SG11201703339UA - Oxidative esterification process for making methyl methacrylate - Google Patents

Oxidative esterification process for making methyl methacrylate

Info

Publication number
SG11201703339UA
SG11201703339UA SG11201703339UA SG11201703339UA SG11201703339UA SG 11201703339U A SG11201703339U A SG 11201703339UA SG 11201703339U A SG11201703339U A SG 11201703339UA SG 11201703339U A SG11201703339U A SG 11201703339UA SG 11201703339U A SG11201703339U A SG 11201703339UA
Authority
SG
Singapore
Prior art keywords
methyl methacrylate
esterification process
oxidative esterification
making methyl
making
Prior art date
Application number
SG11201703339UA
Other languages
English (en)
Inventor
Kirk W Limbach
Dmitri A Kraptchetov
Christopher D Frick
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of SG11201703339UA publication Critical patent/SG11201703339UA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6445—Antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6447—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11201703339UA 2014-10-31 2015-10-07 Oxidative esterification process for making methyl methacrylate SG11201703339UA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201462073290P 2014-10-31 2014-10-31
PCT/US2015/054437 WO2016069225A1 (en) 2014-10-31 2015-10-07 Oxidative esterification process for making methyl methacrylate

Publications (1)

Publication Number Publication Date
SG11201703339UA true SG11201703339UA (en) 2017-05-30

Family

ID=54478203

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201703339UA SG11201703339UA (en) 2014-10-31 2015-10-07 Oxidative esterification process for making methyl methacrylate

Country Status (12)

Country Link
US (1) US9969672B2 (zh)
EP (1) EP3212608B1 (zh)
JP (1) JP6661629B2 (zh)
KR (1) KR102455959B1 (zh)
CN (1) CN107074727B (zh)
BR (1) BR112017007934B1 (zh)
CA (1) CA2965481C (zh)
MX (1) MX2017004880A (zh)
SA (1) SA517381345B1 (zh)
SG (1) SG11201703339UA (zh)
TW (1) TWI577659B (zh)
WO (1) WO2016069225A1 (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020073458A (ja) * 2017-03-02 2020-05-14 Ａｇｃ株式会社 α，β−不飽和酸エステルまたはα−ハロエステルの製造方法
MX2020001032A (es) * 2017-07-28 2020-07-20 Dow Global Technologies Llc Método para producción de metacrilato de metilo por esterificación oxidativa mediante el uso de un catalizador heterogéneo.
EP3814007B1 (en) * 2018-06-28 2024-10-02 Dow Global Technologies, LLC Heterogeneous catalyst and method of preparing methyl methacrylate from methacrolein and methanol
KR102417077B1 (ko) * 2019-01-18 2022-07-04 주식회사 엘지화학 메틸메타크릴레이트의 제조 방법

Family Cites Families (22)

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Publication number Priority date Publication date Assignee Title
JPS51141810A (en) * 1975-06-02 1976-12-07 Nippon Kayaku Co Ltd Process for simultaneous preparation of methacrylic acid and methylmet hacrylate or acrylic acid and methylacrylate
DE2633728C3 (de) * 1976-07-27 1979-07-12 Boehringer Mannheim Gmbh, 6800 Mannheim NADH-Peroxidase, ihre Gewinnung und Verwendung
DE3018071C2 (de) 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Verfahren zur Herstellung von Carbonsäureestern
JPS5687530A (en) 1979-12-19 1981-07-16 Asahi Chem Ind Co Ltd Dehydrating method of gas containing unsaturated aldehyde
GB2094782A (en) * 1981-03-16 1982-09-22 Johnson Matthey Co Ltd Production of alkyl methacrylates
EP1361206B1 (en) * 1995-07-18 2004-10-27 Asahi Kasei Chemicals Corporation Method for producing carboxylic esters
JPH09216850A (ja) * 1996-02-09 1997-08-19 Mitsubishi Rayon Co Ltd カルボン酸エステルの製造方法
TW385304B (en) 1996-09-10 2000-03-21 Asahi Chemical Ind Process for producing methacrylic acid ester or acrylic acid ester
JP3313993B2 (ja) * 1996-11-29 2002-08-12 三菱レイヨン株式会社 カルボン酸エステルの製造法
TW377306B (en) 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support
JP3297342B2 (ja) * 1997-03-24 2002-07-02 三菱レイヨン株式会社 カルボン酸エステルの製造法
JP3511350B2 (ja) * 1997-03-25 2004-03-29 旭化成ケミカルズ株式会社 カルボン酸エステル製造用触媒
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
CN1122569C (zh) * 1997-08-07 2003-10-01 三菱丽阳株式会社 用于制造羧酸酯的催化剂和羧酸酯的制造方法
US7326806B2 (en) 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
CN1214865C (zh) * 2003-01-22 2005-08-17 中国科学院过程工程研究所 一种用于甲基丙烯醛一步氧化酯化生产甲基丙烯酸甲酯的新型催化剂
EP2177267B1 (en) 2007-08-13 2013-07-31 Asahi Kasei Chemicals Corporation Catalyst for carboxylic acid ester production, method for producing the same, and method for producing carboxylic acid ester
EP2617679B1 (en) 2010-09-16 2020-02-19 Asahi Kasei Kabushiki Kaisha Silica-based material, manufacturing process therefor, noble metal carrying material, and carboxylic acid manufacturing process using same as catalyst
CN103772171B (zh) * 2012-10-17 2016-08-17 中国石油化工股份有限公司 异丁烯或叔丁醇氧化制甲基丙烯醛方法
US20140206897A1 (en) 2013-01-22 2014-07-24 Saudi Basic Industries Corporation Method for making methyl methacrylate from propionaldehyde and formaldehyde via oxidative esterification
ES2673104T3 (es) * 2013-04-19 2018-06-19 Evonik Röhm Gmbh Procedimiento para la preparación de metacrilato de metilo
CN103721744A (zh) * 2013-12-27 2014-04-16 天津大学 用于一步氧化酯化生产甲基丙烯酸甲酯的疏水催化剂及制备方法

Also Published As

Publication number Publication date
BR112017007934B1 (pt) 2021-11-30
BR112017007934A2 (pt) 2018-01-23
MX2017004880A (es) 2017-07-05
WO2016069225A1 (en) 2016-05-06
TWI577659B (zh) 2017-04-11
US9969672B2 (en) 2018-05-15
EP3212608B1 (en) 2020-12-30
KR102455959B1 (ko) 2022-10-18
US20170226043A1 (en) 2017-08-10
JP2017534622A (ja) 2017-11-24
SA517381345B1 (ar) 2021-01-17
CA2965481A1 (en) 2016-05-06
CN107074727A (zh) 2017-08-18
JP6661629B2 (ja) 2020-03-11
TW201615612A (zh) 2016-05-01
EP3212608A1 (en) 2017-09-06
CN107074727B (zh) 2021-02-09
CA2965481C (en) 2023-03-21
KR20170076708A (ko) 2017-07-04

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