JP2013545893A - 一酸化モリブデン層と物理的蒸着法(pvd)を用いたその製法 - Google Patents
一酸化モリブデン層と物理的蒸着法(pvd)を用いたその製法 Download PDFInfo
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Abstract
Description
・イオン線支援プロセス
・物理的蒸着プロセスすなわちPVDプロセス、例えば、スパッタ蒸着およびスパーク蒸発
・すでにモリブデン被膜された表面中への窒素イオン注入
である。
・極めて滑らかな表面、および、これにより、切断器具におけるとりわけ良好な滑り特性
・高い硬度、および、これにより、機械的な損傷に対する耐性
・蒸発時に鋼鉄の表面中へ金属と窒素とが拡散されることによる、被膜と鋼鉄との間の良好な結合。著者らによれば、アルミニウムは、窒素ととりわけ良好に反応し、その結果、窒素原子の鋼鉄表面への拡散も生じさせ、これにより、被膜と鋼鉄表面との良好な結合が得られ、したがって、鋼鉄表面が追加的に硬くなる。
・著者らによれば、とりわけ層中のチタンおよびクロムが引き起こす高い腐食耐性。
・(金属成分中)少なくとも15原子百分率(at%)のシリコンと、
・(金属成分中)5〜85原子百分率のモリブデンと、
・(非金属成分中)少なくとも10原子百分率の窒素と、
・(非金属成分中)0.1〜10原子百分率の酸素と
を含有する。
・MoNからなる被膜を有する燃料噴射装置(独国特許公報DE19944977 B4号)
・PVD技術を用いて200℃以下で塗布されたMoN被膜を有する燃料噴射システム(米国特許出願公開公報US2010078314 A1号)
・Moおよび酸化モリブデン層を有する熱噴射された被膜を有するシリンダースリーブ(国際特許公開第WO9521994 A1号パンフレット)
・一方で、後酸化が制御されず生じ、これが、MoO3やMoO2の生成を引き起こす点を顧慮すべきである。上述のように、MoO2は研磨特性を有し、これは、例えば必要とされる良好な滑り特性との関連で非常に大きい欠点となる。
・他方で、高い機械的要求度のあるMo−N層の応用では、反応(Mo−Nの後酸化)も、Mo−Nの滑り特性も、MoO3の期待される潤滑特性と組み合わせると安定しないが、この理由は、この応用時に生成される酸化物化合物(とりわけMoO3粒子)が、継続的にMo−N層から離れるからである。これにより、Mo−N層表面が迅速にさらに酸化され、プロセスを継続すると、Mo−N層の分解を招いてしまうからである。
本発明の課題は、さらに良好なトライボロジー面での特性および/または電気的特性以外に、とりわけ良好で安定した潤滑剤特性も有し、かつ/または、柔軟性が改善され、かつ、好ましくは従来公知の層の上述したこれ以外の欠点を、少なくとも低減するような、改善された層およびその製法を提供することである。
本発明によれば、この課題は、モリブデンからなる安定した酸化物を含む硬質材料層を作り出すことにより達成される。
・第1層であって、とりわけ非常に良好な機械安定性を有し、(Mo1−x,Mex)AaBbCcを含有し、0≦x≦0.99で、好ましくは0≦x≦0.5であり、Meは、W、Ti、Al、Cr、Si、Zr、Ta、Nb、Ag、CuおよびVからなる群の1つの金属またはこの群の2つ以上の金属の組み合わせであり、
Aは、0.5≦a≦1の窒素(N)であり、
Bは、0≦b≦0.5の炭素(C)であり、
Cは、0≦c≦0.5の酸素(O)であり、
a、bおよびcは元素N、CおよびO間の原子百分率(at%)を示し、a+b+c=1であり、これ以外の追加的な元素を設けることもできるが、好ましくは設けない、第1層と、
・ 第2層であって、とりわけ非常に良好な潤滑剤特性および滑り特性を有し、(Mo1−y,Mey)AuBvCwを含有し、0≦y≦0.99で、好ましくは0≦y≦0.5であり、Meは、W、Ti、Al、Cr、Si、Zr、Ta、Nb、Ag、CuおよびVからなる群の1つの金属またはこの群の2つ以上の金属の組み合わせであり、
Aは、0≦u≦0.5の窒素であり、
Bは、0≦v≦0.5の炭素であり、
Cは、0.5≦w≦1の酸素であり、
u、vおよびwは元素N、CおよびO間のat%を示し、u+v+w=1であり、これ以外の追加的な元素を設けることもできるが、好ましくは設けない、第2層と
を含む。
・MoOは、MoO2とは異なり研磨性がなく、
・MoOは、MoO3と同様に、非常に良好な滑り特性および潤滑剤特性を有するが、MoO2およびMoO3と比較すると、実質的により安定性を有するとわかっていて、
・MoOは油性染みに対して作用する
からである。
本発明のとりわけ好適な変形例は、Mo−N−O層を、スパーク蒸発および/またはパルススパーク蒸発を用いて、例えば以下のように作り出すことである。
・窒素を被膜室中に導入した後、窒素雰囲気中で、カソードとして機能するモリブデンターゲットにスパークを発火させ、これにより、モリブデンおよび/またはすでに反応していた窒化モリブデンが蒸発する。所定の層厚に達した後に、追加的に、被膜室中にわずかな量の酸素が導入され、これによりMo−N−O層が作り出され、この層は、Mo−Nの非常に良好な特性を有するが、追加的に、層中に取り入れられたMo−O化合物の量が少ないがゆえに、改善された潤滑剤特性および/または柔軟性も有する。
