RU2678072C2 - Порошковый оксид цинка с допирующими добавками ионов марганца, железа и меди - Google Patents
Порошковый оксид цинка с допирующими добавками ионов марганца, железа и меди Download PDFInfo
- Publication number
- RU2678072C2 RU2678072C2 RU2015115886A RU2015115886A RU2678072C2 RU 2678072 C2 RU2678072 C2 RU 2678072C2 RU 2015115886 A RU2015115886 A RU 2015115886A RU 2015115886 A RU2015115886 A RU 2015115886A RU 2678072 C2 RU2678072 C2 RU 2678072C2
- Authority
- RU
- Russia
- Prior art keywords
- component
- manganese
- iron
- dopant
- copper
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 103
- 239000002019 doping agent Substances 0.000 title claims abstract description 59
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 49
- 239000010949 copper Substances 0.000 title claims abstract description 46
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 36
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 29
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title description 30
- 239000011787 zinc oxide Substances 0.000 title description 15
- 150000002500 ions Chemical class 0.000 title 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 title 1
- 239000011572 manganese Substances 0.000 claims abstract description 58
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 48
- 125000002091 cationic group Chemical group 0.000 claims abstract description 47
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 39
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 32
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 32
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 16
- 239000011701 zinc Substances 0.000 claims abstract description 16
- 230000000475 sunscreen effect Effects 0.000 claims abstract description 10
- 239000000516 sunscreening agent Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims description 16
- 239000012255 powdered metal Substances 0.000 claims description 12
- 238000010521 absorption reaction Methods 0.000 abstract description 31
- 238000000034 method Methods 0.000 abstract description 6
- 238000001228 spectrum Methods 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000002537 cosmetic Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000005670 electromagnetic radiation Effects 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 description 27
- -1 oxygen anions Chemical class 0.000 description 26
- 239000000243 solution Substances 0.000 description 25
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 16
- 235000014692 zinc oxide Nutrition 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 12
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 11
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 11
- 239000011565 manganese chloride Substances 0.000 description 11
- 235000002867 manganese chloride Nutrition 0.000 description 11
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 8
- 238000003980 solgel method Methods 0.000 description 7
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 6
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000002835 absorbance Methods 0.000 description 5
- 235000002639 sodium chloride Nutrition 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- WOSISLOTWLGNKT-UHFFFAOYSA-L iron(2+);dichloride;hexahydrate Chemical compound O.O.O.O.O.O.Cl[Fe]Cl WOSISLOTWLGNKT-UHFFFAOYSA-L 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 230000003595 spectral effect Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 208000000453 Skin Neoplasms Diseases 0.000 description 3
- 229910001431 copper ion Inorganic materials 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000004071 biological effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000338 in vitro Methods 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 201000000849 skin cancer Diseases 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000007704 wet chemistry method Methods 0.000 description 2
- 239000004246 zinc acetate Substances 0.000 description 2
- 229960000314 zinc acetate Drugs 0.000 description 2
- 235000013904 zinc acetate Nutrition 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 206010040799 Skin atrophy Diseases 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229940063656 aluminum chloride Drugs 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229940057499 anhydrous zinc acetate Drugs 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 229940032296 ferric chloride Drugs 0.000 description 1
- 229960001781 ferrous sulfate Drugs 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- 229940071125 manganese acetate Drugs 0.000 description 1
- 229940099607 manganese chloride Drugs 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 201000001441 melanoma Diseases 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052699 polonium Inorganic materials 0.000 description 1
