RU95104891A - Катализатор на основе благородного металла и способ переработки с гидроизомеризацией тяжелого углеводородного сырья - Google Patents

Катализатор на основе благородного металла и способ переработки с гидроизомеризацией тяжелого углеводородного сырья

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Publication number
RU95104891A
RU95104891A RU95104891/04A RU95104891A RU95104891A RU 95104891 A RU95104891 A RU 95104891A RU 95104891/04 A RU95104891/04 A RU 95104891/04A RU 95104891 A RU95104891 A RU 95104891A RU 95104891 A RU95104891 A RU 95104891A
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RU
Russia
Prior art keywords
noble metal
catalyst
raw materials
hydrocarbon raw
hydroisomerization
Prior art date
Application number
RU95104891/04A
Other languages
English (en)
Other versions
RU2141380C1 (ru
Inventor
Миньар Самюель
Fr]
Маршаль Натали
Касзтелан Славик
Бижар Пьер-Анри
Бийон Ален
Original Assignee
Энститю Франсэ дю Петроль (FR)
Энститю Франсэ Дю Петроль
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9403866A external-priority patent/FR2718060B1/fr
Priority claimed from FR9403867A external-priority patent/FR2718144B1/fr
Application filed by Энститю Франсэ дю Петроль (FR), Энститю Франсэ Дю Петроль filed Critical Энститю Франсэ дю Петроль (FR)
Publication of RU95104891A publication Critical patent/RU95104891A/ru
Application granted granted Critical
Publication of RU2141380C1 publication Critical patent/RU2141380C1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/67—Pore distribution monomodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Изобретение относится к катализатору для конверсии углеводородного сырья. Катализатор состоит из 0,05 - 10,0 мас.% благородного металла и носителя из смеси диоксида кремния (5 - 70%) с оксидом алюминия, имеющего удельную поверхность 100 - 50 м. Катализатор имеет средний диаметр пор 1-12 нм; объем пор, диаметр которых составляет величину между средним диаметром ±3 нм, более 40% общего парового объема; дисперсию благородного металла 20 - 100% и коэффициент распределения благородного металла выше 0,1. Изобретение также относится к способу переработки с гидроизомеризацией сырья с температурами кипения выше 350С при использовании вышеуказанного катализатора. Способ осуществляют при 200 - 450С под давлением 2 - 25 МПа и с объемной почасовой скоростью 0,1-10,0 чи объемным отношением водород/сырье 100 - 2000.

Claims (1)

  1. Изобретение относится к катализатору для конверсии углеводородного сырья. Катализатор состоит из 0,05 - 10,0 мас.% благородного металла и носителя из смеси диоксида кремния (5 - 70%) с оксидом алюминия, имеющего удельную поверхность 100 - 50 м2. Катализатор имеет средний диаметр пор 1-12 нм; объем пор, диаметр которых составляет величину между средним диаметром ±3 нм, более 40% общего парового объема; дисперсию благородного металла 20 - 100% и коэффициент распределения благородного металла выше 0,1. Изобретение также относится к способу переработки с гидроизомеризацией сырья с температурами кипения выше 350oС при использовании вышеуказанного катализатора. Способ осуществляют при 200 - 450oС под давлением 2 - 25 МПа и с объемной почасовой скоростью 0,1-10,0 ч-1 и объемным отношением водород/сырье 100 - 2000.
RU95104891A 1994-04-01 1995-03-31 Катализатор для гидроконверсии с гидроизомеризацией углеводородного сырья и способ переработки с гидроизомеризацией тяжелых нефтяных углеводородных фракций RU2141380C1 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR9403866A FR2718060B1 (fr) 1994-04-01 1994-04-01 Catalyseur pour la conversion de charges hydrocarbonées, à base de métal noble et silice-alumine.
FR9403866 1994-04-01
FR9403867A FR2718144B1 (fr) 1994-04-01 1994-04-01 Procédé de traitement avec hydroisomérisation de charges lourdes.
FR9403867 1994-04-01

Publications (2)

Publication Number Publication Date
RU95104891A true RU95104891A (ru) 1996-12-27
RU2141380C1 RU2141380C1 (ru) 1999-11-20

Family

ID=26231063

Family Applications (1)

Application Number Title Priority Date Filing Date
RU95104891A RU2141380C1 (ru) 1994-04-01 1995-03-31 Катализатор для гидроконверсии с гидроизомеризацией углеводородного сырья и способ переработки с гидроизомеризацией тяжелых нефтяных углеводородных фракций

Country Status (10)

Country Link
US (1) US5879539A (ru)
EP (1) EP0701480B1 (ru)
JP (1) JP3843345B2 (ru)
KR (1) KR100336723B1 (ru)
CN (1) CN1071134C (ru)
DE (1) DE69511974T2 (ru)
ES (1) ES2138730T3 (ru)
NO (1) NO311501B1 (ru)
RU (1) RU2141380C1 (ru)
WO (1) WO1995026819A1 (ru)

