RU2654089C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2654089C1
RU2654089C1 RU2017110429A RU2017110429A RU2654089C1 RU 2654089 C1 RU2654089 C1 RU 2654089C1 RU 2017110429 A RU2017110429 A RU 2017110429A RU 2017110429 A RU2017110429 A RU 2017110429A RU 2654089 C1 RU2654089 C1 RU 2654089C1
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Russia
Prior art keywords
glaze
cao
mgo
zno
beo
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RU2017110429A
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Russian (ru)
Inventor
Юлия Алексеевна Щепочкина
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Юлия Алексеевна Щепочкина
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Priority to RU2017110429A priority Critical patent/RU2654089C1/en
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Publication of RU2654089C1 publication Critical patent/RU2654089C1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/04Frit compositions, i.e. in a powdered or comminuted form containing zinc
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

Abstract

FIELD: chemistry.
SUBSTANCE: invention relates to the technology of silicates, in particular to glaze compositions that can be used to coat a facing tile. Glaze, which includes SiO2, Al2O3, CaO, MgO, Na2O, K2O, B2O3, ZnO, additionally contains SnO2, SeO2 and BeO, in following ratio of components, mass %: SiO2 49.0–51.0; Al2O3 4.5–5.0; CaO 3.0, or 3.5, or 4.0; MgO 0.2–0.4; Na2O 6.5–7.5; K2O 0.8–1.8; B2O3 9.0–13.3; ZnO 4.0–6.0; SnQ2 10.0, or 10.5, or 11.0; SeQ2 1.0–2.0; BeO 4.0–6.0.
EFFECT: high heat resistance of glaze.
1 cl, 1 tbl

Description

Изобретение относится к технологии силикатов, в частности к составам глазури, которая может быть использована для покрытия облицовочной плитки. The invention relates to the technology of silicates, in particular to compositions of glaze, which can be used to cover tiles.

Известна глазурь, содержащая, мас. %: SiO2 50,1-53,25; Al2O3 5,0-7,12; Fe2O3 1,64-1,72; СаО 15,15-18,25; MgO 1,12-1,21; Na2O 1,86-2,45; K2O 1,77-2,18; B2O3 9,5-11,45; ZnO 5,89-8,0; CuO 0,8-1,0 [1].Known glaze containing, by weight. %: SiO 2 50.1-53.25; Al 2 O 3 5.0-7.12; Fe 2 O 3 1.64-1.72; CaO 15.15-18.25; MgO 1.12-1.21; Na 2 O 1.86-2.45; K 2 O 1.77-2.18; B 2 O 3 9.5-11.45; ZnO 5.89-8.0; CuO 0.8-1.0 [1].

Задачей изобретения является повышение термостойкости глазури.The objective of the invention is to increase the heat resistance of the glaze.

Технический результат достигается тем, что глазурь, включающая SiO2, Al2O3, СаО, MgO, Na2O, K2O, B2O3, ZnO, дополнительно содержит SnO2, SeO2 и ВеО, при следующем соотношении компонентов, мас. %: SiO2 49,0-51,0; Al2O3 4,5-5,0; СаО 3,0, или 3,5, или 4,0; MgO 0,2-0,4; Na2O 6,5-7,5; K2O 0,8-1,8; B2O3 9,0-13,3; ZnO 4,0-6,0; SnO2 10,0, или 10,5, или 11,0; SeO2 1,0-2,0; ВеО 4,0-6,0. В таблице приведены составы глазури.The technical result is achieved in that the glaze, including SiO 2 , Al 2 O 3 , CaO, MgO, Na 2 O, K 2 O, B 2 O 3 , ZnO, additionally contains SnO 2 , SeO 2 and BeO, in the following ratio of components wt. %: SiO 2 49.0-51.0; Al 2 O 3 4.5-5.0; CaO 3.0, or 3.5, or 4.0; MgO 0.2-0.4; Na 2 O 6.5-7.5; K 2 O 0.8-1.8; B 2 O 3 9.0-13.3; ZnO 4.0-6.0; SnO 2 10.0 or 10.5 or 11.0; SeO 2 1.0-2.0; BeO 4.0-6.0. The table shows the glaze compositions.

