SU370868A1 - - Google Patents

Info

Publication number

SU370868A1

SU370868A1 SU1608998A SU1608998A SU370868A1 SU 370868 A1 SU370868 A1 SU 370868A1 SU 1608998 A SU1608998 A SU 1608998A SU 1608998 A SU1608998 A SU 1608998A SU 370868 A1 SU370868 A1 SU 370868A1

Authority

SU

USSR - Soviet Union

Prior art keywords

nitric acid

ethylene

dinitrate

olefins

palladium

Prior art date

1971-01-07

Links

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• 238000000034 method Methods 0.000 description 13
• GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 7
• 150000001336 alkenes Chemical class 0.000 description 7
• 229910017604 nitric acid Inorganic materials 0.000 description 7
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical class OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
• 230000003197 catalytic effect Effects 0.000 description 4
• 150000002823 nitrates Chemical class 0.000 description 4
• GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 4
• 239000000047 product Substances 0.000 description 4
• 239000005977 Ethylene Substances 0.000 description 3
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
• 238000002360 preparation method Methods 0.000 description 3
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
• KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
• 238000006243 chemical reaction Methods 0.000 description 2
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
• 125000001424 substituent group Chemical group 0.000 description 2
• UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
• 229910002651 NO3 Inorganic materials 0.000 description 1
• NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
• PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
• 239000002253 acid Substances 0.000 description 1
• 239000006227 byproduct Substances 0.000 description 1
• 229910001628 calcium chloride Inorganic materials 0.000 description 1
• 239000001110 calcium chloride Substances 0.000 description 1
• 239000003054 catalyst Substances 0.000 description 1
• 239000003795 chemical substances by application Substances 0.000 description 1
• VNCRPVVIOLCQNM-UHFFFAOYSA-N ethane-1,2-diol;nitric acid Chemical class OCCO.O[N+]([O-])=O.O[N+]([O-])=O VNCRPVVIOLCQNM-UHFFFAOYSA-N 0.000 description 1
• UQXKXGWGFRWILX-UHFFFAOYSA-N ethylene glycol dinitrate Chemical compound O=N(=O)OCCON(=O)=O UQXKXGWGFRWILX-UHFFFAOYSA-N 0.000 description 1
• -1 ethylene, propylene Chemical group 0.000 description 1
• 239000000295 fuel oil Substances 0.000 description 1
• 239000007788 liquid Substances 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 239000000203 mixture Substances 0.000 description 1
• 230000000802 nitrating effect Effects 0.000 description 1
• 229910052757 nitrogen Inorganic materials 0.000 description 1
• 229910052763 palladium Inorganic materials 0.000 description 1
• 238000000926 separation method Methods 0.000 description 1
• PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
• 235000021286 stilbenes Nutrition 0.000 description 1
• 238000003756 stirring Methods 0.000 description 1
• QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical class S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1