RU2609915C2 - Способы изготовления графеновых нанолент с применением растворителя - Google Patents

Способы изготовления графеновых нанолент с применением растворителя Download PDF

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RU2609915C2
RU2609915C2 RU2014114285A RU2014114285A RU2609915C2 RU 2609915 C2 RU2609915 C2 RU 2609915C2 RU 2014114285 A RU2014114285 A RU 2014114285A RU 2014114285 A RU2014114285 A RU 2014114285A RU 2609915 C2 RU2609915 C2 RU 2609915C2
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graphene nanoribbons
carbon nanotubes
gnr
functionalized
graphene
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RU2014114285A
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RU2014114285A (ru
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Джеймс М. Тур
Вей ЛУ
Бостьян ДЖЕНОРИО
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Уильям Марш Райс Юниверсити
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/168After-treatment
    • C01B32/174Derivatisation; Solubilisation; Dispersion in solvents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02Monomers containing only one unsaturated aliphatic radical
    • C08F112/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06Hydrocarbons
    • C08F112/08Styrene
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/168After-treatment
    • C01B32/178Opening; Filling
    • CCHEMISTRY; METALLURGY
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    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/18Nanoonions; Nanoscrolls; Nanohorns; Nanocones; Nanowalls
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • C01B32/184Preparation
    • CCHEMISTRY; METALLURGY
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • C01B32/194After-treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/56Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic condensed
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/035Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with saturated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82BNANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0009Forming specific nanostructures
    • B82B3/0033Manufacture or treatment of substrate-free structures, i.e. not connected to any support
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00Structure or properties of carbon nanotubes
    • C01B2202/06Multi-walled nanotubes
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00Structure or properties of graphene
    • C01B2204/06Graphene nanoribbons
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/70Nanostructure
    • Y10S977/734Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/84Manufacture, treatment, or detection of nanostructure
    • Y10S977/842Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
    • Y10S977/846Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes internal modifications, e.g. filling, endohedral modifications
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/902Specified use of nanostructure
    • Y10S977/961Specified use of nanostructure for textile or fabric treatment

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  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Inorganic Fibers (AREA)
  • Artificial Filaments (AREA)
RU2014114285A 2011-09-14 2012-09-14 Способы изготовления графеновых нанолент с применением растворителя RU2609915C2 (ru)

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US201161534553P 2011-09-14 2011-09-14
US61/534,553 2011-09-14
PCT/US2012/055414 WO2013040356A1 (en) 2011-09-14 2012-09-14 Solvent-based methods for production of graphene nanoribbons

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RU2609915C2 true RU2609915C2 (ru) 2017-02-07

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US (2) US9493355B2 (enExample)
EP (1) EP2755776A4 (enExample)
JP (1) JP2014527020A (enExample)
KR (1) KR20140069011A (enExample)
CN (1) CN103796766B (enExample)
AU (1) AU2012308433A1 (enExample)
BR (1) BR112014006025A2 (enExample)
CA (1) CA2848400A1 (enExample)
IL (1) IL231029A0 (enExample)
IN (1) IN2014DN02052A (enExample)
MX (1) MX2014003058A (enExample)
PH (1) PH12014500426A1 (enExample)
RU (1) RU2609915C2 (enExample)
SG (1) SG2014014880A (enExample)
TW (1) TWI568669B (enExample)
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RU2703635C1 (ru) * 2018-12-28 2019-10-21 федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный технический университет имени Н.Э. Баумана (национальный исследовательский университет)" (МГТУ им. Н.Э. Баумана) Способ повышения прочности на разрыв композитного материала с помощью предварительной пропитки углеволокон
RU2765294C1 (ru) * 2018-07-17 2022-01-28 Графенано Медикал Кеа, С.Л. Графеновый продукт и его терапевтические применения
RU2784523C2 (ru) * 2017-08-22 2022-11-28 Нтерма Корпорейшн Графеновые наноленты, графеновые нанопластинки и их смеси, а также способы синтеза
US11560313B2 (en) 2017-08-22 2023-01-24 Ntherma Corporation Graphene nanoribbons, graphene nanoplatelets and mixtures thereof and methods of synthesis

