SU46928A1 - The method of obtaining phenol-aldehyde resin - Google Patents
The method of obtaining phenol-aldehyde resinInfo
- Publication number
- SU46928A1 SU46928A1 SU180592A SU180592A SU46928A1 SU 46928 A1 SU46928 A1 SU 46928A1 SU 180592 A SU180592 A SU 180592A SU 180592 A SU180592 A SU 180592A SU 46928 A1 SU46928 A1 SU 46928A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- phenol
- condensation
- aldehyde resin
- alcohol
- phase
- Prior art date
Links
- 229920005989 resin Polymers 0.000 title description 6
- 239000011347 resin Substances 0.000 title description 6
- 238000009833 condensation Methods 0.000 description 7
- 230000005494 condensation Effects 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- VKYKSIONXSXAKP-UHFFFAOYSA-N Hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 229960004011 Methenamine Drugs 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000004312 hexamethylene tetramine Substances 0.000 description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 2
- 229920003986 novolac Polymers 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 229920003987 resole Polymers 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 206010051602 Laziness Diseases 0.000 description 1
- 206010038192 Red man syndrome Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000001476 alcoholic Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229920002892 amber Polymers 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- -1 castor oil Chemical compound 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 125000000853 cresyl group Chemical class C1(=CC=C(C=C1)C)* 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N n-pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating Effects 0.000 description 1
- RDYOACUIENLGER-UHFFFAOYSA-N phenol;propane-1,2,3-triol Chemical compound OCC(O)CO.OC1=CC=CC=C1 RDYOACUIENLGER-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
J,J
Предлагаемый способ заключаетс в получении I прс1зрачных и полупрозрачйых 1-еплавких и нерастворимых фенопластов ИЗ: фенола и крезолов. Конденсаци осуществл етс сначала нагреванием фенола с сухим гекса в присутствии небольшого количества спирта, с перево цдм полученной смолы типа новолвка j bj резольную при помощи допол|йительНой I обработки новблака в спирто вом растроре тeкcaмeтиJ1eнтeтpамином . Количество гексаметилентетрамина , необходимое дл образовани новолака , ; определ етс , примерно, на 12 мол. фенола 1 мол, гекса, а на резол требуетс на 13 мол. фенола около 2,25 мол. текса. Полученную в спиртовом растворе ;смолу высушивают под уменьшенным давлением, растворитель отгон ют , смолу хо|эошо измельчают и без введени наполнителей прессуют при давлении от 200 до 600 кг/см- поверхности прессуемого издели . Конденсацию с гексаметилентетрамином можно проводить в присутствии небольшого количества едких щелочей, как, например, едкий натр, гидрат окиси бари и т. д. Дл замедлени ;реакции конденсации можно вводить 8 продукты конденсации или в исходный |фенол глицерин, гликоль или амиловым спирт. При примененииThe proposed method consists in obtaining I prc1e and translucent 1-meltable and insoluble phenolic plastics FROM: phenol and cresols. The condensation is carried out first by heating a dry hex phenol in the presence of a small amount of alcohol, transferring the obtained resin of the type jbj resole by means of an additional Novolak I treatment in an alcohol ratchetrothermite. The amount of hexamethylenetetramine required to form a novolak; measured at about 12 mol. phenol 1 mole, hex, and the resol is required at 13 mole. phenol about 2.25 mol. tex. The resin obtained in an alcoholic solution; the resin is dried under reduced pressure; the solvent is distilled off; the resin is finely ground and, without the introduction of fillers, is pressed at a pressure of 200 to 600 kg / cm-surface of the compressible product. Condensation with hexamethylenetetramine can be carried out in the presence of a small amount of caustic alkali, such as caustic soda, barium hydroxide, etc. To slow down the condensation reaction, you can enter 8 condensation products or in the original phenol glycerol, glycol or amyl alcohol. When applied
ЭТОГО метода можно получить прозрачные органические стекла нтарного цвета или окрашенные при помощи специальных красителей в различныецвета . В отличие от литых фенольнь1Х прозрачных пластиков данные фенопласты будут отличатьс высокой механической прочностью и высокими электроизол ционными свойствами. Так например , нормальный брусок дает прочность на удар от 10 до 12 К21см, а пробивной градиент выра аетс в 20000- 30000 вольт на 1 -ifjf толщины. Предлагаемый способ может дать возможность получать .как продукты галантерейногохарактера , так и высокого качества электроизол ционные материалы.This method can be obtained transparent organic glass amber-colored or painted with special dyes in various colors. Unlike cast phenolic transparent plastics, these phenolic plastics will be distinguished by high mechanical strength and high electrical insulation properties. So, for example, a normal bar gives impact resistance from 10 to 12 K21cm, and the penetrative gradient is expressed in 20000-3000 volts per 1 -ifjf thickness. The proposed method can give the possibility to obtain both products of a haberdashery character and high quality electrical insulation materials.
Дл получени полупрозрачных продуктов рекомендуетс при второй фазе конденсации вводить в спиртовые растворы смолы вместе с гекса жирные кислоты или масла, растворимые в. спирте, как например, касторовое и т. д. Количество масел колеблетс в пределах от 2 до 20%.In order to obtain translucent products, it is recommended to introduce fat soluble acids or oils soluble in alcohol solutions of the resin in the second phase of condensation. alcohol, such as castor oil, etc. The number of oils ranges from 2 to 20%.
Конденсаци с гекса дает возможность более легко получать прозрачные продукты, так как при этой реакции конденсации выдел етс аммиак, но не выдел етс вода, что было раньше установлено работами Лебаха, Бэкеланда , Редмана, Кебнера и др. Как показали Ьпыты, конденсаци в , одну фазу, при соотнбшении ilS мол. фенола и 2 мол. формальдегида дл получени прозрачных п родуктс4 методом прессовани не дает |положит ельных результатов, поэтому н рбходимо примен ть метод двухфазной конденсации с текса-едким или присутствй1|1 оснрзаиий, примен вCondensation from a hex makes it possible to more easily obtain transparent products, since ammonia is released during this condensation reaction, but water is not released, as was previously established by the works of Lebach, Bekeland, Redman, Kebner, and others. phase, with the ratio ilS mol. phenol and 2 mol. formaldehyde to obtain transparent products by pressing does not give | positive results, therefore, it is necessary to apply the method of two-phase condensation with texcous or presence1 | 1 osnrzayiy, used in
УХОЙ гекса, и задержива EAR hex, and delay
1рервой фазе Ч бурную экзор рмичесную реакцию дошого количества (5-109-6) бавкой неболь Спирта.In the first phase, a violent exorbitant reaction of the dosage amount (5–109–6) is given by a small alcohol.
Предмет изобретени .The subject matter of the invention.
I . Способ iполучени фенолоальдеЖД .ной змолы i путем двухфазной конденсации с применением гексаметиленТетрЕмица .и с добавлением или без дббаб I. The method of obtaining phenol-aldehyde zmol i by two-phase condensation using hexamethylene. Metric. And with or without the addition of dbbab
едкил или углекислых ШЬлйчей, лени ш ощийс тем, что carbon dioxide or carbonic acid, laziness is the fact that
ао времй BfQотли в спиртдвой фазы конденсации рой ор смолы ввод т жирные кислоты pacTi растворимые в спирте илиIn the alcohol two phase condensation phase, pacTi fatty acids soluble in alcohol or
масли.masli.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU46928A1 true SU46928A1 (en) | 1936-05-31 |
Family
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