SE440609B - Forfarande for separering och regenerering av rodium-fosfin-katalysatorer - Google Patents
Forfarande for separering och regenerering av rodium-fosfin-katalysatorerInfo
- Publication number
- SE440609B SE440609B SE7703986A SE7703986A SE440609B SE 440609 B SE440609 B SE 440609B SE 7703986 A SE7703986 A SE 7703986A SE 7703986 A SE7703986 A SE 7703986A SE 440609 B SE440609 B SE 440609B
- Authority
- SE
- Sweden
- Prior art keywords
- rodium
- regeneration
- separation
- procedure
- phosphine catalysts
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 title 1
- 230000008929 regeneration Effects 0.000 title 1
- 238000011069 regeneration method Methods 0.000 title 1
- 238000000926 separation method Methods 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
- B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2614799A DE2614799C2 (de) | 1976-04-06 | 1976-04-06 | Verfahren zur Regenerierung von Rhodium enthaltenden Katalysatoren durch Behandeln von rhodiumhaltigen Destillationsrückständen von Hydroformylierungsgemischen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE7703986L SE7703986L (sv) | 1977-10-07 |
| SE440609B true SE440609B (sv) | 1985-08-12 |
Family
ID=5974560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7703986A SE440609B (sv) | 1976-04-06 | 1977-04-05 | Forfarande for separering och regenerering av rodium-fosfin-katalysatorer |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4113754A (enExample) |
| JP (1) | JPS52123397A (enExample) |
| AT (1) | AT347909B (enExample) |
| BE (1) | BE853246A (enExample) |
| CA (1) | CA1093057A (enExample) |
| DE (1) | DE2614799C2 (enExample) |
| ES (1) | ES457530A1 (enExample) |
| FR (1) | FR2347099A1 (enExample) |
| GB (1) | GB1576514A (enExample) |
| IT (1) | IT1085517B (enExample) |
| NL (1) | NL180482C (enExample) |
| SE (1) | SE440609B (enExample) |
| SU (1) | SU898951A3 (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0007768A3 (en) * | 1978-07-27 | 1980-02-20 | DAVY McKEE (LONDON) LIMITED | Hydroformylation of alpha-olefinic compounds |
| US4297239A (en) * | 1979-07-16 | 1981-10-27 | Union Carbide Corporation | Hydroformylation catalyst reactivation |
| US4710587A (en) * | 1980-04-16 | 1987-12-01 | Union Carbide Corp. | Process for removing triorganophosphine from an organic liquid |
| US4363764A (en) * | 1980-12-30 | 1982-12-14 | Union Carbide Corporation | Preparation of rhodium complex compounds |
| GB2097795B (en) * | 1981-05-01 | 1984-08-01 | Johnson Matthey Plc | Recovering triaryl phosphine from poisoned thodium catalyst systems |
| US4388476A (en) * | 1981-05-01 | 1983-06-14 | Eastman Kodak Company | Hydroformylation process with rhodium catalyst and oxygen stabilization thereof |
| US4409149A (en) * | 1981-06-29 | 1983-10-11 | Union Carbide Corporation | Process for producing catalyst precursors |
| DE3126265A1 (de) * | 1981-07-03 | 1983-01-20 | Basf Ag, 6700 Ludwigshafen | Verfahren zur hydroformylierung olefinisch ungesaettigter verbindungen |
| US4446074A (en) * | 1981-12-24 | 1984-05-01 | Union Carbide Corporation | Preparation of rhodium complex compounds |
| US4547595A (en) * | 1982-09-02 | 1985-10-15 | Ashland Oil, Inc. | Method of reactivating Group VIII anionic hydroformylation catalysts |
| US4894477A (en) * | 1986-10-14 | 1990-01-16 | Hoechst Celanese Corporation | Process for regenerating a carbonylation catalyst solution to remove corrosion metals and carbonylation of methanol to acetic acid |
| DE3744213A1 (de) * | 1987-12-24 | 1989-07-06 | Ruhrchemie Ag | Verfahren zur rueckgewinnung von rhodium aus rhodiumkomplexverbindungen enthaltenden waessrigen loesungen |
| DE4034501A1 (de) * | 1990-10-30 | 1992-05-07 | Hoechst Ag | Verfahren zur entfernung metallischer korrosionsprodukte aus wasserfrei betriebenen carbonylierungsreaktionen |
| DE4316180A1 (de) * | 1992-09-16 | 1994-11-17 | Basf Ag | Verfahren zur Herstellung von Aldehyden |
| GB9305902D0 (en) * | 1993-03-22 | 1993-05-12 | Bp Chem Int Ltd | Process |