Figure 00000001
Figure 00000002
Figure 00000001
Figure 00000002

Взвешенные в необходимых соотношениях компоненты (кварцевый песок, стеклобой, глинозем, мел, доломит, сода, поташ, бура, оксид цинка, оксид олова и др.) глазури просеивают через сито №07 и сплавляют при температуре 1450-1470°С. Расплав гранулируют в воду, фритту размалывают мокрым способом до прохождения через сетку №0056. Полученную суспензию с влажностью 45-50% наносят на обожженную керамическую плитку и при температуре 930-1000°С проводят ее второй обжиг.The components, weighed in the required proportions (quartz sand, cullet, alumina, chalk, dolomite, soda, potash, borax, zinc oxide, tin oxide, etc.), are glazed through a No. 07 sieve and melted at a temperature of 1450-1470 ° C. The melt is granulated into water, the frit is ground wet before passing through mesh No. 0056. The resulting suspension with a moisture content of 45-50% is applied to the fired ceramic tile and at a temperature of 930-1000 ° C, its second firing is carried out.

Источник информацииThe source of information

1. SU 1245558, 1986.1. SU 1245558, 1986.

Claims (1)

Глазурь, включающая SiO2, Al2O3, СаО, MgO, Na2O, K2O, B2O3, ZnO, отличающаяся тем, что дополнительно содержит SnO2, SeO2 и ВеО, при следующем соотношении компонентов, мас. %: SiO2 49,0-51,0; Al2O3 4,5-5,0; СаО 3,0, или 3,5, или 4,0; MgO 0,2-0,4; Na2O 6,5-7,5; K2O 0,8-1,8; В2О3 9,0-13,3; ZnO 4,0-6,0; SnQ2 10,0, или 10,5, или 11,0; SeQ2 1,0-2,0; ВеО 4,0-6,0.Glaze, including SiO 2 , Al 2 O 3 , CaO, MgO, Na 2 O, K 2 O, B 2 O 3 , ZnO, characterized in that it further contains SnO 2 , SeO 2 and BeO, in the following ratio of components, wt . %: SiO 2 49.0-51.0; Al 2 O 3 4.5-5.0; CaO 3.0, or 3.5, or 4.0; MgO 0.2-0.4; Na 2 O 6.5-7.5; K 2 O 0.8-1.8; B 2 O 3 9.0-13.3; ZnO 4.0-6.0; SnQ 2 10.0 or 10.5 or 11.0; SeQ 2 1.0-2.0; BeO 4.0-6.0.
RU2017110429A 2017-03-28 2017-03-28 Glaze RU2654089C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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RU2654089C1 true RU2654089C1 (en) 2018-05-16

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116655247A (en) * 2023-07-26 2023-08-29 佛山市三水新明珠建陶工业有限公司 Matte marble Dan Mianyou, matte marble ceramic tile and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1245558A1 (en) * 1984-09-29 1986-07-23 Проектно-Конструкторское И Технологическое Бюро Главленстройматериалов Glaze
US20040152579A1 (en) * 2001-07-05 2004-08-05 Shigeru Ishiki Glaze composition and antifouling ceramic ware
RU2303008C1 (en) * 2006-04-17 2007-07-20 Юлия Алексеевна Щепочкина Glaze
RU2304105C1 (en) * 2006-04-17 2007-08-10 Юлия Алексеевна Щепочкина Glaze
RU2320578C1 (en) * 2006-11-02 2008-03-27 Юлия Алексеевна Щепочкина Stained glaze

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1245558A1 (en) * 1984-09-29 1986-07-23 Проектно-Конструкторское И Технологическое Бюро Главленстройматериалов Glaze
US20040152579A1 (en) * 2001-07-05 2004-08-05 Shigeru Ishiki Glaze composition and antifouling ceramic ware
RU2303008C1 (en) * 2006-04-17 2007-07-20 Юлия Алексеевна Щепочкина Glaze
RU2304105C1 (en) * 2006-04-17 2007-08-10 Юлия Алексеевна Щепочкина Glaze
RU2320578C1 (en) * 2006-11-02 2008-03-27 Юлия Алексеевна Щепочкина Stained glaze

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116655247A (en) * 2023-07-26 2023-08-29 佛山市三水新明珠建陶工业有限公司 Matte marble Dan Mianyou, matte marble ceramic tile and preparation method thereof
CN116655247B (en) * 2023-07-26 2023-11-07 佛山市三水新明珠建陶工业有限公司 Matte marble Dan Mianyou, matte marble ceramic tile and preparation method thereof

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