・窒素を被膜室中に導入した後、窒素雰囲気中で、カソードとして機能するモリブデンターゲットにスパークを発火させ、これにより、モリブデンおよび/またはすでに反応していた窒化モリブデンが蒸発する。所定の層厚に達した後に、追加的に、被膜室中にわずかな量の酸素が導入され、所定の時間経過後、酸素流を再度中断し、その結果再び窒化モリブデンのみが生成される。被膜プロセスは、このように交互に続けられ、これは、多重層からなるMo−N/Mo−N−O/Mo−N/Mo−N−O層の所望の全層厚が達成されるまで続けられる。個々の層厚、および、全層厚は、応用に応じて合わせられる。この変形例では、1つの被膜中に、非常に良好なMo−Nの特性と、Mo−Oの潤滑剤特性および/または柔軟性を組み合わせることができる。
・主要構成成分としてMoNを有し、したがって非常に良好な機械安定性を有する第1層と、
・主要構成成分として一酸化モリブデンを有し、したがって非常に良好な潤滑剤特性を有する第2層と
が含まれる場合、本発明の層システムのとりわけ望ましい変形例となる。
粘性の実質的な改善は、多重層からなる層を析出することにより達成される。同時に、このようにして、表面から基材へ向かう亀裂の広がりが阻止される。さらに、多くの場合では、最大の層厚を大きくすることができるが、これは、多重層からなる層結合では、単層である層と比較すると、機械的な内部応力を小さくすることができるからである。
以下の実施例は、本発明を詳細に説明するのに役立つが、本発明の範囲を限定するものとしてみなされるべきではない。
一般に、ピストンリングおよびシャフト密閉リングは、良好な機械安定性および同時に良好な潤滑剤特性および/または柔軟性を有する場合に有利である。本実施例では、ステンレススチール製のピストンリングを、Mo−Nを用いたスパーク蒸発で被膜する。このために、ピストンリングを被膜設備の被膜室中に設置する。被膜室を真空にして表面を清浄化/活性化するために、表面を被膜前に加熱し、エッチングする。窒素を被膜室中に導入した後に、窒素雰囲気中で、カソードとして機能するモリブデンターゲットに対して、スパークを発火させる。これにより、モリブデンおよび/またはすでに反応した窒化モリブデンが蒸発する。ピストン表面上への材料の析出により、2μmの厚さのMo−N層が形成される。この被膜方法では、応用に応じて層厚を合わせることができる。
eは、Mo−N−O層中の酸素原子濃度であり、
dは、Mo−N−O層中の窒素原子濃度であり、
zは、Mo−N−O層中のモリブデン原子濃度であり、
z≧yである。
Aは、0.5≦a≦1の窒素(N)であり、
Bは、0≦b≦0.5の炭素(C)であり、
Cは、0≦c≦0.5の酸素(O)であり、
a、bおよびcは元素N、CおよびO間のat%(原子百分率)を示し、a+b+c=1であり、これ以外の追加的な元素を設けることもできるが、好ましくは設けず、x≧cである。
Aは、0≦u≦0.5の窒素であり、
Bは、0≦v≦0.5の炭素であり、
Cは、0.5≦w≦1の酸素であり、
u、vおよびwは元素N、CおよびO間のat%を示し、u+v+w=1であり、これ以外の追加的な元素を設けることもできるが、好ましくは設けず、y≧wである。
・とりわけ非常に良好な機械安定性を有する少なくとも1つの第1Mo含有層(上述のような(Mo1−x,Mex)AaBbCc層)と、
・とりわけ非常に良好な潤滑剤特性および滑り特性を有する少なくとも1つの第2Mo層(上述のような(Mo1−y,Mey)AuBvCw層)と
を含むように構築されることができた。
とりわけ、金属または合金製の構成部品を製造するための機械切削工具および成形工具は、工具の被膜された表面上での加工した金属または合金の油性の染みを低減するため、または、好ましくは完全に回避するために、本発明により被膜される。
3 付着層および/または機能層
5 第1層
7 移行層
9 第2層
Claims (18)
- 酸化モリブデンを有する少なくとも1つのモリブデン含有層を含む被膜において、前記酸化モリブデンが実質的に一酸化モリブデンであることを特徴とする被膜。
- 前記被膜は、実質的に一酸化モリブデンを含む少なくとも1つの酸化モリブデン層を含み、前記一酸化モリブデン層のX線回折(XRD)スペクトルは実質的にMoO2ピークもMoO3ピークも示さないことを特徴とする請求項1に記載の被膜。
- 前記被膜は、少なくとも1つの窒化モリブデン層を含むことを特徴とする上記請求項のいずれか1項に記載の被膜。
- 前記被膜は、モリブデン窒素結合と酸化モリブデン結合とを含むMo−N−O層を少なくとも1つ含み、実質的にモリブデン原子は、最大1つの酸素原子と化合物を形成し、前記被膜中に好ましくは一酸化モリブデンを含有することを特徴とする上記請求項のいずれか1項に記載の被膜。
- 前記Mo−N−O層は、窒化モリブデン層と一酸化モリブデン層との間にあることを特徴とする請求項4に記載の被膜。
- 前記Mo−N−O層中の原子濃度割合は、以下の式により表され、すなわち、
Moz(NdOe)で、
eは、前記Mo−N−O層中の酸素原子濃度であり、
dは、前記Mo−N−O層中の窒素原子濃度であり、
zは、前記Mo−N−O層中のモリブデン原子濃度であり、