Families Citing this family (14)

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Publication number Priority date Publication date Assignee Title
CN1123383C (zh) * 1997-09-10 2003-10-08 中国石油化工集团公司 一种无定形硅铝及其制备方法
NL1015035C2 (nl) * 1999-04-29 2001-02-12 Inst Francais Du Petrole Flexibel proces voor de productie van basisoliÙn en destillatieproducten door een omzetting-hydroisomerisatie op een weinig gedispergeerde katalysator, gevolgd door een katalytische ontparaffinering.
FR2792851B1 (fr) * 1999-04-29 2002-04-05 Inst Francais Du Petrole Catalyseur a base de metal noble faiblement disperse et son utilisation pour la conversion de charges hydrocarbonees
CN1102077C (zh) * 1999-06-25 2003-02-26 李海 一种支撑、复盖催化剂的保护剂及其制造方法
FR2846574B1 (fr) * 2002-10-30 2006-05-26 Inst Francais Du Petrole Catalyseur et procede d'hydrocraquage de charges hydrocarbonees
US7030053B2 (en) * 2002-11-06 2006-04-18 Conocophillips Company Catalyst composition comprising ruthenium and a treated silica support component and processes therefor and therewith for preparing high molecular weight hydrocarbons such as polymethylene
US6902664B2 (en) * 2002-11-08 2005-06-07 Chevron U.S.A. Inc. Extremely low acidity USY and homogeneous, amorphous silica-alumina hydrocracking catalyst and process
US6995112B2 (en) * 2002-11-08 2006-02-07 Chevron U.S.A. Inc. Highly homogeneous amorphous silica-alumina catalyst composition
FR2851569B1 (fr) * 2003-02-21 2007-04-20 Inst Francais Du Petrole Procede d'hydrocraquage en deux etapes utilisant un catalyseur amorphe a base de platine et de palladium
US7943547B2 (en) * 2005-09-14 2011-05-17 Hamilton Sundstrand Space Systems International, Inc. Selective catalytic oxidation of ammonia to water and nitrogen
US8114806B2 (en) 2008-04-10 2012-02-14 Shell Oil Company Catalysts having selected pore size distributions, method of making such catalysts, methods of producing a crude product, products obtained from such methods, and uses of products obtained
US9187702B2 (en) * 2009-07-01 2015-11-17 Chevron U.S.A. Inc. Hydroprocessing catalyst and method of making the same
JP5745538B2 (ja) * 2009-12-15 2015-07-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 芳香族化合物水素化用触媒とその方法
US11559789B2 (en) * 2021-03-11 2023-01-24 Chevron U.S.A. Inc. Base oil hydrotreating catalyst and process of use

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6021802A (ja) * 1983-07-15 1985-02-04 Daido Sanso Kk 均一な細孔を有する金属酸化物、その製造方法およびその金属酸化物からなる触媒用担体
FR2563120A1 (fr) * 1984-04-23 1985-10-25 Leuna Werke Veb Catalyseur pour le reformage d'hydrocarbures, et procede pour sa fabrication
DD223077B1 (de) * 1984-04-23 1989-04-12 Leuna Werke Veb Verfahren zur herstellung eines katalysators fuer die kohlenwasserstoffreformierung
JPS6115739A (ja) * 1984-04-25 1986-01-23 Toa Nenryo Kogyo Kk 水素化処理用触媒
FR2565504B1 (fr) * 1984-06-07 1986-08-29 Inst Francais Du Petrole Procede de fabrication d'un catalyseur d'hydrocraquage de fractions petrolieres lourdes
US5157187A (en) * 1991-01-02 1992-10-20 Mobil Oil Corp. Hydroisomerization process for pour point reduction of long chain alkyl aromatic compounds
US5187138A (en) * 1991-09-16 1993-02-16 Exxon Research And Engineering Company Silica modified hydroisomerization catalyst

Also Published As

Publication number Publication date
DE69511974D1 (de) 1999-10-14
JP3843345B2 (ja) 2006-11-08
NO954876L (no) 1995-11-30
CN1125912A (zh) 1996-07-03
KR100336723B1 (ko) 2002-11-18
EP0701480A1 (fr) 1996-03-20
JPH08511199A (ja) 1996-11-26
KR960702770A (ko) 1996-05-23
ES2138730T3 (es) 2000-01-16
EP0701480B1 (fr) 1999-09-08
DE69511974T2 (de) 2000-05-31
NO954876D0 (no) 1995-11-30
WO1995026819A1 (fr) 1995-10-12
NO311501B1 (no) 2001-12-03
CN1071134C (zh) 2001-09-19
RU2141380C1 (ru) 1999-11-20
US5879539A (en) 1999-03-09

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