TW200540264A - Zero to low voc glass and general purpose cleaner - Google Patents
Zero to low voc glass and general purpose cleaner Download PDFInfo
- Publication number
- TW200540264A TW200540264A TW094111326A TW94111326A TW200540264A TW 200540264 A TW200540264 A TW 200540264A TW 094111326 A TW094111326 A TW 094111326A TW 94111326 A TW94111326 A TW 94111326A TW 200540264 A TW200540264 A TW 200540264A
- Authority
- TW
- Taiwan
- Prior art keywords
- solvent
- cleaning composition
- surface cleaning
- hard surface
- item
- Prior art date
Links
- 239000011521 glass Substances 0.000 title abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 74
- 238000004140 cleaning Methods 0.000 claims abstract description 56
- 239000002904 solvent Substances 0.000 claims abstract description 35
- 239000004094 surface-active agent Substances 0.000 claims abstract description 26
- 239000008365 aqueous carrier Substances 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 239000003960 organic solvent Substances 0.000 claims abstract 8
- 239000012855 volatile organic compound Substances 0.000 claims description 50
- -1 non-ionic Chemical group 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000006184 cosolvent Substances 0.000 claims description 14
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical group CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 claims description 12
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- 239000002280 amphoteric surfactant Substances 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 5
- 244000060011 Cocos nucifera Species 0.000 claims description 5
- 229920006243 acrylic copolymer Polymers 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000000129 anionic group Chemical group 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 125000002091 cationic group Chemical group 0.000 claims description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical group CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- IUJKKCRARYRWFG-UHFFFAOYSA-N 4-[7-(4-carbamimidoylphenoxy)heptoxy]benzenecarboximidamide Chemical group C1=CC(C(=N)N)=CC=C1OCCCCCCCOC1=CC=C(C(N)=N)C=C1 IUJKKCRARYRWFG-UHFFFAOYSA-N 0.000 claims 1
- 229940126062 Compound A Drugs 0.000 claims 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims 1
- 239000004067 bulking agent Substances 0.000 claims 1
- 238000003776 cleavage reaction Methods 0.000 claims 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims 1
- 230000001815 facial effect Effects 0.000 claims 1
- 210000003205 muscle Anatomy 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 230000007017 scission Effects 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 10
- 239000003086 colorant Substances 0.000 description 10
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- 239000000908 ammonium hydroxide Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 239000008234 soft water Substances 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- 235000013772 propylene glycol Nutrition 0.000 description 6
- 101150076749 C10L gene Proteins 0.000 description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000002671 adjuvant Substances 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 2
- OXQGTIUCKGYOAA-UHFFFAOYSA-N 2-Ethylbutanoic acid Chemical compound CCC(CC)C(O)=O OXQGTIUCKGYOAA-UHFFFAOYSA-N 0.000 description 2
