RU2622553C2 - Слои монооксида молибдена и их получение с помощью pvd - Google Patents
Слои монооксида молибдена и их получение с помощью pvd Download PDFInfo
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- RU2622553C2 RU2622553C2 RU2013124399A RU2013124399A RU2622553C2 RU 2622553 C2 RU2622553 C2 RU 2622553C2 RU 2013124399 A RU2013124399 A RU 2013124399A RU 2013124399 A RU2013124399 A RU 2013124399A RU 2622553 C2 RU2622553 C2 RU 2622553C2
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- molybdenum
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- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 229910052750 molybdenum Inorganic materials 0.000 title claims abstract description 45
- 239000011733 molybdenum Substances 0.000 title claims abstract description 44
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 87
- 238000000576 coating method Methods 0.000 claims abstract description 83
- 239000011248 coating agent Substances 0.000 claims abstract description 71
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 64
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000001301 oxygen Substances 0.000 claims abstract description 55
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims abstract description 48
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 75
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- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 18
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- QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 description 13
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
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- CXOWYMLTGOFURZ-UHFFFAOYSA-N azanylidynechromium Chemical compound [Cr]#N CXOWYMLTGOFURZ-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
- C23C28/048—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material with layers graded in composition or physical properties
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
- C23C28/322—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
- C23C28/3455—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/347—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with layers adapted for cutting tools or wear applications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/36—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including layers graded in composition or physical properties
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/40—Coatings including alternating layers following a pattern, a periodic or defined repetition
- C23C28/42—Coatings including alternating layers following a pattern, a periodic or defined repetition characterized by the composition of the alternating layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23H—WORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
- B23H9/00—Machining specially adapted for treating particular metal objects or for obtaining special effects or results on metal objects
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physical Vapour Deposition (AREA)
- Lubricants (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Laminated Bodies (AREA)
- Drilling Tools (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Coating By Spraying Or Casting (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US40765610P | 2010-10-28 | 2010-10-28 | |
| US61/407,656 | 2010-10-28 | ||
| DE102010053751.9 | 2010-12-08 | ||
| DE102010053751A DE102010053751A1 (de) | 2010-10-28 | 2010-12-08 | Molybdänmonoxidschichten und deren Herstellung mittels PVD |
