AR106350A2 - Control de la conversión de ácido n-(fosfonometil)iminodiacético en la fabricación de glifosato - Google Patents
Control de la conversión de ácido n-(fosfonometil)iminodiacético en la fabricación de glifosatoInfo
- Publication number
- AR106350A2 AR106350A2 ARP160103142A ARP160103142A AR106350A2 AR 106350 A2 AR106350 A2 AR 106350A2 AR P160103142 A ARP160103142 A AR P160103142A AR P160103142 A ARP160103142 A AR P160103142A AR 106350 A2 AR106350 A2 AR 106350A2
- Authority
- AR
- Argentina
- Prior art keywords
- phosphonomethyl
- iminodiacetic acid
- glycine
- oxidation
- phosphonometil
- Prior art date
Links
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title abstract 6
- 238000006243 chemical reaction Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000005562 Glyphosate Substances 0.000 title 1
- 229940097068 glyphosate Drugs 0.000 title 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 title 1
- FDQQNNZKEJIHMS-UHFFFAOYSA-N 3,4,5-trimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1C FDQQNNZKEJIHMS-UHFFFAOYSA-N 0.000 abstract 7
- 238000007254 oxidation reaction Methods 0.000 abstract 5
- 230000003647 oxidation Effects 0.000 abstract 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 abstract 2
- 239000012431 aqueous reaction media Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000004471 Glycine Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- -1 phosphonomethyl Chemical group 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3577—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing liquids, e.g. polluted water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00193—Sensing a parameter
- B01J2219/00195—Sensing a parameter of the reaction system
- B01J2219/00202—Sensing a parameter of the reaction system at the reactor outlet
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N2021/3595—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using FTIR
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/12—Circuits of general importance; Signal processing
- G01N2201/122—Kinetic analysis; determining reaction rate
- G01N2201/1222—Endpoint determination; reaction time determination
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/16—Phosphorus containing
- Y10T436/163333—Organic [e.g., chemical warfare agents, insecticides, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/204998—Inorganic carbon compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/207497—Molecular oxygen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/207497—Molecular oxygen
- Y10T436/209163—Dissolved or trace oxygen or oxygen content of a sealed environment
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Organic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Biophysics (AREA)
- Combustion & Propulsion (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Reivindicación 1: Un proceso para preparar N-(fosfonometil)glicina que comprende la oxidación de ácido N-(fosfonometil)iminodiacético o una sal del mismo, caracterizado porque dicho proceso comprende: poner en contacto ácido N-(fosfonometil)iminodiacético con un agente oxidante en un medio de reacción acuoso dentro de una zona de reacción de oxidación en presencia de un catalizador de oxidación, para efectuar de esa manera la oxidación de ácido N-(fosfonometil)iminodiacético y producir una solución de reacción que comprende N-(fosfonometil)glicina u otro intermediario que se puede convertir a N-(fosfonometil)glicina; y seguir tratando dicha solución de reacción para obtener un producto N-(fosfonometil)glicina que no contiene más de aproximadamente 600 ppm de ácido N-(fosfonometil)iminodiacético o una sal del mismo; donde la oxidación de ácido N-(fosfonometil)iminodiacético en dicho medio de reacción acuoso se continúa hasta que la concentración de ácido N-(fosfonometil)iminodiacético en dicho medio de reacción se haya reducido hasta una concentración terminal de tal manera que dicho tratamiento adicional rinde un producto N-(fosfonometil)glicina con un contenido de ácido N-(fosfonometil)iminodiacético no mayor de aproximadamente 600 ppm en peso, en base a la N-(fosfonometil)glicina.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US66778305P | 2005-04-01 | 2005-04-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR106350A2 true AR106350A2 (es) | 2018-01-03 |
Family
ID=37027921
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP060101315A AR057271A1 (es) | 2005-04-01 | 2006-04-03 | Control de la conversion de acido n-(fosfonometil)iminodiacetico en la elaboracion de glifosato |