- WFSMVVDJSNMRAR-UHFFFAOYSA-N 2-[2-(2-ethoxyethoxy)ethoxy]ethanol Chemical compound CCOCCOCCOCCO WFSMVVDJSNMRAR-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical group [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical compound CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- HRQDCDQDOPSGBR-UHFFFAOYSA-M sodium;octane-1-sulfonate Chemical compound [Na+].CCCCCCCCS([O-])(=O)=O HRQDCDQDOPSGBR-UHFFFAOYSA-M 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 1
- MQVBKQCAXKLACB-UHFFFAOYSA-N 1-pentoxypropan-2-ol Chemical compound CCCCCOCC(C)O MQVBKQCAXKLACB-UHFFFAOYSA-N 0.000 description 1
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- CKCGJBFTCUCBAJ-UHFFFAOYSA-N 2-(2-ethoxypropoxy)propyl acetate Chemical compound CCOC(C)COC(C)COC(C)=O CKCGJBFTCUCBAJ-UHFFFAOYSA-N 0.000 description 1
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 1
- GOHZKUSWWGUUNR-UHFFFAOYSA-N 2-(4,5-dihydroimidazol-1-yl)ethanol Chemical compound OCCN1CCN=C1 GOHZKUSWWGUUNR-UHFFFAOYSA-N 0.000 description 1
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 1
- MSKPOTMPSSAFKF-UHFFFAOYSA-N 2-aminoethanol;propane-1,2-diol Chemical compound NCCO.CC(O)CO MSKPOTMPSSAFKF-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- OQQMLOABWOWXKW-UHFFFAOYSA-N C(C1=CC=CC=C1)(=O)OCCCCCCCCCCCC.[Na] Chemical compound C(C1=CC=CC=C1)(=O)OCCCCCCCCCCCC.[Na] OQQMLOABWOWXKW-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000922 anti-bactericidal effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 125000005588 carbonic acid salt group Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000013527 degreasing agent Substances 0.000 description 1
- 238000005237 degreasing agent Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- NADLFKPLFQRHBN-UHFFFAOYSA-N ethane-1,2-diol;2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound OCCO.CC(O)COC(C)COC(C)CO NADLFKPLFQRHBN-UHFFFAOYSA-N 0.000 description 1
- XTEBISFIAYHLQY-UHFFFAOYSA-N ethene;2-(2-hydroxyethoxy)ethanol Chemical compound C=C.OCCOCCO XTEBISFIAYHLQY-UHFFFAOYSA-N 0.000 description 1
- 150000002171 ethylene diamines Chemical class 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000008379 phenol ethers Chemical class 0.000 description 1
- LHRDPNCJODOVFS-UHFFFAOYSA-N phenyl sulfo sulfate Chemical compound OS(=O)(=O)OS(=O)(=O)OC1=CC=CC=C1 LHRDPNCJODOVFS-UHFFFAOYSA-N 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- AGFPRHALNHTGLS-UHFFFAOYSA-N propane-1,2-diol;prop-1-ene Chemical compound CC=C.CC=C.CC(O)CO AGFPRHALNHTGLS-UHFFFAOYSA-N 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- NQGYKBYMGGHSSJ-UHFFFAOYSA-N trimethyl(octan-4-yl)azanium Chemical compound C[N+](C(CCCC)CCC)(C)C NQGYKBYMGGHSSJ-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 230000001755 vocal effect Effects 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Description
200540264 九、發明說明： C考务日月戶斤才支冬"1^々貝3 發明領域 本發明論及用於清潔硬表面的組成物，該等硬表面包 5 含玻璃表面。该專組成物含有從不含至一種或多種僅含低 量的揮發有機化合物(VOCs)。 C先前#支冬好】
發明背景 理想地，玻璃及一般用途清潔組成物具有良好的清潔特 10性，該等特性包含良好的清潔力、可蒸發性以及無條痕或模 糊。一般，玻璃及一般用途清潔劑視醇、含高量揮發性乙二 醇_、含低量揮發性乙二_以及界面活性劑之組合的使用 而定以獲得清潔以及可接受的乾燥速率。醇、含高量揮發性 乙二醇醚(諸如在習知化學式中所使用者）分成v〇Cs類而如 15 在本發明中有用之含低量揮發性乙二_以及界面活性劑 係被分成非VQCs類。因此，非鞭溶劑係被稱為含低㈣ 發性非資溶劑。而到目前為止，存在的政府環境條例允許 玻璃及-般用途清潔劑在配方中具有—6%v〇Cs的最大 值，非常低V〇C位準為所欲的，正如在2004年12月31日之 後，加州制定規章將在此等配方中改變至只允許―彻⑽ 的最大值所證實的。含歸以含V()c位準補對環境將為 有利的而且造成顯著的節約成本，因為揮發性有機化合物的 =:增加花費。為此問題形成一種不含或含低量揮發 性同_有可接受的清紅乾燥速率之清潔組成物。 20 200540264 【發明内容】 發明概要 因此，本發明的一主要目的為形成一種不含至含低量 揮發性有機化合物(VOC)含量同時具有可接受的清潔以及 5 乾燥速率之玻璃及一般用途清潔組成物。
