SE8600606D0 - CELL CORROSION REDUCTION - Google Patents

CELL CORROSION REDUCTION

Info

Publication number
SE8600606D0
SE8600606D0 SE8600606A SE8600606A SE8600606D0 SE 8600606 D0 SE8600606 D0 SE 8600606D0 SE 8600606 A SE8600606 A SE 8600606A SE 8600606 A SE8600606 A SE 8600606A SE 8600606 D0 SE8600606 D0 SE 8600606D0
Authority
SE
Sweden
Prior art keywords
metal
particles
reduction
grains
corrosion
Prior art date
Application number
SE8600606A
Other languages
Swedish (sv)
Other versions
SE8600606L (en
Inventor
P Chalilpoyil
F E Parsen
J R Rea
C-C Wang
Original Assignee
Duracell Int
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/749,688 external-priority patent/US4632890A/en
Priority claimed from US06/764,454 external-priority patent/US4585716A/en
Application filed by Duracell Int filed Critical Duracell Int
Publication of SE8600606D0 publication Critical patent/SE8600606D0/en
Publication of SE8600606L publication Critical patent/SE8600606L/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/628Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/04Cells with aqueous electrolyte

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

Gassing is significantly reduced in electrochemical cells having anodes of metals, such as zinc, by reducing the number of grains in the particles of the polycrystalline metal to at least a third of the original number of grains and thereafter using the metal in the formation of the cell anode. Such grain number reduction is effected by heat treatment of the anode metal at a temperature below that of the melting point of the metal. Corrosion is further reduced with such reduced grain number particles and particularly with single crystal particles by the addition of small amounts of a gas inhibiting surfactant, for example, an organic phosphate inhibitor such as RA600 from GAF Corp. to the cell. Alternatively, or in addition, corrosion is reduced by prealloying the metal particles with small amounts of one or more of indium, thallium, gallium, bismuth, cadmium, tin and lead prior to reduction of the number of grains or the formation of the single crystal particles. A synergistically lowered rate of corrosion and cell gassing is obtained even with reduction of mercury content.
SE8600606A 1985-02-12 1986-02-11 CELL CORROSION REDUCTION SE8600606L (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US70083685A 1985-02-12 1985-02-12
US06/749,688 US4632890A (en) 1985-06-28 1985-06-28 Anode metal treatment and use of said anode in cell
US06/764,454 US4585716A (en) 1984-07-09 1985-08-12 Cell corrosion reduction

Publications (2)

Publication Number Publication Date
SE8600606D0 true SE8600606D0 (en) 1986-02-11
SE8600606L SE8600606L (en) 1986-08-13

Family

ID=27418711

Family Applications (1)

Application Number Title Priority Date Filing Date
SE8600606A SE8600606L (en) 1985-02-12 1986-02-11 CELL CORROSION REDUCTION

Country Status (16)

Country Link
AU (1) AU594661B2 (en)
BE (1) BE904216A (en)
BR (1) BR8600570A (en)
CA (1) CA1271217A (en)
CH (1) CH671304A5 (en)
DE (1) DE3603342A1 (en)
DK (1) DK66886A (en)
ES (1) ES8706854A1 (en)
FR (1) FR2577351B1 (en)
GB (2) GB2170946B (en)
IE (1) IE57432B1 (en)
IT (1) IT1204791B (en)
MX (1) MX163835B (en)
NL (1) NL8600347A (en)
NO (1) NO169098C (en)
SE (1) SE8600606L (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1267189A (en) * 1985-06-28 1990-03-27 Jerrold Winger Alkaline cell employing a zinc electrode with reduced mercury additive
EP0352604A1 (en) * 1988-07-25 1990-01-31 Cipel Primary electrochemical generator with an alkaline electrolyte and a negative zinc electrode
FR2634594B1 (en) * 1988-07-25 1993-06-18 Cipel Wonder ELECTROCHEMICAL GENERATOR WITH ALKALINE ELECTROLYTE AND ZINC NEGATIVE ELECTRODE
DE3902650A1 (en) * 1989-01-30 1990-08-02 Varta Batterie GALVANIC PRIME ELEMENT
CA2046148C (en) * 1990-08-14 1997-01-07 Dale R. Getz Alkaline cells that are substantially free of mercury
US5626988A (en) * 1994-05-06 1997-05-06 Battery Technologies Inc. Sealed rechargeable cells containing mercury-free zinc anodes, and a method of manufacture
EP1962357B1 (en) * 2006-06-28 2013-01-16 Panasonic Corporation Alkaline dry battery
JP4516092B2 (en) * 2007-05-10 2010-08-04 パナソニック株式会社 Alkaline battery
CN112928236A (en) * 2021-01-21 2021-06-08 福建南平南孚电池有限公司 Alkaline battery