| PCT/EP2011/004990 WO2012055485A1 (de) | 2010-10-28 | 2011-10-06 | Molybdänmonoxidschichten und deren herstellung mittels pvd |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2013124399A RU2013124399A (ru) | 2014-12-10 |
| RU2622553C2 true RU2622553C2 (ru) | 2017-06-16 |
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| RU2013124399A RU2622553C2 (ru) | 2010-10-28 | 2011-10-06 | Слои монооксида молибдена и их получение с помощью pvd |
Country Status (13)
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| US (1) | US9822322B2 (enExample) |
| EP (1) | EP2633095B1 (enExample) |
| JP (2) | JP2013545893A (enExample) |
| KR (1) | KR101930564B1 (enExample) |
| CN (1) | CN103270188B (enExample) |
| BR (1) | BR112013010147A2 (enExample) |
| CA (1) | CA2815911A1 (enExample) |
| DE (1) | DE102010053751A1 (enExample) |
| MX (1) | MX350887B (enExample) |
| MY (1) | MY179397A (enExample) |
| RU (1) | RU2622553C2 (enExample) |
| SG (1) | SG190021A1 (enExample) |
| WO (1) | WO2012055485A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2839660C1 (ru) * | 2024-04-10 | 2025-05-07 | Федеральное государственное автономное образовательное учреждение высшего образования "Московский государственный технологический университет "СТАНКИН" (ФГАОУ ВО "МГТУ "СТАНКИН") | Способ изготовления биметаллической детали из углеродистой стали и молибдена комбинированным методом |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012200378A1 (de) * | 2012-01-12 | 2013-07-18 | Federal-Mogul Burscheid Gmbh | Kolbenring |
| US10041017B2 (en) | 2012-03-12 | 2018-08-07 | Oerlikon Surface Solutions Ag, Pfäffikon | Coating with enhanced sliding properties |
| DE102012207814A1 (de) * | 2012-05-10 | 2013-11-14 | Mahle International Gmbh | Bauelement, insbesondere ein Gleitelement |
| DE102012207813A1 (de) * | 2012-05-10 | 2013-11-14 | Mahle International Gmbh | Gleitkörper mit Beschichtung |
| SG11201501437YA (en) * | 2012-08-29 | 2015-03-30 | Oerlikon Surface Solutions Ag Trubbach | Arc pvd coating with enhanced reducing friction and reducing wear properties |
| DE102012017033A1 (de) * | 2012-08-29 | 2014-05-28 | Oerlikon Trading Ag, Trübbach | PVD Lichtbogenbeschichtung mit verbesserten reibungsmindernden und verschleissreduzierenden Eigenschaften |
| AR092945A1 (es) | 2012-10-10 | 2015-05-06 | Oerlikon Trading Ag Trübbach | Recubrimiento para usos a altas temperaturas con solicitacion tribologica |
| DE102012023260A1 (de) * | 2012-11-29 | 2014-06-05 | Oerlikon Trading Ag, Trübbach | Verfahren zur Strukturierung von Schichtoberflächen und Vorrichtung dazu |
| CN104372299B (zh) * | 2013-09-23 | 2017-08-04 | 中国科学院合肥物质科学研究院 | 多层结构硬质、耐磨、润滑涂层及其制备方法 |
| DE102013018007A1 (de) | 2013-11-29 | 2015-06-03 | Oerlikon Trading Ag, Trübbach | Verfahren zur Verbesserung des Gegenkörperverschleisses im tribologischen Kontakt |
| CN103789725B (zh) * | 2014-01-29 | 2016-08-31 | 仪征亚新科双环活塞环有限公司 | 一种活塞环表面的多层多元复合硬质pvd镀层、活塞环及制备工艺 |
| EP3172359B1 (en) * | 2014-07-24 | 2018-06-06 | Oerlikon Surface Solutions AG, Pfäffikon | Arc evaporated me11-ame2azi/mo1-b-csicbbzii multilayer coatings |
| KR101673712B1 (ko) * | 2014-12-10 | 2016-11-08 | 현대자동차주식회사 | 자동차 습동 부품용 코팅재 및 이를 이용한 자동차 습동부품 표면처리 방법 |
| CN108048809B (zh) * | 2017-09-22 | 2019-07-30 | 南京航空航天大学 | 耐蚀抗菌的含银MoO3-SiO2纳米晶复合涂层的制备方法 |
| US11149651B2 (en) * | 2019-08-07 | 2021-10-19 | Raytheon Technologies Corporation | Seal ring assembly for a gas turbine engine |
| WO2021053072A1 (de) * | 2019-09-19 | 2021-03-25 | Oerlikon Surface Solutions Ag, Pfäffikon | Substrat mit einem molydännitrid schichtsystem, sowie beschichtungsverfahren zur herstellung eines schichtsystems |
| KR20230115987A (ko) * | 2020-11-30 | 2023-08-03 | 오를리콘 서피스 솔루션스 아크티엔게젤샤프트, 페피콘 | 마모 및 마찰 감소를 위한 질화몰리브덴 기반 다층 코팅 |