進一步的主要目的為形成一種提供無條痕清潔以及可 接受的乾燥速率同時包含從不含至含低量，即〇至大約4% 以重量計VOCs，之特性的清潔組成物。 進一步的主要目的為形成一種玻璃及一般用途清潔組 10 成物，該組成物形成沒有揮發性有機化合物尤其是醇之可 接受的清潔以及乾燥速率。 本發明之玻璃及一般用途清潔組成物具有作為一蒸發性 溶劑之從大於〇至大約3 0 %以重量計的至少一種低揮發性非 V0C有機化合物以及從0至大約4%以重量計的一種或多種 15 V0C溶劑。該等溶劑用來達到清潔以可接受的乾燥速率二者。 本發明的清潔組成物包含一種水性載體、一種或多種 低揮發非V0C有機蒸發性溶劑、一種或多種界面活性劑、 任擇地一種或多種助溶劑以及任擇地一種或多種輔助劑 (諸如pH值調節劑、著色劑、香料、聚結劑以及諸如此類）。 20 較佳地，該等組分係被包含於在下列範圍内··大約大於〇至 大約20%以重量計之該一種或多種含低量揮發性非V0C蒸 發性溶劑、大約大於〇至大約1 〇%以重量計之該一種或多種 界面活性劑、大約50至大約99.9%以重量計之該水性載體、 從0至大約3 0 %以重量計之一種或多種助溶劑以及從0至大 200540264 約5%以重量計之-種或多種辅助劑，該㈣”B 常大約。至大約0·5%以重量計著色劑、大約。至大約二 量計香料 '大約0至大約2%以重量計聚結劑以及。 5 10 15 20 組成物中以形成一大約2至大約13ΡΗ值的师調°〜 本發明的清潔組成物作為一種一般表面清潔^ 菌性清_、低TOC脫脂劑、脂4浮餘淨劑、= 劑以及諸如此_有用的。該清潔組成物可藉岣知= 作為-種濃縮物就是呈—種準備好使㈣稀釋 = (諸如以液體、噴霧、霧劑或凝膠形峨分散。作為2 料，該=物可在使用時藉由，，如，在―水桶中與: 代匕合或水管端使用而被稀釋。 ’、 C實施方式】 較佳實施例之詳細說明 本發明之麵及_般用途清潔 ，非V〇C蒸發性溶劑(諸如低揮發非 清潔劑之一種或多種界面活性劑以及一;二為 擇地有至二—本^同於低揮發非VGC蒸發性溶劑二溶^ 小於聽之㈣==非rc蒸發性溶劑在水中具有 於40達因/公分。界 4組成物的表面張力減少至小 陰離子、_子、，_=劑較佳料低條痕且可為兩性、 及任擇的助溶•作用:或其等之混合物。界面活性劑以 該組成物巾的組分良如=㈣料亦提供其他存在於 ^合解化作用。本發明的清潔組成 7 200540264 物具有一從〇至大約以重量計之V〇C含量，較佳地，從 、、句〇至大約1%以重量計、更佳地從大約〇至大約0.5%以重 里计且最佳地大約0以重量計。 低揮發非voc蒸發性溶劑較佳地為非v〇C乙二醇醚。 5此供給無條痕清潔。適合在本發明之組成物中使用的祚 V〇C乙二醇醚包含那些具有一化學式如下者：
Rr0-R2 其中R]為任擇地由-OH、-〇CH3或·〇αί2(：Η3所取代之一Cr Cs線性、分枝或環狀烷基或鏈烯基；以及R2為由-OH所取代 之— 線性、分枝或環狀烷基或鏈烯基。 幸父佳地’ R〗為一任擇地經取代之^-(^烷基或鏈烯基， 以及R2為一經單取代的仏'*線性或分枝烷基或鏈烯基。 更佳地，R]為一未經取代或經單取代之線性或分枝的 C3<6燒基，以及反2為一經單取代的C2_C4線性或分枝烷基。 5 最佳地，Rl為一未經取代正-C3-C4或正-C6線性烷基或 - CH2CHCH3，
OH 以及R2為-CH2CH2OH或 -ch2chch,，
I
OH 合適的非voc乙二醇醚包含三聚丙烯乙二醇正_丙基 20醚、乙二醇正己醚、二甘醇正-己基醚、二丙二醇正-丁基醚、 二丙二醇正-丁基醚以及丙二醇戊基醚。 包含於清潔組成物中之較佳的非V0C6二醇醚為乙二 8 200540264 醇正己醚，亦被通稱為己基溶纖劑。 =他適合於作為低揮發請c蒸發性溶劑❹的化八 物包含但不被限制於非v〇c乙二_ 其他在水中呈有限.、办紐南 夕兀醇、胺或 5 10 15 用來將η Γ 即低於20%’之有機化合物且 括上非voc蒸發性溶劑的特定另外實施例包 =(=來將水組成物的表面張力減至細達因/ 土 ，己一醇（辛二醇）、-甘gj、· 限溶解度，即低於胺“及(3)在水… 較佳地，低揮發非V0C蒸發性溶劑係以在大約〇 ι至大 約20¾以重量計的範圍内之 輝更佳地大約0.1至大約 /〇以重！相及最佳地大敝1至大約1%以重量計。 除低揮發非VOC蒸發性溶劑以外的其他溶劑可被包含 於本發明之清潔組成物内。適合於❹之助溶劑包含非 VOC以及VOC類型乙二_、脂族以及多元醇、嗣、酸以 及胺。該⑺助溶财部分地或完全地糾於水巾。此等助 溶劑用來控制乾燥以及使用性質。這些助溶劑亦可達到大 部分油、脂以及污垢的另外清潔。當助溶劑為一種低揮發 非VOC溶劑之時，此溶劑與該低揮發非欺蒸發性溶劑相 比或為-不同的水溶解度或是不同的張力減少能力。 亦適合於使用之不同於以上述之低揮發非voc蒸發性 乙二醇醚溶劑之助溶劑的特定實施例包含如下：⑴非voc 20 200540264
及v〇c乙二醇以及乙二醇醚（諸如三聚丙烯曱基乙二醇、二 甘醇正-丁基醚、三甘醇曱基醚、三甘醇乙基醚、三甘醇正 -丁基醚、甘醇正-丁基醚、二聚丙烯甲基乙二醇、丙二醇正 -丁基醚以及丙二醇正-丙基醚）；p)非VOC及VOC酯（諸如乙 5 酸曱酯、乙酸乙酯、二丙二醇曱基醚乙酸酯）；（3)非VOC 及VOC脂族及多元醇（諸如異丙醇、丙二醇、1，3-丁二醇、 己二醇）；（4)非VOC及VOC酮（諸如丙酮、曱基乙基（曱）酮、 環己酮、雙丙酮醇）；（5)非VOC及VOC酸(諸如乙酸、乳酸、 三氟乙酸、2-乙基丁酸）；以及（6)非VOC及VOC胺（諸如鏈 10 烷醇胺，即，單乙醇胺、二乙醇胺、三乙醇胺、正-戊胺、 二乙胺）；以及其等之組合。 較佳地，此等助溶劑係以一從0至大約30%以重量計清 潔組成物之量存在，更佳地大約0至大約5%以重量計以及 最佳地大約0至大約1%以重量計。若一種VOC化合物必要 15 地被作為一種助溶劑，此化合物係以一使得該組成物具有 小於大約4%以重量計VOC含量之量存在。 一種或多種界面活性劑可存在以本發明的組成物中以 達到清潔以及存在於組成物中其他組分之溶解化作用。該 (等）界面活性劑可為兩性、陰離子、非離子、陽離子或其等 20 之混合物。較佳地，此等界面活性劑可被擇自於低條痕界 面活性劑化合物。該一種或多種界面活性劑係以一在大約0 至大約10%以重量計的範圍内之量存在，更佳地大約0至大 約3%以重量計以及最佳地大約0至大約0.6%以重量計。 適合於使用之兩性界面活性劑包含，例如，三甲銨乙 10 200540264 内酯、烷基咪唑啉、椰子兩性丙酸酯或其中之組合。 一較佳的兩性界面活性劑為椰子兩性二丙酸二鈉（亦 通稱為椰子咪唑啉羧酸鹽）(諸如於MACKAM 2CSF商標名 下所販售者）。當使用一兩性界面活性劑之時，該兩性界面 5活性劑較佳地於驗性條件下被使用以使兩性化合物的陰離 子部分活化。 適合於使用之陰離子界面活性劑包含烷基硫酸鹽、烷 基苯磺酸鹽、α-烯烴磺酸鹽、烷基牛磺酸鹽、烷基肌氨酸 鹽、烧基一本基氧一確酸鹽、烧基萘續酸鹽、烧基醚硫酸 10鹽、烷基醚磺酸鹽、磺基琥珀酸鹽以及其他已知在清潔組 成物中所使用的陰離子界面活性劑。該等界面活性劑一般 係以其等之鹼金屬、鹼土以及胺鹽形式而獲得。較佳的陰 罐子界面活性劑為線性C^C]6烧基疏酸鹽、c8-C]6烧基磺酸 鹽、c^c]6烷基苯磺酸鹽以及CrC]6烷基二苯基氧二磺酸 15鹽。在本發明的組成物中使用之最佳的陰離子界面活性劑 為六基〜基苯氧基苯/氧代雙癸基苯續酸二鈉鹽（諸如於 DOWFAX C10L界面活性劑商標名下所販售者）以及辛烷磺 酸鈉、十二烷基磺酸鈉及月桂硫酸鈉。 適合於清潔組成物中使用之非離子性界面活性劑包含 2〇烷氧化醇、烷氧化苯酚醚、以聚矽氧為基的化合物（諸如聚 矽氧乙二醇共聚物）以及半極性非離子表面活性劑（諸如三 烷基氧化胺）。較佳的非離子表面活性劑為乙氧基化(e⑺及 /或丙氧基化(P〇)醇（諸如，每莫耳醇具大約2_1〇莫耳的E〇 或？〇或M0莫耳EO及M0莫耳]3〇之]£〇及/或]?() 11 200540264 醇；或EO、p〇以及E0/P0烷基笨酚）。 陽離子界面活性劑亦可以加以包含用於清潔能力以及 在合適的選擇上抗-細菌性/殺菌性特性二者，即，季胺化合 物。有用的陽離子界面活性劑之實施例包含队烧基三甲基 5辛基銨氣化物以及二曱基二椰子李胺氯化物。