z≧yである
ことを特徴とする請求項4または5に記載の被膜。 - 前記Mo−N−O層は漸進的な層であり、前記Mo−N−O層の基板に近い境界面から表面に近い境界面に向かって、窒素濃度は低下し、酸素濃度は上昇することを特徴とする請求項4、5または6に記載の被膜。
- 前記Mo−N−O層は漸進的な層であり、前記Mo−N−O層の基板に近い境界面から表面に近い境界面に向かって、酸素濃度は低下し、窒素濃度は上昇することを特徴とする請求項4、5または6に記載の被膜。
- 前記被膜は、請求項7に記載の被膜を少なくとも1つと、請求項8に記載の被膜を少なくとも1つ含むことを特徴とする請求項4、5または6に記載の被膜。
- 前記被膜は、MoO3を有する被覆層を有することを特徴とする上記請求項のいずれか1項に記載の被膜。
- 基体と前記Mo含有層との間に、少なくとも1つの付着層および/または少なくとも1つの機能層が析出されていることを特徴とする上記請求項のいずれか1項に記載の被膜。
- 少なくとも1つのMo含有層は、とりわけ非常に良好な機械安定性を有し、(Mo1−x,Mex)AaBbCcを含有し、
0≦x≦0.99で、好ましくは0≦x≦0.5であり、
Meは、W、Ti、Al、Cr、Si、Zr、Ta、Nb、Ag、CuおよびVの群の1つの金属またはこの群の2つ以上の金属の組み合わせであり、
Aは、0.5≦a≦1の窒素(N)であり、
Bは、0≦b≦0.5の炭素(C)であり、
Cは、0≦c≦0.5の酸素(O)であり、
a、bおよびcは元素N、CおよびO間のat%(原子百分率)を示し、a+b+c=1であり、これ以外の追加的な元素を設けることもできるが、好ましくは設けず、x≧cであることを特徴とする上記請求項のいずれか1項に記載の被膜。 - 少なくとも1つのMo含有層は、とりわけ非常に良好な潤滑剤特性および滑り特性を有し、(Mo1−y,Mey)AuBvCwを含有し、
0≦y≦0.99で、好ましくは0≦y≦0.5であり、
Meは、W、Ti、Al、Cr、Si、Zr、Ta、Nb、Ag、CuおよびVの群の1つの金属またはこの群の2つ以上の金属の組み合わせであり、
Aは、0≦u≦0.5の窒素であり、
Bは、0≦v≦0.5の炭素であり、
Cは、0.5≦w≦1の酸素であり、
u、vおよびwは元素N、CおよびO間のat%を示し、u+v+w=1であり、これ以外の追加的な元素を設けることもできるが、好ましくは設けず、y≧wであることを特徴とする上記請求項のいずれか1項に記載の被膜。 - 前記被膜は、少なくとも1つの請求項12に記載の第1層と、1つの請求項13に記載の第2層とを含むことを特徴とする上記請求項のいずれか1項に記載の被膜。
- 上記請求項のいずれか1項に記載の被膜を作り出すためのPVD(物理的蒸着法)またはPVDとCVD(化学的蒸着法)とを組み合わせた方法において、前記一酸化モリブデンを含む層中の前記一酸化モリブデンは、スパーク蒸発を用いて析出されることを特徴とする方法。
- 上記請求項のいずれか1項に記載の被膜を作り出すためのPVD方法において、前記モリブデン含有層は、反応雰囲気中で少なくとも1つのモリブデン含有ターゲットをスパーク蒸発させることにより作り出されることを特徴とする方法。
- 被膜を備えた構成部品において、前記被膜が上記請求項1から14のいずれか1項に記載の被膜であることを特徴とする構成部品。
- 金属または合金製の構成部品を作るために請求項17に記載の被膜がなされた工具の応用において、前記被膜により、前記工具の被膜した表面への、加工した金属または合金の油性染みの発生が低減または好ましくは完全に回避されることを特徴とする応用。
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015516506A (ja) * | 2012-03-12 | 2015-06-11 | エリコン・サーフェス・ソリューションズ・アクチェンゲゼルシャフト,トリュープバッハ | 摺動特性が向上した被膜 |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102012200378A1 (de) * | 2012-01-12 | 2013-07-18 | Federal-Mogul Burscheid Gmbh | Kolbenring |
DE102012207813A1 (de) * | 2012-05-10 | 2013-11-14 | Mahle International Gmbh | Gleitkörper mit Beschichtung |
DE102012207814A1 (de) * | 2012-05-10 | 2013-11-14 | Mahle International Gmbh | Bauelement, insbesondere ein Gleitelement |
SG11201501437YA (en) * | 2012-08-29 | 2015-03-30 | Oerlikon Surface Solutions Ag Trübbach | Arc pvd coating with enhanced reducing friction and reducing wear properties |
