SE445366B - Forfarande i flera steg for blekning av cellulosa med alkaliska peroxid- och sura kloritlosningar - Google Patents
Forfarande i flera steg for blekning av cellulosa med alkaliska peroxid- och sura kloritlosningarInfo
- Publication number
- SE445366B SE445366B SE7907850A SE7907850A SE445366B SE 445366 B SE445366 B SE 445366B SE 7907850 A SE7907850 A SE 7907850A SE 7907850 A SE7907850 A SE 7907850A SE 445366 B SE445366 B SE 445366B
- Authority
- SE
- Sweden
- Prior art keywords
- concentration
- cellulose
- minutes
- process according
- weight
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 16
- 229910001919 chlorite Inorganic materials 0.000 title claims description 10
- 229910052619 chlorite group Inorganic materials 0.000 title claims description 10
- 239000002253 acid Substances 0.000 title claims description 6
- 150000002978 peroxides Chemical class 0.000 title claims description 4
- QBWCMBCROVPCKQ-UHFFFAOYSA-M chlorite Chemical compound [O-]Cl=O QBWCMBCROVPCKQ-UHFFFAOYSA-M 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 229920002678 cellulose Polymers 0.000 claims description 22
- 239000001913 cellulose Substances 0.000 claims description 22
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 16
- 238000004061 bleaching Methods 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 9
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims description 8
- 159000000003 magnesium salts Chemical class 0.000 claims description 5
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims description 5
- 239000008139 complexing agent Substances 0.000 claims description 4
- 229960002218 sodium chlorite Drugs 0.000 claims description 4
- -1 chlorite compound Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 description 18
- 238000005406 washing Methods 0.000 description 10
- 239000000460 chlorine Substances 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- 241000294754 Macroptilium atropurpureum Species 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 229910052754 neon Inorganic materials 0.000 description 4
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 241000218657 Picea Species 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- 229920002955 Art silk Polymers 0.000 description 2
- 240000005589 Calophyllum inophyllum Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 206010029412 Nightmare Diseases 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- IENXJNLJEDMNTE-UHFFFAOYSA-N acetic acid;ethane-1,2-diamine Chemical compound CC(O)=O.NCCN IENXJNLJEDMNTE-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1057—Multistage, with compounds cited in more than one sub-group D21C9/10, D21C9/12, D21C9/16
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Detergent Compositions (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2841013A DE2841013C2 (de) | 1978-09-21 | 1978-09-21 | Verfahren zur Vollbleiche von Zellstoff |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE7907850L SE7907850L (sv) | 1980-03-22 |
| SE445366B true SE445366B (sv) | 1986-06-16 |
Family
ID=6049994
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7907850A SE445366B (sv) | 1978-09-21 | 1979-09-21 | Forfarande i flera steg for blekning av cellulosa med alkaliska peroxid- och sura kloritlosningar |
Country Status (11)
| Country | Link |
|---|---|
| AT (1) | AT372426B (de) |
| BE (1) | BE878841A (de) |
| BR (1) | BR7905860A (de) |
| CA (1) | CA1122358A (de) |
| CH (1) | CH641515A5 (de) |
| DE (1) | DE2841013C2 (de) |
| FI (1) | FI68681C (de) |
| FR (1) | FR2436846A1 (de) |
| IT (1) | IT1119314B (de) |
| NO (1) | NO153342C (de) |
| SE (1) | SE445366B (de) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3937932A1 (de) * | 1989-11-15 | 1991-05-16 | Holtzmann & Cie Ag E | Verfahren zum delignifizieren und bleichen von ungebleichten zellstoffsuspensionen mit alkalichlorit |