水性載體較佳地為呈大約30至大約99 5%以重量計之 量的水，更佳地為大約90至大約99.5¾以重量計以及最佳地 為大約95至大約99.5%以重量計。 種有利地可存在於本發明不含至含低量V〇c之玻璃 10或一般用途清潔劑中的另外組分為一種聚合物或共聚物， 最值得注意地為一種丙烯酸聚合物或共聚物。已經發現在 本發明配方中存在之丙稀酸聚合物或共聚物將水薄膜性質 提供至以本發明之含有丙烯酸聚合物或共聚物的配方所清 潔的表面。一適合於使用之一種丙烯酸共聚物的實施例為 15 由Cognis股份有限公司所售之POLYQUART AMPHO 149。 POLYQUART AMPHO 149 (192003-74-0)為具2-丙稀酸乙 西旨以及N，N，N-三甲基-3-((2-曱基-1-氧代-2-丙基）胺）小丙烧 按氣之聚合物的納鹽。 可存在一種或多種輔助劑以增進清潔組成物的清潔及 20 /或美學上的品質。合適的輔助劑包含pH值調節劑、增水溶 劑、香料、染料或著色劑、防腐劑、抗細菌性試劑、增稠 劑以及諸如此類已知在清潔組成物中使用的。輔助劑一般 以低量存在，例如，低於大約5%以重量計。用以調節口1_1值 之合適的試劑包含習知的酸、鹼以及其等之鹽類（諸如，Cm 12 200540264 鏈烧醇胺、氨水、驗金屬氫氧化物、碎酸鹽、硼酸鹽、碳 酸鹽、碳酸氫鹽、檸檬酸鹽、檸檬酸或其等之混合物）。 pH值調節劑較佳的實施例包含氫氧化銨以及單乙醇 胺。單乙醇胺亦可達到清潔。本發明的清潔組成物較佳地 5 具有一在2或以上之範圍内的pH值、更佳地在大約9至大約 13之範圍内以及最佳地大約10至大約11.5。pH值調節劑係 以達到所欲的pH值之適當量而被添加。
實施例 下列的實施例係被提供作為本發明之一種玻璃及一般 10 用途清潔組成物的例證。
成份 軟水 著色劑 己基溶纖劑 氫氧化銨（28-30%) 單乙醇胺 MACKAM 2CSF 香料_ VOC 含量=0.2% 實施例1 %以重量計 98.1926 0.0074 0.60 0.30 0.20 0.40 0.05 ~"100% 實施例2 成份 %以重量計 軟水 98.0426 己基溶纖劑 0.60 氫氧化銨（28-30%) 0.30 丙二醇 0.25 單乙醇胺 0.20 MACKAM 2CSF 0.40 著色劑 0.0074 香料 0.05 DOWFAX C10L界面活性劑 0.15 V〇C含量二0.2% 100% 13 200540264 成份 軟水 己基溶纖劑 氫氧化銨（28-30%) 丙二醇 單乙醇胺 MACKAM 2CSF 著色劑 香料_ VOC 含量=0.4% 實施例3 %以重量計 97.9926 0.60 0.30 0.25 0.20 0.40 0.0074 0.05 "100%~~~
實施例4 成份 %以重量計 軟水 97.5926 己基溶纖劑 0.60 氫氧化銨（28-30%) 0.30 丙二醇 0.25 單乙醇胺 0.40 MACKAM 2CSF 0.40 著色劑 0.0074 香料 〇.〇5 陰離子界面活性劑* 0.40 VOC 含量=0.4% 100%~
*辛烧確酸納或十二烧基苯續酸納、或十二烧基硫酸鈉。 實施例5 成份 %以重量計 軟水 97.9926 己基溶纖劑 0.60 無水異丙醇 3.00 MACKAM 2CSF 0.60 D〇WFAX C10L界面活性劑 0.15 單乙醇胺 0.25 丙二醇 0.25 氫氧化銨 0.30 香料 0.05 著色劑 0.0074 VOC 含量=3.6% 100% 14 200540264
實施例6 成份 %以重量計 軟水 94.2426 己基溶纖劑 0.60 無水異丙醇 3.00 MACKAM 2CSF 0.60 DOWFAX C10L界面活性劑 0.15 POLYQUART AMPHO 149* 0.20 單乙醇胺 0.60 丙二醇 0.25 鼠氧化錢 0.30 香料 0.05 著色劑 0.0074 乂0(：含量=3.6% 100% * 一種的丙稀酸共聚物的水溶液。 實施例7 成份 %以重量計 軟水 94.1s426 己基溶纖劑 0.60 無水異丙醇 1.50 MACKAM 2CSF 0.30 DO WFAX C10L界面活性劑 0.15 十二烷基苯磺酸鈉 0.15 單乙醇胺 0.40 辛烷磺酸鈉 0.15 丙二醇 0.25 氫氧化銨 0.30 香料 0.05 著色劑 0.0074 VOC 含量= 1.9% 100%
落在以上所述之範疇内所作之各種改良對熟悉此項技 5 藝者為顯而易見的。此等在熟悉此項技藝者之能力内的改 良形成本發明之一部分且為所附的申請專利範圍所含括。 L圖式簡單說明3 (無） 【主要元件符號說明】 (無） 15
Claims (1)
- 20054026410 1520 十、申請專利範圍： 1. 一種硬表面清潔組成物，該組成物包含： (a) —有效量之至少一種低揮發非揮發性有機化合 物(VOC)蒸發性有機溶劑，該溶劑在水中具有小於20% 之有限溶解度且將該組成物的表面張力減少至小於40 達因/公分； (b) —有效量之至少一種界面活性劑，該界面活性劑 為兩性、陰離子性、非離子性、陽離子性或其等之混合 物； (c) 任擇地一有效量之至少一種不同於（a)之助溶劑 且當該助溶劑為一低揮發非揮發性有機化合物(VOC)溶 劑時，該助溶劑具有至少一不同於該（a)溶劑之水溶解度 或表面張力減少能力；以及 (d) —種水性載體； 其中該組成物具有小於大約4重量百分比之揮發性有機 化合物(VOC)含量。 2. —種硬表面清潔組成物，該組成物包含： (a)大於0至大約4重量百分比之至少一種低揮發及/ 或高揮發之蒸發性有機溶劑，該溶劑具有在水中小於 20%之有限溶解度且將該組成物的表面張力減少至小 於40達因/公分； (b)大於0至大約5重量百分比之至少一種為兩性、陰 離子性、非離子性、陽離子性或其等之混合物的界面活 性劑； 16 200540264 之助:约30重量百分比之至少-種不同於⑷ ==且”料織—_發_發財機化合) 之水，該助溶劑具有至少一不同於該_ 水4度或表面張力減少能力；以及 (d)—均衡量之一種水性载體； 2該組成物具有小於大約4重量百分比 化合物(VOC)含量。 有故 10 15 20 2月專利關第⑷項之硬表面清潔組成物，其中該 、、容•種低揮發非揮發性有機化合物(V〇C)蒸發性有機 / ―具有—如下化學式之乙二醇醚： Rr〇、R2 其中R】為任擇地由_0Η、·〇〇Η3或細2CH3所取代之一 8、、友丨生刀枝或環狀烷基或鏈烯基，以及R2為由七Η 所取代之-CVC6^、分枝或環脉基或鏈稀基。 盆^月專利軌圍第W項任一項之硬表面清潔組成物， ，、中該界面活性劑為兩性的。 申月專利乾圍第4項之硬表面清潔組成物 面活性劑為椰子兩性二丙酸二納。 “ 6·如^專利範圍第1或2項之硬表面清潔組成物，其中該 矛重低揮發瘵發性有機溶劑為乙二醇正己醚。 • ^請專利範圍第5項之硬表面清潔組成物，其中該至 種低揮發非揮發性有機化合物㈤q蒸發性有機溶 七叫為乙二醇正己醚。 / 申㈢專利域第1、2或3項之硬表面清潔組成物，其 17 200540264 中（b)之该至少一種界面活性劑包含一種兩性界面活性 劑以及一種陰離子性界面活性劑。 9·如申請專利範圍第8項之硬表面清潔組成物，其中該兩 $ 性界面活性劑為椰子兩性二丙酸二鈉，且該陰離子性界 5 面活性劑為一種硫酸鹽及/或磺酸鹽化合物。 10·如申請專利範圍第9項之硬表面清潔組成物，其中該至 少一種揮發蒸發性有機溶劑為乙二醇正己醚。 U·如申請專利範圍第項之硬表面清潔組成物，其中該 組成物具有2或以上的pH值。 10 A如申請專利範圍第_項之硬表面清潔組成物，其中該 組成物具有2至13的PH值。 13.如申請專利範圍第⑴項中任—項之硬表面清潔組成 物，其中（c)之該至少一種助溶劑為丙二醇。 b 14·如中請專利範圍第⑴項中任—項之硬表面清潔組成 物，其中（C)之該至少一種助溶劑為單乙醇胺。 Μ·如申請專利範圍第1至4項以及第8至9項中任一項之硬 表面清潔組成物，其中⑷之該至少-種助溶劑為異丙 酉箏。 〇 6·如中％專利範圍第！項之硬表面清潔組成物，其中該組 成物進一步包含一種聚合物或一種共聚物。 17·如申請專利範圍第16項之硬表面清潔組成物，其中該聚 合物或共聚物為一種丙烯酸聚合物或共聚物。 ]8· 一種硬表面清潔組成物，該組成物包含： (a)大於0至大約4重量百分比之至少一種低揮發及/ 18 200540264 我向揮發蒸發性有機溶 5 鲁 10 15 20 夕+ 〜分削隹水宁具有小於20% =限溶解度且將該組成物的表面張力減少至小於40 達因/公分； ⑻大於〇至大約5重量百分比之至少_種界面活性 :，該界面活㈣為兩性、陰離子性、麵子性、陽離 子性或其等之混合物； ⑷從〇至大約鄕重量百分比之至少_種不同於⑷ 之助溶劑且當該助溶劑為—低揮發非揮發性有機化A 物(V叫容劑時，該助溶劑具有至少一不同於該⑷溶劑 之水溶解度或表面張力減少能力； (d)—種聚合物或一種共聚物，·以及 (旬一均衡量之水性載體； 其中該組成物具有小於大約4重量百分比之揮發性有機 化合物(VOC)含量。 K如申請專利範圍第18項之硬表面清潔組成物，其中該聚 合物或共聚物為一種丙烯酸聚合物或共聚物。 肌如申請專利範圍第18項之硬表面清潔組成物，其中⑷ 之該溶劑為一種乙二_，⑻之該至少—種界面活性劑 包括-種兩性界面活性劑以及一種陰離子性界面活性 劑’（C)之該至少一種助溶劑包括一種脂族醇、一種乙二 醇以及一種鏈烧醇胺。 19 200540264 七、指定代表圖： (一） 本案指定代表圖為：第（ ）圖。（無) (二） 本代表圖之元件符號簡單說明：八、本案若有化學式時，請揭示最能顯示發明特徵的化學式：
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/822,301 US20050227898A1 (en) | 2004-04-09 | 2004-04-09 | Zero to low VOC glass and general purpose cleaner |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200540264A true TW200540264A (en) | 2005-12-16 |
Family
ID=34966311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW094111326A TW200540264A (en) | 2004-04-09 | 2005-04-11 | Zero to low voc glass and general purpose cleaner |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20050227898A1 (zh) |
| EP (1) | EP1735417B1 (zh) |
| JP (1) | JP5265185B2 (zh) |
| AU (1) | AU2005233608B2 (zh) |
| CA (1) | CA2561759C (zh) |
| TW (1) | TW200540264A (zh) |
| WO (1) | WO2005100522A1 (zh) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7604702B2 (en) * | 2004-10-29 | 2009-10-20 | Crest Ultrasonics Corp. | Method, apparatus, and system for bi-solvent based cleaning of precision components |
| US20070253926A1 (en) * | 2006-04-28 | 2007-11-01 | Tadrowski Tami J | Packaged cleaning composition concentrate and method and system for forming a cleaning composition |
| US8932702B2 (en) * | 2007-06-15 | 2015-01-13 | Sba Materials, Inc. | Low k dielectric |
| US7741265B2 (en) | 2007-08-14 | 2010-06-22 | S.C. Johnson & Son, Inc. | Hard surface cleaner with extended residual cleaning benefit |
| CN102712875A (zh) * | 2009-10-22 | 2012-10-03 | 约翰逊父子公司 | 提供抗雾与清洁优势的低voc硬表面处理组合物 |
| BR112013010673A2 (pt) * | 2010-11-16 | 2019-09-24 | Dow Global Technologies Llc | composição de limpeza de superfície dura |
| US8808464B2 (en) | 2011-02-15 | 2014-08-19 | Ecolab Usa Inc. | Method for removal of a hydrophobic and particulate soil composition |
| US8349782B2 (en) | 2011-02-15 | 2013-01-08 | Ecolab Usa Inc. | Hydrophobic and particulate soil removal composition |
| US8641827B2 (en) | 2011-09-21 | 2014-02-04 | Ecolab Usa Inc. | Cleaning composition with surface modification polymer |
| WO2013043705A2 (en) | 2011-09-21 | 2013-03-28 | Ecolab Usa Inc. | Bio-based glass cleaner |
| EP2864462B1 (en) | 2012-06-22 | 2018-11-28 | The Procter and Gamble Company | Low voc hard surface cleaning composition |