DE102012017033A1 (de) * | 2012-08-29 | 2014-05-28 | Oerlikon Trading Ag, Trübbach | PVD Lichtbogenbeschichtung mit verbesserten reibungsmindernden und verschleissreduzierenden Eigenschaften |
AR092945A1 (es) * | 2012-10-10 | 2015-05-06 | Oerlikon Trading Ag Trübbach | Recubrimiento para usos a altas temperaturas con solicitacion tribologica |
DE102012023260A1 (de) * | 2012-11-29 | 2014-06-05 | Oerlikon Trading Ag, Trübbach | Verfahren zur Strukturierung von Schichtoberflächen und Vorrichtung dazu |
CN104372299B (zh) * | 2013-09-23 | 2017-08-04 | 中国科学院合肥物质科学研究院 | 多层结构硬质、耐磨、润滑涂层及其制备方法 |
DE102013018007A1 (de) | 2013-11-29 | 2015-06-03 | Oerlikon Trading Ag, Trübbach | Verfahren zur Verbesserung des Gegenkörperverschleisses im tribologischen Kontakt |
CN103789725B (zh) * | 2014-01-29 | 2016-08-31 | 仪征亚新科双环活塞环有限公司 | 一种活塞环表面的多层多元复合硬质pvd镀层、活塞环及制备工艺 |
JP6257837B2 (ja) * | 2014-07-24 | 2018-01-10 | エリコン・サーフェス・ソリューションズ・アクチェンゲゼルシャフト,プフェフィコーンOerlikon Surface Solutions Ag, Pfaeffikon | アーク蒸着Me11−aMe2aZI/Mo1−b−cSicBbZII多層被覆 |
KR101673712B1 (ko) * | 2014-12-10 | 2016-11-08 | 현대자동차주식회사 | 자동차 습동 부품용 코팅재 및 이를 이용한 자동차 습동부품 표면처리 방법 |
CN108048809B (zh) * | 2017-09-22 | 2019-07-30 | 南京航空航天大学 | 耐蚀抗菌的含银MoO3-SiO2纳米晶复合涂层的制备方法 |
US11149651B2 (en) * | 2019-08-07 | 2021-10-19 | Raytheon Technologies Corporation | Seal ring assembly for a gas turbine engine |
JP2022548893A (ja) * | 2019-09-19 | 2022-11-22 | エリコン サーフェス ソリューションズ エージー、プフェッフィコン | 窒化モリブデンコーティングシステムを備えた基材、およびコーティングシステムを製造するコーティング方法 |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08144046A (ja) * | 1994-11-21 | 1996-06-04 | Teikoku Piston Ring Co Ltd | 摺動部材およびその製造方法 |
JPH08178069A (ja) * | 1994-12-22 | 1996-07-12 | Teikoku Piston Ring Co Ltd | 摺動部材およびその製造方法 |
JPH111763A (ja) * | 1997-06-09 | 1999-01-06 | Teikoku Piston Ring Co Ltd | 硬質被覆材およびそれを被覆した摺動部材ならびにその製造方法 |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4847171A (en) * | 1988-03-10 | 1989-07-11 | Ford Motor Company | Molybdenum oxide electrodes for thermoelectric generators |
SU1832751A1 (ru) | 1990-06-18 | 1998-01-20 | Научно-производственное объединение "НИИТавтопром" | Способ получения износостойких покрытий из соединений металлов |
ES2083301T3 (es) * | 1993-03-26 | 1996-04-01 | Siemens Ag | Catalizador para la reduccion de oxido de nitrogeno en el gas de escape de un motor de combustion interna. |
