SU294298A1 - - Google Patents

Info

Publication number

SU294298A1

SU294298A1 SU1239264A SU1239264A SU294298A1 SU 294298 A1 SU294298 A1 SU 294298A1 SU 1239264 A SU1239264 A SU 1239264A SU 1239264 A SU1239264 A SU 1239264A SU 294298 A1 SU294298 A1 SU 294298A1

Authority

SU

USSR - Soviet Union

Prior art keywords

catalyst

propylene

acrolein

selectivity

acrylic acid

Prior art date

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• HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 30
• 239000003054 catalyst Substances 0.000 description 23
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 21
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 21
• 238000006243 chemical reaction Methods 0.000 description 19
• 239000007789 gas Substances 0.000 description 18
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 15
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 13
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
• 229910001868 water Inorganic materials 0.000 description 13
• 239000000203 mixture Substances 0.000 description 11
• UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 10
• 239000002253 acid Substances 0.000 description 9
• 239000000243 solution Substances 0.000 description 9
• CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
• 230000003647 oxidation Effects 0.000 description 7
• 238000007254 oxidation reaction Methods 0.000 description 7
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
• VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 6
• 150000001299 aldehydes Chemical class 0.000 description 6
• ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
• 238000009835 boiling Methods 0.000 description 6
• 229910052760 oxygen Inorganic materials 0.000 description 6
• 239000001301 oxygen Substances 0.000 description 6
• 229910002092 carbon dioxide Inorganic materials 0.000 description 5
• 229910002090 carbon oxide Inorganic materials 0.000 description 5
• ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
• 150000007513 acids Chemical class 0.000 description 4
• 229910002091 carbon monoxide Inorganic materials 0.000 description 4
• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical group [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
• 229910052751 metal Inorganic materials 0.000 description 4
• 239000002184 metal Substances 0.000 description 4
• JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
• 229910052759 nickel Inorganic materials 0.000 description 4
• 229910052714 tellurium Inorganic materials 0.000 description 4
• PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 4
• QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
• 229910003069 TeO2 Inorganic materials 0.000 description 3
• 150000001336 alkenes Chemical class 0.000 description 3
• 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
• 229910052799 carbon Inorganic materials 0.000 description 3
• 239000001569 carbon dioxide Substances 0.000 description 3
• 150000001728 carbonyl compounds Chemical class 0.000 description 3
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
• 239000005078 molybdenum compound Substances 0.000 description 3
• 150000002752 molybdenum compounds Chemical class 0.000 description 3
• 229910052757 nitrogen Inorganic materials 0.000 description 3
• 239000000047 product Substances 0.000 description 3
• 150000003839 salts Chemical class 0.000 description 3
• LAJZODKXOMJMPK-UHFFFAOYSA-N tellurium dioxide Chemical compound O=[Te]=O LAJZODKXOMJMPK-UHFFFAOYSA-N 0.000 description 3
• 239000002912 waste gas Substances 0.000 description 3
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
• 150000003863 ammonium salts Chemical class 0.000 description 2
• 239000003153 chemical reaction reagent Substances 0.000 description 2
• 238000004587 chromatography analysis Methods 0.000 description 2
• 150000001875 compounds Chemical class 0.000 description 2
• 230000000694 effects Effects 0.000 description 2
• 239000008187 granular material Substances 0.000 description 2
• 238000004519 manufacturing process Methods 0.000 description 2
• 239000011733 molybdenum Substances 0.000 description 2
• 229910052750 molybdenum Inorganic materials 0.000 description 2
• 229910000476 molybdenum oxide Inorganic materials 0.000 description 2
• PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 2
• JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
• 239000000843 powder Substances 0.000 description 2
• 239000000725 suspension Substances 0.000 description 2
• 239000012808 vapor phase Substances 0.000 description 2
• PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
• STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 description 1
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
• 229910017234 MnSO4 H2O Inorganic materials 0.000 description 1
• 229910017237 MnSO4-H2O Inorganic materials 0.000 description 1
• 229910017228 MnSO4—H2O Inorganic materials 0.000 description 1
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
• APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
• 229940010552 ammonium molybdate Drugs 0.000 description 1
• 235000018660 ammonium molybdate Nutrition 0.000 description 1
• 239000011609 ammonium molybdate Substances 0.000 description 1
• 239000007864 aqueous solution Substances 0.000 description 1
• 230000015572 biosynthetic process Effects 0.000 description 1
• 125000004432 carbon atom Chemical group C* 0.000 description 1
• 229910017052 cobalt Inorganic materials 0.000 description 1
• 239000010941 cobalt Substances 0.000 description 1
• 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
• 229940044175 cobalt sulfate Drugs 0.000 description 1
• KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
• 239000013078 crystal Substances 0.000 description 1
• 238000004821 distillation Methods 0.000 description 1
• 238000001035 drying Methods 0.000 description 1
• 239000011261 inert gas Substances 0.000 description 1
• 150000002576 ketones Chemical class 0.000 description 1
• 229910052748 manganese Inorganic materials 0.000 description 1
• 239000011572 manganese Substances 0.000 description 1
• ISPYRSDWRDQNSW-UHFFFAOYSA-L manganese(II) sulfate monohydrate Chemical compound O.[Mn+2].[O-]S([O-])(=O)=O ISPYRSDWRDQNSW-UHFFFAOYSA-L 0.000 description 1
• 239000000320 mechanical mixture Substances 0.000 description 1
• 238000000034 method Methods 0.000 description 1
• 238000002156 mixing Methods 0.000 description 1
• LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
• GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
• 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
• QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
• 239000007800 oxidant agent Substances 0.000 description 1
• 210000004197 pelvis Anatomy 0.000 description 1
• DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 1
• 239000002244 precipitate Substances 0.000 description 1
• 239000008262 pumice Substances 0.000 description 1
• 238000001953 recrystallisation Methods 0.000 description 1
• 229920006395 saturated elastomer Chemical class 0.000 description 1
• 238000000926 separation method Methods 0.000 description 1
• 229910010271 silicon carbide Inorganic materials 0.000 description 1
• 239000000377 silicon dioxide Substances 0.000 description 1
• 239000000126 substance Substances 0.000 description 1
• 229910021653 sulphate ion Inorganic materials 0.000 description 1
• 238000005979 thermal decomposition reaction Methods 0.000 description 1