| BR9606526A (pt) * | 1995-07-18 | 1997-12-23 | Atochem North America Elf | Processo para purificar e seperar o catalisador de ródio ativo do catalisador de ródio anativo contido em uma corrente do processo de hidroformilação composição compreendendo uma resina de troca iônica ácida e processo de hidroformilação aperfeiçoado compreendendo uma reação de hidroformilação de uma olefina com h2 na presença de um complexo de catalisador organo-ródio |
| US5773665A (en) * | 1996-07-01 | 1998-06-30 | Elf Atochem North America, Inc. | Hydroformylation process with separation and recycle of active rhodium catalyst |
| GB0113080D0 (en) * | 2001-05-30 | 2001-07-18 | Kvaerner Process Tech Ltd | Process |
| GB0113079D0 (en) * | 2001-05-30 | 2001-07-18 | Kvaerner Process Tech Ltd | Process |
| RU2628609C2 (ru) * | 2015-12-30 | 2017-08-21 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) | Способ получения альдегидов гидроформилированием с модификацией лигандов ацетализацией |
| CN106187721B (zh) * | 2016-08-25 | 2019-04-02 | 浙江巴陵恒逸己内酰胺有限责任公司 | 利用蒸汽加热导热油进行环己醇脱氢反应的工艺系统 |
| TW201840362A (zh) * | 2016-11-08 | 2018-11-16 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
| TWI758353B (zh) | 2016-11-08 | 2022-03-21 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
| TW201840363A (zh) | 2016-11-08 | 2018-11-16 | 美商陶氏科技投資有限公司 | 處理氫甲醯化催化劑溶液之方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3515757A (en) * | 1966-04-01 | 1970-06-02 | Ethyl Corp | Organic compounds and processes |
| US3547964A (en) * | 1968-07-24 | 1970-12-15 | Union Oil Co | Group viii noble metal catalyst recovery |
| US3560539A (en) * | 1968-08-21 | 1971-02-02 | Union Oil Co | Selective catalyst recovery |
| DE1954315C3 (de) * | 1969-10-29 | 1975-08-14 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Abtrennung von Metallcarbonylkatalysatoren aus Oxoreaktionsge mischen |
| DE2045416C3 (de) * | 1970-09-15 | 1979-10-25 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Elution von Rhodium, das als Rhodiumcarbonylat auf einem basischen Ionenaustauscher gebunden ist |
| AT312559B (de) * | 1972-01-07 | 1974-01-10 | Basf Ag | Verfahren zur Abscheidung von Rhodium aus Rhodiumcarbonylkomplexe enthaltenden Lösungen und Überführung des abgescheidenen Rhodiums in lösliche Rhodiumcarbonylkomplexe |
| IT1007026B (it) * | 1974-01-23 | 1976-10-30 | Montedison Spa | Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione |
| DE2448005C2 (de) * | 1974-10-09 | 1983-10-20 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Regenerierung von Rhodium oder Iridium enthaltenden Katalysatoren aus Destillationsrückständen von Hydroformylierungsgemischen |
-
1976
- 1976-04-06 DE DE2614799A patent/DE2614799C2/de not_active Expired
-
1977
- 1977-03-10 IT IT21148/77A patent/IT1085517B/it active
- 1977-03-23 US US05/780,297 patent/US4113754A/en not_active Expired - Lifetime
- 1977-03-23 CA CA274,599A patent/CA1093057A/en not_active Expired
- 1977-04-01 FR FR7709902A patent/FR2347099A1/fr active Granted
- 1977-04-04 SU SU772466670A patent/SU898951A3/ru active
- 1977-04-05 SE SE7703986A patent/SE440609B/xx not_active IP Right Cessation
- 1977-04-05 ES ES457530A patent/ES457530A1/es not_active Expired
- 1977-04-05 JP JP3817977A patent/JPS52123397A/ja active Granted
- 1977-04-05 BE BE176421A patent/BE853246A/xx not_active IP Right Cessation
- 1977-04-05 NL NLAANVRAGE7703723,A patent/NL180482C/xx not_active IP Right Cessation
- 1977-04-05 GB GB14274/77A patent/GB1576514A/en not_active Expired
- 1977-04-05 AT AT236477A patent/AT347909B/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPS616703B2 (enExample) | 1986-02-28 |
| NL180482C (nl) | 1987-03-02 |
| IT1085517B (it) | 1985-05-28 |
| JPS52123397A (en) | 1977-10-17 |
| ES457530A1 (es) | 1978-03-16 |
| BE853246A (fr) | 1977-10-05 |
| DE2614799C2 (de) | 1986-02-27 |
| FR2347099A1 (fr) | 1977-11-04 |
| DE2614799A1 (de) | 1977-10-27 |
| ATA236477A (de) | 1978-06-15 |
| GB1576514A (en) | 1980-10-08 |
| AT347909B (de) | 1979-01-25 |
| SE7703986L (sv) | 1977-10-07 |
| SU898951A3 (ru) | 1982-01-15 |
| FR2347099B1 (enExample) | 1980-05-09 |
| NL7703723A (nl) | 1977-10-10 |
| CA1093057A (en) | 1981-01-06 |
| US4113754A (en) | 1978-09-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
Ref document number: 7703986-5 Effective date: 19900411 Format of ref document f/p: F |