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE347906C (en) * 1918-11-16 1922-01-25 Alfred Eichhoff Galvanic element
US2233578A (en) * 1937-11-04 1941-03-04 Western Cartridge Co Method of making battery cans
US3623911A (en) * 1969-03-03 1971-11-30 Leesona Corp High-rate consumable metal electrodes
US3853625A (en) * 1970-04-03 1974-12-10 Union Carbide Corp Zinc fibers and needles and galvanic cell anodes made therefrom
BE789556A (en) * 1971-10-01 1973-03-29 Union Carbide Corp ZINC BATTERY ALKAIN ELEMENT
CA1086988A (en) * 1978-02-14 1980-10-07 Maheswar Sahoo Magnesium-lithium alloy
US4195120A (en) * 1978-11-03 1980-03-25 P. R. Mallory & Co. Inc. Hydrogen evolution inhibitors for cells having zinc anodes
JPS56143662A (en) * 1980-04-07 1981-11-09 Tamagawa Kikai Kinzoku Kk High strength zinc alloy for dry cell
EP0080064B1 (en) * 1981-11-20 1986-07-30 VARTA Batterie Aktiengesellschaft Galvanic primary element with a negative electroless zinc-plated electrode collector
JPS58218760A (en) * 1982-06-11 1983-12-20 Toshiba Battery Co Ltd Alkaline battery
DE3246957A1 (en) * 1982-12-18 1984-06-20 Varta Batterie Ag, 3000 Hannover GALVANIC ELEMENT
JPS59186253A (en) * 1983-04-01 1984-10-23 インタ−ナショナル ビジネス マシ−ンズ コ−ポレ−ション Electrode of battery
US4487651A (en) * 1983-04-06 1984-12-11 Duracell Inc. Method for making irregular shaped single crystal particles and the use thereof in anodes for electrochemical cells
BR8503252A (en) * 1984-07-09 1986-03-25 Duracell Int ELECTROCHEMICAL BATTERY, PROCESS FOR THE PRODUCTION OF AQUEOUS ELECTRICAL CHEMICAL BATTERY, AND COMPOSITION OF MATERIAL FOR USE IN THE PRODUCTION OF AQUEOUS ELECTROCHEMICAL BATTERY WITH REDUCED YEAST
JPS61131363A (en) * 1984-11-28 1986-06-19 Fuji Elelctrochem Co Ltd Alkaline battery
JPS61131367A (en) * 1984-11-30 1986-06-19 Fuji Elelctrochem Co Ltd Method of processing granular zinc alloy for alkaline battery
JPS61131366A (en) * 1984-11-30 1986-06-19 Fuji Elelctrochem Co Ltd Method of processing granular zinc alloy for alkaline battery

Also Published As

Publication number Publication date
GB8802013D0 (en) 1988-02-24
DE3603342A1 (en) 1986-08-14
CH671304A5 (en) 1989-08-15
NO860475L (en) 1986-08-13
GB2170946B (en) 1989-11-22
AU5324886A (en) 1986-08-21
CA1271217A (en) 1990-07-03
AU594661B2 (en) 1990-03-15
MX163835B (en) 1992-06-25
SE8600606L (en) 1986-08-13
NO169098B (en) 1992-01-27
GB8603413D0 (en) 1986-03-19
IT8619386A0 (en) 1986-02-12
FR2577351A1 (en) 1986-08-14
NL8600347A (en) 1986-09-01
BE904216A (en) 1986-05-29
ES8706854A1 (en) 1987-07-01
GB2170946A (en) 1986-08-13
BR8600570A (en) 1986-10-21
DK66886D0 (en) 1986-02-11
IE57432B1 (en) 1992-09-09
DK66886A (en) 1986-08-13
IT1204791B (en) 1989-03-10
IE860198L (en) 1986-08-12
FR2577351B1 (en) 1989-09-29
GB2200791A (en) 1988-08-10
GB2200791B (en) 1989-11-29
NO169098C (en) 1992-05-06
ES551801A0 (en) 1987-07-01

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Ref document number: 8600606-1

Effective date: 19921029