| US8648027B2 (en) | 2012-07-06 | 2014-02-11 | The Clorox Company | Low-VOC cleaning substrates and compositions comprising a cationic biocide |
| US9096821B1 (en) | 2014-07-31 | 2015-08-04 | The Clorox Company | Preloaded dual purpose cleaning and sanitizing wipe |
| CN110023468A (zh) | 2016-11-28 | 2019-07-16 | 约翰逊父子公司 | 包括氟化表面活性剂的硬表面清洁剂 |
| US10973385B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes having particular pore volume distribution characteristics |
| US10982177B2 (en) | 2017-09-18 | 2021-04-20 | The Clorox Company | Cleaning wipes with particular lotion retention and efficacy characteristics |
| US10973386B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes system having particular performance characteristics |
| US10975341B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes having particular MABDF characteristics |
| US11364711B2 (en) | 2018-12-21 | 2022-06-21 | The Clorox Company | Multi-layer substrates comprising sandwich layers and polyethylene |
Family Cites Families (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3839234A (en) * | 1973-01-26 | 1974-10-01 | C Roscoe | Multi-purpose cleaning concentrate |
| US3939090A (en) * | 1973-10-23 | 1976-02-17 | Colgate-Palmolive Company | Antifogging cleaner |
| US4692277A (en) * | 1985-12-20 | 1987-09-08 | The Procter & Gamble Company | Higher molecular weight diols for improved liquid cleaners |
| DE3713998A1 (de) * | 1987-04-27 | 1988-11-10 | Henkel Kgaa | Reinigungsmittel fuer harte oberflaechen |
| US4921629A (en) * | 1988-04-13 | 1990-05-01 | Colgate-Palmolive Company | Heavy duty hard surface liquid detergent |
| US5336445A (en) * | 1990-03-27 | 1994-08-09 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing beta-aminoalkanols |
| US5540864A (en) * | 1990-12-21 | 1996-07-30 | The Procter & Gamble Company | Liquid hard surfce detergent compositions containing zwitterionic detergent surfactant and monoethanolamine and/or beta-aminoalkanol |
| ZA925727B (en) * | 1991-08-09 | 1993-03-10 | Bristol Myers Squibb Co | Glass cleaning composition. |
| US5252245A (en) * | 1992-02-07 | 1993-10-12 | The Clorox Company | Reduced residue hard surface cleaner |
| US5536451A (en) * | 1992-10-26 | 1996-07-16 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing short chain amphocarboxylate detergent surfactant |
| US5362422A (en) * | 1993-05-03 | 1994-11-08 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing amphoteric detergent surfactant and specific anionic surfactant |
| DE69423233T2 (de) * | 1993-11-12 | 2000-10-26 | The Procter & Gamble Company, Cincinnati | Amphoterestensid und parfümenthaltende, flüssige waschmittelzusammensetzungen für harte oberflächen |
| EP0772668A4 (en) * | 1994-06-09 | 1999-06-30 | Johnson & Son Inc S C | GLASS CLEANER WITH IMPROVED ANTI-FOG PROPERTIES |
| US5534198A (en) * | 1994-08-02 | 1996-07-09 | The Procter & Gamble Company | Glass cleaner compositions having good filming/streaking characteristics and substantive modifier to provide long lasting hydrophilicity |
| US5663134A (en) * | 1994-08-12 | 1997-09-02 | The Procter & Gamble Company | Composition for reducing malodor impression on inanimate surfaces |
| WO1996038522A1 (en) * | 1995-06-02 | 1996-12-05 | Ashland Inc. | Stable microemulsion cleaners having low volatile organic content |