DK16494A (da) | 1994-02-08 | 1995-08-09 | Man B & W Diesel Gmbh | Fremgangsmåde til fremstilling af en cylinderforing samt en sådan foring |
DE29620687U1 (de) | 1996-11-28 | 1997-01-30 | Fehling Ulrike | Chirurgisches Instrument |
US6802457B1 (en) | 1998-09-21 | 2004-10-12 | Caterpillar Inc | Coatings for use in fuel system components |
RU12540U1 (ru) * | 1999-07-02 | 2000-01-20 | Открытое акционерное общество "ГАЗ" | Устройство для электроискрового легирования металлических поверхностей |
US6537613B1 (en) * | 2000-04-10 | 2003-03-25 | Air Products And Chemicals, Inc. | Process for metal metalloid oxides and nitrides with compositional gradients |
US7311961B2 (en) * | 2000-10-24 | 2007-12-25 | Ppg Industries Ohio, Inc. | Method of making coated articles and coated articles made thereby |
RU2196665C1 (ru) * | 2001-09-10 | 2003-01-20 | Открытое акционерное общество "Иркутское авиационное производственное объединение" | Способ электроискрового легирования |
RU2211260C1 (ru) * | 2001-12-26 | 2003-08-27 | Федеральное государственное унитарное предприятие Всероссийский научно-исследовательский институт авиационных материалов | Антифрикционное композиционное покрытие |
US7344806B2 (en) * | 2003-03-31 | 2008-03-18 | Shin-Etsu Chemical Co., Ltd. | Method of producing phase shift mask blank, method of producing phase shift mask, phase shift mask blank, and phase shift mask |
US20060042728A1 (en) | 2004-08-31 | 2006-03-02 | Brad Lemon | Molybdenum sputtering targets |
US7332618B2 (en) * | 2004-09-28 | 2008-02-19 | Praxair Technology, Inc. | Organometallic precursor compounds |
TW200706863A (en) * | 2005-03-18 | 2007-02-16 | Nano Proprietary Inc | Gated gas sensor |
US7950271B2 (en) | 2005-03-18 | 2011-05-31 | Applied Nanotech Holdings, Inc. | Gated beta-molybdenum oxide sensor |
MX2007011703A (es) * | 2005-03-24 | 2008-03-10 | Oerlikon Trading Ag | Capa de material duro. |
KR100655366B1 (ko) | 2005-07-04 | 2006-12-08 | 한국과학기술연구원 | 내열, 내마모, 저마찰 특성을 가지는 코팅제 및 이의코팅방법 |
DE102006036101A1 (de) | 2005-08-02 | 2007-02-08 | Caterpillar Motoren Gmbh & Co. Kg | Verfahren zur Herstellung von Ventilkomponenten |
JP4824989B2 (ja) | 2005-11-02 | 2011-11-30 | 株式会社神戸製鋼所 | 硬質皮膜 |
JP2006255708A (ja) | 2006-07-05 | 2006-09-28 | Mitsubishi Heavy Ind Ltd | 中空糸膜の逆洗方法及び中空糸膜水処理装置 |
