TW200709849A - Heterogeneous ruthenium catalyst and process for hydrogenating a carbocyclic aromatic group, in particular for preparing ring-hydrogenated bisglycidyl ethers of bisphenols a and F - Google Patents
Heterogeneous ruthenium catalyst and process for hydrogenating a carbocyclic aromatic group, in particular for preparing ring-hydrogenated bisglycidyl ethers of bisphenols a and FInfo
- Publication number
- TW200709849A TW200709849A TW095122512A TW95122512A TW200709849A TW 200709849 A TW200709849 A TW 200709849A TW 095122512 A TW095122512 A TW 095122512A TW 95122512 A TW95122512 A TW 95122512A TW 200709849 A TW200709849 A TW 200709849A
- Authority
- TW
- Taiwan
- Prior art keywords
- ruthenium catalyst
- hydrogenating
- aromatic group
- bisphenols
- carbocyclic aromatic
- Prior art date
Links
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 3
- 229910052707 ruthenium Inorganic materials 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 title 1
- 229930185605 Bisphenol Natural products 0.000 title 1
- 150000002170 ethers Chemical class 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000002837 carbocyclic group Chemical group 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000003303 ruthenium Chemical class 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/28—Ethers with hydroxy compounds containing oxirane rings
- C07D303/30—Ethers of oxirane-containing polyhydroxy compounds in which all hydroxyl radicals are etherified with oxirane-containing hydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/394—Metal dispersion value, e.g. percentage or fraction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/638—Pore volume more than 1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005029294A DE102005029294A1 (de) | 2005-06-22 | 2005-06-22 | Ruthenium-Heterogenkatalysator und Verfahren zur Hydrierung einer carbocyclischen aromatischen Gruppe, insbesondere zur Herstellung von kernhydrierten Bisglycidylethern der Bisphenole A und F |
| DE102006002180A DE102006002180A1 (de) | 2006-01-16 | 2006-01-16 | Ruthenium-Heterogenkatalysator und Verfahren zur Hydrierung einer carbocyclischen aromatischen Gruppe, insbesondere zur Herstellung von kernhydrierten Bisglycidylethern der Bisphenole A und F |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200709849A true TW200709849A (en) | 2007-03-16 |
Family
ID=37057387
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW095122512A TW200709849A (en) | 2005-06-22 | 2006-06-22 | Heterogeneous ruthenium catalyst and process for hydrogenating a carbocyclic aromatic group, in particular for preparing ring-hydrogenated bisglycidyl ethers of bisphenols a and F |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20080200703A1 (zh) |
| EP (1) | EP1896174A1 (zh) |
| JP (1) | JP2008543551A (zh) |
| TW (1) | TW200709849A (zh) |
| WO (1) | WO2006136569A1 (zh) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9084983B2 (en) | 2009-12-15 | 2015-07-21 | Basf Se | Catalyst and process for hydrogenating aromatics |
| ITMI20110735A1 (it) * | 2011-05-03 | 2012-11-04 | Industrie De Nora Spa | Elettrodo per processi elettrolitici e metodo per il suo ottenimento |
| WO2014046009A1 (ja) * | 2012-09-21 | 2014-03-27 | Ｊｘ日鉱日石エネルギー株式会社 | フィッシャー・トロプシュ合成用触媒及びその製造方法、並びに炭化水素の製造方法 |
| CN111032214B (zh) * | 2017-09-01 | 2024-02-06 | 恩亿凯嘉股份有限公司 | 核氢化反应用催化剂 |
| CN114602463B (zh) * | 2022-04-13 | 2023-12-05 | 宏业生物科技股份有限公司 | 一种对羟基苯甲酸乙酯加氢催化剂及其制备方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3336241A (en) * | 1963-11-12 | 1967-08-15 | Shell Oil Co | Process for preparing epoxy compounds and resulting products |
| US6248924B1 (en) * | 1996-06-19 | 2001-06-19 | Basf Aktiengesellschaft | Process for reacting an organic compound in the presence of a supported ruthenium catalyst |
| DE19832087A1 (de) * | 1998-07-16 | 2000-01-20 | Basf Ag | Verfahren zur Umsetzung von organischen Verbindungen mit boroxidhaltigen, makroporösen Trägerkatalysatoren |
| JP4792570B2 (ja) * | 1999-12-08 | 2011-10-12 | ダウ、グローバル、テクノロジーズ、リミテッド、ライアビリティー、カンパニー | 不飽和ポリマー特に芳香族ポリマーを水素化する方法 |
| US7452844B2 (en) * | 2001-05-08 | 2008-11-18 | Süd-Chemie Inc | High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis |
| DE10128204A1 (de) * | 2001-06-11 | 2002-12-12 | Basf Ag | Verfahren zur Herstellung von cycloaliphatischen Verbindungen I, die Seitenketten mit Epoxidgruppen aufweisen |
| ATE422962T1 (de) * | 2002-05-31 | 2009-03-15 | Evonik Degussa Gmbh | Geträgerter rutheniumkatalysator und verfahren zur hydrierung eines aromatischen amins in gegenwart dieses katalysators |
| DE10253802A1 (de) * | 2002-11-18 | 2004-06-03 | Degussa Ag | Verfahren zur Hydrierung von aromatischen Urethanen in Gegenwart eines geträgerten Rutheniumkatalysators |
| EP1699557A1 (de) * | 2003-12-22 | 2006-09-13 | Basf Aktiengesellschaft | Ruthenium-heterogenkatalysator, verfahren zur hydrierung einer carbocyclischen aromatischen gruppe und kernhydrierte bisglycidylether der bisphenole a und f |
| DE10361157A1 (de) * | 2003-12-22 | 2005-07-21 | Basf Ag | Ruthenium-Heterogenkatalysator und Verfahren zur Herstellung eines Bisglycidylethers der Formel I |
-
2006
- 2006-06-21 WO PCT/EP2006/063380 patent/WO2006136569A1/de not_active Application Discontinuation
- 2006-06-21 US US11/917,635 patent/US20080200703A1/en not_active Abandoned
- 2006-06-21 EP EP06777381A patent/EP1896174A1/de not_active Withdrawn
- 2006-06-21 JP JP2008517492A patent/JP2008543551A/ja not_active Withdrawn
- 2006-06-22 TW TW095122512A patent/TW200709849A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006136569A9 (de) | 2007-02-22 |
| WO2006136569A1 (de) | 2006-12-28 |
| JP2008543551A (ja) | 2008-12-04 |
| US20080200703A1 (en) | 2008-08-21 |
| EP1896174A1 (de) | 2008-03-12 |
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