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WO2013040356A1 (en) 2011-09-14 2013-03-21 William Marsh Rice University Solvent-based methods for production of graphene nanoribbons
CN104204131A (zh) 2012-01-27 2014-12-10 威廉马什莱斯大学 并入了磁性碳纳米带和磁性功能化碳纳米带的井筒流体和其使用方法
CN104936888A (zh) 2012-12-04 2015-09-23 威廉马歇莱思大学 用于井眼流体电导率的碳纳米颗粒添加剂
US11128152B2 (en) 2014-04-08 2021-09-21 StoreDot Ltd. Systems and methods for adaptive fast-charging for mobile devices and devices having sporadic power-source connection
US10293704B2 (en) 2014-04-08 2019-05-21 StoreDot Ltd. Electric vehicles with adaptive fast-charging, utilizing supercapacitor-emulating batteries
US10549650B2 (en) 2014-04-08 2020-02-04 StoreDot Ltd. Internally adjustable modular single battery systems for power systems
US10110036B2 (en) 2016-12-15 2018-10-23 StoreDot Ltd. Supercapacitor-emulating fast-charging batteries and devices
GB201408221D0 (en) 2014-05-09 2014-06-25 Univ Manchester Functionalised graphene
JP6825781B2 (ja) * 2014-06-12 2021-02-03 センター ナショナル デ ラ レシェルシェ サイエンティフィック(シーエヌアールエス)Centre National De La Recherche Scientifique(Cnrs) 剥離ナノカーボン材料の水性および有機懸濁液、その作製方法及びその使用
US9840418B2 (en) 2014-06-16 2017-12-12 William Marsh Rice University Production of graphene nanoplatelets by oxidative anhydrous acidic media
US10199646B2 (en) 2014-07-30 2019-02-05 StoreDot Ltd. Anodes for lithium-ion devices
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US10299366B2 (en) 2015-08-06 2019-05-21 International Business Machines Corporation Tamper detection circuits
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US10096859B2 (en) 2016-04-07 2018-10-09 StoreDot Ltd. Electrolytes with ionic liquid additives for lithium ion batteries
US10818919B2 (en) 2016-04-07 2020-10-27 StoreDot Ltd. Polymer coatings and anode material pre-lithiation
US10367192B2 (en) 2016-04-07 2019-07-30 StoreDot Ltd. Aluminum anode active material
US11205796B2 (en) 2016-04-07 2021-12-21 StoreDot Ltd. Electrolyte additives in lithium-ion batteries
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US10367191B2 (en) 2016-04-07 2019-07-30 StoreDot Ltd. Tin silicon anode active material
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US10355271B2 (en) 2016-04-07 2019-07-16 StoreDot Ltd. Lithium borates and phosphates coatings
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US10680289B2 (en) 2016-04-07 2020-06-09 StoreDot Ltd. Buffering zone for preventing lithium metallization on the anode of lithium ion batteries
US10916811B2 (en) 2016-04-07 2021-02-09 StoreDot Ltd. Semi-solid electrolytes with flexible particle coatings
JP6769109B2 (ja) * 2016-05-24 2020-10-14 凸版印刷株式会社 ガスバリア性フィルムの製造方法
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US11246962B2 (en) 2016-08-22 2022-02-15 William Marsh Rice University Neuronal scaffold-water soluble graphene for treatment of severed spinal cords and neuronal repair
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JP6839355B2 (ja) * 2017-02-08 2021-03-10 富士通株式会社 グラフェンナノリボン、グラフェンナノリボンの製造方法及び半導体装置
US10183754B1 (en) * 2017-12-20 2019-01-22 The Florida International University Board Of Trustees Three dimensional graphene foam reinforced composite coating and deicing systems therefrom
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CN108383111A (zh) * 2018-05-11 2018-08-10 深圳市本征方程石墨烯技术股份有限公司 一种石墨烯浆料及其制备方法
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CN114735680B (zh) * 2022-04-27 2023-07-25 北京化工大学 一种石墨烯纳米带及其制备方法

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RU2784523C2 (ru) * 2017-08-22 2022-11-28 Нтерма Корпорейшн Графеновые наноленты, графеновые нанопластинки и их смеси, а также способы синтеза
US11560313B2 (en) 2017-08-22 2023-01-24 Ntherma Corporation Graphene nanoribbons, graphene nanoplatelets and mixtures thereof and methods of synthesis
RU2765294C1 (ru) * 2018-07-17 2022-01-28 Графенано Медикал Кеа, С.Л. Графеновый продукт и его терапевтические применения
RU2703635C1 (ru) * 2018-12-28 2019-10-21 федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный технический университет имени Н.Э. Баумана (национальный исследовательский университет)" (МГТУ им. Н.Э. Баумана) Способ повышения прочности на разрыв композитного материала с помощью предварительной пропитки углеволокон
RU2839727C1 (ru) * 2024-09-06 2025-05-12 федеральное государственное автономное образовательное учреждение высшего образования "Пермский национальный исследовательский политехнический университет" Способ получения композита из графитосодержащего материала для изготовления изделий

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US9493355B2 (en) 2016-11-15
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EP2755776A4 (en) 2015-10-28
BR112014006025A2 (pt) 2017-06-13
KR20140069011A (ko) 2014-06-09
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