US20090087673A1 (en) | 2007-09-28 | 2009-04-02 | Taylor Steven C | Method for coating fuel system components |
EP2166128B1 (de) * | 2008-09-19 | 2011-11-09 | Oerlikon Trading AG, Trübbach | Verfahren zum Herstellen von Metalloxidschichten durch Funkenverdampfung |
JP5562336B2 (ja) * | 2008-08-17 | 2014-07-30 | エリコン・トレーディング・アクチェンゲゼルシャフト,トリュープバッハ | アーク蒸発のためのターゲットの使用および前記使用に適したターゲットの製造方法 |
KR101127236B1 (ko) * | 2008-12-29 | 2012-03-29 | 주식회사 하이닉스반도체 | 저항성 메모리 소자의 제조 방법 |
-
2010
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2011
- 2011-10-06 CA CA2815911A patent/CA2815911A1/en not_active Abandoned
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- 2011-10-06 MX MX2013004780A patent/MX350887B/es active IP Right Grant
-
2017
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08144046A (ja) * | 1994-11-21 | 1996-06-04 | Teikoku Piston Ring Co Ltd | 摺動部材およびその製造方法 |
JPH08178069A (ja) * | 1994-12-22 | 1996-07-12 | Teikoku Piston Ring Co Ltd | 摺動部材およびその製造方法 |
JPH111763A (ja) * | 1997-06-09 | 1999-01-06 | Teikoku Piston Ring Co Ltd | 硬質被覆材およびそれを被覆した摺動部材ならびにその製造方法 |
Non-Patent Citations (2)
Title |
---|
JPN6015027439; O.O. Iloria,et al.: 'Preparation and characterization of metallorganic chemical vapourdeposited molybdenum (II) oxide (Mo' Thin Solid Films vol.472, 20040911, 84-89 * |
JPN6015027440; 上條富士太: '酸化モリブデン膜の作成と基本的特性の評価' 高知工科大学修士論文 , 20030127, 高知工科大学 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015516506A (ja) * | 2012-03-12 | 2015-06-11 | エリコン・サーフェス・ソリューションズ・アクチェンゲゼルシャフト,トリュープバッハ | 摺動特性が向上した被膜 |
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CA2815911A1 (en) | 2012-05-03 |
MX350887B (es) | 2017-09-22 |
CN103270188B (zh) | 2016-03-16 |
JP2018035442A (ja) | 2018-03-08 |
KR20140066967A (ko) | 2014-06-03 |
US20130303414A1 (en) | 2013-11-14 |
DE102010053751A1 (de) | 2012-05-03 |
BR112013010147A2 (pt) | 2016-09-06 |
US9822322B2 (en) | 2017-11-21 |
MY179397A (en) | 2020-11-05 |
RU2622553C2 (ru) | 2017-06-16 |
WO2012055485A1 (de) | 2012-05-03 |
RU2013124399A (ru) | 2014-12-10 |
EP2633095B1 (de) | 2017-09-13 |
CN103270188A (zh) | 2013-08-28 |
SG190021A1 (en) | 2013-06-28 |
EP2633095A1 (de) | 2013-09-04 |
KR101930564B1 (ko) | 2019-03-11 |
MX2013004780A (es) | 2013-12-16 |
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