ARP160103142A AR106350A2 (es) | 2005-04-01 | 2016-10-14 | Control de la conversión de ácido n-(fosfonometil)iminodiacético en la fabricación de glifosato |
ARP160103141A AR106349A2 (es) | 2005-04-01 | 2016-10-14 | Control de la conversión de ácido n-(fosfonometil)iminodiacético en la fabricación de glifosato |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP060101315A AR057271A1 (es) | 2005-04-01 | 2006-04-03 | Control de la conversion de acido n-(fosfonometil)iminodiacetico en la elaboracion de glifosato |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP160103141A AR106349A2 (es) | 2005-04-01 | 2016-10-14 | Control de la conversión de ácido n-(fosfonometil)iminodiacético en la fabricación de glifosato |
Country Status (11)
Country | Link |
---|---|
US (5) | US7799571B2 (es) |
EP (2) | EP3159348A1 (es) |
CN (3) | CN101218242A (es) |
AR (3) | AR057271A1 (es) |
AU (1) | AU2006232348B2 (es) |
BR (1) | BRPI0607713A2 (es) |
CA (1) | CA2602200A1 (es) |
ES (1) | ES2611305T3 (es) |
MX (1) | MX2007012239A (es) |
TW (1) | TW200716658A (es) |
WO (1) | WO2006107824A2 (es) |
Families Citing this family (22)
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WO2006096617A2 (en) | 2005-03-04 | 2006-09-14 | Monsanto Technology Llc | Mitigating necrosis in transgenic glyphosate-tolerant cotton plants treated with herbicidal glyphosate formulations |
CN101218242A (zh) | 2005-04-01 | 2008-07-09 | 孟山都技术公司 | 在草甘膦的生产中对n-(膦酰甲基)亚氨基二乙酸转化率的控制 |
US7603351B2 (en) * | 2006-04-19 | 2009-10-13 | Apple Inc. | Semantic reconstruction |
EP2112498B1 (en) * | 2007-02-16 | 2015-03-11 | Tokyo Institute of Technology | Spectroscopic analyzing device and spectroscopic analyzing method |
EP2014641A3 (en) * | 2007-06-06 | 2009-03-18 | Huntsman International Llc | Process for preparing mixtures of diphenylmethane diisocyanates and polyphenyl polymethylene polyisocyanates |
CN102649799B (zh) * | 2011-02-23 | 2015-02-04 | 重庆紫光化工股份有限公司 | 一种草甘膦的制备方法 |
CN104812765B (zh) | 2012-07-17 | 2017-06-06 | 斯特雷特马克控股股份公司 | 用于合成α‑氨基亚烷基膦酸的方法 |
EP2875036A1 (en) | 2012-07-17 | 2015-05-27 | Straitmark Holding AG | Method for the synthesis of aminoalkylenephosphonic acid |
WO2014012986A1 (en) | 2012-07-17 | 2014-01-23 | Straitmark Holding Ag | Method for the synthesis of n-phosphonomethyliminodiacetic acid |
EP2875037B1 (en) | 2012-07-17 | 2016-09-07 | Straitmark Holding AG | Method for the synthesis of n-(phosphonomethyl)glycine |
PL2875034T3 (pl) | 2012-07-17 | 2017-12-29 | Straitmark Holding Ag | Sposób syntezy N-(fosfonometylo)glicyny |
KR101970807B1 (ko) * | 2012-08-20 | 2019-04-19 | 사빅 글로벌 테크놀러지스 비.브이. | 근적외선 분광법 및 케모메트릭스를 이용한 공정 스크러버 내의 부식제의 실시간 온라인 결정 |
EP2757088B1 (de) * | 2013-01-22 | 2016-08-03 | Covestro Deutschland AG | Verfahren zur Herstellung von aromatischen Aminen |
CN104262393B (zh) * | 2014-07-08 | 2017-01-11 | 重庆紫光化工股份有限公司 | 一种草甘膦的节能清洁生产方法及装置 |
ES2805524T3 (es) * | 2014-08-29 | 2021-02-12 | Henkel Ag & Co Kgaa | Fotoiniciador modificado con organosilicio y composición adhesiva fotocurable del mismo |
JP6432494B2 (ja) * | 2015-11-30 | 2018-12-05 | オムロン株式会社 | 監視装置、監視システム、監視プログラムおよび記録媒体 |
US11899417B2 (en) * | 2019-05-02 | 2024-02-13 | Fisher-Rosemount Systems, Inc. | Methods and apparatus to implement predictive analytics for continuous control system processes |
WO2020234617A1 (en) * | 2019-05-22 | 2020-11-26 | Biomerieux | Methods and systems for manufacturing a production assay reactor |
CN110514608B (zh) * | 2019-08-28 | 2021-08-24 | 浙江工业大学 | 一种基于光谱的反应动力学速率常数的无偏估计方法 |
CN112129890B (zh) * | 2020-08-17 | 2022-10-25 | 西安近代化学研究所 | 一种准确获得含能材料合成反应过程动力学参数的方法 |
CN113713685A (zh) * | 2021-09-10 | 2021-11-30 | 镇江江南化工有限公司 | 一种基于数字孪生技术的草甘膦生产设备实时监测系统 |
CN117723526B (zh) * | 2024-02-04 | 2024-04-12 | 云南伦扬科技有限公司 | 一种单原子纳米酶基荧光探针快速检测草甘膦和镉方法 |
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US5087740A (en) | 1989-08-17 | 1992-02-11 | Monsanto Company | Process for purifying N-phosphonomethylglycine |
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US5095140A (en) | 1990-06-25 | 1992-03-10 | Monsanto Company | Peroxide process for producing N-phosphonomethylglycine |
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US5948938A (en) | 1995-03-07 | 1999-09-07 | Sankyo Company, Limited | Process for preparing N-phosphonomethylglycine |
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US5962729A (en) * | 1998-05-14 | 1999-10-05 | Calgon Carbon Corporation | Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon |
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CA2395206A1 (en) | 1999-12-21 | 2001-06-28 | Monsanto Technology Llc | Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal-containing catalyst in liquid phase oxidation reactions |
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US6818450B2 (en) * | 2001-05-22 | 2004-11-16 | Monsanto Technology Llc | Use of infrared spectroscopy for on-line process control and endpoint detection |
CA2476255C (en) | 2002-02-14 | 2012-07-31 | Monsanto Technology Llc | Oxidation catalyst and process for its preparation and process for oxidation using it |
AR040319A1 (es) | 2002-06-28 | 2005-03-23 | Monsanto Technology Llc | Uso de telurio en catalizadores con contenido de metales nobles y con soporte de carbon para reacciones de oxidacion en fase liquida |
ES2407031T3 (es) * | 2003-08-14 | 2013-06-11 | Monsanto Technology Llc | Procedimiento para la oxidación del ácido N-(fosfonometil)iminodiacético o de una de sus sales |
US7179936B2 (en) | 2003-09-17 | 2007-02-20 | Monsanto Technology Llc | Process for recovering a crystalline product from solution |
WO2006031938A2 (en) | 2004-09-15 | 2006-03-23 | Monsanto Technology Llc | Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
TW200624151A (en) | 2004-11-12 | 2006-07-16 | Monsanto Technology Llc | Recovery of noble metals from aqueous process streams |
AU2006214086B2 (en) | 2005-02-17 | 2012-01-19 | Monsanto Technology Llc | Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts |
WO2006096617A2 (en) * | 2005-03-04 | 2006-09-14 | Monsanto Technology Llc | Mitigating necrosis in transgenic glyphosate-tolerant cotton plants treated with herbicidal glyphosate formulations |
CN101218242A (zh) | 2005-04-01 | 2008-07-09 | 孟山都技术公司 | 在草甘膦的生产中对n-(膦酰甲基)亚氨基二乙酸转化率的控制 |
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2006
- 2006-04-03 CN CNA200680019755XA patent/CN101218242A/zh active Pending
- 2006-04-03 AR ARP060101315A patent/AR057271A1/es active IP Right Grant
- 2006-04-03 CN CN202010122645.8A patent/CN111393474A/zh active Pending
- 2006-04-03 EP EP16188426.7A patent/EP3159348A1/en active Pending
- 2006-04-03 WO PCT/US2006/012214 patent/WO2006107824A2/en active Application Filing
- 2006-04-03 AU AU2006232348A patent/AU2006232348B2/en not_active Expired - Fee Related
- 2006-04-03 ES ES06749127.4T patent/ES2611305T3/es active Active
- 2006-04-03 CN CN201510124742.XA patent/CN104829648A/zh active Pending
- 2006-04-03 US US11/910,146 patent/US7799571B2/en active Active
- 2006-04-03 MX MX2007012239A patent/MX2007012239A/es unknown
- 2006-04-03 EP EP06749127.4A patent/EP1863824B1/en active Active
- 2006-04-03 TW TW095111853A patent/TW200716658A/zh unknown
- 2006-04-03 CA CA002602200A patent/CA2602200A1/en not_active Abandoned
- 2006-04-03 BR BRPI0607713-7A patent/BRPI0607713A2/pt not_active Application Discontinuation
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2010
- 2010-09-17 US US12/884,289 patent/US9409935B2/en active Active
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2016
- 2016-06-30 US US15/198,188 patent/US11067502B2/en active Active
- 2016-10-14 AR ARP160103142A patent/AR106350A2/es unknown
- 2016-10-14 AR ARP160103141A patent/AR106349A2/es unknown
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2021
- 2021-06-15 US US17/348,250 patent/US11802835B2/en active Active
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2023
- 2023-09-22 US US18/371,627 patent/US20240094120A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
US20160370330A1 (en) | 2016-12-22 |
AR106349A2 (es) | 2018-01-03 |
AU2006232348A1 (en) | 2006-10-12 |
WO2006107824A3 (en) | 2007-02-22 |
US20240094120A1 (en) | 2024-03-21 |
TW200716658A (en) | 2007-05-01 |
US20210381962A1 (en) | 2021-12-09 |
EP1863824A2 (en) | 2007-12-12 |
ES2611305T3 (es) | 2017-05-08 |
CN101218242A (zh) | 2008-07-09 |
AR057271A1 (es) | 2007-11-28 |
US11802835B2 (en) | 2023-10-31 |
CN111393474A (zh) | 2020-07-10 |
BRPI0607713A2 (pt) | 2009-09-22 |
EP1863824B1 (en) | 2016-10-19 |
EP3159348A1 (en) | 2017-04-26 |
US20110097810A1 (en) | 2011-04-28 |
WO2006107824A2 (en) | 2006-10-12 |
US7799571B2 (en) | 2010-09-21 |
CA2602200A1 (en) | 2006-10-12 |
CN104829648A (zh) | 2015-08-12 |
US20090011515A1 (en) | 2009-01-08 |
US11067502B2 (en) | 2021-07-20 |
MX2007012239A (es) | 2007-12-07 |
US9409935B2 (en) | 2016-08-09 |
AU2006232348B2 (en) | 2010-11-25 |
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