid |
| CN104854117B (zh) | 2012-07-17 | 2018-12-25 | 孟山都技术有限责任公司 | 用于合成n-膦酰基甲基亚氨基二乙酸的方法 |
| EP2875036A1 (en) | 2012-07-17 | 2015-05-27 | Straitmark Holding AG | Method for the synthesis of aminoalkylenephosphonic acid |
| PL2875034T3 (pl) | 2012-07-17 | 2017-12-29 | Straitmark Holding Ag | Sposób syntezy N-(fosfonometylo)glicyny |
| WO2014031678A1 (en) * | 2012-08-20 | 2014-02-27 | Sabic Innovative Plastics Ip B.V. | Real-time online determination of caustic in process scrubbers using near infrared spectroscopy and chemometrics |
| EP2757088B1 (de) * | 2013-01-22 | 2016-08-03 | Covestro Deutschland AG | Verfahren zur Herstellung von aromatischen Aminen |
| CN104262394B (zh) * | 2014-07-08 | 2016-08-24 | 重庆紫光化工股份有限公司 | 一种双甘膦制备草甘膦的环保清洁生产方法及装置 |
| KR102336227B1 (ko) * | 2014-08-29 | 2021-12-07 | 헨켈 아게 운트 코. 카게아아 | 유기규소 개질된 광개시제 및 그의 광경화성 접착제 조성물 |
| JP6432494B2 (ja) * | 2015-11-30 | 2018-12-05 | オムロン株式会社 | 監視装置、監視システム、監視プログラムおよび記録媒体 |
| US11899417B2 (en) * | 2019-05-02 | 2024-02-13 | Fisher-Rosemount Systems, Inc. | Methods and apparatus to implement predictive analytics for continuous control system processes |
| US20220244171A1 (en) * | 2019-05-22 | 2022-08-04 | bioMérieux | Methods and systems for manufacturing a production assay reactor |
| CN110514608B (zh) * | 2019-08-28 | 2021-08-24 | 浙江工业大学 | 一种基于光谱的反应动力学速率常数的无偏估计方法 |
| CN112129890B (zh) * | 2020-08-17 | 2022-10-25 | 西安近代化学研究所 | 一种准确获得含能材料合成反应过程动力学参数的方法 |
| CN113713685A (zh) * | 2021-09-10 | 2021-11-30 | 镇江江南化工有限公司 | 一种基于数字孪生技术的草甘膦生产设备实时监测系统 |
| CN117723526B (zh) * | 2024-02-04 | 2024-04-12 | 云南伦扬科技有限公司 | 一种单原子纳米酶基荧光探针快速检测草甘膦和镉方法 |
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| US3835000A (en) | 1972-12-21 | 1974-09-10 | Monsanto Co | Electrolytic process for producing n-phosphonomethyl glycine |
| US4624937A (en) | 1984-05-10 | 1986-11-25 | Monsanto Company | Process for removing surface oxides from activated carbon catalyst |
| HU206363B (en) | 1989-04-11 | 1992-10-28 | Alkaloida Vegyeszeti Gyar | Process for selective, complexometric analysis of n-(phosphonomethyl)-glycine, n-(phosphonomethyl)-n-(carboxymethyl)-glycine and n,n-bis (phosphonomethyl)-glycine |
| US5087740A (en) | 1989-08-17 | 1992-02-11 | Monsanto Company | Process for purifying N-phosphonomethylglycine |
| ES2021229A6 (es) | 1990-03-12 | 1991-10-16 | Ercros Sa | Perfeccionamientos introducidos en un procedimiento de obtencion de n-fosfonometilglicina por oxidacion de n-fosfonometiliminodiacetico. |
| US5095140A (en) | 1990-06-25 | 1992-03-10 | Monsanto Company | Peroxide process for producing N-phosphonomethylglycine |
| US5043475A (en) | 1990-06-25 | 1991-08-27 | Monsanto Company | Peroxide process for producing N-phosphonomethylglycine |
| US5077431A (en) | 1990-06-25 | 1991-12-31 | Monsanto Company | Peroxide process for producing n-phosphonomethylglycine |
| US5948938A (en) | 1995-03-07 | 1999-09-07 | Sankyo Company, Limited | Process for preparing N-phosphonomethylglycine |
| US6365772B1 (en) | 1995-05-30 | 2002-04-02 | Hampshire Chemical Corp. | Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid |
| US6232494B1 (en) * | 1998-02-12 | 2001-05-15 | Monsanto Company | Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine |
| US6417133B1 (en) | 1998-02-25 | 2002-07-09 | Monsanto Technology Llc | Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
| US5962729A (en) * | 1998-05-14 | 1999-10-05 | Calgon Carbon Corporation | Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon |
| US5942643A (en) * | 1998-05-14 | 1999-08-24 | Calgon Carbon Corporation | Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a low temperature catalytic carbon |
| DE50004440D1 (de) * | 1999-08-11 | 2003-12-18 | Basf Ag | Verfahren zur herstellung von phosphonomethylglycin |
| EA200200696A1 (ru) | 1999-12-21 | 2003-02-27 | Монсанто Текнолоджи Ллс | Применение дополнительного промотора в сочетании с катализатором, содержащим благородный металл на углеродном носителе, в жидкофазных реакциях окисления |
| EP1676851A3 (en) * | 2000-05-22 | 2009-06-03 | Monsanto Technology, LLC | Reaction systems for making N-(phosphonomethyl) glycine compounds |
| US7013351B2 (en) | 2000-10-02 | 2006-03-14 | Microsoft Corporation | Template architecture and rendering engine for web browser access to databases |