- HZEBHPIOVYHPMT-UHFFFAOYSA-N polonium atom Chemical compound [Po] HZEBHPIOVYHPMT-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000037072 sun protection Effects 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- YZYKBQUWMPUVEN-UHFFFAOYSA-N zafuleptine Chemical compound OC(=O)CCCCCC(C(C)C)NCC1=CC=C(F)C=C1 YZYKBQUWMPUVEN-UHFFFAOYSA-N 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- DJWUNCQRNNEAKC-UHFFFAOYSA-L zinc acetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 229960001939 zinc chloride Drugs 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/006—Compounds containing, besides zinc, two ore more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/02—Oxides; Hydroxides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/61—Surface treated
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/65—Characterized by the composition of the particulate/core
- A61K2800/651—The particulate/core comprising inorganic material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Compounds Of Iron (AREA)
- Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/269,416 | 2014-05-05 | ||
| US14/269,416 US9144536B1 (en) | 2014-05-05 | 2014-05-05 | Particulate zinc oxide with manganese, iron and copper dopant ions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2015115886A RU2015115886A (ru) | 2016-11-20 |
| RU2015115886A3 RU2015115886A3 (de) | 2018-08-27 |
| RU2678072C2 true RU2678072C2 (ru) | 2019-01-22 |
Family
ID=53054903
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015115886A RU2678072C2 (ru) | 2014-05-05 | 2015-04-27 | Порошковый оксид цинка с допирующими добавками ионов марганца, железа и меди |
Country Status (9)
| Country | Link |
|---|---|
| US (3) | US9144536B1 (de) |
| EP (1) | EP2947050B1 (de) |
| KR (1) | KR102397505B1 (de) |
| CN (1) | CN105084411B (de) |
| AU (1) | AU2015202309B2 (de) |
| BR (1) | BR102015010065B8 (de) |
| CA (1) | CA2890509C (de) |
| ES (1) | ES2624615T3 (de) |
| RU (1) | RU2678072C2 (de) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9144536B1 (en) * | 2014-05-05 | 2015-09-29 | Johnson & Johnson Consumer Inc. | Particulate zinc oxide with manganese, iron and copper dopant ions |
| EP3273932A1 (de) | 2015-03-24 | 2018-01-31 | Landa Labs (2012) Ltd. | Uv-schutzzusammensetzungen und deren verwendung |
| US10682294B2 (en) | 2015-09-03 | 2020-06-16 | International Business Machines Corporation | Controlling zinc oxide particle size for sunscreen applications |
| US10952942B2 (en) | 2015-09-03 | 2021-03-23 | International Business Machines Corporation | Plasmonic enhancement of zinc oxide light absorption for sunscreen applications |
| US10772808B2 (en) | 2015-09-03 | 2020-09-15 | International Business Machines Corporation | Anti-reflective coating on oxide particles for sunscreen applications |
| US9883994B2 (en) | 2015-09-03 | 2018-02-06 | International Business Machines Corporation | Implementing organic materials in sunscreen applications |
| US9883993B2 (en) | 2015-09-03 | 2018-02-06 | International Business Machines Corporation | Notch filter coatings for use in sunscreen applications |
| US10369092B2 (en) | 2015-09-03 | 2019-08-06 | International Business Machines Corporation | Nitride-based nanoparticles for use in sunscreen applications |
| US9993402B2 (en) | 2015-09-03 | 2018-06-12 | International Business Machines Corporation | Sunscreen additives for enhancing vitamin D production |
| US9937112B2 (en) | 2015-09-03 | 2018-04-10 | International Business Machines Corporation | Doping of zinc oxide particles for sunscreen applications |
| US10092487B2 (en) | 2015-10-22 | 2018-10-09 | International Business Machines Corporation | Plasmonic enhancement of absorption in sunscreen applications |
| US10045918B2 (en) | 2015-10-22 | 2018-08-14 | International Business Machines Corporation | Embedding oxide particles within separate particles for sunscreen applications |
| US10076475B2 (en) | 2015-10-23 | 2018-09-18 | International Business Machines Corporation | Shell-structured particles for sunscreen applications |
| US11931379B2 (en) | 2015-12-22 | 2024-03-19 | Johnson & Johnson Consumer Inc. | Stable foaming composition and method of use |
| US10278905B1 (en) | 2017-11-07 | 2019-05-07 | Johnson And Johnson Consumer Inc. | Sprayable compositions containing metal oxides |
| CN110697759A (zh) * | 2019-09-25 | 2020-01-17 | 安徽省含山县锦华氧化锌厂 | 一种吸收紫外线的纳米氧化锌 |
| US11590064B2 (en) | 2019-10-04 | 2023-02-28 | Johnson & Johnson Consumer Inc. | Sprayable sunscreen composition |
| US11291621B2 (en) | 2019-10-04 | 2022-04-05 | Johnson & Johnson Consumer Inc. | Transparent sunscreen composition |
| CN111333102A (zh) * | 2020-04-22 | 2020-06-26 | 安徽锦华氧化锌有限公司 | 一种用于除硫剂的氧化锌制备方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5198025A (en) * | 1990-10-20 | 1993-03-30 | Basf Aktiengesellschaft | Preparation of metal oxide-doped zinc oxide pigments |
| WO2004058209A2 (en) * | 2002-12-24 | 2004-07-15 | Oxonica Limited | Sunscreens |
| US6869596B1 (en) * | 1998-05-27 | 2005-03-22 | Isis Innovation Limited | Ultraviolet light screening compositions |