| US5977050A (en) * | 1995-06-16 | 1999-11-02 | Theodore P. Faris | Sprayable cleaning gel |
| US5849681A (en) * | 1996-02-09 | 1998-12-15 | S. C. Johnson & Son, Inc. | Glass cleaner with enhanced anti-streaking properties |
| ES2190520T3 (es) * | 1996-03-19 | 2003-08-01 | Procter & Gamble | Composiciones limpiadoras de vidrio que contienen perfume. |
| US5869601A (en) * | 1996-04-05 | 1999-02-09 | S. C. Johnson & Son, Inc. | Method of stabilizing the viscosity of a thickened composition |
| US5798324A (en) * | 1996-04-05 | 1998-08-25 | S.C. Johnson & Son, Inc. | Glass cleaner with adjustable rheology |
| US5948741A (en) * | 1996-04-12 | 1999-09-07 | The Clorox Company | Aerosol hard surface cleaner with enhanced soil removal |
| US5770548B1 (en) * | 1996-05-14 | 1999-06-29 | Johnson & Son Inc S C | Rinseable hard surface cleaner comprising silicate and hydrophobic acrylic polymer |
| US5849864A (en) * | 1996-08-01 | 1998-12-15 | Ashland Chemical Company | Sulfonic acid blocked metal catalysts for amine trigger urethane reactions |
| US5773395A (en) * | 1996-11-21 | 1998-06-30 | Colgate-Palmolive Co. | Microemulsion all purpose liquid cleaning compositions |
| US6242412B1 (en) * | 1997-03-14 | 2001-06-05 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Personal liquid cleansing composition comprising high levels of polyethylene glycol |
| US6302969B2 (en) * | 1997-05-02 | 2001-10-16 | The Procter & Gamble Company | Cleaning methods and/or articles for hard surfaces |
| US6399553B1 (en) * | 1997-06-05 | 2002-06-04 | The Clorox Company | Reduced residue hard surface cleaner |
| US6432897B1 (en) * | 1997-06-05 | 2002-08-13 | The Clorox Company | Reduced residue hard surface cleaner |
| AU7796598A (en) * | 1997-06-06 | 1998-12-21 | Colgate-Palmolive Company, The | Microemulsion all purpose liquid cleaning compositions |
| CA2299292C (en) * | 1997-08-13 | 2003-07-15 | The Procter & Gamble Company | Glass cleaner compositions having good surface lubricity and alkaline buffer |
| NZ503088A (en) * | 1997-09-03 | 2001-11-30 | S | Method and cleaning composition for sanitizing, disinfecting and inhibiting mold and mildew growth on non-porous hard surfaces |
| JP2001520268A (ja) * | 1997-10-14 | 2001-10-30 | ザ、プロクター、エンド、ギャンブル、カンパニー | 中鎖分枝鎖界面活性剤を包含する硬質表面クリーニング組成物 |
| AU1829500A (en) * | 1998-11-25 | 2000-06-13 | Petroferm Inc. | Aqueous cleaning |
| MXPA01006925A (es) * | 1999-01-06 | 2003-06-04 | Union Carbide Chem Plastic | Composiciones de limpieza acuosas. |
| FR2795088B1 (fr) * | 1999-06-21 | 2002-05-24 | Atofina | Compositions de nettoyage a froid du type microemulsions |
| US6107261A (en) * | 1999-06-23 | 2000-08-22 | The Dial Corporation | Compositions containing a high percent saturation concentration of antibacterial agent |
| KR20030011349A (ko) * | 2000-06-05 | 2003-02-07 | 에스.씨. 존슨 앤드 선, 인코포레이티드 | 살생 클리너 조성물 |
| US6384010B1 (en) * | 2000-06-15 | 2002-05-07 | S.C. Johnson & Son, Inc. | All purpose cleaner with low organic solvent content |
| US6762157B1 (en) * | 2000-07-31 | 2004-07-13 | S. C. Johnson & Son, Inc. | Low residue surface treatment |
| US6569260B2 (en) * | 2000-08-07 | 2003-05-27 | Microblend, Llc | Non-solvent very low VOC formulation for removal of ink from printing presses and the like, and methods of using the same |
