SK72097A3 - Process for controlling static charge in polymerization of alpha-olefinic polymers utilizing metallocene catalysts - Google Patents

Process for controlling static charge in polymerization of alpha-olefinic polymers utilizing metallocene catalysts Download PDF

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Publication number
SK72097A3
SK72097A3 SK720-97A SK72097A SK72097A3 SK 72097 A3 SK72097 A3 SK 72097A3 SK 72097 A SK72097 A SK 72097A SK 72097 A3 SK72097 A3 SK 72097A3
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SK
Slovakia
Prior art keywords
group
antistatic agent
carbon atoms
reactor
catalyst
Prior art date
Application number
SK720-97A
Other languages
English (en)
Slovak (sk)
Inventor
Hee Lee Kiu
Fathi D Hussein
Clark C Williams
Original Assignee
Union Carbide Chem Plastic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic
Publication of SK72097A3 publication Critical patent/SK72097A3/sk

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1809—Controlling processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00734—Controlling static charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00247—Fouling of the reactor or the process equipment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
SK720-97A 1996-06-06 1997-06-05 Process for controlling static charge in polymerization of alpha-olefinic polymers utilizing metallocene catalysts SK72097A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US65944196A 1996-06-06 1996-06-06

Publications (1)

Publication Number Publication Date
SK72097A3 true SK72097A3 (en) 1999-02-11

Family

ID=24645413

Family Applications (1)

Application Number Title Priority Date Filing Date
SK720-97A SK72097A3 (en) 1996-06-06 1997-06-05 Process for controlling static charge in polymerization of alpha-olefinic polymers utilizing metallocene catalysts

Country Status (16)

Country Link
EP (1) EP0811638A3 (id)
JP (1) JPH1060019A (id)
KR (1) KR980002076A (id)
AR (1) AR007505A1 (id)
AU (1) AU2469497A (id)
BR (1) BR9703491A (id)
CA (1) CA2207094A1 (id)
CZ (1) CZ170897A3 (id)
HU (1) HUP9701009A3 (id)
ID (1) ID17377A (id)
MX (1) MX9704157A (id)
PL (1) PL320396A1 (id)
SG (1) SG74589A1 (id)
SK (1) SK72097A3 (id)
TR (1) TR199700473A2 (id)
ZA (1) ZA974927B (id)

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TW475934B (en) 1998-06-27 2002-02-11 Basell Technology Co Bv Process for the production of Α-olefin polymer
DE19835467A1 (de) 1998-08-06 2000-02-17 Elenac Gmbh Feststoffreaktor mit antistatischer Beschichtung zur Durchführung von Reaktionen in der Gasphase
US6201076B1 (en) * 1999-04-29 2001-03-13 Equistar Chemicals, L.P. Olefin polymerization process with fatty amine additives for improved activity and reduced fouling
JP4895426B2 (ja) 1999-05-07 2012-03-14 イネオス ユーロープ リミテッド 流動床反応器におけるオレフィンの気相（共）重合法
US6417301B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
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CN1387540A (zh) * 1999-09-09 2002-12-25 英国石油化学品有限公司 在流化床反应器上烯烃的连续气相(共)聚合的方法
US6476165B1 (en) 2000-03-08 2002-11-05 Equistar Chemicals, Lp Olefin polymerization process using fatty amine additives and boron-modified supported catalyst
US6720396B2 (en) * 2000-11-30 2004-04-13 Univation Technologies, Llc Polymerization process
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US6933258B2 (en) * 2000-12-19 2005-08-23 Univation Technologies, L.L.C. Catalyst composition and methods for its preparation and use in a polymerization process
JP2002265507A (ja) * 2001-03-09 2002-09-18 Sumitomo Chem Co Ltd オレフィンの気相流動床式重合反応におけるシーティング防止
CN100509872C (zh) * 2002-12-13 2009-07-08 陶氏环球技术公司 含有13族氨化物衍生物的烯烃聚合催化剂组合物
US6858684B2 (en) * 2002-12-30 2005-02-22 Univation Technologies, Llc Processes for transitioning between various polymerization catalysts
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WO2005003184A1 (en) * 2003-06-11 2005-01-13 Exxonmobil Chemical Patents Inc. Polymerization processes using antistatic agents
US20070073012A1 (en) 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
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Also Published As

Publication number Publication date
PL320396A1 (en) 1997-12-08
HUP9701009A2 (hu) 1998-03-02
SG74589A1 (en) 2000-08-22
MX9704157A (es) 1997-12-31
EP0811638A2 (en) 1997-12-10
JPH1060019A (ja) 1998-03-03
KR980002076A (ko) 1998-03-30
CA2207094A1 (en) 1997-12-06
ZA974927B (en) 1997-12-30
CZ170897A3 (en) 1997-12-17
BR9703491A (pt) 1999-06-15
TR199700473A2 (xx) 1997-12-21
HUP9701009A3 (en) 2000-03-28
AR007505A1 (es) 1999-11-10
ID17377A (id) 1997-12-24
HU9701009D0 (en) 1997-07-28
EP0811638A3 (en) 1998-05-13
AU2469497A (en) 1997-12-11

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