| US6818450B2 (en) * | 2001-05-22 | 2004-11-16 | Monsanto Technology Llc | Use of infrared spectroscopy for on-line process control and endpoint detection |
| AU2003215241B2 (en) | 2002-02-14 | 2008-07-31 | Monsanto Technology Llc | Oxidation catalyst and process for its preparation and process for oxidation using it |
| WO2004002622A1 (en) | 2002-06-28 | 2004-01-08 | Monsanto Technology Llc | Use of tellurium in carbon-supported, noble metal-containing catalysts for liquid phase oxidation reactions |
| MXPA06001800A (es) | 2003-08-14 | 2006-05-04 | Monsanto Technology Llc | Catalizadores que contienen carburo-metal de transicion y nitruro, su preparacion y uso como catalizadores de oxidacion y deshidrogenacion. |
| US7179936B2 (en) | 2003-09-17 | 2007-02-20 | Monsanto Technology Llc | Process for recovering a crystalline product from solution |
| AR051926A1 (es) | 2004-09-15 | 2007-02-21 | Monsanto Technology Llc | Catalizadores de oxidacion, procedimientos de preparacion de dichos catalizadores y proceso para la elaboracion de n-( fosfonometil)glicina o una sal de la misma |
| TW200624151A (en) | 2004-11-12 | 2006-07-16 | Monsanto Technology Llc | Recovery of noble metals from aqueous process streams |
| WO2006089193A2 (en) * | 2005-02-17 | 2006-08-24 | Monsanto Technology Llc | Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts |
| AU2006220768B2 (en) * | 2005-03-04 | 2011-10-13 | Monsanto Technology Llc | Mitigating necrosis in transgenic glyphosate-tolerant cotton plants treated with herbicidal glyphosate formulations |
| ES2611305T3 (es) | 2005-04-01 | 2017-05-08 | Monsanto Technology, Llc | Control de la conversión de ácido N-(fosfonometil)iminodiacético en la fabricación de glifosato |
-
2006
- 2006-04-03 ES ES06749127.4T patent/ES2611305T3/es active Active
- 2006-04-03 CN CNA200680019755XA patent/CN101218242A/zh active Pending
- 2006-04-03 AU AU2006232348A patent/AU2006232348B2/en not_active Expired - Fee Related
- 2006-04-03 CN CN202010122645.8A patent/CN111393474A/zh active Pending
- 2006-04-03 MX MX2007012239A patent/MX2007012239A/es unknown
- 2006-04-03 EP EP16188426.7A patent/EP3159348A1/en active Pending
- 2006-04-03 EP EP06749127.4A patent/EP1863824B1/en active Active
- 2006-04-03 AR ARP060101315A patent/AR057271A1/es active IP Right Grant
- 2006-04-03 CN CN201510124742.XA patent/CN104829648A/zh active Pending
- 2006-04-03 WO PCT/US2006/012214 patent/WO2006107824A2/en active Application Filing
- 2006-04-03 BR BRPI0607713-7A patent/BRPI0607713A2/pt not_active Application Discontinuation
- 2006-04-03 CA CA002602200A patent/CA2602200A1/en not_active Abandoned
- 2006-04-03 US US11/910,146 patent/US7799571B2/en active Active
- 2006-04-03 TW TW095111853A patent/TW200716658A/zh unknown
-
2010
- 2010-09-17 US US12/884,289 patent/US9409935B2/en active Active
-
2016
- 2016-06-30 US US15/198,188 patent/US11067502B2/en active Active
- 2016-10-14 AR ARP160103142A patent/AR106350A2/es unknown
- 2016-10-14 AR ARP160103141A patent/AR106349A2/es unknown
-
2021
- 2021-06-15 US US17/348,250 patent/US11802835B2/en active Active
-
2023
- 2023-09-22 US US18/371,627 patent/US20240094120A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU2006232348B2 (en) | 2010-11-25 |
| AR106349A2 (es) | 2018-01-03 |
| US11067502B2 (en) | 2021-07-20 |
| US11802835B2 (en) | 2023-10-31 |
| US9409935B2 (en) | 2016-08-09 |
| EP1863824A2 (en) | 2007-12-12 |
| AR057271A1 (es) | 2007-11-28 |
| CN101218242A (zh) | 2008-07-09 |
| US20090011515A1 (en) | 2009-01-08 |
| EP1863824B1 (en) | 2016-10-19 |
| AU2006232348A1 (en) | 2006-10-12 |
| US20160370330A1 (en) | 2016-12-22 |
| BRPI0607713A2 (pt) | 2009-09-22 |
| ES2611305T3 (es) | 2017-05-08 |
| US20240094120A1 (en) | 2024-03-21 |
| CA2602200A1 (en) | 2006-10-12 |
| US7799571B2 (en) | 2010-09-21 |
| CN111393474A (zh) | 2020-07-10 |
| US20110097810A1 (en) | 2011-04-28 |
| EP3159348A1 (en) | 2017-04-26 |
| AR106350A2 (es) | 2018-01-03 |
| MX2007012239A (es) | 2007-12-07 |
| WO2006107824A2 (en) | 2006-10-12 |
| CN104829648A (zh) | 2015-08-12 |
| US20210381962A1 (en) | 2021-12-09 |
| WO2006107824A3 (en) | 2007-02-22 |
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