| SE466060C (sv) | 1990-02-13 | 1995-09-11 | Moelnlycke Ab | Absorberande kemitermomekanisk massa och framställning därav |
| US5607546A (en) * | 1990-02-13 | 1997-03-04 | Molnlycke Ab | CTMP-process |
| AU642971B2 (en) * | 1990-02-19 | 1993-11-04 | Paper Australia Pty Ltd | Bleaching of paper pulp |
| NZ237019A (en) * | 1990-02-19 | 1992-11-25 | Amcor Ltd | Bleaching paper pulp by initially treating with oxygen and/or hydrogen peroxide and subsequently treating with a bleaching agent without intervening washing steps |
| US6398908B1 (en) | 1991-04-30 | 2002-06-04 | Eka Nobel Ab | Process for acid bleaching of lignocellulose-containing pulp with a magnesium compound |
| SE500353C2 (sv) * | 1992-10-26 | 1994-06-06 | Sca Wifsta Oestrand Ab | Peroxidblekning av sulfatmassa med tillsats av magnesium före blekningen |
| SE9203366L (sv) * | 1992-11-11 | 1994-05-12 | Mo Och Domsjoe Ab | Förfarande vid delignifiering och/eller blekning av cellulosamassa |
| SE501325E (sv) * | 1993-01-29 | 1999-09-20 | Kvaerner Pulping Tech | Förfarande för klorfri blekning av massa, varvid massan surgöres med ättiksyra vid behandlingen med komplexbildare |
| SE502706E (sv) * | 1994-04-05 | 1999-09-27 | Mo Och Domsjoe Ab | Framställnng av blekt cellulosamassa genom blekning med klordioxid och behandling av komplexbildare i samma steg |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE582239C (de) * | 1929-03-16 | 1933-09-14 | I G Farbenindustrie Akt Ges | Verfahren zum Bleichen von Bastfasern, insbesondere von Leinen und Hanf, in Form von Garnen und Geweben wie auch in Form von Rohfasern unter Verwendung von Superoxyd- und Hypochloritbaedern |
| FR1010501A (fr) * | 1948-08-31 | 1952-06-12 | Papiers Abadie Sa Des | Procédé de blanchîment des pâtes cellulosiques |
| SE335053B (de) * | 1969-05-13 | 1971-05-10 | Mo Och Domsjoe Ab | |
| DE2219504C2 (de) * | 1972-04-21 | 1974-10-03 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Mehrstufenbleiche von Zellstoffen mit erheblich reduziertem Chloreinsatz |
| DE2327900C3 (de) * | 1973-06-01 | 1985-02-07 | Degussa Ag, 6000 Frankfurt | Bleichaufschluß von Zellstoff mit erheblich reduziertem Chloreinsatz |
| DE2721402C2 (de) * | 1977-05-12 | 1984-04-12 | Degussa Ag, 6000 Frankfurt | Verfahren zum Bleichen von Zellstoff |
-
1978
- 1978-09-21 DE DE2841013A patent/DE2841013C2/de not_active Expired
-
1979
- 1979-06-20 NO NO792067A patent/NO153342C/no unknown
- 1979-06-29 IT IT68380/79A patent/IT1119314B/it active
- 1979-07-04 FI FI792115A patent/FI68681C/fi not_active IP Right Cessation
- 1979-07-10 FR FR7917876A patent/FR2436846A1/fr active Granted
- 1979-09-11 CA CA335,412A patent/CA1122358A/en not_active Expired
- 1979-09-13 BR BR7905860A patent/BR7905860A/pt unknown
- 1979-09-17 BE BE6/46946A patent/BE878841A/fr not_active IP Right Cessation
- 1979-09-20 AT AT0620579A patent/AT372426B/de not_active IP Right Cessation
- 1979-09-20 CH CH849479A patent/CH641515A5/de not_active IP Right Cessation
- 1979-09-21 SE SE7907850A patent/SE445366B/sv not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ATA620579A (de) | 1983-02-15 |
| CH641515A5 (en) | 1984-02-29 |
| DE2841013C2 (de) | 1984-06-07 |
| FR2436846B1 (de) | 1982-08-27 |
| NO153342C (no) | 1986-02-26 |
| FI68681B (fi) | 1985-06-28 |
| NO153342B (no) | 1985-11-18 |
| BR7905860A (pt) | 1980-05-20 |
| IT1119314B (it) | 1986-03-10 |
| NO792067L (no) | 1980-03-24 |
| CA1122358A (en) | 1982-04-27 |
| IT7968380A0 (it) | 1979-06-29 |
| AT372426B (de) | 1983-10-10 |
| DE2841013A1 (de) | 1980-04-03 |
| FR2436846A1 (fr) | 1980-04-18 |
| FI792115A7 (fi) | 1980-03-22 |
| SE7907850L (sv) | 1980-03-22 |
| BE878841A (fr) | 1980-03-17 |
| FI68681C (fi) | 1985-10-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
Ref document number: 7907850-7 Effective date: 19880622 Format of ref document f/p: F |