| US6699825B2 (en) * | 2001-01-12 | 2004-03-02 | S.C. Johnson & Son, Inc. | Acidic hard-surface antimicrobial cleaner |
| JP2002212597A (ja) * | 2001-01-18 | 2002-07-31 | Lion Corp | 精密部品用水系洗浄剤組成物 |
| US6277800B1 (en) * | 2001-02-13 | 2001-08-21 | Iris Galloway | All purpose household cleaner comprising rubbing alcohol and ammonia |
| WO2002077143A1 (en) * | 2001-03-21 | 2002-10-03 | The Procter & Gamble Company | Hand dishwashing composition |
| US6867174B2 (en) * | 2001-04-16 | 2005-03-15 | Bissell Homecare, Inc. | Non-foaming cleaning compositions and a method for their use |
| US6786223B2 (en) * | 2001-10-11 | 2004-09-07 | S. C. Johnson & Son, Inc. | Hard surface cleaners which provide improved fragrance retention properties to hard surfaces |
| US6701940B2 (en) * | 2001-10-11 | 2004-03-09 | S. C. Johnson & Son, Inc. | Hard surface cleaners containing ethylene oxide/propylene oxide block copolymer surfactants |
| US6881711B1 (en) * | 2001-10-26 | 2005-04-19 | Prestone Products Corporation | Low VOC cleaning compositions for hard surfaces |
-
2004
- 2004-04-09 US US10/822,301 patent/US20050227898A1/en not_active Abandoned
-
2005
- 2005-04-08 EP EP05737586.7A patent/EP1735417B1/en active Active
- 2005-04-08 WO PCT/US2005/011948 patent/WO2005100522A1/en not_active Application Discontinuation
- 2005-04-08 JP JP2007507528A patent/JP5265185B2/ja active Active
- 2005-04-08 CA CA2561759A patent/CA2561759C/en active Active
- 2005-04-08 AU AU2005233608A patent/AU2005233608B2/en active Active
- 2005-04-11 TW TW094111326A patent/TW200540264A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2561759C (en) | 2011-09-20 |
| CA2561759A1 (en) | 2005-10-27 |
| JP5265185B2 (ja) | 2013-08-14 |
| WO2005100522A1 (en) | 2005-10-27 |
| AU2005233608B2 (en) | 2010-05-20 |
| AU2005233608A1 (en) | 2005-10-27 |
| EP1735417A1 (en) | 2006-12-27 |
| JP2007532720A (ja) | 2007-11-15 |
| EP1735417B1 (en) | 2013-06-12 |
| US20050227898A1 (en) | 2005-10-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW200540264A (en) | Zero to low voc glass and general purpose cleaner | |
| US6849589B2 (en) | Cleaning composition | |
| US10138443B2 (en) | Cleaning composition with rapid foam collapse | |
| US6271191B1 (en) | Hard surface cleaner containing anionic surfactant | |
| WO2005113735A1 (en) | Acidic hard surface cleaner with alkoxylated quaternary compound | |
| JP5364396B2 (ja) | 拭き取り用洗浄剤組成物及び洗浄方法 | |
| AU2020221009B2 (en) | High foaming liquid alkaline cleaner concentrate composition | |
| JP2011190376A (ja) | 浴室用洗浄剤組成物 | |
| JP2023106471A (ja) | 発泡性洗剤組成物 | |
| JP2017522413A (ja) | 低起泡性多酵素洗浄剤 | |
| EP0524075A1 (fr) | Composition acide désinfectante à propriétés détergentes et détartrantes et procédé pour sa mise en oeuvre | |
| JP6093279B2 (ja) | 硬質表面用液体洗浄剤組成物 | |
| JP6585145B2 (ja) | 水洗トイレ用洗浄組成物 | |
| JPH07228892A (ja) | 硬質表面用洗浄剤組成物 | |
| JP6391998B2 (ja) | 発泡剤 | |
| JP2002194388A (ja) | 液体洗浄剤組成物 | |
| JP4633448B2 (ja) | 硬質表面用洗浄剤 | |
| JP5659087B2 (ja) | 硬質表面用液体洗浄剤組成物 | |
| MXPA06011485A (en) | Zero to low voc glass and general purpose cleaner | |
| JP2005206772A (ja) | 漂白剤組成物 | |
| JPH11335700A (ja) | 浴室用洗浄剤組成物 | |
| WO2024194301A1 (en) | Concentrated liquid cleaning composition | |
| JP2542130B2 (ja) | 水洗トイレ用清浄剤組成物 | |
| JPH04345699A (ja) | 水洗トイレ用清浄剤組成物 | |
| CN105705485A (zh) | 均三甲苯磺酸盐组合物及其方法 |