RU2612383C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2612383C1
RU2612383C1 RU2016107250A RU2016107250A RU2612383C1 RU 2612383 C1 RU2612383 C1 RU 2612383C1 RU 2016107250 A RU2016107250 A RU 2016107250A RU 2016107250 A RU2016107250 A RU 2016107250A RU 2612383 C1 RU2612383 C1 RU 2612383C1
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Russia
Prior art keywords
glaze
zro
cao
zno
sio
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RU2016107250A
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Russian (ru)
Inventor
Юлия Алексеевна Щепочкина
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Юлия Алексеевна Щепочкина
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Priority to RU2016107250A priority Critical patent/RU2612383C1/en
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Publication of RU2612383C1 publication Critical patent/RU2612383C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/10—Frit compositions, i.e. in a powdered or comminuted form containing lead
    • C03C8/12—Frit compositions, i.e. in a powdered or comminuted form containing lead containing titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes

Abstract

FIELD: motors and pumps.
SUBSTANCE: glaze contains, wt %: SiO2 38.0-41.0; Al2O3 0.5-1.5; B2O3 15.0-17.0; ZnO 7.0-8.0; ZrO2 15.0-16.0; CaO 15.0-16.5; Na3AlF6 4.5-5.5.
EFFECT: increased heat resistance.
1 tbl

Description

Изобретение относится к технологии силикатов, в частности к составам глазурей, которые могут быть использованы для нанесения на керамическую плитку.The invention relates to the technology of silicates, in particular to compositions of glazes that can be used for application on ceramic tiles.

Известна глазурь, содержащая, мас. %: SiO2 47,4-50,52; Al2O3 10,56-12,78; Fe2O3 1,5-1,61; В2O3 5,13-5,86; ZnO 8,0-9,0; ZrO2 8,0-12,0; CaO 10,19-11,61; МgO 0,35-0,36; Na2O 1,83-2,04; K2O 1,55-1,71 [1].Known glaze containing, by weight. %: SiO 2 47.4-50.52; Al 2 O 3 10.56-12.78; Fe 2 O 3 1.5-1.61; In 2 O 3, 5.13-5.86; ZnO 8.0-9.0; ZrO 2 8.0-12.0; CaO 10.19-11.61; MgO 0.35-0.36; Na 2 O 1.83-2.04; K 2 O 1.55-1.71 [1].

Задача изобретения - повышение термостойкости глазури.The objective of the invention is to increase the heat resistance of the glaze.

Технический результат достигается тем, что глазурь, включающая SiO2, Al2O3, В2O3, ZnO, ZrO2, СаО, дополнительно содержит Na3AlF6, при следующем соотношении компонентов, мас. %: SiO2 38,0-41,0; Al2O3 0,5-1,5; B2O3 15,0-17,0; ZnO 7,0-8,0; ZrO2 15,0-16,0; СаО 15,0-16,5; Na3AlF6 4,5-5,5.The technical result is achieved in that the glaze, including SiO 2 , Al 2 O 3 , B 2 O 3 , ZnO, ZrO 2 , CaO, additionally contains Na 3 AlF 6 , in the following ratio, wt. %: SiO 2 38.0-41.0; Al 2 O 3 0.5-1.5; B 2 O 3 15.0-17.0; ZnO 7.0-8.0; ZrO 2 15.0-16.0; CaO 15.0-16.5; Na 3 AlF 6 4.5-5.5.

В таблице приведены составы глазури.The table shows the glaze compositions.

Figure 00000001
Figure 00000001

Взвешенные сырьевые компоненты (кварцевый песок, стеклобой, борная кислота, циркон, мел и др.) сплавляют при температуре 1400-1430°С, расплав гранулируют в воду, после чего полученную фритту размалывают мокрым способом до прохождения через сито №008. Суспензию с влажностью 45-50% наносят (напыление, полив) на обожженные керамические плитки и закрепляют оплавлением при температуре 950°С.Suspended raw materials (quartz sand, cullet, boric acid, zircon, chalk, etc.) are melted at a temperature of 1400-1430 ° C, the melt is granulated into water, after which the resulting frit is ground wet until passing through a No. 008 sieve. A suspension with a moisture content of 45-50% is applied (sputtering, watering) on fired ceramic tiles and fixed by fusion at a temperature of 950 ° C.

Источник информацииThe source of information

1. SU 1270147, С03С 41/86, 1986.1. SU 1270147, C03C 41/86, 1986.

Claims (1)

Глазурь, включающая SiO2, Al2O3, B2O3, ZnO, ZrO2, CaO, отличающаяся тем, что дополнительно содержит Na3AlF6, при следующем соотношении компонентов, мас. %: SiO2 38,0-41,0; Al2O3 0,5-1,5; B2O3 15,0-17,0; ZnO 7,0-8,0; ZrO2 15,0-16,0; CaO 15,0-16,5; Na3AlF6 4,5-5,5.Glaze, including SiO 2 , Al 2 O 3 , B 2 O 3 , ZnO, ZrO 2 , CaO, characterized in that it additionally contains Na 3 AlF 6 , in the following ratio, wt. %: SiO 2 38.0-41.0; Al 2 O 3 0.5-1.5; B 2 O 3 15.0-17.0; ZnO 7.0-8.0; ZrO 2 15.0-16.0; CaO 15.0-16.5; Na 3 AlF 6 4.5-5.5.
RU2016107250A 2016-02-29 2016-02-29 Glaze RU2612383C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2016107250A RU2612383C1 (en) 2016-02-29 2016-02-29 Glaze

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RU2612383C1 true RU2612383C1 (en) 2017-03-09

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU537050A1 (en) * 1975-06-10 1976-11-30 Ташкентский Научно-Исследовательский И Проектный Институт Строительных Материалов Glaze
SU1073198A1 (en) * 1982-07-14 1984-02-15 Белорусский Ордена Трудового Красного Знамени Технологический Институт Им.С.М.Кирова Glaze composition
SU1270147A1 (en) * 1984-11-30 1986-11-15 Харьковский Ордена Ленина Политехнический Институт Им.В.И.Ленина Nonfritted glaze
SU1530589A1 (en) * 1988-01-06 1989-12-23 Ивановский Химико-Технологический Институт Glaze composition
EP1845073A1 (en) * 2006-04-10 2007-10-17 Consorzio Interuniversitario per lo Sviluppo dei Sistemi a Grande Interfase, C.S.G.I Compositions comprising nanoparticles of zirconium hydroxide and/or glass frits for coating ceramic products
RU2467961C1 (en) * 2011-07-26 2012-11-27 Юлия Алексеевна Щепочкина Tile glaze

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU537050A1 (en) * 1975-06-10 1976-11-30 Ташкентский Научно-Исследовательский И Проектный Институт Строительных Материалов Glaze
SU1073198A1 (en) * 1982-07-14 1984-02-15 Белорусский Ордена Трудового Красного Знамени Технологический Институт Им.С.М.Кирова Glaze composition
SU1270147A1 (en) * 1984-11-30 1986-11-15 Харьковский Ордена Ленина Политехнический Институт Им.В.И.Ленина Nonfritted glaze
SU1530589A1 (en) * 1988-01-06 1989-12-23 Ивановский Химико-Технологический Институт Glaze composition
EP1845073A1 (en) * 2006-04-10 2007-10-17 Consorzio Interuniversitario per lo Sviluppo dei Sistemi a Grande Interfase, C.S.G.I Compositions comprising nanoparticles of zirconium hydroxide and/or glass frits for coating ceramic products
RU2467961C1 (en) * 2011-07-26 2012-11-27 Юлия Алексеевна Щепочкина Tile glaze

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