| US20060104925A1 (en) * | 1999-12-01 | 2006-05-18 | Oxonica Limited | Particle comprising a host lattice and a guest, its preparation and use in ultraviolet light screening compositions |
| US20080031832A1 (en) * | 2004-01-28 | 2008-02-07 | Oxonica Limited | Surface-Doped Particles Of Ti02 Or Zno And Their Use |
| RU2465982C1 (ru) * | 2011-07-15 | 2012-11-10 | Учреждение Российской академии наук Институт электрофизики Уральского отделения РАН (ИЭФ УрО РАН) | Способ получения нанопорошков оксида цинка, допированных медью, методом электрического взрыва проволоки |
| RU2514085C2 (ru) * | 2012-06-20 | 2014-04-27 | Закрытое акционерное общество "Научно-производственная фирма "Магнетон Варистор" | Керамический материал для варисторов на основе оксида цинка |
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| WO1993011135A1 (en) * | 1991-11-27 | 1993-06-10 | Richardson-Vicks Inc. | Process for preparing uva-absorbing sunscreen metal complexes |
| US5441726A (en) | 1993-04-28 | 1995-08-15 | Sunsmart, Inc. | Topical ultra-violet radiation protectants |
| DE19537480A1 (de) * | 1995-10-09 | 1997-04-10 | Basf Ag | Verwendung von mit Metalloxiden dotierten Zinkoxiden für kosmetische Zwecke |
| GB0230156D0 (en) * | 2002-12-24 | 2003-02-05 | Oxonica Ltd | Sunscreens |
| GB0315656D0 (en) * | 2003-07-03 | 2003-08-13 | Oxonica Ltd | Metal oxide formulations |
| US20060111955A1 (en) | 2004-11-24 | 2006-05-25 | Agilis Systems, Inc. | System and method for mobile resource management with customer confirmation |
| GB0426820D0 (en) | 2004-12-07 | 2005-01-12 | Oxonica Ltd | Anti-aging composition |
| US20110150792A1 (en) * | 2008-12-10 | 2011-06-23 | Yun Shao | Zinc oxide aqueous and non-aqueous dispersions |
| DE102007005186A1 (de) | 2007-01-29 | 2008-07-31 | Merck Patent Gmbh | Partikuläres UV-Schutzmittel |
| CN101879439A (zh) * | 2009-05-08 | 2010-11-10 | 中国科学院兰州化学物理研究所 | 一种复合氧化物的制备方法 |
| JP2013224244A (ja) | 2012-03-19 | 2013-10-31 | Ngk Insulators Ltd | エアロゾルデポジション法に用いられる酸化亜鉛原料粉末 |
| US9144536B1 (en) * | 2014-05-05 | 2015-09-29 | Johnson & Johnson Consumer Inc. | Particulate zinc oxide with manganese, iron and copper dopant ions |
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2014
- 2014-05-05 US US14/269,416 patent/US9144536B1/en active Active
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2015
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- 2015-04-30 KR KR1020150061290A patent/KR102397505B1/ko active IP Right Grant
- 2015-05-01 AU AU2015202309A patent/AU2015202309B2/en active Active
- 2015-05-04 CA CA2890509A patent/CA2890509C/en active Active
- 2015-05-04 BR BR102015010065A patent/BR102015010065B8/pt active IP Right Grant
- 2015-05-05 ES ES15166404.2T patent/ES2624615T3/es active Active
- 2015-05-05 CN CN201510224783.6A patent/CN105084411B/zh active Active
- 2015-05-05 EP EP15166404.2A patent/EP2947050B1/de active Active
- 2015-09-23 US US14/862,622 patent/US20160008240A1/en not_active Abandoned
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2016
- 2016-07-25 US US15/218,208 patent/US20160331656A1/en not_active Abandoned
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5198025A (en) * | 1990-10-20 | 1993-03-30 | Basf Aktiengesellschaft | Preparation of metal oxide-doped zinc oxide pigments |
| US6869596B1 (en) * | 1998-05-27 | 2005-03-22 | Isis Innovation Limited | Ultraviolet light screening compositions |
| US20060104925A1 (en) * | 1999-12-01 | 2006-05-18 | Oxonica Limited | Particle comprising a host lattice and a guest, its preparation and use in ultraviolet light screening compositions |
| WO2004058209A2 (en) * | 2002-12-24 | 2004-07-15 | Oxonica Limited | Sunscreens |
| US20080031832A1 (en) * | 2004-01-28 | 2008-02-07 | Oxonica Limited | Surface-Doped Particles Of Ti02 Or Zno And Their Use |
| RU2465982C1 (ru) * | 2011-07-15 | 2012-11-10 | Учреждение Российской академии наук Институт электрофизики Уральского отделения РАН (ИЭФ УрО РАН) | Способ получения нанопорошков оксида цинка, допированных медью, методом электрического взрыва проволоки |
| RU2514085C2 (ru) * | 2012-06-20 | 2014-04-27 | Закрытое акционерное общество "Научно-производственная фирма "Магнетон Варистор" | Керамический материал для варисторов на основе оксида цинка |
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| AU2015202309A1 (en) | 2015-11-19 |
| US20160331656A1 (en) | 2016-11-17 |
| CN105084411B (zh) | 2018-11-23 |
| CA2890509C (en) | 2022-09-06 |
| US20160008240A1 (en) | 2016-01-14 |
| EP2947050A1 (de) | 2015-11-25 |
| KR102397505B1 (ko) | 2022-05-13 |
| KR20150126782A (ko) | 2015-11-13 |
| BR102015010065B1 (pt) | 2021-12-21 |
| RU2015115886A3 (de) | 2018-08-27 |
| EP2947050B1 (de) | 2017-03-22 |
| BR102015010065A2 (pt) | 2016-06-21 |
| US9144536B1 (en) | 2015-09-29 |
| BR102015010065B8 (pt) | 2022-08-30 |
| ES2624615T3 (es) | 2017-07-17 |
| AU2015202309B2 (en) | 2018-12-06 |
| CA2890509A1 (en) | 2015-11-05 |
| RU2015115886A (ru) | 2016-11-20 |
| CN105084411A (zh) | 2015-11-25 |
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