| CN114583055B (zh) * | 2022-02-18 | 2023-09-15 | 电子科技大学 | 一种喷涂MoO3薄膜的有机光电探测器及其制备方法 |
| CN114907900B (zh) * | 2022-05-31 | 2023-07-21 | 东莞市嘉丰润滑科技有限公司 | 一种自动变速箱油、i类金属切削液和新型润滑油 |
| JP2024018601A (ja) * | 2022-07-29 | 2024-02-08 | 株式会社Screenホールディングス | 基板処理方法および基板処理装置 |
| CN117488301B (zh) * | 2023-10-31 | 2025-10-24 | 深圳技术大学 | 一种金属表面的蜂窝状复合氧化钼涂层及其制备方法和在油水分离中的应用 |
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2010
- 2010-12-08 DE DE102010053751A patent/DE102010053751A1/de not_active Withdrawn
-
2011
- 2011-10-06 MX MX2013004780A patent/MX350887B/es active IP Right Grant
- 2011-10-06 WO PCT/EP2011/004990 patent/WO2012055485A1/de not_active Ceased
- 2011-10-06 KR KR1020137013593A patent/KR101930564B1/ko not_active Expired - Fee Related
- 2011-10-06 JP JP2013535294A patent/JP2013545893A/ja active Pending
- 2011-10-06 CN CN201180063789.XA patent/CN103270188B/zh not_active Expired - Fee Related
- 2011-10-06 US US13/881,855 patent/US9822322B2/en not_active Expired - Fee Related
- 2011-10-06 SG SG2013032081A patent/SG190021A1/en unknown
- 2011-10-06 CA CA2815911A patent/CA2815911A1/en not_active Abandoned
- 2011-10-06 EP EP11779086.5A patent/EP2633095B1/de not_active Not-in-force
- 2011-10-06 RU RU2013124399A patent/RU2622553C2/ru not_active IP Right Cessation
- 2011-10-06 BR BR112013010147A patent/BR112013010147A2/pt active Search and Examination
- 2011-10-06 MY MYPI2013001508A patent/MY179397A/en unknown
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2017
- 2017-09-05 JP JP2017170564A patent/JP2018035442A/ja active Pending
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| RU12540U1 (ru) * | 1999-07-02 | 2000-01-20 | Открытое акционерное общество "ГАЗ" | Устройство для электроискрового легирования металлических поверхностей |
| RU2196665C1 (ru) * | 2001-09-10 | 2003-01-20 | Открытое акционерное общество "Иркутское авиационное производственное объединение" | Способ электроискрового легирования |
| RU2211260C1 (ru) * | 2001-12-26 | 2003-08-27 | Федеральное государственное унитарное предприятие Всероссийский научно-исследовательский институт авиационных материалов | Антифрикционное композиционное покрытие |
| US20090256215A1 (en) * | 2005-03-18 | 2009-10-15 | Nano-Proprietary, Inc. | Gated metal oxide sensor |
| WO2010020362A1 (de) * | 2008-08-17 | 2010-02-25 | Oerlikon Trading Ag, Trübbach | Verwendung eines targets für das funkenverdampfen und verfahren zum herstellen eines für diese verwendung geeigneten targets |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2839660C1 (ru) * | 2024-04-10 | 2025-05-07 | Федеральное государственное автономное образовательное учреждение высшего образования "Московский государственный технологический университет "СТАНКИН" (ФГАОУ ВО "МГТУ "СТАНКИН") | Способ изготовления биметаллической детали из углеродистой стали и молибдена комбинированным методом |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013545893A (ja) | 2013-12-26 |
| JP2018035442A (ja) | 2018-03-08 |
| RU2013124399A (ru) | 2014-12-10 |
| EP2633095B1 (de) | 2017-09-13 |
| EP2633095A1 (de) | 2013-09-04 |
| CN103270188B (zh) | 2016-03-16 |
| WO2012055485A1 (de) | 2012-05-03 |
| MX2013004780A (es) | 2013-12-16 |
| MY179397A (en) | 2020-11-05 |
| CA2815911A1 (en) | 2012-05-03 |
| MX350887B (es) | 2017-09-22 |
| SG190021A1 (en) | 2013-06-28 |
| BR112013010147A2 (pt) | 2016-09-06 |
| KR20140066967A (ko) | 2014-06-03 |
| US20130303414A1 (en) | 2013-11-14 |
| DE102010053751A1 (de) | 2012-05-03 |
| CN103270188A (zh) | 2013-08-28 |
| KR101930564B1 (ko) | 2019-03-11 |
| US9822322B2 (en) | 2017-11-21 |
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