RU2632869C2 - Дегидратирование содержащего воду источника формальдегида и способ получения сложного эфира этилен-ненасыщенной карбоновой кислоты - Google Patents

Дегидратирование содержащего воду источника формальдегида и способ получения сложного эфира этилен-ненасыщенной карбоновой кислоты Download PDF

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RU2632869C2
RU2632869C2 RU2014137472A RU2014137472A RU2632869C2 RU 2632869 C2 RU2632869 C2 RU 2632869C2 RU 2014137472 A RU2014137472 A RU 2014137472A RU 2014137472 A RU2014137472 A RU 2014137472A RU 2632869 C2 RU2632869 C2 RU 2632869C2
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Prior art keywords
water
formaldehyde
source
zeolite membrane
carboxylic acid
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RU2014137472A
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English (en)
Russian (ru)
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RU2014137472A (ru
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Йосиюки ХИМЕНО
Кен ООЯТИ
Масахиде КОНДО
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ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
    • B01D61/362—Pervaporation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/448—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by pervaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/028—Molecular sieves
    • B01D71/0281—Zeolites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/786—Separation; Purification; Stabilisation; Use of additives by membrane separation process, e.g. pervaporation, perstraction, reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/56—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/34—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/79—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
RU2014137472A 2012-02-17 2013-02-18 Дегидратирование содержащего воду источника формальдегида и способ получения сложного эфира этилен-ненасыщенной карбоновой кислоты RU2632869C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/JP2012/054498 WO2013121594A1 (en) 2012-02-17 2012-02-17 Dehydration of water containing source of formaldehyde, and a method for producing an ethylenically unsaturated carboxylic ester
JPPCT/JP2012/054498 2012-02-17
PCT/JP2013/054639 WO2013122268A1 (en) 2012-02-17 2013-02-18 Dehydration of water containing source of formaldehyde, and a method for producing an ethylenically unsaturated carboxylic ester

Publications (2)

Publication Number Publication Date
RU2014137472A RU2014137472A (ru) 2016-04-10
RU2632869C2 true RU2632869C2 (ru) 2017-10-11

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RU2014137472A RU2632869C2 (ru) 2012-02-17 2013-02-18 Дегидратирование содержащего воду источника формальдегида и способ получения сложного эфира этилен-ненасыщенной карбоновой кислоты

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US (2) US10093559B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (2) EP4029593A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JP6391744B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
KR (1) KR102058178B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CN (1) CN104254389B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU2013221193B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BR (1) BR112014020319B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA2864701C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ES (1) ES2913076T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IN (1) IN2014MN01685A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
MX (1) MX367141B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
MY (1) MY173232A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
RU (1) RU2632869C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
SG (1) SG11201404923SA (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TW (1) TWI582071B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (2) WO2013121594A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (5)

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Publication number Priority date Publication date Assignee Title
DE102014112021A1 (de) 2014-08-22 2016-02-25 Karlsruher Institut für Technologie Verfahren zur Herstellung von Oxymethylendialkylethern und deren Verwendung
US10377689B2 (en) 2016-11-17 2019-08-13 OME Technologies GmbH Process for preparing polyoxymethylene dimethyl ethers from formaldehyde and methanol in aqueous solutions
DE102016222657A1 (de) 2016-11-17 2018-05-17 OME Technologies GmbH Verfahren zur Herstellung von Polyoxymethylendimethylethern aus Formaldehyd und Methanol in wässrigen Lösungen
CN106831380B (zh) * 2017-01-19 2020-05-22 中国科学院成都有机化学有限公司 甲醛溶液脱水浓缩的方法
CN117482988A (zh) * 2023-06-19 2024-02-02 中国科学院过程工程研究所 一种用于合成丙烯酸甲酯的催化剂制备方法

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SU141148A1 (ru) * 1960-12-14 1961-11-30 В.Б. Коган Метод концентрировани водных растворов формальдегида
GB1107234A (en) * 1965-10-22 1968-03-27 Air Reduction Production of acrylate and methacrylate esters
US4035291A (en) * 1970-06-16 1977-07-12 Monsanto Company Process for separating aqueous formaldehyde mixtures
WO1999064387A1 (en) * 1998-06-05 1999-12-16 Ineos Acrylics Uk Limited Dewatering process
DE10004562A1 (de) * 2000-02-02 2001-08-09 Basf Ag Verfahren zur Herstellung von alkoholischen Formaldehydlösungen mittels Membrantrennverfahren

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DE4337231A1 (de) * 1993-10-30 1995-05-04 Basf Ag Verfahren zur Gewinnung konzentrierter wäßriger Formaldehydlösungen durch Pervaporation
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JP3686262B2 (ja) 1998-07-27 2005-08-24 三井造船株式会社 混合物分離膜
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JP5135671B2 (ja) 2005-09-28 2013-02-06 三菱化学株式会社 ゼオライト分離膜の製造方法
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SU141148A1 (ru) * 1960-12-14 1961-11-30 В.Б. Коган Метод концентрировани водных растворов формальдегида
GB1107234A (en) * 1965-10-22 1968-03-27 Air Reduction Production of acrylate and methacrylate esters
US4035291A (en) * 1970-06-16 1977-07-12 Monsanto Company Process for separating aqueous formaldehyde mixtures
WO1999064387A1 (en) * 1998-06-05 1999-12-16 Ineos Acrylics Uk Limited Dewatering process
DE10004562A1 (de) * 2000-02-02 2001-08-09 Basf Ag Verfahren zur Herstellung von alkoholischen Formaldehydlösungen mittels Membrantrennverfahren

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Publication number Publication date
MX2014009868A (es) 2015-06-05
IN2014MN01685A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 2015-05-29
US20150053616A1 (en) 2015-02-26
MY173232A (en) 2020-01-07
RU2014137472A (ru) 2016-04-10
ES2913076T3 (es) 2022-05-31
WO2013121594A1 (en) 2013-08-22
JP6391744B2 (ja) 2018-09-19
SG11201404923SA (en) 2014-09-26
CA2864701A1 (en) 2013-08-22
US20190062181A1 (en) 2019-02-28
US10793448B2 (en) 2020-10-06
KR102058178B1 (ko) 2019-12-20
EP2814596B1 (en) 2022-04-06
AU2013221193B2 (en) 2017-11-23
AU2013221193A1 (en) 2014-09-11
CN104254389A (zh) 2014-12-31
CN104254389B (zh) 2017-05-31
MX367141B (es) 2019-08-07
JP2017137335A (ja) 2017-08-10
TWI582071B (zh) 2017-05-11
TW201336821A (zh) 2013-09-16
US10093559B2 (en) 2018-10-09
KR20140129199A (ko) 2014-11-06
WO2013122268A1 (en) 2013-08-22
BR112014020319B1 (pt) 2021-05-04
CA2864701C (en) 2022-04-26
EP2814596A1 (en) 2014-12-24
EP4029593A1 (en) 2022-07-20

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