RU2759004C1 - Способ получения катализатора олигомеризации этилена и его олигомеризация - Google Patents

Способ получения катализатора олигомеризации этилена и его олигомеризация Download PDF

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RU2759004C1
RU2759004C1 RU2020139816A RU2020139816A RU2759004C1 RU 2759004 C1 RU2759004 C1 RU 2759004C1 RU 2020139816 A RU2020139816 A RU 2020139816A RU 2020139816 A RU2020139816 A RU 2020139816A RU 2759004 C1 RU2759004 C1 RU 2759004C1
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zirconium
compound
additive
ethylene
aluminum
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RU2020139816A
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Russian (ru)
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Гурмит Сингх
Рашми РАНИ
Сукхдип КАУР
Дхир СИНГХ
Анджу ЧОПРА
Гурприт Сингх КАПУР
Шанкара Шри Венката РАМАКУМАР
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Индиан Оил Корпорейшн Лимитед
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0209—Esters of carboxylic or carbonic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2217—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/40—Non-coordinating groups comprising nitrogen
    • B01J2540/44—Non-coordinating groups comprising nitrogen being derivatives of carboxylic or carbonic acids, e.g. amide (RC(=O)-NR2, RC(=O)-NR-C(=O)R), nitrile, urea (R2N-C(=O)-NR2), guanidino (R2N-C(=NR)-NR2) groups
    • B01J2540/442—Amide groups or imidato groups (R-C=NR(OR))
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    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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RU2020139816A 2019-12-11 2020-12-04 Способ получения катализатора олигомеризации этилена и его олигомеризация RU2759004C1 (ru)

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KR (1) KR102459568B1 (enExample)
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2821397C2 (ru) * 2021-11-23 2024-06-24 Индиан Оил Корпорейшн Лимитед Способ и каталитическая композиция для получения линейных альфа-олефинов с высоким выходом олигомеризацией этилена

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11667590B2 (en) * 2021-05-26 2023-06-06 Chevron Phillips Chemical Company, Lp Ethylene oligomerization processes
KR102392332B1 (ko) 2021-06-08 2022-04-28 에스케이씨솔믹스 주식회사 블랭크 마스크 및 이를 이용한 포토마스크
EP4183486A1 (en) * 2021-11-23 2023-05-24 Indian Oil Corporation Limited Process and catalyst composition for producing linear alpha olefins in high yield by ethylene oligomerization
EP4524143A1 (en) * 2023-09-15 2025-03-19 LANXESS Organometallics GmbH Efficient preperation of organo alumnium chloride compounds

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WO1980000224A1 (fr) * 1978-07-19 1980-02-21 Inst Khim Fiz An Sssr Catalyseur d'oligomerisation de l'ethylene en alpha-olefines superieures
US4855525A (en) * 1987-06-19 1989-08-08 Exxon Chemical Patents Inc. Process for preparing linear alpha-olefins using zirconium adducts as catalysts
US5496783A (en) * 1992-07-09 1996-03-05 Institut Francais Du Petrole Catalyst for the production of light alpha olefins by oligomerization of ethylene
WO2003050126A1 (en) * 2001-12-13 2003-06-19 Polimeri Europa S.P.A. Complexes with sulfonic ligands for selective oligomerization of ethylene
RU2410367C2 (ru) * 2005-04-08 2011-01-27 Сауди Бейсик Индастриз Корпорейшн СПОСОБ ПОЛУЧЕНИЯ ЛИНЕЙНЫХ ОЛИГОМЕРОВ α-ОЛЕФИНОВ
RU2456076C2 (ru) * 2007-12-06 2012-07-20 Линде Аг Композиция катализатора и способ получения линейных альфа-олефинов
RU2462309C2 (ru) * 2007-12-12 2012-09-27 Сауди Бейсик Индастриз Корпорейшн Композиция катализатора для олигомеризации этилена, способ олигомеризации и способ получения композиции катализатора

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US4361714A (en) 1981-12-14 1982-11-30 Exxon Research And Engineering Co. Preparation of linear olefin products
EP0241596B1 (en) 1986-04-17 1990-10-31 Idemitsu Petrochemical Co. Ltd. A process for preparing linear alpha-olefins
JP2538811B2 (ja) 1990-10-19 1996-10-02 出光石油化学株式会社 線状α―オレフィンの製造方法
KR0160424B1 (ko) * 1994-06-01 1999-01-15 윤종용 냉장고
JP4152696B2 (ja) 2002-08-28 2008-09-17 独立行政法人科学技術振興機構 エステル縮合物の製造方法
ES2352741T3 (es) 2005-08-31 2011-02-22 Saudi Basic Industries Corporation Proceso para la preparación de alfa-olefinas lineales y catalizador utilizado en el mismo.
EP1981832A2 (en) 2006-02-08 2008-10-22 Saudi Basic Industries Corporation A catalyst composition and a process for the oligomerization of ethylene
JP5984173B2 (ja) * 2012-09-24 2016-09-06 インディアン オイル コーポレーション リミテッド オレフィン重合用の触媒を調製するプロセス
JP6739186B2 (ja) 2016-02-19 2020-08-12 三井化学株式会社 オレフィン重合体の製造方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1980000224A1 (fr) * 1978-07-19 1980-02-21 Inst Khim Fiz An Sssr Catalyseur d'oligomerisation de l'ethylene en alpha-olefines superieures
US4855525A (en) * 1987-06-19 1989-08-08 Exxon Chemical Patents Inc. Process for preparing linear alpha-olefins using zirconium adducts as catalysts
US5496783A (en) * 1992-07-09 1996-03-05 Institut Francais Du Petrole Catalyst for the production of light alpha olefins by oligomerization of ethylene
WO2003050126A1 (en) * 2001-12-13 2003-06-19 Polimeri Europa S.P.A. Complexes with sulfonic ligands for selective oligomerization of ethylene
RU2410367C2 (ru) * 2005-04-08 2011-01-27 Сауди Бейсик Индастриз Корпорейшн СПОСОБ ПОЛУЧЕНИЯ ЛИНЕЙНЫХ ОЛИГОМЕРОВ α-ОЛЕФИНОВ
RU2456076C2 (ru) * 2007-12-06 2012-07-20 Линде Аг Композиция катализатора и способ получения линейных альфа-олефинов
RU2462309C2 (ru) * 2007-12-12 2012-09-27 Сауди Бейсик Индастриз Корпорейшн Композиция катализатора для олигомеризации этилена, способ олигомеризации и способ получения композиции катализатора

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2821397C2 (ru) * 2021-11-23 2024-06-24 Индиан Оил Корпорейшн Лимитед Способ и каталитическая композиция для получения линейных альфа-олефинов с высоким выходом олигомеризацией этилена

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ES2932156T3 (es) 2023-01-13
KR20210074221A (ko) 2021-06-21
IN201921051272A (enExample) 2022-01-06
EP3834932A1 (en) 2021-06-16
CN112934266A (zh) 2021-06-11
JP7212027B2 (ja) 2023-01-24
EP3834932B1 (en) 2022-10-05
KR102459568B1 (ko) 2022-10-27
JP2021090959A (ja) 2021-06-17
US11344871B2 (en) 2022-05-31

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